WO2024136204A1 - Oxygen generating functional composition capable of long-term oxygen supply to crop cultivation areas and farming method using same - Google Patents
Oxygen generating functional composition capable of long-term oxygen supply to crop cultivation areas and farming method using same Download PDFInfo
- Publication number
- WO2024136204A1 WO2024136204A1 PCT/KR2023/019539 KR2023019539W WO2024136204A1 WO 2024136204 A1 WO2024136204 A1 WO 2024136204A1 KR 2023019539 W KR2023019539 W KR 2023019539W WO 2024136204 A1 WO2024136204 A1 WO 2024136204A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- oxygen
- ppm
- acid
- solution
- concentration
- Prior art date
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 102
- 239000001301 oxygen Substances 0.000 title claims abstract description 102
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 102
- 239000000203 mixture Substances 0.000 title claims abstract description 55
- 238000009313 farming Methods 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims abstract description 26
- 230000007774 longterm Effects 0.000 title description 2
- 239000002689 soil Substances 0.000 claims abstract description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 37
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 34
- 230000029058 respiratory gaseous exchange Effects 0.000 claims abstract description 25
- 239000003054 catalyst Substances 0.000 claims abstract description 20
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 18
- 150000003839 salts Chemical group 0.000 claims abstract description 15
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims abstract description 14
- 239000010949 copper Substances 0.000 claims abstract description 13
- 239000011651 chromium Substances 0.000 claims abstract description 12
- 239000011572 manganese Substances 0.000 claims abstract description 12
- 239000010936 titanium Substances 0.000 claims abstract description 12
- 239000010941 cobalt Substances 0.000 claims abstract description 7
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims abstract description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 6
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims abstract description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910002651 NO3 Inorganic materials 0.000 claims abstract description 6
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 6
- 229910052802 copper Inorganic materials 0.000 claims abstract description 6
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 6
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 6
- 239000010452 phosphate Substances 0.000 claims abstract description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 6
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 6
- 239000010937 tungsten Substances 0.000 claims abstract description 6
- 238000005507 spraying Methods 0.000 claims abstract description 3
- 235000015097 nutrients Nutrition 0.000 claims description 22
- 239000002738 chelating agent Substances 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 239000003337 fertilizer Substances 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 6
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 6
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 6
- 229950007919 egtazic acid Drugs 0.000 claims description 6
- DEFVIWRASFVYLL-UHFFFAOYSA-N ethylene glycol bis(2-aminoethyl)tetraacetic acid Chemical compound OC(=O)CN(CC(O)=O)CCOCCOCCN(CC(O)=O)CC(O)=O DEFVIWRASFVYLL-UHFFFAOYSA-N 0.000 claims description 6
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 6
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 5
- VKZRWSNIWNFCIQ-WDSKDSINSA-N (2s)-2-[2-[[(1s)-1,2-dicarboxyethyl]amino]ethylamino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)NCCN[C@H](C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-WDSKDSINSA-N 0.000 claims description 4
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical group OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- PZZHMLOHNYWKIK-UHFFFAOYSA-N eddha Chemical compound C=1C=CC=C(O)C=1C(C(=O)O)NCCNC(C(O)=O)C1=CC=CC=C1O PZZHMLOHNYWKIK-UHFFFAOYSA-N 0.000 claims description 4
- 229960001484 edetic acid Drugs 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 3
- 235000010323 ascorbic acid Nutrition 0.000 claims description 3
- 239000011668 ascorbic acid Substances 0.000 claims description 3
- 229960005070 ascorbic acid Drugs 0.000 claims description 3
- 235000015165 citric acid Nutrition 0.000 claims description 3
- 239000004220 glutamic acid Substances 0.000 claims description 3
- 235000013922 glutamic acid Nutrition 0.000 claims description 3
- 239000000575 pesticide Substances 0.000 claims description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 2
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 claims description 2
- PUKLDDOGISCFCP-JSQCKWNTSA-N 21-Deoxycortisone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)C)(O)[C@@]1(C)CC2=O PUKLDDOGISCFCP-JSQCKWNTSA-N 0.000 claims description 2
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 2
- BDDLHHRCDSJVKV-UHFFFAOYSA-N 7028-40-2 Chemical compound CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O BDDLHHRCDSJVKV-UHFFFAOYSA-N 0.000 claims description 2
- 101100345345 Arabidopsis thaliana MGD1 gene Proteins 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 2
- FCYKAQOGGFGCMD-UHFFFAOYSA-N Fulvic acid Natural products O1C2=CC(O)=C(O)C(C(O)=O)=C2C(=O)C2=C1CC(C)(O)OC2 FCYKAQOGGFGCMD-UHFFFAOYSA-N 0.000 claims description 2
- WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical compound CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 claims description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 2
- 235000001014 amino acid Nutrition 0.000 claims description 2
- 150000001413 amino acids Chemical class 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- 235000019253 formic acid Nutrition 0.000 claims description 2
- 239000002509 fulvic acid Substances 0.000 claims description 2
- 229940095100 fulvic acid Drugs 0.000 claims description 2
- 239000001530 fumaric acid Substances 0.000 claims description 2
- 239000000417 fungicide Substances 0.000 claims description 2
- 239000004021 humic acid Substances 0.000 claims description 2
- 239000004310 lactic acid Substances 0.000 claims description 2
- 235000014655 lactic acid Nutrition 0.000 claims description 2
- 239000001630 malic acid Substances 0.000 claims description 2
- 235000011090 malic acid Nutrition 0.000 claims description 2
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 claims description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 2
- 235000019260 propionic acid Nutrition 0.000 claims description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 2
- BUUPQKDIAURBJP-UHFFFAOYSA-N sulfinic acid Chemical compound OS=O BUUPQKDIAURBJP-UHFFFAOYSA-N 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- OHOTVSOGTVKXEL-UHFFFAOYSA-K trisodium;2-[bis(carboxylatomethyl)amino]propanoate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C(C)N(CC([O-])=O)CC([O-])=O OHOTVSOGTVKXEL-UHFFFAOYSA-K 0.000 claims description 2
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims 2
- 229960003330 pentetic acid Drugs 0.000 claims 2
- 229940024606 amino acid Drugs 0.000 claims 1
- 238000007865 diluting Methods 0.000 claims 1
- 229940013688 formic acid Drugs 0.000 claims 1
- 235000011087 fumaric acid Nutrition 0.000 claims 1
- 229940095574 propionic acid Drugs 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract description 16
- 241000196324 Embryophyta Species 0.000 abstract description 14
- 239000000126 substance Substances 0.000 abstract description 5
- 239000013522 chelant Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 59
- 230000012010 growth Effects 0.000 description 17
- 238000003860 storage Methods 0.000 description 15
- 244000141359 Malus pumila Species 0.000 description 13
- 230000000694 effects Effects 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 11
- 241000219109 Citrullus Species 0.000 description 10
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 description 10
- 230000008569 process Effects 0.000 description 8
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 7
- 235000011430 Malus pumila Nutrition 0.000 description 7
- 235000015103 Malus silvestris Nutrition 0.000 description 7
- 240000003768 Solanum lycopersicum Species 0.000 description 7
- 240000006365 Vitis vinifera Species 0.000 description 6
- 235000014787 Vitis vinifera Nutrition 0.000 description 6
- 235000021016 apples Nutrition 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 240000007124 Brassica oleracea Species 0.000 description 5
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 5
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 5
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 5
- SXTLQDJHRPXDSB-UHFFFAOYSA-N copper;dinitrate;trihydrate Chemical compound O.O.O.[Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O SXTLQDJHRPXDSB-UHFFFAOYSA-N 0.000 description 5
- JVJUWCMBRUMDDQ-UHFFFAOYSA-N methylmercuric dicyanamide Chemical compound C[Hg]N=C(N)NC#N JVJUWCMBRUMDDQ-UHFFFAOYSA-N 0.000 description 5
- CCWMOGXFIDXIKC-UHFFFAOYSA-L zinc;diacetate;trihydrate Chemical compound O.O.O.[Zn+2].CC([O-])=O.CC([O-])=O CCWMOGXFIDXIKC-UHFFFAOYSA-L 0.000 description 5
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 4
- 241000219094 Vitaceae Species 0.000 description 4
- 235000009754 Vitis X bourquina Nutrition 0.000 description 4
- 235000012333 Vitis X labruscana Nutrition 0.000 description 4
- 241000607479 Yersinia pestis Species 0.000 description 4
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 4
- INQZXVMNJLSCGI-UHFFFAOYSA-M azanium;potassium;hydrogen phosphate Chemical compound [NH4+].[K+].OP([O-])([O-])=O INQZXVMNJLSCGI-UHFFFAOYSA-M 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 201000010099 disease Diseases 0.000 description 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 4
- 235000021021 grapes Nutrition 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- 230000003213 activating effect Effects 0.000 description 3
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- WOSISLOTWLGNKT-UHFFFAOYSA-L iron(2+);dichloride;hexahydrate Chemical compound O.O.O.O.O.O.Cl[Fe]Cl WOSISLOTWLGNKT-UHFFFAOYSA-L 0.000 description 3
- NPFOYSMITVOQOS-UHFFFAOYSA-K iron(III) citrate Chemical compound [Fe+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NPFOYSMITVOQOS-UHFFFAOYSA-K 0.000 description 3
- 208000030159 metabolic disease Diseases 0.000 description 3
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- 239000004343 Calcium peroxide Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- LHJQIRIGXXHNLA-UHFFFAOYSA-N calcium peroxide Chemical compound [Ca+2].[O-][O-] LHJQIRIGXXHNLA-UHFFFAOYSA-N 0.000 description 2
- 235000019402 calcium peroxide Nutrition 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 230000034994 death Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 230000004720 fertilization Effects 0.000 description 2
- 230000004060 metabolic process Effects 0.000 description 2
- 235000015816 nutrient absorption Nutrition 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- XXQBEVHPUKOQEO-UHFFFAOYSA-N potassium superoxide Chemical compound [K+].[K+].[O-][O-] XXQBEVHPUKOQEO-UHFFFAOYSA-N 0.000 description 2
- 230000002786 root growth Effects 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 230000008685 targeting Effects 0.000 description 2
- KVZLHPXEUGJPAH-UHFFFAOYSA-N 2-oxidanylpropanoic acid Chemical compound CC(O)C(O)=O.CC(O)C(O)=O KVZLHPXEUGJPAH-UHFFFAOYSA-N 0.000 description 1
- SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 description 1
- 244000144730 Amygdalus persica Species 0.000 description 1
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 description 1
- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910020599 Co 3 O 4 Inorganic materials 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 206010053759 Growth retardation Diseases 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- VJFCXDHFYISGTE-UHFFFAOYSA-N O=[Co](=O)=O Chemical compound O=[Co](=O)=O VJFCXDHFYISGTE-UHFFFAOYSA-N 0.000 description 1
- 244000131316 Panax pseudoginseng Species 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- 241000220324 Pyrus Species 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- LDSQGEOPRWAACZ-UHFFFAOYSA-N [P].OO Chemical compound [P].OO LDSQGEOPRWAACZ-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 229960002684 aminocaproic acid Drugs 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000001925 catabolic effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 229960002413 ferric citrate Drugs 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 230000005078 fruit development Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910021389 graphene Inorganic materials 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 231100000001 growth retardation Toxicity 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000033001 locomotion Effects 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000009335 monocropping Methods 0.000 description 1
- 239000002101 nanobubble Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 238000010606 normalization Methods 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 230000000243 photosynthetic effect Effects 0.000 description 1
- 230000035790 physiological processes and functions Effects 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001850 reproductive effect Effects 0.000 description 1
- 230000036387 respiratory rate Effects 0.000 description 1
- 230000021749 root development Effects 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G29/00—Root feeders; Injecting fertilisers into the roots
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/02—Preparation of oxygen
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
Definitions
- the present invention improves the quality and production of crops by maximizing root attachment and developmental activity by supplying sufficient oxygen when the roots of plants growing in soil and water breathe during the process of cultivating crops by soil cultivation and nutrient solution cultivation.
