AR072762A1 - Procedimiento para la recuperacion de catalizadores - Google Patents
Procedimiento para la recuperacion de catalizadoresInfo
- Publication number
- AR072762A1 AR072762A1 ARP080105435A ARP080105435A AR072762A1 AR 072762 A1 AR072762 A1 AR 072762A1 AR P080105435 A ARP080105435 A AR P080105435A AR P080105435 A ARP080105435 A AR P080105435A AR 072762 A1 AR072762 A1 AR 072762A1
- Authority
- AR
- Argentina
- Prior art keywords
- acid
- recovery
- extractant
- heteropolytic
- heteropolitungstic
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 238000011084 recovery Methods 0.000 title abstract 2
- 239000002253 acid Substances 0.000 abstract 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 239000003456 ion exchange resin Substances 0.000 abstract 1
- 229920003303 ion-exchange polymer Polymers 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 239000010937 tungsten Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
- B01J38/68—Liquid treating or treating in liquid phase, e.g. dissolved or suspended including substantial dissolution or chemical precipitation of a catalyst component in the ultimate reconstitution of the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/30—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/28—Regeneration or reactivation
- B01J27/285—Regeneration or reactivation of catalysts comprising compounds of phosphorus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/74—Regeneration or reactivation of catalysts, in general utilising ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/30—Obtaining chromium, molybdenum or tungsten
- C22B34/36—Obtaining tungsten
- C22B34/365—Obtaining tungsten from spent catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/92—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
- B01J38/06—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using steam
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
- B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
- B01J38/52—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids oxygen-containing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
- B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
- B01J38/56—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/30—Tungsten
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/14—Phosphorus; Compounds thereof
- C07C2527/16—Phosphorus; Compounds thereof containing oxygen
- C07C2527/18—Phosphorus; Compounds thereof containing oxygen with metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Un procedimiento para la recuperacion de tungsteno a partir de un catalizador agotado que comprende un ácido heteropolitungstico soportado, caracterizándose el procedimiento porque comprende: (a) poner en contacto el catalizador agotado con un extractante seleccionado entre agua, metanol, etanol o una mezcla de cualesquiera dos o más de los mismos durante un tiempo suficiente para extraer del mismo al menos parte del ácido heteropolitungstico; (b) separar el extractante que contiene ácido heteropolitungstico del catalizador agotado tratado; (c) poner en contacto el extractante que contiene ácido heteropolitungstico con una resina de intercambio ionico de ácido fuerte para separar los metales de corrosion allí contenidos; y (d) recuperar el extractante tratado que contiene ácido heteropiolitungstico para su posterior uso.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07254848A EP2075070A1 (en) | 2007-12-13 | 2007-12-13 | Catalyst recovery process |
Publications (1)
Publication Number | Publication Date |
---|---|
AR072762A1 true AR072762A1 (es) | 2010-09-22 |
Family
ID=39507445
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP080105435A AR072762A1 (es) | 2007-12-13 | 2008-12-12 | Procedimiento para la recuperacion de catalizadores |
Country Status (11)
Country | Link |
---|---|
US (1) | US20100210448A1 (es) |
EP (2) | EP2075070A1 (es) |
CN (1) | CN101896269B (es) |
AR (1) | AR072762A1 (es) |
BR (1) | BRPI0819848A2 (es) |
DK (1) | DK2225035T3 (es) |
ES (1) | ES2671451T3 (es) |
RU (1) | RU2484900C2 (es) |
TR (1) | TR201807479T4 (es) |
WO (1) | WO2009074774A2 (es) |
