ZA200300127B

ZA200300127B - Vehicle used to apply chemical compounds to wood.

Info

Publication number: ZA200300127B
Application number: ZA200300127A
Authority: ZA
Inventors: Rafael Rodriguez Ramos
Original assignee: Rafael Rodriguez Ramos
Priority date: 2003-01-06
Filing date: 2003-01-06
Publication date: 2004-04-28

Description

. " | . ®

VEHICLE FOR APPLYING CHEMICAL COMPOUNDS ON WOOD

FIELD OF THE INVENTION :

This invention is generally related to the treatment of woods by means of applying chemical compounds. The invention specifically refers to a vehicle that is useful for applying chemical compounds on woods. :

BACKGROUND OF THE INVENTION : .

Various harmful biological agents are known that are capable of attacking wood, causing significant damage. Among ) said biological agents harmful for wood are insects, for : example beetles (a term which includes various species of woocd~-eating insects whose larvae gnaw and bore wood), termites, moths, etc., and fungi, for example Poria vaillantii oo 15 Fr., Coniophora cerebella Duey, Merulius lacrymans Wulf,

Lentinus lepideus Fr., Lenzites sepiaria Wulf, Chaetomium globosum Kunz, etc.

The products normally used for treating and conserving © wood generally comprise one or more active substances that are © 20 effective against the harmful biological agents to be : eliminated, for example one or more insecticides and/or fungicides, and a vehicle for introducing said active substances into the tunnels and cavities generated in the wood by the action of said harmful biological agents.

The number of vehicles that are effective as active substance carriers inside the wood is currently very limited.

Among those vehicles normally used in products for treating and conserving wood are water, inorganic arsenic derivatives, pentachlorophenol and creosote.

Water is the most commonly used carrier. However, it scarcely penetrates the wood, so the active substances applied to the wood using said vehicle therefore do not suitably ] penetrate it, remaining on the surface, thereby significantly . } reducing the effectiveness of said active substances. oo 35 The other vehicles have a very slight wood penetration

. ‘ , ® index, generally comprised between 2 and 6 mm after 24 hours.

In soft and porous woods, penetration indices of the vehicle of up to 6 mm are obtained, whereas in hard and not porous woods, the vehicles penetrate between 2 and 3 mm during a 24 hour time period.

Therefore, there is a necessity to find new vehicles that are useful for applying chemical compounds on woods which advantageously have a high wood penetration index. . The invention provides a solution to the existing : 10 necessity that comprises the development of a new vehicle for applying chemical compounds on woods, comprising a mixture of several components. Said vehicle has a high wood penetration index, determined by means of a trial comprising the application of the vehicle at a point on the wood, allowing the vehicle to act for a period of time, and determining the advance of the vehicle front by means of cutting the wood and measuring the advance of the vehicle front.

A vehicle such as the one provided by this invention is useful - for treating woods, specifically for treating and ’ 20 preventing damage caused by the attack of biological agents } that are harmful for wood. :

An object of this invention is constituted of said vehicle for applying chemical compounds on woods.

An additional object of this invention is constituted of : a composition comprising said vehicle together with at least . one chemical compound.

Another additional object of this invention is constituted of a method for treating wood, comprising applying . said composition in a sufficient quantity to the wood to be treated. Co

DETAILED DESCRIPTION OF THE INVENTION } . "The invention provides a vehicle that is useful for applying chemical compounds on woods, heretofore vehicle of the invention, comprising: :

Components | Percentage by weight regarding total (%)

@

Toluene 40-70

Xylene © 6-40 . Benzophenone : 3-18

Butyl glycol 2-9

Cetyl acetate 1-7 ’

Methanol : 0.3-4

All the components constituting the vehicle of the invention are commercial products. In the sense used in this i description, the term “benzophenone” includes both benzophenone ' (diphenylmethanone) and the hydroxylated or methoxylated derivatives thereof [see for example The Merck

