AR003364A1 - INDOLINOESPIROXACINAS AND FOTOCROMATICAS, COMPOSITION AND MATRIX OF COPOLIMERO THAT UNDERSTAND THEM AND ARTICLES THAT CONTAIN THEM. - Google Patents

INDOLINOESPIROXACINAS AND FOTOCROMATICAS, COMPOSITION AND MATRIX OF COPOLIMERO THAT UNDERSTAND THEM AND ARTICLES THAT CONTAIN THEM.

Info

Publication number
AR003364A1
AR003364A1 ARP960104127A AR10412796A AR003364A1 AR 003364 A1 AR003364 A1 AR 003364A1 AR P960104127 A ARP960104127 A AR P960104127A AR 10412796 A AR10412796 A AR 10412796A AR 003364 A1 AR003364 A1 AR 003364A1
Authority
AR
Argentina
Prior art keywords
poly
optionally
group
aryl
alkyl
Prior art date
Application number
ARP960104127A
Other languages
Spanish (es)
Original Assignee
Corning Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Corning Inc filed Critical Corning Inc
Publication of AR003364A1 publication Critical patent/AR003364A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D498/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D498/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and oxygen atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D498/10—Spiro-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
    • C09K9/02—Organic tenebrescent materials
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/20—Filters
    • G02B5/22—Absorbing filters
    • G02B5/23—Photochromic filters
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/685—Compositions containing spiro-condensed pyran compounds or derivatives thereof, as photosensitive substances

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Eyeglasses (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)

Abstract

La invención se refiere a compuestos fotocromáticos con la fórmula (I), en donde R1 es un grupo policíclico formado por al menos un grupo alicíclico quese encuentra ligado a al menos un anillo alifático y/o aromático, cuyos anillos contienen, opcionalmente, al menos un heteroátomo y al menos una insaturación;R2 y R3 son idénticos o diferentes y representan un grupo alquilo, lineal o ramificado, de 1-12 átomos de carbono, un grupo alquenilo, alquinilo, arilo,alquiloarilo, cicloalquilo; R2 yR3 pueden opcionalmente, combinado para formar un grupo carboxíclico o heterocíclico que tenga de 5 a 10 átomos; R4, R5, R6 yR7 son idénticos o diferentes y representan: hidrógeno;un alquilo,cicloalquilo, alquenilo, alquinilo, arilo, heteroarilo, ariloxi o aralquilo, siendo dichogrupo opcionalmente halogenado; un halógeno; OR, SR, -OCOR, con R= H, alquilo y/ocicloalquilo y/o arilo; un (poli)éter, una (poli)amida, un (poli)carbonato,un (poli)carbamato, una (poli)urea, o un (poli)éster; un radical amino que da origen, cuando se encuentra ligado en (I), a una amina primaria, secundaria oterciaria, donde dicha amina puede ser alquilo, arilo o aralquilo, mono o disustituida, o un radical aminocíclico conteniendo opcionalmente uno o másheteroátomos; o un grupo que capte un electrón, seleccionado preferentemente, entre el grupo que consta de CF3, CH, NO2, SCN; en que al menos dos de losradicales R4, R5, R6 y R7 pueden formar opcionalmente un conjunto de al menos un anillo aromático que tiene 5 o 6 miembros o un anillo alifático que tenga de5 a 7 miembros, comprendiendo dicho(s) anillo(s), opcionalmente al menos un heteroátomo, de modo de formar al menos un anillo heterocíclico, siendo elúltimo opcionalmente sustituido por uno o más radicales que pueden ser idénticos o diferentes y que tengan la misma definición que se dió más arribaThe invention relates to photochromic compounds with formula (I), wherein R1 is a polycyclic group formed by at least one alicyclic group that is linked to at least one aliphatic and / or aromatic ring, the rings of which optionally contain at least a heteroatom and at least one unsaturation, R2 and R3 are identical or different and represent a linear or branched alkyl group of 1-12 carbon atoms, an alkenyl, alkynyl, aryl, alkylaryl, cycloalkyl group; R2 and R3 can optionally, combined to form a carboxylic or heterocyclic group having 5 to 10 atoms; R4, R5, R6 and R7 are identical or different and represent: hydrogen: an alkyl, cycloalkyl, alkenyl, alkynyl, aryl, heteroaryl, aryloxy or aralkyl, optionally dichogroup being halogenated; a halogen; OR, SR, -OCOR, with R = H, alkyl and / ocycloalkyl and / or aryl; a (poly) ether, a (poly) amide, a (poly) carbonate, a (poly) carbamate, a (poly) urea, or a (poly) ester; an amino radical that gives rise, when linked in (I), to a primary, secondary or oterciary amine, where said amine can be alkyl, aryl or aralkyl, mono or disubstituted, or an aminocyclic radical optionally containing one or more heteroatoms; or an electron-picking group, preferably selected from the group consisting of CF3, CH, NO2, SCN; wherein at least two of the radicals R4, R5, R6 and R7 can optionally form a set of at least one aromatic ring having 5 or 6 members or an aliphatic ring having from 5 to 7 members, said ring (s) comprising ), optionally at least one heteroatom, so as to form at least one heterocyclic ring, the latter being optionally substituted by one or more radicals that may be identical or different and have the same definition as given above

ARP960104127A 1995-08-30 1996-08-27 INDOLINOESPIROXACINAS AND FOTOCROMATICAS, COMPOSITION AND MATRIX OF COPOLIMERO THAT UNDERSTAND THEM AND ARTICLES THAT CONTAIN THEM. AR003364A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9510221A FR2738248B1 (en) 1995-08-30 1995-08-30 PHOTOCHROMIC SPIROXAZINES, COMPOSITIONS AND ARTICLES CONTAINING THEM

Publications (1)

Publication Number Publication Date
AR003364A1 true AR003364A1 (en) 1998-07-08

Family

ID=9482169

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP960104127A AR003364A1 (en) 1995-08-30 1996-08-27 INDOLINOESPIROXACINAS AND FOTOCROMATICAS, COMPOSITION AND MATRIX OF COPOLIMERO THAT UNDERSTAND THEM AND ARTICLES THAT CONTAIN THEM.

Country Status (2)

Country Link
AR (1) AR003364A1 (en)
FR (1) FR2738248B1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1044979A3 (en) * 1999-03-24 2001-05-09 Corning S.A. 1-[(N-(un)substituted)amidoalkyl]spiroindolinonaphthoxazines, their preparation, compositions and (co)polymer matrices containing them
EP1044978A3 (en) * 1999-03-24 2001-05-09 Corning S.A. 1-N-alkyl-5'-[(N'-(un)substituted)amido]spiroindolinonaphthoxazines, their preparation, compositions and (co)polymer matrices containing them
US8188181B2 (en) 2009-09-22 2012-05-29 Corning Incorporated Photochromic compositions, resins and articles obtained therefrom

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1927849A1 (en) * 1969-05-31 1970-12-10 Licentia Gmbh Spiro-1:4-oxazines

Also Published As

Publication number Publication date
FR2738248B1 (en) 1997-11-28
FR2738248A1 (en) 1997-03-07

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