WO2014200123A1 - Pyrolysis apparatus for combustible material in solid state - Google Patents

Pyrolysis apparatus for combustible material in solid state Download PDF

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Publication number
WO2014200123A1
WO2014200123A1 PCT/KR2013/005078 KR2013005078W WO2014200123A1 WO 2014200123 A1 WO2014200123 A1 WO 2014200123A1 KR 2013005078 W KR2013005078 W KR 2013005078W WO 2014200123 A1 WO2014200123 A1 WO 2014200123A1
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WO
WIPO (PCT)
Prior art keywords
pyrolysis
combustible material
gas
screw
solid
Prior art date
Application number
PCT/KR2013/005078
Other languages
French (fr)
Korean (ko)
Inventor
구재완
Original Assignee
Ku Jae-Wan
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Filing date
Publication date
Application filed by Ku Jae-Wan filed Critical Ku Jae-Wan
Priority to PCT/KR2013/005078 priority Critical patent/WO2014200123A1/en
Publication of WO2014200123A1 publication Critical patent/WO2014200123A1/en

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/027Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/08Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
    • F23G5/14Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion
    • F23G5/16Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion in a separate combustion chamber
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/44Details; Accessories
    • F23G5/46Recuperation of heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2203/00Furnace arrangements
    • F23G2203/80Furnaces with other means for moving the waste through the combustion zone
    • F23G2203/801Furnaces with other means for moving the waste through the combustion zone using conveyors
    • F23G2203/8013Screw conveyors
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2205/00Waste feed arrangements
    • F23G2205/12Waste feed arrangements using conveyors
    • F23G2205/121Screw conveyor
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2206/00Waste heat recuperation
    • F23G2206/10Waste heat recuperation reintroducing the heat in the same process, e.g. for predrying

Definitions

  • the present invention relates to a pyrolysis device of a flammable material present in the solid phase, and more particularly, to induce heat decomposition of a flammable material in a solid state indirectly under a high temperature, anoxic or low oxygen atmosphere to reduce the emission of pollutants and improve the yield.
  • the present invention relates to a pyrolysis apparatus for combustible materials in a solid state.
  • the use of energy is rapidly increasing due to the increase of factories due to industrial development, and technology for converting the form of energy by recycling or reusing energy is being developed.
  • the initial energy resources in nature for example, combustible crude oil, coal, wood, etc.
  • inorganic materials are processed from minerals which are not combustible materials. It is used in activities.
  • the combustible material has its own energy value because the calorific value varies depending on the element composition of the material (carbon, hydrogen, oxygen, nitrogen, sulfur, phosphorus, chlorine, etc.). If we use it around us and throw it away, it is called waste.
  • a pyrolysis device is applied to treat such solid combustible materials.
  • a predetermined amount of waste is introduced into a pyrolysis chamber in a batch manner, and a lid is closed to remove high temperature heat from the outside.
  • a batch method is adopted in which the waste is pyrolyzed and converted into liquid, gas and solid materials.
  • the batch type pyrolysis method has a lot of difficulties in pyrolysis of wastes in which various substances are mixed, and especially when foreign substances (such as grass, soil, ferrous and nonferrous metals) are mixed, heat transfer is not performed smoothly. Large scale pyrolysis is not achieved.
  • there is a limit to the production of pyrolysis gas and refined oil in the mixed combustible and non-combustible material has a problem that the use value is lowered.
  • the present invention is to solve the problems as described above, in the case of pyrolyzing a solid combustible material in a high temperature, oxygen-free or low oxygen atmosphere by indirect heat, it is possible to process a large amount of solid combustible material in a small space It is an object to provide a pyrolysis device.
  • Another object of the present invention is to provide a pyrolysis apparatus capable of sufficiently removing foreign substances such as chlorine and sulfur contained in pyrolysis gas generated after pyrolysis to increase the purity of oil or gas extracted after pyrolysis.
  • the present invention is to solve the problems as described above, having a main hopper to which the solid combustible material is injected, the pyrolysis screw 220 for transporting, melting and vaporizing the injected combustible material is provided, the transport direction of the combustible material
  • the first body 211, the second body 213, and the third body 215 is formed to be stepwise extended along the second body 213, the second body 213 is provided to be rotatable rotational speed with the pyrolysis screw
  • a pyrolysis chamber 240 installed outside the pyrolyzer body 210 to continuously decompose the combustible material by indirect heating by maintaining an atmosphere of high temperature and low oxygen state;
  • the pyrolysis chamber is provided on one side of the pyrolysis chamber 240 to burn the non-condensing gas of pyrolysis gas generated during pyrolysis of the combustible material so as
  • a sealing unit may be provided between the first body 211 and the second body 213, and between the second body 213 and the third body 215, respectively.
  • the inlet portion of the third body 215 is formed in a circular shape so that no gap is formed with the pyrolysis screw
  • the middle portion of the third body 215 is formed in a streamline so that a predetermined space is formed with the pyrolysis screw.
  • the rear end of the third body 215 may be formed in a circular shape such that a gap is not formed with the pyrolysis screw.
  • the discharge hole 223 is formed in the screw blades of the pyrolysis screw provided in the second body 213 and the third body 215 section.
  • gas retention tower 510 may be provided above the middle portion of the third body 215 of the pyrolysis body to retain the pyrolysis gas generated during pyrolysis of the combustible material for a predetermined time.
  • a spiral screw 520 is provided inside the gas retention tower 510 to separate tar and carbonized material attached to the inner wall of the gas retention tower.
  • one side of the gas retention tower is preferably provided with a desalination device for removing chlorine in the pyrolysis gas.
  • a gas purification means 700 for purifying the pyrolysis gas from which chlorine is removed from the desalination apparatus.
  • refined oil producing means 800 for generating gasoline, light oil and heavy oil according to boiling points in the distillation column after sedimentation and condensation of pyrolysis gas from which chlorine is removed from the dechlorination reaction tower.
  • a carbonized material discharge means for continuously discharging the carbonized material generated after pyrolysis from the pyrolysis chamber 240.
  • the desalination removal apparatus since the desalination removal apparatus is provided in duplicate, the amount of chlorine removal in the pyrolysis gas can be minimized, thereby increasing the purity of oil or gas extracted after pyrolysis of the combustible material.
  • FIG. 1 is a block diagram showing the configuration of a pyrolysis apparatus for a solid combustible material according to an embodiment of the present invention
  • Figure 2 is a partial perspective view showing the "X", "Y" display portion of FIG.
  • FIG. 3 is a cross-sectional view showing lines "A-A”, "B-B”, “C-C”, “D-D”, “E-E”, “F-F”, and "G-G" of FIG.
  • FIG. 4 is a partially enlarged view illustrating a display portion “Z” of FIG. 1;
  • FIG. 5 is a partially enlarged view showing a “W” display unit of FIG. 1;
  • Figure 6 is a schematic block diagram showing a refined oil production process according to an embodiment of the present invention.
  • FIG. 1 is a block diagram schematically showing the configuration of a pyrolysis apparatus for a solid combustible material according to an embodiment of the present invention.
  • the pyrolysis apparatus for a solid combustible material according to an embodiment of the present invention, a pyrolysis means for heating and thermally decomposing the combustible combustible material, a gas for removing chlorine from the pyrolysis gas generated during pyrolysis of the combustible material And reforming means, refining oil producing means for producing refined oil using the reformed gas, and carbonaceous material discharge means for continuously discharging carbonized material (char) discharged after pyrolysis from the pyrolysis means.
  • the pyrolysis principle used in the pyrolysis system of the present embodiment configured as described above is that when a solid combustible material is indirectly heated in an oxygen-free or low oxygen atmosphere, the pyrolysis space is formed in a reducing atmosphere, and the combustible material is decomposed to evaporate into a gas or a liquid. What does not remain solid.
  • the combustible material meaning a flammable polymer compound
  • heat gas (non-condensing gas) + liquid (refined oil) + solid (char).
  • the pyrolysis means comprises a pyrolyzer body 210 to maintain a high temperature and low oxygen atmosphere to continuously pyroly decompose combustible materials by indirect heating.
  • One side of the pyrolyzer body 210 is provided with a main hopper for the input of the pulverized solid combustible material.
  • the combustible combustible material introduced through the main hopper is moved to the pyrolyzer body 210 to pyrolyze.
  • the main hopper is provided with a sensor so that the amount of combustible combustible material is always stored in the main hopper constantly.
  • the detection sensor automatically adjusts the feeding amount of an input conveyor (not shown) of the solid combustible material so that the solid combustible material does not always fall below the set value.
  • a pyrolysis screw 220 for transporting and pyrolyzing the combustible material introduced through the automatic input device 400 is rotatably installed by the drive motor 260.
  • the pyrolysis screw is configured to include a drive shaft 220 connected to the drive motor 230, and a screw blade 221 formed on the outside of the drive shaft 220.
  • the pyrolysis screw is rotated by receiving power from the driving motor 230.
  • a pyrolysis chamber 240 made of a heat insulating material to continuously decompose the combustible material by indirect heating by maintaining a high temperature (350 ⁇ 500 °C) and low oxygen atmosphere.
  • a combustion chamber 250 for supplying high temperature heat to the pyrolysis chamber 240 is used as a heat source for pyrolyzing the combustible material transported by burning it.
  • a burner 251 is provided in the combustion chamber 250.
  • the pyrolyzer body 210 is divided into a first body 211, a second body 213, and a third body 215 in the order of progress of the combustible material.
  • the body is stepped to enlarge the inner diameter step by step to perform the pyrolysis process while going through a three-step process.
  • the first body 211 and the third body 215 is fixed and installed, the second body 213 is installed to be rotatable.
  • the combustible material introduced from the drying means is transferred to the second body 213 by the rotation of the pyrolysis screw 220, and in the section of the second body 213, pyrolysis. Due to the difference in the rotational speed between the screw 220 and the second body 213, the combustible material is moved, and the portion of which thermal decomposition of the preheating, raising the temperature, and vaporizing is substantially performed.
  • the residue which is pyrolyzed is discharged, and the pyrolysis gas is transferred to the second pyrolysis chamber.
  • each of the pyrolyzer body 210 will be described.
  • the first body 211 is installed to be fixed, the combustible material introduced from the drying means is moved to the second body 213 while the thermal decomposition screw 220 is rotated.
  • a first sealing unit 212 is provided between the rear end of the first body 211 and the front end of the second body 213.
  • the first sealing unit 212 has the same configuration as the second sealing 216, which will be described later, is the same as the configuration shown in FIG.
  • the first sealing unit 212 includes a first bushing coupled to the first flange portion formed at the front end of the second body, and a second bushing coupled to the front end of the first bushing. Packings are provided on the inner circumferences of the first bushing and the second bushing, respectively, to double seal between the first body and the second body.
