AR094060A1 - Tetrahidronaftil(tio)carboxamidas - Google Patents

Tetrahidronaftil(tio)carboxamidas

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Publication number
AR094060A1
AR094060A1 ARP130104794A ARP130104794A AR094060A1 AR 094060 A1 AR094060 A1 AR 094060A1 AR P130104794 A ARP130104794 A AR P130104794A AR P130104794 A ARP130104794 A AR P130104794A AR 094060 A1 AR094060 A1 AR 094060A1
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Argentina
Prior art keywords
alkyl
cycloalkyl
optionally substituted
different
halogen atoms
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ARP130104794A
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English (en)
Inventor
Dr Wachendorff-Neumann Ulrike
Dr Carles Lionel
Dubost Christophe
Vors Jean
Pierre - Brunet Stephane
Coqueron Pierre
Yves - Dr Es-Sayed Mazen
Maechling Simon
Sudau Alexander
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Bayer Cropscience Ag
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Publication of AR094060A1 publication Critical patent/AR094060A1/es

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    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D333/38—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
    • A—HUMAN NECESSITIES
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    • A01N43/10—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with sulfur as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/32—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/57—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings being part of condensed ring systems of the carbon skeleton
    • C07C211/60—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings being part of condensed ring systems of the carbon skeleton containing a ring other than a six-membered aromatic ring forming part of at least one of the condensed ring systems
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    • C07C225/22—Compounds containing amino groups and doubly—bound oxygen atoms bound to the same carbon skeleton, at least one of the doubly—bound oxygen atoms not being part of a —CHO group, e.g. amino ketones having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
    • C07D241/02—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings
    • C07D241/10—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D241/14—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D241/24—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
    • C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D277/32—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
    • C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D277/32—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D277/56—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
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    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/68—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
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    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D327/00—Heterocyclic compounds containing rings having oxygen and sulfur atoms as the only ring hetero atoms
    • C07D327/02—Heterocyclic compounds containing rings having oxygen and sulfur atoms as the only ring hetero atoms one oxygen atom and one sulfur atom
    • C07D327/06—Six-membered rings

