WO2024086981A1 - Battery cell and manufacturing method therefor, battery, and electrical device - Google Patents

Battery cell and manufacturing method therefor, battery, and electrical device Download PDF

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Publication number
WO2024086981A1
WO2024086981A1 PCT/CN2022/127083 CN2022127083W WO2024086981A1 WO 2024086981 A1 WO2024086981 A1 WO 2024086981A1 CN 2022127083 W CN2022127083 W CN 2022127083W WO 2024086981 A1 WO2024086981 A1 WO 2024086981A1
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WO
WIPO (PCT)
Prior art keywords
active material
material layer
battery cell
conductive column
shell
Prior art date
Application number
PCT/CN2022/127083
Other languages
French (fr)
Chinese (zh)
Inventor
许虎
金海族
曾毓群
赵丰刚
郭继鹏
牛少军
Original Assignee
宁德时代新能源科技股份有限公司
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Application filed by 宁德时代新能源科技股份有限公司 filed Critical 宁德时代新能源科技股份有限公司
Priority to PCT/CN2022/127083 priority Critical patent/WO2024086981A1/en
Publication of WO2024086981A1 publication Critical patent/WO2024086981A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/054Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/058Construction or manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/70Carriers or collectors characterised by shape or form
    • H01M4/75Wires, rods or strips

Definitions

  • the present application relates to the field of battery technology, and in particular to a battery cell and a manufacturing method thereof, a battery and an electrical device.
  • the embodiments of the present application provide a battery cell and a manufacturing method thereof, a battery, and an electrical device, which can effectively improve the production efficiency of the battery cell and reduce the manufacturing cost of the battery cell.
  • an embodiment of the present application provides a battery cell, comprising a shell, a conductive column and an end cover; a accommodating cavity is formed inside the shell, and along a first direction, one end of the shell is provided with an opening connected to the accommodating cavity, and a first active material layer is provided on the side of the shell facing the accommodating cavity; the conductive column extends along the first direction and is inserted into the accommodating cavity, and a second active material layer is provided on the outer peripheral surface of the conductive column, the second active material layer is arranged facing the first active material layer, and the second active material layer has an opposite polarity to the first active material layer; the end cover covers the opening and is connected to the conductive column.
  • a first active material layer and a second active material layer with opposite polarities are respectively arranged on the side of the shell facing the accommodating cavity and on the outer peripheral surface of the conductive column, and the conductive column is inserted into the accommodating cavity of the shell along the first direction, so that the first active material layer and the second active material layer are arranged facing each other, so that the shell and the conductive column can be used as the positive and negative output poles of the battery cell respectively to realize the input or output of the electric energy of the battery cell.
  • the battery cell adopting this structure does not need to wind the pole piece, and saves the process of assembling and connecting the current collecting component and the pole ear, which is conducive to improving the production efficiency of the battery cell.
  • a conductive column is arranged at the center of the battery cell, so as to alleviate the risk of collapse of the center hole of the battery cell during the later use, which is conducive to improving the stability of the battery cell and improving the safety of the battery cell.
  • the first active material layer is coated on a surface of the shell facing the accommodating cavity.
  • the shell can be directly used as the output electrode of the battery cell.
  • This structure does not require the first active material layer to be arranged on the current collector and then the current collector is connected to the shell, which is beneficial to optimize the production process of the battery cell, save the manufacturing cost of the battery cell, and can improve the connection stability and reliability of the first active material layer arranged on the shell.
  • the shell is a columnar structure, and a central axis of the shell extends along the first direction.
  • the battery cell is a columnar structure extending along the first direction
  • the battery cell adopting this structure is relatively simple and easy to assemble, which is beneficial to reduce the difficulty of assembling the battery cell and improve the production efficiency of the battery cell.
  • the length of the shell is L
  • the maximum dimension of a cross section of the shell perpendicular to the first direction is D 1 , satisfying L ⁇ D 1 .
  • the shell is a long strip structure extending along the first direction.
  • the battery cell adopting this structure is beneficial to improving the capacity of the first active material layer and the second active material layer, and can effectively increase the area of the region where the first active material layer and the second active material layer are facing each other, which is beneficial to improving the energy density and performance of the battery cell.
  • the ratio of the length of the shell in the first direction to the maximum dimension of the cross section of the shell perpendicular to the first direction can be greater than or equal to 1.5, so as to increase the coating amount of the first active material layer and the second active material layer, and the area of the area where the first active material layer and the second active material layer face each other, thereby alleviating the phenomenon that the capacity of the first active material layer and the second active material layer is insufficient due to the ratio being too small, and the area of the area where the first active material layer and the second active material layer face each other is too small.
  • the ratio of the length of the shell in the first direction to the maximum dimension of the cross section of the shell perpendicular to the first direction to be less than or equal to 25
  • the structure of the battery cell that is too slender due to the ratio being too large can be alleviated, so as to reduce the difficulty of manufacturing the battery cell.
  • both the first active material layer and the second active material layer are annular structures extending along the circumference of the conductive column.
  • the battery cell adopting this structure can further increase the capacity of the first active material layer and the second active material layer and the area of the region where the first active material layer and the second active material layer are arranged facing each other, thereby effectively improving the energy density of the battery cell and improving the performance of the battery cell.
  • the first active material layer surrounds the conductive column along its circumference to form a mounting channel for inserting the conductive column, and an inner surface of the mounting channel fits with an outer circumferential surface of the second active material layer.
  • the second active material layer is inserted into the installation channel formed by the first active material layer, and the shape of the surface of the second active material layer facing the first active material layer is the same as the shape of the surface of the first active material layer facing the second active material layer, it is convenient to assemble the conductive column provided with the second active material layer into the installation channel formed by the first active material layer, which is beneficial to reduce the difficulty of assembling the battery cell, and is beneficial to reduce the space waste between the first active material layer and the second active material layer, so as to improve the energy density of the battery cell.
  • a cross-section of the mounting channel perpendicular to the first direction is circular.
  • the cross-section of the installation channel formed by the first active material layer is set to a circle, that is, the installation channel is a circular channel.
  • This structure can effectively alleviate the interference or scratching between the first active material layer and the second active material layer when the second active material layer is assembled into the installation channel.
  • it can be beneficial to improve the assembly efficiency of the battery cell, and on the other hand, it can effectively improve the production quality of the battery cell.
  • the first active material layer includes a plurality of first reaction layers, and the plurality of first reaction layers are stacked along a radial direction of the conductive pillar.
  • the first active material layer is stacked by multiple first reaction layers arranged along the radial direction of the conductive column.
  • the first active material layer with such a structure is easy to manufacture on the one hand, which is beneficial to reduce the manufacturing difficulty of setting the first active material layer on the wall surface of the cavity of the shell. On the other hand, it can enhance the wetting effect of the electrolyte of the first active material layer to ensure the penetration of metal ions in the first active material layer.
  • the density of the first reaction layer close to the second active material layer among the plurality of first reaction layers is smaller than the density of other first reaction layers.
  • the kinetics of the first reaction layer close to the second active material layer is made better, so that the metal ions can diffuse into other first reaction layers, which is beneficial to reduce the internal resistance and improve the performance of the battery cell, and at the same time can alleviate the polarization phenomenon of the battery cell.
  • a particle diameter of the first reaction layer close to the second active material layer among the plurality of first reaction layers is smaller than a particle diameter of other first reaction layers.
  • the kinetics of the first reaction layer close to the second active material layer is made better, so that the metal ions can diffuse into other first reaction layers, which is beneficial to reduce the internal resistance and improve the performance of the battery cell, and at the same time can alleviate the polarization phenomenon of the battery cell.
  • the number of the first reaction layers of the first active material layer is N 1 , satisfying 2 ⁇ N 1 ⁇ 3.
  • the phenomenon of poor electrolyte infiltration caused by too small a number of first reaction layers can be alleviated to ensure the performance of the battery cell; on the other hand, the difficulty in manufacturing the first active material layer and the risk of falling off caused by too many first reaction layers can be reduced.
  • the second active material layer includes a plurality of second reaction layers, and the plurality of second reaction layers are stacked along a radial direction of the conductive pillar.
  • the second active material layer is stacked by multiple second reaction layers arranged radially along the conductive column.
  • the second active material layer with such a structure is easy to manufacture, which is beneficial to reduce the manufacturing difficulty of setting the second active material layer on the wall surface of the accommodating cavity of the shell. On the other hand, it can enhance the wetting effect of the electrolyte of the second active material layer to ensure the penetrability of metal ions in the second active material layer.
  • the density of the second reaction layer close to the first active material layer among the plurality of second reaction layers is smaller than the density of other second reaction layers.
  • the dynamics of the second reaction layer close to the first active material layer is made better, so that the metal ions can diffuse into other second reaction layers, which is beneficial to reduce the internal resistance and improve the performance of the battery cell, and at the same time can alleviate the polarization phenomenon of the battery cell.
  • a particle diameter of the second reaction layer close to the first active material layer among the plurality of second reaction layers is smaller than a particle diameter of other second reaction layers.
  • the kinetics of the second reaction layer close to the first active material layer is made better, so that the metal ions can diffuse into other second reaction layers, which is beneficial to reduce the internal resistance and improve the performance of the battery cell, and at the same time can alleviate the polarization phenomenon of the battery cell.
  • the number of the second reaction layers of the second active material layer is N 2 , satisfying 2 ⁇ N 2 ⁇ 3.
  • the phenomenon of poor electrolyte infiltration caused by too small a number of second reaction layers can be alleviated to ensure the performance of the battery cell; on the other hand, the difficulty in manufacturing the second active material layer and the risk of falling off caused by too many second reaction layers can be reduced.
