AR081319A1 - Piridinas sustituidas que tienen accion herbicida - Google Patents
Piridinas sustituidas que tienen accion herbicidaInfo
- Publication number
- AR081319A1 AR081319A1 ARP110100937A ARP110100937A AR081319A1 AR 081319 A1 AR081319 A1 AR 081319A1 AR P110100937 A ARP110100937 A AR P110100937A AR P110100937 A ARP110100937 A AR P110100937A AR 081319 A1 AR081319 A1 AR 081319A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkyl
- alkoxy
- haloalkyl
- haloalkoxy
- alkynyl
- Prior art date
Links
- 229910052717 sulfur Inorganic materials 0.000 abstract 11
- 229910052757 nitrogen Inorganic materials 0.000 abstract 10
- 229910052760 oxygen Inorganic materials 0.000 abstract 10
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 abstract 9
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 8
- 125000005842 heteroatom Chemical group 0.000 abstract 8
- 229910052739 hydrogen Inorganic materials 0.000 abstract 8
- 239000001257 hydrogen Substances 0.000 abstract 8
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 8
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 abstract 5
- -1 Z-C3-6-cycloalkenyl Chemical group 0.000 abstract 5
- 229910052736 halogen Inorganic materials 0.000 abstract 5
- 125000002911 monocyclic heterocycle group Chemical group 0.000 abstract 5
- 229920006395 saturated elastomer Polymers 0.000 abstract 5
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 4
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 abstract 4
- 125000004122 cyclic group Chemical group 0.000 abstract 4
- 150000002367 halogens Chemical group 0.000 abstract 4
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 abstract 3
- 125000004648 C2-C8 alkenyl group Chemical group 0.000 abstract 3
- 125000004649 C2-C8 alkynyl group Chemical group 0.000 abstract 3
- 125000002619 bicyclic group Chemical group 0.000 abstract 3
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 3
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 abstract 3
- 125000004767 (C1-C4) haloalkoxy group Chemical group 0.000 abstract 2
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 2
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 125000000623 heterocyclic group Chemical group 0.000 abstract 2
- 125000002950 monocyclic group Chemical group 0.000 abstract 2
- 125000004739 (C1-C6) alkylsulfonyl group Chemical group 0.000 abstract 1
- 125000006642 (C1-C6) cyanoalkyl group Chemical group 0.000 abstract 1
- 125000004737 (C1-C6) haloalkoxy group Chemical group 0.000 abstract 1
- 125000006656 (C2-C4) alkenyl group Chemical group 0.000 abstract 1
- 125000006650 (C2-C4) alkynyl group Chemical group 0.000 abstract 1
- 125000003320 C2-C6 alkenyloxy group Chemical group 0.000 abstract 1
- 150000001204 N-oxides Chemical class 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 125000002618 bicyclic heterocycle group Chemical group 0.000 abstract 1
- 150000001721 carbon Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000004009 herbicide Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 abstract 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 1
- 150000003222 pyridines Chemical class 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D491/00—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
- C07D491/02—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