  • the first sealing unit 212 does not leak the combustible material between the step formed between the first body 211 and the second body 213, the second body 213 in the first body 211 As a result, the influx of flammable substances occurs naturally. Accordingly, pyrolysis of the combustible material moving from the first body 211 to the second body 213 is naturally performed. In addition, due to the first sealing unit 212, the friction generated by the rotation of the first body 211 and the second body 213 is minimized, and the first body 211 and the second body 213 The exact level can be maintained, and prevent the back flow of the combustible material from the second body 213 to the first body 211.
  • a rotation motor 260 is provided at one side of the second body 213 so that the second body 213 is rotatable. At this time, the second body 213 is supported by the tire 213c so that the second body 213 is stably rotated.
  • a driven gear 213b is formed on an outer circumference of the second body 213, and the driving gear 264 and the driven gear 213b are engaged with each other so that the driving force generated in the rotary motor 260 is the second body.
  • the second body 213 is rotated by being transferred to 213.
  • At least one tire 213c is provided on an outer circumferential surface of the second body 213.
  • the tire 213c is supported by the support roller 266 so that the second body 213 can stably rotate.
  • the second body 213 and the drying screw is rotated at a relatively slow speed, the flammability by the difference between the rotational speed of the pyrolysis screw 220 provided in the second body 213
  • the material is gradually moved compared to the inside of the first body 211. Therefore, it is possible to provide at least three times more heat transfer area than when the second body 213 is fixed, so that more decomposition of the combustible material can be performed in a smaller space.
  • the combustible material moves in the section of the second body 213, the combustible material completely vaporizes from solid to liquid, liquid to gaseous material (sometimes, directly sublimates from solid state to gaseous state), Residue of the combustible material which lost its intrinsic properties is moved to the third body 215 section in the form of carbon.
  • the second sealing unit 216 is provided between the rear end of the second body 213 and the front end of the third body 215.
  • the second sealing unit 216 is coupled to the first bushing 217 coupled to the second flange portion 215 ′ formed at the front end of the third body 215, and to the front end of the first bushing 217.
  • the second bushing 218 is configured to include. Inner circumferences of the first bushing 217 and the second bushing 218 are provided with packings 217a and 218a, respectively, to double seal between the second body 213 and the third body 215. .
  • the second sealing unit 216 minimizes friction caused by the rotation of the second body 213 and the third body 215, and the second body 213 and the third body 215 are precisely horizontal This can be maintained.
  • the third body 215 is fixedly installed, the front end portion 215a of the third body 215 and the screw blade 221 of the pyrolysis screw 220 for connection with the second body 213.
  • the middle portion 215b of the third body 215 is formed in a streamlined structure so that a space is formed on the upper portion of the screw blade 221 (see Figure 3d).
  • the pyrolysis gas generated at the time of pyrolysis temporarily stays in the space above the screw blades, and the pyrolysis gas can be smoothly moved to the gas retention tower 510 which will be described later.
  • the rear end portion 215c of the third body 215 is a section for discharging ash which has undergone all thermal decomposition, and is formed in a circular shape so as to correspond to the outer diameter of the screw blade to minimize the gap between the screw blade and the third body 215. (See FIG. 3E). Accordingly, fly ash generated after pyrolysis is prevented from moving to the gas retention tower 510.
  • the discharge hole 223 is formed in the screw blade in the section of the second body 213 and the third body 215. Since the discharge hole 223 is formed in the screw blade, the pyrolysis gas generated in the pyrolysis process may naturally move to the gas retention tower 510, and the stirring of the flammable material may be performed smoothly, thereby improving the pyrolysis efficiency.
  • one side of the pyrolyzer body 210 is provided with a nitrogen input device (not shown).
  • a nitrogen input device not shown.
  • valve body 620 such as a slide gate or a rotary valve provided on one side of the third body 215 The air can be blocked from entering the pyrolyzer body 210.
  • the gas reforming means is a gas detention tower 510 connected to the outlet side of the pyrolyzer body 210 and a first desalination apparatus 550 and a second desalination apparatus for removing chlorine from the reformed gas. And 560.
  • the spiral screw 520 is provided inside the gas retention tower 510 to sufficiently secure the residence time of the heat source in the process of being discharged after heating the combustible material in the pyrolyzer body 210 by the heat source supplied from the combustion chamber 250. ) Is provided.
  • the gas is discharged while rotating spirally along the spiral screw 520 to secure a time for the gas to stay in the gas retention tower.
  • a driving motor 530 is coupled to an upper end of the spiral screw 520 to provide a driving force for rotating the spiral screw 520 at a predetermined speed.
  • the pyrolysis gas generated inside the pyrolyzer body 210 is molecularly bonded at a high speed in the inner space of the gas retention tower 510, and detection starts from a substance having a large molecular weight having a long chain of carbon chains.
  • a wax or tar component mainly composed of 24 or more carbon chains is detected.
  • the tar and dewaxing processes are performed in the inner space of the gas retention tower 510.
  • the screw blade of the spiral screw 520 rotated by the drive motor 530 is configured to have an outer diameter corresponding to the inner diameter of the gas retention lead is tar or carbonized material attached to the inner peripheral surface of the gas retention tower 510 By scraping the role of separating from the inner circumferential surface of the gas retention tower 510.
  • the heat source supply chamber 540 is provided on the outside of the gas retention tower 510 to communicate with the pyrolysis chamber 240 through a connection passage. Since the heat source supply chamber 540 is provided, the temperature may be corrected so that the pyrolysis gas rising through the gas retention tower 510 does not condense.
  • the high heat of about 800 ⁇ 900 °C used as indirect heat in the pyrolysis chamber 240 is introduced into the heat source supply chamber 540 surrounding the gas retention tower 510 while falling to about 500 ⁇ 600 °C, the gas The temperature of the retention column 510 is maintained at about 200 ⁇ 250 °C. Therefore, the pyrolysis gas in the gas retention tower 510 is transferred to the first desalination unit 550 without condensation.
  • the chlorine gas is inevitably generated during the thermal decomposition of the combustible material containing the PVC-based additive having a chlorine component among the combustible materials.
  • the temperature of the gas retention tower 510 is calibrated to about 200 to 250 ° C. so that no chlorine compound is generated, and the first desalination unit 550 removes the chlorine component by exposing the pyrolysis gas to a basic aqueous solution. do. That is, in the first desalination apparatus 550, by chemical reaction of HCl + NaOH ⁇ NaCl + H 2 O, reaction products having 7 to 23 carbon chains are continuously generated in pyrolysis gas to remove chlorine. .
  • One side of the first desalination unit 550 of the gas reforming means is provided with a second desalination unit 560 for additionally removing chlorine from the dechlorinated gas.
  • the second desalination unit 560 since pyrolysis gas from which chlorine is first removed is continuously formed in the first desalination unit 550, molecular hydrogen is sprayed to quench the pyrolysis gas by spraying an aqueous sodium hydroxide (NaOH) solution. In this way, generation of benzenes can be suppressed, and the formation of long chains in the carbon chain can be suppressed to obtain light oil.
  • NaOH sodium hydroxide
  • tar which is a black viscous liquid
  • the second desalting apparatus 560 minimizes the space and time at which tar can occur.
  • One side of the second desalination apparatus 560 is provided with a gas purification means 700 for purifying the dechlorinated pyrolysis gas, and a refining oil producing means 800 for generating refined oil using the pyrolysis gas.
  • the gas purification means 700 includes a precipitation condensation apparatus for condensing the dechlorinated pyrolysis gas under a stable atmosphere to generate a primary refined oil, and a purification apparatus for improving gas quality.
  • the gas purified through the gas purification means 700 is stored in the gas storage tank through a water seal device and then supplied to the combustion chamber 250 through a pressure regulating device to be used as a gas for combustion.
  • the refined oil producing means 800 is a storage tank for storing the primary refined oil supplied from the settling condensation device, an oil-separator for oil-separating the primary refined oil stored in the storage tank and the oil-separated refined oil according to the boiling point gasoline, diesel And a distillation column separated by heavy oil.
  • the carbonization material discharge means is a configuration for discharging the carbonized material generated after pyrolysis from the pyrolyzer body 210, and comprises a discharge hopper 610 formed at the end of the pyrolyzer body 210.
  • Carbonization material generated after the pyrolysis is continuously discharged through the end of the pyrolyzer body 210, discharge hopper to block the pyrolysis gas discharged from the outside air and pyrolyzer body 210 when the carbonized material is discharged from the outside.
  • the slide gate 620 is provided.
  • the slide gate 620 is preferably configured in at least two stages to maximize the blocking of the outside and prevent malfunction.
  • the carbonized material continuously discharged through the carbonized material discharge means is discharged to the carbonized material forming means 900 to produce solid fuel. Since the discharged carbonized material is discharged by mixing foreign substances such as superfluous, iron, and non-ferrous metals together, the foreign materials and carbonized material are completely separated through the crushing device and sorting device, and then the foreign materials are removed, and only the carbonized material is passed through the molding device. It produces fuel having a shape, such as briquettes.
  • Solid combustible materials including metal fragments, plastics, paper, industrial combustibles, etc. are shredded to a predetermined size in the crusher after arrival, and the soil, dust, etc. are removed through a sorting machine, and non-ferrous metals are selected and selected. Flammable materials are recycled.
  • the sorted solid combustible material is transferred to a grinder and ground to a relatively small size.
  • the combustible combusted material is secondly re-selected through a magnetic screening device and partly recycled.
  • the pulverized solid combustible material is introduced into the pyrolysis means through the main hopper, and the combustible material transferred to the pyrolyzer body 210 is pyrolyzed by an indirect heating method of a heat source provided to the pyrolysis chamber 240, and the combustible material is pyrolyzed.
  • the combustible material that is melted and vaporized while being transferred to the right direction based on FIG. 1 is continuously pyrolyzed by heat applied indirectly in the pyrolysis chamber 240 maintaining an atmosphere of high temperature and low oxygen state. .
  • the pyrolysis gas generated after the pyrolysis is stayed in the gas retention tower 510 provided above the pyrolyzer body 210, and is indirectly heated to the combustible material to be pyrolyzed, and then transferred to the dechlorination tower.
  • the pyrolysis gas transferred after the pyrolysis passes through the first desalting unit 550 and the second desalting unit 560 and then is transferred to the refining oil producing means 800.
  • the carbonized material lost the properties after the pyrolysis is discharged through the discharge hopper provided on the lower side of the pyrolyzer body (210).
  • the discharged carbonized material is discharged by mixing foreign matters such as superfluous, iron, non-ferrous metal, etc., and produces a fuel having a predetermined shape, such as briquettes, through a crusher and a sorting device.
