CN110496526A - The method for absorbing slurry-spraying pelletizing flue gas is purified using resin complexes - Google Patents
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- B01D53/34—Chemical or biological purification of waste gases
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- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
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Abstract
The invention belongs to environmental technology fields, disclose the method that slurry-spraying pelletizing flue gas is absorbed using resin complexes purification, include the following steps: that slurry-spraying pelletizing flue gas first passes around spray scrubber and carries out spray washing, it is cooled to 33 DEG C or less, subsequently into purification absorption is carried out in the reaction chamber equipped with resin complexes, it is then discharged out.The present invention absorbs slurry-spraying pelletizing flue gas using resin complexes purification, simple and feasible, can effectively remove the H in flue gas2S、SO2And the major pollutants such as NOx.
Description
Technical field
The invention belongs to environmental technology fields, and in particular to the side for absorbing slurry-spraying pelletizing flue gas is purified using resin complexes
Method.
Background technique
Compound fertilizer workshop is during producing compound fertilizer using amino acid waste liquid, using spray granulation, tail
Composition is more complex in gas, mainly there is floating dust, dust and tiny compound fertilizer granules, and gas main ingredient is brought by fire coal
The gas of a large amount of toxic, irritant smells.Predominant gas composition has hydrogen sulfide, sulfur dioxide, ammonia nitrogen, ketone, aldehydes, ester
Class, benzene class dust, vapor etc..Especially in rainy days or lower air pressure, plant area and neighbouring resident living area smog are often resulted in
Boundless and indistinct, the harm of acid mist and acid rain is quite serious, the rule of the concentration of emission of flue dust and exhaust gas considerably beyond national emission standard
It is fixed, biggish negative effect is generated to environment and human body, so compound fertilizer workshop treating tail gas is very urgent, it is necessary to carry out
It administers.How to reduce slurry-spraying pelletizing tail gas peculiar smell is our very urgent technical issues that need to address.
In view of the urgency of environmental protection, applicant persistently studies the improvement of slurry-spraying pelletizing flue gas, early period
Patented technology include " 201610508054, a kind of processing method of slurry-spraying pelletizing tail gas cooling and deodorizing desulphurization denitration ",
" 201410586080, a method of pernicious gas in removal boiler smoke " and " one kind is for removing slurry-spraying pelletizing tail gas
Biological agent of peculiar smell " etc., wherein it is " a kind of for removing the biological agent of slurry-spraying pelletizing tail gas peculiar smell " using three kinds of bacterial strains into
Row compatibility, synergisticing performance are good preferable, and prepare absorption carrier with clinker, stalk, clay and calcirm-fluoride, which can be with
Absorption tail gas peculiar smell, the tail gas being adsorbed can be absorbed and utilized by bacterial strain, to achieve the purpose that handle tail gas, this method is obtained
Certain regulation effect, but adhesion amount of the bacterial strain on carrier be still to be improved.
Macroporous absorbent resin is a kind of polymeric sorbent with good macroreticular structure and large specific surface area,
Organic matter can be selectively adsorbed from aqueous solution by physical absorption, be the novel high polymer to grow up the 1960s
Adsorbent is used widely in environmental protection, food, medicine and other fields.Currently, macroporous absorbent resin is improved, to make
Research for bacterial strain absorption carrier is relatively fewer.
Summary of the invention
In order to overcome the drawbacks of the prior art, the purpose of the present invention is to provide purifications to absorb the compound of slurry-spraying pelletizing flue gas
Object, the compound include resin adsorption carrier and bacterium, and carrier is good to the adsorption effect of bacterium, and adhesion amount improves, the effect of purifying smoke
Fruit is mutually due for promotion.
To achieve the above object, the invention provides the following technical scheme:
The method for absorbing slurry-spraying pelletizing flue gas is purified using resin complexes, includes the following steps: that slurry-spraying pelletizing flue gas passes through first
It crosses spray scrubber and carries out spray washing, cooling processing is to 33 DEG C hereinafter, subsequently into the reaction chamber equipped with resin complexes
Purification absorption is carried out, is then discharged out.
