AR066715A1 - Derivados de aminoazolina y urea para combatir plagas animales - Google Patents

Derivados de aminoazolina y urea para combatir plagas animales

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AR066715A1
AR066715A1 ARP080102197A ARP080102197A AR066715A1 AR 066715 A1 AR066715 A1 AR 066715A1 AR P080102197 A ARP080102197 A AR P080102197A AR P080102197 A ARP080102197 A AR P080102197A AR 066715 A1 AR066715 A1 AR 066715A1
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Argentina
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radicals
carry
alkyl
ring
alkynyl
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ARP080102197A
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Basf Se
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    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D261/00—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings
    • C07D261/02—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings
    • C07D261/06—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members
    • C07D261/10—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D261/18—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
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    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/32—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing >N—CO—N< or >N—CS—N< groups directly attached to a cycloaliphatic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
    • A01N47/44—Guanidine; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P33/00—Antiparasitic agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C275/26—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of rings other than six-membered aromatic rings
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C279/00—Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups
    • C07C279/16—Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of guanidine groups bound to carbon atoms of rings other than six-membered aromatic rings
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C335/00—Thioureas, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C335/04—Derivatives of thiourea
    • C07C335/14—Derivatives of thiourea having nitrogen atoms of thiourea groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/79—Acids; Esters
    • C07D213/80—Acids; Esters in position 3
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    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D233/28—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D233/44—Nitrogen atoms not forming part of a nitro radical
    • C07D233/50—Nitrogen atoms not forming part of a nitro radical with carbocyclic radicals directly attached to said nitrogen atoms
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    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/02—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings
    • C07D263/08—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D263/16—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D263/28—Nitrogen atoms not forming part of a nitro radical
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    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
    • C07D277/08—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D277/12—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D317/44—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D317/46—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems condensed with one six-membered ring
    • C07D317/48—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring
    • C07D317/50—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to atoms of the carbocyclic ring
    • C07D317/60—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
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    • C07C2602/00—Systems containing two condensed rings
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    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
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    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/10—One of the condensed rings being a six-membered aromatic ring the other ring being six-membered, e.g. tetraline

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Pretreatment Of Seeds And Plants (AREA)
  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
  • Thiazole And Isothizaole Compounds (AREA)
  • Pyridine Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