- This is an invention in the field of technology related to an oxygen-generating functional composition that can supply oxygen to crop fields for a long time and a farming method using the same in order to implement oxygen farming for crops.
- the rooting and growth of roots is related to the air (oxygen) and temperature in the soil, and the respiration of the roots, the activity of enzymes and microorganisms, and the action of root fungi are closely related to the air in the soil. there is.
- the amount and distribution of air in the soil are very important in order to discharge carbon monoxide generated through root respiration and decomposition of organic matter above the ground and to facilitate the supply of oxygen.
- the minimum oxygen concentration required for crop growth is 5 ppm, so it should not be lower than this.
- the energy required for plant root development is the energy obtained through respiration for growth and physiological functions, so if the amount of dissolved oxygen near the roots is insufficient, a rapid decrease in respiration can occur. As a result, metabolic disorders occur and growth is reduced. In particular, at higher temperatures, plants grow more vigorously and oxygen requirements increase for nutrient absorption, but the dissolved oxygen concentration in the supplied water rapidly decreases, becoming a limiting factor for growth.
- dissolved oxygen concentration is not increased and continued for 2 to 3 hours, dissolved oxygen will be depleted and there is a risk of death if it falls below 2 ppm.
- dissolved oxygen is sufficiently supplied, nutrients and moisture supply to the crop will be smooth. The growth of crops improves, resulting in improved quality and increased production by more than 20%.
- Oxygen farming for this purpose maximizes the catabolic/biochemical functions of the crop's metabolism by supplying 20 ppm or more of the basic oxygen requirement for root respiration and thereby maximizing the energy efficiency of photosynthesis. , By supplying more than twice the root growth energy to the underground roots, which is the most important condition for the nutritional and reproductive growth of crops, compared to the existing farming method (13:3:0), maximizing root establishment in the soil and water and the longest lifespan A plan to guarantee is required.
- root oxygen in the soil and water is abundant during soil cultivation and nutrient solution cultivation, optimization of root respiration and rooting, maximization of catabolism, assimilation, and biochemistry, maximization of nutrient or water absorption, normalization of metabolism, strengthening of crop resistance, and additional fertilization. and reduction of the use of pesticides, maximum stabilization of crop development status, increase in production and marketability, overcoming and resolving salt accumulation phenomenon, overcoming and resolving gas disturbances and continuous cropping disturbances, and improving the growth environment of soil cultivation and nutrient solution cultivation, as well as crop growth.
- a plan is needed to significantly improve the growing environment.
- oxygen farming increases the marketability and production of crops by providing fundamental and natural vitality and vitality to the underground roots and above-ground leaves, stems, and fruit growth of crops cultivated in soil and nutrient solution, and further increases their own resistance to diseases and pests. It is recognized that root oxygen in the soil is very important when growing crops for farmers. However, due to lack of technology, oxygen supply technology for root respiration of crops is insufficient or requires a lot of expense, making it virtually impossible to use. The reality is that it is not widely used by farmers.
- Korean Patent Application No. 10-2020-0031826 is characterized in that it is composed of a zeolite lump in the center, a calcium peroxide inner shell containing a decomposition catalyst and surrounding the outer surface of the zeolite lump, and a slag outer skin surrounding the outer surface of the calcium peroxide inner skin.
- An oxygen-generating mineral fertilizer is presented.
- Korean Patent Application No. 10-2018-0100503 presents a plant cultivation box for bottom watering with an air layer that allows plants to be grown in pots without drainage holes.
- Korean Patent Application No. 10-2020-0143784 an oxygen generator using homogeneous intake air is proposed, and in Korean Patent Publication No. 10-2017-0008933, oxygen generating substances potassium peroxide (K 2 O 2 ) and potassium acetate ( 30 to 60% by weight of a mixture of KO 2 ) and sodium peroxide (Na 2 O 2 ); and 40 to 70% by weight of one or more reaction regulators selected from activated carbon, zeolite, and silicon dioxide, and citric acid, potassium phosphate, glutamic acid, ascorbic acid, tartaric acid, salicylic acid, glycolic acid, lactic acid, and glycolic acid.
- An oxygen generator composition is presented, which is characterized in that it contains 1 to 3 times the amount of the mixture with one or more neutralizing agents selected from the group consisting of silicic acid and aminocaproic acid.
- Korean Patent Application No. 10-2017-0047422 proposes a liquid aquaponic system that can control the amount of dissolved oxygen.
- an ultra-fine bubble generating device including a primary porous plate and a plurality of secondary porous plates is combined with a hydroponic cultivation container to use ultra-fine bubble oxygen dissolved water for hydroponic cultivation.
- a hydroponic cultivator including an ultra-fine bubble generating device is presented.
- a ginseng plant with a bed fixing device and a nanobubble generating device is created by creating a three-stage bending area on the top of the four sides of the hydroponic cultivation tank to prevent the tank from bending due to the weight of fresh water in the tank.
- a water tank device for hydroponic cultivation is presented.
- oxygen is supplied to the crop roots at a randomly selected necessary time during the process of cultivating crops in soil cultivation or nutrient solution cultivation, as in the present invention, or oxygen is generated in a salt state diluted with water in the upper part of the soil.
- the composition of the catalyst and the diluted peroxide source is configured to be individually filled in a container shaped like a Ringer bottle connected to a drainage line, and the oxygen generating catalyst and the diluted composition are used for crops that require root respiration by oxygen.
- the composition of the peroxide source is gradually supplied to the soil individually, activating the basic metabolic activity of the crop by supplying oxygen, and providing a stable and active farming method to maintain normal growth balance in the underground part of the crop itself.
- the concentration of oxygen required for root respiration the basic growth activity of crops, be maintained at a concentration of 12 ppm or higher, but the dissolved oxygen contained in water supplied for most crop cultivation is maintained at an average concentration of 5 ppm or less.
- water with high dissolved oxygen is required for normal growth, but as the temperature rises or the surrounding environment changes, the amount of dissolved oxygen in the water decreases, resulting in a lack of dissolved oxygen near the roots.
- This technology was developed in recognition of the need for a functional composition that can supply oxygen for a long time as a technology that eliminates the risk of growth retardation due to metabolic disorders due to decreased respiratory rate.
- the technical idea disclosed herein as a means to achieve the above objective is a technology for providing an oxygen-generating functional composition for crop cultivation to implement oxygen farming by maximizing the oxygen demand for root respiration of crops during the soil cultivation and nutrient solution cultivation process, Among aluminum (Al), titanium (Ti), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), and tungsten (W).
- the selected inorganic is one of Sulfate, Chloride, Nitrate, Acetate, Phosphate, Fluoride, and Salt combined with a chelating agent.
- oxygen-generating catalyst in the form of a metal salt (salt) in which each stored B solution is individually composed and diluted to a concentration of 10 ppm to 900 ppm to apply oxygen farming to relatively small crops, such as vegetables.
- a solution composition consisting of is applied to be sprayed into the soil or nutrient solution cultivation area by primary supply means, and when root respiration of crops is required immediately or after a certain period of time, it is used as an oxygen source.
- the B solution composition of hydrogen peroxide (H 2 O 2 ) or the B solution of the persulfate composition may be applied to be supplied diluted to a concentration of 25 ppm to 5,000 ppm.
- solution A when it is desired to apply oxygen farming to crops such as apples, peaches, and pears that are large in size and have a large distance between the crops, the components of solution A and B are the same, and solution A is mixed with 10 Dilute the solution to a concentration of 25 ppm to 5,000 ppm and store it in a container (A-1) equipped with a drain line and a discharge means, and dilute solution B to a concentration of 25 ppm to 5,000 ppm and store it in a container (B) equipped with a drain line and a discharge means.
- This invention was completed by confirming that high-yield cultivation can be achieved by implementing oxygen farming of crops by applying it as a D means that is stored in -1) and sprayed on crop fields.
- our technical philosophy is a farming method applied to enable high-yield cultivation by realizing oxygen farming by maximizing the oxygen demand required for root respiration of crops,
- the selected inorganic is one of Sulfate, Chloride, Nitrate, Acetate, Phosphate, Fluoride, and Salt combined with a chelating agent. is selected to store the oxygen-generating catalyst composition dissolved in water at a concentration of 0.05 to 25% by weight, and the oxygen-generating composition in which hydrogen peroxide (H 2 O 2 ) or persulfate is dissolved in water at a concentration of 50% by weight or less.
- Each stored B solution is individually composed, and depending on the crop cultivation environment, A solution is first diluted and sprayed on the soil to a concentration range of 10 ppm to 900 ppm, and then B solution is diluted to a concentration range of 25 ppm to 5,000 ppm and sprayed on the soil. It is applied as means C, which is sprayed on or, depending on the crop cultivation environment, solution A is diluted to a concentration of 10 ppm ⁇ 900 ppm and stored in a container (A-1) equipped with a drainage line and discharge means, and solution B is diluted to a concentration of 10 ppm ⁇ 900 ppm.
- composition of solution A or solution B used in the present technology can be selected from pesticides, fungicides, fertilizer ingredients, and nutrients, and additional ingredients necessary for crop cultivation can be applied to enable high-yield cultivation by implementing oxygen farming of crops.
- pesticides pesticides, fungicides, fertilizer ingredients, and nutrients
- additional ingredients necessary for crop cultivation can be applied to enable high-yield cultivation by implementing oxygen farming of crops.
- the chelating agent is EDTA (Ethylene-diamine-tetraacetic acid), DTPA (Dithylenetriamine pentaacetic acid), EDDHA (Ethylenediamine-N, N′-bis (2-hydroxyphenylacetic acid), NTA (Nitrilitriacetic acid), CyDTA (1,2-cyclo-hexadiamine tetraacetic acid), EDDS (Ethylenediaminedisuccinic acid), MGDA (Methylglycinediacetic acid), EGTA (Ethyleneglycoltetraacetic acid), DCTA (Ethyleneglycoltetraacetic acid), GLDA (Glutamic acid diacetic acid), IDS (Aminodisuccinic acid), Fumaric acid, Lactic acid (Lactic acid), Citric acid, Malic acid, Butyric acid, Formic acid, Propionic acid, Ascorbic
- the persulfate may be selected from among ammonium persulfate, sodium persulfate, and potassium persulfate.
- this institute increases the oxygen concentration by supplying oxygen to the soil of the soil cultivation area or the water of the nutrient solution cultivation area for a long time in any form as needed during the process of cultivating crops, resulting in an increase in oxygen concentration.
- By providing vigorous root growth, increased root nutrient absorption, increased photosynthetic products, and active crop growth energy it provides active fruit development of crops, minimizing farm labor while improving the marketability of crops, increasing production, and eliminating diseases and pests. It is expected that it will be effective in creating economic benefits for farms and securing technical competitiveness of farms by increasing resistance.
- Figure 1 Illustration of an embodiment for applying the oxygen farming method of the present invention to short crops in a large cultivation area
- Figure 2 Illustration of an embodiment for applying oxygen farming to individual tall crops of the present invention
- a storage solution of 25% by weight of aluminum sulfate 6-8 hydrate (Samjeon Pure Pharmaceutical, Al 2 (SO 4 ) 3 ⁇ 6-8H 2 O) was prepared as an oxygen generation catalyst composition, and oxygen generation was performed.
