AR035947A1 - Derivados sinteticos de 21-butenilespinosina de compuestos relacionados,composiciones insecticidas y acaricidas formuladas con dichos derivados y metodos de aplicacion de los derivados mencionados - Google Patents

Derivados sinteticos de 21-butenilespinosina de compuestos relacionados,composiciones insecticidas y acaricidas formuladas con dichos derivados y metodos de aplicacion de los derivados mencionados

Info

Publication number
AR035947A1
AR035947A1 ARP020101029A ARP020101029A AR035947A1 AR 035947 A1 AR035947 A1 AR 035947A1 AR P020101029 A ARP020101029 A AR P020101029A AR P020101029 A ARP020101029 A AR P020101029A AR 035947 A1 AR035947 A1 AR 035947A1
Authority
AR
Argentina
Prior art keywords
alkylcarbonyl
alkyl
formula
derivatives
group
Prior art date
Application number
ARP020101029A
Other languages
English (en)
Original Assignee
Dow Agrosciences Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Agrosciences Llc filed Critical Dow Agrosciences Llc
Publication of AR035947A1 publication Critical patent/AR035947A1/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H17/00—Compounds containing heterocyclic radicals directly attached to hetero atoms of saccharide radicals
    • C07H17/04—Heterocyclic radicals containing only oxygen as ring hetero atoms
    • C07H17/08—Hetero rings containing eight or more ring members, e.g. erythromycins
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N45/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring
    • A01N45/02—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring having three carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
    • A01N63/30—Microbial fungi; Substances produced thereby or obtained therefrom
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P33/00—Antiparasitic agents
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P33/00—Antiparasitic agents
    • A61P33/14—Ectoparasiticides, e.g. scabicides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
    • C07H15/00—Compounds containing hydrocarbon or substituted hydrocarbon radicals directly attached to hetero atoms of saccharide radicals
    • C07H15/26—Acyclic or carbocyclic radicals, substituted by hetero rings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Biotechnology (AREA)
  • Zoology (AREA)
  • Genetics & Genomics (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • Molecular Biology (AREA)
  • Veterinary Medicine (AREA)
  • Environmental Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Dentistry (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Public Health (AREA)
  • Medicinal Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mycology (AREA)
  • Virology (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Saccharide Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Pyrane Compounds (AREA)

Abstract

Se describen y reivindican derivados de síntesis relacionados con la 21-butenilespinosina. Específicamente se trata de fórmula (1), respectivamente de la fórmula (2), donde: R3 es un grupo de las fórmulas (3a) a (3v); R4 es H, OH, OR15, ó =O; R5 es H ó CH3; R6 y R7 son H o se combinan para formar una unión doble o un grupo epoxi; R8 en la fórmula (1) es un butenilo-1-trans, 1,3-butadienilo, n-butilo, 3-hidroxi-1-butenilo, n-propilo, 1-propenilo, 1,2-epoxi-1-butilo, 3-oxo-1-butenilo, ó CH3COR15CH=CH-, y R8 en la fórmula (2) es etilo; R9 es H o un grupo que contiene una de las fórmula (9a) a (9p); R15 es alquilo C2-6, alquilo C3-6 ramificado, cicloalquilo C3-7, alquilo C1-6-alcoxi C1-6, alquilo C1-6-alquiltio C1-6, halo-alquilo C1-6, alquenilo C2-6, formilo, alquinilo C2-6, alquilcarbonilo C1-6 o alquilcarbonilo C3-6 ramificado, cicloalquilcarbonilo C3-7, alquilcarbonilo C1-6-alcoxi C1-6, alquilcarbonilo C1-6 halo, alquenilcarbonilo C2-6, y alquinilcarbonilo C2-6; R16 en la fórmula (9m) es un alquilo C1-6, alquenilo C1-6, formilo, alquilcarbonilo C1-6 o alquilcarbonilo ramificado C3-6; N en la fórmula (9n) es un interger de 1 a 4; siempre que al menos se cumpla una de las siguientes condiciones: a) R3 se selecciona del grupo formado por las fórmulas (3g) a (3v); b) R4 es -OCH3, -OR15 ó =O; c) R6 y R7 son H o R6 y R7 se combinan para formar un grupo epoxi; d) R8 es propilo, n-butilo, 1,2-epoxi-1-butilo; CH3C(O)CH=CH, CH3CH(OCH3)CH=CH ó CH3CH(OR15)CH=CH; e) R9 se selecciona del grupo formado por las fórmulas (9j) a (9p); y siempre que el compuesto 22,23-dihidro-ram-I esté excluido. Dichos compuestos provienen de modificaciones introducidas, vía sintética, en factores que producen ciertas cepas de Saccharopolyspora pogona-LW 107129-NRRL 30141-, o cepas mutantes, que contienen genes inactivados de las O-metiltransferasa que poseen actividad acaricida e insecticida y que resultan útiles en la preparación de compuestos con actividad acaricida e insecticida. Se describen y reivindican además los objetos mencionados en el título.
ARP020101029A 2001-03-21 2002-03-21 Derivados sinteticos de 21-butenilespinosina de compuestos relacionados,composiciones insecticidas y acaricidas formuladas con dichos derivados y metodos de aplicacion de los derivados mencionados AR035947A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US27754601P 2001-03-21 2001-03-21

