AT78987B - Process for the preparation of water-soluble condensation products. - Google Patents
Process for the preparation of water-soluble condensation products.Info
- Publication number
- AT78987B AT78987B AT78987DA AT78987B AT 78987 B AT78987 B AT 78987B AT 78987D A AT78987D A AT 78987DA AT 78987 B AT78987 B AT 78987B
- Authority
- AT
- Austria
- Prior art keywords
- water
- condensation products
- preparation
- soluble condensation
- soluble
- Prior art date
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
<Desc/Clms Page number 1>
Verfahren zur Darstellung wasserlöslicher Kondensationsprodukte.
Es ist bekannt, dass sich naphtol mit Ameisensäure unter dem Einfluss von Salz. säure zu Kondensationsprodukten vereinigt (Zentrallblatt 1911, Seite 855). Das Produkt dieser Reaktion ist aber in Wasser nicht löslich. Man gelangt nun zu wasserlöslichen Kondensationsprodukten, wenn man als Kondensationsmittel konzentrierte Schwefelsäure verwendet und die Temperatur so wählt, dass gleichzeitig Sulfierung erfolgt. Im Gegensatz zu der Kondensation mit Salzsäure titt auf diese Weise auch das ss-Naphtol in Reaktion.
Beispiel :
EMI1.1
20 kg Schwefelsäure von 66 Bé angerührt und langsam bis auf 150 bis 1700 erhitzt. Die Schmelze aus der zuerst Kohlenoxyd entweicht, färbt sich dunkel und gibt mit Wasser eine rötliche Fällung. Nachdem die Schmelze vollkommen in Wasser löslich geworden ist. wird dieselbe mit Wasser versetzt. Das Produkt zeigt nach dem Abstumpfen der über- schüssigen Schwefelsäure starke Fällbarkeit mit Leimlösung.
**WARNUNG** Ende DESC Feld kannt Anfang CLMS uberlappen**.
<Desc / Clms Page number 1>
Process for the preparation of water-soluble condensation products.
It is known that naphtol reacts with formic acid under the influence of salt. acid combined to form condensation products (Zentrallblatt 1911, page 855). However, the product of this reaction is not soluble in water. Water-soluble condensation products are now obtained if concentrated sulfuric acid is used as the condensation agent and the temperature is chosen so that sulphonation takes place at the same time. In contrast to the condensation with hydrochloric acid, the ß-naphtol also reacts in this way.
Example:
EMI1.1
20 kg of sulfuric acid from 66 Bé and slowly heated to 150 to 1700. The melt, from which carbon oxide escapes first, turns dark and gives a reddish precipitate with water. After the melt has become completely soluble in water. water is added to the same. After the excess sulfuric acid has been blunted, the product shows strong precipitability with glue solution.
** WARNING ** End of DESC field may overlap beginning of CLMS **.
Claims (1)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT78987T | 1917-01-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
AT78987B true AT78987B (en) | 1919-11-10 |
Family
ID=3600526
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT78987D AT78987B (en) | 1917-01-11 | 1917-01-11 | Process for the preparation of water-soluble condensation products. |
Country Status (1)
Country | Link |
---|---|
AT (1) | AT78987B (en) |
-
1917
- 1917-01-11 AT AT78987D patent/AT78987B/en active
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