  • the desalination removal apparatus since the desalination removal apparatus is provided in duplicate, the amount of chlorine removal in the pyrolysis gas can be minimized, thereby increasing the purity of oil or gas extracted after pyrolysis of the combustible material.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

The present invention relates to a pyrolysis apparatus for a combustible material in a solid state, capable of reducing discharge of pollutants and increasing yield, by subjecting a material in a solid state to pyrolysis by indirectly applying heat in a high-temperature and oxygen-free or low-oxygen atmosphere. To this end, the present invention comprises: a pyrolysis device body provided with a pyrolysis screw, which comprises a main hopper into which the combustible material in the solid state is introduced, for transporting, melting, and gasifying the combustible material that is introduced, a first body, a second body, and a third body which are extendedly formed in a stepped manner along a transporting direction of the combustible material, wherein the second body is provided so as to be rotatable so that the combustible material is transported by means of a difference in rotating speed between the second body and the pyrolysis screw; a pyrolysis chamber, installed on the outside of the pyrolysis body, for continuously subjecting the combustible material to pyrolysis by means of indirect heating by maintaining the high-temperature and the low-oxygen atmosphere; and a combustion chamber, provided on one side of the pyrolysis chamber, for providing heat to the pyrolysis chamber by combusting a non-condensable gas among pyrolysis gases, which are generated during the pyrolysis of the combustible material, so that the non-condensable gas is used as a heat source for the pyrolysis of the combustible material transported to the pyrolysis device body.

Description

고체 상태 가연성 물질의 열분해장치Pyrolysis device for solid state flammable material
본 발명은 고체상으로 존재하는 가연성 물질의 열분해장치에 관한 것으로, 더욱 상세하게는 고상 상태의 가연성 물질을 고온, 무산소 또는 저산소 분위기하에서 간접적으로 열을 가하여 열분해시켜 공해물질의 배출을 줄이고 수율을 향상시킬 수 있도록 한 고체 상태의 가연성 물질의 열분해장치에 관한 것이다.The present invention relates to a pyrolysis device of a flammable material present in the solid phase, and more particularly, to induce heat decomposition of a flammable material in a solid state indirectly under a high temperature, anoxic or low oxygen atmosphere to reduce the emission of pollutants and improve the yield. The present invention relates to a pyrolysis apparatus for combustible materials in a solid state.
일반적으로, 산업 발전으로 인한 공장 증가로 에너지의 사용이 급증하고 에너지를 재활용 또는 재이용하여 에너지의 형태를 변환시키는 기술이 발전하고 있다. 그리고 사용처의 요구에 따라 자연에 존재하는 초기의 에너지 자원들(예를 들면, 가연성물질인 원유, 석탄, 목재 등)이 개발되고 있으며, 비가연성 물질인 광물에서 무기물질이 가공되어 일상생활 및 산업활동에 사용되어지고 있다.In general, the use of energy is rapidly increasing due to the increase of factories due to industrial development, and technology for converting the form of energy by recycling or reusing energy is being developed. In accordance with the requirements of the user, the initial energy resources in nature (for example, combustible crude oil, coal, wood, etc.) are being developed, and inorganic materials are processed from minerals which are not combustible materials. It is used in activities.
이 중에서 가연성 물질은 그 고유의 에너지값을 가지는데 이는 물질의 원소조성(탄소, 수소, 산소, 질소, 황, 인, 염소 등)에 따라서 발열량이 다르기 때문이다. 우리 주변에서 사용하다가 버리면 폐기물이라고 하는데 이를 에너지의 관점에서 보면 변한 것이 전혀 없는 것이다.Among them, the combustible material has its own energy value because the calorific value varies depending on the element composition of the material (carbon, hydrogen, oxygen, nitrogen, sulfur, phosphorus, chlorine, etc.). If we use it around us and throw it away, it is called waste.
산업화의 진행에 따라서 사용하고 버려진 각종 금속파편, 플라스틱, 종이, 산업폐기물의 찌꺼기 등이 대폭적으로 증가하고 있는데, 이 중에서 가연성 물질들은 대부분이 소각장치를 이용하여 연소시키기 때문에 환경오염으로 인한 사회문제로 대두되고 있다. 그러나 이와 같이 가연성 물질들을 소각처리하는 방식은 전 세계적으로 CO2를 절감하고자 하는 정책에 거스르고 있는 현실이다.With the progress of industrialization, various kinds of metal debris, plastics, paper, and industrial wastes, which are used and discarded, have increased dramatically. Among them, combustible materials are burned by incinerator, which is a social problem due to environmental pollution. It is becoming. However, this method of incineration of combustible materials is a reality against the policy of reducing CO2 around the world.
또한, 가연성 물질들을 소각하는데에 소요되는 처리비용 및 공간의 한계에 직면하게 되므로, 폐기물의 대부분은 매립(埋立) 또는 불법처리하는 방식을 채택하고 있는 실정이다. 또한, 화석연료인 석탄 등은 직접 연소를 함으로써 일산화탄소, 이산화탄소, 아황산가스 등 인체에 해로운 물질을 다량 방출하고 있는 실정이다. 이와 같이 고상의 가연성 물질의 소각과 매립시 발생하는 공해배출 물질과 침출수 등으로 인해 대기와 토질 및 지하수가 심각하게 오염되는 문제점을 갖게 된다.In addition, since the processing costs and space limitations required for incineration of flammable materials are faced, most of the wastes are landfilled or illegally disposed. In addition, coal, which is a fossil fuel, emits a large amount of harmful substances such as carbon monoxide, carbon dioxide, and sulfurous acid gas by directly burning. As such, there is a problem that air, soil, and groundwater are seriously polluted due to pollution emission material and leachate generated during incineration and landfill of solid combustible materials.
이러한 고상의 가연성 물질을 처리하기 위해서 열분해장치가 적용되었는데, 종래에 사용되는 열분해장치는 배치(batch) 식으로 일정한 분량의 폐기물을 열분해실 내부에 투입시킨 후, 뚜껑을 닫아 외부로부터 고온의 열을 가하여 열분해실을 소정 온도로 가열함에 따라, 폐기물을 열분해시켜 액체, 기체 및 고체상태의 물질로 변환시키는 회분식의 방법을 채택하고 있다.A pyrolysis device is applied to treat such solid combustible materials. In the conventional pyrolysis device, a predetermined amount of waste is introduced into a pyrolysis chamber in a batch manner, and a lid is closed to remove high temperature heat from the outside. When the pyrolysis chamber is heated to a predetermined temperature, a batch method is adopted in which the waste is pyrolyzed and converted into liquid, gas and solid materials.
그런데, 배치 타입의 열분해 방식은 여러 가지 물질이 혼합되는 폐기물의 열분해에 많은 어려움이 뒤따르고, 특히 이물질(초자류, 흙, 철·비철금속류 등)이 혼합되는 경우 열전달이 원활하게 이루어지지 않게 되어 대용량의 열분해가 이루어지지 못하고 있다. 또한 혼합된 가연성 물질과 비가연성 물질에서 열분해가스와 정제유를 생산하는데 한계를 갖게 되어 그 사용가치가 떨어지는 문제점을 갖게 된다.However, the batch type pyrolysis method has a lot of difficulties in pyrolysis of wastes in which various substances are mixed, and especially when foreign substances (such as grass, soil, ferrous and nonferrous metals) are mixed, heat transfer is not performed smoothly. Large scale pyrolysis is not achieved. In addition, there is a limit to the production of pyrolysis gas and refined oil in the mixed combustible and non-combustible material has a problem that the use value is lowered.
본 발명은 상기한 바와 같은 문제점을 해결하기 위한 것으로, 고상의 가연성 물질을 고온, 무산소 또는 저산소 분위기에서 간접적으로 열을 가하여 열분해하는 경우, 적은 공간에서 많은 양의 고상의 가연성 물질을 처리할 수 있는 열분해장치를 제공하는 것을 목적으로 한다.The present invention is to solve the problems as described above, in the case of pyrolyzing a solid combustible material in a high temperature, oxygen-free or low oxygen atmosphere by indirect heat, it is possible to process a large amount of solid combustible material in a small space It is an object to provide a pyrolysis device.
그리고 열분해된 후 발생하는 열분해가스에 포함되어 있는 염소, 황 등의 이물질을 충분히 제거하여 열분해 이후 추출되는 기름이나 가스의 순도를 높일 수 있는 열분해장치를 제공하는 것을 또 다른 목적으로 한다.Another object of the present invention is to provide a pyrolysis apparatus capable of sufficiently removing foreign substances such as chlorine and sulfur contained in pyrolysis gas generated after pyrolysis to increase the purity of oil or gas extracted after pyrolysis.
본 발명은 상기한 바와 같은 문제점을 해결하기 위한 것으로, 고상 가연성 물질이 투입되는 메인호퍼를 구비하여, 투입된 가연성 물질을 이송, 용융 및 기화시키는 열분해스크류(220)가 구비되고, 가연성 물질의 이송방향을 따라 제1몸체(211)와 제2몸체(213), 그리고 제3몸체(215)가 단차지게 확장 형성되며, 상기 제2몸체(213)는 회전가능하도록 구비되어 상기 열분해 스크류와의 회전속도 차이에 의해 가연성 물질을 이송시키는 열분해기몸체(210); 상기 열분해기몸체(210)의 외측에 설치되어 고온 및 저산소 상태의 분위기를 유지하여 가연성 물질을 간접 가열에 의해 연속적으로 열분해시키는 열분해실(240); 그리고 상기 열분해실(240)의 일측에 마련되며, 열분해기몸체(210)로 이송되는 가연성 물질을 열분해시키는 열원으로서 이용하도록 가연성 물질의 열분해시 발생되는 열분해가스 중 비응축가스를 연소시켜 상기 열분해실(240)에 열을 공급하는 연소실(250)을 포함하는 것을 기술적 특징으로 한다.The present invention is to solve the problems as described above, having a main hopper to which the solid combustible material is injected, the pyrolysis screw 220 for transporting, melting and vaporizing the injected combustible material is provided, the transport direction of the combustible material The first body 211, the second body 213, and the third body 215 is formed to be stepwise extended along the second body 213, the second body 213 is provided to be rotatable rotational speed with the pyrolysis screw A pyrolyzer body 210 for transporting the combustible material by the difference; A pyrolysis chamber 240 installed outside the pyrolyzer body 210 to continuously decompose the combustible material by indirect heating by maintaining an atmosphere of high temperature and low oxygen state; In addition, the pyrolysis chamber is provided on one side of the pyrolysis chamber 240 to burn the non-condensing gas of pyrolysis gas generated during pyrolysis of the combustible material so as to be used as a heat source for pyrolyzing the combustible material transferred to the pyrolyzer body 210. Technical features include a combustion chamber 250 that supplies heat to 240.
그리고 상기 제1몸체(211)와 제2몸체(213), 상기 제2몸체(213)와 제3몸체(215)의 사이에는 각각 실링유닛이 구비되는 것이 바람직하다.In addition, a sealing unit may be provided between the first body 211 and the second body 213, and between the second body 213 and the third body 215, respectively.
