CN106932340A - Optical detection system based on integrating sphere - Google Patents

Optical detection system based on integrating sphere Download PDF

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Publication number
CN106932340A
CN106932340A CN201511026936.2A CN201511026936A CN106932340A CN 106932340 A CN106932340 A CN 106932340A CN 201511026936 A CN201511026936 A CN 201511026936A CN 106932340 A CN106932340 A CN 106932340A
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sample
integrating sphere
light
hole
smooth
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CN201511026936.2A
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CN106932340B (en
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池田英柱
孙胜胜
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Shimadzu Corp
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Shimadzu Corp
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/01Arrangements or apparatus for facilitating the optical investigation

Abstract

The present invention relates to instrument and meter industry analysis meter survey technology field, a kind of optical detection system based on integrating sphere is disclosed.Optical detection system based on integrating sphere of the invention includes the first spectrophotometer, first integral ball and the first attenuator;First spectrophotometer includes the first photodetector and the second photodetector;In the first detection light path of optical detection system, sample light is entered in first integral ball via after sample transmission or reflection by the first smooth through hole of first integral ball, and by the second smooth through hole outgoing and enters the first photodetector after the inner surface diffusing reflection by first integral ball;In the second detection light path of optical detection system, reference light enters the second photodetector after decaying via the first attenuator.The detecting system improves the signal detecting mode of existing integrating sphere product, simplifies and has fallen the original detection circuit of integrating sphere itself, reduces integrating sphere cost, and it can be made preferably to complete and the effect that detection sample is engaged between spectrophotometer.