ZA (1) | ZA201002129B (es) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2287145A1 (en) | 2009-08-12 | 2011-02-23 | BP p.l.c. | Process for purifying ethylene |
US11338280B2 (en) * | 2020-02-03 | 2022-05-24 | Usa Debusk Llc | Catalytic reactor system treatment processes |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2968527A (en) * | 1957-10-03 | 1961-01-17 | Columbia Southern Chem Corp | Method of recovering tungstic acid values from aqueous media |
GB894592A (en) * | 1957-10-03 | 1962-04-26 | Columbia Southern Chem Corp | Process for the recovery of tungstic acid catalyst |
US3644497A (en) * | 1968-11-01 | 1972-02-22 | Celanese Corp | Conversion of ethylenically unsaturated compounds using heteropoly-molybdic and heteropolytungstic acids as catalysts |
GB1518338A (en) * | 1974-11-18 | 1978-07-19 | Degussa | Process for separating epoxidation and hydroxylation catalysts from distillation residues |
US4007130A (en) * | 1975-12-29 | 1977-02-08 | Monsanto Company | Catalyst regeneration method |
CA1150293A (en) * | 1979-10-01 | 1983-07-19 | Keisuke Wada | Process for the production of methylenedicarbanilates |
JPS56163755A (en) * | 1980-05-23 | 1981-12-16 | Mitsubishi Chem Ind Ltd | Recovery method for heteropolyacid catalyst component |
US5716895A (en) * | 1993-04-01 | 1998-02-10 | Nippon Kayaku Kabushiki Kaisha | Process for regeneration of catalysts |
US5387702A (en) | 1993-09-29 | 1995-02-07 | Council Of Scientific And Industrial Research | Process for the preparation of cabofuran |
CN1093000C (zh) * | 1996-12-27 | 2002-10-23 | 吉林化学工业公司研究院 | 醚裂解制异丁烯催化剂及其应用 |
JP3887511B2 (ja) * | 1999-05-19 | 2007-02-28 | 三菱レイヨン株式会社 | 触媒の製造方法 |
EP1172348A1 (en) | 2000-07-14 | 2002-01-16 | Haldor Topsoe A/S | Process of paraffin isomerisation |
GB0113079D0 (en) * | 2001-05-30 | 2001-07-18 | Kvaerner Process Tech Ltd | Process |
GB0316756D0 (en) * | 2003-07-17 | 2003-08-20 | Bp Chem Int Ltd | Process |
CN1921941B (zh) * | 2004-02-24 | 2013-01-16 | 三菱丽阳株式会社 | 钼的回收方法和催化剂的制造方法 |
US7291272B2 (en) * | 2004-05-07 | 2007-11-06 | Orica Australia Pty Ltd. | Inorganic contaminant removal from water |
GB0410289D0 (en) * | 2004-05-07 | 2004-06-09 | Bp Chem Int Ltd | Process |
US8367886B2 (en) * | 2005-07-06 | 2013-02-05 | Bp Chemicals Limited | Reactive distillation for the dehydration of mixed alcohols |
US7485267B2 (en) * | 2005-07-29 | 2009-02-03 | Chevron U.S.A. Inc. | Process for metals recovery from spent catalyst |
EP1790627A1 (en) * | 2005-11-29 | 2007-05-30 | BP Chemicals Limited | Process for producing olefins |
US20080053909A1 (en) * | 2006-09-06 | 2008-03-06 | Fassbender Alexander G | Ammonia recovery process |
JP5172859B2 (ja) * | 2007-01-19 | 2013-03-27 | ザ・ピュロライト・カンパニー | 逆浸透膜の汚染減少 |
-
2007
- 2007-12-13 EP EP07254848A patent/EP2075070A1/en not_active Ceased
-
2008
- 2008-12-03 EP EP08859059.1A patent/EP2225035B1/en active Active
- 2008-12-03 BR BRPI0819848-9A patent/BRPI0819848A2/pt not_active Application Discontinuation
- 2008-12-03 DK DK08859059.1T patent/DK2225035T3/en active
- 2008-12-03 TR TR2018/07479T patent/TR201807479T4/tr unknown
- 2008-12-03 ES ES08859059.1T patent/ES2671451T3/es active Active
- 2008-12-03 RU RU2010128238/04A patent/RU2484900C2/ru active
- 2008-12-03 CN CN2008801203735A patent/CN101896269B/zh active Active
- 2008-12-03 US US12/733,811 patent/US20100210448A1/en not_active Abandoned
- 2008-12-03 WO PCT/GB2008/004014 patent/WO2009074774A2/en active Application Filing
- 2008-12-12 AR ARP080105435A patent/AR072762A1/es unknown
-
2010
- 2010-03-25 ZA ZA2010/02129A patent/ZA201002129B/en unknown
Also Published As
Publication number | Publication date |
---|---|
US20100210448A1 (en) | 2010-08-19 |
WO2009074774A2 (en) | 2009-06-18 |
WO2009074774A3 (en) | 2009-11-05 |
EP2075070A1 (en) | 2009-07-01 |
EP2225035B1 (en) | 2018-04-25 |
RU2010128238A (ru) | 2012-01-20 |
BRPI0819848A2 (pt) | 2015-06-16 |
DK2225035T3 (en) | 2018-06-18 |
ZA201002129B (en) | 2014-09-25 |
ES2671451T3 (es) | 2018-06-06 |
EP2225035A2 (en) | 2010-09-08 |
RU2484900C2 (ru) | 2013-06-20 |
TR201807479T4 (tr) | 2018-06-21 |
CN101896269B (zh) | 2013-06-19 |
CN101896269A (zh) | 2010-11-24 |
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