The resin complexes are prepared by resin adsorption carrier and composite bacteria liquid；
The compound is prepared in accordance with the following steps: composite bacteria liquid is added in the resin adsorption carrier of 1-2 times of quality,
100rpm stirs 30min, is then allowed to stand 6h, solid content is collected by filtration, last low temperature drying to obtain the final product.
Further, the preparation method of the resin adsorption carrier includes the following steps:
The methylene blue that 10wt% methanol and 2wt% are added into the sodium acetate aqueous solution that concentration is 1M, stirs evenly, is heated to 50
DEG C, the organic solution of same volume is then added, is reacted, is warming up to 65 DEG C, is stirred to react 12h under heat-retaining condition, obtains
Partial size is the sphere of 20-40 mesh, and sphere is collected by filtration, and then addition accounts for the vinyl triethoxyl silicon of sphere 5wt%
Alkane, 100rpm stirs 3min, then adds the nano-silicon rubber powder for accounting for sphere 10wt%, continues to stir 5min with 100rpm, then set
The dry 30min in 80 DEG C of baking oven, takes out, cooled to room temperature to get.
Further, the preparation method of the composite bacteria liquid includes the following steps:
1) micrococcus luteus is inoculated into seed culture medium, 30 DEG C of culture viable counts into product reach 2.0 × 108Cfu/ml,
Up to micrococcus luteus seed liquor；The component of the seed culture medium are as follows: yeast extract 5g/L, (NH4)2SO42g/L g, glucose
3g/L, K2HPO40.5g/L, KH2PO40.5g/L；
2) Achromobacter xylosoxidans being inoculated into seed culture medium, 28 DEG C of culture viable counts into product reach 1.0 ×
108Cfu/ml is to get Achromobacter xylosoxidans seed liquor；The seed culture based component are as follows: urea 1.0g/L, CH3 COONa
3.0g/L, MgC12 0.1g/L, CaC120.1g/L, KH2 PO40.5g/L, K2 HPO40.5g/L；
3) Acidithiobacillus ferrooxidans strain GF being inoculated into seed culture medium, 28 DEG C of culture viable counts into bacterium solution reach 5.0 ×
108Cfu/ml is to get Acidithiobacillus ferrooxidans strain GF seed liquor；The seed culture medium component are as follows: (NH4) 2SO42g/L, KCl
0.1g/L, K2HPO40.5g/L, KH2PO40.5g/L, Ca (NO3)20.01g/L, FeSO4·7H2O 10g/L；
4) micrococcus luteus seed liquor, Achromobacter xylosoxidans seed liquor and Acidithiobacillus ferrooxidans strain GF seed liquor are pressed
According to 3-5:2-3:5-7 volume ratio mix to get.
Preferably, the organic solution by vinylacetate, divinylbenzene, butyl acetate and benzoyl peroxide according to
Mass ratio 5:1:8:2 mixing.
Purposes of the above-mentioned compound in slurry-spraying pelletizing gas cleaning absorption is also claimed in the present invention.
Preferably,
Contain H in the slurry-spraying pelletizing flue gas2S、SO2And NOx.
It infuses, bacterium cultural method is not unique in above-mentioned steps, and it is suitable that those skilled in the art can select according to common sense
Culture medium and cultural method, so that the order of magnitude of viable count is reached 108Cfu/ml, and conventionally prepare compound bacteria
Liquid.
Compared with prior art, the beneficial effect that the present invention obtains mainly includes but is not limited to the following aspects:
The present invention absorbs slurry-spraying pelletizing flue gas using resin complexes purification, simple and feasible, can effectively remove in flue gas
H2S、SO2And the major pollutants such as NOx.