Description

Optical detection system based on integrating sphere
Technical field
The present invention relates to instrument and meter industry analysis meter survey technology field, more particularly, to a kind of light inspection based on integrating sphere Examining system.
Background technology
Current integrating sphere product, when coordinating test with the instrument such as spectrophotometer, the detector carried using integrating sphere is carried out Signal detection.As shown in figure 1, when being detected to sample, the sample light A and not of sample or sample reflection is will transmit through Contrasted after the reference light B of sample transmission or reflection carries out diffusing reflection in integrating sphere, drawn the test result of sample. Wherein, in the detection light path of transmission sample light, after sample light A reflects via speculum (speculum 1 and 2), pass through Ocean flat 9 enters in integrating sphere 3, after being integrated the inwall diffusing reflection of ball 3, is integrated the detector 8 inside ball 3 and receives, together When, in the detection light path of reference light, reference light is reflected into integrating sphere 3 via speculum 7, is then detected by device 8 Receive.The method of testing of sample reflected sample light is similar with the method for testing of sample transmission sample light, for example, in sample light In detection light path, sample light cuts across integrating sphere 3 after speculum 1 and 2 reflects, and reaches the surface of sample 10, quilt Sample 10 enters in integrating sphere 3 after launching, and is connect by the detector 8 inside integrating sphere 3 after being integrated the inwall diffusing reflection of ball 3 Receive.Additionally, in order to tackle wider range wavelength (such as:185nm~3300nm) signal detection, integrating sphere will also Using various detectors for carrying, the waste of the complicated and cost of structure is caused.
The content of the invention
In order to solve the above problems, the invention discloses a kind of optical detection system based on integrating sphere, using spectrophotometric The signal detector of itself is counted to detect by the sample signal of integrating sphere and through the reference signal after overdamping balance.
In order to solve the above technical problems, embodiments of the present invention disclose a kind of optical detection system based on integrating sphere, including First spectrophotometer, first integral ball and the first attenuator;
First spectrophotometer includes the first photodetector and the second photodetector;
First integral ball scribbles the hollow spheres of diffuse-reflective material for inwall, and the first integral ball includes the first smooth through hole and second Light through hole;
Optical detection system first detection light path on, sample light via after sample transmission or reflection by the first of first integral ball Light through hole enters in first integral ball, and by the second smooth through hole outgoing and enters after the inner surface diffusing reflection by first integral ball First photodetector;In the second detection light path of optical detection system, reference light enters second after decaying via the first attenuator Photodetector.
The signal detecting mode of existing integrating sphere product is improved, the spectrophotometer itself commonly used when being measured using integrating sphere Signal detector, the reference light after detecting by the sample light of integrating sphere and being balanced through overdamping, so as to simplify fall integrating sphere Itself original detection circuit, reduces integrating sphere cost, and it can be made preferably to complete to be engaged between spectrophotometer Detect the effect of sample.
In a preference, the first attenuator is equal to enter without sample transmission or the sample light of reflection to the attenuation ratio of reference light Enter the attenuation ratio that the inner surface of first integral ball carries out before and after diffusing reflection.
Because the integrating sphere after simplification is without detection circuit, when measuring, during reference light is not further into integrating sphere, In order to ensure the accuracy of measurement result, it is necessary to reference light is decayed, so that itself and the decay for assuming to enter after integrating sphere Ratio is identical, even if its decay with the sample light without sample transmission or reflection before and after diffusing reflection is carried out into integrating sphere Ratio is identical, so that when the sample light when attenuation ratio of the first attenuator is reference light and blank sample carries out energy balance The attenuation ratio of determination.
In another preference, the optical detection system based on integrating sphere also includes at least one speculum;Light path is detected first On, sample light reaches sample after being reflected via speculum.
Sample light can be made to be focused at the sample of detection using speculum, energy loss is reduced.
In another preference, the optical detection system based on integrating sphere includes the first speculum and the second speculum, in the first inspection On light-metering road, sample light reaches sample after being reflected via the first speculum and the second speculum successively.
Embodiments of the present invention also disclose a kind of optical detection system based on integrating sphere, it is characterised in that the second light splitting light Degree meter, second integral ball and the second attenuator;
Second spectrophotometer includes the 3rd photodetector and the 4th photodetector;
Second integral ball scribbles the hollow spheres of diffuse-reflective material for inwall, and the second integral ball includes the 3rd smooth through hole, the 4th Light through hole and the 5th smooth through hole;
In the 3rd detection light path of optical detection system, sample light passes sequentially through the 3rd smooth through hole and the 4th smooth through hole is passed straight through Second integral ball reaches sample, enters in second integral ball after being reflected by sample, and unrestrained anti-by the inner surface of second integral ball By the 5th smooth through hole outgoing and the 3rd photodetector of entrance after penetrating;In the 4th detection light path of optical detection system, reference light warp Enter the 4th photodetector after being decayed by the second attenuator.
The signal detecting mode of existing integrating sphere product is improved, the spectrophotometer itself commonly used when being measured using integrating sphere Signal detector, the reference light after detecting by the sample light of integrating sphere and being balanced through overdamping, so as to simplify fall integrating sphere Itself original detection circuit, reduces integrating sphere cost, and it can be made preferably to complete to be engaged between spectrophotometer Detect the effect of sample.
