WO2015067474A3 - Electrochemical cell and method for the production thereof - Google Patents

Electrochemical cell and method for the production thereof Download PDF

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Publication number
WO2015067474A3
WO2015067474A3 PCT/EP2014/072701 EP2014072701W WO2015067474A3 WO 2015067474 A3 WO2015067474 A3 WO 2015067474A3 EP 2014072701 W EP2014072701 W EP 2014072701W WO 2015067474 A3 WO2015067474 A3 WO 2015067474A3
Authority
WO
WIPO (PCT)
Prior art keywords
electrochemical cell
production
lithium
protective layer
containing anode
Prior art date
Application number
PCT/EP2014/072701
Other languages
German (de)
French (fr)
Other versions
WO2015067474A2 (en
Inventor
Thomas Wöhrle
Felix Eberle
Bernd Schumann
Calin Iulius WURM
Vikram Anil GODBOLE
Original Assignee
Robert Bosch Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Robert Bosch Gmbh filed Critical Robert Bosch Gmbh
Priority to CN201480061234.5A priority Critical patent/CN105765759B/en
Publication of WO2015067474A2 publication Critical patent/WO2015067474A2/en
Publication of WO2015067474A3 publication Critical patent/WO2015067474A3/en

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134Electrodes based on metals, Si or alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/403Manufacturing processes of separators, membranes or diaphragms
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0561Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
    • H01M10/0562Solid materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00Hybrid cells; Manufacture thereof
    • H01M12/08Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • H01M4/1395Processes of manufacture of electrodes based on metals, Si or alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/38Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/381Alkaline or alkaline earth metals elements
    • H01M4/382Lithium
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409Separators, membranes or diaphragms characterised by the material
    • H01M50/411Organic material
    • H01M50/414Synthetic resins, e.g. thermoplastics or thermosetting resins
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409Separators, membranes or diaphragms characterised by the material
    • H01M50/431Inorganic material
    • H01M50/434Ceramics
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409Separators, membranes or diaphragms characterised by the material
    • H01M50/44Fibrous material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/46Separators, membranes or diaphragms characterised by their combination with electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0068Solid electrolytes inorganic
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0088Composites
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/38Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/40Alloys based on alkali metals
    • H01M4/405Alloys based on lithium
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/14Cells with non-aqueous electrolyte
    • H01M6/18Cells with non-aqueous electrolyte with solid electrolyte
    • H01M6/185Cells with non-aqueous electrolyte with solid electrolyte with oxides, hydroxides or oxysalts as solid electrolytes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Hybrid Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Electric Double-Layer Capacitors Or The Like (AREA)
  • Secondary Cells (AREA)

Abstract

Described is an electrochemical cell (10) comprising a lithium-containing anode (14) and a cathode (16). The lithium-containing anode (14) has a protective layer (18) comprising fibers (20) which are made of a material not conducting lithium ions and which are in contact with a material (22) of the protective layer (18) that conducts lithium ions.
PCT/EP2014/072701 2013-11-08 2014-10-23 Electrochemical cell and method for the production thereof WO2015067474A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201480061234.5A CN105765759B (en) 2013-11-08 2014-10-23 Electrochemical cell and its manufacturing method

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE201310222784 DE102013222784A1 (en) 2013-11-08 2013-11-08 Electrochemical cell and process for its preparation
DE102013222784.1 2013-11-08

Publications (2)

Publication Number Publication Date
WO2015067474A2 WO2015067474A2 (en) 2015-05-14
WO2015067474A3 true WO2015067474A3 (en) 2015-07-02

Family

ID=51799080

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2014/072701 WO2015067474A2 (en) 2013-11-08 2014-10-23 Electrochemical cell and method for the production thereof

Country Status (3)

Country Link
CN (1) CN105765759B (en)
DE (1) DE102013222784A1 (en)
WO (1) WO2015067474A2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101926917B1 (en) * 2016-08-17 2018-12-07 현대자동차주식회사 Anode for lithium air battery and preparation method thereof
KR102328253B1 (en) * 2016-09-30 2021-11-18 주식회사 엘지에너지솔루션 Anode with buffer layer made by conductive textile, lithium secondary battery containing the same
US10826145B2 (en) 2017-02-10 2020-11-03 General Electric Company Electrochemical cell for use in high temperature metal-air battery
US10177427B2 (en) * 2017-02-10 2019-01-08 General Electric Company Electrochemical cell for use in high temperature metal-air battery
CN107293690B (en) * 2017-06-12 2019-12-13 中航锂电(洛阳)有限公司 Lithium ion battery positive electrode composite pole piece, preparation method thereof and lithium ion battery
WO2019170415A1 (en) * 2018-03-05 2019-09-12 Robert Bosch Gmbh Ion deposition biasing to inhibit dendrite formation and growth in a metal ion battery cell
CN110911685B (en) * 2019-11-28 2021-09-14 宁德新能源科技有限公司 Composition for negative electrode, and protective film, negative electrode and device comprising same