Uso de derivados de aminoazolina y urea para combatir plagas animales. También un método para controlar plagas animales usando estos compuestos, semillas y una composicion agrícola y veterinaria que comprende dichos compuestos y derivados de azolina y urea específicos. Reivindicacion 1: El uso de compuestos de la formula (1) o de una de sus sales para combatir plagas animales caracterizado porque Z es un grupo de las formulas (2A), (2B) o (2C), n es 0, 1, 2, 3 o 4; m es 1 o 2; es el sitio de union con el resto de la molécula; X es S, O o NR5; Y es S, O o NR5a; T es -ORT1, -SRT2, -O-C(O)-RT3, -O-C(S)-RT4 o -S-C-(S)-RT5, RT1, RT2, RT3, RT4 y RT5 se seleccionan de hidrogeno, alquilo C1-6, alquenilo C2-6 o alquinilo C2-6, donde los ultimos tres radicales mencionados pueden llevar 1, 2 o 3 sustituyentes RTa; cicloalquilo C3-6 que pueden llevar 1, 2 o 3 sustituyentes RTb; fenilo que puede llevar 1 2 o 3 sustituyentes RTc; donde el anillo fenilo también puede estar fusionado con otro anillo fenilo o a un anillo heterocíclico saturado, parcialmente insaturado o aromático de 5 o 6 miembros que contiene 1, 2 o 3 heteroátomos seleccionados de O, S y N y opcionalmente 1 o 2 grupos carbonilo como miembros del anillo, donde el sistema de anillos fusionados pueden llevar 1, 2 o 3 sustituyentes RTc; heterociclo saturado, parcialmente insaturado o aromático de 5 o 6 miembros que contiene 1, 2 o 3 heteroátomos seleccionados de O, S y N y opcionalmente 1 o 2 grupos carbonilo como miembros del anillo, que pueden llevar 1, 2 o 3 sustituyentes RTd; o RT3, RT4, RT5 son NRT31RT32, donde RT31 y RT32, de modo independiente entre sí, se seleccionan de hidrogeno, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, donde los tres ultimos grupos mencionados pueden llevar 1, 2 o 3 sustituyentes RTa, cicloalquilo C3-6, que pueden llevar 1, 2 o 3 sustituyentes RTb; arilo y aril-alquilo C1-4, donde el resto de arilo en los dos ultimos grupos mencionados pueden llevar 1, 2 o 3 sustituyentes RTc; o RT31 y RT32 junto con el átomo de nitrogeno al que están unidos forman un heterocíclico saturado, parcialmente insaturado o aromático de 3, 4, 5 o 6 miembros que contiene 1, 2 o 3 heteroátomos seleccionados de O, S y N y opcionalmente 1 o 2 grupos carbonilo como miembros del anillo, donde el anillo heterocíclico puede llevar 1, 2 o 3 sustituyentes RTd; R1 está seleccionado del grupo que consiste en hidrogeno, ciano, alquilo C1-6, haloalquilo C1-6, alquenilo C2-6, alquinilo C1-6, alcoxicarbonilo C1-6, alquil C1-6-carbonilo, alquenil C2-6-carbonilo, alquinil C2-6-carbonilo; cicloalquilo C3-6, fenilo, bencilo, fenoxicarbonilo, hetarilo de 5 o 6 miembros y hetarilmetilo de 5 o 6 miembros cada uno de los ultimos seis radicales mencionados pueden no estar sustituidos o pueden llevar cualquier combinacion de 1, 2, 3, 4 o 5 radicales Rb1; R2a, R2b se seleccionan del grupo que consiste en hidrogeno, formilo, CN, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, alquil C1-6-carbonilo, alquenil C2-6-carbonilo, alquinil C2-6-carbonilo, alcoxicarbonilo C1-6, alquil C1-6-tiocarbonilo, alcoxi C1-6-tiocarbonilo, en donde los átomos de carbono en los radicales alifáticos de los grupos antes mencionados pueden llevar cualquier combinacion de 1, 2 o 3 radicales Ra2, C(O)NRaRb, C(S)NRaRb, (SO2)NRaRb, fenilo, benzoilo, fenoxicarbonilo, bencilo, bencilcarbonilo, benciloxicarbonilo, un anillo saturado, parcialmente insaturado o aromático de 5 o 6 miembros, hetarilmetilo de 5 o 6 miembros, hetarilcarbonilo de 5 o 6 miembros, hetarilmetilcarbonilo de 5 o 6 miembros, en donde cada uno de los ultimos diez radicales mencionados pueden no estar sustituidos o pueden llevar cualquier combinacion de 1, 2, 3, 4 o 5 radicales Rb2, y en donde el anillo heteroaromático de 5 o 6 miembros en hetarilmetilo, hetarilcarbonilo y hetarilmetilcarbonilo contiene 1, 2, 3 o 4 heteroátomos seleccionados de oxígeno, azufre y nitrogeno como miembros del anillo, y en donde el anillo heterocíclico de 5 o 6 miembros contiene 1, 2 o 3 heteroátomos seleccionados de oxígeno, azufre y nitrogeno como miembros del anillo; o R1 junto con R2a puede ser alcan C3-5-diilo que pueden llevar 1, 2, 3, 4 o 5 radicales R21 y donde uno o dos grupos metileno del radical alcan C3-5-diílo pueden estar reemplazados por 1 o 2 heteroátomos no adyacentes o grupos que contienen heteroátomos seleccionados de O, S y NR22; R1 junto con R2b también puede ser un grupo carbonilo de puente C(O); R2c y R2d, de modo independiente entre sí, se seleccionan de hidrogeno, formilo, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, arilo, aril-alquilo C1-4, hetarilo, hetaril-alquilo C1-4, alquil C1-6-carbonilo, alquil C1-6-tiocarbonilo, alquenil C2-6-carbonilo, alquinil C2-6-carbonilo, alcoxicarbonilo C1-6, alcoxi C1-6-tiocarbonilo, arilcarbonilo, hetarilcarbonilo, ariloxicarbonilo y hetariloxicarbonilo, donde los restos alifáticos, aromáticos o heteroaromáticos en los ultimos 17 radicales mencionados pueden llevar 1, 2, 3, 4 o 5 radicales Rc2, y donde hetarilo es un anillo heteroaromático de 5 o 6 miembros que contiene 1, 2, 3 o 4 heteroátomos seleccionados de O, S y N como miembros del anillo; R3a, R3b, R3c, R3d, de modo independiente entre sí, se seleccionan del grupo