ZA200504872B - Waterbased heatset offset ink compositions - Google Patents
Waterbased heatset offset ink compositions Download PDFInfo
- Publication number
- ZA200504872B ZA200504872B ZA200504872A ZA200504872A ZA200504872B ZA 200504872 B ZA200504872 B ZA 200504872B ZA 200504872 A ZA200504872 A ZA 200504872A ZA 200504872 A ZA200504872 A ZA 200504872A ZA 200504872 B ZA200504872 B ZA 200504872B
- Authority
- ZA
- South Africa
- Prior art keywords
- pigment
- ink
- present
- amount
- water
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title description 27
- 239000000049 pigment Substances 0.000 claims description 59
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 43
- 239000011347 resin Substances 0.000 claims description 22
- 229920005989 resin Polymers 0.000 claims description 22
- 238000007639 printing Methods 0.000 claims description 21
- HBAIZGPCSAAFSU-UHFFFAOYSA-N 1-(2-hydroxyethyl)imidazolidin-2-one Chemical compound OCCN1CCNC1=O HBAIZGPCSAAFSU-UHFFFAOYSA-N 0.000 claims description 19
- GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical class NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 claims description 16
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 16
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 16
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 16
- 239000000944 linseed oil Substances 0.000 claims description 15
- 235000021388 linseed oil Nutrition 0.000 claims description 14
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 10
- 229920006122 polyamide resin Polymers 0.000 claims description 8
- 235000012544 Viola sororia Nutrition 0.000 claims description 3
- 241001106476 Violaceae Species 0.000 claims description 3
- 235000021384 green leafy vegetables Nutrition 0.000 claims description 3
- 240000006240 Linum usitatissimum Species 0.000 claims description 2
- 235000004431 Linum usitatissimum Nutrition 0.000 claims description 2
- 235000004426 flaxseed Nutrition 0.000 claims description 2
- 239000000976 ink Substances 0.000 description 64
- 239000011230 binding agent Substances 0.000 description 10
- 238000000034 method Methods 0.000 description 9
- 238000007645 offset printing Methods 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 238000009998 heat setting Methods 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000012855 volatile organic compound Substances 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 125000005396 acrylic acid ester group Chemical group 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 239000003906 humectant Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000000643 oven drying Methods 0.000 description 2
- 239000003209 petroleum derivative Substances 0.000 description 2
- 239000010695 polyglycol Substances 0.000 description 2
- 229920000151 polyglycol Polymers 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- 244000201986 Cassia tora Species 0.000 description 1
- 229940090898 Desensitizer Drugs 0.000 description 1
- 239000004908 Emulsion polymer Substances 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- -1 glycol ethers Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- UWZUWNMEIDBHOF-DPMBMXLASA-M lithium;(z,12r)-12-hydroxyoctadec-9-enoate Chemical compound [Li+].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O UWZUWNMEIDBHOF-DPMBMXLASA-M 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- NCAIGTHBQTXTLR-UHFFFAOYSA-N phentermine hydrochloride Chemical compound [Cl-].CC(C)([NH3+])CC1=CC=CC=C1 NCAIGTHBQTXTLR-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000172 poly(styrenesulfonic acid) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229940005642 polystyrene sulfonic acid Drugs 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 238000010020 roller printing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229920005792 styrene-acrylic resin Polymers 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/08—Printing inks based on natural resins
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/323,284 US6709503B1 (en) | 2002-12-19 | 2002-12-19 | Waterbased heatset offset ink compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200504872B true ZA200504872B (en) | 2006-04-26 |
Family
ID=31978092
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200504872A ZA200504872B (en) | 2002-12-19 | 2005-06-14 | Waterbased heatset offset ink compositions |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6709503B1 (zh) |
