AR003364A1 - INDOLINOESPIROXACINAS AND FOTOCROMATICAS, COMPOSITION AND MATRIX OF COPOLIMERO THAT UNDERSTAND THEM AND ARTICLES THAT CONTAIN THEM. - Google Patents
INDOLINOESPIROXACINAS AND FOTOCROMATICAS, COMPOSITION AND MATRIX OF COPOLIMERO THAT UNDERSTAND THEM AND ARTICLES THAT CONTAIN THEM.Info
- Publication number
- AR003364A1 AR003364A1 ARP960104127A AR10412796A AR003364A1 AR 003364 A1 AR003364 A1 AR 003364A1 AR P960104127 A ARP960104127 A AR P960104127A AR 10412796 A AR10412796 A AR 10412796A AR 003364 A1 AR003364 A1 AR 003364A1
- Authority
- AR
- Argentina
- Prior art keywords
- poly
- optionally
- group
- aryl
- alkyl
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D498/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D498/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
- C07D498/10—Spiro-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
- C09K9/02—Organic tenebrescent materials
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/22—Absorbing filters
- G02B5/23—Photochromic filters
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/685—Compositions containing spiro-condensed pyran compounds or derivatives thereof, as photosensitive substances
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Eyeglasses (AREA)
Abstract
La invención se refiere a compuestos fotocromáticos con la fórmula (I), en donde R1 es un grupo policíclico formado por al menos un grupo alicíclico quese encuentra ligado a al menos un anillo alifático y/o aromático, cuyos anillos contienen, opcionalmente, al menos un heteroátomo y al menos una insaturación;R2 y R3 son idénticos o diferentes y representan un grupo alquilo, lineal o ramificado, de 1-12 átomos de carbono, un grupo alquenilo, alquinilo, arilo,alquiloarilo, cicloalquilo; R2 yR3 pueden opcionalmente, combinado para formar un grupo carboxíclico o heterocíclico que tenga de 5 a 10 átomos; R4, R5, R6 yR7 son idénticos o diferentes y representan: hidrógeno;un alquilo,cicloalquilo, alquenilo, alquinilo, arilo, heteroarilo, ariloxi o aralquilo, siendo dichogrupo opcionalmente halogenado; un halógeno; OR, SR, -OCOR, con R= H, alquilo y/ocicloalquilo y/o arilo; un (poli)éter, una (poli)amida, un (poli)carbonato,un (poli)carbamato, una (poli)urea, o un (poli)éster; un radical amino que da origen, cuando se encuentra ligado en (I), a una amina primaria, secundaria oterciaria, donde dicha amina puede ser alquilo, arilo o aralquilo, mono o disustituida, o un radical aminocíclico conteniendo opcionalmente uno o másheteroátomos; o un grupo que capte un electrón, seleccionado preferentemente, entre el grupo que consta de CF3, CH, NO2, SCN; en que al menos dos de losradicales R4, R5, R6 y R7 pueden formar opcionalmente un conjunto de al menos un anillo aromático que tiene 5 o 6 miembros o un anillo alifático que tenga de5 a 7 miembros, comprendiendo dicho(s) anillo(s), opcionalmente al menos un heteroátomo, de modo de formar al menos un anillo heterocíclico, siendo elúltimo opcionalmente sustituido por uno o más radicales que pueden ser idénticos o diferentes y que tengan la misma definición que se dió más arribaThe invention relates to photochromic compounds with formula (I), wherein R1 is a polycyclic group formed by at least one alicyclic group that is linked to at least one aliphatic and / or aromatic ring, the rings of which optionally contain at least a heteroatom and at least one unsaturation, R2 and R3 are identical or different and represent a linear or branched alkyl group of 1-12 carbon atoms, an alkenyl, alkynyl, aryl, alkylaryl, cycloalkyl group; R2 and R3 can optionally, combined to form a carboxylic or heterocyclic group having 5 to 10 atoms; R4, R5, R6 and R7 are identical or different and represent: hydrogen: an alkyl, cycloalkyl, alkenyl, alkynyl, aryl, heteroaryl, aryloxy or aralkyl, optionally dichogroup being halogenated; a halogen; OR, SR, -OCOR, with R = H, alkyl and / ocycloalkyl and / or aryl; a (poly) ether, a (poly) amide, a (poly) carbonate, a (poly) carbamate, a (poly) urea, or a (poly) ester; an amino radical that gives rise, when linked in (I), to a primary, secondary or oterciary amine, where said amine can be alkyl, aryl or aralkyl, mono or disubstituted, or an aminocyclic radical optionally containing one or more heteroatoms; or an electron-picking group, preferably selected from the group consisting of CF3, CH, NO2, SCN; wherein at least two of the radicals R4, R5, R6 and R7 can optionally form a set of at least one aromatic ring having 5 or 6 members or an aliphatic ring having from 5 to 7 members, said ring (s) comprising ), optionally at least one heteroatom, so as to form at least one heterocyclic ring, the latter being optionally substituted by one or more radicals that may be identical or different and have the same definition as given above
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9510221A FR2738248B1 (en) | 1995-08-30 | 1995-08-30 | PHOTOCHROMIC SPIROXAZINES, COMPOSITIONS AND ARTICLES CONTAINING THEM |
Publications (1)
Publication Number | Publication Date |
---|---|
AR003364A1 true AR003364A1 (en) | 1998-07-08 |
Family
ID=9482169
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP960104127A AR003364A1 (en) | 1995-08-30 | 1996-08-27 | INDOLINOESPIROXACINAS AND FOTOCROMATICAS, COMPOSITION AND MATRIX OF COPOLIMERO THAT UNDERSTAND THEM AND ARTICLES THAT CONTAIN THEM. |
Country Status (2)
Country | Link |
---|---|
AR (1) | AR003364A1 (en) |
FR (1) | FR2738248B1 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1044979A3 (en) * | 1999-03-24 | 2001-05-09 | Corning S.A. | 1-[(N-(un)substituted)amidoalkyl]spiroindolinonaphthoxazines, their preparation, compositions and (co)polymer matrices containing them |
EP1044978A3 (en) * | 1999-03-24 | 2001-05-09 | Corning S.A. | 1-N-alkyl-5'-[(N'-(un)substituted)amido]spiroindolinonaphthoxazines, their preparation, compositions and (co)polymer matrices containing them |
US8188181B2 (en) | 2009-09-22 | 2012-05-29 | Corning Incorporated | Photochromic compositions, resins and articles obtained therefrom |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1927849A1 (en) * | 1969-05-31 | 1970-12-10 | Licentia Gmbh | Spiro-1:4-oxazines |
-
1995
- 1995-08-30 FR FR9510221A patent/FR2738248B1/en not_active Expired - Fee Related
-
1996
- 1996-08-27 AR ARP960104127A patent/AR003364A1/en unknown
Also Published As
Publication number | Publication date |
---|---|
FR2738248B1 (en) | 1997-11-28 |
FR2738248A1 (en) | 1997-03-07 |
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