AR091970A1 - Soluciones de nbpt para la preparacion de fertilizantes de urea inhibidos con ureasa preparados a partir de n-alquilo; n,n-alquilo; y n-alquil-n-alcoxi amino alcoholes - Google Patents
Soluciones de nbpt para la preparacion de fertilizantes de urea inhibidos con ureasa preparados a partir de n-alquilo; n,n-alquilo; y n-alquil-n-alcoxi amino alcoholesInfo
- Publication number
- AR091970A1 AR091970A1 ARP130102747A ARP130102747A AR091970A1 AR 091970 A1 AR091970 A1 AR 091970A1 AR P130102747 A ARP130102747 A AR P130102747A AR P130102747 A ARP130102747 A AR P130102747A AR 091970 A1 AR091970 A1 AR 091970A1
- Authority
- AR
- Argentina
- Prior art keywords
- amino alcohols
- alkyl
- solution
- urea
- nbpt
- Prior art date
Links
- 229910052757 nitrogen Inorganic materials 0.000 title abstract 13
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 title abstract 12
- 239000004202 carbamide Substances 0.000 title abstract 12
- 239000003337 fertilizer Substances 0.000 title abstract 9
- 150000001414 amino alcohols Chemical class 0.000 title 1
- HEPPIYNOUFWEPP-UHFFFAOYSA-N n-diaminophosphinothioylbutan-1-amine Chemical compound CCCCNP(N)(N)=S HEPPIYNOUFWEPP-UHFFFAOYSA-N 0.000 abstract 12
- 239000000243 solution Substances 0.000 abstract 11
- 239000000203 mixture Substances 0.000 abstract 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 4
- 125000004432 carbon atom Chemical group C* 0.000 abstract 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- 239000003112 inhibitor Substances 0.000 abstract 2
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 abstract 2
- DHFGYXVVIQTUSZ-UHFFFAOYSA-N 2-[2-(2-hydroxyethoxy)ethyl-methylamino]ethanol Chemical compound OCCN(C)CCOCCO DHFGYXVVIQTUSZ-UHFFFAOYSA-N 0.000 abstract 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 1
- 239000010828 animal waste Substances 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000006184 cosolvent Substances 0.000 abstract 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 abstract 1
- 235000015097 nutrients Nutrition 0.000 abstract 1
- 239000002699 waste material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C9/00—Fertilisers containing urea or urea compounds
- C05C9/005—Post-treatment
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/90—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting the nitrification of ammonium compounds or urea in the soil
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/22—Amides of acids of phosphorus
- C07F9/224—Phosphorus triamides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
- Y02P60/20—Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
- Y02P60/21—Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Soil Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
- Treating Waste Gases (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Reivindicación 1: Una solución para usar en la reducción de volatilización del nitrógeno que comprende triamida de N-(n-butil)-tiofosfórica (NBPT) disuelta en uno o más N-alquil amino alcoholes, N,N-dialquil amino alcoholes, N-alquil-N-alcoxi amino alcoholes, y mezclas de los anteriores. Reivindicación 2: La solución de la reivindicación 1, en donde dichos N-alquil amino alcoholes y N,N-dialquil amino alcoholes tienen la fórmula (1) donde R¹ es una cadena de carbono de 2 hasta 4 átomos de carbono y R² es una cadena de carbono con 1 hasta 4 átomos de carbono; m, n, son números enteros