그리고 상기 제3몸체(215)의 입구부는 상기 열분해 스크류와 간극이 형성되지 않도록 원형으로 형성되고, 상기 제3몸체(215)의 중간부는 상기 열분해 스크류와 소정 공간이 형성될 수 있도록 유선형으로 형성되며, 상기 제3몸체(215)의 후단부는 상기 열분해 스크류와 간극이 형성되지 않도록 원형으로 형성되는 것이 바람직하다.And the inlet portion of the third body 215 is formed in a circular shape so that no gap is formed with the pyrolysis screw, the middle portion of the third body 215 is formed in a streamline so that a predetermined space is formed with the pyrolysis screw. The rear end of the third body 215 may be formed in a circular shape such that a gap is not formed with the pyrolysis screw.
그리고 상기 상기 제2몸체(213)와 제3몸체(215) 구간에 구비되는 열분해스크류의 스크류날개에는 배출홀(223)이 형성되는 것이 바람직하다.And it is preferable that the discharge hole 223 is formed in the screw blades of the pyrolysis screw provided in the second body 213 and the third body 215 section.
그리고 상기 열분해 몸체의 제3몸체(215)부의 중간부 상측에는 가연성 물질의 열분해시 발생하는 열분해가스를 소정시간 체류시키는 가스체류탑(510)이 구비되는 것이 바람직하다.In addition, the gas retention tower 510 may be provided above the middle portion of the third body 215 of the pyrolysis body to retain the pyrolysis gas generated during pyrolysis of the combustible material for a predetermined time.
그리고 상기 가스체류탑(510)의 내부에는, 상기 가스 체류탑의 내벽에 부착된 타르, 탄화재를 분리시키는 나선스크류(520)가 구비되는 것이 바람직하다.In addition, it is preferable that a spiral screw 520 is provided inside the gas retention tower 510 to separate tar and carbonized material attached to the inner wall of the gas retention tower.
그리고 상기 가스 체류탑의 일측에는 열분해가스 중 염소를 제거하기 위한 탈염장치가 구비되는 것이 바람직하다.And one side of the gas retention tower is preferably provided with a desalination device for removing chlorine in the pyrolysis gas.
그리고 상기 탈염장치로부터 염소가 제거된 열분해가스를 정제하기 위한 가스정제수단(700)을 더 포함하는 것이 바람직하다.And it is preferable to further include a gas purification means 700 for purifying the pyrolysis gas from which chlorine is removed from the desalination apparatus.
그리고 상기 탈염소 반응탑으로부터 염소가 제거된 열분해가스를 침강 응축시킨 후 증류탑에서 비등점에 따라 휘발유, 경유 및 중유를 생성하는 정제유생성수단(800)을 더 포함하는 것이 바람직하다.Further, it is preferable to further include refined oil producing means 800 for generating gasoline, light oil and heavy oil according to boiling points in the distillation column after sedimentation and condensation of pyrolysis gas from which chlorine is removed from the dechlorination reaction tower.
그리고 상기 열분해실(240)로부터 열분해된 후 생성되는 탄화재를 연속적으로 배출시키는 탄화재 배출수단을 더 포함하는 것이 바람직하다.And it is preferable to further include a carbonized material discharge means for continuously discharging the carbonized material generated after pyrolysis from the pyrolysis chamber 240.
상기한 바와 같은 본 발명에 의하면, 열분해기몸체의 일부를 열분해스크류와 같이 회전시키도록 하여 열분해시의 열제공면적을 최대화 함으로써 적은 공간에서 많은 양의 고상의 가연성 물질을 열분해할 수 있는 효과를 가진다.According to the present invention as described above, it is possible to thermally decompose a large amount of solid combustible material in a small space by maximizing the heat providing area during pyrolysis by rotating a portion of the pyrolyzer body together with the pyrolysis screw. .
그리고 탈염제거장치를 2중으로 구비함으로써 열분해가스 내의 염소제거량을 최소화할 수 있어, 가연성 물질의 열분해 이후 추출되는 기름이나 가스의 순도를 높일 수 있는 효과를 가진다.In addition, since the desalination removal apparatus is provided in duplicate, the amount of chlorine removal in the pyrolysis gas can be minimized, thereby increasing the purity of oil or gas extracted after pyrolysis of the combustible material.
본 명세서에 첨부되는 다음의 도면들은 본 발명의 바람직한 일실시예를 예시하는 것이며, 발명의 상세한 설명과 함께 본 발명의 기술적 사상을 더욱 이해시키는 역할을 하는 것이므로, 본 발명은 그러한 도면에 기재된 사항에만 한정되어 해석 되어서는 아니 된다.The following drawings, which are attached to this specification, illustrate one preferred embodiment of the present invention, and together with the detailed description thereof, serve to further understand the technical spirit of the present invention. It should not be construed as limited.
도 1은 본 발명의 일 실시예에 의한 고상 가연성 물질의 열분해 장치의 구성을 도시한 구성도,1 is a block diagram showing the configuration of a pyrolysis apparatus for a solid combustible material according to an embodiment of the present invention,
도 2는 도 1의 "X", "Y" 표시부를 보인 부분 사시도,Figure 2 is a partial perspective view showing the "X", "Y" display portion of FIG.
도 3은 도 1의 "A-A", "B-B", "C-C", "D-D", "E-E", "F-F", "G-G"선을 보인 단면도,3 is a cross-sectional view showing lines "A-A", "B-B", "C-C", "D-D", "E-E", "F-F", and "G-G" of FIG.
도 4는 도 1의 "Z" 표시부를 도시한 부분 확대도,4 is a partially enlarged view illustrating a display portion “Z” of FIG. 1;
도 5는 도 1의 "W" 표시부를 도시한 부분 확대도,FIG. 5 is a partially enlarged view showing a “W” display unit of FIG. 1;
도 6은 본 발명의 일 실시예에 의한 정제유 생성 과정을 개략적으로 보인 블럭도.Figure 6 is a schematic block diagram showing a refined oil production process according to an embodiment of the present invention.
* 도면의 주요 부분에 대한 부호의 설명 *Explanation of symbols on the main parts of the drawings
210:열분해기몸체210: pyrolyzer body
211:제1몸체211: first body
213:제2몸체213: second body
215:제3몸체215: Third body
400:자동투입장치400: automatic feeding device
510:가스체류탑510: gas retention tower
610:배출호퍼610: discharge hopper
700:가스정제수단700: gas purification means
800:정제유 생성수단800: refining oil generating means
이하, 도면을 참조하여 본 발명의 바람직한 일 실시예에 대해서 설명한다. 또한, 이하에 설명하는 일 실시예는 특허청구범위에 기재된 본 발명의 내용을 부당하게 한정하지 않으며, 본 실시 형태에서 설명되는 구성 전체가 본 발명의 해결 수단으로서 필수적이라고는 할 수 없다.Hereinafter, with reference to the drawings will be described a preferred embodiment of the present invention. In addition, one Example described below does not unduly limit the content of this invention described in the Claim, and the whole structure described in this Embodiment is not necessarily required as a solution of this invention.
도 1에는 본 발명의 일 실시예에 의한 고상 가연성 물질의 열분해 장치의 구성을 개략적으로 도시한 구성도가 도시되어 있다.1 is a block diagram schematically showing the configuration of a pyrolysis apparatus for a solid combustible material according to an embodiment of the present invention.
도면에 도시된 바와 같이, 본 발명의 일 실시예에 의한 고상 가연성 물질의 열분해 장치는, 분쇄된 가연성 물질을 가열하여 열분해하는 열분해수단, 가연성 물질의 열분해시 생성된 열분해가스로부터 염소를 제거하는 가스 개질수단, 개질된 가스를 이용하여 정제유를 생성하는 정제유생성수단 및 열분해수단으로부터 열분해된 후 배출되는 탄화재(char)를 연속적으로 배출시키는 탄화재 배출수단을 포함하여 구성된다.As shown in the drawings, the pyrolysis apparatus for a solid combustible material according to an embodiment of the present invention, a pyrolysis means for heating and thermally decomposing the combustible combustible material, a gas for removing chlorine from the pyrolysis gas generated during pyrolysis of the combustible material And reforming means, refining oil producing means for producing refined oil using the reformed gas, and carbonaceous material discharge means for continuously discharging carbonized material (char) discharged after pyrolysis from the pyrolysis means.
이와 같이 구성된 본 실시예의 열분해시스템에서 사용되는 열분해 원리는 고상 가연성 물질을 무산소 또는 저산소 분위기 하에서 간접적으로 열을 가하면 열분해공간은 환원성 분위기가 조성되고, 가연성 물질은 분해되어 기체, 액체로 증발되며, 분해되지 않는 것은 고체(char)로 남게 된다.The pyrolysis principle used in the pyrolysis system of the present embodiment configured as described above is that when a solid combustible material is indirectly heated in an oxygen-free or low oxygen atmosphere, the pyrolysis space is formed in a reducing atmosphere, and the combustible material is decomposed to evaporate into a gas or a liquid. What does not remain solid.
즉, 가연성 물질(가연성 고분자화합물을 의미함) + 열 = 기체(비응축가스) + 액체(정제유) + 고체(char)임을 알 수 있다.That is, it can be seen that the combustible material (meaning a flammable polymer compound) + heat = gas (non-condensing gas) + liquid (refined oil) + solid (char).
먼저, 도 1 및 도 2를 참조하여, 상기 열분해 수단의 구성에 대해 설명하도록 한다. 상기 열분해 수단은 고온 및 저산소 상태의 분위기를 유지하여 가연성 물질을 간접 가열에 의해 연속적으로 열분해하도록 열분해기몸체(210)를 포함하여 구성된다. First, referring to Figures 1 and 2, the configuration of the thermal decomposition means will be described. The pyrolysis means comprises a pyrolyzer body 210 to maintain a high temperature and low oxygen atmosphere to continuously pyroly decompose combustible materials by indirect heating.
상기 열분해기몸체(210)의 일측에는 분쇄된 고상 가연성 물질의 투입을 위한 메인호퍼가 구비된다. 상기 메인호퍼를 통해 투입되는 분쇄된 가연성 물질은 열분해기몸체(210)로 이동하여 열분해가 이루어진다.One side of the pyrolyzer body 210 is provided with a main hopper for the input of the pulverized solid combustible material. The combustible combustible material introduced through the main hopper is moved to the pyrolyzer body 210 to pyrolyze.
상기 메인호퍼에는 분쇄된 가연성 물질의 양을 항상 일정하게 메인호퍼에 저장할 수 있도록 감지센서가 구비된다. 상기 감지센서는 고상 가연성 물질의 투입컨베이어(도시되지 않음)의 이송투입량을 자동 조절하여 항상 설정치 이하로 고상 가연성 물질이 내려가지 않도록 한다.The main hopper is provided with a sensor so that the amount of combustible combustible material is always stored in the main hopper constantly. The detection sensor automatically adjusts the feeding amount of an input conveyor (not shown) of the solid combustible material so that the solid combustible material does not always fall below the set value.
상기 열분해기몸체(210)의 내부에는 자동투입장치(400)를 통해 투입되는 가연성 물질을 이송 및 열분해시키는 열분해스크류(220)가 구동모터(260)에 의해 회전 가능하게 설치된다.Inside the pyrolyzer body 210, a pyrolysis screw 220 for transporting and pyrolyzing the combustible material introduced through the automatic input device 400 is rotatably installed by the drive motor 260.
