ZA200300680B - Processing elemental sulfur-bearing materials using high temperature pressure leaching for sulfuric acid production and metal recovery. - Google Patents
Processing elemental sulfur-bearing materials using high temperature pressure leaching for sulfuric acid production and metal recovery. Download PDFInfo
- Publication number
- ZA200300680B ZA200300680B ZA200300680A ZA200300680A ZA200300680B ZA 200300680 B ZA200300680 B ZA 200300680B ZA 200300680 A ZA200300680 A ZA 200300680A ZA 200300680 A ZA200300680 A ZA 200300680A ZA 200300680 B ZA200300680 B ZA 200300680B
- Authority
- ZA
- South Africa
- Prior art keywords
- pressure leaching
- temperature
- sulfuric acid
- sulfur
- pressure
- Prior art date
Links
- 238000002386 leaching Methods 0.000 title claims description 99
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims description 90
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 title claims description 76
- 239000000463 material Substances 0.000 title claims description 68
- 229910052751 metal Inorganic materials 0.000 title claims description 42
- 239000002184 metal Substances 0.000 title claims description 42
- 238000012545 processing Methods 0.000 title claims description 36
- 238000011084 recovery Methods 0.000 title claims description 29
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- 238000000034 method Methods 0.000 claims description 65
- 229910052717 sulfur Inorganic materials 0.000 claims description 57
- 239000011593 sulfur Substances 0.000 claims description 56
- 239000002002 slurry Substances 0.000 claims description 41
- 239000007787 solid Substances 0.000 claims description 23
- 239000002270 dispersing agent Substances 0.000 claims description 20
- 239000010970 precious metal Substances 0.000 claims description 20
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 18
- 239000001301 oxygen Substances 0.000 claims description 18
- 229910052760 oxygen Inorganic materials 0.000 claims description 18
- 239000004576 sand Substances 0.000 claims description 11
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 8
- 239000011707 mineral Substances 0.000 claims description 8
- 239000012530 fluid Substances 0.000 claims description 4
- 244000287680 Garcinia dulcis Species 0.000 claims 1
- 239000002253 acid Substances 0.000 description 14
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 13
- 229910052802 copper Inorganic materials 0.000 description 13
- 239000010949 copper Substances 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 9
- 239000000047 product Substances 0.000 description 8
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 description 7
- 150000002739 metals Chemical class 0.000 description 7
- 239000012141 concentrate Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000005191 phase separation Methods 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 229910052951 chalcopyrite Inorganic materials 0.000 description 5
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 description 5
- 239000007791 liquid phase Substances 0.000 description 5
- 229910052976 metal sulfide Inorganic materials 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 229910052569 sulfide mineral Inorganic materials 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 238000009854 hydrometallurgy Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 239000007790 solid phase Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- -1 without limitation Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical class [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 description 2
- 238000010908 decantation Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910000358 iron sulfate Inorganic materials 0.000 description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical class [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229910052948 bornite Inorganic materials 0.000 description 1
- 229910052947 chalcocite Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005363 electrowinning Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052595 hematite Inorganic materials 0.000 description 1