  • a first notch groove is provided on the surface of the first active material layer facing the second active material layer, and the first notch groove is used to accommodate an electrolyte; and/or a second notch groove is provided on the surface of the second active material layer facing the first active material layer, and the second notch groove is used to accommodate an electrolyte.
  • the battery cell of this structure can effectively improve the first active material layer's ability to retain the electrolyte, and can improve the electrolyte's wetting effect on the first active material layer, thereby helping to improve the battery cell's performance.
  • the battery cell of this structure can effectively improve the second active material layer's ability to retain the electrolyte, and can improve the electrolyte's wetting effect on the second active material layer, thereby helping to improve the battery cell's performance.
  • the first active material layer is an annular structure extending along the circumference of the conductive column, and the first notch groove extends along the circumference of the conductive column.
  • the first notch groove is arranged as an annular structure extending along the circumference of the conductive column, that is, the first notch groove is arranged around the entire circumference of the first active material layer, which is beneficial to increase the capacity of the first notch groove for the electrolyte, and further can effectively improve the liquid retention capacity of the first active material layer to ensure the wetting effect of the electrolyte of the first active material layer.
  • first notch grooves there are a plurality of first notch grooves, and the plurality of first notch grooves are spaced apart along the first direction.
  • the second active material layer is an annular structure extending along the circumference of the conductive column, and the second notch groove extends along the circumference of the conductive column.
  • the second notch groove is arranged as an annular structure extending along the circumference of the conductive column, that is, the second notch groove is arranged around the entire circumference of the second active material layer, which is beneficial to increase the capacity of the second notch groove for the electrolyte, and further can effectively improve the liquid retention capacity of the first active material layer to ensure the wetting effect of the electrolyte of the first active material layer.
  • the end cover includes a cover body and a pole; the cover body covers the opening; the pole is insulated and installed on the cover body; wherein the conductive pole is connected to the pole.
  • the input or output of the electric energy of the battery cell can be realized through the pole, thereby alleviating the short circuit phenomenon between the conductive column and the shell through the cover body, which is beneficial to reduce the safety hazards of the battery cell during use.
  • the conductive column and the polar column are an integrally formed structure.
  • the battery cell adopting this structure is beneficial to improving the connection stability and reliability between the conductive column and the pole to ensure the conduction area on the one hand, and it is convenient to assemble the conductive column and the end cover as a whole with the shell on the other hand, which is beneficial to reduce the difficulty of assembling the battery cell and improve the assembly efficiency of the battery cell.
  • the first active material layer is a negative electrode active material layer
  • the second active material layer is a positive electrode active material layer
  • the first active material layer arranged on the side of the shell facing the accommodating cavity is the negative electrode active material layer
  • the second active material layer arranged on the outer peripheral surface of the conductive column is the positive electrode active material layer, so that the negative electrode active material layer can be coated on the outside of the positive electrode active material layer.
  • the battery cell further includes a separator; the separator is disposed between the first active material layer and the second active material layer to separate the first active material layer from the second active material layer.
  • the battery cell is also provided with an isolation membrane located between the first active material layer and the second active material layer, so as to effectively realize the insulation isolation between the first active material layer and the second active material layer, so as to reduce the short circuit phenomenon between the first active material layer and the second active material layer, thereby helping to reduce the safety hazards of the electrode assembly during use.
  • an embodiment of the present application further provides a battery, comprising the above-mentioned battery cell.
  • an embodiment of the present application further provides an electrical device, comprising the above-mentioned battery cell, wherein the battery cell is used to provide electrical energy; or comprising the above-mentioned battery, wherein the battery is used to provide electrical energy.
  • an embodiment of the present application also provides a method for manufacturing a battery cell, comprising: providing a shell, a conductive column and an end cover, the shell having a accommodating cavity formed therein, one end of the shell having an opening connected to the accommodating cavity along a first direction, and the conductive column extending along the first direction; a first active material layer is provided on a side of the shell facing the accommodating cavity; the conductive column is connected to the end cover; a second active material layer is provided on an outer peripheral surface of the conductive column, the second active material layer having an opposite polarity to the first active material layer; the conductive column is inserted into the accommodating cavity of the shell along the first direction so that the first active material layer and the second active material layer are arranged facing each other, and the end cover is covered with the opening.
  • a first active material layer is first arranged on a side of the shell facing the accommodating cavity, and a second active material layer is arranged on the outer peripheral surface of the conductive column after the conductive column is connected to the end cover. Then, the conductive column provided with the second active material layer is inserted into the accommodating cavity of the shell along the first direction to realize the facing arrangement of the first active material layer and the second active material layer, and at the same time, the end cover and the opening are covered with each other, thereby completing the assembly and manufacturing of the battery cell.
  • the battery cell manufactured by this manufacturing method does not need to wind the pole piece, and saves the process of assembling and connecting the current collecting component and the pole ear, thereby greatly optimizing the production process and production rhythm of the battery cell, which is beneficial to improving the production efficiency of the battery cell.
  • the method for manufacturing the battery cell also includes: providing an isolation membrane; before inserting the conductive column into the accommodating cavity of the shell along the first direction so that the first active material layer and the second active material layer are arranged face to face, and the end cover is covered on the opening, the method for manufacturing the battery cell also includes: wrapping the isolation membrane on the outside of the second active material layer.
  • the isolation membrane is first coated on the outside of the second active material layer, so that when the conductive column is inserted into the accommodating cavity of the shell, the isolation membrane can be assembled into the shell at the same time, and the isolation membrane is arranged between the first active material layer and the second active material layer.
  • This manufacturing method can improve the assembly efficiency of the isolation membrane on the one hand, and reduce the difficulty of assembling the isolation membrane on the other hand.
  • FIG1 is a schematic diagram of the structure of a vehicle provided in some embodiments of the present application.
  • FIG2 is an exploded view of a battery structure provided by some embodiments of the present application.
  • FIG3 is a schematic diagram of the structure of a battery cell provided in some embodiments of the present application.
  • FIG4 is an exploded view of the structure of a battery cell provided in some embodiments of the present application.
  • FIG5 is a cross-sectional view of a battery cell provided in some embodiments of the present application.
  • FIG6 is an exploded view of the structure of a battery cell provided in some other embodiments of the present application.
  • FIG7 is an exploded view of the structure of a battery cell provided in some other embodiments of the present application.
  • FIG8 is a cross-sectional view of a battery cell provided in some other embodiments of the present application.
  • FIG9 is a partial enlarged view of the battery cell A shown in FIG8;
  • FIG10 is an exploded view of the structure of a battery cell provided in yet other embodiments of the present application.
  • FIG11 is a cross-sectional view of a first active material layer of a battery cell provided in yet other embodiments of the present application.
  • FIG12 is a schematic flow chart of a method for manufacturing a battery cell provided in some embodiments of the present application.
  • FIG. 13 is a schematic flow chart of a method for manufacturing a battery cell provided in some other embodiments of the present application.
  • Icon 1000-vehicle; 100-battery; 10-box; 11-first box body; 12-second box body; 20-battery cell; 21-shell; 211-accommodating chamber; 212-opening; 22-conductive column; 23-end cover; 231-cover body; 232-pole; 24-first active material layer; 241-installation channel; 242-first reaction layer; 243-first notch groove; 25-second active material layer; 251-second reaction layer; 252-second notch groove; 26-isolation membrane; 200-controller; 300-motor; X-first direction; Y-radial direction of the conductive column.
  • the terms “installed”, “connected”, “connected”, and “attached” should be understood in a broad sense, for example, it can be a fixed connection, a detachable connection, or an integral connection; it can be a direct connection, or an indirect connection through an intermediate medium, or it can be the internal communication of two elements.
  • installed should be understood in a broad sense, for example, it can be a fixed connection, a detachable connection, or an integral connection; it can be a direct connection, or an indirect connection through an intermediate medium, or it can be the internal communication of two elements.
  • a and/or B can represent: A exists alone, A and B exist at the same time, and B exists alone.
  • the character "/" in this application generally indicates that the associated objects before and after are in an "or" relationship.
  • battery cells may include lithium-ion secondary batteries, lithium-ion primary batteries, lithium-sulfur batteries, sodium-ion batteries or magnesium-ion batteries, etc., and the embodiments of the present application do not limit this.
  • Battery cells may be cylindrical, flat, rectangular or other shapes, etc., and the embodiments of the present application do not limit this. Battery cells are generally divided into three types according to the packaging method: cylindrical battery cells, square battery cells and soft-pack battery cells, and the embodiments of the present application do not limit this.
  • the battery mentioned in the embodiments of the present application refers to a single physical module including one or more battery cells to provide higher voltage and capacity.
  • the battery mentioned in the present application may include a battery module or a battery pack.
  • the battery generally includes a box for encapsulating one or more battery cells or multiple battery modules. The box can prevent liquid or other foreign matter from affecting the charging or discharging of the battery cells.
  • Batteries have outstanding advantages such as high energy density, low environmental pollution, high power density, long service life, wide adaptability, and low self-discharge coefficient. They are an important part of the development of new energy today. With the continuous development of battery technology, higher requirements have been put forward in terms of battery production efficiency and manufacturing cost. Among them, the battery is composed of multiple battery cells, so the production efficiency and manufacturing cost of the battery cells determine the production efficiency and manufacturing cost of the battery.
  • the battery cells are usually assembled into electrode assemblies (bare cells) by winding or laminating positive electrode sheets, negative electrode sheets and separators, which are then loaded into a housing, covered with end caps, and finally injected with electrolyte.
  • the electrode sheets need to be wound or laminated first, and then the pole ears of the electrode assembly need to be welded and assembled with the current collecting components, and finally the current collecting components need to be welded and assembled with the end caps or housings, which results in a more complicated and difficult manufacturing process for the battery cells, and more assembly parts and electrolytes are required, which leads to lower production efficiency and higher manufacturing costs for the battery cells.