상기 열분해스크류는 구동모터(230)와 연결되는 구동축(220)과, 상기 구동축(220)의 외측에 형성되는 스크류날개(221)를 포함하여 구성된다. 상기 열분해스크류는 구동모터(230)로부터 동력을 전달받아 회전하게 된다.The pyrolysis screw is configured to include a drive shaft 220 connected to the drive motor 230, and a screw blade 221 formed on the outside of the drive shaft 220. The pyrolysis screw is rotated by receiving power from the driving motor 230.
상기 열분해기몸체(210)의 외측에는 고온(350∼500℃) 및 저산소 상태의 분위기를 유지하여 가연성 물질을 간접가열에 의해 연속적으로 열분해시키는 단열재로 이루어진 열분해실(240)이 마련된다.Outside the pyrolyzer body 210 is provided with a pyrolysis chamber 240 made of a heat insulating material to continuously decompose the combustible material by indirect heating by maintaining a high temperature (350 ~ 500 ℃) and low oxygen atmosphere.
한편, 가연성 물질의 열분해시 발생하는 열분해가스 중 탄소고리가 적은 응축이 되지 않은 가벼운 가스로서 C2H6, C3H8, C5H12(에탄가스, 프로판가스, 부탄가스)가 주종을 이루는데, 상기 열분해실(240)의 하측에는 이를 연소시켜 이송되는 가연성 물질을 열분해시키는 열원으로 이용하도록, 도 3b에 도시된 바와 같이, 열분해실(240)에 고온의 열을 공급하는 연소실(250)이 구비되고, 상기 연소실(250)에는 버너(251)가 구비되어 있다.On the other hand, among the pyrolysis gases generated during pyrolysis of combustible materials, C 2 H 6 , C 3 H 8 , C 5 H 12 (ethane gas, propane gas, butane gas) dominate the main species as light gases with little carbon ring condensation. At the lower side of the pyrolysis chamber 240, a combustion chamber 250 for supplying high temperature heat to the pyrolysis chamber 240, as shown in FIG. 3B, is used as a heat source for pyrolyzing the combustible material transported by burning it. ) And a burner 251 is provided in the combustion chamber 250.
다시 도 1을 참조하면, 상기 열분해기몸체(210)는 가연성 물질의 진행 순서에 따라 제1몸체(211)와, 제2몸체(213), 그리고 제3몸체(215)로 구분되며, 각각의 몸체는 단계적으로 내경이 확대되도록 단차 형성되어 3단계의 과정을 거치면서 열분해 공정을 수행한다. 이때, 상기 제1몸체(211)와 제3몸체(215)는 고정되어 설치되고, 상기 제2몸체(213)는 회전가능하도록 설치된다.Referring back to FIG. 1, the pyrolyzer body 210 is divided into a first body 211, a second body 213, and a third body 215 in the order of progress of the combustible material. The body is stepped to enlarge the inner diameter step by step to perform the pyrolysis process while going through a three-step process. At this time, the first body 211 and the third body 215 is fixed and installed, the second body 213 is installed to be rotatable.
상기 제1몸체(211) 구간에서는 상기 건조수단으로부터 유입된 가연성 물질이 열분해스크류(220)의 회전에 의해 상기 제2몸체(213)로 이송시키는 부분이고, 상기 제2몸체(213) 구간에서는 열분해스크류(220)와 제2몸체(213)와의 회전속도의 차이로 가연성 물질이 이동하면서 예열, 승온, 기화의 열분해가 실질적으로 이루어지는 부분이다. 그리고 제3몸체(215) 구간에서는 열분해가 이루어진 잔재를 배출시키고, 열분해가스를 제2열분해실로 이송시키는 역할을 수행한다.In the section of the first body 211, the combustible material introduced from the drying means is transferred to the second body 213 by the rotation of the pyrolysis screw 220, and in the section of the second body 213, pyrolysis. Due to the difference in the rotational speed between the screw 220 and the second body 213, the combustible material is moved, and the portion of which thermal decomposition of the preheating, raising the temperature, and vaporizing is substantially performed. In the third body 215 section, the residue which is pyrolyzed is discharged, and the pyrolysis gas is transferred to the second pyrolysis chamber.
구체적으로, 상기 각각의 열분해기몸체(210)의 구성에 대해 설명하도록 한다.Specifically, the configuration of each of the pyrolyzer body 210 will be described.
먼저, 상기 제1몸체(211)는 고정되도록 설치되고, 상기 열분해스크류(220)가 회전하면서 상기 건조수단으로부터 유입된 가연성 물질이 상기 제2몸체(213)로 이동하게 된다.First, the first body 211 is installed to be fixed, the combustible material introduced from the drying means is moved to the second body 213 while the thermal decomposition screw 220 is rotated.
이때, 상기 제1몸체(211)의 후단과 제2몸체(213)의 전단 사이에는 제1실링유닛(212)이 구비된다. 상기 제1실링유닛(212)은 후술할 제2실링(216)과 동일한 구성으로, 도 5에 도시된 구성과 동일하다.At this time, a first sealing unit 212 is provided between the rear end of the first body 211 and the front end of the second body 213. The first sealing unit 212 has the same configuration as the second sealing 216, which will be described later, is the same as the configuration shown in FIG.
구체적으로, 상기 제1실링유닛(212)은 제2몸체의 전단에 형성되는 제1플랜지부에 결합하는 제1부싱과, 상기 제1부싱의 전단에 결합하는 제2부싱을 포함하여 구성된다. 상기 제1부싱과 제2부싱의 내주에는 각각 패킹이 구비되어, 상기 제1몸체와 제2몸체와의 사이를 이중으로 밀봉하게 된다.Specifically, the first sealing unit 212 includes a first bushing coupled to the first flange portion formed at the front end of the second body, and a second bushing coupled to the front end of the first bushing. Packings are provided on the inner circumferences of the first bushing and the second bushing, respectively, to double seal between the first body and the second body.
상기 제1실링유닛(212)에 의해 상기 제1몸체(211)와 제2몸체(213)와의 사이에 형성된 단차 사이로 가연성 물질이 누설되지 않고, 제1몸체(211)에서 제2몸체(213)로 가연성 물질의 유입이 자연스럽게 이루어진다. 이에 따라 제1몸체(211)에서 제2몸체(213)로 이동하는 가연성 물질의 열분해가 자연스럽게 이루어진다. 또한, 상기 제1실링유닛(212)으로 인해 제1몸체(211)와 제2몸체(213)와의 회전에 의해 발생하는 마찰을 최소화하고, 상기 제1몸체(211)와 제2몸체(213)가 정확한 수평이 유지될 수 있으며, 상기 제2몸체(213)에서 제1몸체(211)로 가연성 물질이 역류하는 것을 방지한다.The first sealing unit 212 does not leak the combustible material between the step formed between the first body 211 and the second body 213, the second body 213 in the first body 211 As a result, the influx of flammable substances occurs naturally. Accordingly, pyrolysis of the combustible material moving from the first body 211 to the second body 213 is naturally performed. In addition, due to the first sealing unit 212, the friction generated by the rotation of the first body 211 and the second body 213 is minimized, and the first body 211 and the second body 213 The exact level can be maintained, and prevent the back flow of the combustible material from the second body 213 to the first body 211.
다음으로, 상기 제2몸체(213)의 일측에는 회전모터(260)가 구비되어 있어, 상기 제2몸체(213)가 회전가능하도록 설치된다. 이때, 상기 제2몸체(213)는 타이어(213c)에 의해 지지되어 상기 제2몸체(213)가 안정적으로 회전된다.Next, a rotation motor 260 is provided at one side of the second body 213 so that the second body 213 is rotatable. At this time, the second body 213 is supported by the tire 213c so that the second body 213 is stably rotated.
구체적으로, 상기 회전모터(260)의 구동력을 전달하기 위해 벨트(261, 262)를 통해 구동기어(264)로 동력을 전달한다. 상기 제2몸체(213)의 외주에는 피동기어(213b)가 형성되어 있어, 상기 구동기어(264)와 피동기어(213b)가 서로 치합되어 상기 회전모터(260)에서 발생한 구동력이 상기 제2몸체(213)으로 전달되어 상기 제2몸체(213)가 회전하게 된다.Specifically, power is transmitted to the drive gear 264 through the belts 261 and 262 to transmit the driving force of the rotary motor 260. A driven gear 213b is formed on an outer circumference of the second body 213, and the driving gear 264 and the driven gear 213b are engaged with each other so that the driving force generated in the rotary motor 260 is the second body. The second body 213 is rotated by being transferred to 213.
그리고 상기 제2몸체(213)의 외주면에는 적어도 하나의 타이어(213c)이 구비되어 있다. 상기 타이어(213c)은 지지롤러(266)에 의해 지지되어 상기 제2몸체(213)가 안정적으로 회전할 수 있게 된다.At least one tire 213c is provided on an outer circumferential surface of the second body 213. The tire 213c is supported by the support roller 266 so that the second body 213 can stably rotate.
이때, 상기 제2몸체(213)와 상기 건조스크류에 비해 상대적으로 느린 속도로 회전하게 되는데, 상기 제2몸체(213)의 내부에 구비된 열분해스크류(220)의 회전속도와의 차이에 의해 가연성 물질이 제1몸체(211) 내부에서와 비교하여 점진적으로 이동하게 된다. 따라서 상기 제2몸체(213)가 고정되어 있을 때보다, 적어도 3배 이상의 많은 열전달 면적을 제공할 수 있게 되어, 적은 공간에서 더 많은 가연성 물질의 열분해가 이루어질 수 있게 된다.At this time, the second body 213 and the drying screw is rotated at a relatively slow speed, the flammability by the difference between the rotational speed of the pyrolysis screw 220 provided in the second body 213 The material is gradually moved compared to the inside of the first body 211. Therefore, it is possible to provide at least three times more heat transfer area than when the second body 213 is fixed, so that more decomposition of the combustible material can be performed in a smaller space.
상기 제2몸체(213) 구간에서 가연성 물질이 이동하면서 가연성 물질은 물질의 형태가 고체에서 액체로, 액체에서 기체상의 물질로 완전 기화를 하게 되고(때로는 고체상태에서 기체상태로 바로 승화됨), 고유의 물성을 잃은 가연성 물질의 잔재는 카본 형태로 제3몸체(215) 구간으로 이동하게 된다.As the combustible material moves in the section of the second body 213, the combustible material completely vaporizes from solid to liquid, liquid to gaseous material (sometimes, directly sublimates from solid state to gaseous state), Residue of the combustible material which lost its intrinsic properties is moved to the third body 215 section in the form of carbon.
