WO2024110436A1 - A method of compressing a water-containing oxygen-containing stream - Google Patents
A method of compressing a water-containing oxygen-containing stream Download PDFInfo
- Publication number
- WO2024110436A1 WO2024110436A1 PCT/EP2023/082492 EP2023082492W WO2024110436A1 WO 2024110436 A1 WO2024110436 A1 WO 2024110436A1 EP 2023082492 W EP2023082492 W EP 2023082492W WO 2024110436 A1 WO2024110436 A1 WO 2024110436A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- stream
- oxygen
- water
- obtaining
- ejector
- Prior art date
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 61
- 239000001301 oxygen Substances 0.000 title claims abstract description 60
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 60
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 56
- 238000000034 method Methods 0.000 title claims abstract description 39
- 239000012530 fluid Substances 0.000 claims abstract description 75
- 239000007788 liquid Substances 0.000 claims abstract description 36
- 239000007789 gas Substances 0.000 claims abstract description 34
- 150000002926 oxygen Chemical class 0.000 claims abstract description 28
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000004064 recycling Methods 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 description 11
- 230000006835 compression Effects 0.000 description 9
- 238000007906 compression Methods 0.000 description 9
- 239000001257 hydrogen Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 230000003068 static effect Effects 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 238000006356 dehydrogenation reaction Methods 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 238000011144 upstream manufacturing Methods 0.000 description 3
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- -1 ethylene, propylene, methanol Chemical class 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000001535 kindling effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- QVGXLLKOCUKJST-BJUDXGSMSA-N oxygen-15 atom Chemical compound [15O] QVGXLLKOCUKJST-BJUDXGSMSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000020030 perry Nutrition 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04F—PUMPING OF FLUID BY DIRECT CONTACT OF ANOTHER FLUID OR BY USING INERTIA OF FLUID TO BE PUMPED; SIPHONS
- F04F5/00—Jet pumps, i.e. devices in which flow is induced by pressure drop caused by velocity of another fluid flow
- F04F5/02—Jet pumps, i.e. devices in which flow is induced by pressure drop caused by velocity of another fluid flow the inducing fluid being liquid
- F04F5/04—Jet pumps, i.e. devices in which flow is induced by pressure drop caused by velocity of another fluid flow the inducing fluid being liquid displacing elastic fluids
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
- C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/05—Pressure cells
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04F—PUMPING OF FLUID BY DIRECT CONTACT OF ANOTHER FLUID OR BY USING INERTIA OF FLUID TO BE PUMPED; SIPHONS
- F04F5/00—Jet pumps, i.e. devices in which flow is induced by pressure drop caused by velocity of another fluid flow
- F04F5/02—Jet pumps, i.e. devices in which flow is induced by pressure drop caused by velocity of another fluid flow the inducing fluid being liquid
- F04F5/10—Jet pumps, i.e. devices in which flow is induced by pressure drop caused by velocity of another fluid flow the inducing fluid being liquid displacing liquids, e.g. containing solids, or liquids and elastic fluids
Definitions
- the present invention relates to a method of compressing a water-containing oxygen-containing stream originating from an electrolyzer, wherein the obtained compressed oxygen-containing stream is used, in 5 particular in a gasifier.
- Compression of gaseous streams is well known in the art.
- the compression of gaseous streams is achieved by positive displacement devices such as reciprocating or screw compressors which 10 reduce the volume that the gas occupies and hence increase the pressure.
- This kind of ‘dry’ compression can also be achieved by centrifugal blowers, compressors or pumps, which use impellers to accelerate the gas and then decelerate the gas 15 converting the kinetic energy of the gas to pressure.
- centrifugal blowers, compressors or pumps which use impellers to accelerate the gas and then decelerate the gas 15 converting the kinetic energy of the gas to pressure.
- multiple stages of compression and cooling between the stages is required.
- a problem of multi-stage compressors is that they 20 are typically associated with high capital costs due to associated equipment, installation and high operation costs.
- a further problem of conventional ‘dry’ compression is that it cannot be used for compressing water-saturated 25 oxygen-containing streams as for example originating from an electrolyzer.
- Conventional compressors cannot tolerate any water in an oxygen-containing stream and the use of such compressors for oxygen-containing streams originating from an electrolyzer would result in a safety risk.
- a method of compressing a water-containing oxygen- containing stream originating from an electrolyzer at least comprising the steps of: (a) providing a water-containing oxygen-containing stream; 30 (b) combining the water-containing oxygen-containing stream provided in step (a) as a suction fluid in an ejector with a water-containing stream as a motive fluid, thereby obtaining a combined stream; (c) flashing the combined stream by the ejector, thereby obtaining a two-phase fluid discharged from the ejector; (d) separating the two-phase fluid discharged from 5 the ejector into an oxygen-containing gas stream and a liquid stream; (e) pressurizing the liquid stream obtained in step (d), thereby obtaining a pressurized liquid stream; (f) using the pressurized liquid stream obtained in 10 step (e) as the motive fluid in step (b); (g) dehydrogenating the oxygen-containing gas stream obtained
- a pressurized oxygen-containing gas stream can be obtained in a surprisingly simple manner, without the safety issues as confronted in ‘dry compression’.
- a further advantage of the process according to the 30 present invention is that a static piece of equipment can be used to achieve pressure transfer. Such a static piece of equipment is reliable, simple and requires less expensive construction materials. Ejectors are considered static equipment and are generally associated with low capital and operating costs in comparison to compressors.
- the ejector converts the pressure energy available in the motive fluid to velocity energy, brings in the (lower 5 pressure) suction fluid, mixes the two fluids and discharges the mixture at an intermediate pressure without the use of rotating or moving parts.
- ejectors are known per se for decades, but have not been suggested for the 10 use of compressing a water-containing oxygen-containing streams originating from an electrolyzer, wherein the compressed oxygen-containing stream is used as a product in e.g. a gasifier.