- C07D491/04—Ortho-condensed systems
- C07D491/044—Ortho-condensed systems with only one oxygen atom as ring hetero atom in the oxygen-containing ring
- C07D491/052—Ortho-condensed systems with only one oxygen atom as ring hetero atom in the oxygen-containing ring the oxygen-containing ring being six-membered
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pyridine Compounds (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Abstract
Composiciones que las comprenden y su uso como herbicidas, así como también los métodos para controlar la vegetacion no deseada. Reivindicacion 1: Una piridina sustituida de la formula (1) en donde las variables tienen el siguiente significado: R es O-RA, S(O)n-RA o O-S(O)n-RA; RA es hidrogeno, C1-4-alquilo, Z-C3-6-cicloalquilo, C1-4-haloalquilo, C2-6-alquenilo, Z-C3-6-cicloalquenilo, C2-6-alquinilo, Z-(tri-C1-4-alquil)sililo, Z-C(=O)-Ra, Z-NRi-C(O)-NRiRii, Z-P(=O)(Ra)2, NRiRii, un heterociclo monocíclico de 3- a 7-miembros o bicíclico de 9- o 10-miembros saturado, insaturado o aromático que contiene 1, 2, 3 o 4 heteroátomos seleccionados del grupo que consiste en O, N y S y que pueden estar sustituidos total o parcialmente por los grupos Ra y/o Rb, Ra es hidrogeno, OH, C1-8-alquilo, C1-4-haloalquilo, Z-C3-6-cicloalquilo, C2-8-alquenilo, Z-C5-6-cicloalquenilo, C2-8-alquinilo, Z-C1-6-alcoxi, Z-C1-4-haloalcoxi, Z-C3-8-alqueniloxi, Z-C3-8- alquiniloxi, NRiRii, C1-6-alquilsulfonilo, Z-(tri-C1-4-alquil)sililo, Z-fenilo, Z-fenoxi, Z-fenilamino o un heterociclo monocíclico de 5- o 6- miembros o bicíclico de 9- o 10- miembros que contiene 1, 2, 3 o 4 heteroátomos seleccionados del grupo que consiste en O, N y S, en donde los grupos cíclicos son no sustituidos o sustituidos con 1, 2, 3 o 4 grupos Rb; Ri, Rii, independientemente entre sí, son hidrogeno, C1-8-alquilo, C1-4-haloalquilo, C3-8-alquenilo, C3-8-alquinilo, Z-C3-6-cicloalquilo, Z-C1-8-alcoxi, Z-C1-8-haloalcoxi, Z-C(=O)-Ra, Z-fenilo, un heterociclo monocíclico de 3- a 7- miembros o bicíclico de 9- o 10- miembros saturado, insaturado o aromático que contiene 1, 2, 3 o 4 heteroátomos seleccionados del grupo que consiste en O, N y S y que se encuentra unido mediante Z; Ri y Rii junto con el átomo de nitrogeno al cual se encuentran unidos también pueden formar un heterociclo monocíclico de 5- o 6- miembros o bicíclico de 9- o 10- miembros que contiene 1, 2, 3 o 4 heteroátomos seleccionados del grupo que consiste en O, N y S; Z es un enlace covalente o C1-4-alquileno; n es 0, 1 o 2; R1 es ciano, halogeno, nitro, C1-6-alquilo, C2-6-alquenilo, C2-6-alquinilo, C1-6-haloalquilo, Z-C1-6-alcoxi, Z-C1-4-alcoxi-C1-4-alcoxi, Z-C1-4-alquiltio, Z-C1-4-alquiltio-C1-4-alquiltio, C2-6-alqueniloxi, C2-6-alquiniloxi, C1-6-haloalcoxi, C1-4-haloalcoxi-C1-4-alcoxi, S(O)nRbb, Z-fenoxi, Z-heterociclilooxi, en donde el heterociclilo es un heterociclo monocíclico de 5- o 6-miembros o bicíclico de 9- o 10-miembros saturado, parcialmente insaturado o aromático que contiene 1, 2, 3 o 4 heteroátomos seleccionados del grupo que consiste en O, N y S, en donde los grupos cíclicos son no sustituidos o parcial o totalmente sustituidos con Rb; Rbb es C1-8-alquilo, C2-6-alquenilo, C2-6-alquinilo, C2-6-haloalquenilo, C2-6-haloalquinilo o C1-6-haloalquilo y n es 0, 1 o 2; A es N o C-R2; R2 