AT34243B - Process for the preparation of CC dialkylbarbituric acids. - Google Patents
Process for the preparation of CC dialkylbarbituric acids.Info
- Publication number
- AT34243B AT34243B AT34243DA AT34243B AT 34243 B AT34243 B AT 34243B AT 34243D A AT34243D A AT 34243DA AT 34243 B AT34243 B AT 34243B
- Authority
- AT
- Austria
- Prior art keywords
- preparation
- dialkylbarbituric acids
- dialkylbarbituric
- acids
- condensation products
- Prior art date
Links
- 239000002253 acid Substances 0.000 title claims 2
- 150000007513 acids Chemical class 0.000 title claims 2
- 238000000034 method Methods 0.000 title claims 2
- 238000002360 preparation method Methods 0.000 title claims 2
- 239000007859 condensation product Substances 0.000 claims description 3
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims 1
- FTOAOBMCPZCFFF-UHFFFAOYSA-N 5,5-diethylbarbituric acid Chemical compound CCC1(CC)C(=O)NC(=O)NC1=O FTOAOBMCPZCFFF-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229960002319 barbital Drugs 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- DPHBCBNBDNTWKL-UHFFFAOYSA-N 2,2-diethyl-3-hydroxybutanedinitrile Chemical compound C(C)C(C(C#N)O)(C#N)CC DPHBCBNBDNTWKL-UHFFFAOYSA-N 0.000 description 1
- SQSPRWMERUQXNE-UHFFFAOYSA-N Guanylurea Chemical compound NC(=N)NC(N)=O SQSPRWMERUQXNE-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
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Wasser werden grosse Kristalle von reiner Diäthylbarbitursäure erhalten.
Beispiel 4 : 10 Teile des Kondensationsprodukts von Diäthylmalonitril mit Guanylharnstoff werden 4 Stunden mit 350 Teilen Salpetersäure (50prozentig) am Rückflusskühler gekocht. Die dal) ei entstehende Diäthylbarbitursäure wird mit Äther ausgeschüttelt und durch Umkristallisieren aus Wasser rein erhalten.
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EMI2.1
Water, large crystals of pure diethylbarbituric acid are obtained.
Example 4: 10 parts of the condensation product of diethyl malonitrile with guanylurea are refluxed for 4 hours with 350 parts of nitric acid (50 percent). The resulting diethylbarbituric acid is extracted with ether and obtained pure by recrystallization from water.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE165223D | 1904-03-18 | ||
| DE187990D | 1904-10-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AT34243B true AT34243B (en) | 1908-09-10 |
Family
ID=25754169
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT34243D AT34243B (en) | 1904-03-18 | 1906-02-03 | Process for the preparation of CC dialkylbarbituric acids. |
Country Status (1)
| Country | Link |
|---|---|
| AT (1) | AT34243B (en) |
-
1906
- 1906-02-03 AT AT34243D patent/AT34243B/en active
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