- a storage solution of 35% by weight of hydrogen peroxide (Daemyung Chemical, H 2 O 2 ) was prepared as a composition.
- the storage solution of aluminum sulfate was diluted with water to a concentration of 40 ppm, and the diluted aluminum sulfate solution was evenly sprinkled on the soil of a 660 m2 greenhouse for growing watermelons.
- hydrogen peroxide diluted to a concentration of 100 ppm was added.
- the solution was sprinkled uniformly on the soil and the oxygen-generating composition for cultivated soil for watermelon cultivation was supplied to the soil at intervals of 10 days during the watermelon cultivation period. It was used as a normal source to ensure the quality and quantity of watermelons during the watermelon cultivation period.
- 1 kg of Agrosol liquid fertilizer [Agrobiz Co., Ltd.] with a nitrogen-phosphate-potassium concentration ratio of 20-20-20% by weight was diluted in water and drenched at 330 m2 at intervals of 3 days.
- the watermelon cultivation period was 120 days, and the average weight of 450 watermelons harvested was confirmed to compare the effects of our technology philosophy.
- An oxygen-generating composition for cultivated soil for cabbage cultivation was sprayed uniformly on the soil and supplied to the soil at intervals of 13 days during the cabbage cultivation period.
- Nitrogen- 1 kg of Agrosol liquid fertilizer [Agrobiz Co., Ltd.] with a phosphate-potassium concentration ratio of 20-20-20% by weight was diluted in water and drenched at 330 m2 at intervals of 3 days.
- the storage solution of copper nitrate trihydrate was diluted with water to a concentration of 500 ppm, the diluted copper nitrate trihydrate solution was filled into a 1 liter container connected to a drain line, and 2,000 ppm was added to another 1 liter container connected to a drain line. The concentration of hydrogen peroxide was filled.
- a container filled with copper nitrate trihydrate solution and a container filled with hydrogen peroxide were hung on the stems of 20 grapevines, and copper nitrate trihydrate solution diluted to a concentration of 500 ppm and hydrogen peroxide at a concentration of 2,000 ppm were each administered at a rate of 5 ml per minute. It was controlled to be discharged to the surface of the grapevine at a level and supplied to the soil at the same intervals of 3 days during the grape growing period. The concentration ratio of nitrogen-phosphate-potassium was used as a common source to ensure the quality and quantity of grapes during the grape growing period. 1 kg of 20-20-20% by weight Agrosol liquid fertilizer [Agrobiz Co., Ltd.] was diluted in water and drenched at 330 m2 at 3-day intervals.
- the grape cultivation period was 150 days, and the average weight of Campbell variety grapes for 20 weeks was confirmed to compare the effects of our technical philosophy.
- Oxygen-generating compositions for hydroponic cultivation were prepared individually using 0.5% by weight of ferric citrate (Samjeon Pure Pharmaceutical) storage solution and 50% by weight ammonium persulfate (Ammonium persulfate) storage solution.
- Agrosol liquid fertilizer [Agrobiz Co., Ltd.] with a nitrogen-phosphate-potassium concentration ratio of 20-20-20% by weight is used as a source of oxygen to ensure a concentration of 10 ppm as a common source for securing the quality and quantity of crops. It was mixed with a diluted solution of phosphorus hydrogen peroxide, and this mixed solution was continuously supplied to the nutrient solution culture medium at a rate of about 2.5 ml per minute.
- the period of cultivating ripe tomatoes was 5 months, and in order to compare the effects of our technical ideas, the average weight of 500 ripe tomatoes harvested over 5 months was confirmed.
- the storage solution of zinc acetate trihydrate was diluted with water to a concentration of 900 ppm, the diluted zinc acetate trihydrate solution was filled into a 1 liter container connected to a drain line, and 5,000 ppm was added to another 1 liter container connected to a drain line. A concentrated sodium persulfate solution was filled.
- a container filled with zinc acetate trihydrate solution and a container filled with hydrogen peroxide were hung on the stems of 20 apple trees, and zinc acetate trihydrate solution diluted to 900 ppm concentration and sodium persulfate solution diluted to 5,000 ppm concentration were administered at a rate of 5 per minute. It was controlled to be discharged to the surface of apple trees at the level of ml, and supplied to the soil seven times at three-day intervals during the apple cultivation period, starting from early March (March 2), which is the sap movement period of apples (when water is sucked from the soil).
- Agrosol liquid fertilizer [Agrobiz Co., Ltd.] with a nitrogen-phosphate-potassium concentration ratio of 20-20-20% by weight is diluted in water. So, 20 apple trees were irrigated at 5-day intervals.
- the apple cultivation period was 8 months, and the average weight of apples per 20 plants (trees) was confirmed to compare the effects of our technology philosophy.
- Example 1 10.4 - - - - Example 2 - 5.74 - - - Example 3 - - 363 - - Example 4 - - - 284 - Example 5 - - - - 504 Comparison example 1 7.68 - - - - Comparison example 2 - 4.23 - - - Comparison example 3 - - 294 - - Comparison example 4 - - - 262- - Comparison example 5 - - - - - 476
- the average weight of watermelon was 7.68 kg, and in the case of cabbage, the average weight was 4.23 kg per head.
- the average weight was expressed in kg, in the case of grapes, the average weight was 294 g per bunch, in the case of ripe tomatoes, the average weight was 262 g per piece, and in the case of apples, the average weight was 476 g. did.
- the watermelon averages according to the growth and development activity of the roots due to sufficient oxygen supply during root respiration of plants growing in the soil. It was found that the weight increased significantly to 10.4 kg, in the case of cabbage, the average weight increased to 5.74 kg per bunch, and in the case of grapes, it was found that the average weight increased to 363 g per bunch, and in the case of ripe tomatoes, the average weight increased to 363 g per bunch. In the case of , the average weight increased to 284 g, and in the case of Busa apples, an apple crop with 504 g was harvested.
- the composition of the oxygen generating catalyst is sprayed on the soil immediately after spraying, or as needed, after an appropriate date has passed.
- the oxygen-generating catalyst composition of the metal salt already present in the soil is later supplied with the oxygen-generating composition, sprayed by a supply means of hydrogen peroxide or persulfate, or drained.
- the oxygen generating catalyst composition of metal salt and the oxygen generating composition of hydrogen peroxide or persulfate are individually filled in a container connected to a line, and the metal salt is slowly discharged to the soil surface of the crop cultivation area through the drain line of the container.
- the mixing process provides a long-term stable supply of oxygen in the soil through a chemical reaction of hydrogen peroxide or persulfate, resulting in the possibility of producing a large number of high-quality crops by activating root respiration. It is expected to greatly contribute to creating economic profits for farms and securing their technical competitiveness by improving crop growth and increasing productivity while minimizing labor.
- Figure 1 shows in the form of a photograph an example of an embodiment for applying the technical idea of the present application to oxygen farming on a wide cultivation area targeting short crops
- Figure 2 shows oxygen farming on individual crops targeting tall crops. Since examples of embodiments for application are shown in photographic form, there is no need for separate explanation of symbols.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Toxicology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Soil Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Cultivation Of Plants (AREA)
Abstract
Description
본 발명은 토양재배와 양액재배에 의한 작물을 재배하는 과정 중 토양 및 수중에서 자라고 있는 식물의 뿌리가 호흡할 때 충분한 산소 공급에 의해 뿌리의 근착 및 발육활성을 극대화하여 작물의 품질과 생산량이 향상될 수 있는 작물의 산소농법 구현을 위해 작물 재배지에 산소를 오랫 동안 공급할 수 있는 산소발생 기능조성물 및 이를 이용한 영농방법 관련 기술분야의 발명이다.The present invention improves the quality and production of crops by maximizing root attachment and developmental activity by supplying sufficient oxygen when the roots of plants growing in soil and water breathe during the process of cultivating crops by soil cultivation and nutrient solution cultivation. This is an invention in the field of technology related to an oxygen-generating functional composition that can supply oxygen to crop fields for a long time and a farming method using the same in order to implement oxygen farming for crops.
작물을 재배하는 과정 중 뿌리가 발근되어 생장하는데는 토양 중의 공기(산소) 및 온도와 연관되어 뿌리의 호흡작용, 효소작용 및 미생물의 활동, 뿌리 근균류의 작용 등은 토양 중의 공기와 밀접한 관계가 있다. During the process of cultivating crops, the rooting and growth of roots is related to the air (oxygen) and temperature in the soil, and the respiration of the roots, the activity of enzymes and microorganisms, and the action of root fungi are closely related to the air in the soil. there is.
수목은 일반적으로 뿌리가 깊으므로 공기유통이 불량하여 지표면의 세근과 같이 잘 발달되지 못하므로 지표면은 물론 지하부의 깊은 곳까지 세근의 발달을 유도하여 수목을 건전하게 육성하는 것이 중요하다. Since trees generally have deep roots, air circulation is poor and they do not develop as well as the fine roots on the surface. Therefore, it is important to foster the trees soundly by encouraging the development of fine roots not only on the surface but also deep underground.
또한 뿌리의 호흡작용과 유기물의 분해로 생성되는 일산화탄소를 지상 위로 배출하고, 산소의 공급을 원활하게 하기 위해서는 토양 속의 공기량과 유통이 대단히 중요하다. In addition, the amount and distribution of air in the soil are very important in order to discharge carbon monoxide generated through root respiration and decomposition of organic matter above the ground and to facilitate the supply of oxygen.
식물이 튼튼하게 자라려면 뿌리가 튼튼해야 하고 식물 뿌리가 튼튼하게 자라려면 적당한 양분과 수분 뿐만 아니라 산소가 필요하다. For plants to grow strong, their roots must be strong, and for plant roots to grow strong, they need not only adequate nutrients and moisture, but also oxygen.
간과하기 쉬운 부분이지만, 식물도 잎 뿐만 아니라 뿌리를 통해서 호흡을 하고 뿌리 호흡이 원활해야 식물이 잘 자라게 되며 토양에서 기르는 경우에도 배수가 잘되도록 공기구멍을 만들기 위해 굵은 입자의 하얀 펄라이트를 섞어주는 방법이 적용되기도 한다. It's an easy part to overlook, but plants also breathe through roots as well as leaves, and root respiration must be smooth for plants to grow well. Even when grown in soil, a method of mixing white perlite with coarse particles to create air holes for good drainage This also applies.
하물며, 뿌리가 물속에 잠기는 양액재배에서는 산소가 부족해지기 더욱 쉽기 때문에 산소 공급에 항상 신경을 쓰는 것이 중요하며, 특히 여름철 양액 온도가 올라가게 되면, 식물의 산소 흡수 능력이 떨어지므로 산소를 잘 공급해 주는 것이 더욱 중요해진다. Moreover, in nutrient solution cultivation, where the roots are submerged in water, it is more likely to become deficient in oxygen, so it is important to always pay attention to oxygen supply. Especially in summer, when the temperature of the nutrient solution rises, the plant's ability to absorb oxygen decreases, so it is necessary to ensure a good supply of oxygen. becomes more important.
작물이 자라는데 필요한 최소의 산소 농도는 5 ppm이므로 이보다 낮아져서는 안되며, 식물 뿌리가 발육하는데 필요한 에너지는 호흡에 의해 얻어진 에너지로 생장이나 생리작용을 하므로 뿌리 부근의 용존산소량이 부족하면 급격한 호흡량의 저하로 인하여 대사 장해가 일어나 생장이 위축되고 특히 고온일수록 식물의 생육이 왕성하여 양분 흡수를 위해 산소 요구량이 증가하는데 비해, 공급 용수의 용존산소 농도는 급격히 저하되어 생육의 제한 요인이 된다. The minimum oxygen concentration required for crop growth is 5 ppm, so it should not be lower than this. The energy required for plant root development is the energy obtained through respiration for growth and physiological functions, so if the amount of dissolved oxygen near the roots is insufficient, a rapid decrease in respiration can occur. As a result, metabolic disorders occur and growth is reduced. In particular, at higher temperatures, plants grow more vigorously and oxygen requirements increase for nutrient absorption, but the dissolved oxygen concentration in the supplied water rapidly decreases, becoming a limiting factor for growth.
