AR075230A1 - Iniciadores multifuncionales azo para polimerizaciones de radicales libres: metodos de preparacion. - Google Patents

Iniciadores multifuncionales azo para polimerizaciones de radicales libres: metodos de preparacion.

Info

Publication number
AR075230A1
AR075230A1 ARP100100293A ARP100100293A AR075230A1 AR 075230 A1 AR075230 A1 AR 075230A1 AR P100100293 A ARP100100293 A AR P100100293A AR P100100293 A ARP100100293 A AR P100100293A AR 075230 A1 AR075230 A1 AR 075230A1
Authority
AR
Argentina
Prior art keywords
star
azo
free radical
preparation methods
methods
Prior art date
Application number
ARP100100293A
Other languages
English (en)
Original Assignee
Nalco Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nalco Co filed Critical Nalco Co
Publication of AR075230A1 publication Critical patent/AR075230A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/04—Azo-compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/32—Polymerisation in water-in-oil emulsions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B29/00—Monoazo dyes prepared by diazotising and coupling
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52—Amides or imides
    • C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/56—Acrylamide; Methacrylamide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)

Abstract

La solicitud presenta composiciones de materia, métodos para su síntesis y métodos para su uso en reacciones de polimerizacion. Las composiciones incluyen iniciadores polifuncionales utilizados para la preparacion de polímeros en forma de estrella al polimerizarse con los monomeros. Los iniciadores polifuncionales se sintetizan de un nucleo multifuncional con por lo menos dos grupos funcionales y dos o más unidades de iniciador enlazadas a los grupos funcionales. Las unidades de iniciador tienen dos grupos captadores de electrones enlazados a un átomo de carbono central y un grupo azo entre el átomo de carbono central y el grupo funcional. Los iniciadores polifuncionales son particularmente eficaces, puesto que se descomponen para formar el nucleo radical de un polímero en forma de estrella, los grupos captadores de electrones impiden que el radical correspondiente forme ninguna contaminacion con polímeros lineales y solo se produzcan los polímeros en forma de estrella pretendidos.
ARP100100293A 2009-02-09 2010-02-03 Iniciadores multifuncionales azo para polimerizaciones de radicales libres: metodos de preparacion. AR075230A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US12/367,984 US20100204361A1 (en) 2009-02-09 2009-02-09 Novel multifunctional azo initiators for free radical polymerizations: methods of preparation

Publications (1)

Publication Number Publication Date
AR075230A1 true AR075230A1 (es) 2011-03-16

Family

ID=42145087

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP100100293A AR075230A1 (es) 2009-02-09 2010-02-03 Iniciadores multifuncionales azo para polimerizaciones de radicales libres: metodos de preparacion.

Country Status (9)

Country Link
US (2) US20100204361A1 (es)
EP (1) EP2393843A2 (es)
CN (1) CN102307908A (es)
AR (1) AR075230A1 (es)
AU (1) AU2010210449B2 (es)
BR (1) BRPI1005697A2 (es)
CA (1) CA2751146A1 (es)
TW (1) TW201038517A (es)
WO (1) WO2010091333A2 (es)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8097687B2 (en) * 2009-02-09 2012-01-17 Nalco Company Multifunctional azo initiators for free radical polymerizations: uses thereof
US8436094B2 (en) * 2010-08-25 2013-05-07 Henkel Corporation Curable compositions with moisture-curable functionality clusters near the chain ends
US9410288B2 (en) 2013-08-08 2016-08-09 Ecolab Usa Inc. Use of nanocrystaline cellulose and polymer grafted nanocrystaline cellulose for increasing retention in papermaking process
US9034145B2 (en) 2013-08-08 2015-05-19 Ecolab Usa Inc. Use of nanocrystaline cellulose and polymer grafted nanocrystaline cellulose for increasing retention, wet strength, and dry strength in papermaking process
US9303360B2 (en) 2013-08-08 2016-04-05 Ecolab Usa Inc. Use of nanocrystaline cellulose and polymer grafted nanocrystaline cellulose for increasing retention in papermaking process
US9834730B2 (en) 2014-01-23 2017-12-05 Ecolab Usa Inc. Use of emulsion polymers to flocculate solids in organic liquids
US10570347B2 (en) 2015-10-15 2020-02-25 Ecolab Usa Inc. Nanocrystalline cellulose and polymer-grafted nanocrystalline cellulose as rheology modifying agents for magnesium oxide and lime slurries
WO2017205339A1 (en) 2016-05-23 2017-11-30 Ecolab Usa Inc. Reduced misting acidic cleaning, sanitizing, and disinfecting compositions via the use of high molecular weight water-in-oil emulsion polymers
WO2017205334A1 (en) 2016-05-23 2017-11-30 Ecolab Usa Inc. Reduced misting alkaline and neutral cleaning, sanitizing, and disinfecting compositions via the use of high molecular weight water-in-oil emulsion polymers
WO2018160818A1 (en) 2017-03-01 2018-09-07 Ecolab Usa Inc. Reduced inhalation hazard sanitizers and disinfectants via high molecular weight polymers
CN110997593B (zh) 2017-07-17 2023-01-24 埃科莱布美国股份有限公司 使浆料的流变性改性的方法
FR3096985B1 (fr) 2019-06-05 2021-05-14 S N F Sa Procede de preparation de polymeres structures sous forme de poudre par voie gel
MX2022000454A (es) 2019-07-12 2022-04-18 Ecolab Usa Inc Limpiador alcalino de niebla reducida mediante el uso de polímeros en emulsión solubles en álcali.

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4101464A (en) * 1975-02-11 1978-07-18 Pennwalt Corporation Process for preparing foamed solids using two or more azo compounds
US4532301A (en) * 1984-11-05 1985-07-30 Atlantic Richfield Company Radial block polymers
US4929721A (en) * 1988-06-29 1990-05-29 The Dow Chemical Company Polymerizable aromatic-azo-aliphatic compounds capable of generating photoinitiated free radicals
AU5129100A (en) * 1999-05-10 2000-11-21 Procter & Gamble Company, The Non-symmetrical free radical initiators and process for use therewith
US6433092B2 (en) * 2000-04-20 2002-08-13 Nova Chemicals Inc. Tetrafunctional initiator
US6166099A (en) * 2000-04-20 2000-12-26 Nova Chemicals Inc Tetrafunctional initiator
US6420444B1 (en) * 2000-10-04 2002-07-16 Nova Chemicals, Inc. Tetrafunctional initiator
US6605674B1 (en) * 2000-06-29 2003-08-12 Ondeo Nalco Company Structurally-modified polymer flocculants
DE10047155A1 (de) 2000-09-22 2002-04-11 Basf Ag Verzweigte Polymerisate, Verfahren zu deren Herstellung und deren Verwendung
US6627719B2 (en) * 2001-01-31 2003-09-30 Ondeo Nalco Company Cationic latex terpolymers for sludge dewatering
US8097687B2 (en) * 2009-02-09 2012-01-17 Nalco Company Multifunctional azo initiators for free radical polymerizations: uses thereof

Also Published As

Publication number Publication date
TW201038517A (en) 2010-11-01
BRPI1005697A2 (pt) 2016-03-15
AU2010210449A1 (en) 2011-09-29
US20100204361A1 (en) 2010-08-12
CA2751146A1 (en) 2010-08-12
CN102307908A (zh) 2012-01-04
US8258208B2 (en) 2012-09-04
US20120123072A1 (en) 2012-05-17
EP2393843A2 (en) 2011-12-14
AU2010210449B2 (en) 2014-12-04
WO2010091333A2 (en) 2010-08-12
WO2010091333A3 (en) 2010-10-28

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