AR086744A1 - HETEROCICLIC COMPOUND CONTAINING NITROGEN AND FUNGICIDE FOR USE IN AGRICULTURE AND GARDENING - Google Patents

HETEROCICLIC COMPOUND CONTAINING NITROGEN AND FUNGICIDE FOR USE IN AGRICULTURE AND GARDENING

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Publication number
AR086744A1
AR086744A1 ARP120102265A AR086744A1 AR 086744 A1 AR086744 A1 AR 086744A1 AR P120102265 A ARP120102265 A AR P120102265A AR 086744 A1 AR086744 A1 AR 086744A1
Authority
AR
Argentina
Prior art keywords
substituted
unsubstituted
alkyl
heterocyclyl
alkynyl
Prior art date
Application number
Other languages
Spanish (es)
Inventor
Inagaki Jun
Shibayama Kotaro
Sato Motoaki
Kuwahara Raito
Yokoyama Masahiro
Shiinoki Yasuyuki
Saiki Yuto
Original Assignee
Nippon Soda Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Soda Co filed Critical Nippon Soda Co
Publication of AR086744A1 publication Critical patent/AR086744A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D215/00Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
    • C07D215/02Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom
    • C07D215/16Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D215/20Oxygen atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A01N43/42Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/601,4-Diazines; Hydrogenated 1,4-diazines
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system