- WO 2022/069906 A1 discloses 15 the use of an ejector for condensing in particular CO2.
- 25 JP2003105577A discloses a fuel cell hybrid system comprising a gas generating section (using electrolysis of water) for producing hydrogen and oxygen and a fuel cell section for generating electricity by using the hydrogen and/or oxygen as generated in the gas generating 30 section in the fuel cell section.
- WO 2020/035470 A1 discloses a gas power cycle for power generation where use is made of an ejector. There is no mention in WO 2020/035470 A1 that a water-containing oxygen-containing stream is originating from an electrolyzer. In step (a) of the method according to the present invention, a water-containing oxygen-containing stream is provided.
- the water-containing oxygen-containing stream provided in step (a) is not limited in any way (in terms of composition, temperature, pressure, etc.), as long as it contains oxygen (O2) and water (H2O) and as long as it is originating from an electrolyzer.
- the water-containing oxygen-containing stream provided in step (a) is a gaseous stream, and it preferably is a water-saturated stream. It may even contain some liquid water carryover (up to 1.0 vol.%).
- the water-containing oxygen-containing stream provided in step (a) comprises at least 80 mol% O 2 , preferably at least 90 mol% O 2 , more preferably at least 95 mol% O2.
- the water-containing oxygen-containing stream provided in step (a) comprises at most 99 mol.% O2, more preferably at most 98 mol% O2. Further, it is preferred that the water-containing oxygen-containing stream provided in step (a) comprises from 2.0 to 20 mol% H2O, preferably from 3.0 mol% to 10.0 mol% H2O.
- the water-containing oxygen-containing stream provided in step (a) typically also comprises hydrogen (H 2 ).
- the water-containing oxygen-containing stream provided in step (a) comprises from 0.3 to 2.0 mol% H 2 .
- the water-containing oxygen-containing stream provided in step (a) has a pressure of from 0.1 bara to 2.5 bara, preferably from 0.5 bara to 1.5 bara.
- the pressure of the water-containing oxygen-containing stream provided in step (a) may be referred to as ‘first pressure’. Further it is preferred that the water-containing oxygen-containing stream provided in step (a) has a temperature of from 20 to 90°C, preferably from 40 to 80°C. If appropriate, the water-containing oxygen- containing stream provided in step (a) may have been pre- processed to obtain the desired composition and conditions.
- step (b) of the method according to the present invention the water-containing oxygen-containing stream provided in step (a) is combined as a suction fluid in an ejector with a water-containing stream as a motive fluid, thereby obtaining a combined stream. As ejectors are known in the art, these are not further described here in detail.
- the motive fluid in step (b) comprises at least 80 mol% H2O, preferably at least 90 mol%, more preferably at least 95 mol%.
- the motive fluid in step (b) comprises at most 99 mol% H2O.
- the motive fluid in step (b) may also contain some O 2 and H 2 .
- the motive fluid contains ⁇ 0.5 mol.% O 2 .
- the pressure of the ‘motive fluid’ is higher than the pressure of the ‘suction fluid’ as used in the ejector.
- the pressure of the motive fluid is at least 10 bar higher than the suction fluid, preferably at least 20 bar higher, more preferably at least 50 bar higher, even more preferably at least 80 bar higher.
- the motive fluid in step (b) has a 5 pressure in the range of from 60 to 300 bara, preferably from 80 bara to 200 bara. Further it is preferred that the motive fluid in step (b) has a temperature of from 20 to 70°C, preferably from 30 to 50°C.
- the (water-containing 10 oxygen-containing stream to be used as the) suction fluid has a pressure of from 0.1 bara to 2.5 bara, preferably from 0.5 bara to 1.5 bara.
- step (c) of the method according to the present invention the combined stream is flashed by the ejector, 15 thereby obtaining a two-phase fluid discharged from the ejector.
- the flashing takes place in the throat of the ejector, thereby obtaining the two-phase fluid whilst leaving the ejector.
- the pressure of the 20 combined stream is reduced.
- the two-phase fluid obtained in step (c) has a pressure of from 2.0 bara to 10.0 bara, preferably from 3.0 bara to 6.0 bara.
- the pressure of the two-phase fluid obtained in step (c) may be referred to as ‘second pressure’.
- This second 25 pressure is higher than the ‘first pressure’ (of the water-containing oxygen-containing stream provided in step (a)).
- step (d) of the method according to the present invention the two-phase fluid discharged from the 30 ejector is separated into an oxygen-containing gas stream and a liquid stream. This separation in step (d) is not particularly limited and typically takes place in a conventional gas/liquid-separator.
- step (d) 5 (which is at the increased, second pressure) will be further processed (e.g. dehydrogenated, dehydrated and further compressed) and used as a product, for example in a gasifier.
- step (e) of the method according to the present 10 invention the liquid stream obtained in step (d) is pressurized, thereby obtaining a pressurized liquid stream.
- this pressurizing may be performed in many ways, e.g. by using a pump, in order to obtain the 15 desired pressure for use as the motive fluid.
- step (f) of the method according to the present invention the pressurized liquid stream obtained in step (e) is used as the motive fluid in step (b).
- step (g) of the method according to the present 20 invention the oxygen-containing gas stream obtained in step (d) is dehydrogenated, thereby obtaining a dehydrogenated oxygen-containing stream.
- the dehydrogenation can 25 be done by for example catalytic H2/O2 combustion. If such catalytic H2/O2 combustion is used, then reactor temperatures are in the range of 70 to 150°C.
- the dehydrogenated oxygen-containing stream preferably has a H 2 content of less than 1 mol%, 30 preferably less than 10 ppm, more preferably less than 5 ppm.
- step (h) of the method according to the present invention the dehydrogenated oxygen-containing stream obtained in step (g) is dehydrated, thereby obtaining a dehydrated dehydrogenated oxygen-containing stream.