  • the battery cell includes a shell, a conductive column and an end cover.
  • a accommodating cavity is formed inside the shell. Along the first direction, one end of the shell is provided with an opening connected to the accommodating cavity, and a first active material layer is provided on the side of the shell facing the accommodating cavity.
  • the conductive column extends along the first direction and is inserted into the accommodating cavity.
  • a second active material layer is provided on the outer peripheral surface of the conductive column. The second active material layer is arranged facing the first active material layer, and the second active material layer has an opposite polarity to the first active material layer.
  • the end cover covers the opening and is connected to the conductive column.
  • a first active material layer and a second active material layer with opposite polarities are respectively arranged on the side of the shell facing the accommodating cavity and on the outer peripheral surface of the conductive column, and the conductive column is inserted into the accommodating cavity of the shell along the first direction, so that the first active material layer and the second active material layer are arranged facing each other, so that the shell and the conductive column can be used as the positive and negative output poles of the battery cell respectively to realize the input or output of the electric energy of the battery cell.
  • the battery cell adopting this structure does not need to wind the pole piece, and saves the process of assembling and connecting the current collecting component and the pole ear, which is conducive to improving the production efficiency of the battery cell.
  • a conductive column is arranged at the center of the battery cell, so as to alleviate the risk of collapse of the center hole of the battery cell during the later use, which is conducive to improving the stability of the battery cell and improving the safety of the battery cell.
  • the battery cells disclosed in the embodiments of the present application can be used, but not limited to, in electrical devices such as vehicles, ships or aircraft.
  • a power supply system comprising the battery cells and batteries disclosed in the present application can be used to form the electrical device, which is conducive to optimizing the manufacturing process of the battery cells and the accessories required for the battery cells, so as to improve the production efficiency of the battery cells and reduce the manufacturing cost of the battery cells.
  • the embodiment of the present application provides an electric device using a battery as a power source
  • the electric device may be, but is not limited to, a mobile phone, a tablet, a laptop, an electric toy, an electric tool, a battery car, an electric car, a ship, a spacecraft, etc.
  • the electric toy may include a fixed or mobile electric toy, for example, a game console, an electric car toy, an electric ship toy, an electric airplane toy, etc.
  • the spacecraft may include an airplane, a rocket, a space shuttle, a spacecraft, etc.
  • FIG. 1 is a schematic diagram of the structure of a vehicle 1000 provided in some embodiments of the present application.
  • the vehicle 1000 may be a fuel vehicle, a gas vehicle or a new energy vehicle, and the new energy vehicle may be a pure electric vehicle, a hybrid vehicle or an extended-range vehicle, etc.
  • a battery 100 is provided inside the vehicle 1000, and the battery 100 may be provided at the bottom, head or tail of the vehicle 1000.
  • the battery 100 may be used to power the vehicle 1000, for example, the battery 100 may be used as an operating power source for the vehicle 1000.
  • the vehicle 1000 may also include a controller 200 and a motor 300, and the controller 200 is used to control the battery 100 to power the motor 300, for example, for the starting, navigation and driving power requirements of the vehicle 1000.
  • the battery 100 can not only serve as an operating power source for the vehicle 1000, but also serve as a driving power source for the vehicle 1000, replacing or partially replacing fuel or natural gas to provide driving power for the vehicle 1000.
  • Figure 2 is an exploded view of the structure of the battery 100 provided in some embodiments of the present application
  • Figure 3 is a schematic diagram of the structure of the battery cell 20 provided in some embodiments of the present application.
  • the battery 100 includes a box body 10 and a battery cell 20, and the battery cell 20 is used to be accommodated in the box body 10.
  • the box body 10 is used to provide an assembly space for the battery cell 20, and the box body 10 can adopt a variety of structures.
  • the box body 10 may include a first box body 11 and a second box body 12, and the first box body 11 and the second box body 12 cover each other, and the first box body 11 and the second box body 12 jointly define an assembly space for accommodating the battery cell 20.
  • the second box body 12 can be a hollow structure with one end open, and the first box body 11 can be a plate-like structure.
  • the first box body 11 covers the open side of the second box body 12, so that the first box body 11 and the second box body 12 jointly define an assembly space;
  • the first box body 11 and the second box body 12 can also be hollow structures with one side open, and the open side of the first box body 11 covers the open side of the second box body 12.
  • the box body 10 formed by the first box body 11 and the second box body 12 can be in various shapes, such as a cylinder, a cuboid, etc.
  • the battery 100 there may be multiple battery cells 20, and the multiple battery cells 20 may be connected in series, in parallel, or in a mixed connection.
  • a mixed connection means that the multiple battery cells 20 are both connected in series and in parallel.
  • the multiple battery cells 20 may be directly connected in series, in parallel, or in a mixed connection, and then the whole formed by the multiple battery cells 20 is accommodated in the box 10; of course, the battery 100 may also be a battery module formed by connecting multiple battery cells 20 in series, in parallel, or in a mixed connection, and then the multiple battery modules are connected in series, in parallel, or in a mixed connection to form a whole, and accommodated in the box 10.
  • the battery 100 may also include other structures, for example, the battery 100 may also include a busbar component for realizing electrical connection between the multiple battery cells 20.
  • Each battery cell 20 may be a secondary battery or a primary battery; it may also be a lithium-sulfur battery, a sodium-ion battery or a magnesium-ion battery, but is not limited thereto.
  • the battery cell 20 may be cylindrical, flat, rectangular or in other shapes. For example, in FIG3 , the battery cell 20 is a cylindrical structure.
  • FIG. 4 is an exploded view of the structure of a battery cell 20 provided in some embodiments of the present application
  • FIG. 5 is a cross-sectional view of a battery cell 20 provided in some embodiments of the present application.
  • the present application provides a battery cell 20, and the battery cell 20 includes a shell 21, a conductive column 22, and an end cover 23.
  • a receiving cavity 211 is formed inside the shell 21, and an opening 212 communicating with the receiving cavity 211 is provided at one end of the shell 21 along the first direction X, and a first active material layer 24 is provided on the side of the shell 21 facing the receiving cavity 211.
  • the conductive column 22 extends along the first direction X and is inserted into the receiving cavity 211, and a second active material layer 25 is provided on the outer peripheral surface of the conductive column 22, and the second active material layer 25 is arranged facing the first active material layer 24, and the second active material layer 25 is opposite to the first active material layer 24.
  • the end cover 23 covers the opening 212 and is connected to the conductive column 22.
  • the first active material layer 24 is arranged on the side of the shell 21 facing the accommodating cavity 211, and the second active material layer 25 is arranged on the conductive column 22, and the conductive column 22 is connected to the end cover 23, so that the shell 21 and the end cover 23 respectively serve as the output pole of the battery cell 20 to realize the input or output of electrical energy.
  • the first active material layer 24 can be arranged on the side of the shell 21 facing the accommodating cavity 211 in various structures.
  • the first active material layer 24 can be directly coated on the surface of the shell 21 facing the accommodating cavity 211, that is, the first active material layer 24 is coated on the cavity wall surface of the accommodating cavity 211.
  • the first active material layer 24 can also be indirectly arranged on the surface of the shell 21 facing the accommodating cavity 211.
  • the first active material layer 24 is coated on a current collector made of metal foil, and then the current collector is covered and connected to the surface of the shell 21 facing the accommodating cavity 211.
  • the first active material layer 24 may also be not electrically connected to the shell 21, that is, the first active material layer 24 is insulated and installed on the surface of the shell 21 facing the accommodating cavity 211.
  • the first active material layer 24 is coated on a current collector made of metal foil, and the current collector is then covered on the surface of the shell 21 facing the accommodating cavity 211, and an insulating layer is arranged between the current collector and the shell 21. That is to say, the current collector provided with the first active material layer 24 is connected to the surface of the shell 21 facing the accommodating cavity 211 through the insulating layer to achieve insulation isolation between the current collector provided with the first active material layer 24 and the shell 21.
  • the current collector provided with the first active material layer 24 can be connected to the end cover 23 so that the end cover 23 serves as the output pole of the first active material layer 24, and can also be connected to the electrode terminal insulated and installed on the shell 21, so that the electrode terminal insulated and installed on the shell 21 serves as the output pole of the first active material layer 24.
  • the first active material layer 24 and the second active material layer 25 are active materials disposed on the shell 21 and the conductive column 22 respectively.
  • the first active material layer 24 and the second active material layer 25 are areas where chemical reactions occur in the battery cell 20, and they mainly work by moving metal ions between the first active material layer 24 and the second active material layer 25.
  • the material of the first active material layer 24 may be lithium cobalt oxide, lithium iron phosphate, ternary lithium or lithium manganese oxide, etc.
  • the second active material layer 25 is a negative electrode active material layer, and the material of the second active material layer 25 may be carbon or silicon, etc.
  • the material of the first active material layer 24 may be carbon or silicon, etc.
  • the second active material layer 25 is a positive electrode active material layer, and the material of the second active material layer 25 may be lithium cobalt oxide, lithium iron phosphate, ternary lithium or lithium manganese oxide, etc.
  • the conductive pillar 22 extends along the first direction X and is inserted into the accommodating cavity 211 , that is, the conductive pillar 22 is inserted into the accommodating cavity 211 of the housing 21 along the first direction X.
  • the second active material layer 25 is disposed on the outer peripheral surface of the conductive column 22 , that is, the conductive column 22 is inserted into the accommodating cavity 211 , and the second active material layer 25 is disposed on the surface of the conductive column 22 facing the housing 21 .
  • the conductive pillar 22 may have a variety of structures.
  • the conductive pillar 22 may be a solid structure, that is, the conductive pillar 22 is a solid columnar structure extending along the first direction X.
