AT69755B - Process for the preparation of nitric acid urea. - Google Patents
Process for the preparation of nitric acid urea.Info
- Publication number
- AT69755B AT69755B AT69755DA AT69755B AT 69755 B AT69755 B AT 69755B AT 69755D A AT69755D A AT 69755DA AT 69755 B AT69755 B AT 69755B
- Authority
- AT
- Austria
- Prior art keywords
- nitric acid
- preparation
- acid urea
- urea
- temperature
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 3
- GHKNVDRFFNAVHG-UHFFFAOYSA-N nitric acid urea Chemical compound [N+](=O)(O)[O-].NC(=O)N.[N+](=O)(O)[O-].NC(=O)N GHKNVDRFFNAVHG-UHFFFAOYSA-N 0.000 title claims 2
- 238000002360 preparation method Methods 0.000 title description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 4
- 229910017604 nitric acid Inorganic materials 0.000 claims description 4
- QHDUJTCUPWHNPK-UHFFFAOYSA-N methyl 7-methoxy-2h-indazole-3-carboxylate Chemical compound COC1=CC=CC2=C(C(=O)OC)NN=C21 QHDUJTCUPWHNPK-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
<Desc/Clms Page number 1>
EMI1.1
EMI1.2
<Desc/Clms Page number 2>
ausreicht, ein Ansteigen der Temperatur bis zur beginnenden Gasentwicklung zu verhindern.
Eine Temperatur von 20 pflegt schon gefährlich zu sein. Sollte sich etwa Gas zu entwickeln anfangen, so unterbricht man unter fortgesetzter Kühlung den Säurezusatz. bis die Erscheinung aufhört, worauf fortgesetzt wird.
Die Lauge erstarrt zu einem dicken Brei. Es schadet nicht, wenn Salpetersäure im Überschuss angewendet wird, da in diesem Falle die Mutterlauge bei einer nächsten Operation zugesetzt werden kann.
Der Niederschlag wird abgenutscht und muss, was wesentlich ist, durch Decken mit einer reinen, konzentrierten, wässerigen Lösung von Harnstoffnitrat von anhaftender Salpetersäure befreit werden. Geschieht dies nicht, so zersetzt sich das Präparat beim Trocknen.
PATENT-ANSPRÜCHE :
1. Verfahren zur Darstellung von satpetersaurem Harnstoff durch Behandlung von wässerigen Lösungen von Cyanam@l mit Salpetersäure, dadurch gekennzeichnet, dass der Zusatz der Säure unter einer steten Abkühlung des Reaktionsgemisches und so langsam erfolgt. dass die Temperatur im Reaktionsgemisch nicht über 200 steigt.
<Desc / Clms Page number 1>
EMI1.1
EMI1.2
<Desc / Clms Page number 2>
sufficient to prevent the temperature from rising until gas evolution begins.
A temperature of 20 tends to be dangerous. If, for example, gas begins to develop, the addition of acid is interrupted while cooling is continued. until the apparition ceases, after which it continues.
The lye solidifies to a thick paste. There is no harm in using excess nitric acid, as in this case the mother liquor can be added during the next operation.
The precipitate is filtered off with suction and, what is essential, has to be freed from adhering nitric acid by covering it with a pure, concentrated, aqueous solution of urea nitrate. If this does not happen, the preparation will decompose on drying.
PATENT CLAIMS:
1. A method for the preparation of acidic urea by treatment of aqueous solutions of Cyanam @ l with nitric acid, characterized in that the addition of the acid takes place with a constant cooling of the reaction mixture and so slowly. that the temperature in the reaction mixture does not rise above 200.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT69755T | 1913-11-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AT69755B true AT69755B (en) | 1915-09-10 |
Family
ID=3591568
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT69755D AT69755B (en) | 1913-11-17 | 1913-11-17 | Process for the preparation of nitric acid urea. |
Country Status (1)
| Country | Link |
|---|---|
| AT (1) | AT69755B (en) |
-
1913
- 1913-11-17 AT AT69755D patent/AT69755B/en active
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| AT69755B (en) | Process for the preparation of nitric acid urea. | |
| AT107314B (en) | Process for the synthetic production of ammonia from the elements. | |
| DE1768890C3 (en) | Process for the preparation of 4-fluoro-3-nitroaniline | |
| DE414257C (en) | Process for the production of formic acid | |
| AT153694B (en) | Process for the production of ammonium persulphate from solutions by crystallization. | |
| DE576697C (en) | Process for the production of thiourea by the action of sulphides on calcium cyanamide | |
| DE499523C (en) | Process for the production of ª ‡ -oxy acids from their nitriles | |
| DE445668C (en) | Production of ammonium nitrate and blanc fixe | |
| AT26685B (en) | Process for the production of cyano compounds from gases containing cyano and ammonia. | |
| AT95482B (en) | Process for the production of urea from cyanamide. | |
| CH98312A (en) | Process for the preparation of 2: 3 diaminoanthraquinone. | |
| AT52958B (en) | Process for the simultaneous preparation of chlorammonium and sulphites of barium, strontium, calcium, magnesium and zinc. | |
| DE955413C (en) | Process for the production of hydrazine from hydroxylamine-O-sulfonic acid | |
| AT211845B (en) | Process for removing nitrous compounds from sulfuric acid | |
| AT81462B (en) | Process for the manufacture of guanylurea sulfate Process for the manufacture of guanylurea sulfate. t. | |
| AT318657B (en) | Process for the production of the new trisilver monoalkali (or alkaline earth, ammonium, quaternary ammonium) salts of diimidodioxosulfuric acid (VI) or the new tetrasilver diimidodioxosulfate (VI) | |
| AT64081B (en) | Process for the production of concentrated, low-ammonia copper oxide ammonia cellulose solutions. | |
| AT136012B (en) | Process for the preparation or regeneration of catalysts for the conversion of terpenes. | |
| DE285259C (en) | ||
| AT128350B (en) | Process for the preparation of low-electrolyte aqueous solutions of silk fibroin. | |
| DE420638C (en) | Process for the production of lead carbonate | |
| AT157699B (en) | Method for the preparation of water-soluble organic mercury compounds. | |
| DE921937C (en) | Process for purifying adipic dinitrile | |
| DE601068C (en) | Process for the production of sodium oxalate with simultaneous production of ammonium chloride | |
| DE603687C (en) | Process for the production of catalysts for ammonia synthesis |