- the dehydrated dehydrogenated oxygen- containing stream comprises less than 10 ppm H2O.
- step (i) of the method according to the present invention the dehydrated dehydrogenated oxygen- containing stream obtained in step (h) is compressed, 10 thereby obtaining a compressed oxygen-containing stream.
- the compressed oxygen-containing stream has a pressure in the range of 6 to 70 bara, preferably 30 to 60 bara.
- step (j) of the method according to the present 15 invention the compressed oxygen-containing stream obtained in step (i) is used, in particular in a gasifier.
- a gasifier As a person skilled in the art is familiar with a gasifier, this is not further discussed here in detail. Suitable gasifiers have for example been disclosed in WO 20 2017/102942 A1. Typically, the gasifier forms part of syngas and fossil-based hydrogen production line-ups and the like.
- the method according to the present invention may 25 comprise further steps. As an example, some cooling may be performed on the liquid stream obtained in step (d) and/or the pressurized liquid stream obtained in step (e), in order to obtain the desired temperature or the motive fluid to be used in step (b).
- the present invention provides an apparatus for compressing a water-containing, in particular a water-saturated, oxygen-containing stream originating from an electrolyzer, the apparatus at least 5 comprising: - an electrolyzer for electrolyzing a water-containing stream, thereby obtaining at least a (water-containing, in particular water-saturated) H2-containing stream and a water-containing (in particular water-saturated) oxygen- 10 containing stream; - an ejector for combining the water-containing oxygen- containing stream as a suction fluid with a water- containing stream as a motive fluid, thereby obtaining a combined stream and flashing the combined stream, thereby 15 obtaining a two-phase fluid discharged from the ejector; - a separator for separating the two-phase fluid discharged from the
- FIG. 4 schematically an alternative embodiment of the 20 method according to the present invention, further containing a cooler upstream of the pump 4 in Fig. 1; and Fig. 5 schematically an exemplary method according to the present invention (based on Fig. 3) also showing a dehydrogenator, a dehydrator, a compressor, and a 25 gasifier.
- Fig. 3 schematically an exemplary method according to the present invention (based on Fig. 3) also showing a dehydrogenator, a dehydrator, a compressor, and a 25 gasifier.
- same reference numbers refer to same or similar components.
- the flow scheme of Figure 1 generally referred to with reference number 1, shows an ejector 2, a 30 gas/liquid-separator 3 and a pump 4.
- one of the inlets ‘2b’ in Fig.
- a water- 5 saturated oxygen-containing stream 10 is combined as a suction fluid in the ejector 2 with a water-containing stream 20 as a motive fluid, thereby obtaining a combined stream.
- the combined stream is flashed by the ejector 2, thereby obtaining a two-phase fluid 30 discharged from 10 the ejector 2.
- FIG. 2 A more detailed view of (a non-limiting embodiment of) the ejector 2 is shown in Fig. 2 and is discussed hereafter.
- the water-saturated oxygen- containing stream 10 is combined as a suction fluid with 15 a motive fluid 20, thereby obtaining a combined stream (not shown in Fig. 1; ‘25’ in Fig. 2).
- the combined stream is flashed by the ejector 2 whilst leaving the ejector 2, thereby obtaining a two-phase fluid 30 discharged from the ejector 2.
- the two-phase fluid 30 discharged from the ejector 2 is separated in a conventional gas/liquid-separator 3 into an oxygen-containing gas stream 40 and a liquid stream 50.
- Part of the liquid stream 50 may be used as a bleed stream (not shown in Fig. 1; cf. stream 60 in Fig. 25 3).
- the oxygen-containing gas 40 (which has an increased pressure when compared to the water-saturated oxygen- containing stream 10) may be routed to further compression and purification (e.g. dehydrogenation, 30 dehydration, ...) prior to end use, e.g. in a gasifier (see also Fig. 5 hereafter).
- the liquid stream 50 coming from the gas/liquid- separator 3 is pressurized in the pump 4, thereby obtaining a pressurized liquid stream, which is used as the motive fluid 20 in the ejector 2.
- Figure 2 shows a more detailed view of an ejector that can be used as the ejector 2 in Fig. 1.
- the ejector 2 comprises an inlet 2a for the motive fluid 20, an inlet 2b for the suction fluid 10, a nozzle 2c within the ejector 2 for the motive fluid, a throat 2d with a diffuser section 2e and an outlet 2f for the fluid 30 to be discharged.
- the motive fluid 20 and suction fluid 10 are combined in the ejector 2 (just after nozzle 2c) to form a combined stream 25.
- FIG. 3 and 4 schematically show alternative embodiments of the method according to the present invention, wherein a cooler 5 is used downstream (Fig. 3) or upstream (Fig. 4) of the pump 4 in Fig. 1. It goes 20 without saying, that also a cooler may be present both downstream and upstream of the pump 4.
- the cooler 5 is in the form of an indirect heat exchanger.
- the cooler 5 cools the 25 pressurized liquid stream (referred to as ‘45’ in Fig.
- FIG. 5 provides a fuller overview of the flow scheme of the method according to the present invention (based on the embodiment of Fig. 3), also showing a dehydrogenator 6, a dehydrator 7, a compressor 8, and a 5 gasifier 9. During use of the flow scheme of Fig.
- Example 1 The flow scheme of Fig. 3 was used for illustrating the compressing of a gaseous water-saturated oxygen- containing stream originating from an electrolyzer.
- the compositions and conditions of the fluid (i.e. gas and liquid) streams in the various flow lines are provided in 25 Table 1 below.
- the Psuction was 1.1 bara, whilst the Pdischarge was 6.0 bara.
- Table 1 Fluid stream 10 20 30 40 45 50 60 Phase V L V/L V L L L scuss o 5
- An important advantage of the present invention is 10 that by using the water-saturated oxygen-containing stream as a suction fluid in an ejector, a pressurized oxygen-containing gas stream can be obtained in a surprisingly simple manner, without the safety issues as confronted in ‘dry compression’.