Abstract

Se proporciona un fungicida para el uso en agricultura y jardinería que tiene una buena eficiencia y seguridad, y un compuesto heterocíclico conteniendo nitrógeno o una sal del mismo que es útil como principio activo de un fungicida para el uso en agricultura y jardinería. Reivindicación 1: Un compuesto heterocíclico conteniendo nitrógeno que presenta la fórmula (1) o una sal del mismo. (En la fórmula (1), R representa OR¹, NR¹R², SR¹, S(=O)R³, SO₂R³, S(=O)(=NR⁴)R⁵, N=S(=O)R⁴R⁵ o nitro; R¹ representa un átomo de hidrógeno, alquilo C₁₋₈ sin sustituir o sustituido, alquenilo C₂₋₈ sin sustituir o sustituido, alquinilo C₂₋₈ sin sustituir o sustituido, cicloalquilo C₃₋₈ sin sustituir o sustituido, cicloalquenilo C₄₋₈ sin sustituir o sustituido, arilo C₆₋₁₀ sin sustituir o sustituido, heterociclilo sin sustituir o sustituido, acilo C₁₋₈ sin sustituir o sustituido, carboxilo sin sustituir o sustituido, carbamoilo sin sustituir o sustituido, sulfonilo sustituido, o amino sin sustituir o sustituido. R² representa un átomo de hidrógeno, alquilo C₁₋₈ sin sustituir o sustituido, alquenilo C₂₋₈ sin sustituir o sustituido, alquinilo C₂₋₈ sin sustituir o sustituido, cicloalquilo C₃₋₈ sin sustituir o sustituido, cicloalquenilo C₄₋₈ sin sustituir o sustituido, arilo C₆₋₁₀ sin sustituir o sustituido, heterociclilo sin sustituir o sustituido, acilo C₁₋₈ sin sustituir o sustituido, carboxilo sin sustituir o sustituido, carbamoilo sin sustituir o sustituido, sulfonilo sustituido, hidroxi sin sustituir o sustituido, o amino sin sustituir o sustituido. R³ representa alquilo C₁₋₈ sin sustituir o sustituido, alquenilo C₂₋₈ sin sustituir o sustituido, alquinilo C₂₋₈ sin sustituir o sustituido, cicloalquilo C₃₋₈ sin sustituir o sustituido, cicloalquenilo C₄₋₈ sin sustituir o sustituido, arilo C₆₋₁₀ sin sustituir o sustituido, heterociclilo sin sustituir o sustituido, mercapto sin sustituir o sustituido, hidroxi sin sustituir o sustituido, o amino sin sustituir o sustituido. R⁴ y R⁵ representan, independientemente entre sí, alquilo C₁₋₈ sin sustituir o sustituido, alquenilo C₂₋₈ sin sustituir o sustituido, alquinilo C₂₋₈ sin sustituir o sustituido, cicloalquilo C₃₋₈ sin sustituir o sustituido, cicloalquenilo C₄₋₈ sin sustituir o sustituido, arilo C₆₋₁₀ sin sustituir o sustituido, o heterociclilo sin sustituir o sustituido. En el grupo NR¹R², el conjunto de R¹ y R² puede formar cíclilo de 3 - 8 miembros sin sustituir o sustituido, =CRᵃRᵇ o =NRᶜ. Rᵃ y Rᵇ representan, independientemente entre sí, un átomo de hidrógeno, alquilo C₁₋₈ sin sustituir o sustituido, alquenilo C₂₋₈ sin sustituir o sustituido, alquinilo C₂₋₈ sin sustituir o sustituido, cicloalquilo C₃₋₈ sin sustituir o sustituido, cicloalquenilo C₄₋₈ sin sustituir o sustituido, arilo C₆₋₁₀ sin sustituir o sustituido, heterociclilo sin sustituir o sustituido, acilo C₁₋₈ sin sustituir o sustituido, carboxilo sin sustituir o sustituido, carbamoilo sin sustituir o sustituido, sulfonilo sustituido, mercapto sin sustituir o sustituido, hidroxilo sin sustituir o sustituido, o amino sin sustituir o sustituido. Rᶜ representa hidroxilo sin sustituir o sustituido, o alquilo C₁₋₈ sin sustituir o sustituido. En el grupo N=S(=O)R⁴R⁵, el conjunto de R⁴ y R⁵ puede formar cíclilo de 5 - 8 miembros sin sustituir o sustituido. X¹ representa, independientemente entre sí, alquilo C₁₋₈ sin sustituir o sustituido, alquenilo C₂₋₈ sin sustituir o sustituido, alquinilo C₂₋₈ sin sustituir o sustituido, cicloalquilo C₃₋₈ sin sustituir o sustituido, cicloalquenilo C₄₋₈ sin sustituir o sustituido, arilo C₆₋₁₀ sin sustituir o sustituido, heterociclilo sin sustituir o sustituido, acilo C₁₋₈ sin sustituir o sustituido, (1-imino) alquilo C₁₋₈ sin sustituir o sustituido, carboxilo sin sustituir o sustituido, carbamoilo sin sustituir o sustituido, hidroxilo sin sustituir o sustituido, amino sin sustituir o sustituido, mercapto sin sustituir o sustituido, sulfonilo sustituido, halógeno, ciano o nitro. m representa el número de X¹ y un número entero de 0 a 5. B representa un átomo de carbono o de nitrógeno. D representa hidrocarburo cíclico de 5 - 7 miembros sin sustituir o sustituido con X¹ o heterociclilo de 5 - 7 miembros sin sustituir o sustituido con X¹. X² representa, independientemente entre sí, alquilo C₁₋₈ sin sustituir o sustituido, alquenilo C₂₋₈ sin sustituir o sustituido, alquinilo C₂₋₈ sin sustituir o sustituido, cicloalquilo C₃₋₈ sin sustituir o sustituido, cicloalquenilo C₄₋₈ sin sustituir o sustituido, arilo C₆₋₁₀ sin sustituir o sustituido, heterociclilo sin sustituir o sustituido, acilo C₁₋₈ sin sustituir o sustituido, (1-imino) alquilo C₁₋₈ sin sustituir o sustituido, carboxilo sin sustituir o sustituido, carbamoilo sin sustituir o sustituido, hidroxilo sin sustituir o sustituido, amino sin sustituir o sustituido, mercapto sin sustituir o sustituido, sulfonilo sustituido, halógeno, ciano o nitro. n representa el número de X² y un número entero de 0 a 3. El conjunto de uno de X² y R puede formar cíclilo de 5 - 8 miembros sin sustituir o sustituido. E representa hidrocarburo cíclico de 5 - 7 miembros sin sustituir o sustituido con X² o heterociclilo de 5 - 7 miembros sin sustituir o sustituido con X². X representa un átomo de oxígeno o de nitrógeno, o un átomo de nitrógeno sustituido con alquilo C₁₋₈).A