Publications (1)

Publication Number Publication Date
AR035947A1 true AR035947A1 (es) 2004-07-28

Family

ID=23061327

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP020101029A AR035947A1 (es) 2001-03-21 2002-03-21 Derivados sinteticos de 21-butenilespinosina de compuestos relacionados,composiciones insecticidas y acaricidas formuladas con dichos derivados y metodos de aplicacion de los derivados mencionados

Country Status (12)

Country Link
EP (1) EP1370566B1 (es)
JP (1) JP4346310B2 (es)
KR (1) KR100904942B1 (es)
CN (1) CN100354293C (es)
AR (1) AR035947A1 (es)
AU (1) AU2008202480B2 (es)
DK (1) DK1370566T3 (es)
ES (1) ES2634110T3 (es)
IL (1) IL157975A0 (es)
MX (1) MXPA03008505A (es)
TW (1) TWI275592B (es)
WO (1) WO2002077004A1 (es)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK1373290T3 (da) * 2001-03-21 2014-12-01 Dow Agrosciences Llc Pesticidale spinosynderivater
AR033022A1 (es) * 2001-03-30 2003-12-03 Dow Agrosciences Llc Genes biosinteticos para la produccion de insecticida de butenilespinosina
US20030225006A1 (en) * 2002-02-19 2003-12-04 Burns Lesley S Novel spinosyn-producing polyketide synthases
DE10320505A1 (de) 2003-05-08 2004-11-25 Bayer Healthcare Ag Mittel zum Bekämpfen von Parasiten an Tieren
BRPI0718128B8 (pt) * 2006-11-03 2022-06-28 Dow Agrosciences Llc Redução seletiva de fatores espinosina et-j e et-l a espinetorama
CN102202506B (zh) * 2008-09-22 2015-07-29 克里斯廷·克里蒂考 刺糖多孢菌素防污组合物、其使用方法、以及受到保护而免于附着污损生物的制品
CN102190694B (zh) * 2010-03-12 2015-09-09 中南大学 多杀菌素衍生物、制备方法及其作为杀虫剂的用途
AU2010101148C4 (en) * 2010-10-19 2015-01-22 Dow Agrosciences Llc Methods of controlling pests
CN102977166B (zh) * 2012-12-05 2015-07-29 湖南化工研究院 13-硫醚取代多杀菌素衍生物及其制备方法
WO2017040769A1 (en) 2015-09-03 2017-03-09 Agrimetis, Llc Spinosyn derivatives as insecticides
BR102017003580B1 (pt) * 2016-03-04 2022-03-29 Dow Agrosciences Llc Sistema e processos para produzir spinetoram
KR20190103341A (ko) * 2017-01-13 2019-09-04 에그리메티스, 엘엘씨 아지리딘 스피노신 유도체 및 제조 방법
AR125402A1 (es) 2021-04-23 2023-07-12 Acies Bio D O O Profármacos nuevos de espinosinas
EP4079744A1 (en) 2021-04-23 2022-10-26 Acies Bio d.o.o. Novel spinosyn prodrugs
EP4101858A1 (en) 2021-06-08 2022-12-14 Acies Bio d.o.o. Novel spinosyn compounds

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PE5591A1 (es) * 1988-12-19 1991-02-15 Lilly Co Eli Un nuevo grupo de compuestos de macrolida
US6001981A (en) * 1996-06-13 1999-12-14 Dow Agrosciences Llc Synthetic modification of Spinosyn compounds
IL148601A0 (en) * 1999-09-13 2002-09-12 Dow Agrosciences Llc Pesticidal macrolides
DK1373290T3 (da) * 2001-03-21 2014-12-01 Dow Agrosciences Llc Pesticidale spinosynderivater

Also Published As

Publication number Publication date
TWI275592B (en) 2007-03-11
ES2634110T3 (es) 2017-09-26
MXPA03008505A (es) 2004-06-30
CN100354293C (zh) 2007-12-12
EP1370566A1 (en) 2003-12-17
JP4346310B2 (ja) 2009-10-21
EP1370566B1 (en) 2017-04-19
KR100904942B1 (ko) 2009-06-29
IL157975A0 (en) 2004-03-28
AU2008202480A1 (en) 2008-06-26
DK1370566T3 (en) 2017-07-24
KR20030085019A (ko) 2003-11-01
AU2008202480B2 (en) 2011-09-01
WO2002077004A1 (en) 2002-10-03
JP2004530665A (ja) 2004-10-07
CN1531543A (zh) 2004-09-22

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