- the pressurized oxygen- 15 containing gas stream can subsequently be used in a gasifier.
- the person skilled in the art will readily understand that many modifications may be made without departing from the scope of the invention. Further, the person 20 skilled in the art will readily understand that, while the present invention in some instances may have been illustrated making reference to a specific combination of features and measures, many of those features and measures are functionally independent from other features 25 and measures given in the respective embodiment(s) such that they can be equally or similarly applied independently in other embodiments.
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Abstract
The present invention provides a method of compressing a water-containing oxygen-containing stream originating from an electrolyzer, the method at least comprising the steps of: (a) providing a water-containing oxygen-containing stream (10); (b) combining the water-containing oxygen-containing stream (10) provided in step (a) as a suction fluid in an ejector (2) with a water-containing stream (20) as a motive fluid, thereby obtaining a combined stream; (c) flashing the combined stream by the ejector (2), thereby obtaining a two-phase fluid (30) discharged from the ejector (2); (d) separating the two-phase fluid (30) discharged from the ejector (2) into an oxygen-containing gas stream (40) and a liquid stream (50); (e) pressurizing the liquid stream (40) obtained in step (d), thereby obtaining a pressurized liquid stream; (f) using the pressurized liquid stream obtained in step (e) as the motive fluid (20) in step (b); (g) dehydrogenating the oxygen-containing gas stream (40) obtained in step (d), thereby obtaining a dehydrogenated oxygen-containing stream (70); (h) dehydrating the dehydrogenated oxygen-containing stream (70) obtained in step (g), thereby obtaining a dehydrated dehydrogenated oxygen-containing stream (80); (i) compressing the dehydrated dehydrogenated oxygen-containing stream (80) obtained in step (h) thereby obtaining a compressed oxygen-containing stream (90); and (j) using the compressed oxygen-containing stream (90) obtained in step (i), in particular in a gasifier (9).
Description
SP 2964-WO-PCT A METHOD OF COMPRESSING A WATER-CONTAINING OXYGEN- CONTAINING STREAM The present invention relates to a method of compressing a water-containing oxygen-containing stream originating from an electrolyzer, wherein the obtained compressed oxygen-containing stream is used, in 5 particular in a gasifier. Compression of gaseous streams is well known in the art. Typically, the compression of gaseous streams is achieved by positive displacement devices such as reciprocating or screw compressors which 10 reduce the volume that the gas occupies and hence increase the pressure. This kind of ‘dry’ compression can also be achieved by centrifugal blowers, compressors or pumps, which use impellers to accelerate the gas and then decelerate the gas 15 converting the kinetic energy of the gas to pressure. Usually, to achieve the desired pressure increase, multiple stages of compression and cooling between the stages is required. A problem of multi-stage compressors is that they 20 are typically associated with high capital costs due to associated equipment, installation and high operation costs. A further problem of conventional ‘dry’ compression is that it cannot be used for compressing water-saturated 25 oxygen-containing streams as for example originating from an electrolyzer. Conventional compressors cannot tolerate any water in an oxygen-containing stream and the use of such compressors for oxygen-containing streams originating
from an electrolyzer would result in a safety risk. This, as hydrogen and oxygen present in the oxygen-containing streams originating from an electrolyzer may form an explosive mixture; this issue is even more significnant in 5 case the oxygen-containing stream is subsequently to be used in a gasifier. Further, the presence of water may lead to corrosion of the compressor/pipes. If this leads to any dust particles in the system and, as a result of compression, the temperature of the gas mixture increases, 10 it could lead to a kindling chain reaction leading to possible fire or explosion. It may be possible to avoid this through the selection of special alloy materials, but this would entail excessive cost. It is an object of the present invention to solve, 15 minimize or at least reduce one or more of the above problems. It is a further object of the present invention to provide an alternative process for compressing a water- containing, in particular a water-saturated, oxygen- 20 containing stream originating from an electrolyzer, wherein the obtained compressed oxygen-containing stream is used, in particular in a gasifier. One or more of the above or other objects may be achieved according to the present invention by providing25 a method of compressing a water-containing oxygen- containing stream originating from an electrolyzer, the method at least comprising the steps of: (a) providing a water-containing oxygen-containing stream; 30 (b) combining the water-containing oxygen-containing stream provided in step (a) as a suction fluid in an ejector with a water-containing stream as a motive fluid, thereby obtaining a combined stream;
(c) flashing the combined stream by the ejector, thereby obtaining a two-phase fluid discharged from the ejector; (d) separating the two-phase fluid discharged from 5 the ejector into an oxygen-containing gas stream and a liquid stream; (e) pressurizing the liquid stream obtained in step (d), thereby obtaining a pressurized liquid stream; (f) using the pressurized liquid stream obtained in 10 step (e) as the motive fluid in step (b); (g) dehydrogenating the oxygen-containing gas stream obtained in step (d), thereby obtaining a dehydrogenated oxygen-containing stream; (h) dehydrating the dehydrogenated oxygen-containing 15 stream obtained in step (g), thereby obtaining a dehydrated dehydrogenated oxygen-containing stream; (i) compressing the dehydrated dehydrogenated oxygen- containing stream obtained in step (h) thereby obtaining a compressed oxygen-containing stream; and 20 (j) using the compressed oxygen-containing stream obtained in step (i), in particular in a gasifier. It has surprisingly been found according to the present invention that by using the water-containing (preferably water-saturated) oxygen-containing stream 25 originating from an electrolyzer as a suction fluid in an ejector, a pressurized oxygen-containing gas stream can be obtained in a surprisingly simple manner, without the safety issues as confronted in ‘dry compression’. A further advantage of the process according to the 30 present invention is that a static piece of equipment can be used to achieve pressure transfer. Such a static piece of equipment is reliable, simple and requires less expensive construction materials. Ejectors are considered