| EP (1) | EP1585794A1 (zh) |
| JP (1) | JP5285831B2 (zh) |
| CN (1) | CN1321161C (zh) |
| AU (1) | AU2003297215A1 (zh) |
| BR (1) | BR0316907A (zh) |
| CA (1) | CA2510867A1 (zh) |
| WO (1) | WO2004058904A1 (zh) |
| ZA (1) | ZA200504872B (zh) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050083048A1 (en) * | 2003-10-21 | 2005-04-21 | Applied Materials, Inc. | Plating system with integrated substrate inspection |
| ATE399824T1 (de) | 2004-06-03 | 2008-07-15 | Sun Chemical B V Nl | Nichtwellende hitzehärtende tintenzusammensetzung |
| JP4687186B2 (ja) * | 2005-03-29 | 2011-05-25 | Ｄｉｃ株式会社 | ジオキサジンバイオレット顔料組成物 |
| JP4687185B2 (ja) * | 2005-03-29 | 2011-05-25 | Ｄｉｃ株式会社 | ジオキサジンバイオレット粗顔料組成物及びそれを用いたジオキサジンバイオレット顔料組成物の製造方法 |
| US20060252914A1 (en) * | 2005-05-03 | 2006-11-09 | Czebotar Martin T | Modified rosin ester for water borne heatset weboffset inks |
| JP4923577B2 (ja) * | 2005-11-29 | 2012-04-25 | 東洋インキＳｃホールディングス株式会社 | 水性平版印刷インキならびに印刷物 |
| US7429292B2 (en) * | 2006-06-15 | 2008-09-30 | Sun Chemical Corporation | Water washable lithographic printing ink |
| US20080009573A1 (en) * | 2006-07-10 | 2008-01-10 | Ching Wah Chong | Labeled tackifiers |
| CA2666432A1 (en) * | 2006-10-13 | 2008-04-24 | Sun Chemical Corporation | Stable offset emulsion inks containing non-water soluble polymeric surfactants |
| CN101547979B (zh) * | 2006-10-13 | 2013-04-17 | 太阳化学公司 | 非水溶性聚合物表面活性剂 |
| US8013034B2 (en) * | 2006-11-03 | 2011-09-06 | Sun Chemical Corporation | Stable offset emulsion inks containing water tolerant emulsion stabilizer |
| JP5309463B2 (ja) * | 2007-03-30 | 2013-10-09 | 東洋インキＳｃホールディングス株式会社 | 平版インキ印刷方法、インキセットならびに印刷物 |
| FI123126B (fi) * | 2007-04-25 | 2012-11-15 | Upm Kymmene Oyj | Paperi ja menetelmä paperin valmistamiseksi |
| US20090214790A1 (en) * | 2008-02-25 | 2009-08-27 | Stephen Simpson | Method of making an ink-printed fibrous web |
| US8163038B2 (en) | 2010-03-03 | 2012-04-24 | Superior Printing Ink Co., Inc. | Low volatile sublimation printing |
| US8425675B2 (en) * | 2010-06-09 | 2013-04-23 | Dong-A Teaching Materials Co., Ltd. | Recrystallization type of ink composition |
| US20140230689A1 (en) * | 2011-08-25 | 2014-08-21 | Meadwestvaco Corporation | Vegetable oil-based metal resinate compositions and materials comprising same |
| US10150878B2 (en) | 2012-10-15 | 2018-12-11 | Sun Chemical Corporation | Pigment dispersions and printing inks with improved coloristic properties |
| JP2015151481A (ja) * | 2014-02-17 | 2015-08-24 | 株式会社ティ−アンドケイ東華 | 低臭インキ |
Family Cites Families (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3356030A (en) | 1964-04-30 | 1967-12-05 | Interchem Corp | Planographic printing method |
| US3877372A (en) | 1973-12-03 | 1975-04-15 | Kenneth W Leeds | Treatment of a printing plate with a dampening liquid |
| DE2500500B2 (de) | 1975-01-08 | 1979-10-18 | Alkor Gmbh Kunststoffverkauf, 8000 Muenchen | Verfahren zum Bedrucken von Kunststoffbahnen |
| US4196033A (en) * | 1977-03-08 | 1980-04-01 | Dai Nippon Insatsu Kabushiki Kaisha | Process for producing decorative sheets |
| US4079026A (en) | 1977-06-20 | 1978-03-14 | Hercules Incorporated | Printing inks and process for using the same |
| US4173554A (en) | 1978-07-10 | 1979-11-06 | Sun Chemical Corporation | Aqueous printing inks with improved transfer properties |
| US4278467A (en) | 1978-09-11 | 1981-07-14 | Graphic Arts Technical Foundation | Substitutive additives for isopropyl alcohol in fountain solution for lithographic offset printing |
| DE3276471D1 (en) | 1981-10-10 | 1987-07-09 | Basf Lacke & Farben | Flat-bed printing method |
| US4419132A (en) | 1982-01-06 | 1983-12-06 | American Newspaper Publishers Association | Printing ink |
| DE3365843D1 (en) | 1982-06-04 | 1986-10-09 | Ciba Geigy Ag | Aqueous inks for transfer printing |
| US4854969A (en) | 1986-07-02 | 1989-08-08 | Sun Chemical Corporation | Lithographic fountain solutions |
| EP0302450B2 (en) | 1987-08-03 | 1997-03-05 | Mitsubishi Paper Mills, Ltd. | Lithographic printing ink additive |
| US4954556A (en) | 1987-11-23 | 1990-09-04 | Ppg Industries, Inc. | Water-based ink compositions |
| USRE34389E (en) | 1988-04-27 | 1993-09-28 | Sicpa Holding Sa | Security document printing ink |