The resin adsorption carrier that the present invention uses belongs to macroreticular resin, during the preparation process, by nano material through vinyl
When triethoxysilane coupling agent treatment, one end of coupling agent is combined with nano material with chemical bond, other end of amino
Functional group can chemically react with resin material, enhance the combination of phase interface, improve compatibility, reduce interface cavity
Hole and defect, and increase specific surface area；
Thiobacillus ferrooxidans has preferable desulfidation；Micrococcus luteus belongs to heterotrophism denitrifier, aoxidizes the colourless bar of xylose
Pseudomonas can occasionally slough nitrogen oxides in aerobic denitrifying bacteria；Contain a certain amount of oxygen in flue gas, but concentration is lower, In
Formd under low concentration aerobic conditions, in carrier distinctive heterotrophism denitrifier, aerobic denitrifying bacteria and Thiobacillus coexist it is micro-
Biosystem, symbiosis of mutually promoting, synergy are good；
Compound of the present invention is prepared using resin adsorption carrier and mixed bacteria liquid, and thallus adhesion effect is good, and load capacity is big, than
Surface area is big, can improve adsorption effect.
Detailed description of the invention
Fig. 1: influence of the carrier to purified treatment flue gas effect；
Fig. 2: bacterial strain selects the influence to purified treatment flue gas effect.
Specific embodiment
In order to make those skilled in the art better understand the technical solutions in the application, having below in conjunction with the application
Body embodiment more clearly and completely describes the present invention, it is clear that described embodiment is only the application one
Divide embodiment, instead of all the embodiments.Based on the embodiment in the application, those of ordinary skill in the art are not making
Every other embodiment obtained, should fall within the scope of the present invention under the premise of creative work.
Embodiment 1
The method for absorbing slurry-spraying pelletizing flue gas is purified using resin complexes, includes the following steps: that slurry-spraying pelletizing flue gas passes through first
It crosses spray scrubber and carries out spray washing, cooling processing is to 33 DEG C hereinafter, subsequently into the reaction chamber equipped with resin complexes
Purification absorption is carried out, is then discharged out.
The resin complexes are prepared by resin adsorption carrier and composite bacteria liquid；
The resin complexes are prepared in accordance with the following steps: the resin adsorption that composite bacteria liquid is added to 1.5 times of quality is carried
In body, 100rpm stirs 30min, is then allowed to stand 6h, solid content is collected by filtration, last low temperature drying to obtain the final product.
The preparation method of the resin adsorption carrier includes the following steps:
The methylene blue that 10wt% methanol and 2wt% are added into the sodium acetate aqueous solution that concentration is 1M, stirs evenly, is heated to 50
DEG C, then add organic solution (vinylacetate, divinylbenzene, butyl acetate and the benzoyl peroxide of same volume
Mass ratio 5:1:8:2), it is reacted, is warming up to 65 DEG C, is stirred to react 12h under heat-retaining condition, obtains sphere, be collected by filtration
Sphere, then addition accounts for the vinyltriethoxysilane of sphere 5wt%, and 100rpm stirs 3min, then adds and account for sphere
The nano-silicon rubber powder of 10wt% continues to stir 5min with 100rpm, is subsequently placed in 80 DEG C of baking oven dry 30min, takes out, from
So be cooled to room temperature to get.
