AT377787B - METHOD FOR REMOVING RUST AND FORMING A PROTECTIVE LAYER AGAINST FURTHER RUST FORMATION - Google Patents

METHOD FOR REMOVING RUST AND FORMING A PROTECTIVE LAYER AGAINST FURTHER RUST FORMATION

Info

Publication number
AT377787B
AT377787B AT336983A AT336983A AT377787B AT 377787 B AT377787 B AT 377787B AT 336983 A AT336983 A AT 336983A AT 336983 A AT336983 A AT 336983A AT 377787 B AT377787 B AT 377787B
Authority
AT
Austria
Prior art keywords
rust
protective layer
forming
layer against
against further
Prior art date
Application number
AT336983A
Other languages
German (de)
Other versions
ATA336983A (en
Original Assignee
Pollhammer Otto
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pollhammer Otto filed Critical Pollhammer Otto
Priority to AT336983A priority Critical patent/AT377787B/en
Publication of ATA336983A publication Critical patent/ATA336983A/en
Application granted granted Critical
Publication of AT377787B publication Critical patent/AT377787B/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G5/00Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C26/00Coating not provided for in groups C23C2/00 - C23C24/00
    • C23C26/02Coating not provided for in groups C23C2/00 - C23C24/00 applying molten material to the substrate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Description

  

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   Die Erfindung betrifft eine Verfahren zum Entfernen von Rost und zur Bildung einer Schutzschicht gegen weitere Rostbildung. 



   Es ist bekannt, dass Eisen an feuchter, Kohlendioxyd enthaltender Luft bzw. in Kohlendioxyd und Luft enthaltendem Wasser unter Bildung von Eisenoxydhydrat (FeO, OH), angegriffen wird, wobei sich zunächst Eisencarbonate bilden, die dann der Hydrolyse unterliegen. 



   Die auf diesem Weg gebildete Eisenoxydschicht (Rost) stellt keine zusammenhängende, festhaftende Haut dar, sondern springt in Schuppen ab und legt frische Eisenoberflächen frei, so dass die Korrosion weiter in das Innere fortschreitet. Insbesondere bei Eisenblechen (Autokarosserien) kommt es auch zum   Durchrosten.   



   Werden die Rostschichten, wie dies beispielsweise aus F. Tödt Korrosion und Korrosionschutz, Walter de Gruyter & Co. vormals G. J. Göschen'sche Verlagshandlung, Berlin 1955, Seiten 538 bis 540 beispielsweise auf mechanischem Wege entfernt, dann müssen die so freigelegten Metalloberflächen vor erneutem korrosivem Angriff geschützt werden. 



   Aus der AT-PS Nr. 198583 ist ein Verbundwerkstoff aus einem eisernen Kernwerkstoff und Aluminium bekannt, wobei dieser Verbundwerkstoff durch Plattierung hergestellt werden soll. Hiebei wird in der AT-PS Nr. 198583 vorgeschlagen, ein Eisenblech zunächst mit einer 1% Lithium enthaltenen Aluminiumlegierung und im Anschluss daran mit einer Aluminiumlegierung, enthaltend 1% Magnesium zu plattieren. An keiner Stelle der AT-PS Nr. 198583 ist davon die Rede, dass beim Aufbringen der Aluminiumschichten auf den Grundwerkstoff aus Eisen an diesem allenfalls vorhandene Rostteile durch eine Reaktion mit Aluminiummetall entfernt werden können. 
 EMI1.1 
 

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   Bei der praktischen Durchführung des erfindungsgemässen Verfahrens wird man so vorgehen, dass man die Roststelle bis zum Glühen, vorzugsweise auf eine Temperatur zwischen 800 bis   1000 C   erhitzt. 



   Es wird also die beispielsweise mit Stahlwolle oder Schleifpapier vom gröbsten Rost befreite
Stelle beispielsweise mit einer Gasflamme bis zum Glühen erhitzt, wobei die Temperatur auch von der Dicke der Oxydschicht abhängen wird. 