Index, 11th Edition, 1989]. Likewise, the term “butyl” : includes any of the butyl isomers. - In a particular embodiment, the vehicle of the invention has the following composition:

Co Components Percentage by weight regarding total (%)

Toluene 64

Xylene 16

Benzophenone 10

Butyl glycol 5

Cetyl acetate 4

Methanol 1

The vehicle of the invention can be easily prepared by means of a process that comprises mixing the components in the desired proportions. }

Several trials have clearly shown the high penetration index of the vehicle of the invention in different woods [see

Example 1], it can therefore be used for applying chemical ~ compounds on woods, for example, chemical compounds useful for treating woods, specifically for treating and preventing damage caused by the attack of biological agents that are harmful for wood [see Example 2]. | .

The invention also provides a composition, heretofore composition of the invention, comprising at least one chemical compound and a vehicle of the invention. The vehicle of the

. , . @ invention can be present in the composition of the invention in a widely variable quantity; for example, the composition of the invention may contain between 0.1 and 99.9% by weight of the vehicle of the invention, the rest being constituted of said compound or chemical compounds, in which case said chemical compounds can be present in any weight ratio that is suitable among them. The composition of the invention can be =. easily obtained by mixing the vehicle of the invention with said compound or chemical compound in the suitable weight ratio. The composition of the invention is in liquid form, for example in a solution or dispersion. oo

In a particular embodiment of the invention, the composition of the invention is a composition that is useful : for treating wood, comprising one or more chemical compounds “15 that are useful for treating wood, in addition to the vehicle - of the invention. In another more specific embodiment of the invention, the composition of the invention is an insecticide and/or fungicide composition, useful for treating and/or preventing damage caused by insects and/or fungi which attack © 20 wood, comprising one or more insecticides and/or one or more fungicides, in addition to the vehicle of the invention. Among those insecticides and/or fungicides that may be present in the composition of the invention, the following are included: chlorpyrifos, fipronil, silafluofen, acetamiprid, etofenprozx, tripropyl isocyanurate, fenobucarb, hexaflumuron, fenitrothion, esfenvalerate, imidacloprid, difluobenzuron, lambda-cyhalothrin, clothalonil, propiconazole and the mixtures thereof. In this case, the composition of the invention is useful for inhibiting the development of biological agents that are harmful for wood, such as insects, for example, beetles, termites, moths, etc., and fungi, for example, Poria vaillantii Fr., Coniophora cerebella Duey,

Merulius lacrymans Wulf, Lentinus lIepideus Fr., Lenzites sepiaria Wulf, Chaetomium globosum Kunz, etc.

The wood penetration index obtained with the composition

_ of the invention generally corresponds to that of the vehicle used. Said penetration index may vary, depending on the type of wood as well as the degree of humidity thereof.

The invention also provides a method for treating wood 5 which comprises applying a composition of the invention to the wood to be treated in a sufficient quantity so as to obtain the desired effect. In the sense used in this description, the : expression “applying a composition of the invention to "the wood to be treated” includes applying the composition of the invention on the surface to the wood to be treated as well as introducing the composition of the invention, by any suitable . means, into the tunnels and cavities generated in the wood by the action of, for example, harmful biological agents.

The following examples serve to illustrate the invention and must not be considered limiting for the scope thereof.

EXAMPLE 1 : Determination of the wood penetration index of a vehicle 1.1 Materials and method

The method used for determining the wood penetration index of a vehicle consists of applying a determined quantity : of the vehicle to be tested (between 3 and 10 ml) at a point (origin) of the surface of the wood, allowing the vehicle to : act for a determined time period (between 1-23 minutes), and ~ 25 measuring the advance of the vehicle front by means of cutting .the wood and measuring the advance of the vehicle front inside the wood from the origin. oo }

The woods used were representative of a broad spectrum of woods, from very soft and porous woods to very hard and not porous woods. The woods that were specifically tested were the following: poplar, scots pine, walnut, cedar and beech wood. :

The woods were shaped into 20 x7 x 7 cm pieces.