그리고 상기 제2몸체(213)의 후단과 제3몸체(215)의 전단의 사이에는 제2실링유닛(216)이 구비된다. 상기 제2실링유닛(216)은 제3몸체(215)의 전단에 형성되는 제2플랜지부(215')에 결합하는 제1부싱(217)과, 상기 제1부싱(217)의 전단에 결합하는 제2부싱(218)을 포함하여 구성된다. 상기 제1부싱(217)과 제2부싱(218)의 내주에는 각각 패킹(217a,218a)이 구비되어, 상기 제2몸체(213)와 제3몸체(215)와의 사이를 이중으로 밀봉하게 된다.The second sealing unit 216 is provided between the rear end of the second body 213 and the front end of the third body 215. The second sealing unit 216 is coupled to the first bushing 217 coupled to the second flange portion 215 ′ formed at the front end of the third body 215, and to the front end of the first bushing 217. The second bushing 218 is configured to include. Inner circumferences of the first bushing 217 and the second bushing 218 are provided with packings 217a and 218a, respectively, to double seal between the second body 213 and the third body 215. .
상기 제2실링유닛(216)에 의해 상기 제2몸체(213)와 제3몸체(215)와의 회전에 의한 마찰을 최소화하고, 상기 제2몸체(213)와 제3몸체(215)가 정확한 수평이 유지될 수 있게 된다.The second sealing unit 216 minimizes friction caused by the rotation of the second body 213 and the third body 215, and the second body 213 and the third body 215 are precisely horizontal This can be maintained.
상기 제3몸체(215)는 고정 설치되는데, 상기 제3몸체(215)의 전단부(215a)는 상기 제2몸체(213)와의 연결을 위해 상기 열분해스크류(220)의 스크류날개(221)와 대응되도록 원형으로 형성되고(도 3c 참조), 상기 제3몸체(215)의 중간부(215b)는 스크류날개(221)의 윗부분에 공간이 형성되도록 유선형의 구조로 형성된다(도 3d 참조). 상기 스크류날개의 윗 공간에는 열분해시에 발생한 열분해가스를 일시적으로 체류시키고, 후술할 가스체류탑(510)으로 열분해가스가 원활하게 이동될 수 있게 한다.The third body 215 is fixedly installed, the front end portion 215a of the third body 215 and the screw blade 221 of the pyrolysis screw 220 for connection with the second body 213. Correspondingly formed in a circular shape (see Figure 3c), the middle portion 215b of the third body 215 is formed in a streamlined structure so that a space is formed on the upper portion of the screw blade 221 (see Figure 3d). The pyrolysis gas generated at the time of pyrolysis temporarily stays in the space above the screw blades, and the pyrolysis gas can be smoothly moved to the gas retention tower 510 which will be described later.
그리고 상기 제3몸체(215)의 후단부(215c)는 열분해가 모두 진행된 재를 배출하기 위한 구간으로 스크류날개의 외경과 대응되도록 원형으로 형성되어 스크류날개와 제3몸체(215)와의 간극을 최소화 시킨다(도 3e 참조). 이에 따라 열분해 이후 발생하는 비산재가 가스체류탑(510)으로 이동하는 것을 방지한다.In addition, the rear end portion 215c of the third body 215 is a section for discharging ash which has undergone all thermal decomposition, and is formed in a circular shape so as to correspond to the outer diameter of the screw blade to minimize the gap between the screw blade and the third body 215. (See FIG. 3E). Accordingly, fly ash generated after pyrolysis is prevented from moving to the gas retention tower 510.
한편, 상기 제2몸체(213)와 제3몸체(215) 구간에서의 스크류날개에는 배출홀(223)이 형성되어 있다. 상기 스크류날개에 배출홀(223)이 형성되어 있음으로써, 열분해과정에서 발생하는 열분해가스가 자연스럽게 가스체류탑(510)으로 이동할 수 있고, 가연성 물질의 교반이 원활하게 이루어져 열분해 효율이 향상된다.On the other hand, the discharge hole 223 is formed in the screw blade in the section of the second body 213 and the third body 215. Since the discharge hole 223 is formed in the screw blade, the pyrolysis gas generated in the pyrolysis process may naturally move to the gas retention tower 510, and the stirring of the flammable material may be performed smoothly, thereby improving the pyrolysis efficiency.
그리고 상기 열분해기몸체(210)의 일측에는 질소투입장치(도시는 생략)가 구비된다. 상기 열분해기의 작동시 사용상의 부주의 또는 장비의 오동작 등으로 인해 화재가 발생하는 경우, 상기 질소투입장치에서 열분해기몸체(210)로 질소를 투입함으로써 화재를 진압할 수 있게 된다.And one side of the pyrolyzer body 210 is provided with a nitrogen input device (not shown). When a fire occurs due to inadvertent use or malfunction of equipment during operation of the pyrolyzer, it is possible to extinguish the fire by injecting nitrogen into the pyrolyzer body 210 from the nitrogen input device.
상기 열분해기몸체(210)에서 열분해가 완전히 이루어진 재의 배출은 연속적으로 이루어지며, 상기 제3몸체(215)의 일측에 구비된 슬라이드 게이트 또는 로타리 밸브와 같은 밸브체(620)를 통해 재의 배출시 외부의 공기가 열분해기몸체(210)로 유입되는 것을 차단할 수 있다.When the pyrolysis is completely discharged from the pyrolyzer body 210 is discharged continuously, when the ash is discharged through the valve body 620 such as a slide gate or a rotary valve provided on one side of the third body 215 The air can be blocked from entering the pyrolyzer body 210.
다음으로는, 상기 가스 개질수단은 열분해기몸체(210)의 출구 측에 수직으로 연결되는 가스체류탑(510)과 개질된 가스로부터 염소를 제거하는 제1탈염장치(550) 및 제2탈염장치(560)를 포함하여 구성된다.Next, the gas reforming means is a gas detention tower 510 connected to the outlet side of the pyrolyzer body 210 and a first desalination apparatus 550 and a second desalination apparatus for removing chlorine from the reformed gas. And 560.
상기 가스체류탑(510)의 내부에는 연소실(250)에서 공급된 열원이 열분해기몸체(210) 내의 가연성 물질을 가열한 후 배출되는 과정에서 열원의 체류시간을 충분히 확보할 수 있도록 나선스크류(520)가 구비된다. 상기 나선스크류(520)를 따라 가스가 나선형으로 회전하면서 배출되어 상기 가스 체류탑 내에서 가스가 체류되는 시간을 확보할 수 있게 된다. 상기 나선스크류(520)의 상단에는 구동모터(530)가 결합되어 상기 나선스크류(520)를 소정 속도로 회전시키기 위한 구동력을 제공한다.The spiral screw 520 is provided inside the gas retention tower 510 to sufficiently secure the residence time of the heat source in the process of being discharged after heating the combustible material in the pyrolyzer body 210 by the heat source supplied from the combustion chamber 250. ) Is provided. The gas is discharged while rotating spirally along the spiral screw 520 to secure a time for the gas to stay in the gas retention tower. A driving motor 530 is coupled to an upper end of the spiral screw 520 to provide a driving force for rotating the spiral screw 520 at a predetermined speed.
상기 열분해기몸체(210)의 내부에서 발생한 열분해가스는 상기 가스체류탑(510)의 내부 공간에서 빠른 속도로 분자결합이 이루어져 탄소쇄의 고리가 긴 분자량이 많은 물질부터 검출이 시작된다.The pyrolysis gas generated inside the pyrolyzer body 210 is molecularly bonded at a high speed in the inner space of the gas retention tower 510, and detection starts from a substance having a large molecular weight having a long chain of carbon chains.
탄소쇄가 24개 이상인 물질로 구성된 왁스나 타르 성분이 주로 검출되는데 상기 가스체류탑(510)의 내부공간에서 탈타르 및 탈왁스 공정이 진행된다. 이때, 상기 구동모터(530)에 의해 회전하는 나선스크류(520)의 스크류날개는 상기 가스체류납의 내경에 대응되는 외경을 갖도록 구성되어 상기 가스체류탑(510)의 내주면에 부착되는 타르 또는 탄화재를 긁어 가스체류탑(510)의 내주면으로부터 분리시키는 역할을 하게 된다.A wax or tar component mainly composed of 24 or more carbon chains is detected. The tar and dewaxing processes are performed in the inner space of the gas retention tower 510. At this time, the screw blade of the spiral screw 520 rotated by the drive motor 530 is configured to have an outer diameter corresponding to the inner diameter of the gas retention lead is tar or carbonized material attached to the inner peripheral surface of the gas retention tower 510 By scraping the role of separating from the inner circumferential surface of the gas retention tower 510.
상기 가스체류탑(510)의 외측에는 상기 열분해실(240)과 연결통로를 통해 연통되는 열원공급실(540)이 구비된다. 상기 열원공급실(540)이 마련되어 있음으로써, 상기 가스체류탑(510)을 통해 상승하는 열분해가스가 응축되지 않도록 온도를 보정할 수 있다.The heat source supply chamber 540 is provided on the outside of the gas retention tower 510 to communicate with the pyrolysis chamber 240 through a connection passage. Since the heat source supply chamber 540 is provided, the temperature may be corrected so that the pyrolysis gas rising through the gas retention tower 510 does not condense.
즉, 상기 열분해실(240)에서 간접열로 사용되는 약 800~900℃의 고열이 약 500~600℃로 떨어진 채로 상기 가스체류탑(510)을 감싸는 열원공급실(540) 내로 유입되어, 상기 가스체류탑(510)의 온도는 약 200~250℃정도로 유지된다. 따라서 상기 가스체류탑(510)내의 열분해가스가 응축되지 않고 제1탈염장치(550) 측으로 이송된다.That is, the high heat of about 800 ~ 900 ℃ used as indirect heat in the pyrolysis chamber 240 is introduced into the heat source supply chamber 540 surrounding the gas retention tower 510 while falling to about 500 ~ 600 ℃, the gas The temperature of the retention column 510 is maintained at about 200 ~ 250 ℃. Therefore, the pyrolysis gas in the gas retention tower 510 is transferred to the first desalination unit 550 without condensation.
상기 제1탈염장치(550)에서는, 가연성 물질 중에서 염소계 성분을 가진 PVC 계열의 첨가제가 들어간 가연성 물질의 열분해과정에서 필연적으로 발생하는 염소가스를 처리하기 위한 구성이다.In the first desalting apparatus 550, the chlorine gas is inevitably generated during the thermal decomposition of the combustible material containing the PVC-based additive having a chlorine component among the combustible materials.
상기 가스체류탑(510)의 온도는 약 200~250℃로 보정되어 염소화합물이 발생하지 못한 상태가 되고, 상기 제1탈염장치(550)에서 열분해가스를 염기성 수용액에 노출시킴으로써 염소성분을 제거하게 된다. 즉, 상기 제1탈염장치(550)에서는 HCl + NaOH → NaCl + H2O의 화학반응을 일으킴으로써 열분해가스중에서 탄소쇄가 7~23개 사이의 반응생성물이 연속적으로 생성되어 염소를 제거하게 된다.The temperature of the gas retention tower 510 is calibrated to about 200 to 250 ° C. so that no chlorine compound is generated, and the first desalination unit 550 removes the chlorine component by exposing the pyrolysis gas to a basic aqueous solution. do. That is, in the first desalination apparatus 550, by chemical reaction of HCl + NaOH → NaCl + H 2 O, reaction products having 7 to 23 carbon chains are continuously generated in pyrolysis gas to remove chlorine. .