   Bei der Durchführung des erfindungsgemässen Verfahrens empfiehlt es sich auch, dass man auch den die Roststelle umgebenden Bereich bis zum Glühen, vorzugsweise auf eine Temperatur zwischen 800 und   1000 C   erhitzt. 



   Das Anpressen der Aluminiumfolie (Schokoladenfolie, Frischhaltealuminiumfolie) auf die glühen- de bzw. erhitzte Metallstelle wird in der Regel mit einem Eisenroller   od. dgl.   durchgeführt, wobei es sich im Rahmen der Erfindung bewährt, wenn man den Anpressvorgang mehrmals ausführt. 



   Dabei empfiehlt es sich erfindungsgemäss so vorzugehen, dass man zwischen aufeinanderfolgen- den Anpressvorgängen jeweils abkühlen lässt. 



   Beim erfindungsgemässen Verfahren wird also der auf dem zu behandelnden Metallgegenstand vorhandene Rost zu Eisenmetall reduziert, wobei sich ein Aluminiumoxyd an Stellen ausbildet, wo Rost war. Das entstandene Aluminiumoxyd und restliches metallisches Aluminium aus der Aluminiumfolie verschliesst zusätzlich durch Rost allenfalls gebildete Poren. Die so gebildete Schutzschicht verhindert zuverlässlich weitere Rostbildung, da die festhaftende, zusammenhängende Aluminiumoxydschicht darunterliegendes Metall vor weiterem korrosivem Angriff (Rosten) schützt. 



    PATENTANSPRÜCHE :    
1. Verfahren zum Entfernen von Rost und zur Bildung einer Schutzschicht gegen weitere Rostbildung, gekennzeichnet durch folgende Schritte : a) Entfernen loser Rostanteile in an sich bekannter Weise,   b)   Erwärmen der Roststelle und c) Anpressen einer Aluminiumfolie auf die erwärmte Roststelle.



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   The invention relates to a method for removing rust and for forming a protective layer against further rust formation.



   It is known that iron is attacked in moist air containing carbon dioxide or in water containing carbon dioxide and air with the formation of iron oxide hydrate (FeO, OH), iron carbonates initially forming, which are then subject to hydrolysis.



   The iron oxide layer (rust) formed in this way does not represent a coherent, adherent skin, but jumps off in scales and exposes fresh iron surfaces, so that the corrosion progresses further inside. Rusting occurs in particular in the case of iron sheets (car bodies).



   If the rust layers, as for example from F. Tödt Corrosion and Corrosion Protection, Walter de Gruyter & Co. formerly GJ Göschen'sche Verlagshandlung, Berlin 1955, pages 538 to 540, are removed mechanically, for example, the metal surfaces thus exposed must be corrosive again Attack be protected.



   A composite material made of an iron core material and aluminum is known from AT-PS No. 198583, this composite material being intended to be produced by plating. Hiebei suggests in AT-PS No. 198583 to first plate an iron sheet with an aluminum alloy containing 1% lithium and then with an aluminum alloy containing 1% magnesium. At no point in AT-PS No. 198583 is it mentioned that when the aluminum layers are applied to the base material made of iron, any rust parts present on it can be removed by a reaction with aluminum metal.
 EMI1.1
 

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   When the process according to the invention is carried out in practice, the procedure will be such that the rust point is heated to an annealing temperature, preferably to a temperature between 800 and 1000.degree.



   It is freed of the coarsest rust, for example with steel wool or sandpaper
Place, for example, heated to a glow with a gas flame, the temperature also depending on the thickness of the oxide layer.



   When carrying out the method according to the invention, it is also recommended that the area surrounding the rust point be heated to an annealing temperature, preferably to a temperature between 800 and 1000.degree.



   The pressing of the aluminum foil (chocolate foil, fresh-keeping aluminum foil) onto the glowing or heated metal point is generally carried out using an iron roller or the like, it having proven itself within the scope of the invention if the pressing process is carried out several times.



   It is recommended to proceed according to the invention in such a way that it is allowed to cool down between successive pressing processes.