es Z1-fenilo, fenoxi o Z1-heterociclilo, en donde el heterociclilo es un heterociclo monocíclico de 5- o 6- miembros o bicíclico de 9- o 10- miembros saturado, parcialmente insaturado o aromático que contiene 1, 2, 3 o 4 heteroátomos seleccionados del grupo que consiste en O, N y S, en donde los grupos cíclicos son no sustituidos o parcial o totalmente sustituidos con Rb; C1-8-alquilo, C2-4-haloalquilo, C1-4-alcoxi-C1-4-alquilo, C1-4-alquiltio-C1-4-alquilo, C2-8-alquenilo, C2-8-alquinilo, C2-8-haloalquenilo, C2-C8-haloalquinilo, C2-6-alcoxi, Z-C1-4-alcoxi-C1-4-alcoxi, Z-C1-4-haloalcoxi-C1-4-alcoxi, C2-6-haloalcoxi, C3-6-alqueniloxi, C3-6-alquiniloxi, C2-6-alquiltio, C2-6-haloalquiltio, Z-C(=O)-Ra, S(O)1-2Rbb; Z1 es un enlace covalente, C1-4-alquilenooxi, C1-4-oxialquileno o C1-4-alquilenooxi-C1-4-alquileno; Rb independientemente entre sí, son Z-CN, Z-OH, Z-NO2, Z-halogeno, oxo (=O), =N-Ra, C1-8-alquilo, C1-4-haloalquilo, C2-8-alquenilo, C2-8-alquinilo, Z-C1-8-alcoxi, Z-C1-8-haloalcoxi, Z-C3-10-cicloalquilo, O-Z-C3-10-cicloalquilo, Z-C(=O)-Ra, NRiRii, Z-(tri-C1-4-alquil)sililo, Z-fenilo y S(O)nRbb, dos grupos Rb pueden formar, de manera conjunta, un anillo que tiene de 3 a 6 miembros del anillo y, además de los átomos de carbono, también pueden contener heteroátomos del grupo que consiste en O, N y S y puede ser sustituido o no sustituido por otros grupos Rb; R2 junto con el grupo unido al átomo de carbono adyacente también puede formar un anillo biceclico o monocíclico de 5 a 10 miembros saturado o parcial o totalmente insaturado que, además de átomos de carbono, puede contener 1, 2 o 3 heteroátomos seleccionados del grupo que consiste en O, N y S y puede sustituirse con otros grupos Rb; R3 es hidrogeno, halogeno, ciano, nitro, C1-4-alquilo, C1-4-haloalquilo, C1-4-alcoxi, C1-4-haloalcoxi, C2-4-alquenilo, C2-4-alquinilo, C2-4-alqueniloxi, C2-4-alquiniloxi, S(O)nRbb; R4 es hidrogeno, halogeno o C1-4-haloalkyl; R5 es hidrogeno, C1-4-alquilo, C1-4-haloalquilo, C1-4-alcoxi, C1-4-alquiltio, C1-4-haloalcoxi, C1-4-haloalquiltio; R6, R7 independientemente entre sí, son hidrogeno, halogeno o C1-4-alquilo; Y es O o S; X es O, S o N-Rx; Rx es hidrogeno, C1-6-alquilo, C1-4-haloalquilo, C2-6-alquenilo, C3-6-alquinilo, Z-C3-10-cicloalquilo, C1-6-alcoxi-C1-6-alquilo, C1-6-cianoalquilo, Z-fenilo, Z-C(=O)Ra2 o tri-C1-4-alquilsililo; Ra2 es C1-6-alquilo, C1-4-haloalquilo, Z-C1-6-alcoxi, Z-C1-4-haloalcoxi o NRiRii; en donde los grupos RA y sus subsustituyentes, las cadenas de carbono y/o los grupos cíclicos pueden ser parcial o totalmente sustituidos por grupos Rb, o un N-oxido o su sal adecuada para la agricultura.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US31640010P | 2010-03-23 | 2010-03-23 | |
| EP10157312 | 2010-03-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR081319A1 true AR081319A1 (es) | 2012-08-08 |
Family
ID=43836970
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP110100937A AR081319A1 (es) | 2010-03-23 | 2011-03-22 | Piridinas sustituidas que tienen accion herbicida |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8809535B2 (es) |
| EP (1) | EP2550276A1 (es) |
| JP (1) | JP2013522339A (es) |
| CN (1) | CN102906096A (es) |
| AR (1) | AR081319A1 (es) |
| BR (1) | BR112012023765A2 (es) |