| US5039339A (en) | 1988-07-28 | 1991-08-13 | Eastman Kodak Company | Ink composition containing a blend of a polyester and an acrylic polymer |
| EP0360212A3 (en) | 1988-09-19 | 1992-01-08 | BASF Corporation | Fast drying water inks |
| US4908063A (en) | 1988-11-04 | 1990-03-13 | Petrolite Corporation | Additive composition for water-based inks |
| US5167704A (en) | 1989-11-20 | 1992-12-01 | Brower Sharen E | Soy ink based art media |
| US5189089A (en) | 1990-08-31 | 1993-02-23 | Union Camp Corporation | Resinous binders having improved dilution |
| US5098478A (en) | 1990-12-07 | 1992-03-24 | Sun Chemical Corporation | Water-based ink compositions |
| DE4119348A1 (de) | 1991-06-12 | 1992-12-17 | Leipzig Tech Hochschule | Offsetdruckverfahren und druckfarbe |
| BR9206346A (pt) | 1991-08-09 | 1995-04-11 | Minnesota Mining & Mfg | Composição química à base de água, e, processo de impressão em tela. |
| CN1035329C (zh) * | 1992-12-25 | 1997-07-02 | 黎光 | 水溶性印刷油墨及其生产方法 |
| US5389130A (en) | 1993-06-25 | 1995-02-14 | Milliken Research Corporation | Printing ink emulsion having reduced VOC |
| US5429841A (en) | 1993-06-25 | 1995-07-04 | Milliken Research Corporation | Printing ink emulsion with poly(oxyalkylene) substituted colorant |
| US5367005A (en) | 1993-10-29 | 1994-11-22 | Sun Chemical Corporation | Heatset security ink |
| US5370906A (en) | 1993-11-02 | 1994-12-06 | Dankert; Fred | Waterless planographic plates |
| US5417749A (en) | 1994-03-29 | 1995-05-23 | Sun Chemical Corporation | Microemulsion printing ink |
| CA2156005A1 (en) | 1994-08-16 | 1996-02-17 | John W. Bird | Multiple color offset press utilizing aqueous ink and waterless printing plates with interstation drying and extraction |
| JPH08100142A (ja) | 1994-09-29 | 1996-04-16 | Riso Kagaku Corp | 孔版印刷用エマルジョンインク |
| US5694848A (en) | 1996-03-13 | 1997-12-09 | Heidelberger Druckmaschinen Ag | Printing unit for water based inks |
| US20020083865A1 (en) * | 1996-03-13 | 2002-07-04 | Ramasamy Krishnan | Water-based offset lithographic printing inks containing polymerizable surfactants |
| US5725646A (en) | 1996-03-13 | 1998-03-10 | Sun Chemical Corporation | Water-based offset lithographic printing ink |
| US5972088A (en) * | 1996-03-13 | 1999-10-26 | Sun Chemical Corporation | Water-based gravure printing ink |
| US5778789A (en) * | 1996-03-13 | 1998-07-14 | Sun Chemical | Offset lithographic printing process with a water based ink |
| EP0814136B1 (en) | 1996-06-17 | 2001-11-21 | Westvaco Corporation | Acrylic resins as binders for gravure inks |
| US6019829A (en) * | 1996-10-31 | 2000-02-01 | Mitsubishi Chemical Corporation | Carbon black aggregate |
| JP3261695B2 (ja) * | 1997-12-26 | 2002-03-04 | 日本製紙株式会社 | 硬化型バインダー樹脂組成物とその用途 |
| JP2000212489A (ja) * | 1999-01-28 | 2000-08-02 | Pilot Ink Co Ltd | 熱変色性ドライオフセットインキ及びそれを用いた印刷物 |
| JP2001031889A (ja) * | 1999-07-19 | 2001-02-06 | Matsui Kagaku Kk | 焼き付け用組成物 |
| US6444021B1 (en) | 2000-05-19 | 2002-09-03 | Sun Chemical Corporation | Water washable lithographic newspaper printing ink |
| US6444022B1 (en) | 2000-05-20 | 2002-09-03 | Sun Chemical Corporation | Water based offset lithographic printing ink |
| JP2002265838A (ja) * | 2001-02-28 | 2002-09-18 | Sun Chemical Corp | 水性のオフセットリソグラフィー新聞印刷用インク |
-
2002
- 2002-12-19 US US10/323,284 patent/US6709503B1/en not_active Expired - Lifetime
-
2003
- 2003-12-16 CN CNB2003801068957A patent/CN1321161C/zh not_active Expired - Fee Related
- 2003-12-16 CA CA002510867A patent/CA2510867A1/en not_active Abandoned
- 2003-12-16 AU AU2003297215A patent/AU2003297215A1/en not_active Abandoned
- 2003-12-16 WO PCT/US2003/040109 patent/WO2004058904A1/en not_active Application Discontinuation
- 2003-12-16 EP EP03814064A patent/EP1585794A1/en not_active Withdrawn
- 2003-12-16 JP JP2004563635A patent/JP5285831B2/ja not_active Expired - Fee Related
- 2003-12-16 BR BR0316907-3A patent/BR0316907A/pt not_active IP Right Cessation
-
2005
- 2005-06-14 ZA ZA200504872A patent/ZA200504872B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP1585794A1 (en) | 2005-10-19 |
| CA2510867A1 (en) | 2004-07-15 |
| CN1321161C (zh) | 2007-06-13 |
| JP2006511642A (ja) | 2006-04-06 |
| CN1729259A (zh) | 2006-02-01 |
| WO2004058904A1 (en) | 2004-07-15 |
| JP5285831B2 (ja) | 2013-09-11 |
| US6709503B1 (en) | 2004-03-23 |
| BR0316907A (pt) | 2005-10-18 |
| AU2003297215A1 (en) | 2004-07-22 |
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