The preparation method of the composite bacteria liquid includes the following steps:
Micrococcus luteus ATCC10240 is inoculated into seed culture medium, 30 DEG C of culture viable counts into product reach 2.0 ×
108Cfu/ml is to get micrococcus luteus seed liquor；The medium component are as follows: the component of seed culture medium are as follows: yeast extract 5g/
L, (NH4) 2SO42g/L g, glucose 3g/L, K2HPO40.5g/L, KH2PO40.5g/L；
Achromobacter xylosoxidans ATCC27061 is inoculated into seed culture medium, 28 DEG C of culture viable counts into product reach 1.0
×108Cfu/ml is to get Achromobacter xylosoxidans seed liquor；The medium component are as follows: urea 1.0g/L, CH3 COONa
3.0g/L, MgC12 0.1g/L, CaC120.1g/L, KH2 PO40.5g/L, K2 HPO40.5g/L；
Acidithiobacillus ferrooxidans strain GF ATCC 23270 is inoculated into seed culture medium, 28 DEG C of culture viable counts into bacterium solution reach
To 5.0 × 108Cfu/ml is to get Acidithiobacillus ferrooxidans strain GF seed liquor；The seed culture medium component are as follows: (NH4)2SO4
2g/L, KCl 0.1g/L, K2HPO40.5g/L, KH2PO40.5g/L, Ca (NO3)20.01g/L, FeSO4·7H2O 10g/L；
By micrococcus luteus seed liquor, Achromobacter xylosoxidans seed liquor and Acidithiobacillus ferrooxidans strain GF seed liquor according to
The volume ratio of 3:2:5 mix to get.
Embodiment 2
The method for absorbing slurry-spraying pelletizing flue gas is purified using resin complexes, includes the following steps: that slurry-spraying pelletizing flue gas passes through first
It crosses spray scrubber and carries out spray washing, cooling processing is to 33 DEG C hereinafter, subsequently into the reaction chamber equipped with resin complexes
Purification absorption is carried out, is then discharged out.
The resin complexes are prepared by resin adsorption carrier and composite bacteria liquid；
The resin complexes are prepared in accordance with the following steps: composite bacteria liquid is added to the resin adsorption carrier of 2 times of quality
In, 100rpm stirs 30min, is then allowed to stand 6h, solid content is collected by filtration, last low temperature drying to obtain the final product.
The preparation method of the resin adsorption carrier includes the following steps:
The methylene blue that 10wt% methanol and 2wt% are added into the sodium acetate aqueous solution that concentration is 1M, stirs evenly, is heated to 50
DEG C, then add organic solution (vinylacetate, divinylbenzene, butyl acetate and the benzoyl peroxide of same volume
Mass ratio 5:1:8:2), it is reacted, is warming up to 65 DEG C, is stirred to react 12h under heat-retaining condition, obtains sphere, be collected by filtration
Sphere, then addition accounts for the vinyltriethoxysilane of sphere 5wt%, and 100rpm stirs 3min, then adds and account for sphere
The nano-silicon rubber powder of 10wt% continues to stir 5min with 100rpm, is subsequently placed in 80 DEG C of baking oven dry 30min, takes out, from
So be cooled to room temperature to get.
The preparation method of the composite bacteria liquid includes the following steps:
Micrococcus luteus ATCC10240 is inoculated into seed culture medium, 30 DEG C of culture viable counts into product reach 2.0 ×
108Cfu/ml is to get micrococcus luteus seed liquor；The medium component are as follows: the component of seed culture medium are as follows: yeast extract 5g/
L, (NH4) 2SO42g/L g, glucose 3g/L, K2HPO40.5g/L, KH2PO40.5g/L；
Achromobacter xylosoxidans ATCC27061 is inoculated into seed culture medium, 28 DEG C of culture viable counts into product reach 1.0
×108Cfu/ml is to get Achromobacter xylosoxidans seed liquor；The medium component are as follows: urea 1.0g/L, CH3 COONa
3.0g/L, MgC12 0.1g/L, CaC120.1g/L, KH2 PO40.5g/L, K2 HPO40.5g/L；
Acidithiobacillus ferrooxidans strain GF ATCC 23270 is inoculated into seed culture medium, 28 DEG C of culture viable counts into bacterium solution reach
To 5.0 × 108Cfu/ml is to get Acidithiobacillus ferrooxidans strain GF seed liquor；The seed culture medium component are as follows: (NH4) 2SO4
2g/L, KCl 0.1g/L, K2HPO40.5g/L, KH2PO40.5g/L, Ca (NO3)20.01g/L, FeSO4·7H2O 10g/L；
By micrococcus luteus seed liquor, Achromobacter xylosoxidans seed liquor and Acidithiobacillus ferrooxidans strain GF seed liquor according to
The volume ratio of 5:3:7 mix to get.