이 때 용존산소 농도를 높여 주지 않고, 2~3시간 지속시키면 용존산소가 고갈되어 2 ppm 이하가 될 경우 고사될 우려가 있는 반면 용존산소를 충분히 공급하여주면 작물의 양분 및 수분 공급이 원할해지고, 작물의 생장이 좋아져 품질향상 및 생산량도 20 % 이상 증대되는 효과를 거둘 수 있다.At this time, if the dissolved oxygen concentration is not increased and continued for 2 to 3 hours, dissolved oxygen will be depleted and there is a risk of death if it falls below 2 ppm. However, if dissolved oxygen is sufficiently supplied, nutrients and moisture supply to the crop will be smooth. The growth of crops improves, resulting in improved quality and increased production by more than 20%.
이를 위한 산소농법은 작물이 기본적으로 필요로 하는 뿌리호흡 산소요구량 20 ppm과 그 이상을 공급하여 작물의 대사작용인 이화작용/생화학 작용을 극대화시키고 이에 따른 광합성작용의 에너지 효율을 최대로 끌어 올림으로서, 작물의 영양성장과 생식성장에 있어 가장 중요한 조건인 지하부 뿌리에 뿌리 생육 에너지를 기존 농법(13:3:0) 대비 2배 이상을 공급하여 토양 및 수중의 뿌리 활착을 극대화하고 그 최장 수명시간을 보장할 수 있는 방안이 요구된다. Oxygen farming for this purpose maximizes the catabolic/biochemical functions of the crop's metabolism by supplying 20 ppm or more of the basic oxygen requirement for root respiration and thereby maximizing the energy efficiency of photosynthesis. , By supplying more than twice the root growth energy to the underground roots, which is the most important condition for the nutritional and reproductive growth of crops, compared to the existing farming method (13:3:0), maximizing root establishment in the soil and water and the longest lifespan A plan to guarantee is required.
만약 토양재배 및 양액재배 시 토양과 수중 내의 뿌리산소가 풍부할 경우 뿌리 호흡 및 활착의 최적화, 이화, 동화, 생화학 작용의 극대화, 양분 또는 수분 흡수율의 극대화, 대사 작용의 정상화, 작물 저항력 강화, 추비와 농약 사용의 감소, 작물의 발육상태 최대 안정화, 생산량 증가 및 상품성 증가, 염류집적현상 극복 및 해소, 가스장해나 연작장해의 극복 및 해소를 도모하고 토양재배 및 양액재배의 생육환경 개선을 비롯하여 작물의 생육환경을 크게 개선시킬 수 있는 방안이 필요하다.If root oxygen in the soil and water is abundant during soil cultivation and nutrient solution cultivation, optimization of root respiration and rooting, maximization of catabolism, assimilation, and biochemistry, maximization of nutrient or water absorption, normalization of metabolism, strengthening of crop resistance, and additional fertilization. and reduction of the use of pesticides, maximum stabilization of crop development status, increase in production and marketability, overcoming and resolving salt accumulation phenomenon, overcoming and resolving gas disturbances and continuous cropping disturbances, and improving the growth environment of soil cultivation and nutrient solution cultivation, as well as crop growth. A plan is needed to significantly improve the growing environment.
또한, 뿌리산소가 결핍될 경우 뿌리 활착의 저조 및 양수분 흡수 저하, 뿌리의 대사장해 초래, 이화. 동화, 생화학 작용 저조, 양분 손실 결과 초래, 과다한 추비, 염류 집적 원인, 병해충 저항력 저하에 의한 작물들이 제대로 성장하지 못함은 물론 에틸렌 생성이 많아져서 뿌리가 고사될 수 있는 문제점이 고려되어야 한다.In addition, if root oxygen is deficient, root survival is slowed, water absorption is reduced, metabolic disorders in the roots occur, and catabolism occurs. Problems that must be taken into consideration include low assimilation and biochemical activity, resulting in nutrient loss, excessive fertilization, salt accumulation, and low disease and pest resistance, which can cause crops to not grow properly, as well as cause root death due to increased ethylene production.
따라서 산소농법은 토양재배 및 양액재재 작물의 지하부 뿌리와 지상부의 잎, 줄기, 열매 생육의 근본적, 본성적인 활력과 생기를 갖게 함으로서 작물의 상품성 및 생산량을 증가시키고, 나아가 병?해충에 스스로 저항력을 갖도록 할 수 있는 것으로, 농가의 작물을 재배하는데 토양의 뿌리산소는 매우 중요하다 인정하고 있으나 그럼에도 불구하고, 기술력 부족으로 인하여 작물의 뿌리호흡을 위한 산소공급 기술이 미흡하거나 많은 경비가 소요되어 실질적으로 농가에서는 널리 이용하지 못하고 있는 실정에 있다. Therefore, oxygen farming increases the marketability and production of crops by providing fundamental and natural vitality and vitality to the underground roots and above-ground leaves, stems, and fruit growth of crops cultivated in soil and nutrient solution, and further increases their own resistance to diseases and pests. It is recognized that root oxygen in the soil is very important when growing crops for farmers. However, due to lack of technology, oxygen supply technology for root respiration of crops is insufficient or requires a lot of expense, making it virtually impossible to use. The reality is that it is not widely used by farmers.
결과적으로 노동력 및 경제적 규모가 작은 농가에서 저렴한 경비로 간편한 방법에 의해 토양재배 및 양액재배를 위한 작물의 뿌리 호흡을 활성화하기 위한 방법이 미진하거나 전무한 실정에 있다. As a result, there is little or no method for activating root respiration of crops for soil cultivation and nutrient solution cultivation by simple methods at low cost in farms with small labor force and economic scale.
지금까지 토양재배 및 양액재배를 통한 작물의 재배과정 중 산소의 뿌리호흡을 위한 산소농법을 구현하기 위해 개시된 선행기술을 살펴보면 다음과 같다.The prior technologies disclosed so far to implement oxygen farming for root respiration during the cultivation process of crops through soil cultivation and nutrient solution cultivation are as follows.
한국공개특허 출원번호 10-2020-0031826에서는 중심부의 제올라이트덩어리, 분해촉매를 포함하고 상기 제올라이트덩어리의 외면을 감싸는 과산화칼슘 내피와, 상기 과산화칼 슘내피의 외면을 감싸는 슬래그 외피로 구성되는 것을 특징으로 하는 산소발생 미네랄 비료가 제시되어 있다. Korean Patent Application No. 10-2020-0031826 is characterized in that it is composed of a zeolite lump in the center, a calcium peroxide inner shell containing a decomposition catalyst and surrounding the outer surface of the zeolite lump, and a slag outer skin surrounding the outer surface of the calcium peroxide inner skin. An oxygen-generating mineral fertilizer is presented.
한국공개특허 출원번호 10-2018-0100503에서는 배수구가 없는 화분에서 식물을 재배하도록 하는 공기층이 있는 저면 급수용 식물 재배 상자가 제시되어 있다.Korean Patent Application No. 10-2018-0100503 presents a plant cultivation box for bottom watering with an air layer that allows plants to be grown in pots without drainage holes.
한국공개특허 출원번호 10-2009-0098349에서는 마이크로버블장치를 이용한 산소농법 시스템이 제시되고 있다.In Korean Patent Application No. 10-2009-0098349, an oxygen farming system using a microbubble device is proposed.
한국공개특허 출원번호 10-2020-0170459에서는 2Na2CO3·3H2O2; K2O; Ca(OH)2; CaCO3; 및 수용성 산을 포함하는 산소발생제 조성물과 이의 제조방법이 제시되고 있다. In Korean Patent Application No. 10-2020-0170459, 2Na 2 CO 3 · 3H 2 O 2 ; K2O ; Ca(OH) 2 ; CaCO 3 ; and an oxygen generator composition containing a water-soluble acid and a method for producing the same are presented.
한국공개특허 출원번호 10-2020-0125838에서는 환원된 그래핀옥사이드 지지체 상에 커켄들(Kirkendall) 효과로 인해, 사산화삼코발트(Co3O4) 중공(hollow) 나노입자가 분산된 구조를 가짐으로써, 수전해에 적합한 전기화학 반응 활성을 가지며, 산성 고전위 조건 하에서 촉매 안정성이 현저히 향상되는 산소발생반응용 코발트 촉매 및 그 제조방법이 제시되어 있다. In Korean Patent Application No. 10-2020-0125838, due to the Kirkendall effect on the reduced graphene oxide support, cobalt trioxide (Co 3 O 4 ) hollow nanoparticles have a dispersed structure, A cobalt catalyst for oxygen evolution reaction that has electrochemical reaction activity suitable for water electrolysis and significantly improves catalyst stability under acidic high potential conditions and a method of manufacturing the same are presented.
한국공개특허 출원번호 10-2020-0143784에서는 균질 흡입공기를 이용한 산소발생장치가 제시되어 있으며, 한국 공개특10-2017-0008933에서는 산소발생 물질인 과산화칼륨(K2O2), 초산화칼륨(KO2) 및 과산화나트륨(Na2O2)의 혼합물 30~60중량%; 및 활성탄, 제올라이트, 이산화규소에서 선택된 1종 이상의 반응조절제 40~70 중량%로 구성되고, 구연산, 인산칼륨, 글루타민산, 아스코빅산, 타르타릭산, 살리실릭산, 글라이콜릭산, 락틱산, 글리시리직산, 아미노카프로익산으로 이루어진 군에서 선택된 1종 이상의 중화제를 상기 혼합물 함량의 1~3배 포함하여 구성되는 것을 특징으로 하는 산소발생제 조성물이 제시되어 있다. In Korean Patent Application No. 10-2020-0143784, an oxygen generator using homogeneous intake air is proposed, and in Korean Patent Publication No. 10-2017-0008933, oxygen generating substances potassium peroxide (K 2 O 2 ) and potassium acetate ( 30 to 60% by weight of a mixture of KO 2 ) and sodium peroxide (Na 2 O 2 ); and 40 to 70% by weight of one or more reaction regulators selected from activated carbon, zeolite, and silicon dioxide, and citric acid, potassium phosphate, glutamic acid, ascorbic acid, tartaric acid, salicylic acid, glycolic acid, lactic acid, and glycolic acid. An oxygen generator composition is presented, which is characterized in that it contains 1 to 3 times the amount of the mixture with one or more neutralizing agents selected from the group consisting of silicic acid and aminocaproic acid.
한국공개특허 출원번호 10-2017-0047422에서는 용존산소량을 조절할 수 있는 담액수경 시스템을 제시하고 있다. Korean Patent Application No. 10-2017-0047422 proposes a liquid aquaponic system that can control the amount of dissolved oxygen.
한국공개특허 출원번호 10-2015-0082577에서는 1차 다공판 및 복수개의 2차 다공판을 포함하는 초미세기포 생성 장치를 수경 재배 용기와 결합시킴으로서 수경 재배에 초미세기포 산소 용해수를 이용할 수 있는 초미세기포 생성 장치를 포함하는 수경재배기를 제시하고 있다.In Korean Patent Application No. 10-2015-0082577, an ultra-fine bubble generating device including a primary porous plate and a plurality of secondary porous plates is combined with a hydroponic cultivation container to use ultra-fine bubble oxygen dissolved water for hydroponic cultivation. A hydroponic cultivator including an ultra-fine bubble generating device is presented.