In a preference, in the 3rd detection light path, sample light enters second integral after being reflected by sample by the 4th smooth through hole In ball.
In another preference, second integral ball includes the 6th smooth through hole;
In the 3rd detection light path, sample light is entered in second integral ball after being reflected by sample by the 6th smooth through hole.
In another preference, the second attenuator is equal to the sample light without sample reflection to the attenuation ratio of reference light and enters the The inner surface of two integrating spheres carries out the attenuation ratio before and after diffusing reflection.
Because the integrating sphere after simplification is without detection circuit, when measuring, during reference light is not further into integrating sphere, In order to ensure the accuracy of measurement result, it is necessary to reference light is decayed, so that itself and the decay for assuming to enter after integrating sphere Ratio is identical, even if its decay with the sample light without sample transmission or reflection before and after diffusing reflection is carried out into integrating sphere Ratio is identical, so that when the sample light when attenuation ratio of the second attenuator is reference light and blank sample carries out energy balance The attenuation ratio of determination.
In another preference, the optical detection system based on integrating sphere also includes at least one speculum;Light path is detected the 3rd On, sample light is entered in second integral ball after being reflected via speculum by the 3rd smooth through hole.
Sample light can be made to be focused at the sample of detection using speculum, energy loss is reduced.
In another preference, the optical detection system based on integrating sphere includes the 3rd speculum and the 4th speculum, in the 3rd inspection On light-metering road, sample light enters second integral ball after being reflected via the 3rd speculum and the 4th speculum successively by the 3rd smooth through hole It is interior.
Brief description of the drawings
Fig. 1 is the structural representation of the light measurement system based on integrating sphere in the prior art;
Fig. 2 is the structural representation of the light measurement system based on integrating sphere of first embodiment of the invention;
Fig. 3 is the structural representation of the light measurement system based on integrating sphere of second embodiment of the invention.
Specific embodiment
In the following description, in order that reader more fully understands the present invention and proposes many ins and outs.But, ability Even if the those of ordinary skill in domain be appreciated that many variations without these ins and outs and based on following implementation method and Modification, it is also possible to realize each claim technical scheme required for protection of the invention.
To make the object, technical solutions and advantages of the present invention clearer, below in conjunction with accompanying drawing to embodiments of the present invention It is described in further detail.In the record of the following drawings, same or similar reference indicates same or similar Part and component, and be possible to omit the description.
First embodiment of the invention is related to a kind of optical detection system based on integrating sphere.Fig. 2 is the light that this is based on integrating sphere The structural representation of detecting system.
Specifically, as shown in Fig. 2 the optical detection system that should be based on integrating sphere includes the first spectrophotometer, first integral The attenuator 4 of ball 3 and first;First spectrophotometer includes the first photodetector 5 and the second photodetector 6;First integral Ball 3 scribbles the hollow spheres of diffuse-reflective material (such as diffusive white reflective material magnesia or barium sulfate) for inwall, and this first Integrating sphere includes the first smooth through hole and the second smooth through hole (not shown);In the first detection light path of optical detection system, sample Light A to be transmitted via sample 9 and enter the by the first smooth through hole of first integral ball 3 after (or reflection, reflected light path not shown) In one integrating sphere, and by the second smooth through hole outgoing and enter the first photodetector after the inner surface diffusing reflection by first integral ball 5, in the specific implementation, can be by the second smooth through hole close proximity to the first photodetector 5, to increase the intensity of detection signal; In second detection light path of optical detection system, reference light enters the second photodetector 6 after decaying via the first attenuator 4.The One attenuator 4 is equal to the sample light A without sample transmission or reflection and enters in first integral ball to the attenuation ratio of reference light Surface carries out the attenuation ratio before and after diffusing reflection.
Because the integrating sphere after simplification is without detection circuit, when measuring, during reference light is not further into integrating sphere, In order to ensure the accuracy of measurement result, it is necessary to reference light is decayed, so that itself and the decay for assuming to enter after integrating sphere Ratio is identical, even if its decay with the sample light without sample transmission or reflection before and after diffusing reflection is carried out into integrating sphere Ratio is identical, so that when the sample light when attenuation ratio of the first attenuator is reference light and blank sample carries out energy balance The attenuation ratio of determination.
Sample light can be made to be focused at the sample of detection using speculum, energy loss is reduced.Therefore, in a preference, Optical detection system based on integrating sphere also includes at least one speculum;In the first detection light path, sample light is via speculum Sample is reached after reflection.
The setting of speculum can as the case may be depending on, be not limited herein, for example, in a preference, such as Fig. 2 institutes Show, the optical detection system based on integrating sphere includes the first speculum 1 and the second speculum 2, in the first detection light path, sample Product light A reaches sample 9 after being reflected via the first speculum 1 and the second speculum 2 successively.
Furthermore, it is to be understood that in the embodiments of the present invention, light through hole is sample light or reference light turnover integrating sphere Through hole, concrete shape is not limited.For example, it may be a window of single hole, or multiple aperture compositions.