The vehicles tested were those whose compositions are ) described below. As the trials were being carried out and results were being obtained, the products were selected and

. : . | : [ those which resulted to be ineffective for the desired objective were discarded. Thus the composition of the vehicle of the invention was obtained.

I. Combinations of 2 different components: 1) Ethylene glycol/toluene i : 2) benzophenone-2/ethyl ether : 3) disodium phosphate/monoxinol-9 4) butyl glycol/acetylene © 5) methanol/benzol 6) dodecyl diamino ethyl/xylene 7) sodium sulphate/cetyl acetate : 8) sodium hydroxide/methylene chloride

For -each combination, different concentrations were tested (in each case comprised between 0.5 and 80% by weight regarding the total) of each .one of the components present in : each combination. The remainder up to 100% was composed of the other component.

II. Combinations of 3 different components: oo 1) cetyl acetate/sodium hydroxide/monoxinol-9 2) butyl glycol/ethyl ether/disodium phosphate : © 3) acetylene/dodecyl diamino ethyl/toluene | . 4) - benzol/methylene chloride/sodium sulphate 5) benzophenone-2/acetylene/monoxinol-9 6) xylene/ethylene glycol/methanol :

For each combination, different concentrations were tested (in each case comprised between 0.5 and 80% by weight regarding the total) of each one of the components present in : each combination. The remainder up to 100% was composed of the ’ other components. :

III. Combinations of 4 different components: 1) ethyl ether/methanocl/butyl glycol/sodium hydroxide 2) sodium sulphate/xylene/methylene chloride/ benzol 3) dodecyl diamino ethyl/cetyl acetate/disodium : phosphate /acetylene 4) benzophene-2/ethylene glycol/monoxinol=-9/toluene

_

L

5) xylene/ethylene glycol/methanol

For each combination, different concentrations were tested (in each case comprised between 0.5 and 80% by weight ) regarding the total) of each one of the components present in each combination. The remainder up to 100% was composed of the other components.

IV. Combinations of 5 different components: : 1) methanol/acetylene/ethylene glycol/benzol/disodium phosphate 2) xylene/methylene chloride/dodecyl diamino ethyl/sodium sulphate/monoxinol-9 3) benzophenone-2/sodium hydroxide/methanol/cetyl acetate/ethyl ether : 4) acetylene/disodium sulphate/butyl glycol/methylene chloride/toluene

For each combination, different concentrations were tested (in each case comprised between 0.5 and 80% by weight regarding the total) of each one of the components present in each combination. The remainder up to 100% was composed of the other components. : ] V. Combinations of 6 different compounds: 1) toluene/ethyl ether/ethylene glycol/methanol/ monoxinol-9/acetylene 2) sodium hydroxide/cetyl acetate/sodium sulphate/ xylene/dodecyl diamino ethyl/benzol 3) benzophenone-2/methylene chloride/disodium phosphate/ butyl glycol/acetylene/sodium hydroxide 4) toluene/xylene/benzophenone-2/butyl glycol/cetyl acetate/methanol : . : For each combination, different concentrations were : tested (in each case comprised between 0.5 and 80% by weight regarding the total) of each one of the components present in : each combination. The remainder up to 100% was composed of the other components. . "1.2 RESULTS B

® -

In general, the best results, expressed as the measurement (in mm) of the advance of the vehicle front, were obtained with a vehicle whose composition contained 6 different components, specifically with a composition of type

V.4 composed of toluene, xylene, benzophenone-2, butyl glycol, cetyl acetate and methanol. Specifically, with a vehicle having Composition A: 64% toluene, 16% xylene, 10% ) benzophenone~-2, 5% butyl glycol, 4% cetyl acetate and 1% methanol, where all the percentages are by weight regarding the total, the results that were obtained are included in