한국공개특허 출원번호 10-2014-0093075에서는 수경재배용 수조의 4면 상단에 3단 절곡 부위를 만들어 수조의 담수 중량으로 인한 수조의 휘어짐을 방지하기 위한 배드고정거치 장치와 나노버블 생성장치가 있는 인삼 수경재배용 수조장치를 제시하고 있다. In Korean Patent Application No. 10-2014-0093075, a ginseng plant with a bed fixing device and a nanobubble generating device is created by creating a three-stage bending area on the top of the four sides of the hydroponic cultivation tank to prevent the tank from bending due to the weight of fresh water in the tank. A water tank device for hydroponic cultivation is presented.
그러나 상기와 같은 종래기술에서는 본원과 같이 토양재배나 양액재배에서 작물을 재배하는 과정 중 작물 뿌리에 임의로 선택되는 필요한 시기에 산소를 공급하거나 토양의 상부에 물로 희석된 염(Salt) 상태의 산소발생 촉매와 희석된 과산화 소스(Source)의 조성물이 배수라인이 연결된 링거병(Ringer bottle)과 같은 형태의 용기에 개별적으로 충진되도록 구성되고, 산소에 의한 뿌리호흡이 필요한 작물에 산소발생 촉매와 희석된 과산화 소스(Source)의 조성물이 토양에 개별적으로 서서히 공급하여 산소 공급에 의한 작물의 기초대사 활동을 활발하게 하고, 작물 자체에 지하부 생육균형을 정상적으로 유지해 갈 수 있도록 안정적이고, 적극적인 농법을 제공하여 건강한 뿌리를 제공하여 노동력 및 생산비를 줄이고, 수확량을 증가시켜 농가 소득을 향상시키는 산소농법의 구현기술이 개시된바 없음을 확인하고, 개발된 신규의 기술이다.However, in the above-described prior art, oxygen is supplied to the crop roots at a randomly selected necessary time during the process of cultivating crops in soil cultivation or nutrient solution cultivation, as in the present invention, or oxygen is generated in a salt state diluted with water in the upper part of the soil. The composition of the catalyst and the diluted peroxide source is configured to be individually filled in a container shaped like a Ringer bottle connected to a drainage line, and the oxygen generating catalyst and the diluted composition are used for crops that require root respiration by oxygen. The composition of the peroxide source is gradually supplied to the soil individually, activating the basic metabolic activity of the crop by supplying oxygen, and providing a stable and active farming method to maintain normal growth balance in the underground part of the crop itself. This is a new technology developed after confirming that there has been no known technology for implementing oxygen farming, which reduces labor and production costs by providing roots and improves farm income by increasing yield.
본원은 작물의 기본 생육활동 뿌리호흡에 필요로 하는 산소요구량은 12 ppm 이상의 농도를 유지하는 것이 바람직한데 대부분 작물 재배를 위해 공급되는 물에 포함된 용존산소량은 평균 5 ppm 이하의 농도를 유지하고 있으므로 작물을 재배할 때 정상적인 생육활동을 위해 용존산소가 높은 물이 필요하나 수중에 용존된 산소는 온도가 올라가거나 주변환경 변화에 따라 수중 용존 산소 양이 낮아지는 결과가 되고 뿌리 부근의 용존산소량이 부족하게 되면 호흡량 저하로 대사장해가 일어나 생장에 위축될 우려를 배제할 기술로 산소를 오랫 동안 공급할 수 있는 기능조성물이 필요함을 인식하여 개발된 기술이다.We recommend that the concentration of oxygen required for root respiration, the basic growth activity of crops, be maintained at a concentration of 12 ppm or higher, but the dissolved oxygen contained in water supplied for most crop cultivation is maintained at an average concentration of 5 ppm or less. When growing crops, water with high dissolved oxygen is required for normal growth, but as the temperature rises or the surrounding environment changes, the amount of dissolved oxygen in the water decreases, resulting in a lack of dissolved oxygen near the roots. This technology was developed in recognition of the need for a functional composition that can supply oxygen for a long time as a technology that eliminates the risk of growth retardation due to metabolic disorders due to decreased respiratory rate.
본원은 토양재배 및 양액재배 과정 중 작물 뿌리에 산소 공급이 필요할 때 간단하고, 편리한 수단에 의해 식물이 기본적으로 필요로 하는 뿌리호흡 산소요구량을 극대화시켜 작물의 상품성 및 생산량을 증대시키고, 생산비를 감소시켜 기존 농업 대비 농가의 소득을 증대시킴은 물론 병해충에 대한 저항력을 가지면서 작물의 개선된 생육환경을 제공하는 작물의 산소농법 구현을 위해 산소를 오랫 동안 공급할 수 있는 산소발생 기능조성물을 제공하고 이를 이용한 영농방법을 제공하고자 하는 목적을 갖는다. When oxygen supply is needed to the roots of crops during the soil cultivation and nutrient solution cultivation process, our center maximizes the oxygen demand for root respiration, which is fundamentally needed by plants, through simple and convenient means, thereby increasing the marketability and production of crops and reducing production costs. We provide an oxygen-generating functional composition that can supply oxygen for a long time to implement oxygen farming of crops, which not only increases the income of farmers compared to existing agriculture, but also provides an improved growth environment for crops while maintaining resistance to diseases and pests. The purpose is to provide agricultural methods using agricultural methods.
상기 목적을 달성하기 위한 수단으로 본원에서 개시되는 기술사상은 토양재배 및 양액재배 과정 중 농작물의 뿌리호흡 산소요구량을 극대화시켜 산소농법을 구현시키기 위한 작물재배용 산소발생 기능성 조성물을 제공하기 위한 기술인 바, 알루미늄(Al), 티타늄(Ti), 크롬(Cr), 망간(Mn), 철(Fe), 코발트(Co), 니켈(Ni), 구리(Cu), 아연(Zn), 텅스텐(W) 중에서 선택되어지는 무기물(Inorganic)이 황산염(Sulfate), 염화물(Chloride), 질산염(Nitrate), 초산염(Acetate), 인산염(Phosphate), 불화염(Fluoride), 킬레이트제로 결합된 염(Salt) 형태 중에서 하나가 선택되어 0.05 ~ 25 중량% 농도로 수중 용해된 산소발생 촉매 조성물이 저장되는 A용액과 과산화수소(H2O2) 또는 과황산염(Persulfate)이 50 중량% 이하 농도로 수중 용해된 산소발생 조성물이 저장되는 B용액이 각각 개별적으로 구성되고, 예를 들어 채소와 같이 크기가 비교적 작은 작물을 대상으로 산소농법을 적용하기 위해 10 ppm ~ 900 ppm 농도로 희석된 금속 염(Salt) 상태의 산소발생 촉매로 이루어지는 A 용액 조성물이 토양 재배지나 또는 양액재배지의 수중에 1차적 공급수단에 의해 살포되어 지도록 적용되고, 곧바로 또는 추후 일정한 기간이 경과한 후 작물의 뿌리 호흡이 필요로 할 경우 산소 소스(Source)의 B 용액 조성물인 과산화수소(H2O2) 또는 과황산염 조성물인 B용액이 25 ppm ~ 5,000 ppm 농도로 희석되어 공급되도록 적용될 수 있다.The technical idea disclosed herein as a means to achieve the above objective is a technology for providing an oxygen-generating functional composition for crop cultivation to implement oxygen farming by maximizing the oxygen demand for root respiration of crops during the soil cultivation and nutrient solution cultivation process, Among aluminum (Al), titanium (Ti), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), and tungsten (W). The selected inorganic is one of Sulfate, Chloride, Nitrate, Acetate, Phosphate, Fluoride, and Salt combined with a chelating agent. is selected to store the oxygen-generating catalyst composition dissolved in water at a concentration of 0.05 to 25% by weight, and the oxygen-generating composition in which hydrogen peroxide (H 2 O 2 ) or persulfate is dissolved in water at a concentration of 50% by weight or less. An oxygen-generating catalyst in the form of a metal salt (salt) in which each stored B solution is individually composed and diluted to a concentration of 10 ppm to 900 ppm to apply oxygen farming to relatively small crops, such as vegetables. A solution composition consisting of is applied to be sprayed into the soil or nutrient solution cultivation area by primary supply means, and when root respiration of crops is required immediately or after a certain period of time, it is used as an oxygen source. The B solution composition of hydrogen peroxide (H 2 O 2 ) or the B solution of the persulfate composition may be applied to be supplied diluted to a concentration of 25 ppm to 5,000 ppm.
또 다른 실시양태로 사과, 복숭아, 배와 같이 작물의 크기가 크고 작물과 작물과의 거리가 큰 농작물을 대상으로 산소농법을 적용하기 원할 때는 A용액과 B용액 성분은 동일하고, A용액을 10 ppm ~ 900 ppm의 농도로 희석하여 배수라인 및 배출수단이 부착된 용기(A-1)에 저류하고, B용액을 25 ppm ~ 5,000 ppm 농도로 희석하여 배수라인 및 배출수단이 부착된 용기(B-1)에 저류하고 농작물 재배지에 살포되는 D수단으로 적용되어 농작물의 산소농법을 구현시켜 다수확 재배가 가능할 수 있음을 확인하여 완성된 발명이다. In another embodiment, when it is desired to apply oxygen farming to crops such as apples, peaches, and pears that are large in size and have a large distance between the crops, the components of solution A and B are the same, and solution A is mixed with 10 Dilute the solution to a concentration of 25 ppm to 5,000 ppm and store it in a container (A-1) equipped with a drain line and a discharge means, and dilute solution B to a concentration of 25 ppm to 5,000 ppm and store it in a container (B) equipped with a drain line and a discharge means. This invention was completed by confirming that high-yield cultivation can be achieved by implementing oxygen farming of crops by applying it as a D means that is stored in -1) and sprayed on crop fields.