The present invention improves the signal detecting mode of existing integrating sphere product, the spectrophotometer commonly used when being measured using integrating sphere The signal detector of itself, the reference light after detecting by the sample light of integrating sphere and being balanced through overdamping, so as to simplify The original detection circuit of integrating sphere itself, reduces integrating sphere cost, and it can be made preferably to complete and spectrophotometer between It is engaged the effect of detection sample.
The specific detection process of the present embodiment is as follows:
When specifically used, first integral ball 3 is placed in spectrophotometer sample room, in the environment of complete shading, with declining Subtract the sample signal and reference signal (i.e. sample light and reference light) under the balance blank sample state of device 4.Then test sample will be treated Before product 9 are placed in the entrance of first integral ball 3 (the i.e. first smooth through hole), by the detector (i.e. first of spectrophotometer itself Photodetector 5), the reference signal after detection sample signal, with balance is compared, and finally draws test data.
Second embodiment of the present invention discloses a kind of optical detection system based on integrating sphere.Fig. 3 is that this is based on integrating sphere The structural representation of optical detection system.
Specifically, as shown in figure 3, the optical detection system that should be based on integrating sphere includes the second spectrophotometer, second integral Ball 3 ' and the second attenuator 4 ';Second spectrophotometer includes the 3rd photodetector 5 ' and the 4th photodetector 6 ';Second integral Ball 3 ' scribbles the hollow spheres of diffuse-reflective material for inwall, the second integral ball 3 ' include the 3rd smooth through hole, the 4th smooth through hole and 5th smooth through hole (not shown);In the 3rd detection light path of optical detection system, sample light A ' passes sequentially through the 3rd smooth through hole Second integral ball is passed straight through with the 4th smooth through hole reach sample 10, it is interior into second integral ball 3 ' after being reflected by sample 10, And by the 5th smooth through hole outgoing and enter the 3rd photodetector 5 ' after the inner surface diffusing reflection by second integral ball 3 ', specific During implementation, can be by the second smooth through hole close proximity to the 3rd photodetector 5 ', to increase the intensity of detection signal;Detected in light and be In 4th detection light path of system, reference light enters the 4th photodetector 6 ' after decaying via the second attenuator 4 '.Second attenuator 4 ' are equal to before the sample light without sample reflection carries out diffusing reflection into the inner surface of second integral ball to the attenuation ratio of reference light Attenuation ratio afterwards.
Because the integrating sphere after simplification is without detection circuit, when measuring, during reference light is not further into integrating sphere, In order to ensure the accuracy of measurement result, it is necessary to reference light is decayed, so that itself and the decay for assuming to enter after integrating sphere Ratio is identical, even if its decay with the sample light without sample transmission or reflection before and after diffusing reflection is carried out into integrating sphere Ratio is identical, so that when the sample light when attenuation ratio of the second attenuator is reference light and blank sample carries out energy balance The attenuation ratio of determination.
In the present invention, the sample light after being launched by sample 10 can back into second integral ball 3 ' by the 4th smooth through hole It is interior, it is also possible to carry out diffusing reflection into second integral ball 3 ' is interior from other light through holes.For example, in a preference, the 3rd In detection light path, sample light is entered in second integral ball after being reflected by sample by the 4th smooth through hole.And in another preference, Second integral ball includes the 6th smooth through hole (not shown);The 3rd detection light path on, sample light reflected by sample after by the 6th Light through hole enters in second integral ball.
Sample light can be made to be focused at the sample of detection using speculum, energy loss is reduced.Therefore, in a preference, Optical detection system based on integrating sphere also includes at least one speculum;In the 3rd detection light path, sample light is via speculum Entered in second integral ball by the 3rd smooth through hole after reflection.
The setting of speculum can as the case may be depending on, be not limited herein, for example, in a preference, based on integration The optical detection system of ball includes the 3rd speculum 1 ' and the 4th speculum 2 ', and in the 3rd detection light path, sample light A is passed through successively It is interior into second integral ball 3 ' by the 3rd smooth through hole after being reflected by the 3rd speculum 1 ' and four speculum 2 '.
The signal detecting mode of existing integrating sphere product is improved, the spectrophotometer itself commonly used when being measured using integrating sphere Signal detector, the reference light after detecting by the sample light of integrating sphere and being balanced through overdamping, so as to simplify fall integrating sphere Itself original detection circuit, reduces integrating sphere cost, and it can be made preferably to complete to be engaged between spectrophotometer Detect the effect of sample.
It should be noted that in the claim and specification of this patent, such as first and second or the like relational terms It is used merely to make a distinction an entity or operation with another entity or operation, and not necessarily requires or imply these There is any this actual relation or order between entity or operation.And, term " including ", "comprising" or its is any Other variants are intended to including for nonexcludability, so that process, method, article including a series of key elements or setting It is standby not only to include those key elements, but also other key elements including being not expressly set out, or also include for this process, Method, article or the intrinsic key element of equipment.In the absence of more restrictions, limited by sentence " including " Key element, it is not excluded that also there is other identical element in the process including the key element, method, article or equipment.
Although by referring to some of the preferred embodiment of the invention, being shown and described to the present invention, ability The those of ordinary skill in domain should be understood that can to it, various changes can be made in the form and details, without departing from of the invention Spirit and scope.