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  • Organic Chemistry (AREA)
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  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
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  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La presente se refiere a tetrahidronaftil(tio)carboxamidas, a los procedimientos para preparar estos compuestos, a las composiciones que comprenden estos compuestos, y a su uso como compuestos biológicamente activos, en especial para controlar los microorganismos perjudiciales en la protección de cultivos y en la protección de materiales. Reivindicación 1: Tetrahidronaftil(tio)carboxamidas de la fórmula (1) en la que Het representa un radical seleccionado del grupo de formulas Het1 a Het11; X¹, X² y X³ representan de modo independiente hidrógeno; halógeno; ciano; nitro, hidroxilo; alquilo C₁₋₁₆, haloalquilo C₁₋₆ que tiene 1 a 9 átomos de halógeno idénticos o diferentes; cicloalquilo C₃₋₇, halocicloalquilo C₃₋₇ que tiene 1 a 9 átomos de halógeno idénticos o diferentes; alcoxi C₁₋₆; haloalcoxi C₁₋₆ que tiene 1 a 9 átomos de halógeno idénticos o diferentes; con la condición de que cuando Het representa Het¹, X¹ no es difluoro- o diclorometilo y X² no es cloro o flúor; T representa un átomo de oxígeno o azufre; Q representa hidrógeno, alquil C₁₋₆sulfonilo, alcoxi C₁₋₄-alquilo C₁₋₄, haloalquil C₁₋₄sulfonilo, halo-alcoxi C₁₋₄-alquilo C₁₋₄; X representa halógeno, nitro, ciano, alquilo C₁₋₁₂; haloalquilo C₁₋₆ que tiene 1 a 9 átomos de halógeno idénticos o diferentes; alcoxi C₁₋₆; haloalcoxi C₁₋₆ que tiene 1 a 9 átomos de halógeno idénticos o diferentes; alquil C₁₋₆sulfanilo; haloalquil C₁₋₆sulfanilo que tiene 1 a 9 átomos de halógeno idénticos o diferentes; alquil C₁₋₆sulfonilo; haloalquil C₁₋₆sulfonilo que tiene 1 a 9 átomos de halógeno idénticos o diferentes; alquenilo C₂₋₁₂; alquinilo C₂₋₁₂; cicloalquilo C₃₋₇; fenilo; trialquil C₁₋₈sililo; trialquil C₁₋₈silil-alquilo C₁₋₈; m representa ,1, 2 ó 3; R¹, R², R³, R⁴, R⁵, R⁶, R⁷ y R⁸ de modo independiente entre sí representan hidrógeno; halógeno; ciano; alquilo C₁₋₁₆; haloalquilo C₂₋₁₆ que tiene 1 a 9 átomos de halógeno idénticos o diferentes; cicloalquilo C₃₋₈; halocicloalquilo C₃₋₇ que tiene 1 a 9 átomos de halógeno idénticos o diferentes; haloalquilo C₁₋₆ que tiene 1 a 9 átomos de halógeno idénticos o diferentes; (cicloalquil C₃₋₈)-alquilo C₁₋₈; (cicloalquil C₃₋₈)-cicloalquilo C₃₋₈; alquenilo C₂₋₁₆; alquinilo C₂₋₁₆; alquenilo C₂₋₁₆-alquilo C₁₋₁₆; alquinilo C₂₋₁₆-alquilo C₁₋₁₆; alcoxi C₁₋₁₆; cicloalquiloxi C₃₋₈; (cicloalquil C₃₋₈)-alquiloxi C₁₋₈; alquil C₁₋₈sulfanilo; cicloalquil C₃₋₈sulfanilo; (cicloalquilo C₃₋₈)-alquil C₁₋₈sulfanilo; alqueniloxi C₂₋₁₆; alquiniloxi C₃₋₈; aril-alquiloxi C₁₋₈ que está opcionalmente sustituido con hasta 6 grupos Rᵇ idénticos o diferentes; aril-alquil C₁₋₈sulfanilo que está opcionalmente sustituido con hasta 6 grupos Rᵇ idénticos o diferentes; ariloxi que está opcionalmente sustituido con hasta 6 grupos Rᵇ idénticos o diferentes; arilsulfanilo que está opcionalmente sustituido con hasta 6 grupos Rᵇ idénticos o diferentes; (cicloalquil C₃₋₈)-alquenilo C₂₋₈; (cicloalquil C₃₋₈)-alquinilo C₂₋₈; trialquil C₁₋₈sililo; trialquil C₁₋₈silil-alquilo C₁₋₈; aril-alquilo C₁₋₈ que está opcionalmente sustituido con hasta 6 grupos Rᵇ idénticos o diferentes; aril-alquenilo C₂₋₈ que está opcionalmente sustituido con hasta 6 grupos Rᵇ idénticos o diferentes; aril-alquinilo C₂₋₈ que está opcionalmente sustituido con hasta 6 grupos Rᵇ idénticos o diferentes; alquilamino C₁₋₈; di-alquilamino C₁₋₈; arilamino que está opcionalmente