따라서 본원 기술사상은 농작물의 뿌리호흡에 필요한 산소요구량을 극대화시켜 산소농법을 구현시켜 다수확 재배가 가능하도록 적용되는 영농방법에서, Therefore, our technical philosophy is a farming method applied to enable high-yield cultivation by realizing oxygen farming by maximizing the oxygen demand required for root respiration of crops,
알루미늄(Al), 티타늄(Ti), 크롬(Cr), 망간(Mn), 철(Fe), 코발트(Co), 니켈(Ni), 구리(Cu), 아연(Zn), 텅스텐(W) 중에서 선택되어지는 무기물(Inorganic)이 황산염(Sulfate), 염화물(Chloride), 질산염(Nitrate), 초산염(Acetate), 인산염(Phosphate), 불화염(Fluoride), 킬레이트제로 결합된 염(Salt) 형태 중에서 하나가 선택되어 0.05 ~ 25 중량% 농도로 수중 용해된 산소발생 촉매 조성물이 저장되는 A용액과 과산화수소(H2O2) 또는 과황산염(Persulfate)이 50 중량% 이하 농도로 수중 용해된 산소발생 조성물이 저장되는 B용액이 각각 개별적으로 구성되고,농작물 재배 환경에 따라 토양에 A용액이 먼저 10 ppm ~ 900 ppm의 농도범위로 희석되어 살포된 후 B용액이 25 ppm ~ 5,000 ppm 농도로 희석되어 농작물 재배지에 살포되는 C수단으로 적용되거나 또는 농작물 재배 환경에 따라 A용액을 10 ppm ~ 900 ppm의 농도로 희석하여 배수라인 및 배출수단이 부착된 용기(A-1)에 저류하고 B용액을 25 ppm ~ 5,000 ppm 농도로 희석하여 배수라인 및 배출수단이 부착된 용기(B-1)에 저류하고 농작물 재배지에 살포되는 D수단으로 적용되어 농작물의 산소농법을 구현시켜 다수확 재배가 가능하도록 적용되는 영농방법으로 구현될 수 있다.Among aluminum (Al), titanium (Ti), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), and tungsten (W). The selected inorganic is one of Sulfate, Chloride, Nitrate, Acetate, Phosphate, Fluoride, and Salt combined with a chelating agent. is selected to store the oxygen-generating catalyst composition dissolved in water at a concentration of 0.05 to 25% by weight, and the oxygen-generating composition in which hydrogen peroxide (H 2 O 2 ) or persulfate is dissolved in water at a concentration of 50% by weight or less. Each stored B solution is individually composed, and depending on the crop cultivation environment, A solution is first diluted and sprayed on the soil to a concentration range of 10 ppm to 900 ppm, and then B solution is diluted to a concentration range of 25 ppm to 5,000 ppm and sprayed on the soil. It is applied as means C, which is sprayed on or, depending on the crop cultivation environment, solution A is diluted to a concentration of 10 ppm ~ 900 ppm and stored in a container (A-1) equipped with a drainage line and discharge means, and solution B is diluted to a concentration of 10 ppm ~ 900 ppm. It is a farming method that is diluted to a concentration of 5,000 ppm, stored in a container (B-1) equipped with a drainage line and discharge means, and applied as a D means to be sprayed on crop fields to implement oxygen farming of crops and enable high-yield cultivation. It can be implemented.
본원기술에 사용되는 상기 A용액 또는 B용액 조성물에 살충제, 살균제, 비료성분, 영양성분 중에서 선택되어 작물 재배에 필요한 성분이 추가 적용되어 농작물의 산소농법을 구현시켜 다수확 재배가 가능하도록 적용될 수 있음은 물론이다.The composition of solution A or solution B used in the present technology can be selected from pesticides, fungicides, fertilizer ingredients, and nutrients, and additional ingredients necessary for crop cultivation can be applied to enable high-yield cultivation by implementing oxygen farming of crops. Of course.
상기 킬레이트제로 결합된 염(Salt)을 얻을 때 킬레이트제는 이디티에이(EDTA, Ethylene-diamine-tetraacetic acid), 디티피에이(DTPA, Diethylenetriamine pentaacetic acid), 이디디헤치에이(EDDHA, [Ethylenediamine-N,N′-bis(2-hydroxyphenylacetic acid), 엔티에이(NTA, Nitrilitriacetic acid), 싸이클로 디티에이(CyDTA(1,2-cyclo-hexadiamine tetraacetic acid), 이디디에스(EDDS, Ethylenediaminedisuccinic acid), 엠지디에이(MGDA(Methylglycinediacetic acid), 이지티에이(EGTA, Ethyleneglycoltetraacetic acid), 디시티에이(DCTA, Ethyleneglycoltetraacetic acid), 지엘디에이(GLDA, Glutamic acid diacetic acid), 아이디에스(IDS, 아미노디숙신산), 푸마르산(Fumaric acid), 젖산(Lactic acid), 구연산(Citric acid), 사과산(Malic acid), 뷰티르산(Butyric acid), 개미산(Formic acid), 프로피온산(Propionic acid acid), 아스코빈산(Ascorbic acid), 아미노산(Amino acids), 펄빅산(Fulvic acid), 휴믹산(Humic acid), 카르복실산(Carboxylic acid), 설핀산(Sulfinic acid), 설폰산(Sulfonic acid), 설파민산(Sulfamic acid) 중 선택되어지는 1종 이상의 킬레이트제를 사용할 수 있다. When obtaining a salt combined with the chelating agent, the chelating agent is EDTA (Ethylene-diamine-tetraacetic acid), DTPA (Dithylenetriamine pentaacetic acid), EDDHA (Ethylenediamine-N, N′-bis (2-hydroxyphenylacetic acid), NTA (Nitrilitriacetic acid), CyDTA (1,2-cyclo-hexadiamine tetraacetic acid), EDDS (Ethylenediaminedisuccinic acid), MGDA (Methylglycinediacetic acid), EGTA (Ethyleneglycoltetraacetic acid), DCTA (Ethyleneglycoltetraacetic acid), GLDA (Glutamic acid diacetic acid), IDS (Aminodisuccinic acid), Fumaric acid, Lactic acid (Lactic acid), Citric acid, Malic acid, Butyric acid, Formic acid, Propionic acid, Ascorbic acid, Amino acids, One or more chelating agents selected from Fulvic acid, Humic acid, Carboxylic acid, Sulfinic acid, Sulfonic acid, and Sulfamic acid can be used.
또한 상기 과황산염은 과황산암모늄, 과황산나트륨, 과황산칼륨 중에서 하나가 선택되어 사용될 수 있다.Additionally, the persulfate may be selected from among ammonium persulfate, sodium persulfate, and potassium persulfate.
이상에서 살펴본 바와 같이 본원은 상기 배경기술에서 밝히고 있듯이 작물을 재배하는 과정 중 필요에 따라 임의의 형태로 토양재배지의 토양이나 양액재배지의 수중에 산소를 오랫 동안 공급할 수 있도록 하여 산소 농도를 증가시켜 결과적으로 왕성한 뿌리생육 제공, 뿌리 영양 흡수력 증대, 광합성 산물 증대, 작물 생육 에너지 왕성 현상을 통해 작물의 열매 발육의 왕성을 제공함에 따라 농가의 노동력은 최소화하면서 작물의 상품성 향상, 생산량 증가는 물론 병,해충 저항력 증대에 의한 농가의 경제적 이익 창출 및 농가의 기술적 경쟁력을 확보하는데 효과를 제공할수 있을 것으로 기대된다.As discussed above, as stated in the background technology, this institute increases the oxygen concentration by supplying oxygen to the soil of the soil cultivation area or the water of the nutrient solution cultivation area for a long time in any form as needed during the process of cultivating crops, resulting in an increase in oxygen concentration. By providing vigorous root growth, increased root nutrient absorption, increased photosynthetic products, and active crop growth energy, it provides active fruit development of crops, minimizing farm labor while improving the marketability of crops, increasing production, and eliminating diseases and pests. It is expected that it will be effective in creating economic benefits for farms and securing technical competitiveness of farms by increasing resistance.
도 1: 본 발명의 키가 작은 작물을 대상으로 넓은 재배지의 산소농법을 적용하기 위한 실시양태 예시도Figure 1: Illustration of an embodiment for applying the oxygen farming method of the present invention to short crops in a large cultivation area
도 2: 본 발명의 키가 큰 작물을 대상으로 개별적 작물에 산소농법을 적용하기 위한 실시양태 예시도Figure 2: Illustration of an embodiment for applying oxygen farming to individual tall crops of the present invention
본원의 기술사상을 구현하기 위한 발명의 실시내용을 실시예 형태로 기재하기에 앞서, 본 출원의 명세서나 청구범위에 사용된 용어나 단어는 통상적이거나 사전적인 의미로 한정해서 해석되어서는 아니 될 것이며, 본원의 보호범위는 본원발명의 기술적 사상에 부합하는 의미와 개념으로 해석되어야만 할 것이며, 본 명세서에 기재된 예시는 본 발명의 가장 바람직한 일 실시 예에 불과할 뿐이고 본원의 기술사상을 모두 대변하는 것은 아니므로, 본 출원시점에 있어서 이들을 대체할 수 있는 다양한 균등물과 변형 예들이 있을 수 있음을 이해하여야 할 것이다.Prior to describing the implementation of the invention in the form of embodiments for implementing the technical idea of the present application, the terms or words used in the specification or claims of the present application should not be construed as limited to the ordinary or dictionary meaning. , the scope of protection of the present application should be interpreted as meaning and concept consistent with the technical idea of the present invention, and the examples described in this specification are only one of the most preferred embodiments of the present invention and do not represent all of the technical idea of the present invention. Therefore, it should be understood that at the time of filing this application, there may be various equivalents and modifications that can replace them.
실시 예 1Example 1
본원의 기술구성을 구현하기 위하여 산소발생 촉매 조성물로 25 중량 %의 황산알루미늄6~8 수화물[삼전순약, Al2(SO4)3·6-8H2O]의 저장용액을 준비하고, 산소발생 조성물로 35 중량%의 과산화수소(대명케미칼, H2O2)의 저장용액을 준비하였다.In order to implement the technical composition of the present application, a storage solution of 25% by weight of aluminum sulfate 6-8 hydrate (Samjeon Pure Pharmaceutical, Al 2 (SO 4 ) 3· 6-8H 2 O) was prepared as an oxygen generation catalyst composition, and oxygen generation was performed. A storage solution of 35% by weight of hydrogen peroxide (Daemyung Chemical, H 2 O 2 ) was prepared as a composition.
황산알루미늄의 저장용액을 물로 희석하여 40 ppm 농도로 희석하고, 희석된 황산알루미늄 용액을 수박을 재배하기 위한 660 ㎡ 비닐하우스의 토양에 균일하게 뿌려준 후 하루가 경과한 다음 100 ppm 농도로 희석된 과산화수소 용액을 토양에 균일하게 뿌려주어 토양에 수박 재배를 위한 경작 토양용 산소 발생 조성물을 10일 간격으로 수박 재배기간 동안 토양에 공급하였으며, 수박 재배기간 동안 수박의 품질 및 수량 확보를 위한 통상적인 공급원으로 질소-인산-칼륨의 농도비율이 20-20-20 중량%인 아그로솔 액상비료[(주)아그로비즈] 1 kg을 물에 희석하여 3일 간격으로 330 ㎡에 관주하였다. The storage solution of aluminum sulfate was diluted with water to a concentration of 40 ppm, and the diluted aluminum sulfate solution was evenly sprinkled on the soil of a 660 ㎡ greenhouse for growing watermelons. One day later, hydrogen peroxide diluted to a concentration of 100 ppm was added. The solution was sprinkled uniformly on the soil and the oxygen-generating composition for cultivated soil for watermelon cultivation was supplied to the soil at intervals of 10 days during the watermelon cultivation period. It was used as a normal source to ensure the quality and quantity of watermelons during the watermelon cultivation period. 1 kg of Agrosol liquid fertilizer [Agrobiz Co., Ltd.] with a nitrogen-phosphate-potassium concentration ratio of 20-20-20% by weight was diluted in water and drenched at 330 ㎡ at intervals of 3 days.
이 때 수박을 재배하는 기간은 120일로 하였으며, 본원의 기술사상에 의한 효과를 비교하기 위하여 수확한 450 개 수박의 평균 무게를 확인하였다. At this time, the watermelon cultivation period was 120 days, and the average weight of 450 watermelons harvested was confirmed to compare the effects of our technology philosophy.