static equipment and are generally associated with low capital and operating costs in comparison to compressors. The ejector converts the pressure energy available in the motive fluid to velocity energy, brings in the (lower 5 pressure) suction fluid, mixes the two fluids and discharges the mixture at an intermediate pressure without the use of rotating or moving parts. In this respect it is noted that ejectors are known per se for decades, but have not been suggested for the 10 use of compressing a water-containing oxygen-containing streams originating from an electrolyzer, wherein the compressed oxygen-containing stream is used as a product in e.g. a gasifier. As a mere recent example, WO 2022/069906 A1 discloses 15 the use of an ejector for condensing in particular CO2. Although WO 2022/069906 A1 suggests (see page 4, lines 8- 11) various fluids (i.e. water, methane, ethane, propane, ethylene, propylene, methanol, ethanol, acetone, nitrous oxide) to be used as motive fluid and gas to be 20 compressed, no mention of an oxygen-containing stream (typically also comprising hydrogen) originating from an electrolyzer to be used as a suction fluid in an ejector has been made. As a further example where an ejector is used, 25 JP2003105577A discloses a fuel cell hybrid system comprising a gas generating section (using electrolysis of water) for producing hydrogen and oxygen and a fuel cell section for generating electricity by using the hydrogen and/or oxygen as generated in the gas generating 30 section in the fuel cell section. Further, WO 2020/035470 A1 discloses a gas power cycle for power generation where use is made of an ejector. There is no mention in WO 2020/035470 A1 that a
water-containing oxygen-containing stream is originating from an electrolyzer. In step (a) of the method according to the present invention, a water-containing oxygen-containing stream is provided. The water-containing oxygen-containing stream provided in step (a) is not limited in any way (in terms of composition, temperature, pressure, etc.), as long as it contains oxygen (O2) and water (H2O) and as long as it is originating from an electrolyzer. Typically and preferably, the water-containing oxygen-containing stream provided in step (a) is a gaseous stream, and it preferably is a water-saturated stream. It may even contain some liquid water carryover (up to 1.0 vol.%). Preferably, the water-containing oxygen-containing stream provided in step (a) comprises at least 80 mol% O2, preferably at least 90 mol% O2, more preferably at least 95 mol% O2. Preferably, the water-containing oxygen-containing stream provided in step (a) comprises at most 99 mol.% O2, more preferably at most 98 mol% O2. Further, it is preferred that the water-containing oxygen-containing stream provided in step (a) comprises from 2.0 to 20 mol% H2O, preferably from 3.0 mol% to 10.0 mol% H2O. The water-containing oxygen-containing stream provided in step (a) typically also comprises hydrogen (H2). Preferably, the water-containing oxygen-containing stream provided in step (a) comprises from 0.3 to 2.0 mol% H2. Preferably, the water-containing oxygen-containing stream provided in step (a) has a pressure of from 0.1 bara to 2.5 bara, preferably from 0.5 bara to 1.5 bara.
The pressure of the water-containing oxygen-containing stream provided in step (a) may be referred to as ‘first pressure’. Further it is preferred that the water-containing oxygen-containing stream provided in step (a) has a temperature of from 20 to 90°C, preferably from 40 to 80°C. If appropriate, the water-containing oxygen- containing stream provided in step (a) may have been pre- processed to obtain the desired composition and conditions. In step (b) of the method according to the present invention, the water-containing oxygen-containing stream provided in step (a) is combined as a suction fluid in an ejector with a water-containing stream as a motive fluid, thereby obtaining a combined stream. As ejectors are known in the art, these are not further described here in detail. Ejectors have for example been described in Perry’s Chemical Engineers’ Handbook, 6th edition, 1985, pages 5-21 to 5-22 and 6-31 to 6-33. Ejectors are considered static equipment and are generally associated with low capital and operating costs in comparison to compressors. Preferably, the motive fluid in step (b) comprises at least 80 mol% H2O, preferably at least 90 mol%, more preferably at least 95 mol%. Typically, the motive fluid in step (b) comprises at most 99 mol% H2O. The motive fluid in step (b) may also contain some O2 and H2. Typically, the motive fluid contains < 0.5 mol.% O2. The person skilled in the art will readily understand that the pressure of the ‘motive fluid’ is higher than the pressure of the ‘suction fluid’ as used in the ejector. Preferably, the pressure of the motive fluid is
at least 10 bar higher than the suction fluid, preferably at least 20 bar higher, more preferably at least 50 bar higher, even more preferably at least 80 bar higher. Preferably, the motive fluid in step (b) has a 5 pressure in the range of from 60 to 300 bara, preferably from 80 bara to 200 bara. Further it is preferred that the motive fluid in step (b) has a temperature of from 20 to 70°C, preferably from 30 to 50°C. As already mentioned above, the (water-containing 10 oxygen-containing stream to be used as the) suction fluid has a pressure of from 0.1 bara to 2.5 bara, preferably from 0.5 bara to 1.5 bara. In step (c) of the method according to the present invention, the combined stream is flashed by the ejector, 15 thereby obtaining a two-phase fluid discharged from the ejector. Typically, the flashing takes place in the throat of the ejector, thereby obtaining the two-phase fluid whilst leaving the ejector. As a consequence of the flashing, the pressure of the 20 combined stream is reduced. Preferably, the two-phase fluid obtained in step (c) has a pressure of from 2.0 bara to 10.0 bara, preferably from 3.0 bara to 6.0 bara. The pressure of the two-phase fluid obtained in step (c) may be referred to as ‘second pressure’. This second 25 pressure is higher than the ‘first pressure’ (of the water-containing oxygen-containing stream provided in step (a)). In step (d) of the method according to the present invention, the two-phase fluid discharged from the 30 ejector is separated into an oxygen-containing gas stream and a liquid stream.