상기 가스개질수단의 제1탈염장치(550) 일측에는 1차적으로 탈염소된 가스에서 추가로 염소성분을 제거하는 제2탈염장치(560)가 구비된다.One side of the first desalination unit 550 of the gas reforming means is provided with a second desalination unit 560 for additionally removing chlorine from the dechlorinated gas.
상기 제2탈염장치(560)에서는 제1탈염장치(550)에서 1차적으로 염소가 제거된 열분해가스가 계속적으로 분자 상호간의 결합이 이루어지기 때문에 수산화나트륨(NaOH) 수용액을 분무시켜 열분해가스를 급냉시킴으로써 벤젠류의 발생을 억제하고 탄소쇄의 긴고리 형성을 억제하여 경질유의 기름을 얻을 수 있다.In the second desalination unit 560, since pyrolysis gas from which chlorine is first removed is continuously formed in the first desalination unit 550, molecular hydrogen is sprayed to quench the pyrolysis gas by spraying an aqueous sodium hydroxide (NaOH) solution. In this way, generation of benzenes can be suppressed, and the formation of long chains in the carbon chain can be suppressed to obtain light oil.
또한, HCl + NaOH → NaCl + H2O의 화학반응이 활발히 이루어져 응축이 되지 않은 탄소쇄가 적은 가스는 청정의 상태로 배출된다. 따라서 탄소쇄가 긴 왁스의 생성도 최소화할 수 있다.In addition, since the chemical reaction of HCl + NaOH → NaCl + H 2 O is actively performed, gas with a small amount of carbon chain which is not condensed is discharged in a clean state. Therefore, it is possible to minimize the generation of wax with a long carbon chain.
그리고 유류성분을 다량 함유한 가연성 물질을 열분해하게 되면 검은 점성의 액체인 타르가 발생하게 되는데, 이의 주성분은 방향족 탄화수소로써 안정적인 형태를 취하면서 분해되었던 가스성분중에서 서로 결합하면서 발생하게 된다. 이러한 타르의 발생을 최소화하기 위해 상기 제2탈염장치(560)에서 타르가 발생할 수 있는 공간과 시간을 최소화하게 된다.When pyrolyzing flammable substances containing a large amount of oil components, tar, which is a black viscous liquid, is generated, and its main components are formed by combining with each other in the decomposed gas components while taking a stable form as an aromatic hydrocarbon. In order to minimize the generation of tar, the second desalting apparatus 560 minimizes the space and time at which tar can occur.
상기 제2탈염장치(560)의 일측에는 탈염소 처리된 열분해가스를 정제하는 가스정제수단(700)과, 열분해가스를 이용하여 정제유를 생성하는 정제유생성수단(800)이 구비된다.One side of the second desalination apparatus 560 is provided with a gas purification means 700 for purifying the dechlorinated pyrolysis gas, and a refining oil producing means 800 for generating refined oil using the pyrolysis gas.
상기 가스정제수단(700)은, 탈염소 처리된 열분해가스를 안정적인 분위기 하에서 응축하여 1차 정제유를 생성하는 침전응축장치와, 가스의 질을 높이기 위한 정제장치를 구비한다. 상기 가스정제수단(700)을 통해 정제된 가스는 수봉장치를 거쳐 가스저장탱크에 저장되었다가 압력조절장치를 거쳐서 연소실(250)로 공급되어 연소용 가스로 사용된다.The gas purification means 700 includes a precipitation condensation apparatus for condensing the dechlorinated pyrolysis gas under a stable atmosphere to generate a primary refined oil, and a purification apparatus for improving gas quality. The gas purified through the gas purification means 700 is stored in the gas storage tank through a water seal device and then supplied to the combustion chamber 250 through a pressure regulating device to be used as a gas for combustion.
상기 정제유생성수단(800)은 침전응축장치로부터 공급받은 1차 정제유를 저장하는 저장탱크와, 이 저장탱크에 저장된 1차 정제유를 유수분리하는 유수분리기 및 유수분리된 정제유를 비등점에 따라 휘발유, 경유, 중유로 분리하는 증류탑을 구비한다.The refined oil producing means 800 is a storage tank for storing the primary refined oil supplied from the settling condensation device, an oil-separator for oil-separating the primary refined oil stored in the storage tank and the oil-separated refined oil according to the boiling point gasoline, diesel And a distillation column separated by heavy oil.
상기 탄화재 배출수단은 열분해기몸체(210)로부터 열분해된 후 생성된 탄화재를 배출하는 구성으로, 열분해기몸체(210)의 끝단에 형성되는 배출호퍼(610)를 포함하여 구성된다.The carbonization material discharge means is a configuration for discharging the carbonized material generated after pyrolysis from the pyrolyzer body 210, and comprises a discharge hopper 610 formed at the end of the pyrolyzer body 210.
열분해 후 생성된 탄화재는 열분해기몸체(210)의 끝단을 통해서 연속적으로 배출되고, 탄화재의 배출시 외부로부터 유입되는 외부공기 및 열분해기몸체(210)로부터 배출되는 열분해가스를 차단하도록 배출호퍼에는 슬라이드 게이트(620)가 구비된다. 슬라이드 게이트(620)는 외부와의 차단을 극대화하며 오작동을 방지할 수 있도록 적어도 2단 이상으로 구성되는 것이 바람직하다.Carbonization material generated after the pyrolysis is continuously discharged through the end of the pyrolyzer body 210, discharge hopper to block the pyrolysis gas discharged from the outside air and pyrolyzer body 210 when the carbonized material is discharged from the outside. The slide gate 620 is provided. The slide gate 620 is preferably configured in at least two stages to maximize the blocking of the outside and prevent malfunction.
상기 탄화재 배출수단을 통하여 연속적으로 배출되는 탄화재는 탄화재성형수단(900)으로 배출되어 고형 연료를 생산하게 된다. 배출되는 탄화재에는 초자류, 쇠, 비철금속 등 이물질이 함께 섞여서 배출되기 때문에, 분쇄장치 및 선별장치를 거쳐서 이물질과 탄화재를 완전 분리한 뒤에 이물질은 제거하고 탄화재만을 가지고 성형장치를 거쳐서 소정의 형상을 가지는 연료, 예컨대 조개탄 등을 생산한다.The carbonized material continuously discharged through the carbonized material discharge means is discharged to the carbonized material forming means 900 to produce solid fuel. Since the discharged carbonized material is discharged by mixing foreign substances such as superfluous, iron, and non-ferrous metals together, the foreign materials and carbonized material are completely separated through the crushing device and sorting device, and then the foreign materials are removed, and only the carbonized material is passed through the molding device. It produces fuel having a shape, such as briquettes.
이하에서는, 본 발명의 일 실시예에 의한 고상 가연성 물질의 열분해방법에 대해 설명하도록 한다.Hereinafter, a thermal decomposition method of a solid combustible material according to an embodiment of the present invention will be described.
금속파편, 플라스틱, 종이, 산업가연성 물질의 찌꺼기 등을 포함하는 고상 가연성 물질은 입하 후 파쇄기에서 소정 크기로 파쇄된 후, 선별기를 경유하여 흙, 먼지 등이 제거되며 비철금속 등이 선별되어 선별된 일부 가연성 물질은 재활용된다. 선별 처리된 고상 가연성 물질은 분쇄기로 이동되어 비교적 작은 크기로 분쇄된다. 분쇄된 가연성 물질은 2차로 자력 선별장치를 통해 철자재를 재선별하여 일부는 재활용된다.Solid combustible materials including metal fragments, plastics, paper, industrial combustibles, etc. are shredded to a predetermined size in the crusher after arrival, and the soil, dust, etc. are removed through a sorting machine, and non-ferrous metals are selected and selected. Flammable materials are recycled. The sorted solid combustible material is transferred to a grinder and ground to a relatively small size. The combustible combusted material is secondly re-selected through a magnetic screening device and partly recycled.
분쇄된 고상 가연성 물질은 메인호퍼를 통해 열분해수단으로 투입되며, 열분해기몸체(210)로 이송된 가연성 물질은 열분해실(240)로 제공된 열원의 간접 가열 방식에 의해 열분해되는데, 가연성 물질이 열분해기몸체(210)로 투입되면, 도 1을 기준으로 우측방향으로 이송되면서 용융 및 기화되는 가연성 물질은 고온 및 저산소 상태의 분위기를 유지하는 열분해실(240)에서 간접적으로 가해지는 열에 의해 연속적으로 열분해된다.The pulverized solid combustible material is introduced into the pyrolysis means through the main hopper, and the combustible material transferred to the pyrolyzer body 210 is pyrolyzed by an indirect heating method of a heat source provided to the pyrolysis chamber 240, and the combustible material is pyrolyzed. When introduced into the body 210, the combustible material that is melted and vaporized while being transferred to the right direction based on FIG. 1 is continuously pyrolyzed by heat applied indirectly in the pyrolysis chamber 240 maintaining an atmosphere of high temperature and low oxygen state. .
이때, 상기 열분해기몸체(210)의 제2몸체(213)가 열분해스크류(220)와 같이 회전하면서, 상기 열분해스크류(220)와의 회전속도의 차이에 의해 천천히 이동하게 되어, 상기 제2몸체(213)가 고정되어있을 때에 비해 적어도 3배 이상의 전열면적이 제공할 수 있게 된다. 따라서 적은 공간에서 많은 양의 가연성 물질을 열분해 할 수 있게 된다.At this time, while the second body 213 of the pyrolyzer body 210 rotates together with the pyrolysis screw 220, the second body 213 moves slowly due to the difference in the rotational speed with the pyrolysis screw 220. At least three times more heat transfer area can be provided than when 213 is fixed. Therefore, it is possible to pyrolyze a large amount of combustible material in a small space.
열분해된 이후의 발생하는 열분해가스는 열분해기몸체(210)의 상측에 구비되는 가스체류탑(510)에 체류하면서 가연성 물질에 간접적으로 고온의 열을 가하여 열분해시킨 후 탈염소반응탑으로 이송된다.The pyrolysis gas generated after the pyrolysis is stayed in the gas retention tower 510 provided above the pyrolyzer body 210, and is indirectly heated to the combustible material to be pyrolyzed, and then transferred to the dechlorination tower.
열분해된 후 이송된 열분해가스는 제1탈염장치(550) 및 제2탈염장치(560)를 통과한 후 정제유생성수단(800)으로 이송된다.The pyrolysis gas transferred after the pyrolysis passes through the first desalting unit 550 and the second desalting unit 560 and then is transferred to the refining oil producing means 800.