Table 1. Co ] Table 1

Penetration index (PI) of composition A on different woods

I SN EE cc I I EN

CLL ER EC a

J I ICO

II ER EL ER

Fc A A J

IC I EL ER

I I IA RSA oo Further trials carried out with compositions containing one or more insecticides and/or fungicides together with a vehicle provided by this invention clearly showed that the

@® . penetration index of the composition was the same as that of the vehicle [without active substance (s)]. oo EXAMPLE 2

Insecticide composition and effectiveness trials

An insecticide composition was prepared, heretofore

Composition B, which exhibited the following composition:

Fenitrothion 25% (total weight/volume) | }

Esfenvalerate 2% (total weight/volume)

Vehicle* remainder up to 100% : * The vehicle composition was the following: 64% toluene, 16% : Xylene, 10% benzophenone-2, 5% butyl glycol, 4% cetyl acetate . and 1% methanol, where all the rates are by weight with regard : to the total weight [corresponds to Composition A mentioned in Co : Example 1].

The density of the insecticide composition was 0.9 g/ml.

The insecticide composition was obtained by adding. fenitrothion and esfenvalerate, in suitable amounts, to the vehicle obtained previously by means of mixing its components in the suitable amounts. g

In order to evaluate the effectiveness of said . : insecticide composition [Composition BJ], which contained a vehicle provided by this invention, the following trials were carried out: 2.1 Determination of the preventive effectiveness against termites; and "+ 2.2 Determination of the threshold of preventive effectiveness against termites . 2.1 Determination of the preventive effectiveness against termites 2.1.1 Brushing 2.1.1.1 Materials and methods

BN The tested insecticide composition is Composition B. No solvent was used to dissolve the insecticide composition. Pure gelatin was used for clogging up to the heads of the test tubes, as indicated by the standard. )

® | .

The biological material used was Reticulitermes lucifugus Rossi.

The trial standard was UNE standard 56411:1992 (Una

Norma Espanola- A Spanish Standard) (EN 118:1990) “Wood protectors. Determination of preventive effectiveness against ’ Reticulitermes santonensis of Feytaud. Laboratory method.”

The trial was carried out on wood test tubes obtained from Pinus sylvestris ©L. originating from the Valsain mountain, in accordance with the requirements of the standard.

The minimum dose obtained by means of "treatment by brushing, as indicated by the standard, was 43.05 ml/m’. 2.1.1.2 Treatment .

On the 10 March of 2000, the minimum possible amount of : insecticide composition (43.05 ml/r?), with a tolerance of +5%, was applied by brushing on one of the sides of the test tube, checking by means of weighing that the desired amount had been applied, thus obtaining the insecticide composition absorptions and retentions that are included in Table 2.

After treatment, the test specimen were left to dry and were treated in an air conditioned chamber at a temperature of 20+2°C and a relative humidity of 65+5% for 7 weeks, prior to putting them in contact with the insect colonies. The termite colonies were put in contact with the test tube using a polyurethane foam on the 3 of May of 2000, and the test apparatuses were placed in a chamber at a temperature of } : 27+42°C and a relative humidity of 754+5% for 8 weeks. Co

The final examination was carried out on the 26 of June of 2000. The attacks of the test tubes were evaluated as per the following scale: a 0: No sign of attack } 1: Tentative attack . : 2: Light attack 3: Medium attack 4: Strong attack

The results obtained are included in Table 2.

®

Table 2 : Preventive effectiveness against termites (UNE 56411:1992) .