This separation in step (d) is not particularly limited and typically takes place in a conventional gas/liquid-separator. The oxygen-containing gas stream obtained in step (d) 5 (which is at the increased, second pressure) will be further processed (e.g. dehydrogenated, dehydrated and further compressed) and used as a product, for example in a gasifier. In step (e) of the method according to the present 10 invention, the liquid stream obtained in step (d) is pressurized, thereby obtaining a pressurized liquid stream. The person skilled in the art will readily understand that this pressurizing may be performed in many ways, e.g. by using a pump, in order to obtain the 15 desired pressure for use as the motive fluid. In step (f) of the method according to the present invention, the pressurized liquid stream obtained in step (e) is used as the motive fluid in step (b). In step (g) of the method according to the present 20 invention, the oxygen-containing gas stream obtained in step (d) is dehydrogenated, thereby obtaining a dehydrogenated oxygen-containing stream. As the person skilled in the art is familiar with dehydrogenation, this is not discussed here in detail. The dehydrogenation can 25 be done by for example catalytic H2/O2 combustion. If such catalytic H2/O2 combustion is used, then reactor temperatures are in the range of 70 to 150°C. The dehydrogenated oxygen-containing stream preferably has a H2 content of less than 1 mol%, 30 preferably less than 10 ppm, more preferably less than 5 ppm. In step (h) of the method according to the present invention, the dehydrogenated oxygen-containing stream
obtained in step (g) is dehydrated, thereby obtaining a dehydrated dehydrogenated oxygen-containing stream. As the person skilled in the art is familiar with dehydration, this is not discussed here in detail. 5 Typically, the dehydrated dehydrogenated oxygen- containing stream comprises less than 10 ppm H2O. In step (i) of the method according to the present invention, the dehydrated dehydrogenated oxygen- containing stream obtained in step (h) is compressed, 10 thereby obtaining a compressed oxygen-containing stream. Typically, the compressed oxygen-containing stream has a pressure in the range of 6 to 70 bara, preferably 30 to 60 bara. In step (j) of the method according to the present 15 invention, the compressed oxygen-containing stream obtained in step (i) is used, in particular in a gasifier. As a person skilled in the art is familiar with a gasifier, this is not further discussed here in detail. Suitable gasifiers have for example been disclosed in WO 20 2017/102942 A1. Typically, the gasifier forms part of syngas and fossil-based hydrogen production line-ups and the like. The person skilled in the art will readily understand that the method according to the present invention may 25 comprise further steps. As an example, some cooling may be performed on the liquid stream obtained in step (d) and/or the pressurized liquid stream obtained in step (e), in order to obtain the desired temperature or the motive fluid to be used in step (b). As the person 30 skilled in the art is familiar with cooling, this is not discussed here in detail. The cooling can for example take place by means of a heat exchanger, e.g. using air or another medium.
In a further aspect, the present invention provides an apparatus for compressing a water-containing, in particular a water-saturated, oxygen-containing stream originating from an electrolyzer, the apparatus at least 5 comprising: - an electrolyzer for electrolyzing a water-containing stream, thereby obtaining at least a (water-containing, in particular water-saturated) H2-containing stream and a water-containing (in particular water-saturated) oxygen- 10 containing stream; - an ejector for combining the water-containing oxygen- containing stream as a suction fluid with a water- containing stream as a motive fluid, thereby obtaining a combined stream and flashing the combined stream, thereby 15 obtaining a two-phase fluid discharged from the ejector; - a separator for separating the two-phase fluid discharged from the ejector into an oxygen-containing gas stream and a liquid stream; - a pressure increaser, in particular a pump, for 20 pressurizing the liquid stream, thereby obtaining a pressurized liquid stream; and - a recycle line for recycling at least a part of the pressurized liquid stream to be used as the motive fluid in the ejector; 25 - a dehydrogenator for dehydrogenating the oxygen- containing gas stream, thereby obtaining a dehydrogenated oxygen-containing stream; - a dehydrator for dehydrating the dehydrogenated oxygen- containing stream, thereby obtaining a dehydrated 30 dehydrogenated oxygen-containing stream; - at least one compressor for compressing the dehydrated dehydrogenated oxygen-containing stream, thereby obtaining a compressed oxygen-containing stream; and
- a gasifier, in which the compressed oxygen-containing stream is used. A bleed or make-up of water may be present as well for the recycle line (to remove or add water if needed). 5 Hereinafter the present invention will be further illustrated by the following non-limiting drawings. Herein shows: Fig. 1 schematically a flow scheme of part of the method for compressing a water-saturated oxygen- 10 containing stream originating from an electrolyzer according to the present invention; Fig. 2 schematically a detailed view of an exemplary, non-limiting embodiment of an ejector that can be used in the method according to the present invention; 15 Fig. 3 schematically an alternative embodiment of part of the method according to the present invention, further containing a cooler downstream of the pump 4 in Fig. 1; Fig. 4 schematically an alternative embodiment of the 20 method according to the present invention, further containing a cooler upstream of the pump 4 in Fig. 1; and Fig. 5 schematically an exemplary method according to the present invention (based on Fig. 3) also showing a dehydrogenator, a dehydrator, a compressor, and a 25 gasifier. For the purpose of this description, same reference numbers refer to same or similar components. The flow scheme of Figure 1 generally referred to with reference number 1, shows an ejector 2, a 30 gas/liquid-separator 3 and a pump 4. Preferably, one of the inlets (‘2b’ in Fig. 2) of the ejector 2 is connected with an outlet of an electrolyzer (not shown) for the water-saturated oxygen-containing stream 10 to be used in