- 239000011019 hematite Substances 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000001706 oxygenating effect Effects 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0065—Leaching or slurrying
- C22B15/0067—Leaching or slurrying with acids or salts thereof
- C22B15/0071—Leaching or slurrying with acids or salts thereof containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/04—Obtaining noble metals by wet processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
- C22B3/08—Sulfuric acid, other sulfurated acids or salts thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US22067700P | 2000-07-25 | 2000-07-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200300680B true ZA200300680B (en) | 2004-02-20 |
Family
ID=22824508
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200300680A ZA200300680B (en) | 2000-07-25 | 2003-01-24 | Processing elemental sulfur-bearing materials using high temperature pressure leaching for sulfuric acid production and metal recovery. |
Country Status (13)
| Country | Link |
|---|---|
| US (4) | US6497745B2 (fr) |
| EP (1) | EP1303640B1 (fr) |
| JP (2) | JP4171300B2 (fr) |
| AP (1) | AP1640A (fr) |
| AT (1) | ATE278813T1 (fr) |
| AU (2) | AU2001278015B2 (fr) |
| BR (1) | BR0112758B1 (fr) |
| CA (1) | CA2417422C (fr) |
| DE (1) | DE60106269T2 (fr) |
| EA (1) | EA005279B1 (fr) |
| OA (1) | OA12344A (fr) |
| WO (1) | WO2002008474A2 (fr) |
| ZA (1) | ZA200300680B (fr) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EA005279B1 (ru) * | 2000-07-25 | 2004-12-30 | Фелпс Додж Корпорейшн | Обработка содержащих элементарную серу материалов с использованием высокотемпературного автоклавного выщелачивания для производства серной кислоты и извлечения металла |
| US20050126923A1 (en) * | 2001-07-25 | 2005-06-16 | Phelps Dodge Corporation | Process for recovery of copper from copper-bearing material using medium temperature pressure leaching, direct electrowinning and solvent/solution extraction |
| US6451088B1 (en) | 2001-07-25 | 2002-09-17 | Phelps Dodge Corporation | Method for improving metals recovery using high temperature leaching |
| US7393513B2 (en) * | 2003-06-02 | 2008-07-01 | S&B Engineers And Constructors, Ltd. | System and process for treating sulfur |
| EA010942B1 (ru) * | 2004-10-29 | 2008-12-30 | Фелпс Додж Корпорейшн | Способ извлечения меди из медьсодержащего материала |
| US7736487B2 (en) | 2004-10-29 | 2010-06-15 | Freeport-Mcmoran Corporation | Process for recovery of copper from copper-bearing material using pressure leaching, direct electrowinning and solution extraction |
| US7604783B2 (en) | 2004-12-22 | 2009-10-20 | Placer Dome Technical Services Limited | Reduction of lime consumption when treating refractor gold ores or concentrates |
| GB0516912D0 (en) * | 2005-08-18 | 2005-09-28 | Fiset Gilles | Method and apparatus for the recovery of refractory mineral ores |
| US8061888B2 (en) | 2006-03-17 | 2011-11-22 | Barrick Gold Corporation | Autoclave with underflow dividers |
| AU2007248092B2 (en) * | 2006-05-01 | 2010-10-28 | Freeport-Mcmoran Corporation | Process for recovery of copper from copper-bearing material using pressure leaching, direct electrowinning and solvent/solution extraction |
| US8252254B2 (en) | 2006-06-15 | 2012-08-28 | Barrick Gold Corporation | Process for reduced alkali consumption in the recovery of silver |
| US9605353B2 (en) | 2011-05-27 | 2017-03-28 | Blue Planet Strategies, L.L.C. | Apparatus and method for advanced electrochemical modification of liquids |
| US9011669B2 (en) | 2012-09-17 | 2015-04-21 | Blue Planet Strategies, L.L.C. | Apparatus and method for electrochemical modification of liquids |
| CN102560138B (zh) * | 2012-01-11 | 2013-07-10 | 森松(江苏)海油工程装备有限公司 | 一种难浸金矿预处理方法 |
| CN103240075A (zh) * | 2013-05-06 | 2013-08-14 | 宜春银锂新能源有限责任公司 | 低温生产硫酸用的铷铯钒催化剂及其制备方法 |
| AU2015362587B2 (en) | 2014-12-16 | 2018-02-01 | Flsmidth A/S | System and method for above-atmospheric leaching of metal sulfides |
| PE20180808A1 (es) | 2015-07-06 | 2018-05-09 | Sherritt Int Corporation | Recuperacion de cobre de una alimentacion de proceso que contiene arsenico |