Unaged test tubes. Brushed

Test results of number doses Doses ‘ g/m ml /m* g/m ml/m° [O (%)]| S and N (0-4) :

RAE ESN EE EE

REN EN EE EE

SE EE cit Be It Ei EE CS EE

IE et I SEE EH EE fo-00 Jesse] 0 | 00 | 9

Cc IEE EE I ES

ES I EE EE saves | - Lo pee] bf

SN NE HC EI BE

[O: workers; S: soldiers; N: nymphs; n: number] )

The results obtained clearly. show that the tested . insecticide composition (Composition. B) is effective against termites for surface treatments by means of a method providing . . a dose of approximately 43 ml/m’ on the wood that is actually treated. To evaluate the possibility that the effectiveness threshold is below the tested dose (43 ml/m?), several trials were carried out using a treatment method based on spraying the insecticide composition on the wood to be treated. 2.1.2 Spraying 2.1.2.1 Materials and methods + The tested insecticide composition is Composition B. No solvent was used to dissolve the insecticide composition. Pure gelatin was used for clogging up to the heads of the test tubes, as indicated by the standard.

The biological material used was Reticulitermes lucifugus Rossi (the termite species conventionally existing

® . in Spain).

The trial standard was the UNE standard 56411:1992 (EN 118:1990) “Wood protectors. Determination of preventive efficacy against Reticulitermes santonensis of Feytaud.

Laboratory method.”

The trial was carried out on wood test specimen obtained from Pinus sylvestris L. originating from the Burgui mountain (Navarra), in accordance with the requirements of the standard. " The tested insecticide composition concentrations were : the following: 13.33 ml/m® and 16.66 ml/m?. The insecticide composition was applied by means of spraying. . 2.1.2.2 Treatment on the 20 of June of 2000, the indicated doses of : 15 insecticide composition, with a tolerance of +5%, were applied by spraying on one of the sides of the test specimen, checking by means of weighing that the desired amounts had been applied, thus obtaining the insecticide composition absorptions and retentions that are included in Tables 3 and a4. ) After treatment, the test tubes were left to dry and : were treated in an air conditioned chamber at a temperature of 2042°C and a relative humidity of 65+5% for 10 weeks prior to putting them in contact with the insect colonies or aging’ them. :

In order to age the test tubes, the latter were subjected to an aging trial by evaporation for 12 weeks, as per the methodology indicated in the UNE standard 56406:1992 [Wood protectors. Accelerated aging trials of treated woods prior to biological trials. Evaporation test].

The termite colonies were put in contact with the test specimen using a polyurethane foam on the 27 of July of 2000 (for the unaged test specimen) and on the 30 of October of 2000 (for the test specimen subjected to aging by evaporation), and the test devices were placed in a chamber at

_ a temperature of 27+2°C and a relative humidity of 75+5% for 8 weeks.

The final examination was carried out on the 24 of ]

October of 2000 (for the unaged test specimen) and on the 2 of

January of 2001 (for the test specimen subjected to aging by : evaporation). The attacks of the test specimen were evaluated } | as per the following scale: _ 0: No sign of attack 1: Tentative attack 2: Light attack 3: Medium attack . : . 4: Strong attack

The results obtained are included in Tables 3 and 4.

Table 3 oo

Preventive effectiveness against termites (UNE 56411:1992)

Unaged test specimen. Spraying

Test results of - number doses doses (0-4) g/m ral /m g/m ml/m* |O (%)| S and N| . :

SE

El RE EE BS

Ee ee

IE CG I

— FES I IC I savples | - | - fee oe pot]

EEE EE EE ES

[0: workers; S: soldiers; N: nymphs; n: number]

Table 4

Preventive efficacy against termites (UNE 56411:1992)

Aged test specimen (EN 73). Spraying specimen results .of doses doses (0-4) g/m ml/m g/m ml/m“ |{O (%) |S and N

Sem

IESE JEN FL IC IC

I NC CI IC

Il LN NC ICE CR

J i ES I cc A =] IE I HC NC [O: workers; S: soldiers; N: nymphs; n: number]

The results obtained clearly show that the tested insecticide composition (Composition B) is effective against termites for surface treatments by means of a method providing a dose between 13.33 and 16.66 ml/m* on the wood that is actually treated. Given that the product has shown to be effective at the lowest dose of 13.33 ml/m?, it is likely that © it is effective at doses that are lower than those specified. 2.2 Determination of the threshold of preventive effectiveness against termites 2.2.1 Materials and Method

The tested insecticide composition is Composition B.