| WO (1) | WO2011117195A1 (es) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2011231819A1 (en) | 2010-03-23 | 2012-10-18 | Basf Se | Pyridothiazines having herbicidal action |
| AR081526A1 (es) | 2010-03-23 | 2012-10-03 | Basf Se | Piridazinas sustituidas que tienen accion herbicida |
| EP2550279A1 (en) | 2010-03-23 | 2013-01-30 | Basf Se | Pyrazinothiazines having herbicidal action |
| IN2013CN01335A (es) | 2010-07-22 | 2015-08-07 | Basf Se | |
| EP2802212B1 (en) | 2012-01-12 | 2015-12-30 | Basf Se | Herbicidal isoxazolo[5,4-b]pyridines |
| BR112015012645A2 (pt) | 2012-12-18 | 2018-10-23 | Basf Se | métodos para produção, molécula e constructo de ácido nucleico, vetor, polipeptídeo, núcleo de célula vegetal, planta transgênica, processo, composição, uso do ácido nucleico e método para controlar ervas daninhas |
| WO2014116894A1 (en) * | 2013-01-25 | 2014-07-31 | Dow Agrosciences Llc | Selective weed control methods |
| US9872498B2 (en) * | 2015-02-12 | 2018-01-23 | Rotam Agrochem International Company Limited | Process for preparing a novel formulation of rimsulfuron and use of the same |
| GB201507463D0 (en) * | 2015-04-30 | 2015-06-17 | Syngenta Participations Ag | Herbicidal compounds |
| GB201507464D0 (en) * | 2015-04-30 | 2015-06-17 | Syngenta Participations Ag | Herbicidal compounds |
| ES2732930T3 (es) * | 2015-04-30 | 2019-11-26 | Syngenta Participations Ag | Compuestos Herbicidas |
| GB201507497D0 (en) * | 2015-04-30 | 2015-06-17 | Syngenta Participations Ag | Herbicidal compounds |
| EP3133065A1 (en) | 2015-08-21 | 2017-02-22 | Merck Patent GmbH | Compounds for optically active devices |
| US10573722B2 (en) * | 2016-02-17 | 2020-02-25 | General Electric Company | Systems and methods for in-situ doped semiconductor gate electrodes for wide bandgap semiconductor power devices |
| SI3438095T1 (sl) | 2016-03-30 | 2021-09-30 | Ishihara Sangyo Kaisha, Ltd. | Piridazinonska spojina ali njena sol in herbicid, ki jo vsebuje |
| EP3363786A1 (en) | 2017-02-15 | 2018-08-22 | Merck Patent GmbH | Compounds for optically active devices |
| EP3363793A1 (en) | 2017-02-15 | 2018-08-22 | Merck Patent GmbH | Hydrophobic compounds for optically active devices |
| CN112110846A (zh) * | 2019-06-20 | 2020-12-22 | 河北农业大学 | 一类n-芳基邻苯二甲酰亚胺衍生物及其制备方法和用途 |
| MX2022011615A (es) | 2020-05-20 | 2022-12-15 | AMO Ireland | Derivados de azacoumarina y azatiocumarina para uso en dispositivos ópticamente activos. |
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| ES2417012T3 (es) | 2001-08-09 | 2013-08-05 | Northwest Plant Breeding Co. | Plantas de trigo que exhiben resistencia aumentada a los herbicidas de imidazolinona |
| US7230167B2 (en) | 2001-08-31 | 2007-06-12 | Syngenta Participations Ag | Modified Cry3A toxins and nucleic acid sequences coding therefor |
| AU2002361696A1 (en) | 2001-12-17 | 2003-06-30 | Syngenta Participations Ag | Novel corn event |
| PL375524A1 (en) | 2002-07-10 | 2005-11-28 | The Department Of Agriculture, Western Australia | Wheat plants having increased resistance to imidazolinone herbicides |
| US20040068141A1 (en) | 2002-10-08 | 2004-04-08 | Armstrong Joseph D. | Process for the synthesis of trifluorophenylacetic acids |
| US6870067B2 (en) | 2002-10-08 | 2005-03-22 | Merck & Co., Inc. | Process for the synthesis of trifluorophenylacetic acids |