실시 예 2Example 2
산소발생 촉매 조성물로 25 중량 %의 염화철6수화물[삼전순약, FeCl3·6H2O]의 저장용액을 준비하고, 산소발생 조성물로 35 중량%의 과산화수소(대명케미칼, H2O2)의 저장용액을 준비하였다. 염화철6수화물의 저장용액을 물로 희석하여 10 ppm 농도로 희석하고, 희석된 염화철6수화물 용액을 배추를 재배하기 위한 660 ㎡ 비닐하우스의 토양에 균일하게 뿌려준 후 곧바로 25 ppm 농도로 희석된 과산화수소 용액을 토양에 균일하게 뿌려주어 토양에 배추재배를 위한 경작 토양용 산소 발생 조성물을 13일 간격으로 배추 재배기간 동안 토양에 공급하였으며, 배추 재배기간 동안 배추의 품질 및 수량 확보를 위한 통상적인 공급원으로 질소-인산-칼륨의 농도비율이 20-20-20 중량%인 아그로솔 액상비료[(주)아그로비즈] 1 kg을 물에 희석하여 3일 간격으로 330 ㎡에 관주하였다. Prepare a storage solution of 25% by weight of iron chloride hexahydrate [Samjeon Pure Pharmaceutical, FeCl 3 ·6H 2 O] as an oxygen generating catalyst composition, and store 35% by weight of hydrogen peroxide (Daemyung Chemical, H 2 O 2 ) as an oxygen generating composition. A solution was prepared. The storage solution of iron chloride hexahydrate was diluted with water to a concentration of 10 ppm, and the diluted iron chloride hexahydrate solution was evenly sprinkled on the soil of a 660 ㎡ greenhouse for growing cabbage, followed by immediately adding a diluted hydrogen peroxide solution to a concentration of 25 ppm. An oxygen-generating composition for cultivated soil for cabbage cultivation was sprayed uniformly on the soil and supplied to the soil at intervals of 13 days during the cabbage cultivation period. Nitrogen- 1 kg of Agrosol liquid fertilizer [Agrobiz Co., Ltd.] with a phosphate-potassium concentration ratio of 20-20-20% by weight was diluted in water and drenched at 330 ㎡ at intervals of 3 days.
실시 예 3Example 3
산소발생 촉매 조성물로 25 중량 %의 질산구리3수화물[삼전순약, Cu(NO3)2·3H2O]의 저장용액을 준비하고, 산소발생 조성물로 35 중량%의 과산화수소(대명케미칼, H2O2)의 저장용액을 준비하였다. Prepare a storage solution of 25% by weight of copper nitrate trihydrate [Samjeon Pure Pharmaceutical, Cu(NO 3 ) 2 ·3H 2 O] as an oxygen generating catalyst composition, and prepare a storage solution of 35% by weight of hydrogen peroxide (Daemyung Chemical, H 2 ) as an oxygen generating composition. A storage solution of O 2 ) was prepared.
질산구리3수화물의 저장용액을 물로 희석하여 500 ppm 농도로 희석하고, 희석된 질산구리3수화물 용액을 배수라인이 연결된 1리터의 용기에 충진하고, 다른 배수라인이 연결된 1리터의 용기에 2,000 ppm 농도의 과산화수소를 충진하였다. The storage solution of copper nitrate trihydrate was diluted with water to a concentration of 500 ppm, the diluted copper nitrate trihydrate solution was filled into a 1 liter container connected to a drain line, and 2,000 ppm was added to another 1 liter container connected to a drain line. The concentration of hydrogen peroxide was filled.
질산구리3수화물 용액이 충진된 용기와 과산화수소가 충진된 용기를 20주(그루)의 포도나무 줄기에 각각 매달고 500 ppm 농도로 희석된 질산구리3수화물 용액과 2,000 ppm 농도의 과산화수소가 분당 각각 5 ml 수준으로 포도나무 지표면에 배출되도록 조절하고, 3일 간격으로 동일하게 포도 재배기간 동안 토양에 공급하였으며, 포도 재배기간 동안 포도의 품질 및 수량 확보를 위한 통상적인 공급원으로 질소-인산-칼륨의 농도비율이 20-20-20 중량%인 아그로솔 액상비료[(주)아그로비즈] 1 kg을 물에 희석하여 3일 간격으로 330 ㎡에 관주하였다. A container filled with copper nitrate trihydrate solution and a container filled with hydrogen peroxide were hung on the stems of 20 grapevines, and copper nitrate trihydrate solution diluted to a concentration of 500 ppm and hydrogen peroxide at a concentration of 2,000 ppm were each administered at a rate of 5 ml per minute. It was controlled to be discharged to the surface of the grapevine at a level and supplied to the soil at the same intervals of 3 days during the grape growing period. The concentration ratio of nitrogen-phosphate-potassium was used as a common source to ensure the quality and quantity of grapes during the grape growing period. 1 kg of 20-20-20% by weight Agrosol liquid fertilizer [Agrobiz Co., Ltd.] was diluted in water and drenched at 330 m2 at 3-day intervals.
이 때 포도를 재배하는 기간은 150일로 하였으며, 본원의 기술사상에 의한 효과를 비교하기 위하여 20주에 대한 캠밸 품종 포도의 평균 무게를 확인하였다.At this time, the grape cultivation period was 150 days, and the average weight of Campbell variety grapes for 20 weeks was confirmed to compare the effects of our technical philosophy.
실시 예 4Example 4
0.5 중량%의 구연산철(Ferric citrate, 삼전순약) 저장용액과 50 중량%의 과황산암모늄(삼전순약, Ammonium persulfate) 저장용액을 개별적으로 양액재배를 위한 산소 발생 조성물을 각각 준비하였다. Oxygen-generating compositions for hydroponic cultivation were prepared individually using 0.5% by weight of ferric citrate (Samjeon Pure Pharmaceutical) storage solution and 50% by weight ammonium persulfate (Ammonium persulfate) storage solution.
0.5 중량%의 구연산철 저장용액을 250 ppm 농도로 희석하고, 희석된 구연산철을 330 ㎡의 완숙토마토 양액재배지에 균일하게 공급한 후 곧바로 1,000 ppm 농도로 과황산암모늄을 희석할 때 완숙토마토 재배기간 동안 작물의 품질 및 수량 확보를 위한 통상적인 공급원으로 질소-인산-칼륨의 농도비율이 20-20-20 중량%인 아그로솔 액상비료[(주)아그로비즈]를 10 ppm 농도가 되도록 산소의 소스인 과산화수소 희석 용액에 함께 혼합하고, 이 혼합용액을 양액재배지에 분당 약 2.5 ml씩 연속적으로 공급하였다. Mature tomato cultivation period when 0.5% by weight iron citrate storage solution is diluted to a concentration of 250 ppm, the diluted iron citrate is uniformly supplied to a 330 ㎡ mature tomato nutrient solution culture, and then ammonium persulfate is immediately diluted to a concentration of 1,000 ppm. Agrosol liquid fertilizer [Agrobiz Co., Ltd.] with a nitrogen-phosphate-potassium concentration ratio of 20-20-20% by weight is used as a source of oxygen to ensure a concentration of 10 ppm as a common source for securing the quality and quantity of crops. It was mixed with a diluted solution of phosphorus hydrogen peroxide, and this mixed solution was continuously supplied to the nutrient solution culture medium at a rate of about 2.5 ml per minute.
이 때 완숙토마토를 재배하는 기간은 5개월로 하였으며, 본원의 기술사상에 의한 효과를 비교하기 위하여 5개월간 수확한 완숙토마토 500개에 대한 완숙토마토의 평균 무게를 확인하였다. At this time, the period of cultivating ripe tomatoes was 5 months, and in order to compare the effects of our technical ideas, the average weight of 500 ripe tomatoes harvested over 5 months was confirmed.
실시 예 5Example 5
산소발생 촉매 조성물로 25 중량 %의 초산아연3수화물[삼전순약, Zn(CH3CO2)2·3H2O]의 저장용액을 준비하고, 산소발생 조성물로 50 중량%의 과황산나트륨(삼전순약, Sodium persulfate)의 저장용액을 준비하였다. Prepare a storage solution of 25% by weight of zinc acetate trihydrate [Samjeon Pure Pharmaceutical, Zn(CH 3 CO 2 ) 2 ·3H 2 O] as an oxygen-generating catalyst composition, and 50% by weight of sodium persulfate (Samjeon Pure Pharmaceutical) as an oxygen-generating composition. , Sodium persulfate) storage solution was prepared.
초산아연3수화물의 저장용액을 물로 희석하여 900 ppm 농도로 희석하고, 희석된 초산아연3수화물 용액을 배수라인이 연결된 1리터의 용기에 충진하고, 다른 배수라인이 연결된 1리터의 용기에 5,000 ppm 농도의 과황산나트륨 용액을 충진하였다. The storage solution of zinc acetate trihydrate was diluted with water to a concentration of 900 ppm, the diluted zinc acetate trihydrate solution was filled into a 1 liter container connected to a drain line, and 5,000 ppm was added to another 1 liter container connected to a drain line. A concentrated sodium persulfate solution was filled.
초산아연3수화물 용액이 충진된 용기와 과산화수소가 충진된 용기를 20주(그루)의 사과나무 줄기에 각각 매달고 900 ppm 농도로 희석된 초산아연3수화물 용액과 5,000 ppm 농도의 과황산나트륨이 분당 각각 5 ml 수준으로 사과나무 지표면에 배출되도록 조절하고, 사과의 수액 이동기(토양으로부터 물을 빨아드리는 시기)인 3월초(3월 2일)부터 3일 간격으로 7회 사과 재배기간 동안 토양에 공급하였으며, 사과 재배기간 동안 사과의 품질 및 수량 확보를 위한 통상적인 공급원으로 질소-인산-칼륨의 농도비율이 20-20-20 중량%인 아그로솔 액상비료[(주)아그로비즈] 1 kg을 물에 희석하여 5일 간격으로 20주의 사과나무에 관주하였다. A container filled with zinc acetate trihydrate solution and a container filled with hydrogen peroxide were hung on the stems of 20 apple trees, and zinc acetate trihydrate solution diluted to 900 ppm concentration and sodium persulfate solution diluted to 5,000 ppm concentration were administered at a rate of 5 per minute. It was controlled to be discharged to the surface of apple trees at the level of ml, and supplied to the soil seven times at three-day intervals during the apple cultivation period, starting from early March (March 2), which is the sap movement period of apples (when water is sucked from the soil). As a common source for securing the quality and quantity of apples during the apple cultivation period, 1 kg of Agrosol liquid fertilizer [Agrobiz Co., Ltd.] with a nitrogen-phosphate-potassium concentration ratio of 20-20-20% by weight is diluted in water. So, 20 apple trees were irrigated at 5-day intervals.
이 때 사과를 재배하는 기간은 8개월로 하였으며, 본원의 기술사상에 의한 효과를 비교하기 위하여 20주(그루)에 대한 부사 사과의 평균 무게를 확인하였다.At this time, the apple cultivation period was 8 months, and the average weight of apples per 20 plants (trees) was confirmed to compare the effects of our technology philosophy.
비교 예 1~5Comparative examples 1 to 5
작물을 재배하는 기간 중 산소발생 촉매의 조성물과 과산화수소 내지는 과황산염의 산소발생 조성물이 작물 재배지에 공급되지 않은 것을 제외하고, 실시 예 1~5와 동일하게 수행하였다. The same procedures as Examples 1 to 5 were performed, except that the composition of the oxygen generating catalyst and the oxygen generating composition of hydrogen peroxide or persulfate were not supplied to the crop cultivation area during the crop cultivation period.
비교 예 1~5 및 실시 예 1~5의 결과를 표 1에 나타냈다.The results of Comparative Examples 1 to 5 and Examples 1 to 5 are shown in Table 1.
