AR092617A1 - METHOD AND ELECTROCHEMICAL DEVICE FOR RECOVERY OF LITHIUM WITH LOW ENVIRONMENTAL IMPACT FROM WATER SOLUTIONS - Google Patents

METHOD AND ELECTROCHEMICAL DEVICE FOR RECOVERY OF LITHIUM WITH LOW ENVIRONMENTAL IMPACT FROM WATER SOLUTIONS

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Publication number
AR092617A1
AR092617A1 ARP130103351A ARP130103351A AR092617A1 AR 092617 A1 AR092617 A1 AR 092617A1 AR P130103351 A ARP130103351 A AR P130103351A AR P130103351 A ARP130103351 A AR P130103351A AR 092617 A1 AR092617 A1 AR 092617A1
Authority
AR
Argentina
Prior art keywords
lithium
recovery
environmental impact
low environmental
manganese
Prior art date
Application number
ARP130103351A
Other languages
Spanish (es)
Inventor
Julio Calvo Ernesto
Marchini Florencia
Original Assignee
Consejo Nac De Investig Cientificas Y Tecn (Conicet)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consejo Nac De Investig Cientificas Y Tecn (Conicet) filed Critical Consejo Nac De Investig Cientificas Y Tecn (Conicet)
Publication of AR092617A1 publication Critical patent/AR092617A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/02—Electrolytic production, recovery or refining of metals by electrolysis of solutions of light metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/002—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells of cells comprising at least an electrode made of particles
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/02—Electrodes; Connections thereof
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/04—Diaphragms; Spacing elements
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/54—Reclaiming serviceable parts of waste accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00—Hybrid cells; Manufacture thereof
    • H01M12/08—Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/663—Selection of materials containing carbon or carbonaceous materials as conductive part, e.g. graphite, carbon fibres
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/84—Recycling of batteries or fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Electrolytic Production Of Metals (AREA)

Abstract

Método eficiente y de bajo impacto ambiental para la recuperación de litio a partir de soluciones acuosas, por ejemplo, salmueras de lagos salinos de elevada altitud. El método comprende el uso de un reactor electroquímico con electrodos que son altamente selectivos para litio, donde los iones litio son insertados en la estructura cristalina de óxido de manganeso en el cátodo, y extraídos de la estructura cristalina de óxido de manganeso en el ánodo. También se divulgan electrodos tridimensionales de carbón embebidos en óxidos de manganeso formados mediante impregnación de un soporte poroso por ejemplo un fieltro de carbón, con una suspensión de óxido de manganeso/negro de carbón.Efficient method with low environmental impact for the recovery of lithium from aqueous solutions, for example, brines from high altitude salt lakes. The method comprises the use of an electrochemical reactor with electrodes that are highly selective for lithium, where lithium ions are inserted into the crystalline structure of manganese oxide in the cathode, and extracted from the crystalline structure of manganese oxide in the anode. Three-dimensional carbon electrodes embedded in manganese oxides formed by impregnating a porous support such as a carbon felt, with a suspension of manganese / carbon black oxide are also disclosed.

ARP130103351A 2012-09-19 2013-09-18 METHOD AND ELECTROCHEMICAL DEVICE FOR RECOVERY OF LITHIUM WITH LOW ENVIRONMENTAL IMPACT FROM WATER SOLUTIONS AR092617A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261702985P 2012-09-19 2012-09-19
US13/841,896 US20140076734A1 (en) 2012-09-19 2013-03-15 Method and electrochemical device for low environmental impact lithium recovery from aqueous solutions

Publications (1)

Publication Number Publication Date
AR092617A1 true AR092617A1 (en) 2015-04-29

Family

ID=50273336

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP130103351A AR092617A1 (en) 2012-09-19 2013-09-18 METHOD AND ELECTROCHEMICAL DEVICE FOR RECOVERY OF LITHIUM WITH LOW ENVIRONMENTAL IMPACT FROM WATER SOLUTIONS

Country Status (6)

Country Link
US (2) US20140076734A1 (en)
CN (1) CN106170340B (en)
AR (1) AR092617A1 (en)
AU (1) AU2013317990A1 (en)
CL (1) CL2015000568A1 (en)
WO (1) WO2014047347A1 (en)

Cited By (6)

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US11794182B2 (en) 2017-08-02 2023-10-24 Lilac Solutions, Inc. Lithium extraction with porous ion exchange beads
US11806641B2 (en) 2016-11-14 2023-11-07 Lilac Solutions, Inc. Lithium extraction with coated ion exchange particles
US11865531B2 (en) 2018-02-28 2024-01-09 Lilac Solutions, Inc. Ion exchange reactor with particle traps for lithium extraction
US11964876B2 (en) 2020-06-09 2024-04-23 Lilac Solutions, Inc. Lithium extraction in the presence of scalants
US11986816B2 (en) 2021-04-23 2024-05-21 Lilac Solutions, Inc. Ion exchange devices for lithium extraction
US12076662B2 (en) 2022-03-28 2024-09-03 Lilac Solutions, Inc. Devices for efficient sorbent utilization in lithium extraction