sustituido con hasta 6 grupos Rᵇ idénticos o diferentes; alquil C₁₋₈carbonilo; alquil C₁₋₈carboniloxi; alquil C₁₋₈carbonilamino; alcoxi C₁₋₈carbonilo; alquiloxi C₁₋₈carboniloxi; alquilamino C₁₋₈carboniloxi; di-alquilamino C₁₋₈carboniloxi; N-(alquil C₁₋₈)hidroxicarbamoilo; alcoxi C₁₋₈carbamoilo; N-(alquil C₁₋₈)-alcoxi C₁₋₈carbamoilo; aril-alquilamino C₁₋₈ que está opcionalmente sustituido con hasta 6 grupos Rᵇ idénticos o diferentes; (alcoxiimino C₁₋₆)-alquilo C₁₋₈; (cicloalcoxiimino C₂₋₈)-alquilo C₁₋₈; alquiliminoxi C₁₋₈; alquiliminoxi C₁₋₆-alquilo C₁₋₈; cada uno de los cuales está opcionalmente sustituido; en la que uno o más sustituyentes del grupo seleccionado de R¹, R², R³, R⁴, R⁵, R⁶, R⁷ y R⁸ no representa hidrógeno; o R¹ y R² representan junto con el carbono al cual están unidos un cicloalquilo C₃₋₈; cicloalquenilo C₃₋₈, cada uno de los cuales está opcionalmente sustituido; o puede representar un grupo =C(Y¹)Y² o un grupo N-O-Rᶜ; R³ y R⁴ representan junto con el carbono al cual están unidos un cicloalquilo C₃₋₈; cicloalquenilo C₃₋₈, cada uno de los cuales está opcionalmente sustituido; o puede representar un grupo =C(Y¹)Y² o un grupo N-O-Rᶜ; R⁵ y R⁶ representan junto con el carbono al cual están unidos un cicloalquilo C₃₋₈; cicloalquenilo C₃₋₈, cada uno de los cuales está opcionalmente sustituido; o puede representar un grupo =C(Y¹)Y² o un grupo N-O-Rᶜ; R⁷ y R⁸ representan junto con el carbono al cual están unidos un cicloalquilo C₃₋₈; cicloalquenilo C₃₋₈, cada uno de los cuales está opcionalmente sustituido; o puede representar un grupo =C(Y¹)Y² o un grupo =N-O-Rᶜ; R¹ y R³ representan con los carbonos a los cuales están unidos un cicloalquilo C₃₋₈; cicloalquenilo C₃₋₈, cada uno de los cuales está opcionalmente sustituido; R³ y R⁵ representan con los carbonos a los cuales están unidos un cicloalquilo C₃₋₈; cicloalquenilo C₃₋₈, cada uno de los cuales está opcionalmente sustituido; R⁵ y R⁷ representan con los carbonos a los cuales están unidos un cicloalquilo C₃₋₈; cicloalquenilo C₃₋₈, cada uno de los cuales está opcionalmente sustituido; Rᵇ representa halógeno; nitro, ciano, alquilo C₁₋₁₂; haloalquilo C₁₋₆ que tiene 1 a 9 átomos de halógeno idénticos o diferentes; alcoxi C₁₋₆; haloalcoxi C₁₋₆ que tiene 1 a 9 átomos de halógeno idénticos o diferentes; alquil C₁₋₆sulfanilo; haloalquil C₁₋₆sulfanilo que tiene 1 a 9 átomos de halógeno idénticos o diferentes; alquil C₁₋₆sulfonilo; haloalquil C₁₋₆sulfonilo que tiene 1 a 9 átomos de halógeno idénticos o diferentes; alquenilo C₂₋₁₂; alquinilo C₂₋₁₂; cicloalquilo C₃₋₇; fenilo; trialquil C₁₋₈sililo; trialquil C₁₋₈silil-alquilo C₁₋₈; Y¹ e Y² de modo independiente entre sí representan hidrógeno, halógeno, alquilo C₁₋₁₂; haloalquilo C₁₋₆ que tiene 1 a 9 átomos de halógeno idénticos o diferentes; alquil C₁₋₈sulfanilo; fenilo; cada uno de los cuales está opcionalmente sustituido; o Y¹ e Y² pueden formar junto con el carbono al cual están unidos un cicloalquilo C₃₋₈ o un cicloalquenilo C₃₋₈ o un heterociclo saturado de 5, 6 ó 7 miembros; cada uno de los cuales está opcionalmente sustituido; Rᶜ representa alquilo C₁₋₁₆; haloalquilo C₁₋₆ que tiene 1 a 9 átomos de halógeno idénticos o diferentes; cicloalquilo C₃₋₈; (cicloalquil C₃₋₈)-alquilo C₁₋₈; (cicloalquil C₃₋₈)-cicloalquilo C₃₋₈; alquenilo C₂₋₈-alquilo C₁₋₁₆; alquinil C₂₋₈-alquilo C₁₋₁₆; aril-alquilo C₁₋₈ que está opcionalmente sustituido con hasta 6 grupos Rᵇ idénticos o diferentes; cada uno de los cuales está opcionalmente sustituido.
ARP130104794A 2012-12-19 2013-12-17 Tetrahidronaftil(tio)carboxamidas AR094060A1 (es)

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