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1049186A1 (en) * 1998-10-16 2000-11-02 Matsushita Electric Industrial Co., Ltd. Molded solid electrolyte, molded electrode, and electrochemical element
EP1052718A1 (en) * 1998-12-03 2000-11-15 Sumitomo Electric Industries, Ltd. Lithium storage battery
US20040106037A1 (en) * 2002-11-02 2004-06-03 Samsung Sdi Co., Ltd. Separator having inorganic protective film and lithium battery using the same
US20100068629A1 (en) * 2008-09-12 2010-03-18 John Howard Gordon Alkali metal seawater battery
DE102009045240A1 (en) * 2009-10-01 2011-04-07 Robert Bosch Gmbh Method for producing a ceramic electrode separator device
US20110269007A1 (en) * 2010-04-30 2011-11-03 Polyplus Battery Company High rate seawater activated lithium battery cells bi-polar protected electrodes and multi-cell stacks
US20120100433A1 (en) * 2009-07-17 2012-04-26 Toyota Jidosha Kabushiki Kaisha Solid electrolyte, solid electrolyte sheet, and method for producing solid electrolyte
DE102010054610A1 (en) * 2010-12-15 2012-06-21 Li-Tec Battery Gmbh Electrochemical cell

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US5510209A (en) 1995-01-05 1996-04-23 Eic Laboratories, Inc. Solid polymer electrolyte-based oxygen batteries
US5723140A (en) 1996-01-30 1998-03-03 Pearsall; Charles W. Method for treating pressure ulcers
US6402795B1 (en) 1998-02-18 2002-06-11 Polyplus Battery Company, Inc. Plating metal negative electrodes under protective coatings
DE102004010892B3 (en) 2004-03-06 2005-11-24 Christian-Albrechts-Universität Zu Kiel Chemically stable solid Li ion conductor of garnet-like crystal structure and high Li ion conductivity useful for batteries, accumulators, supercaps, fuel cells, sensors, windows displays
DE102007030604A1 (en) 2007-07-02 2009-01-08 Weppner, Werner, Prof. Dr. Ion conductor with garnet structure
JP5163439B2 (en) * 2008-11-19 2013-03-13 Tdk株式会社 FIBER-CONTAINING POLYMER FILM AND METHOD FOR PRODUCING SAME, ELECTROCHEMICAL DEVICE AND METHOD FOR PRODUCING SAME
CN102959776B (en) * 2010-09-29 2016-02-24 松下知识产权经营株式会社 Lithium primary battery and manufacture method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1049186A1 (en) * 1998-10-16 2000-11-02 Matsushita Electric Industrial Co., Ltd. Molded solid electrolyte, molded electrode, and electrochemical element
EP1052718A1 (en) * 1998-12-03 2000-11-15 Sumitomo Electric Industries, Ltd. Lithium storage battery
US20040106037A1 (en) * 2002-11-02 2004-06-03 Samsung Sdi Co., Ltd. Separator having inorganic protective film and lithium battery using the same
US20100068629A1 (en) * 2008-09-12 2010-03-18 John Howard Gordon Alkali metal seawater battery
US20120100433A1 (en) * 2009-07-17 2012-04-26 Toyota Jidosha Kabushiki Kaisha Solid electrolyte, solid electrolyte sheet, and method for producing solid electrolyte
DE102009045240A1 (en) * 2009-10-01 2011-04-07 Robert Bosch Gmbh Method for producing a ceramic electrode separator device
US20110269007A1 (en) * 2010-04-30 2011-11-03 Polyplus Battery Company High rate seawater activated lithium battery cells bi-polar protected electrodes and multi-cell stacks
DE102010054610A1 (en) * 2010-12-15 2012-06-21 Li-Tec Battery Gmbh Electrochemical cell

Also Published As

Publication number Publication date
DE102013222784A1 (en) 2015-05-13
CN105765759B (en) 2019-04-19
CN105765759A (en) 2016-07-13
WO2015067474A2 (en) 2015-05-14

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