que consiste en hidrogeno, halogeno, ciano, nitro, hidroxi, mercapto, amino, haloalquilo C1-6, alquilo C1-6, alquil C1-6-amino, di-(alquil C1-6)amino, alcoxi C1-6, en donde los átomos de carbono en los ultimos 4 radicales mencionados pueden no estar sustituidos o pueden llevar cualquier combinacion de 1, 2 o 3 radicales Ra3, cicloalquilo C3-6, fenilo o bencilo, cada uno de los ultimos 3 radicales mencionados pueden no estar sustituidos o pueden llevar cualquier combinacion de 1, 2, 3, 4 o 5 radicales Rb3; R4a, R4b, de modo independiente entre sí, se seleccionan del grupo que consiste en hidrogeno, halogeno, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, haloalquilo C1-6, en donde los átomos de carbono en estos grupos pueden llevar cualquier combinacion de 1, 2 o 3 radicales Ra4, fenilo, bencilo, hetarilo de 5 o 6 miembros y hetarilmetilo de 5 o 6 miembros, cada uno de los ultimos 4 radicales mencionados pueden no estar sustituidos o pueden llevar cualquier combinacion de 1 2, 3, 4 o 5 radicales Rb4, y en donde el anillo heteroaromático de 5 o 6 miembros en hetarilmetilo y hetarilo contiene 1, 2, 3 o 4 heteroátomos seleccionados de oxigeno, azufre y nitrogeno como miembros del anillo; o R4a junto con R4b también puede ser =O, =NRc o =CRdRe; o R4a junto con R4b también puede ser alcan C2-5-diílo que pueden llevar 1, 2, 3, 4, 5 o 6 sustituyentes R41 y donde uno o dos grupos metileno del radical alcan C2-5-diílo pueden estar reemplazados por 1 o 2 heteroátomos no adyacentes o grupos que contienen heteroátomos seleccionados de O, S y NR42; o R2a junto con R4a pueden formar un radical bivalente en puente seleccionados del grupo que consiste en C(O)-C(R24a)(R24b), C(S)-C(R24a)(R24b), CH2-C(R24a)(R24b), S(O)2-C(R24a)(R24b), S(O)-C(R24a)(R24b), C(O)-O, C(S)-O, S(O)2-O, S(O)-O, C(O)-NH, C(S)-NH, S(O)2-NH, S(O)-NH; R4c, R4d se definen, de modo independiente, como R4a y R4b; R5, R5a, de modo independiente entre sí, se seleccionan del grupo que consiste en hidrogeno, formilo, CN, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, alquil C1-6-carbonilo, alquenil C2-6-carbonilo, alquinil C2-6-carbonilo, alcoxicarbonilo C1-6, alquil C1-6-tiocarbonilo, en donde los átomos de carbono en los radicales alifáticos de los grupos antes mencionados pueden llevar cualquier combinacion de 1, 2 o 3 radicales Ra5, C(O)NRaRb, (SO2)NRaRb, C(S)NRaRb, fenilo, bencilo, fenoxicarbonilo, hetarilmetilo de 5 o 6 miembros, hetarilcarbonilo de 5 o 6 miembros y benzoílo cada uno de los ultimos 6 radicales mencionados pueden no estar sustituidos o pueden llevar cualquier combinacion de 1, 2, 3, 4 o 5 radicales Rb5, y en donde el anillo heteroaromático de 5 o 6 miembros en hetarilmetilo y hetarilcarbonilo contiene 1, 2, 3 o 4 heteroátomos seleccionados de oxígeno, azufre y nitrogeno como miembros del anillo; cada Rz1 está seleccionado, de modo independiente, del grupo que consiste en halogeno, OH, SH, SO3H, COOH, ciano, nitro, alquilo C1-6, alcoxi C1-6, alquil C1-6-tio, alquenilo C2-6, alquenil C2-6-oxi, alquenil C2-6-tio, alquinilo C2-6, alquinil C2-6-oxi, alquinil C2-6-tio, alquil C1-6-sulfonilo, alquil C1-6-sulfoxilo, alquenil C2-6-sulfonilo, alquinil C2-6-sulfonilo, un radical NRaRb, formilo, alquil C1-6-carbonilo, alquenil C2-6-carbonilo, alquinil C2-6-carbonilo, alcoxicarbonilo C1-6, alquenil C2-6-oxicarbonilo, alquinil C2-6-oxicarbonilo, formiloxi, alquil C1-6-carboniloxi, alquenil C2-6-carboniloxi, alquinil C2-6-carboniloxi, en donde los átomos de carbono en los radicales alifáticos de los grupos antes mencionados pueden levar cualquier combinacion de 1 2, 3, 4 o 5 radicales Raz, C(O)NRaRb, (SO2)NRaRb, y radicales de la formula L-Cy, en donde L es un enlace simple, oxigeno, azufre o alcan C1-6-diílo, en donde un carbono puede estar reemplazado por oxigeno, Cy está seleccionado del grupo que consiste en cicloalquilo C3-12, que no está sustituido o que está sustituido con cualquier combinacion de 1, 2, 3, 4 o 5 radicales Rbz, fenilo, naftilo y heterociclilo mono- o bicíclico de 5 a 10 miembros, que contiene 1, 2, 3 o 4 heteroátomos seleccionados de oxigeno, azufre y nitrogeno como miembros del anillo, en donde Cy no está sustituido o pueden llevar cualquier combinacion de 1, 2, 3, 4 o 5 radicales Rbz; y en donde dos radicales Rz1 que están unidos a átomos de carbono adyacentes pueden formar junto con dichos átomos de carbono un anillo benceno fusionado, un carbociclo fusionado, saturado o parcialmente insaturado de 5, 6 o 7 miembros o un heterociclo fusionado de 5, 6 o 7 miembros, que contiene 1, 2, 3 o 4 heteroátomos seleccionados de oxígeno, azufre y nitrogeno como miembros del anillo, y en donde el anillo fusionado no está sustituido o pueden llevar cualquier combinacion de 1, 2, 3 o 4 radicales Rbz; Ra, Rb están seleccionados
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