그리고 열분해 이후 물성을 잃게 된 탄화재는 열분해기몸체(210)의 하측에 구비된 배출호퍼를 통해 배출된다. 이때, 배출되는 탄화재에는 초자류, 쇠, 비철금속 등 이물질이 함께 섞여서 배출되는데, 분쇄장치와 선별장치를 거쳐 소정의 형상을 가지는 연료, 예컨대 조개탄 등을 생산한다.And the carbonized material lost the properties after the pyrolysis is discharged through the discharge hopper provided on the lower side of the pyrolyzer body (210). At this time, the discharged carbonized material is discharged by mixing foreign matters such as superfluous, iron, non-ferrous metal, etc., and produces a fuel having a predetermined shape, such as briquettes, through a crusher and a sorting device.
이상, 본 발명의 실시예를 참조하여 설명했지만, 본 발명이 이것에 한정되지는 않으며, 다양한 변형 및 응용이 가능하다. 즉, 본 발명의 요지를 일탈하지 않는 범위에서 많은 변형이 가능한 것임을 당업자는 용이하게 이해할 수 있을 것이다.As mentioned above, although demonstrated with reference to the Example of this invention, this invention is not limited to this, A various deformation | transformation and an application are possible. That is, those skilled in the art will readily appreciate that many modifications are possible without departing from the spirit of the invention.
상기한 바와 같은 본 발명에 의하면, 열분해기몸체의 일부를 열분해스크류와 같이 회전시키도록 하여 열분해시의 열제공면적을 최대화 함으로써 적은 공간에서 많은 양의 고상의 가연성 물질을 열분해할 수 있는 효과를 가진다.According to the present invention as described above, it is possible to thermally decompose a large amount of solid combustible material in a small space by maximizing the heat providing area during pyrolysis by rotating a portion of the pyrolyzer body together with the pyrolysis screw. .
그리고 탈염제거장치를 2중으로 구비함으로써 열분해가스 내의 염소제거량을 최소화할 수 있어, 가연성 물질의 열분해 이후 추출되는 기름이나 가스의 순도를 높일 수 있는 효과를 가진다.In addition, since the desalination removal apparatus is provided in duplicate, the amount of chlorine removal in the pyrolysis gas can be minimized, thereby increasing the purity of oil or gas extracted after pyrolysis of the combustible material.

Claims (10)

  1. 고상 가연성 물질이 투입되는 메인호퍼를 구비하여, 투입된 가연성 물질을 이송, 용융 및 기화시키는 열분해스크류(220)가 구비되고, 가연성 물질의 이송방향을 따라 제1몸체(211)와 제2몸체(213), 그리고 제3몸체(215)가 단차지게 확장 형성되며, 상기 제2몸체(213)는 회전가능하도록 구비되어 상기 열분해 스크류와의 회전속도 차이에 의해 가연성 물질을 이송시키는 열분해기몸체(210);It is provided with a main hopper into which the solid combustible material is injected, and a pyrolysis screw 220 for transporting, melting, and vaporizing the injected combustible material is provided, and the first body 211 and the second body 213 along the conveying direction of the combustible material. And, and the third body 215 is formed to be expanded stepwise, the second body 213 is provided to be rotatable pyrolyzer body 210 for transferring the combustible material by the rotational speed difference with the pyrolysis screw ;
    상기 열분해기몸체(210)의 외측에 설치되어 고온 및 저산소 상태의 분위기를 유지하여 가연성 물질을 간접 가열에 의해 연속적으로 열분해시키는 열분해실(240); 그리고A pyrolysis chamber 240 installed outside the pyrolyzer body 210 to continuously decompose the combustible material by indirect heating by maintaining an atmosphere of high temperature and low oxygen state; And
    상기 열분해실(240)의 일측에 마련되며, 열분해기몸체(210)로 이송되는 가연성 물질을 열분해시키는 열원으로서 이용하도록 가연성 물질의 열분해시 발생되는 열분해가스 중 비응축가스를 연소시켜 상기 열분해실(240)에 열을 공급하는 연소실(250)을 포함하는 것을 특징으로 하는 고상 가연성 물질의 열분해 장치.It is provided on one side of the pyrolysis chamber 240, by burning the non-condensing gas of the pyrolysis gas generated during the pyrolysis of the combustible material to use as a heat source for pyrolyzing the combustible material transferred to the pyrolyzer body 210, the pyrolysis chamber ( A pyrolysis apparatus for a solid combustible material, characterized in that it comprises a combustion chamber (250) for supplying heat to 240.
  2. 제 1 항에 있어서,The method of claim 1,
    상기 제1몸체(211)와 제2몸체(213), 상기 제2몸체(213)와 제3몸체(215)의 사이에는 각각 실링유닛이 구비되는 것을 특징으로 하는 고상 가연성 물질의 열분해 장치.And a sealing unit is provided between the first body 211 and the second body 213, and between the second body 213 and the third body 215, respectively.
  3. 제 1 항에 있어서,The method of claim 1,
    상기 제3몸체(215)의 입구부는 상기 열분해 스크류와 간극이 형성되지 않도록 원형으로 형성되고,The inlet portion of the third body 215 is formed in a circular shape so that no gap is formed with the pyrolysis screw.
    상기 제3몸체(215)의 중간부는 상기 열분해 스크류와 소정 공간이 형성될 수 있도록 유선형으로 형성되며, The middle portion of the third body 215 is formed in a streamline so that a predetermined space can be formed with the pyrolysis screw,
    상기 제3몸체(215)의 후단부는 상기 열분해 스크류와 간극이 형성되지 않도록 원형으로 형성되는 것을 특징으로 하는 고상 가연성 물질의 열분해 장치.The rear end of the third body 215 is a pyrolysis device of a solid combustible material, characterized in that formed in a circular shape so as not to form a gap with the pyrolysis screw.
  4. 제 1 항에 있어서,The method of claim 1,
    상기 상기 제2몸체(213)와 제3몸체(215) 구간에 구비되는 열분해스크류의 스크류날개에는 배출홀(223)이 형성되는 것을 특징으로 하는 고상 가연성 물질의 열분해 장치.The pyrolysis apparatus of the solid phase combustible material, characterized in that the discharge hole 223 is formed in the screw blades of the pyrolysis screw provided in the second body 213 and the third body 215 section.
  5. 제 1 항에 있어서, The method of claim 1,
    상기 열분해 몸체의 제3몸체(215)부의 중간부 상측에는 가연성 물질의 열분해시 발생하는 열분해가스를 소정시간 체류시키는 가스체류탑(510)이 구비되는 것을 특징으로 하는 고상 가연성 물질의 열분해 장치.The gas pyrolysis apparatus of the solid phase combustible material, characterized in that the gas retention tower (510) for retaining the pyrolysis gas generated during the thermal decomposition of the combustible material for a predetermined time on the upper side of the middle portion of the third body (215) of the pyrolysis body.
  6. 제 5 항에 있어서,The method of claim 5,
    상기 가스체류탑(510)의 내부에는, 상기 가스 체류탑의 내벽에 부착된 타르, 탄화재를 분리시키는 나선스크류(520)가 구비되는 것을 특징으로 하는 고상 가연성 물질의 열분해 장치.Inside the gas retention tower (510), a spiral screw (520) for separating the tar and the carbonized material attached to the inner wall of the gas retention tower is provided with a pyrolysis device of a solid combustible material.
  7. 제 5 항에 있어서,The method of claim 5,
    상기 가스 체류탑의 일측에는 열분해가스 중 염소를 제거하기 위한 탈염장치가 구비되는 것을 특징으로 하는 고상 가연성 물질의 열분해 장치.One side of the gas retention tower is a pyrolysis device of a solid combustible material, characterized in that the desalination device for removing chlorine in the pyrolysis gas is provided.
  8. 제 7항에 있어서,The method of claim 7, wherein
    상기 탈염장치로부터 염소가 제거된 열분해가스를 정제하기 위한 가스정제수단(700)을 더 포함하는 것을 특징으로 하는 고상 가연성 물질의 열분해 장치.Pyrolysis device of a solid combustible material, characterized in that it further comprises a gas purification means (700) for purifying pyrolysis gas from which chlorine is removed from the desalting apparatus.
  9. 제 7 항에 있어서,The method of claim 7, wherein
    상기 탈염소 반응탑으로부터 염소가 제거된 열분해가스를 침강 응축시킨 후 증류탑에서 비등점에 따라 휘발유, 경유 및 중유를 생성하는 정제유생성수단(800)을 더 포함하는 것을 특징으로 하는 고상 가연성 물질의 열분해 장치.The pyrolysis apparatus of the solid phase combustible material further comprising refined oil producing means 800 for generating gasoline, light oil and heavy oil according to the boiling point in the distillation column after sedimentation and condensation of the pyrolysis gas from which the chlorine is removed from the dechlorination reaction tower. .
  10. 제 1 항에 있어서,The method of claim 1,
    상기 열분해실(240)로부터 열분해된 후 생성되는 탄화재를 연속적으로 배출시키는 탄화재 배출수단을 더 포함하는 것을 특징으로 하는 고상 가연성 물질의 열분해 장치.A pyrolysis device for solid phase combustible material, characterized in that it further comprises a carbon material discharge means for continuously discharging the carbon material generated after pyrolysis from the pyrolysis chamber (240).
PCT/KR2013/005078 2013-06-10 2013-06-10 Pyrolysis apparatus for combustible material in solid state WO2014200123A1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11773330B2 (en) 2016-07-05 2023-10-03 Braven Environmental, Llc System and process for converting waste plastic into fuel

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000167508A (en) * 1998-11-30 2000-06-20 Takuma Co Ltd Apparatus for carbonizing/pyrolyzing waste
KR20030064131A (en) * 2002-01-26 2003-07-31 한반도환경산업 주식회사 Solid fuel extruding machine for utilization of combustibility waste
KR20060028570A (en) * 2004-09-25 2006-03-30 주식회사 알포 Successive pyrolysis system of waste synthetic-highly polymerized compound
KR100820868B1 (en) * 2006-12-04 2008-04-11 박연룡 Oil manufacturing device removing hydrogen chloride for high polymer waste
KR20090117377A (en) * 2008-05-09 2009-11-12 구재완 Scrapped material thermal resolution system and method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000167508A (en) * 1998-11-30 2000-06-20 Takuma Co Ltd Apparatus for carbonizing/pyrolyzing waste
KR20030064131A (en) * 2002-01-26 2003-07-31 한반도환경산업 주식회사 Solid fuel extruding machine for utilization of combustibility waste
KR20060028570A (en) * 2004-09-25 2006-03-30 주식회사 알포 Successive pyrolysis system of waste synthetic-highly polymerized compound
KR100820868B1 (en) * 2006-12-04 2008-04-11 박연룡 Oil manufacturing device removing hydrogen chloride for high polymer waste
KR20090117377A (en) * 2008-05-09 2009-11-12 구재완 Scrapped material thermal resolution system and method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11773330B2 (en) 2016-07-05 2023-10-03 Braven Environmental, Llc System and process for converting waste plastic into fuel

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