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KR101361836B1 (en) * 2012-05-16 2014-02-12 서울대학교산학협력단 Method for recovering a metal from solution, system for recovering a metal from solution, and system for recovering lithium from salt water
US20140076734A1 (en) * 2012-09-19 2014-03-20 Consejo Nacional De Investigaciones Cientificas Y Tecnicas (Conicet) Method and electrochemical device for low environmental impact lithium recovery from aqueous solutions
EP3045223B1 (en) * 2013-09-13 2019-06-19 Hideki Koyanaka Use of a tritium adsorbent, method for separating tritium from within water, and method for regenerating tritium adsorbent
CN104307526B (en) * 2014-10-11 2016-08-31 北京化工大学 A kind of support type lithium doping cobaltosic oxide nano composite catalyst and preparation method thereof
EP3303660A4 (en) 2015-05-30 2019-04-10 alpha-En Corporation High purity lithium and associated products and processes
CN105937038A (en) * 2016-06-17 2016-09-14 天齐锂业股份有限公司 Method for recycling lithium in lithium iron phosphate through electrochemical method
CN105937039A (en) * 2016-06-17 2016-09-14 天齐锂业股份有限公司 Method for recycling lithium in lithium battery cathode materials by electrochemical method
CN108011143A (en) * 2016-10-28 2018-05-08 株式会社赛尔真 By the method for solution and salt Water Sproading lithium
CN109841799B (en) * 2017-11-28 2021-07-06 中国科学院大连化学物理研究所 Activated carbon electrode and preparation and application thereof
CN109440132A (en) * 2018-10-17 2019-03-08 武汉大学 A kind of flow-type electrochemistry proposes lithium system
CN110357055B (en) * 2019-08-09 2022-07-15 深圳市德方纳米科技股份有限公司 Method for extracting lithium from salt lake brine and preparing lithium phosphate and application thereof
CN110438519B (en) * 2019-08-20 2020-10-30 武汉大学 Three-electrolytic-tank chlor-alkali electrolysis preparation system and chlor-alkali preparation method
CN110442178B (en) * 2019-08-22 2021-03-30 河北为信电子科技股份有限公司 Experiment is with salt lake lithium extraction power supply system
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CN111146520B (en) * 2019-12-16 2021-01-19 西安交通大学 Recovery method of waste liquid metal battery
WO2021160241A1 (en) * 2020-02-10 2021-08-19 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Method and apparatus for the extraction of lithium from aqueous lithium sources containing dissolved lithium, carbonate, calcium and/or magnesium with aid of nanofiltration and reverse osmosis membranes
WO2021160240A1 (en) * 2020-02-10 2021-08-19 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Method and apparatus for the electrochemical extraction of lithium from aqueous lithium sources
CN115335543A (en) * 2020-03-06 2022-11-11 内华达高等教育系统董事会代表拉斯维加斯内华达大学 Lithium recovery from lithium salts dissolved in ionic liquids
CN115298139A (en) * 2020-03-16 2022-11-04 莱兰斯坦福初级大学评议会 Lithium extraction by pulsed electrochemical intercalation
CN111377465B (en) * 2020-03-23 2022-06-24 中国科学院青海盐湖研究所 Method for preparing battery-grade lithium carbonate by using lepidolite
EP4133219A1 (en) * 2020-04-08 2023-02-15 Vulcan Energie Ressourcen GmbH System and process for direct lithium extraction and production of low carbon intensity lithium chemicals from geothermal brines
CN115715223A (en) 2020-04-28 2023-02-24 1S1能源有限公司 Oxygen-containing metal compounds for selective extraction of lithium salts and methods of use thereof
CN113307969A (en) * 2021-02-05 2021-08-27 北京航空航天大学 Conductive polymer porous membrane and preparation method thereof
EP4376971A1 (en) * 2021-07-30 2024-06-05 Services Pétroliers Schlumberger Lithium recovery thermal management
CN118119738A (en) 2021-10-20 2024-05-31 利莱克特拉股份有限公司 Method for extracting lithium and electrochemical filtration unit
CN115818801B (en) * 2022-12-20 2024-07-19 中南大学 Method for extracting lithium from salt lake brine
WO2024158743A2 (en) * 2023-01-24 2024-08-02 Lithios Inc. Apparatuses, manufacturing, and operation of electrochemical stacks for metals extraction, and methods thereof
WO2024192617A1 (en) * 2023-03-20 2024-09-26 广东邦普循环科技有限公司 Lithium extraction device and lithium extraction method
WO2024197577A1 (en) * 2023-03-28 2024-10-03 广东邦普循环科技有限公司 Preparation method for modified carbon nanotube, preparation method for electrode, and use of electrode in salt lake lithium extraction

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11806641B2 (en) 2016-11-14 2023-11-07 Lilac Solutions, Inc. Lithium extraction with coated ion exchange particles
US11794182B2 (en) 2017-08-02 2023-10-24 Lilac Solutions, Inc. Lithium extraction with porous ion exchange beads
US11865531B2 (en) 2018-02-28 2024-01-09 Lilac Solutions, Inc. Ion exchange reactor with particle traps for lithium extraction
US11975317B2 (en) 2018-02-28 2024-05-07 Lilac Solutions, Inc. Ion exchange reactor with particle traps for lithium extraction
US11964876B2 (en) 2020-06-09 2024-04-23 Lilac Solutions, Inc. Lithium extraction in the presence of scalants
US11986816B2 (en) 2021-04-23 2024-05-21 Lilac Solutions, Inc. Ion exchange devices for lithium extraction
US12076662B2 (en) 2022-03-28 2024-09-03 Lilac Solutions, Inc. Devices for efficient sorbent utilization in lithium extraction

Also Published As

Publication number Publication date
WO2014047347A1 (en) 2014-03-27
CL2015000568A1 (en) 2015-11-20
US20140076734A1 (en) 2014-03-20
US20150252485A1 (en) 2015-09-10
AU2013317990A1 (en) 2015-03-26
CN106170340A (en) 2016-11-30
CN106170340B (en) 2019-05-28

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