fungicide is provided for use in agriculture and gardening that has good efficiency and safety, and a heterocyclic compound containing nitrogen or a salt thereof that is useful as an active principle of a fungicide for use in agriculture and gardening. Claim 1: A nitrogen-containing heterocyclic compound having the formula (1) or a salt thereof. (In formula (1), R represents OR¹, NR¹R², SR¹, S (= O) R³, SO₂R³, S (= O) (= NR⁴) R⁵, N = S (= O) R⁴R⁵ or nitro; R¹ represents a hydrogen atom, unsubstituted or substituted C₁₋₈ alkyl, unsubstituted or substituted Cque alkenyl, unsubstituted or substituted C₂₋₈ alkynyl, unsubstituted or substituted C₃₋₈ cycloalkyl, unsubstituted or substituted C₄₋₈ cycloalkenyl, aryl Unsubstituted or substituted C₆₋₁₀, unsubstituted or substituted heterocyclyl, unsubstituted or substituted C₁₋₈ acyl, unsubstituted or substituted carboxyl, unsubstituted or substituted carbamoyl, substituted sulfonyl, or unsubstituted or substituted amino.R² represents an atom of hydrogen, unsubstituted or substituted C₁₋₈ alkyl, unsubstituted or substituted C alkenyl, unsubstituted or substituted Cin alkynyl, unsubstituted or substituted C₃₋₈ cycloalkyl, unsubstituted or substituted C ciclo cycloalkenyl, C₆₋ aryl ₁₀ no substitute tuir or substituted, unsubstituted or substituted heterocyclyl, unsubstituted or substituted C₁₋₈ acyl, unsubstituted or substituted carboxyl, unsubstituted or substituted carbamoyl, substituted sulfonyl, unsubstituted or substituted hydroxy, or unsubstituted or substituted amino. R³ represents unsubstituted or substituted C₁₋₈ alkyl, unsubstituted or substituted C alkenyl, unsubstituted or substituted C sustitu alkynyl, unsubstituted or substituted C₃₋₈ cycloalkyl, unsubstituted or substituted C₄₋₈ cycloalkenyl, C₆₋ aryl ₁₀ unsubstituted or substituted, unsubstituted or substituted heterocyclyl, unsubstituted or substituted mercapto, unsubstituted or substituted hydroxy, or unsubstituted or substituted amino. R⁴ and R⁵ represent, independently of each other, unsubstituted or substituted C₁₋₈ alkyl, unsubstituted or substituted Cque alkenyl, unsubstituted or substituted Cin alkynyl, unsubstituted or substituted C₃₋₈ cycloalkyl, C₄₋₈ cycloalkenyl without substituted or substituted, unsubstituted or substituted C₆₋₁₀ aryl, or unsubstituted or substituted heterocyclyl. In the NR¹R² group, the set of R¹ and R² can form 3-8 unsubstituted or substituted cyclyl, = CRᵃRᵇ or = NRᶜ. Rᵃ and Rᵇ represent, independently of each other, a hydrogen atom, unsubstituted or substituted C₁₋₈ alkyl, unsubstituted or substituted Cque alkenyl, unsubstituted or substituted Cin alkynyl, unsubstituted or substituted C ciclo cycloalkyl, C sustituir unsubstituted or substituted cycloalkenyl, unsubstituted or substituted Cilo aryl, unsubstituted or substituted heterocyclyl, unsubstituted or substituted C₁₋₈ acyl, unsubstituted or substituted carboxyl, unsubstituted or substituted carbamoyl, substituted sulfonyl, mercapto without substituted or substituted, unsubstituted or substituted hydroxyl, or unsubstituted or substituted amino. Rᶜ represents unsubstituted or substituted hydroxyl, or unsubstituted or substituted C₁₋₈ alkyl. In the group N = S (= O) R⁴R⁵, the set of R⁴ and R⁵ can form 5-8 membered cyclyl unsubstituted or substituted. X¹ represents, independently of each other, unsubstituted or substituted C₁₋₈ alkyl, unsubstituted or substituted Cque alkenyl, unsubstituted or substituted Cin alkynyl, unsubstituted or substituted C₃₋₈ cycloalkyl, unsubstituted or substituted Cal cycloalkenyl substituted, unsubstituted or substituted C₆₋₁₀ aryl, unsubstituted or substituted heterocyclyl, unsubstituted or substituted C₁₋₈ acyl, (1-imino) unsubstituted or substituted C₁₋₈ alkyl, unsubstituted or substituted carboxyl, unsubstituted carbamoyl or substituted, unsubstituted or substituted hydroxyl, unsubstituted or substituted amino, unsubstituted or substituted mercapto, substituted sulfonyl, halogen, cyano or nitro. m represents the number of X¹ and an integer from 0 to 5. B represents a carbon or nitrogen atom. D represents 5-7 membered cyclic hydrocarbon unsubstituted or substituted with X¹ or 5-7 membered heterocyclyl unsubstituted or substituted with X¹. X² represents, independently of each other, unsubstituted or substituted C₁₋₈ alkyl, unsubstituted or substituted Cque alkenyl, unsubstituted or substituted C₂₋₈ alkynyl, unsubstituted or substituted C₃₋₈ cycloalkyl, unsubstituted or substituted C₄₋₈ cycloalkenyl substituted, unsubstituted or substituted C₆₋₁₀ aryl, unsubstituted or substituted heterocyclyl, unsubstituted or substituted C₁₋₈ acyl, (1-imino) unsubstituted or substituted C₁₋₈ alkyl, unsubstituted or substituted carboxyl, unsubstituted carbamoyl or substituted, unsubstituted or substituted hydroxyl, unsubstituted or substituted amino, unsubstituted or substituted mercapto, substituted sulfonyl, halogen, cyano or nitro. n represents the number of X² and an integer from 0 to 3. The set of one of X² and R can form 5-8 membered cyclyl unsubstituted or substituted. E represents 5-7 membered cyclic hydrocarbon unsubstituted or substituted with X² or 5-7 membered heterocyclyl unsubstituted or substituted with X². X represents an oxygen or nitrogen atom, or a nitrogen atom substituted with C₁₋₈ alkyl).