| PE20191621A1 (es) | 2017-04-14 | 2019-11-06 | Sherritt Int Corporation | Lixiviacion oxidativa presurizada, de bajo contenido de solidos y baja acidez de materiales de alimentacion sulfurados |
| US11124858B2 (en) | 2018-08-27 | 2021-09-21 | Flsmidth A/S | Solid-state catalysts for low or moderate temperature leach applications and methods thereof |
Family Cites Families (98)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1219277A (en) | 1913-02-25 | 1917-03-13 | Norske Elektrokemisk Ind As | Process of producing sulfuric acid. |
| US1570777A (en) * | 1923-06-13 | 1926-01-26 | Robert D Pike | Process for treating sulphide ores |
| US2188324A (en) | 1938-05-10 | 1940-01-30 | John H Walthall | Making sulphuric acid |
| US3260593A (en) | 1962-09-12 | 1966-07-12 | Kennecott Copper Corp | Process for leaching copper from lowgrade, copper-bearing ore materials |
| US3637371A (en) | 1967-02-10 | 1972-01-25 | Sherritt Gordon Mines Ltd | Direct pressure leaching of copper-iron sulphides |
| US3528784A (en) | 1968-03-21 | 1970-09-15 | Banner Mining Co | Method for preliminary beneficiation of calcareous oxidized copper ores by flotation of a high acid-consuming fraction containing low copper values from a low acid-consuming fraction containing higher copper values |
| BE756944A (fr) | 1969-10-02 | 1971-03-16 | American Metal Climax Inc | Procede d'oxydation en phase liquide |
| US3642435A (en) * | 1969-11-10 | 1972-02-15 | Cyprus Mines Corp | Method of recovering water-soluble nonferrous metal sulfates from sulfur-bearing ores |
| US3669651A (en) | 1970-04-15 | 1972-06-13 | Kennecott Copper Corp | Reduction of ferric ions in cyclic process of leaching and precipitation of copper |
| US3961028A (en) | 1971-04-02 | 1976-06-01 | Anumin Pty. Limited | Method of producing cuprous sulfate and bisulfate solutions |
| US4057423A (en) | 1971-09-10 | 1977-11-08 | Mitsui Mining & Smelting Co., Ltd. | Method for the manufacture of mercury free sulfuric acid |
| US3891522A (en) * | 1972-02-28 | 1975-06-24 | Cominco Ltd | Hydrometallurgical process for treating copper-iron sulphides |
| US4020106A (en) | 1972-03-21 | 1977-04-26 | Imperial Chemical Industries Limited | Metal extraction process |
| US3896208A (en) | 1972-06-26 | 1975-07-22 | Ethyl Corp | HCl Treatment of copper sulfide minerals |
| US4028462A (en) | 1972-08-28 | 1977-06-07 | Corporacion De Fomento De La Produccion, Represented By Comite De Investigaciones Technologicas | Method of extraction involving the use of solvents and new combination of reactors used |
| AT319617B (de) | 1973-02-21 | 1974-12-27 | Pawlek Dr Ing Franz | Verfahren zur hydrometallurgischen Gewinnung von Kupfer aus Kupferkies- bzw. Buntkupferkieskonzentraten |
| US3868440A (en) | 1973-05-30 | 1975-02-25 | Anaconda Co | Recovery of metal values from copper slag |
| US3962402A (en) | 1974-02-27 | 1976-06-08 | Freeport Minerals Company | Oxidation-leaching of chalcopyrite |
| US3917519A (en) * | 1974-02-27 | 1975-11-04 | Freeport Minerals Co | Process for the manufacture of electrolytic copper |
| FR2262699B1 (fr) | 1974-02-28 | 1976-12-10 | Commissariat Energie Atomique | |
| US4009250A (en) | 1974-03-18 | 1977-02-22 | Vasily Nikolaevich Novozhilov | Contact method of producing sulphuric acid |
| US3957602A (en) * | 1974-07-24 | 1976-05-18 | Cyprus Metallurgical Processes Corporation | Recovery of copper from chalcopyrite utilizing copper sulfate leach |
| CA1024352A (fr) | 1974-10-17 | 1978-01-17 | Wasyl Kunda | Procede pour recuperer le sulfate de cuivre et d'ammonium des minerals ou des concentres de sulfures contenant du cuivre |
| US3991159A (en) | 1975-01-09 | 1976-11-09 | Amax Inc. | High temperature neutralization of laterite leach slurry |
| US3958985A (en) | 1975-02-07 | 1976-05-25 | Chemsep Corporation | Extraction method for non-ferrous metals |
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| DE2519928C3 (de) | 1975-05-05 | 1981-04-02 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur Herstellung von Schwefelsäure |
| CA1036829A (fr) | 1975-07-30 | 1978-08-22 | Kohur N. Subramanian | Lessivage en deux phases de modules marins a l'aide d'acide sulfurique |