the ejector 2. Of course, there may be a g/l-separator and/or cooler between the outlet of the electrolyzer and the inlet (2b in Fig. 2) of the ejector 2. During use of the flow scheme of Fig. 1, a water- 5 saturated oxygen-containing stream 10 is combined as a suction fluid in the ejector 2 with a water-containing stream 20 as a motive fluid, thereby obtaining a combined stream. The combined stream is flashed by the ejector 2, thereby obtaining a two-phase fluid 30 discharged from 10 the ejector 2. A more detailed view of (a non-limiting embodiment of) the ejector 2 is shown in Fig. 2 and is discussed hereafter. In the ejector 2, the water-saturated oxygen- containing stream 10 is combined as a suction fluid with 15 a motive fluid 20, thereby obtaining a combined stream (not shown in Fig. 1; ‘25’ in Fig. 2). The combined stream is flashed by the ejector 2 whilst leaving the ejector 2, thereby obtaining a two-phase fluid 30 discharged from the ejector 2. 20 The two-phase fluid 30 discharged from the ejector 2 is separated in a conventional gas/liquid-separator 3 into an oxygen-containing gas stream 40 and a liquid stream 50. Part of the liquid stream 50 may be used as a bleed stream (not shown in Fig. 1; cf. stream 60 in Fig. 25 3). The oxygen-containing gas 40 (which has an increased pressure when compared to the water-saturated oxygen- containing stream 10) may be routed to further compression and purification (e.g. dehydrogenation, 30 dehydration, …) prior to end use, e.g. in a gasifier (see also Fig. 5 hereafter). The liquid stream 50 coming from the gas/liquid- separator 3 is pressurized in the pump 4, thereby
obtaining a pressurized liquid stream, which is used as the motive fluid 20 in the ejector 2. Figure 2 shows a more detailed view of an ejector that can be used as the ejector 2 in Fig. 1. 5 As can be seen from Fig. 2, the ejector 2 comprises an inlet 2a for the motive fluid 20, an inlet 2b for the suction fluid 10, a nozzle 2c within the ejector 2 for the motive fluid, a throat 2d with a diffuser section 2e and an outlet 2f for the fluid 30 to be discharged. 10 The motive fluid 20 and suction fluid 10 are combined in the ejector 2 (just after nozzle 2c) to form a combined stream 25. The combined stream 25 is then flashed by (the throat 2d of) the ejector 2, thereby obtaining a two-phase fluid 30 discharged from the 15 (outlet 2f of the) ejector 2. Figures 3 and 4 schematically show alternative embodiments of the method according to the present invention, wherein a cooler 5 is used downstream (Fig. 3) or upstream (Fig. 4) of the pump 4 in Fig. 1. It goes 20 without saying, that also a cooler may be present both downstream and upstream of the pump 4. In the embodiments of Figs 3 and 4, the cooler 5 is in the form of an indirect heat exchanger. In the embodiment of Fig. 3, the cooler 5 cools the 25 pressurized liquid stream (referred to as ‘45’ in Fig. 3) exiting the pump 4; the cooled pressurized liquid stream coming from the cooler 5 is subsequently used as the motive stream 20 in the ejector 2. Further, Figure 3 shows the presence of a bleed stream 60. 30 In the embodiment of Fig. 4, the cooler 5 cools the liquid stream 50 obtained in the gas/liquid-separator 3, which cooled liquid stream is then passed as stream ‘55’ to the pump 4.
Fig. 5 provides a fuller overview of the flow scheme of the method according to the present invention (based on the embodiment of Fig. 3), also showing a dehydrogenator 6, a dehydrator 7, a compressor 8, and a 5 gasifier 9. During use of the flow scheme of Fig. 5, the oxygen- containing gas stream 40 is dehydrogenated in dehydrogenator 6, thereby obtaining a dehydrogenated oxygen-containing stream 70. 10 This dehydrogenated oxygen-containing stream 70 is subsequently dehydrated in dehydrator 7, thereby obtaining a dehydrated dehydrogenated oxygen-containing stream 80 which is compressed in one or more compressors 8 thereby obtaining a compressed oxygen-containing stream 15 90. The compressed oxygen-containing stream 90 can be used, in particular in a gasifier 9. Examples Example 1 20 The flow scheme of Fig. 3 was used for illustrating the compressing of a gaseous water-saturated oxygen- containing stream originating from an electrolyzer. The compositions and conditions of the fluid (i.e. gas and liquid) streams in the various flow lines are provided in 25 Table 1 below. In the ejector 2, the Psuction was 1.1 bara, whilst the Pdischarge was 6.0 bara. 30
Table 1 Fluid stream 10 20 30 40 45 50 60 Phase V L V/L V L L L
scuss o 5 As can be seen from Table 1, the process according to the present invention allows for an effective way of compressing a water-saturated oxygen-containing stream originating from an electrolyzer. An important advantage of the present invention is 10 that by using the water-saturated oxygen-containing stream as a suction fluid in an ejector, a pressurized oxygen-containing gas stream can be obtained in a surprisingly simple manner, without the safety issues as confronted in ‘dry compression’. The pressurized oxygen- 15 containing gas stream can subsequently be used in a gasifier. The person skilled in the art will readily understand that many modifications may be made without departing from the scope of the invention. Further, the person 20 skilled in the art will readily understand that, while the present invention in some instances may have been illustrated making reference to a specific combination of features and measures, many of those features and measures are functionally independent from other features 25 and measures given in the respective embodiment(s) such
that they can be equally or similarly applied independently in other embodiments.