con valores de 1 ó 2; y es un número entero con valores de 0 ó 1 de modo tal que m + n + y = 3; y cuando y = 0 luego m + n = 3; R¹ y/o R² pueden ser estructuras ramificadas en las cuales R² no contiene grupos hidroxilo. Reivindicación 3: La solución de la reivindicación 1, en donde dichos N-alquil-N-alcoxi amino alcoholes tienen la fórmula (2) donde R¹, R³ y R⁴, son cadenas de carbono con de 2 hasta 4 átomos de carbono y R² puede ser una cadena de carbono de 1 hasta 4 átomos de carbono, y R² no contiene grupos hidroxilo. Reivindicación 8: La solución de la reivindicación 1, en donde dicha solución tiene el pH ajustado hasta un pH de desde 7 hasta 10. Reivindicación 9: La solución de la reivindicación 1, que incluye además un co-solvente. Reivindicación 10: La solución de la reivindicación 1, que incluye además un inhibidor de desnitrificación. Reivindicación 12: La solución de la reivindicación 1, en donde dicho NBPT está disuelto en una mezcla de N-metildietanolamina (MDEA) y 2-((2(2-hidroxietoxi)etil)(metil)amino)etanol (MHEEA). Reivindicación 13: La solución de la reivindicación 1, en donde el NBPT se disuelve en una mezcla de un N-alquil, N,N-dialquil, o N-alquil-N-alcoxi amino alcohol que contiene en forma adicional trietanolamina, dietanolamina y mezclas de los anteriores. Reivindicación 16: Un método de reducir la volatilidad del nitrógeno de un fertilizante de urea que comprende combinar dicho fertilizante con triamida de N-(n-butil)-tiofosfórica (NBPT) disuelta en uno o más N-alquil amino alcoholes, N,N-dialquil amino alcoholes, N-alquil-N-alcoxi amino alcoholes, y mezclas de los anteriores. Reivindicación 35: Un fertilizante de urea que tiene volatilidad reducida del nitrógeno formado por urea y una solución de triamida de N-(n-butil)-tiofosfórica (NBPT) disuelta en uno o más de N-alquil amino alcoholes, N,N-dialquil amino alcoholes, N-alquil-N-alcoxi amino alcoholes, y mezclas de los anteriores. Reivindicación 36: El fertilizante que contiene urea de la reivindicación 35, en donde dicho fertilizante de urea está en una solución acuosa. Reivindicación 37: El fertilizante que contiene urea de la reivindicación 35, en donde dicha urea es urea granulada, dicha urea granulada está recubierta con triamida de N-(n-butil)-tiofosfórica (NBPT) disuelta en uno o más de N-alquil amino alcoholes, N,N-dialquil amino alcoholes, N-alquil-N-alcoxi amino alcoholes, y mezclas de los anteriores. Reivindicación 39: El fertilizante que contiene urea de la reivindicación 35, que incluye además nutrientes adicionales de las plantas. Reivindicación 42: El fertilizante que contiene urea de la reivindicación 35, que incluye además un inhibidor de desnitrificación. Reivindicación 43: Un método de reducir el olor del desecho de animales que comprende tratar dicho desecho con una solución de triamida de N-(n-butil)-tiofosfórica (NBPT) disuelta en uno o más N-alquil amino alcoholes, N,N-dialquil amino alcoholes, N-alquil-N-alcoxi amino alcoholes, y mezclas de los anteriores.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/507,848 US20140037570A1 (en) | 2012-08-02 | 2012-08-02 | NBPT solution for preparing urease inhibited urea fertilizers prepared from N-alkyl; N, N-alkyl; and N-alkyl-N-alkoxy amino alcohols |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR091970A1 true AR091970A1 (es) | 2015-03-11 |
Family
ID=50025674