The biological material used was R. lucifugus Rossi (the termite species normally existing in Spain).

The trial standard was the UNE standard 56410:1992 (EN

® © 117:1990) “Wood protectors. Determination of the threshold of preventive efficacy against Reticulitermes santonensis of

Feytaud. Laboratory method.”

The trial was carried out on wood test specimen obtained from Pinus sylvestris L. originating from the Burgui mountain (Navarra), in accordance with the requirements of the standard. )

To dilute the insecticide composition, xylene was used.

The tested concentrations were the following: 0%, 0.01%, 0.023%, 0.045%, 0.065% and 0.085%. 2.2.2 Treatment

On the 16 of June of 2000, the impregnation of the test specimen was carried by atmospheric pressure vacuum, as indicated by the standard, thus obtaining the insecticide composition absorptions and retentions that are included in

Tables 5 and 6.

After treatment, the test specimen were left to dry and ) were treated in an air conditioned chamber at a temperature of © 20+2°C and a relative humidity of 65+5% for 6 weeks prior to putting them in contact with the insect colonies or aging them. :

To age the test specimen, once the latter are treated, they are subjected to an aging trial by evaporation for 12 oo weeks, as per the methodology indicated in the UNE standard 56406:19892.

The termite colonies were put in contact with the test : } specimen by using a polyurethane foam on the 27 of July of 2000 (for the unaged test specimen) and on the 30 of October of 2000 (for the test specimen subjected to aging by evaporation), and the test devices were placed in a chamber at a temperature of 27+2°C and a relative humidity of 75+5% for 8 weeks.

The final examination was carried out on the 18 of

September of 2000 for the unaged test specimen and on the 2 of ~ 35 January of 2001 for the test specimen subjected to aging by

® evaporation. The attacks of the specimen were evaluated as per the following scale: : : 0: No sign of attack ’ 1: Tentative attack 5. 2: Light attack 3: Medium attack oe 4: Strong attack

The results obtained are included in Tables 5 and 6.

These results clearly show that the tested insecticide oo composition (Composition B) is effective against termites for ] deep treatments by a process providing a retention of approximately 0.04 kg/m* on the wood that is actually impregnated. Given that the product has proven to be effective : at the lowest dose (0.01%), it is likely that the effectiveness threshold is below the specified retention. p

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Claims

@ CLAIMS

© 1. Vehicle that is useful for applying chemical compounds on woods, comprising the following composition: Components Percentage by weight regarding total (%) Toluene 40-70 Xylene | 6-40 Benzophenone i 3-18 : ’ - Butyl glycol 2-9 Cetyl acetate } 1-7

10. Methanol 1 0.3-4

) 2. Vehicle according to claim 1, comprising the following composition: | : Components Percentage by weight regarding total (%) Toluene 64 Xylene 16 Benzophenone 10 Butyl glycol 5 Cetyl acetate 4 Methanol 1

3. Composition comprising at least one chemical compound and a vehicle according to any of claims 1 or 2. :

4. Composition according to claim 3, wherein said chemical compound comprises one or more insecticides and/or one or more fungicides. :

5. Composition according to . claim 4, wherein said : chemical compound is selected from chlorpyrifos, fipronil, silafluofen, acetamiprid, etofenprox, tripropyl isocianurate, fenobucarb, hexaflumuron, fenitrothion, = esfenvalerate, imidacloprid, difluobenzuron, lambda-cyhalothrin, clothalonil, : 30 propiconazole and the mixtures thereof.

) 6. Method for treating wood which comprises applying a composition according to any of claims 3 to 5 to the wood to : be treated.

7. Method according to claim 6, for treating and/or Co preventing the damage caused by biological agents that are

, harmful for wood, which comprises applying a composition according to any of claims 4 or 5 to the wood to be treated.