Embodiment 3
Resin adsorption carrier property test of the present invention:
By taking embodiment 1 as an example, control group does not add nano-silicon rubber powder and coupling agent vinyltriethoxysilane, has detected carrier
Specific surface area, average grain diameter and thallus adhesion amount (dry weight), be specifically shown in Table 1:
Table 1
| Group | Specific surface area m2/g | Average grain diameter (mesh) | Thallus adhesion amount mg/g |
| Embodiment 1 | 739 | 45 | 13.7 |
| Control group | 561 | 50 | 8.2 |
Seen from table 1, after the modification of nano-silicon rubber powder, the specific surface area of resin carrier reaches 739m2/ g, than unmodified
Control group is compared, and improves 31.7%, and bacterial strain adhesion amount also significantly improves, and compares, improves than unmodified control group
67.1%。
Embodiment 4
Influence of the resin adsorption carrier of the present invention to purified treatment flue gas effect；
The tail gas in this test selection Fu Feng group compound fertilizer's slurry-spraying pelletizing workshop is handled, and the exhaust gas component after spray is such as
Under: H2S is 133mg/Nm3, SO2For 149g/Nm3, NOx 151mg/Nm3, temperature is 32 DEG C, air speed 6000h-1；Then into
Enter to carry out purification absorption processing in the reaction chamber equipped with compound, the processing time is 60min；Control group: control group 1 is set: system
In standby resin adsorption carrier, nano-silicon rubber powder and coupling agent are not added, remaining is the same as embodiment 1；Control group 2: carrier selects diatom
Soil, remaining is the same as embodiment 1.As shown in Figure 1, using resin adsorption carrier of the present invention, desulfurization efficiencies of nitrogen removal is more preferable, hence it is evident that better than adopting
With the control group 2 and unmodified control group 1 of conventional carrier, wherein in example 1 group, H2S is reduced to 1.5mg/Nm3,
Removal efficiency is 98.9%, SO2It is reduced to 2.1g/Nm3, removal efficiency 98.6%, NOx reduction to 1.3mg/Nm3, removal efficiency is
99.1%。
Embodiment 4
Bacterial strain of the present invention selects the influence to gas cleaning effect:
Group: embodiment 1；Control group 1: not adding micrococcus luteus, remaining is the same as embodiment 1；Control group 2: oxidation wood is not added
Sugared achromobacter, remaining is the same as embodiment 1；Control group 3: not adding Acidithiobacillus ferrooxidans strain GF, remaining is the same as embodiment 1；Tail gas
Batch selection and treatment conditions are with embodiment 3, as shown in Fig. 2, embodiment 1 is using micrococcus luteus, the oxidation colourless bar of xylose
Three kinds of bacterium of bacterium and Acidithiobacillus ferrooxidans strain GF carry out compatibility, are adsorbed using specific resin absorption carrier, thallus load
Amount is big, and it is total that distinctive heterotrophism denitrifier, aerobic denitrifying bacteria and Thiobacillus are formd under low concentration aerobic conditions, in carrier
The microorganism system deposited, symbiosis of mutually promoting, synergy are good, the H in flue gas2S、SO2And the major pollutants index such as NOx
The range of decrease is obvious, and effect is better than the control group 1-3 only with two kinds of bacterial strains.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specific example " or
The description of " some examples " etc. means that particular features, structures, materials, or characteristics described in conjunction with this embodiment or example include
In at least one embodiment of the present invention or example.In the present specification, schematic expression of the above terms necessarily needle
Pair be identical embodiment or example.Although the embodiments of the present invention has been shown and described above, it is to be understood that
Above-described embodiment is exemplary, and is not considered as limiting the invention, and those skilled in the art are of the invention
It can make changes, modifications, alterations, and variations to the above described embodiments in range.