  • the conductive pillar 22 may also be a hollow structure, that is, the conductive pillar 22 is a hollow columnar structure extending along the first direction X, so that the cross section of the conductive pillar 22 perpendicular to the first direction X is annular.
  • the conductive pillar 22 is a solid columnar structure extending along the first direction X.
  • the conductive pillar 22 may have various shapes, such as a cylindrical structure, a rectangular cylindrical structure, a hexagonal prism structure, etc.
  • the conductive pillar 22 is a cylindrical structure extending along the first direction X.
  • the second active material layer 25 is disposed facing the first active material layer 24, that is, in the radial direction Y of the conductive column, the first active material layer 24 and the second active material layer 25 are disposed opposite to each other, wherein the radial direction Y of the conductive column is perpendicular to the first direction X.
  • the radial direction Y of the conductive column is the direction in which the outer edge of the cross section of the conductive column 22 perpendicular to the first direction X points to the central axis of the conductive column 22 or the direction in which the central axis of the conductive column 22 points to the outer edge of the cross section of the conductive column 22 perpendicular to the first direction X.
  • the housing 21 may also be used to contain electrolytes, such as electrolytes.
  • the housing 21 may also be made of a variety of materials, such as copper, iron, aluminum, steel, aluminum alloy, and the like.
  • the housing 21 can be in various structural forms.
  • the housing 21 is a hollow structure with an opening 212 on one side, and the end cap 23 covers the opening 212 of the housing 21 and forms a sealed connection to form a sealed space for accommodating the conductive column 22 and the electrolyte.
  • the housing 21 can be in various shapes, such as a cylinder, a cuboid, etc. Exemplarily, in FIG4 , the housing 21 is a cylindrical structure.
  • the conductive column 22 When assembling the battery cell 20, the conductive column 22 can be first connected to the end cover 23, and then the conductive column 22 coated with the second active material layer 25 can be inserted into the accommodating cavity 211 of the shell 21, and the electrolyte is filled into the shell 21, and finally the end cover 23 and the shell 21 are covered and sealed.
  • the shell 21 is not limited to the above structure, and the shell 21 can also be other structures.
  • the shell 21 is a hollow structure with openings 212 at two opposite ends in the first direction X.
  • the battery cell 20 includes two end covers 23, and one end cover 23 corresponds to covering an opening 212 of the shell 21 to form a sealed connection.
  • the battery cell 20 may further include a pressure relief mechanism, which may be mounted on the end cap 23 or the housing 21.
  • the pressure relief mechanism is used to release the pressure inside the battery cell 20 when the internal pressure or temperature of the battery cell 20 reaches a predetermined value.
  • the pressure relief mechanism may be a component such as an explosion-proof valve, an explosion-proof disk, an air valve, a pressure relief valve or a safety valve.
  • the shell 21 and the conductive column 22 can be used as the positive and negative output electrodes of the battery cell 20 to realize the input or output of electric energy of the battery cell 20.
  • the battery cell 20 adopting such a structure does not need to wind the pole piece, and saves the process of assembling and connecting the current collecting component and the pole ear, which is beneficial to improving the production efficiency of the battery cell 20.
  • a conductive column 22 is provided at the center of the battery cell 20 , thereby alleviating the risk of the center hole of the battery cell 20 collapsing during later use, thereby facilitating improving the use stability of the battery cell 20 and improving the use safety of the battery cell 20 .
  • the first active material layer 24 is coated on the surface of the shell 21 facing the accommodating cavity 211 .
  • the first active material layer 24 is coated on the surface of the housing 21 facing the accommodating cavity 211 , that is, the first active material layer 24 is directly disposed on the cavity wall surface of the accommodating cavity 211 .
  • the shell 21 can be directly used as the output pole of the battery cell 20.
  • This structure does not require the first active material layer 24 to be arranged on the current collector and then the current collector is connected to the shell 21, which is beneficial to optimize the production process of the battery cell 20, save the manufacturing cost of the battery cell 20, and can improve the connection stability and reliability of the first active material layer 24 arranged on the shell 21.
  • the shell 21 is a columnar structure, and the central axis of the shell 21 extends along the first direction X.
  • the central axis of the shell 21 extends along the first direction X, that is, the shell 21 is a columnar structure extending along the first direction X.
  • the shape of the shell 21 can be various.
  • the shell 21 is a cylindrical structure extending along the first direction X.
  • Figure 6, which is a structural explosion diagram of the battery cell 20 provided in some embodiments of the present application.
  • the shell 21 can also be a hexagonal prism structure extending along the first direction X.
  • the shell 21 can also be a triangular prism structure, a rectangular columnar structure or a pentagonal columnar structure, etc.
  • the battery cell 20 By configuring the shell 21 as a columnar structure extending along the first direction X, that is, the battery cell 20 is a columnar structure extending along the first direction X, the battery cell 20 with this structure has a simpler structure and is easy to assemble, thereby helping to reduce the difficulty of assembling the battery cell 20 and improve the production efficiency of the battery cell 20.
  • the length of the shell 21 is L, and the maximum dimension of the cross section of the shell 21 perpendicular to the first direction X is D 1 , satisfying L ⁇ D 1 .
  • the maximum dimension of the cross section of the shell 21 perpendicular to the first direction X in the direction perpendicular to the first direction X is D 1 , that is, the maximum distance between any two points on the outer edge of the cross section of the shell 21 perpendicular to the first direction X is D 1 , that is, if the shell 21 is a cylindrical structure, D 1 is the diameter of the cross section of the shell 21 perpendicular to the first direction X; if the shell 21 is a triangular prism structure, D 1 is the longest side of the cross section of the shell 21 perpendicular to the first direction X; if the shell 21 is a rectangular columnar structure, D 1 is the diagonal of the cross section of the shell 21 perpendicular to the first direction X.
  • the shell 21 in the first direction X By setting the length of the shell 21 in the first direction X to be greater than or equal to the maximum dimension of the cross section of the shell 21 in the direction perpendicular to the first direction X, that is, the shell 21 is a long strip structure extending along the first direction X.
  • the battery cell 20 adopting such a structure is beneficial to improving the capacity of the first active material layer 24 and the second active material layer 25, and can effectively increase the area of the region where the first active material layer 24 and the second active material layer 25 are arranged facing each other, thereby helping to improve the energy density and performance of the battery cell 20.
  • 1.5 ⁇ L/D 1 that is, the length of the shell 21 in the first direction X is more than 1.5 times the maximum dimension of the cross section of the shell 21 perpendicular to the first direction X.
  • L/D 1 ⁇ 25 that is, the length of the shell 21 in the first direction X is less than 25 times the maximum dimension of the cross section of the shell 21 perpendicular to the first direction X.
  • the shell 21 is a cylindrical structure, and the maximum dimension of the cross section of the shell 21 perpendicular to the first direction X is the diameter of the shell 21 .
  • the battery cell 20 is a structure in which the length in the first direction X is greater than the size of the cross section of the battery cell 20, that is, the battery cell 20 is an elongated strip-shaped structure extending along the first direction X.
  • the battery cell 20 is an elongated strip-shaped structure extending along the first direction X
  • the length of the outer peripheral surface of the conductive column 22 in the first direction X can be increased, and the length of the cavity wall surface of the accommodating cavity 211 of the shell 21 in the first direction X can be increased, thereby effectively increasing the coating amount of the first active material layer 24 and the second active material layer 25, and increasing the area of the region where the first active material layer 24 and the second active material layer 25 are arranged facing each other.
  • the length of the shell 21 in the first direction X is more than 3 times the diameter of the shell 21 , so that the battery cell 20 is an elongated structure extending along the first direction X, thereby effectively ensuring the capacity of the first active material layer 24 and the second active material layer 25 , and the area of the region where the first active material layer 24 and the second active material layer 25 are disposed facing each other.
  • the diameter of the shell 21 and the corresponding length of the shell 21 in the first direction X can be: 18 mm and 65 mm, 18 mm and 200 mm, 18 mm and 300 mm, 21 mm and 70 mm, 21 mm and 200 mm, 21 mm and 310 mm, etc.
  • the ratio of the length of the shell 21 in the first direction X to the maximum dimension of the cross section of the shell 21 perpendicular to the first direction X can be greater than or equal to 1.5, so as to increase the coating amount of the first active material layer 24 and the second active material layer 25, and the area of the area where the first active material layer 24 and the second active material layer 25 face each other, thereby alleviating the phenomenon that the first active material layer 24 and the second active material layer 25 are insufficient in the amount of the first active material layer 24 and the second active material layer 25 and the area where the first active material layer 24 and the second active material layer 25 face each other due to the ratio being too small.
  • the battery cell 20 can be relieved from being too slender due to the ratio being too large, so as to reduce the difficulty of manufacturing the battery cell 20.
  • the battery cell 20 can also be set to a structure of 1.5 ⁇ L/D 1 and/or L/D 1 ⁇ 25.
  • the first active material layer 24 and the second active material layer 25 are both annular structures extending along the circumference of the conductive pillar 22 .
  • the first active material layer 24 and the second active material layer 25 are both annular structures extending along the circumferential direction of the conductive column 22, that is, the first active material layer 24 and the second active material layer 25 are both annular structures surrounding the outside of the conductive column 22, that is, the second active material layer 25 surrounds the outer peripheral side of the conductive column 22, and the first active material layer 24 surrounds the outer peripheral side of the second active material layer 25.
  • the circumferential direction of the conductive column 22 refers to the direction of surrounding the central axis of the conductive column 22.
  • the thickness of the first active material layer 24 is D 2 , satisfying 0.1 mm ⁇ D 2 ⁇ 15 mm.
  • the thickness of the first active material layer 24 in the radial direction Y of the conductive pillar may be 0.1 mm, 0.5 mm, 1 mm, 2 mm, 5 mm, 8 mm, 10 mm, or 15 mm.