| US4039405A (en) | 1976-05-14 | 1977-08-02 | Continental Oil Company | Leaching copper ores and solvent extraction of the copper-bearing solutions |
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| CA1093837A (fr) | 1976-06-04 | 1981-01-20 | Gerald F. Fountain | Lessivage de crassier |
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| DE2725432C3 (de) | 1977-06-04 | 1980-02-21 | Davy International Ag, 6000 Frankfurt | Verfahren zur Herstellung von konzentrierter Schwefelsäure |
| CA1104837A (fr) | 1977-08-19 | 1981-07-14 | Donald R. Weir | Methode d'extraction du cuivre et du zinc en presence dans les sulfures complexes |
| US4093526A (en) * | 1977-09-08 | 1978-06-06 | Amax Inc. | Hydrometallurgical leaching and refining of nickel-copper concentrates, and electrowinning of copper |
| US4213958A (en) | 1977-11-14 | 1980-07-22 | Canadian Industries Limited | Production of sulphur trioxide, sulphuric acid and oleum |
| US4178357A (en) | 1977-11-28 | 1979-12-11 | Stoddard Xerxes T | Stripping sulphur compounds from stack and other discharge gases and the commercial products derived therefrom |
| US4139596A (en) | 1978-02-06 | 1979-02-13 | Vaseen Vesper A | Producing sulphuric acid |
| US4619814A (en) | 1978-05-05 | 1986-10-28 | Provincial Holdings Ltd. | Process for the recovery of non-ferrous metals from sulphide ores and concentrates |
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| CA1235907A (fr) | 1984-09-27 | 1988-05-03 | Donald R. Weir | Extraction de l'or des concentres refractaires sulfureux auriferes a teneur de fer |
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-
2001
- 2001-07-25 EA EA200300164A patent/EA005279B1/ru not_active IP Right Cessation
- 2001-07-25 AU AU2001278015A patent/AU2001278015B2/en not_active Ceased
- 2001-07-25 AP APAP/P/2003/002746A patent/AP1640A/en active
- 2001-07-25 AT AT01955969T patent/ATE278813T1/de not_active IP Right Cessation
- 2001-07-25 BR BRPI0112758-6A patent/BR0112758B1/pt not_active IP Right Cessation
- 2001-07-25 JP JP2002513956A patent/JP4171300B2/ja not_active Expired - Fee Related
- 2001-07-25 OA OA1200300016A patent/OA12344A/en unknown
- 2001-07-25 EP EP01955969A patent/EP1303640B1/fr not_active Expired - Lifetime
- 2001-07-25 WO PCT/US2001/023469 patent/WO2002008474A2/fr active IP Right Grant
- 2001-07-25 US US09/912,945 patent/US6497745B2/en not_active Expired - Fee Related
- 2001-07-25 DE DE2001606269 patent/DE60106269T2/de not_active Expired - Lifetime
- 2001-07-25 CA CA 2417422 patent/CA2417422C/fr not_active Expired - Fee Related
- 2001-07-25 AU AU7801501A patent/AU7801501A/xx active Pending
-
2002
- 2002-12-23 US US10/328,633 patent/US6890371B2/en not_active Expired - Fee Related
-
2003
- 2003-01-24 ZA ZA200300680A patent/ZA200300680B/en unknown
-
2005
- 2005-03-29 US US10/907,318 patent/US7041152B2/en not_active Expired - Fee Related
-
2006
- 2006-05-09 US US11/382,436 patent/US20060191377A1/en not_active Abandoned
-
2007
- 2007-08-08 JP JP2007207291A patent/JP2008001993A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| OA12344A (en) | 2006-05-15 |
| DE60106269D1 (de) | 2004-11-11 |
| US7041152B2 (en) | 2006-05-09 |
| US6497745B2 (en) | 2002-12-24 |
| EA005279B1 (ru) | 2004-12-30 |
| US20030086849A1 (en) | 2003-05-08 |
| AU7801501A (en) | 2002-02-05 |
| US20050155459A1 (en) | 2005-07-21 |
| US20020033076A1 (en) | 2002-03-21 |
| AP2003002746A0 (en) | 2003-06-30 |
| AU2001278015B2 (en) | 2004-12-23 |
| EP1303640A2 (fr) | 2003-04-23 |
| CA2417422C (fr) | 2009-01-27 |
| US20060191377A1 (en) | 2006-08-31 |
| BR0112758A (pt) | 2003-09-09 |
| US6890371B2 (en) | 2005-05-10 |
| DE60106269T2 (de) | 2006-02-16 |
| ATE278813T1 (de) | 2004-10-15 |
| EP1303640B1 (fr) | 2004-10-06 |
| CA2417422A1 (fr) | 2002-01-31 |
| EA200300164A1 (ru) | 2003-06-26 |
| JP4171300B2 (ja) | 2008-10-22 |
| JP2004504493A (ja) | 2004-02-12 |
| JP2008001993A (ja) | 2008-01-10 |
| AP1640A (en) | 2006-07-24 |
| WO2002008474A2 (fr) | 2002-01-31 |
| WO2002008474A3 (fr) | 2002-06-06 |
| BR0112758B1 (pt) | 2011-07-12 |
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