ARP120102265 2011-06-28 2012-06-25 HETEROCICLIC COMPOUND CONTAINING NITROGEN AND FUNGICIDE FOR USE IN AGRICULTURE AND GARDENING AR086744A1 (en)

Applications Claiming Priority (2)

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JP2011143479 2011-06-28
JP2012006279 2012-01-16

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AR086744A1 true AR086744A1 (en) 2014-01-22

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JP (1) JP5753583B2 (en)
AR (1) AR086744A1 (en)
TW (1) TW201304681A (en)
WO (1) WO2013002205A1 (en)

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AR106515A1 (en) 2015-10-29 2018-01-24 Bayer Cropscience Ag SILISPHENOXYHETEROCICLES, TRISUSTITUTED AND ANALOG
TWI782983B (en) * 2017-04-27 2022-11-11 德商拜耳廠股份有限公司 Heteroarylphenylaminoquinolines and analogues
EP3619197A1 (en) 2017-05-03 2020-03-11 Bayer Aktiengesellschaft Trisubstitutedsilylmethylphenoxyquinolines and analogues
JP2020518592A (en) 2017-05-03 2020-06-25 バイエル・アクチエンゲゼルシヤフト Trisubstituted silylheteroaryloxyquinolines and analogs
TW201927768A (en) 2017-12-21 2019-07-16 德商拜耳廠股份有限公司 Trisubstitutedsilylmethylheteroaryloxyquinolines and analogues
WO2021209490A1 (en) 2020-04-16 2021-10-21 Bayer Aktiengesellschaft Cyclaminephenylaminoquinolines as fungicides

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JPWO2013002205A1 (en) 2015-02-23
WO2013002205A1 (en) 2013-01-03
JP5753583B2 (en) 2015-07-22
TW201304681A (en) 2013-02-01

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