  • the thickness of the second active material layer 25 is D 3 , satisfying 0.1 mm ⁇ D 3 ⁇ 15 mm.
  • the thickness of the second active material layer 25 in the radial direction Y of the conductive pillar may be 0.1 mm, 0.5 mm, 1 mm, 2 mm, 5 mm, 8 mm, 10 mm, or 15 mm.
  • the battery cell 20 using this structure can further increase the capacity of the first active material layer 24 and the second active material layer 25 and the area of the region where the first active material layer 24 and the second active material layer 25 are facing each other, thereby effectively improving the energy density of the battery cell 20 and improving the performance of the battery cell 20.
  • the first active material layer 24 surrounds the conductive column 22 along the circumference to form a mounting channel 241 for inserting the conductive column 22, and the inner surface of the mounting channel 241 fits with the outer peripheral surface of the second active material layer 25.
  • the first active material layer 24 surrounds the conductive pillar 22 along its circumference to form a mounting channel 241 for the conductive pillar 22 to be inserted into. That is, the first active material layer 24 surrounds the outer circumference of the second active material layer 25 .
  • the inner surface of the mounting channel 241 and the outer peripheral surface of the second active material layer 25 fit each other, that is, the second active material layer 25 is inserted in the mounting channel 241 formed by the first active material layer 24, and the shape of the surface of the second active material layer 25 facing the first active material layer 24 is the same as the shape of the surface of the first active material layer 24 facing the second active material layer 25.
  • the cross-section of the mounting channel 241 formed by the first active material layer 24 perpendicular to the first direction X is circular, then the cross-section of the outer peripheral surface of the second active material layer 25 perpendicular to the first direction X is also circular; if the cross-section of the mounting channel 241 formed by the first active material layer 24 perpendicular to the first direction X is polygonal, then the cross-section of the outer peripheral surface of the second active material layer 25 perpendicular to the first direction X is also polygonal.
  • the inner surface of the first active material layer 24 and the outer peripheral surface of the second active material layer 25 are a mutually fitting structure, it is convenient to assemble the conductive column 22 provided with the second active material layer 25 into the installation channel 241 formed by the first active material layer 24, which is beneficial to reduce the difficulty of assembling the battery cell 20 and reduce the space waste between the first active material layer 24 and the second active material layer 25, so as to improve the energy density of the battery cell 20.
  • a cross section of the mounting channel 241 perpendicular to the first direction X is circular.
  • the cross section of the installation channel 241 perpendicular to the first direction X is circular, and the installation channel 241 is a circular channel.
  • FIG. 7 is a structural explosion diagram of the battery cell 20 provided in some other embodiments of the present application.
  • the cross-section of the installation channel 241 perpendicular to the first direction X is a hexagon.
  • the cross-section of the installation channel 241 perpendicular to the first direction X can also be a rectangle, a pentagon, etc.
  • the cross-sectional shape of the shell 21 perpendicular to the first direction X may be the same as or different from the cross-sectional shape of the mounting channel 241 perpendicular to the first direction X.
  • the cross-sectional shape of the shell 21 perpendicular to the first direction X is the same as the cross-sectional shape of the mounting channel 241 perpendicular to the first direction X, and the cross-sectional shape of the shell 21 perpendicular to the first direction X and the cross-sectional shape of the mounting channel 241 perpendicular to the first direction X are both circular.
  • the cross-sectional shape of the shell 21 perpendicular to the first direction X and the cross-sectional shape of the mounting channel 241 perpendicular to the first direction X are both hexagonal.
  • the cross-sectional shape of the shell 21 perpendicular to the first direction X is different from the cross-sectional shape of the mounting channel 241 perpendicular to the first direction X, and the cross-sectional shape of the shell 21 perpendicular to the first direction X is a hexagon, and the cross-sectional shape of the mounting channel 241 perpendicular to the first direction X is both circular.
  • the cross-sectional shape of the shell 21 perpendicular to the first direction X may also be circular, and the cross-sectional shape of the mounting channel 241 perpendicular to the first direction X may be hexagonal.
  • this structure can effectively alleviate the interference or scratching between the first active material layer 24 and the second active material layer 25 when the second active material layer 25 is assembled into the installation channel 241.
  • it can be beneficial to improve the assembly efficiency of the battery cell 20, and on the other hand, it can effectively improve the production quality of the battery cell 20.
  • Figure 8 is a cross-sectional view of a battery cell 20 provided in other embodiments of the present application
  • Figure 9 is a partial enlarged view of the battery cell 20 at A shown in Figure 8.
  • the first active material layer 24 includes a plurality of first reaction layers 242, and the plurality of first reaction layers 242 are stacked along the radial direction Y of the conductive pillar.
  • the plurality of first reaction layers 242 are stacked along the radial direction Y of the conductive pillar, that is, the plurality of first reaction layers 242 are stacked along the radial direction Y of the conductive pillar between the shell 21 and the second active material layer 25 .
  • the first active material layer 24 is formed by stacking multiple first reaction layers 242 arranged along the radial direction Y of the conductive column.
  • the first active material layer 24 with such a structure is easy to manufacture, which is beneficial to reduce the manufacturing difficulty of setting the first active material layer 24 on the cavity wall surface of the accommodating cavity 211 of the shell 21. On the other hand, it can enhance the wetting effect of the electrolyte of the first active material layer 24 to ensure the penetrability of metal ions in the first active material layer 24.
  • the density of the first reaction layer 242 close to the second active material layer 25 among the plurality of first reaction layers 242 is less than the density of the other first reaction layers 242 .
  • the density of the first reaction layer 242 close to the second active material layer 25 among the multiple first reaction layers 242 is smaller than that of other first reaction layers 242 , that is, the density of the first reaction layer 242 closest to the second active material layer 25 among the multiple first reaction layers 242 is the smallest.
  • the dynamics of the first reaction layer 242 close to the second active material layer 25 is made better, so that the metal ions can diffuse into other first reaction layers 242, which is beneficial to reduce the internal resistance and improve the performance of the battery cell 20, while also alleviating the polarization phenomenon of the battery cell 20.
  • the particle diameter of the first reaction layer 242 close to the second active material layer 25 among the plurality of first reaction layers 242 is smaller than the particle diameters of other first reaction layers 242 .
  • the particle diameter of the first reaction layer 242 close to the second active material layer 25 among the multiple first reaction layers 242 is smaller than the particle diameters of other first reaction layers 242, that is, the material particle size of the first reaction layer 242 closest to the second active material layer 25 among the multiple first reaction layers 242 is the smallest.
  • the dynamics of the first reaction layer 242 close to the second active material layer 25 is made better, so that the metal ions can diffuse into other first reaction layers 242, which is beneficial to reduce the internal resistance and improve the performance of the battery cell 20, while also alleviating the polarization phenomenon of the battery cell 20.
  • the number of the first reaction layers 242 of the first active material layer 24 is N 1 , satisfying 2 ⁇ N 1 ⁇ 3.
  • the number of the first reaction layers 242 of the first active material layer 24 may be 2 or 3.
  • the first active material layer 24 includes two first reaction layers 242 stacked along the radial direction Y of the conductive column.
  • the phenomenon of poor electrolyte infiltration caused by too small a number of first reaction layers 242 can be alleviated to ensure the performance of the battery cell 20; on the other hand, the manufacturing difficulty of the first active material layer 24 and the risk of falling off caused by too many first reaction layers 242 can be reduced.
  • the second active material layer 25 includes a plurality of second reaction layers 251 , and the plurality of second reaction layers 251 are stacked along a radial direction Y of the conductive pillar.
  • the plurality of second reaction layers 251 are stacked along the radial direction Y of the conductive pillars, that is, the plurality of second reaction layers 251 are stacked along the radial direction Y of the conductive pillars between the first active material layer 24 and the conductive pillars 22 .
  • the second active material layer 25 is formed by stacking multiple second reaction layers 251 arranged along the radial direction Y of the conductive column.
  • the second active material layer 25 with such a structure is easy to manufacture, which is beneficial to reduce the manufacturing difficulty of setting the second active material layer 25 on the cavity wall surface of the accommodating cavity 211 of the shell 21. On the other hand, it can enhance the wetting effect of the electrolyte of the second active material layer 25 to ensure the penetrability of metal ions in the second active material layer 25.
  • the density of the second reaction layer 251 close to the first active material layer 24 among the plurality of second reaction layers 251 is less than the density of the other second reaction layers 251 .
  • the density of the second reaction layer 251 close to the first active material layer 24 among the multiple second reaction layers 251 is lower than the density of other second reaction layers 251 , that is, the density of the second reaction layer 251 closest to the first active material layer 24 among the multiple second reaction layers 251 is the smallest.
  • the dynamics of the second reaction layer 251 close to the first active material layer 24 is made better, so that the metal ions can diffuse into other second reaction layers 251, which is beneficial to reduce the internal resistance and improve the performance of the battery cell 20, while also alleviating the polarization phenomenon of the battery cell 20.
  • the particle diameter of the second reaction layer 251 close to the first active material layer 24 among the plurality of second reaction layers 251 is smaller than the particle diameters of other second reaction layers 251 .
  • the particle diameter of the second reaction layer 251 close to the first active material layer 24 among the multiple second reaction layers 251 is smaller than the particle diameters of other second reaction layers 251, that is, the second reaction layer 251 closest to the first active material layer 24 among the multiple second reaction layers 251 has the smallest particle size.
  • the dynamics of the second reaction layer 251 close to the first active material layer 24 is made better, so that the metal ions can diffuse into other second reaction layers 251, which is beneficial to reduce the internal resistance and improve the performance of the battery cell 20, and at the same time alleviate the polarization phenomenon of the battery cell 20.
  • the number of the second reaction layers 251 of the second active material layer 25 is N 2 , satisfying 2 ⁇ N 2 ⁇ 3.