Claims
SP 2964 C L A I M S 1. A method of compressing a water-containing oxygen- containing stream originating from an electrolyzer, the method at least comprising the steps of: 5 (a) providing a water-containing oxygen-containing stream (10) originating from an electrolyzer; (b) combining the water-containing oxygen-containing stream (10) provided in step (a) as a suction fluid in an ejector (2) with a water-containing stream (20) as a 10 motive fluid, thereby obtaining a combined stream; (c) flashing the combined stream by the ejector (2), thereby obtaining a two-phase fluid (30) discharged from the ejector (2); (d) separating the two-phase fluid (30) discharged 15 from the ejector (2) into an oxygen-containing gas stream (40) and a liquid stream (50); (e) pressurizing the liquid stream (50) obtained in step (d), thereby obtaining a pressurized liquid stream; (f) using the pressurized liquid stream obtained in 20 step (e) as the motive fluid (20) in step (b); (g) dehydrogenating the oxygen-containing gas stream (40) obtained in step (d), thereby obtaining a dehydrogenated oxygen-containing stream (70); (h) dehydrating the dehydrogenated oxygen-containing 25 stream (70) obtained in step (g), thereby obtaining a dehydrated dehydrogenated oxygen-containing stream (80); (i) compressing the dehydrated dehydrogenated oxygen- containing stream (80) obtained in step (h) thereby obtaining a compressed oxygen-containing stream (90); and
(j) using the compressed oxygen-containing stream (90) obtained in step (i), in particular in a gasifier (9). 2. The method according to claim 1, wherein the water- containing oxygen-containing stream (10) provided in step (a) comprises at least 80 mol% O2, preferably at least 90 mol% O2, more preferably at least 95 mol% O2. 3. The method according to claim 1 or 2, wherein the water-containing oxygen-containing stream (10) provided in step (a) comprises from 2.0 to 20 mol% H2O, preferably from 3.0 mol% to 10.0 mol% H2O. 4. The method according to any of claims 1 or 2, wherein the water-containing oxygen-containing stream (10) provided in step (a) comprises from 0.3 to 2.0 mol% H2. 5. The method according to any one of the preceding claims, wherein the water-containing oxygen-containing stream (10) provided in step (a) has a pressure of from 0.1 bara to 2.5 bara, preferably from 0.5 bara to 1.5 bara. 6. The method according to any one of the preceding claims, wherein the water-containing oxygen-containing stream (10) provided in step (a) has a temperature of from 20 to 90°C, preferably from 40 to 80°C. 7. The method according to any one of the preceding claims, wherein the motive fluid (20) in step (b) comprises at least 80 mol% H2O, preferably at least 90 mol%, more preferably at least 95 mol%. 8. The method according to any one of the preceding claims, wherein the motive fluid (20) in step (b) has a pressure in the range of from 60 to 300 bara, preferably from 80 bara to 200 bara. 9. The method according to any one of the preceding claims, wherein the motive fluid (20) in step (b) has a
temperature of from 20 to 70°C, preferably from 30 to 50°C. 10. The method according to any one of the preceding claims, wherein the two-phase fluid (30) obtained in step 5 (c) has a pressure of from 2.0 bara to 10.0 bara, preferably from 3.0 bara to 6.0 bara. 11. An apparatus (1) for compressing a water-containing oxygen-containing stream (10) originating from an electrolyzer, the apparatus (1) at least comprising: 10 - an electrolyzer for electrolyzing a water-containing stream, thereby obtaining at least a H2-containing stream and a water-containing oxygen-containing stream (10); - an ejector (2) for combining the water-containing oxygen-containing stream (10) as a suction fluid with a 15 water-containing stream (20) as a motive fluid, thereby obtaining a combined stream (25) and flashing the combined stream (25), thereby obtaining a two-phase fluid (30) discharged from the ejector (2); - a separator (3) for separating the two-phase fluid (30) 20 discharged from the ejector (2) into an oxygen-containing gas stream (40) and a liquid stream (50); - a pressure increaser (4), in particular a pump, for pressurizing the liquid stream (50), thereby obtaining a pressurized liquid stream; 25 - a recycle line for recycling at least a part of the pressurized liquid stream to be used as the motive fluid (20) in the ejector (2); - a dehydrogenator (6) for dehydrogenating the oxygen- containing gas stream (40), thereby obtaining a 30 dehydrogenated oxygen-containing stream (70); - a dehydrator (7) for dehydrating the dehydrogenated oxygen-containing stream (70), thereby obtaining a dehydrated dehydrogenated oxygen-containing stream (80);
- at least one compressor (8) for compressing the dehydrated dehydrogenated oxygen-containing stream (80), thereby obtaining a compressed oxygen-containing stream (90); and 5 - a gasifier (9), in which the compressed oxygen- containing stream (90) is used.
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003105577A (en) | 2001-09-25 | 2003-04-09 | Mitsubishi Heavy Ind Ltd | Gas generator and fuel cell hybrid system |
CN203923390U (en) * | 2014-06-09 | 2014-11-05 | 重庆朝阳气体有限公司 | The device of a kind of brine electrolysis high purity oxygen processed |
WO2017102942A1 (en) | 2015-12-16 | 2017-06-22 | Shell Internationale Research Maatschappij B.V. | Gasification system and process |
WO2020035470A1 (en) | 2018-08-14 | 2020-02-20 | Shell Internationale Research Maatschappij B.V. | Gas cycle and method |
WO2022069906A1 (en) | 2020-10-02 | 2022-04-07 | Transvac Systems Limited | Apparatus and method for condensing a gas |
-
2023
- 2023-11-21 WO PCT/EP2023/082492 patent/WO2024110436A1/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003105577A (en) | 2001-09-25 | 2003-04-09 | Mitsubishi Heavy Ind Ltd | Gas generator and fuel cell hybrid system |
CN203923390U (en) * | 2014-06-09 | 2014-11-05 | 重庆朝阳气体有限公司 | The device of a kind of brine electrolysis high purity oxygen processed |
WO2017102942A1 (en) | 2015-12-16 | 2017-06-22 | Shell Internationale Research Maatschappij B.V. | Gasification system and process |
WO2020035470A1 (en) | 2018-08-14 | 2020-02-20 | Shell Internationale Research Maatschappij B.V. | Gas cycle and method |
WO2022069906A1 (en) | 2020-10-02 | 2022-04-07 | Transvac Systems Limited | Apparatus and method for condensing a gas |
Non-Patent Citations (1)
Title |
---|
"Perry's Chemical Engineers' Handbook", 1985, pages: 5 - 21 |
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