| ATE556139T1 (de) | 2003-05-28 | 2012-05-15 | Basf Se | Weizenpflanzen mit erhöhter resistenz gegenüber imidazolinonherbiziden |
| KR20060063892A (ko) * | 2003-07-18 | 2006-06-12 | 바스프 악티엔게젤샤프트 | 아릴-축합 3-아릴피리딘 화합물 및 그의 병원성 진균류조절 용도 |
| UY28495A1 (es) | 2003-08-29 | 2005-03-31 | Inst Nac De Tecnologia Agropec | Plantas de arroz que tienen una mayor tolerancia a los herbicidas de imidazolinona |
| GB0614471D0 (en) | 2006-07-20 | 2006-08-30 | Syngenta Ltd | Herbicidal Compounds |
| GB0624760D0 (en) | 2006-12-12 | 2007-01-17 | Syngenta Ltd | Herbicidal compounds |
| GB0625598D0 (en) | 2006-12-21 | 2007-01-31 | Syngenta Ltd | Novel herbicides |
| EP2215068B1 (en) | 2007-10-29 | 2012-06-13 | Merck Sharp & Dohme Corp. | Antidiabetic tricyclic compounds |
| GB0722472D0 (en) | 2007-11-15 | 2007-12-27 | Syngenta Ltd | Herbicidal compounds |
| GB0800855D0 (en) * | 2008-01-17 | 2008-02-27 | Syngenta Ltd | Herbicidal compounds |
| GB0800856D0 (en) | 2008-01-17 | 2008-02-27 | Syngenta Ltd | Herbicidal compounds |
| GB0816880D0 (en) | 2008-09-15 | 2008-10-22 | Syngenta Ltd | Improvements in or relating to organic compounds |
| CN102203091B (zh) | 2008-10-29 | 2014-08-13 | 巴斯夫欧洲公司 | 具有除草作用的取代吡啶 |
| BRPI0917738A2 (pt) | 2008-12-18 | 2015-08-11 | Basf Se | Composto heterocíclico, composição e método para controlar vegetação indesejada |
| US20120071322A1 (en) | 2009-06-05 | 2012-03-22 | Basf Se | Substituted Pyridopyrazines with a Herbicidal Action |
| WO2011051212A1 (de) | 2009-10-28 | 2011-05-05 | Basf Se | Verwendung heteroaromatischer verbindungen als herbizide |
| US8329619B2 (en) | 2009-11-03 | 2012-12-11 | Basf Se | Substituted quinolinones having herbicidal action |
| WO2011057989A1 (en) | 2009-11-11 | 2011-05-19 | Basf Se | Heterocyclic compounds having herbicidal action |
| WO2011058036A1 (en) | 2009-11-13 | 2011-05-19 | Basf Se | Tricyclic compounds having herbicidal action |
| WO2011117210A1 (en) | 2010-03-23 | 2011-09-29 | Basf Se | Substituted pyridines having herbicidal action |
| EP2550279A1 (en) | 2010-03-23 | 2013-01-30 | Basf Se | Pyrazinothiazines having herbicidal action |
| AU2011231819A1 (en) | 2010-03-23 | 2012-10-18 | Basf Se | Pyridothiazines having herbicidal action |
| AR081526A1 (es) | 2010-03-23 | 2012-10-03 | Basf Se | Piridazinas sustituidas que tienen accion herbicida |
| AR080781A1 (es) | 2010-03-23 | 2012-05-09 | Basf Se | Piridazinas sustituidas que tienen accion herbicida |
-
2011
- 2011-03-21 WO PCT/EP2011/054258 patent/WO2011117195A1/en active Application Filing
- 2011-03-21 EP EP11708891A patent/EP2550276A1/en not_active Withdrawn
- 2011-03-21 BR BR112012023765A patent/BR112012023765A2/pt not_active IP Right Cessation
- 2011-03-21 JP JP2013500454A patent/JP2013522339A/ja not_active Withdrawn
- 2011-03-21 CN CN2011800246379A patent/CN102906096A/zh active Pending
- 2011-03-21 US US13/636,430 patent/US8809535B2/en not_active Expired - Fee Related
- 2011-03-22 AR ARP110100937A patent/AR081319A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US8809535B2 (en) | 2014-08-19 |
| US20130023415A1 (en) | 2013-01-24 |
| JP2013522339A (ja) | 2013-06-13 |
| EP2550276A1 (en) | 2013-01-30 |
| BR112012023765A2 (pt) | 2015-09-29 |
| WO2011117195A1 (en) | 2011-09-29 |
| CN102906096A (zh) | 2013-01-30 |
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