  • the number of the second reaction layers 251 of the second active material layer 25 may be 2 or 3.
  • the second active material layer 25 includes two second reaction layers 251 stacked along the radial direction Y of the conductive column.
  • the phenomenon of poor electrolyte infiltration caused by too small a number of second reaction layers 251 can be alleviated to ensure the performance of the battery cell 20; on the other hand, the manufacturing difficulty of the second active material layer 25 caused by too many second reaction layers 251 and the risk of falling off can be reduced.
  • FIG. 10 is a structural explosion diagram of a battery cell 20 provided in some other embodiments of the present application
  • FIG. 11 is a cross-sectional view of a first active material layer 24 of a battery cell 20 provided in some other embodiments of the present application.
  • a first notch groove 243 is provided on the surface of the first active material layer 24 facing the second active material layer 25, and the first notch groove 243 is used to accommodate an electrolyte.
  • a second notch groove 252 is provided on the surface of the second active material layer 25 facing the first active material layer 24, and the second notch groove 252 is used to accommodate an electrolyte.
  • a first notch groove 243 is provided on the surface of the first active material layer 24 facing the second active material layer 25, that is, the first active material layer 24 is provided with a groove for accommodating the electrolyte on the surface facing the second active material layer 25; similarly, a second notch groove 252 is provided on the surface of the second active material layer 25 facing the first active material layer 24, that is, the second active material layer 25 is provided with a groove for accommodating the electrolyte on the surface facing the first active material layer 24.
  • first notch groove 243 and the second notch groove 252 may have various structures.
  • first notch groove 243 and the second notch groove 252 may be an annular structure extending along the circumference of the conductive pillar 22 , or may be a strip structure extending along the first direction X.
  • the first notch groove 243 is disposed on the surface of the first reaction layer 242 closest to the second active material layer 25 in the radial direction Y of the conductive pillar among the plurality of first reaction layers 242, facing the second active material layer 25.
  • the second notch groove 252 is disposed on the surface of the second reaction layer 251 closest to the first active material layer 24 in the radial direction Y of the conductive pillar among the plurality of second reaction layers 251, facing the first active material layer 24.
  • a first notch groove 243 is provided on the first active material layer 24 of the battery cell 20, and a second notch groove 252 is provided on the second active material layer 25 of the battery cell 20.
  • the structure of the battery cell 20 is not limited to this. In other embodiments, the battery cell 20 may also only have the first notch groove 243 provided on the surface of the first active material layer 24 facing the second active material layer 25, or may only have the second notch groove 252 provided on the surface of the second active material layer 25 facing the first active material layer 24.
  • the battery cell 20 of this structure can effectively improve the first active material layer 24's ability to retain the electrolyte, and can improve the electrolyte's infiltration effect on the first active material layer 24, thereby facilitating the improvement of the performance of the battery cell 20.
  • the battery cell 20 of this structure can effectively improve the second active material layer 25's ability to retain the electrolyte, and can improve the electrolyte's infiltration effect on the second active material layer 25, thereby facilitating the improvement of the performance of the battery cell 20.
  • the first active material layer 24 is an annular structure extending along the circumference of the conductive pillar 22 , and the first notch groove 243 extends along the circumference of the conductive pillar 22 .
  • the first notched groove 243 extends along the circumference of the conductive pillar 22, that is, the first notched groove 243 is an annular structure extending along the circumference of the conductive pillar 22, that is, the first notched groove 243 is arranged around the entire circumference of the surface of the first active material layer 24 facing the second active material layer 25.
  • the first notched groove 243 may also be a structure extending along the first direction X.
  • first notch groove 243 As an annular structure extending along the circumference of the conductive column 22, it is helpful to increase the capacity of the first notch groove 243 for the electrolyte, thereby effectively improving the liquid retention capacity of the first active material layer 24 to ensure the electrolyte infiltration effect of the first active material layer 24.
  • first notch grooves 243 there are a plurality of first notch grooves 243 , and the plurality of first notch grooves 243 are arranged along the first direction X at intervals.
  • the plurality of first notch grooves 243 are arranged at intervals along the first direction X, that is, the plurality of first notch grooves 243 are arranged along the first direction X.
  • first notch grooves 243 are structures extending along the first direction X, a plurality of first notch grooves 243 may be arranged at intervals along the circumferential direction of the conductive pillar 22 .
  • the liquid retention capacity of the first active material layer 24 and the electrolyte infiltration effect are further improved, thereby improving the performance of the battery cell 20 .
  • the second active material layer 25 is an annular structure extending along the circumference of the conductive pillar 22 , and the second notch groove 252 extends along the circumference of the conductive pillar 22 .
  • the second notched groove 252 extends along the circumference of the conductive pillar 22, that is, the second notched groove 252 is an annular structure extending along the circumference of the conductive pillar 22, that is, the second notched groove 252 is arranged around the entire circumference of the surface of the second active material layer 25 facing the first active material layer 24.
  • the second notched groove 252 may also be a structure extending along the first direction X.
  • the second notch groove 252 As an annular structure extending along the circumference of the conductive column 22, that is, the second notch groove 252 is set around the entire circumference of the second active material layer 25, it is beneficial to increase the capacity of the second notch groove 252 for the electrolyte, and thus can effectively improve the liquid retention capacity of the first active material layer 24, so as to ensure the wetting effect of the electrolyte of the first active material layer 24.
  • the plurality of second notched grooves 252 are arranged along the first direction X at intervals.
  • the plurality of second notch grooves 252 are arranged at intervals along the first direction X, that is, the plurality of second notch grooves 252 are arranged along the first direction X.
  • second notch grooves 252 are structures extending along the first direction X, a plurality of second notch grooves 252 may be arranged at intervals along the circumferential direction of the conductive pillar 22 .
  • the liquid retention capacity of the second active material layer 25 and the electrolyte infiltration effect are further improved, thereby improving the performance of the battery cell 20 .
  • the end cover 23 includes a cover body 231 and a pole 232.
  • the cover body 231 covers the opening 212.
  • the pole 232 is insulated and installed on the cover body 231.
  • the conductive pole 22 is connected to the pole 232.
  • the cover body 231 of the end cover 23 is provided with a pole 232 , which is insulated and mounted on the cover body 231 .
  • the pole 232 is connected to the conductive column 22 so as to serve as an output pole of the battery cell 20 through the pole 232 .
  • the pole 232 is insulated and installed on the cover body 231 , that is, there is no electrical connection between the pole 232 and the cover body 231 , that is, an insulating member is provided between the pole 232 and the cover body 231 , so that there is no electrical connection between the pole 232 and the cover body 231 .
  • the conductive column 22 and the pole 232 may be an integrated structure or a split structure. If the conductive column 22 and the pole 232 are an integrated structure, the conductive column 22 and the pole 232 may be formed by a process such as casting or turning; if the conductive column 22 and the pole 232 are a split structure, the conductive column 22 and the pole 232 may be assembled and connected by a process such as welding, clamping or bolting.
  • the input or output of electrical energy of the battery cell 20 can be realized through the pole 232, thereby alleviating the short circuit phenomenon between the conductive column 22 and the shell 21 through the cover body 231, which is beneficial to reduce the safety hazard of the battery cell 20 during use.
  • the conductive column 22 and the electrode column 232 are integrally formed.
  • the conductive column 22 and the pole 232 are an integrally formed structure, that is, the conductive column 22 and the pole 232 are an integrated structure.
  • the pole 232 and the conductive column 22 may also be a split structure, and the conductive column 22 is connected to the pole 232.
  • the pole 232 and the conductive column 22 may be connected in a variety of ways, and the conductive column 22 may be directly connected to the pole 232, such as welding or abutting.
  • the conductive column 22 may also be indirectly connected to the pole 232, such as the conductive column 22 is first welded or abutted with other components, and then welded or abutted with the pole 232.
  • the battery cell 20 adopting such a structure is beneficial to improving the connection stability and reliability between the conductive column 22 and the pole 232 to ensure the flow conduction area, and is also convenient for assembling the conductive column 22 and the end cover 23 as a whole with the shell 21, which is beneficial to reducing the difficulty of assembling the battery cell 20 and improving the assembly efficiency of the battery cell 20.
  • the first active material layer 24 is a negative electrode active material layer
  • the second active material layer 25 is a positive electrode active material layer.
  • the first active material layer 24 may also be a positive electrode active material layer, and correspondingly, the second active material layer 25 is a negative electrode active material layer.
  • the first active material layer 24 arranged on the side of the shell 21 facing the accommodating cavity 211 is a negative electrode active material layer, and correspondingly, the second active material layer 25 arranged on the outer peripheral surface of the conductive column 22 is a positive electrode active material layer, so that the negative electrode active material layer can be coated on the outside of the positive electrode active material layer.
  • the battery cell 20 adopting this structure can effectively reduce the risk of lithium plating to improve the safety of the battery cell 20.
  • the battery cell 20 further includes a separator 26 .
  • the separator 26 is disposed between the first active material layer 24 and the second active material layer 25 to separate the first active material layer 24 and the second active material layer 25 .
  • the isolation membrane 26 is an annular structure extending along the circumference of the conductive column 22, that is, the isolation membrane 26 is coated on the outer peripheral side of the second active material layer 25, so that the isolation membrane 26 can effectively separate the first active material layer 24 and the second active material layer 25.
  • the material of the isolation film 26 may be polypropylene (PP) or polyethylene (PE).
  • the shape of the isolation membrane 26 matches the outer peripheral surface of the second active material layer 25, that is, the shape of the isolation membrane 26 is the same as the shape of the outer peripheral surface of the second active material layer 25.
  • the isolation membrane 26 is a cylindrical hollow structure; as shown in FIG7, if the cross-section of the outer peripheral surface of the second active material layer 25 perpendicular to the first direction X is hexagonal, the isolation membrane 26 is a hexagonal hollow structure.