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP130102747A AR091970A1 (es) | 2012-08-02 | 2013-08-02 | Soluciones de nbpt para la preparacion de fertilizantes de urea inhibidos con ureasa preparados a partir de n-alquilo; n,n-alquilo; y n-alquil-n-alcoxi amino alcoholes |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20140037570A1 (es) |
| EP (1) | EP2880004A4 (es) |
| AR (1) | AR091970A1 (es) |
| AU (1) | AU2013296874B2 (es) |
| BR (1) | BR112015001811A2 (es) |
| CA (1) | CA2878952A1 (es) |
| CL (1) | CL2015000206A1 (es) |
| CR (1) | CR20150106A (es) |
| UY (1) | UY34958A (es) |
| WO (1) | WO2014022174A1 (es) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10173935B2 (en) | 2011-12-12 | 2019-01-08 | Rhodia Operations | Solvent systems of N-alkyl thiophosphoric triamides and methods of use in agricultural applications |
| AR092147A1 (es) * | 2012-08-15 | 2015-03-25 | Koch Agronomic Services Llc | Composiciones liquidas mejoradas que contienen inhibidores de ureasa y alcoholes aril alquilicos y metodos de elaboracion y uso de las mismas |
| US9199884B2 (en) * | 2012-08-15 | 2015-12-01 | Koch Agronomic Services, Llc | Liquid compositions containing urease inhibitors and glycol alkyl ethers and methods of making a use thereof |
| CN104781265B (zh) * | 2012-10-01 | 2018-01-02 | 加里·戴维·麦克奈特 | 用于肥料的改进的脲酶抑制剂的液体制剂 |
| EP2935159B1 (en) | 2012-12-20 | 2019-02-27 | Rhodia Operations | Liquid dicyandiamide and/or alkyl thiophosphoric triamide compositions and their use in agricultural applications |
| BR112015032664B1 (pt) * | 2013-07-04 | 2021-12-14 | Basf Se | Composições com efeito aprimorado de inibição da urease compreendendo triamida de ácido (tio)fosfórico e compostos adicionais |
| SI3623362T1 (sl) | 2013-12-13 | 2023-03-31 | Eurochem Agro Gmbh | Gnojilna zmes, ki vsebuje nitrifikacijski inhibitor |
| WO2015176076A2 (en) * | 2014-05-12 | 2015-11-19 | Gary David Mcknight | Improving the efficiency of man-made and/or natural organic based animal manure fertilizers by liberating the bound nutrients (macro and micro) through the use of organic, non-aqueous liquid delivery formulations containing organic poly (organicacids) and/or their salts |
| CN104045465B (zh) * | 2014-07-04 | 2016-04-06 | 上海艾拜克国际贸易有限公司 | 一种含有正丁基硫代磷酰三胺的溶液体系及其应用 |
| WO2016012925A1 (en) * | 2014-07-20 | 2016-01-28 | Sabic Global Technologies B.V. | Methods for determining low sulfate concentrations in synthetic urea samples, produced in a manufacturing process and containing high levels of impurities |
| WO2016064973A1 (en) | 2014-10-21 | 2016-04-28 | Rhodia Operations | Improved solvent systems for dicyandiamide and/or alkyl thiophosphoric triamide and use in agricultural applications |
| CN104262065B (zh) * | 2014-10-28 | 2017-03-15 | 中化（烟台）作物营养有限公司 | 一种含氮肥增效剂的缓效长效复混肥料及其制备方法 |
| US10183897B2 (en) | 2014-12-04 | 2019-01-22 | Active Agriscience Inc. | Compositions and methods for reducing nitrogen volatilization of urea fertilizers |
| US9422203B2 (en) | 2014-12-04 | 2016-08-23 | Active AgriProducts Inc. | Compositions and methods for reducing nitrogen volatilization of urea fertilizers |
| EP3233762A1 (en) * | 2014-12-18 | 2017-10-25 | Basaran, Mustafa | Organic and inorganic fertilizer suitable for irrigated farming and including nitrification inhibitor and boron |
| US10577290B2 (en) * | 2014-12-23 | 2020-03-03 | Basf Se | Compositions with improved urease-inhibiting effect comprising (thio)phosphoric acid triamide and further compounds such as amines and colorants |