   In the method according to the invention, the rust present on the metal object to be treated is therefore reduced to iron metal, an aluminum oxide being formed in places where there was rust. The resulting aluminum oxide and the remaining metallic aluminum from the aluminum foil additionally seals any pores formed by rust. The protective layer formed in this way reliably prevents further rust formation, since the firmly adhering, coherent aluminum oxide layer underneath protects metal from further corrosive attack (rusting).



    PATENT CLAIMS:
1. A method for removing rust and for forming a protective layer against further rust formation, characterized by the following steps: a) removing loose rust parts in a manner known per se, b) heating the rust point and c) pressing an aluminum foil onto the heated rust point.

 

Claims (1)

2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass lose Rostanteile durch Abbürsten und/oder Abschleifen entfernt werden.  2. The method according to claim 1, characterized in that loose rust parts are removed by brushing and / or grinding. 3. Verfahren nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass man lose Rostanteile bis auf eine restliche Rostschichte entfernt.  3. The method according to claim 1 or 2, characterized in that loose rust is removed except for a remaining layer of rust. 4. Verfahren nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass man die Roststelle bis zum Glühen, vorzugsweise auf eine Temperatur zwischen 800 und 10000C erhitzt.  4. The method according to any one of claims 1 to 3, characterized in that the rust point is heated to glow, preferably to a temperature between 800 and 10000C. 5. Verfahren nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass man auch den die Roststelle umgebenden Bereich bis zum Glühen, vorzugsweise auf eine Temperatur zwischen 800 und 1000 C erhitzt.  5. The method according to any one of claims 1 to 4, characterized in that the area surrounding the rust point is heated to annealing, preferably to a temperature between 800 and 1000 C. 6. Verfahren nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, dass man den Anpressvorgang mehmals ausführt.  6. The method according to any one of claims 1 to 5, characterized in that the pressing process is carried out several times. 7. Verfahren nach Anspruch 6, dadurch gekennzeichnet, dass man zwischen aufeinanderfolgenden Anpressvorgängen jeweils abkühlen lässt.  7. The method according to claim 6, characterized in that each is allowed to cool between successive pressing operations.
AT336983A 1983-09-22 1983-09-22 METHOD FOR REMOVING RUST AND FORMING A PROTECTIVE LAYER AGAINST FURTHER RUST FORMATION AT377787B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT336983A AT377787B (en) 1983-09-22 1983-09-22 METHOD FOR REMOVING RUST AND FORMING A PROTECTIVE LAYER AGAINST FURTHER RUST FORMATION

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
AT336983A AT377787B (en) 1983-09-22 1983-09-22 METHOD FOR REMOVING RUST AND FORMING A PROTECTIVE LAYER AGAINST FURTHER RUST FORMATION

Publications (2)

Publication Number Publication Date
ATA336983A ATA336983A (en) 1984-09-15
AT377787B true AT377787B (en) 1985-04-25

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
AT336983A AT377787B (en) 1983-09-22 1983-09-22 METHOD FOR REMOVING RUST AND FORMING A PROTECTIVE LAYER AGAINST FURTHER RUST FORMATION

Country Status (1)

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AT (1) AT377787B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1043424A1 (en) * 1999-04-07 2000-10-11 General Electric Company Method for locally removing oxidation and corrosion product from the surface of turbine engine components

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT198583B (en) * 1956-08-11 1958-07-10 Ver Leichtmetall Werke Ges M B Composite
US3210840A (en) * 1961-08-08 1965-10-12 Composite Metal Products Inc Stainless steel clad aluminum and methods of making same

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT198583B (en) * 1956-08-11 1958-07-10 Ver Leichtmetall Werke Ges M B Composite
US3210840A (en) * 1961-08-08 1965-10-12 Composite Metal Products Inc Stainless steel clad aluminum and methods of making same

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
F. TÖDT "KORROSION U. KORROSIONSSCHUTZ", WALTER D. GRUYTER & CO. VORMALS G.J. GÖSCHEN'SCHE VERLAGSHANDLUNG, BERLIN 1955, SEITEN 538 BIS 540 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1043424A1 (en) * 1999-04-07 2000-10-11 General Electric Company Method for locally removing oxidation and corrosion product from the surface of turbine engine components

Also Published As

Publication number Publication date
ATA336983A (en) 1984-09-15

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