(kg/개)watermelon
(kg/piece)
(kg/포기)napa cabbage
(kg/give up)
(g/한송이)grape
(g/one bunch)
(g/개)ripe tomatoes
(g/piece)
(g/개)apologize
(g/piece)
표 1에서 나타낸 바와 같이 토양 및 수중에 산소가 극히 미량 존재하여 산소에 의한 뿌리호흡의 가능성이 낮은 비교 예 1~5의 경우 수박의 평균 무게가 7.68 kg을 나타냈으며, 배추의 경우에는 포기당 4.23 kg의 평균무게를 나타냈고, 포도의 경우에는 한 송이당 294 g의 평균 무게를 나타냈으며, 완숙토마토의 경우에는 개당 262 g을 나타냈고, 사과의 경우에는 476 g의 평균무게를 가진 작물을 수확하였다. As shown in Table 1, in Comparative Examples 1 to 5, where the possibility of root respiration by oxygen is low due to the presence of extremely small amounts of oxygen in the soil and water, the average weight of watermelon was 7.68 kg, and in the case of cabbage, the average weight was 4.23 kg per head. The average weight was expressed in kg, in the case of grapes, the average weight was 294 g per bunch, in the case of ripe tomatoes, the average weight was 262 g per piece, and in the case of apples, the average weight was 476 g. did.
반면, 실시 예 1~5와 같이 토양재배 및 양액재배를 위한 토양 및 수중에 산소가 공급될 경우 토양 속에 자라고 있는 식물의 뿌리 호흡 시 충분한 산소 공급에 따라 뿌리의 생장 및 발육 활성에 따른 수박의 평균 무게가 10.4 kg으로 크게 증가함을 알 수 있었으며, 배추의 경우 포기당 5.74 kg의 평균무게로 증산이 되었고, 포도의 경우에는 한 송이당 363 g의 평균 무게로 증가함을 알 수 있었으며, 완숙토마토인 경우 평균 무게가 284 g으로 증가하였고, 부사 사과의 경우에는 504 g을 가진 사과 작물을 수확하였다.On the other hand, when oxygen is supplied to the soil and water for soil cultivation and nutrient solution cultivation as in Examples 1 to 5, the watermelon averages according to the growth and development activity of the roots due to sufficient oxygen supply during root respiration of plants growing in the soil. It was found that the weight increased significantly to 10.4 kg, in the case of cabbage, the average weight increased to 5.74 kg per bunch, and in the case of grapes, it was found that the average weight increased to 363 g per bunch, and in the case of ripe tomatoes, the average weight increased to 363 g per bunch. In the case of , the average weight increased to 284 g, and in the case of Busa apples, an apple crop with 504 g was harvested.
또한 본원에 의한 토양에 산소를 공급하기 위한 기술수단에 있어서, 산소발생 촉매의 조성물을 토양에 뿌려진 직후나 뿌려진 다음 필요에 의해 임의데로 산소의 공급원이 되는 산소 소스(Source)를 적절한 날짜가 흐른 후 시간에 구애받지 않고, 시기적절하게 토양에 공급할 경우 토양 속에 이미 존재하는 금속염(Metal salt)의 산소발생 촉매 조성물에 추후 산소발생 조성물이 공급되는 과산화수소 내지는 과황산염의 공급수단에 의해 살포되거나, 또는 배수라인이 연결된 용기에 금속염(Metal salt)의 산소발생 촉매 조성물과 과산화수소 내지는 과황산염의 산소발생 조성물이 개별적으로 각각 충진되고, 용기의 배수라인을 통해 서서히 작물 재배지의 토양 지표면에 배출되는 수단에 의해 금속염과 과산화수소 내지는 과황산염 조성물이 토양에 스며들면서 혼합과정에 의해 과산화수소 내지는 과황산염의 화학반응에 의한 토양 내의 산소를 장기적으로 안정적 공급을 하여 뿌리 호흡의 활성화에 의한 고품질의 작물을 다수확 할 수 있는 가능성이 높아 노동력을 최소화하면서 작물의 생육 향상 및 생산성 증가로 농가의 경제적 이익 창출 및 농가의 기술적 경쟁력을 확보하는데 크게 기여할 수 있을 것으로 기대된다. In addition, in the technical means for supplying oxygen to the soil according to the present application, the composition of the oxygen generating catalyst is sprayed on the soil immediately after spraying, or as needed, after an appropriate date has passed. When supplied to the soil in a timely manner, regardless of time, the oxygen-generating catalyst composition of the metal salt already present in the soil is later supplied with the oxygen-generating composition, sprayed by a supply means of hydrogen peroxide or persulfate, or drained. The oxygen generating catalyst composition of metal salt and the oxygen generating composition of hydrogen peroxide or persulfate are individually filled in a container connected to a line, and the metal salt is slowly discharged to the soil surface of the crop cultivation area through the drain line of the container. As the hydrogen peroxide or persulfate composition permeates the soil, the mixing process provides a long-term stable supply of oxygen in the soil through a chemical reaction of hydrogen peroxide or persulfate, resulting in the possibility of producing a large number of high-quality crops by activating root respiration. It is expected to greatly contribute to creating economic profits for farms and securing their technical competitiveness by improving crop growth and increasing productivity while minimizing labor.
[부호의 설명][Explanation of symbols]
도 1은 본원 기술사상을 키가 작은 작물을 대상으로 넓은 재배지의 산소농법을 적용하기 위한 실시양태 예시를 사진도 형태로 나타낸 것이고, 도 2는 키가 큰 작물을 대상으로 개별적 작물에 산소농법을 적용하기 위한 실시양태 예시를 사진도 형태로 나타낸 것이므로 별도의 부호설명이 필요없다 할 것이다.Figure 1 shows in the form of a photograph an example of an embodiment for applying the technical idea of the present application to oxygen farming on a wide cultivation area targeting short crops, and Figure 2 shows oxygen farming on individual crops targeting tall crops. Since examples of embodiments for application are shown in photographic form, there is no need for separate explanation of symbols.
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202380024680.8A CN118804679A (en) | 2022-12-22 | 2023-11-30 | Oxygen-producing functional composition capable of supplying oxygen to crop cultivation sites for a long period of time and agricultural method using the same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-2022-0182334 | 2022-12-22 | ||
KR1020220182334A KR102586212B1 (en) | 2022-12-22 | 2022-12-22 | Functional composition of oxygen generating which for a long time can supply the oxygen to the crop cultivation and farming method using the same |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2024136204A1 true WO2024136204A1 (en) | 2024-06-27 |
Family
ID=88293587
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/KR2023/019539 WO2024136204A1 (en) | 2022-12-22 | 2023-11-30 | Oxygen generating functional composition capable of long-term oxygen supply to crop cultivation areas and farming method using same |
Country Status (3)
Country | Link |
---|---|
KR (1) | KR102586212B1 (en) |
CN (1) | CN118804679A (en) |
WO (1) | WO2024136204A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102586212B1 (en) * | 2022-12-22 | 2023-10-05 | 박상진 | Functional composition of oxygen generating which for a long time can supply the oxygen to the crop cultivation and farming method using the same |
KR102749192B1 (en) | 2023-12-04 | 2025-01-03 | (주)에스코 | The aeration composition which can supplying the long term oxygen to the root of plant and method of using the same |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0716038A (en) * | 1993-06-30 | 1995-01-20 | Mitsubishi Rayon Co Ltd | Oxygen generator |
JPH08386U (en) * | 1993-12-29 | 1996-02-27 | ダイヤゴム株式会社 | Plant growth promotion tool |
KR20030025974A (en) * | 2001-09-24 | 2003-03-31 | (주)에코텍 | The synthetic method of super concentration oxygen generating materials for agriculture |
KR20160131987A (en) * | 2016-11-07 | 2016-11-16 | 장병만 | Plant-activating agent composition with soil improvement property and method of boosting growth of plant as well as improving soil property using the composition |
JP2017222566A (en) * | 2016-06-10 | 2017-12-21 | 宇部マテリアルズ株式会社 | Oxygen sustained-release agent, method for producing the same and oxygen feed method |
KR102586212B1 (en) * | 2022-12-22 | 2023-10-05 | 박상진 | Functional composition of oxygen generating which for a long time can supply the oxygen to the crop cultivation and farming method using the same |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6259503A (en) * | 1985-09-06 | 1987-03-16 | Shinji Ueno | Method of generating oxygen gas |
-
2022
- 2022-12-22 KR KR1020220182334A patent/KR102586212B1/en active IP Right Grant
-
2023
- 2023-11-30 CN CN202380024680.8A patent/CN118804679A/en active Pending
- 2023-11-30 WO PCT/KR2023/019539 patent/WO2024136204A1/en active Application Filing
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0716038A (en) * | 1993-06-30 | 1995-01-20 | Mitsubishi Rayon Co Ltd | Oxygen generator |
JPH08386U (en) * | 1993-12-29 | 1996-02-27 | ダイヤゴム株式会社 | Plant growth promotion tool |
KR20030025974A (en) * | 2001-09-24 | 2003-03-31 | (주)에코텍 | The synthetic method of super concentration oxygen generating materials for agriculture |
JP2017222566A (en) * | 2016-06-10 | 2017-12-21 | 宇部マテリアルズ株式会社 | Oxygen sustained-release agent, method for producing the same and oxygen feed method |
KR20160131987A (en) * | 2016-11-07 | 2016-11-16 | 장병만 | Plant-activating agent composition with soil improvement property and method of boosting growth of plant as well as improving soil property using the composition |
KR102586212B1 (en) * | 2022-12-22 | 2023-10-05 | 박상진 | Functional composition of oxygen generating which for a long time can supply the oxygen to the crop cultivation and farming method using the same |
Also Published As
Publication number | Publication date |
---|---|
KR102586212B9 (en) | 2023-12-15 |
CN118804679A (en) | 2024-10-18 |
KR102586212B1 (en) | 2023-10-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2024136204A1 (en) | Oxygen generating functional composition capable of long-term oxygen supply to crop cultivation areas and farming method using same | |
US10815159B2 (en) | Nutrient system | |
Tattini et al. | Effect of humic acids on growth and nitrogen uptake of container-grown olive (Olea europaea L.‘Maurino’) | |
CN106747927A (en) | A kind of popular ornamental trees and shrubs nutrient solution growth regulator and preparation method thereof | |
CN108929135B (en) | Root-promoting seedling-raising suspension type liquid fertilizer and preparation method and application thereof | |
CN102424610A (en) | Fruit tree nutrient solution | |
CN102612961A (en) | Method for cultivating olive seedlings | |
CN110483213A (en) | A kind of liquid fertilizer and preparation method thereof | |
CN106376322A (en) | Saffron crocus seedball propagation method | |
KR20150013557A (en) | Plant growth enhancing mixture | |
CN1102405A (en) | Nutrition liquid for water cultivation of ornamental plant | |
CN108752107B (en) | Medicament for improving moso bamboo yield and preparation method and use method thereof | |
KR102546127B1 (en) | The oxygen generation composition for the soil for growing crops and feeding method using the same | |
CN111802392A (en) | Plant growth regulator and preparation method thereof | |
CN115152558B (en) | Planting method for increasing oil and enriching selenium of peanuts | |
CN110199793A (en) | A kind of implantation methods for strawberry of getting bumper crops | |
CN108886988A (en) | A kind of blueberry sponge cuttage and seedling culture method | |
CN107586170A (en) | Leaf vegetable nutrient and application thereof | |
KR102749192B1 (en) | The aeration composition which can supplying the long term oxygen to the root of plant and method of using the same | |
CN107285828A (en) | Bion tree body transfusion bottle nutrient solution and its production technology | |
CN112673908B (en) | Atomizing interplanting device and application thereof | |
CN105265483A (en) | Yield increase element for promoting plant growth, and production method thereof | |
CN108484279A (en) | Nutrient solution and preparation method suitable for wheatgrass water planting | |
KR102760042B1 (en) | The aeration composition supplying the long term oxygen in the soil where the plants grow and supply method using the same | |
CN106857171A (en) | The implantation methods of many mycorhiza blueberries |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 23907490 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 202380024680.8 Country of ref document: CN |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2401006528 Country of ref document: TH |