  • the battery cell 20 is also provided with an isolation membrane 26 located between the first active material layer 24 and the second active material layer 25, so as to effectively realize the insulation isolation between the first active material layer 24 and the second active material layer 25, so as to reduce the short circuit phenomenon between the first active material layer 24 and the second active material layer 25, thereby helping to reduce the safety hazards of the electrode assembly during use.
  • a battery 100 is further provided, and the battery 100 includes a battery cell 20 of any of the above schemes.
  • the embodiments of the present application also provide an electrical device, which includes a battery cell 20 of any of the above schemes, and the battery cell 20 is used to provide electrical energy to the electrical device; or, the electrical device includes a battery 100 of any of the above schemes, and the battery 100 is used to provide electrical energy to the electrical device.
  • the electrical device may be any of the aforementioned devices or systems using the battery cell 20 or the battery 100 .
  • the present application provides a battery cell 20 , which includes a housing 21 , a conductive column 22 , an end cover 23 , and an isolation membrane 26 .
  • the housing 21 has a receiving cavity 211 formed inside. An opening 212 communicating with the receiving cavity 211 is provided at one end of the housing 21 along the first direction X.
  • a first active material layer 24 is provided on the surface of the housing 21 facing the receiving cavity 211.
  • the first active material layer 24 is a negative electrode active material layer.
  • the housing 21 is a columnar structure. The central axis of the housing 21 extends along the first direction X. The length of the housing 21 along the first direction X is L. The maximum dimension of the cross section of the housing 21 perpendicular to the first direction X in the direction perpendicular to the first direction X is D 1 , satisfying L ⁇ D 1 .
  • the conductive column 22 extends along the first direction X and is inserted into the receiving cavity 211.
  • a second active material layer 25 is provided on the outer peripheral surface of the conductive column 22.
  • the second active material layer 25 faces the first active material layer 24.
  • the second active material layer 25 is a positive electrode active material layer.
  • the end cover 23 includes a cover body 231 and a pole 232.
  • the cover body 231 covers the opening 212.
  • the pole 232 is insulated and installed on the cover body 231.
  • the conductive column 22 and the pole 232 are an integrally formed structure.
  • the isolation membrane 26 is arranged between the first active material layer 24 and the second active material layer 25 to separate the first active material layer 24 and the second active material layer 25.
  • the first active material layer 24 and the second active material layer 25 are both annular structures extending along the circumference of the conductive column 22.
  • the first active material layer 24 is surrounded along the circumference of the conductive column 22 to form an installation channel 241 for inserting the conductive column 22.
  • the cross section of the installation channel 241 perpendicular to the first direction X is circular, and the inner surface of the installation channel 241 fits with the outer peripheral surface of the second active material layer 25.
  • the first active material layer 24 includes two first reaction layers 242, which are stacked along the radial direction Y of the conductive column.
  • the second active material layer 25 includes two second reaction layers 251, which are stacked along the radial direction Y of the conductive column.
  • the density of the second reaction layer 251 close to the first active material layer 24 of the two second reaction layers 251 is less than the density of the other second reaction layer 251, and the particle diameter of the second reaction layer 251 close to the first active material layer 24 of the two second reaction layers 251 is smaller than the particle diameter of the other second reaction layer 251.
  • a plurality of first notched grooves 243 are provided on the surface of the first active material layer 24 facing the second active material layer 25.
  • the first notched grooves 243 are used to contain electrolyte.
  • the first active material layer 24 is an annular structure extending along the circumference of the conductive pillar 22, and the plurality of first notched grooves 243 are arranged at intervals along the first direction X.
  • a plurality of second notched grooves 252 are provided on the surface of the second active material layer 25 facing the first active material layer 24.
  • the second notched grooves 252 are used to contain electrolyte.
  • the second active material layer 25 is an annular structure extending along the circumference of the conductive pillar 22, and the plurality of second notched grooves 252 are arranged at intervals along the first direction X.
  • the present application also provides a method for manufacturing a battery cell 20.
  • FIG. 12 is a schematic flow chart of a method for manufacturing a battery cell 20 provided in some embodiments of the present application.
  • the manufacturing method includes:
  • S100 providing a housing 21, a conductive column 22 and an end cover 23, wherein a receiving cavity 211 is formed inside the housing 21, and an opening 212 communicating with the receiving cavity 211 is provided at one end of the housing 21 along a first direction X, and the conductive column 22 extends along the first direction X;
  • S200 Disposing a first active material layer 24 on a side of the housing 21 facing the receiving cavity 211;
  • S400 Disposing a second active material layer 25 on the outer peripheral surface of the conductive column 22, wherein the second active material layer 25 has a polarity opposite to that of the first active material layer 24;
  • the first active material layer 24 is directly coated on the surface of the housing 21 facing the accommodating cavity 211, that is, the first active material layer 24 is coated on the cavity wall of the accommodating cavity 211.
  • the first active material layer 24 may be first coated on a current collector made of metal foil, and then the current collector coated with the first active material layer 24 is arranged in the accommodating cavity 211 of the housing 21, and the current collector is connected to the surface of the housing 21 facing the accommodating cavity 211.
  • step S500 the conductive column 22 is inserted into the accommodating cavity 211 of the shell 21 along the first direction X, that is, the conductive column 22 provided with the second active material layer 25 is inserted into the accommodating cavity 211 of the shell 21 along the first direction X, so that the first active material layer 24 and the second active material layer 25 are arranged facing each other in the radial direction Y of the conductive column.
  • the first active material layer 24 is coated on the surface of the housing 21 facing the receiving cavity 211 by a dry coating process.
  • the second active material layer 25 is coated on the outer peripheral surface of the conductive column 22 by a dry coating process.
  • a first active material layer 24 is firstly arranged on a side of the shell 21 facing the accommodating cavity 211, and the second active material layer 25 is arranged on the outer peripheral surface of the conductive column 22 after the conductive column 22 is connected to the end cover 23. Then, the conductive column 22 provided with the second active material layer 25 is inserted into the accommodating cavity 211 of the shell 21 along the first direction X, so that the first active material layer 24 and the second active material layer 25 are arranged facing each other, and at the same time, the end cover 23 and the opening 212 are covered with each other, thereby completing the assembly and manufacturing of the battery cell 20.
  • the battery cell 20 manufactured by this manufacturing method does not need to wind the pole piece, and saves the process of assembling and connecting the current collecting component and the pole ear, thereby greatly optimizing the production process and production rhythm of the battery cell 20, which is conducive to improving the production efficiency of the battery cell 20.
  • FIG. 13 is a schematic flow chart of a method for manufacturing a battery cell 20 provided in some embodiments of the present application.
  • the method for manufacturing the battery cell 20 further includes:
  • the manufacturing method of the battery cell 20 further includes:
  • step S500 is performed after step S700, which means that the conductive column 22 provided with the second active material layer 25 and coated with the isolation film 26 is inserted into the accommodating cavity 211 of the shell 21 along the first direction X, so that the first active material layer 24 and the second active material layer 25 are arranged facing each other, and the isolation film 26 is located between the first active material layer 24 and the second active material layer 25.
  • step S600 is arranged after step S400 .
  • step S600 may be arranged before or after any step before step S700 .
  • the isolation membrane 26 is first coated on the outside of the second active material layer 25, so that when the conductive column 22 is inserted into the accommodating cavity 211 of the shell 21, the isolation membrane 26 can be assembled into the shell 21 at the same time, and the isolation membrane 26 can be arranged between the first active material layer 24 and the second active material layer 25.
  • This manufacturing method can improve the assembly efficiency of the isolation membrane 26 on the one hand, and reduce the difficulty of assembling the isolation membrane 26 on the other hand.

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Abstract

Provided are a battery cell (20) and a manufacturing method therefor, a battery (100), and an electrical device, relating to the technical field of batteries. The battery cell (20) comprises a housing (21), a conductive column (22), and an end cover (23). An accommodating cavity (211) is formed in the housing (21), and in a first direction (X), an opening (212) is provided at one end of the housing (21), and a first active material layer (24) is provided at the side of the housing (21) facing the accommodation cavity (212). The conductive column (22) is inserted in the accommodating cavity (212) in the first direction (X), a second active material layer (25) is provided on the outer peripheral surface of the conductive column (22), the second active material layer (25) is arranged to face the first active material layer (24), and the polarity of the second active material layer (25) and the polarity of the first active material layer (24) are opposite. The end cover (23) covers the opening (212) and is connected to the conductive column (22). Such a battery cell (20) does not require winding of electrode sheets, so that the process of assembling and connecting a current collecting component and a tab to each other is removed, the production efficiency of the battery cell (20) is improved; and there is no need to provide a number of electrolytes in the housing, and members such as a current collecting component are removed, so that the manufacturing costs are reduced, and the space utilization of the battery cell (20) is improved.

Description

电池单体及其制造方法、电池及用电装置Battery cell and manufacturing method thereof, battery and power-using device 技术领域Technical Field
本申请涉及电池技术领域,具体而言,涉及一种电池单体及其制造方法、电池及用电装置。The present application relates to the field of battery technology, and in particular to a battery cell and a manufacturing method thereof, a battery and an electrical device.
背景技术Background technique
近些年,新能源汽车有了飞跃式的发展,在电动汽车领域,动力电池作为电动汽车的动力源,起着不可替代的重要作用。随着新能源汽车的大力推广,对动力电池产品的需求也日益增长,电池作为新能源汽车核心零部件在生产效率和生产成本上也有着较高的要求。其中,电池通常有多个电池单体串联、并联或混联而成。In recent years, new energy vehicles have developed by leaps and bounds. In the field of electric vehicles, power batteries, as the power source of electric vehicles, play an irreplaceable and important role. With the vigorous promotion of new energy vehicles, the demand for power battery products is also growing. Batteries, as core components of new energy vehicles, also have high requirements in production efficiency and production costs. Among them, batteries are usually composed of multiple battery cells connected in series, parallel or mixed.