| RU2675935C1 (ru) * | 2015-02-24 | 2018-12-25 | КОХ АГРОНОМИК СЕРВИСИЗ, ЭлЭлСи | Гранулированное удобрение на основе мочевины с добавками-стабилизаторами азота |
| US10464858B2 (en) * | 2015-05-13 | 2019-11-05 | World Source Enterprises, Llc | Non-aqueous organo liquid delivery systems containing dispersed poly (organic acids) that improve availability of macro and micro-nutrients to plants |
| CN104892166A (zh) * | 2015-06-01 | 2015-09-09 | 张彬 | 一种增效型硝铵尿素液体氮肥 |
| SI3109223T1 (sl) | 2015-06-22 | 2018-11-30 | Eurochem Agro Gmbh | Zmes za obdelavo gnojil, ki vsebujejo sečnino |
| US9834487B2 (en) | 2015-07-13 | 2017-12-05 | Koch Agronomic Services, Llc | Highly concentrated phosphoric or thiophosphoric triamide formulation |
| CN108137426A (zh) | 2015-08-17 | 2018-06-08 | 罗地亚经营管理公司 | 高温胺稳定的dcd和/或烷基硫代磷酰三胺溶剂体系以及在农业应用中的用途 |
| CN109071370B (zh) | 2015-09-08 | 2022-11-22 | 雅苒国际集团 | 改进的基于尿素硫酸铵的组合物及其制备方法 |
| US10590045B2 (en) * | 2015-10-12 | 2020-03-17 | Hydrite Chemical Co. | Liquid fertilizer |
| CN108349827A (zh) | 2015-11-12 | 2018-07-31 | 雅苒国际集团 | 改进的基于尿素的混合组合物及其制备方法 |
| US10319271B2 (en) * | 2016-03-22 | 2019-06-11 | Manufacturing Resources International, Inc. | Cyclic redundancy check for electronic displays |
| US12037300B2 (en) * | 2016-04-01 | 2024-07-16 | Basf Se | Use of a cation source to prevent decomposition of (thio)phosphoric acid triamide urease inhibitors when a phosphorus-containing fertilizer is present |
| CN109415278B (zh) * | 2016-06-18 | 2022-02-22 | 美利肯公司 | 适用于制备肥料的组合物、制备这些组合物的方法、以及使用所述组合物制备肥料的方法 |
| BR112018077258B1 (pt) * | 2016-06-29 | 2023-12-26 | Rhodia Operations | Composição agrícola líquida estável de dcd e/ou triamida tiofosfórica de alquila estabilizados e método de preparação da mesma |
| EP3309137A1 (en) | 2016-10-13 | 2018-04-18 | YARA International ASA | Improved urea-based composition comprising elemental sulphur and method for the manufacture thereof |
| EP3372576A1 (en) | 2017-03-07 | 2018-09-12 | Yara International ASA | Urea-based composition and method for the manufacture thereof |
| CN108410469B (zh) * | 2018-01-22 | 2020-11-17 | 昆明理工大学 | 一种轻质保水材料的制备方法及使用方法 |
| WO2019157472A1 (en) * | 2018-02-11 | 2019-08-15 | Mcknight Gary David | Non-aqueous organo liquid delivery systems containing dispersed organo polycarboxylate functionalities that improves efficiencies and properties of nitrogen sources |
| US11866383B1 (en) | 2018-04-04 | 2024-01-09 | Synsus Private Label Partners, Llc | Nitrification inhibiting compositions and their use in agricultural applications |
| WO2019204163A1 (en) | 2018-04-20 | 2019-10-24 | Tessenderlo Kerley, Inc. | Liquid nitrogen fertilizer compositions and additives therefore |
| EP3575278A1 (en) * | 2018-05-31 | 2019-12-04 | Tessenderlo Kerley, Inc. | Liquid nitrogen fertilizer compositions and additives therefor |
| WO2020033576A1 (en) * | 2018-08-08 | 2020-02-13 | Tessenderlo Kerley, Inc. | Stabilized urea fertilizer compositions and methods for preparing same |
| US11124462B1 (en) | 2018-08-27 | 2021-09-21 | Hocking International Laboratories, LLC | Compositions and their use in agricultural applications |
| US11518720B2 (en) | 2019-05-02 | 2022-12-06 | California Organic Fertilizers, Inc. | Manufacturing process for producing ammonia from anaerobic digestate liquid |