Claims (10)

1. a kind of optical detection system based on integrating sphere, it is characterised in that including the first spectrophotometer, first integral ball and First attenuator;
First spectrophotometer includes the first photodetector and the second photodetector;
The first integral ball scribbles the hollow spheres of diffuse-reflective material for inwall, the first integral ball include the first smooth through hole and Second smooth through hole;
The optical detection system first detection light path on, sample light via after sample transmission or reflection by the first integral First smooth through hole of ball enters in the first integral ball, and by described after by the inner surface diffusing reflection of the first integral ball Second smooth through hole outgoing simultaneously enters the first photodetector;The optical detection system second detection light path on, reference light via Enter the second photodetector after the first attenuator decay.
2. the optical detection system of integrating sphere, attenuation ratio of first attenuator to reference light are based on as claimed in claim 1 Example carries out the attenuation ratio before and after diffusing reflection equal to the sample light without sample transmission or reflection into the inner surface of first integral ball Example.
3. the optical detection system of integrating sphere is based on as claimed in claim 1 or 2, it is characterised in that also including at least one Speculum;In the described first detection light path, the sample light reaches the sample after being reflected via the speculum.
4. the optical detection system based on integrating sphere as claimed in claim 3, it is characterised in that including the first speculum and the Two-mirror, in the described first detection light path, the sample light is anti-via first speculum and the second speculum successively The sample is reached after penetrating.
5. a kind of optical detection system based on integrating sphere, it is characterised in that including the second spectrophotometer, second integral ball and Second attenuator;
Second spectrophotometer includes the 3rd photodetector and the 4th photodetector;
The second integral ball scribbles the hollow spheres of diffuse-reflective material for inwall, the second integral ball include the 3rd smooth through hole, 4th smooth through hole and the 5th smooth through hole;
In the 3rd detection light path of the optical detection system, sample light passes sequentially through the 3rd smooth through hole and the 4th smooth through hole Pass straight through the second integral ball and reach sample, enter in the second integral ball after being reflected by the sample, and by institute State after the inner surface diffusing reflection of second integral ball by the described 5th smooth through hole outgoing and enter the 3rd photodetector;In light inspection In 4th detection light path of examining system, reference light enters the 4th photodetector after decaying via second attenuator.
6. the optical detection system of integrating sphere is based on as claimed in claim 5, it is characterised in that detect light path the described 3rd On, the sample light is entered in the second integral ball after being reflected by the sample by the 4th smooth through hole.
7. the optical detection system of integrating sphere is based on as claimed in claim 5, it is characterised in that the second integral ball includes 6th smooth through hole;
In the described 3rd detection light path, the sample light enters described the after being reflected by the sample by the 6th smooth through hole In two integrating spheres.
8. the optical detection system based on integrating sphere as any one of claim 5 to 7, it is characterised in that described Two attenuators are equal to the sample light without sample reflection and are carried out into the inner surface of second integral ball to the attenuation ratio of reference light Attenuation ratio before and after diffusing reflection.
9. the optical detection system based on integrating sphere as any one of claim 5 to 7, it is characterised in that also include At least one speculum;The described 3rd detection light path on, the sample light via the speculum reflect after by the described 3rd Light through hole enters in the second integral ball.
10. the optical detection system based on integrating sphere as claimed in claim 9, it is characterised in that including the 3rd speculum and 4th speculum, in the described 3rd detection light path, the sample light is successively via the 3rd speculum and the 4th speculum Entered in the second integral ball by the 3rd smooth through hole after reflection.
CN201511026936.2A 2015-12-31 2015-12-31 Light detection system based on integrating sphere Active CN106932340B (en)

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