Claims (9)
1. absorbing the method for slurry-spraying pelletizing flue gas using resin complexes purification, include the following steps: slurry-spraying pelletizing flue gas first
By spray scrubber carry out spray washing, be cooled to 33 DEG C hereinafter, subsequently into equipped with resin complexes reaction chamber in into
Row purification absorbs, and is then discharged out.
2. the method according to claim 1, wherein the resin complexes are by resin adsorption carrier and compound bacteria
Liquid is prepared.
3. according to the method described in claim 2, it is characterized in that, the resin complexes are prepared in accordance with the following steps:
Composite bacteria liquid is added in the resin adsorption carrier of 1-2 times of quality, 100rpm stirs 30min, is then allowed to stand 6h, is collected by filtration
Solid content, last low temperature drying to obtain the final product.
4. according to the method described in claim 2, it is characterized in that, the preparation method of the resin adsorption carrier includes following step
It is rapid:
The methylene blue that 10wt% methanol and 2wt% are added into the sodium acetate aqueous solution that concentration is 1M, stirs evenly, is heated to 50
DEG C, the organic solution of same volume is then added, is reacted, is warming up to 65 DEG C, is stirred to react 12h under heat-retaining condition, obtains
Sphere is collected by filtration in sphere, and then addition accounts for the vinyltriethoxysilane of sphere 5wt%, 100rpm stirring
3min, then the nano-silicon rubber powder for accounting for sphere 10wt% is added, continue to stir 5min with 100rpm, is subsequently placed in 80 DEG C of baking oven
Middle dry 30min, take out, cooled to room temperature to get.
5. according to the method described in claim 2, it is characterized in that, the preparation method of the composite bacteria liquid includes the following steps:
Micrococcus luteus is inoculated into seed culture medium by step 1), and 30 DEG C of culture viable counts into product reach 2.0 × 108cfu/
Ml is to get micrococcus luteus seed liquor；
Achromobacter xylosoxidans are inoculated into seed culture medium by step 2, and 28 DEG C of culture viable counts into product reach 1.0 ×
108Cfu/ml is to get Achromobacter xylosoxidans seed liquor；
Acidithiobacillus ferrooxidans strain GF is inoculated into seed culture medium by step 3), and 28 DEG C of culture viable counts into bacterium solution reach 5.0
×108Cfu/ml is to get Acidithiobacillus ferrooxidans strain GF seed liquor；
Step 4) is by micrococcus luteus seed liquor, Achromobacter xylosoxidans seed liquor and Acidithiobacillus ferrooxidans strain GF seed
Liquid according to 3-5:2-3:5-7 volume ratio mix to get.
6. according to the method described in claim 4, it is characterized in that, the organic solution by vinylacetate, divinylbenzene,
Butyl acetate and benzoyl peroxide are mixed according to mass ratio 5:1:8:2.
7. according to the method described in claim 5, it is characterized in that, in the step 1), the component of seed culture medium are as follows: yeast
Cream 5g/L, (NH4)2SO42g/L g, glucose 3g/L, K2HPO40.5g/L, KH2PO4 0.5g/L。
8. according to the method described in claim 5, it is characterized in that, in the step 2, seed culture based component are as follows: urea
1.0g/L, CH3COONa 3.0g/L, MgC12 0.1g/L, CaC120.1g/L, KH2 PO40.5g/L, K2 HPO4 0.5g/L。
9. according to the method described in claim 5, it is characterized in that, in the step 3), seed culture medium component are as follows: (NH4)2SO42g/L, KCl 0.1g/L, K2HPO40.5g/L, KH2PO40.5g/L, Ca (NO3)20.01g/L, FeSO4·7H2O
10g/L。
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110499262A (en) * | 2018-05-17 | 2019-11-26 | 卢松 | Purification absorbs the compound of slurry-spraying pelletizing flue gas |
| CN113274833A (en) * | 2021-04-18 | 2021-08-20 | 呼伦贝尔东北阜丰生物科技有限公司 | Flue gas treatment and waste heat recovery process |
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