| WO2021003404A1 (en) * | 2019-07-02 | 2021-01-07 | Nanochem Solutions, Inc. | Nitrification and volatilization inhibitor formulations that include carboxylated polymers and methods of use thereof |
| FR3108530B1 (fr) * | 2020-03-30 | 2023-01-06 | Total Marketing Services | Fluide homogène à base de fer pour la dépollution des moteurs thermiques |
| DE102021108187A1 (de) | 2021-03-31 | 2022-10-06 | Skw Stickstoffwerke Piesteritz Gmbh | Granuliertes pH-neutrales Harnstoff-Ammoniumsulfat-Düngemittel mit Ureaseinhibitor |
| EP4183763A1 (en) * | 2021-11-18 | 2023-05-24 | SABIC Global Technologies, B.V. | Fertilizer composition including multi-micronutrients |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4517003A (en) | 1983-06-08 | 1985-05-14 | Allied Corporation | N-acyl phosphoric triamide urease inhibitors and urease inhibited urea based fertilizer compositions |
| NL8403505A (nl) * | 1984-11-16 | 1986-06-16 | Sierra Chemical Europ | Kunstmestsamenstelling in korrelvorm met een geregelde afgifte van meststoffen en werkwijze voor het bereiden hiervan. |
| US5858055A (en) * | 1997-10-07 | 1999-01-12 | The Lubrizol Corporation | Water-in-oil emulsion fertilizer compositions |
| CA2506968A1 (en) | 2002-11-25 | 2004-06-17 | Richard G. Sheets, Sr. | Animal waste effluent treatment |
| US7434540B2 (en) | 2004-10-14 | 2008-10-14 | Absorbent Products Ltd. | Antimicrobial additive for large animal or poultry beddings |
| EP1820788A1 (de) | 2006-02-16 | 2007-08-22 | BASF Aktiengesellschaft | Zubereitungen mit verbesserter Urease-hemmender Wirkung und diese enthaltende harnstoffhaltige Düngemittel |
| DE102007062614C5 (de) * | 2007-12-22 | 2019-03-14 | Eurochem Agro Gmbh | Mischung zur Behandlung von harnstoffhaltigen Düngemitteln, Verwendungen der Mischung und harnstoffhaltiges Düngemittel enthaltend die Mischung |
| US20100206031A1 (en) * | 2009-02-17 | 2010-08-19 | Whitehurst Associates, Inc. | Amino alcohol solutions of N-(n-butyl)thiophosphoric triamide (NBPT) and urea fertilizers using such solutions as urease inhibitors |
| US8048189B2 (en) * | 2009-02-17 | 2011-11-01 | Whitehurst Associates Inc. | Buffered amino alcohol solutions of N-(n-butyl)thiophosphoric triamide (NBPT) and urea fertilizers using such solutions as urease inhibitors |
-
2012
- 2012-08-02 US US13/507,848 patent/US20140037570A1/en not_active Abandoned
-
2013
- 2013-07-24 EP EP13825518.7A patent/EP2880004A4/en not_active Withdrawn
- 2013-07-24 CA CA2878952A patent/CA2878952A1/en not_active Abandoned
- 2013-07-24 AU AU2013296874A patent/AU2013296874B2/en not_active Ceased
- 2013-07-24 WO PCT/US2013/051882 patent/WO2014022174A1/en active Application Filing
- 2013-07-24 BR BR112015001811A patent/BR112015001811A2/pt not_active IP Right Cessation
- 2013-08-02 AR ARP130102747A patent/AR091970A1/es unknown
- 2013-08-02 UY UY0001034958A patent/UY34958A/es not_active Application Discontinuation
-
2015
- 2015-01-27 CL CL2015000206A patent/CL2015000206A1/es unknown
- 2015-02-27 CR CR20150106A patent/CR20150106A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU2013296874A1 (en) | 2015-03-05 |
| CA2878952A1 (en) | 2014-02-06 |
| CR20150106A (es) | 2015-04-08 |
| WO2014022174A1 (en) | 2014-02-06 |
| EP2880004A4 (en) | 2016-07-27 |
| BR112015001811A2 (pt) | 2017-07-04 |
| US20140037570A1 (en) | 2014-02-06 |
| CL2015000206A1 (es) | 2015-11-27 |
| AU2013296874B2 (en) | 2016-06-02 |
| UY34958A (es) | 2014-02-28 |
| EP2880004A1 (en) | 2015-06-10 |
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