AR097927A1 - Instalación y procedimiento para la producción de ésteres de ácidos grasos utilizables como combustible - Google Patents

Instalación y procedimiento para la producción de ésteres de ácidos grasos utilizables como combustible

Info

Publication number
AR097927A1
AR097927A1 ARP140103707A ARP140103707A AR097927A1 AR 097927 A1 AR097927 A1 AR 097927A1 AR P140103707 A ARP140103707 A AR P140103707A AR P140103707 A ARP140103707 A AR P140103707A AR 097927 A1 AR097927 A1 AR 097927A1
Authority
AR
Argentina
Prior art keywords
reaction
alcohol
installation
esters
fuel
Prior art date
Application number
ARP140103707A
Other languages
English (en)
Original Assignee
Supercritical Ideas Sl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Supercritical Ideas Sl filed Critical Supercritical Ideas Sl
Publication of AR097927A1 publication Critical patent/AR097927A1/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11CFATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/04Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
    • C11C3/10Ester interchange
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053Details of the reactor
    • B01J19/0066Stirrers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18Stationary reactors having moving elements inside
    • B01J19/1812Tubular reactors
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/02Preparation of carboxylic acid esters by interreacting ester groups, i.e. transesterification
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/08Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11CFATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/003Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11CFATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/04Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00074Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/0009Coils
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00074Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00103Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/03Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00Components of fuel compositions
    • C10L2200/04Organic compounds
    • C10L2200/0461Fractions defined by their origin
    • C10L2200/0469Renewables or materials of biological origin
    • C10L2200/0476Biodiesel, i.e. defined lower alkyl esters of fatty acids first generation biodiesel
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2270/00Specifically adapted fuels
    • C10L2270/02Specifically adapted fuels for internal combustion engines
    • C10L2270/026Specifically adapted fuels for internal combustion engines for diesel engines, e.g. automobiles, stationary, marine
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/06Heat exchange, direct or indirect
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/24Mixing, stirring of fuel components
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Fats And Perfumes (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

Comprende unos depósitos (10) de aceites y/o grasas a tratar y (11) de alcohol ligero, unas bombas (3) y (4) que alimentan dichas materias a un recipiente tubular de reacción (30) de desarrollo sinuoso dotado de medios de calentamiento para mantener en su interior una temperatura supercrítica respecto al alcohol utilizado y una presión, para producir unas reacciones de esterificación y transesterificación, sin presencia de catalizadores de dichos aceites y/o grasas y alcohol, un intercambiador de calor (8) para calentamiento de los afluentes y enfriamiento de los efluentes de reacción y un depósito de despresurización (21) de los efluentes de reacción. La instalación comprende medios (22, 23, 28) para generar una agitación del producto de reacción a la presión y temperatura de reacción en uno o más tramos del recipiente tubular (30) que abarcan un sector del reactor previo a su zona terminal de salida hacia el depósito de despresurización (21).
ARP140103707A 2013-10-03 2014-10-03 Instalación y procedimiento para la producción de ésteres de ácidos grasos utilizables como combustible AR097927A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP13380042.5A EP2857483B1 (en) 2013-10-03 2013-10-03 Plant and method for production of fatty acid esters to be used as fuel

Publications (1)

Publication Number Publication Date
AR097927A1 true AR097927A1 (es) 2016-04-20

Family

ID=49680949

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP140103707A AR097927A1 (es) 2013-10-03 2014-10-03 Instalación y procedimiento para la producción de ésteres de ácidos grasos utilizables como combustible

Country Status (9)

Country Link
US (1) US9909085B2 (es)
EP (1) EP2857483B1 (es)
JP (1) JP6462701B2 (es)
CN (1) CN105793404B (es)
AR (1) AR097927A1 (es)
BR (1) BR112016007309A2 (es)
ES (1) ES2614454T3 (es)
UY (1) UY35767A (es)
WO (1) WO2015049573A1 (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2614454T3 (es) 2013-10-03 2017-05-31 Supercritical Ideas, Sl Instalación y procedimiento para la producción de ésteres de ácidos grasos utilizables como combustible
WO2016004958A1 (en) * 2014-07-11 2016-01-14 Aarhus Universitet A method and apparatus for producing biofuel in an oscillating flow production line under supercritical fluid conditions

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3837950B2 (ja) * 1998-09-09 2006-10-25 住友化学株式会社 脂肪酸エステルの製造方法および脂肪酸エステルを含む燃料
JP4997681B2 (ja) * 2001-09-28 2012-08-08 住友化学株式会社 脂肪酸エステルの製造方法および製造装置
WO2003106604A1 (ja) * 2002-06-13 2003-12-24 株式会社京都ロンフォード 脂肪酸アルキルエステル組成物の製造方法
JP2004182966A (ja) 2002-10-07 2004-07-02 Kimura Chem Plants Co Ltd 脂肪酸エステルの製造装置
JP2006036817A (ja) * 2004-07-22 2006-02-09 Kimura Chem Plants Co Ltd 脂肪酸エステルの製造方法および製造装置
JP4907872B2 (ja) * 2005-01-05 2012-04-04 木村化工機株式会社 脂肪酸エステルの製造方法および製造装置
WO2007026032A1 (es) 2005-09-01 2007-03-08 Integral Bioenergies Systems, S.L. Reactor químico para la alcoholisis supercrítica de todo tipo de grasas y aceites con distintos tipos de alcoholes
KR100806353B1 (ko) * 2005-11-18 2008-02-27 노민정 초임계 알코올을 이용한 바이오디젤의 제조 방법
US20090277077A1 (en) * 2007-03-05 2009-11-12 Gleason Rodney J Biodiesel fuel and method of manufacture therefor
WO2009118779A1 (ja) * 2008-03-26 2009-10-01 株式会社大正理化 バイオディーゼル燃料製造装置及びバイオディーゼル燃料製造方法
US8188305B2 (en) * 2009-02-03 2012-05-29 David Miller Method of producing biodiesel with supercritical alcohol and apparatus for same
ES2614454T3 (es) 2013-10-03 2017-05-31 Supercritical Ideas, Sl Instalación y procedimiento para la producción de ésteres de ácidos grasos utilizables como combustible

Also Published As

Publication number Publication date
BR112016007309A2 (pt) 2017-08-01
JP2016536445A (ja) 2016-11-24
ES2614454T3 (es) 2017-05-31
CN105793404B (zh) 2020-01-03
US9909085B2 (en) 2018-03-06
EP2857483A1 (en) 2015-04-08
CN105793404A (zh) 2016-07-20
EP2857483B1 (en) 2016-08-24
WO2015049573A1 (en) 2015-04-09
US20160264911A1 (en) 2016-09-15
UY35767A (es) 2015-04-30
JP6462701B2 (ja) 2019-01-30

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