对应一些相关技术中提及的电池单体,研究人员发现,现有的电池单体通常是由正极极片、负极极片和隔膜通过卷绕或者叠片等方式组装成电极组件(裸电芯),之后装入壳体,再盖上端盖,最后注入电解液后得到的,这种结构的电池单体的制造工艺较为繁琐且难度较大,从而造成电池单体的生产效率较低,生产成本较高。因此,亟需明确电池单体的制造工艺繁琐和难度较大的原因并制定改进方案,以解决电池单体的生产效率较低且制造成本较高的问题。Corresponding to the battery cells mentioned in some related technologies, researchers found that existing battery cells are usually assembled into electrode assemblies (bare cells) by winding or laminating positive electrode sheets, negative electrode sheets and separators, which are then loaded into a shell, covered with end covers, and finally injected with electrolyte. The manufacturing process of battery cells with this structure is relatively cumbersome and difficult, resulting in low production efficiency and high production costs of battery cells. Therefore, it is urgent to clarify the reasons why the manufacturing process of battery cells is cumbersome and difficult and to formulate improvement plans to solve the problems of low production efficiency and high manufacturing costs of battery cells.
发明内容Summary of the invention
本申请实施例提供一种电池单体及其制造方法、电池及用电装置,能够有效提升电池单体的生产效率并降低电池单体的制造成本。The embodiments of the present application provide a battery cell and a manufacturing method thereof, a battery, and an electrical device, which can effectively improve the production efficiency of the battery cell and reduce the manufacturing cost of the battery cell.
第一方面,本申请实施例提供一种电池单体,包括壳体、导电柱和端盖;所述壳体的内部形成有容纳腔,沿第一方向,所述壳体的一端设置有与所述容纳腔连通的开口,所述壳体面向所述容纳腔的一侧设置有第一活性物质层;所述导电柱沿所述第一方向延伸并插设于所述容纳腔内,所述导电柱的外周面上设置有第二活性物质层,所述第二活性物质层与所述第一活性物质层面向设置,且所述第二活性物质层与所述第一活性物质层的极性相反;所述端盖盖合于所述开口,并与所述导电柱相连。In a first aspect, an embodiment of the present application provides a battery cell, comprising a shell, a conductive column and an end cover; a accommodating cavity is formed inside the shell, and along a first direction, one end of the shell is provided with an opening connected to the accommodating cavity, and a first active material layer is provided on the side of the shell facing the accommodating cavity; the conductive column extends along the first direction and is inserted into the accommodating cavity, and a second active material layer is provided on the outer peripheral surface of the conductive column, the second active material layer is arranged facing the first active material layer, and the second active material layer has an opposite polarity to the first active material layer; the end cover covers the opening and is connected to the conductive column.
在上述技术方案中,通过在壳体面向容纳腔的一侧和导电柱的外周面上分别设置有极性相反的第一活性物质层和第二活性物质层,并将导电柱沿第一方向插设于壳体的容纳腔内,使得第一活性物质层与第二活性物质层面向设置,从而能够通过壳体和导电柱分别作为电池单体的正负输出极实现电池单体的电能的输入或输出,采用这种结构的电池单体一方面无需对极片进行卷绕,且节省了集流构件与极耳相互装配连接的工艺,进而有利于提升电池单体的生产效率,另一方面无需在壳体内设置大量的电解质,且取消了集流构件等部件,进而有利于降低电池单体的制造成本,且有利于提高电池单体的内部空间利用率,以提升电池单体的能量密度。此外,电池单体的中心位置设置有导电柱,从而缓解了电池单体的中心孔在后期使用过程中存在塌陷的风险,进而有利于提升电池单体的使用稳定性,以提升电池单体的使用安全性。In the above technical solution, a first active material layer and a second active material layer with opposite polarities are respectively arranged on the side of the shell facing the accommodating cavity and on the outer peripheral surface of the conductive column, and the conductive column is inserted into the accommodating cavity of the shell along the first direction, so that the first active material layer and the second active material layer are arranged facing each other, so that the shell and the conductive column can be used as the positive and negative output poles of the battery cell respectively to realize the input or output of the electric energy of the battery cell. On the one hand, the battery cell adopting this structure does not need to wind the pole piece, and saves the process of assembling and connecting the current collecting component and the pole ear, which is conducive to improving the production efficiency of the battery cell. On the other hand, it is not necessary to set a large amount of electrolyte in the shell, and the current collecting component and other components are eliminated, which is conducive to reducing the manufacturing cost of the battery cell, and is conducive to improving the internal space utilization of the battery cell, so as to improve the energy density of the battery cell. In addition, a conductive column is arranged at the center of the battery cell, so as to alleviate the risk of collapse of the center hole of the battery cell during the later use, which is conducive to improving the stability of the battery cell and improving the safety of the battery cell.
在一些实施例中,所述第一活性物质层涂覆于所述壳体面向所述容纳腔的表面上。In some embodiments, the first active material layer is coated on a surface of the shell facing the accommodating cavity.
在上述技术方案中,通过将第一活性物质层涂覆于壳体面向容纳腔的表面上,即第一活性物质层设置于容纳腔的腔壁面上,从而使得壳体能够直接作为电池单体的输出极,采用这种结构无需先将第一活性物质层设置于集流体上后再将集流体与壳体相连,从而有利于优化电池单体的生产工艺,节省电池单体的制造成本,且能够提升第一活性物质层设置于壳体上的连接稳定性和可靠性。In the above technical solution, by coating the first active material layer on the surface of the shell facing the accommodating cavity, that is, the first active material layer is arranged on the cavity wall of the accommodating cavity, the shell can be directly used as the output electrode of the battery cell. This structure does not require the first active material layer to be arranged on the current collector and then the current collector is connected to the shell, which is beneficial to optimize the production process of the battery cell, save the manufacturing cost of the battery cell, and can improve the connection stability and reliability of the first active material layer arranged on the shell.
在一些实施例中,所述壳体为柱状结构,所述壳体的中心轴线沿所述第一方向延伸。In some embodiments, the shell is a columnar structure, and a central axis of the shell extends along the first direction.
在上述技术方案中,通过将壳体设置为沿第一方向延伸的柱状结构,也就是说,电池单体为沿第一方向延伸的柱状结构,采用这种结构的电池单体的结构较为简单,便于装配,从而有利于降低电池单体的装配难度,以提升电池单体的生产效率。In the above technical solution, by setting the shell as a columnar structure extending along the first direction, that is, the battery cell is a columnar structure extending along the first direction, the battery cell adopting this structure is relatively simple and easy to assemble, which is beneficial to reduce the difficulty of assembling the battery cell and improve the production efficiency of the battery cell.
在一些实施例中,沿所述第一方向,所述壳体的长度为L,所述壳体垂直于所述第一方向的横截面在垂直于所述第一方向上的最大尺寸为D 1,满足,L≥D 1In some embodiments, along the first direction, the length of the shell is L, and the maximum dimension of a cross section of the shell perpendicular to the first direction is D 1 , satisfying L ≥ D 1 .
在上述技术方案中,通过将壳体在第一方向上的长度设置为大于或等于壳体的横截面在垂直于第一方向上的最大尺寸,也就是说,壳体为沿第一方向延伸的长条状结构,采用这种结构的电池单体有利于提升第一活性物质层和第二活性物质层的容纳量,且能够有效增加第一活性物质层与第二活性物质层相互面向设置的区域的面积,从而有利于提升电池单体的能量密度和使用性能。In the above technical solution, by setting the length of the shell in the first direction to be greater than or equal to the maximum dimension of the cross section of the shell in the direction perpendicular to the first direction, that is, the shell is a long strip structure extending along the first direction. The battery cell adopting this structure is beneficial to improving the capacity of the first active material layer and the second active material layer, and can effectively increase the area of the region where the first active material layer and the second active material layer are facing each other, which is beneficial to improving the energy density and performance of the battery cell.
在一些实施例中,1.5≤L/D 1;和/或,L/D 1≤25。 In some embodiments, 1.5≤L/D 1 ; and/or, L/D 1 ≤25.
在上述技术方案中,通过将壳体在第一方向上的长度与壳体的横截面在垂直于第一方向上的最大尺寸的比值设置为大于或等于1.5,从而在电池单体的体积相同的情况下能够有效增加导电柱的外周面与壳体的内表面相互面向设置的面积,以增加第一活性物质层与第二活性物质层的涂覆量,以及第一活性物质层与第二活性物质层相互面向设置的区域的面积,进而能够缓解因比值过小而造成第一活性物质层和第二活性物质层的容纳量不足,且第一活性物质层与第二活性物质层相互面向设置的区域的面积过小的现象。此外,通过将壳体在第一方向上的长度与壳体的横截面在垂直于第一方向上的最大尺寸的比值设置为小于或等于25,从而能够缓解因比值过大而造成电池单体为过于细长型的结构,以降低电池单体的制造难度过大。In the above technical solution, by setting the ratio of the length of the shell in the first direction to the maximum dimension of the cross section of the shell perpendicular to the first direction to be greater than or equal to 1.5, the area where the outer peripheral surface of the conductive column and the inner surface of the shell face each other can be effectively increased under the same volume of the battery cell, so as to increase the coating amount of the first active material layer and the second active material layer, and the area of the area where the first active material layer and the second active material layer face each other, thereby alleviating the phenomenon that the capacity of the first active material layer and the second active material layer is insufficient due to the ratio being too small, and the area of the area where the first active material layer and the second active material layer face each other is too small. In addition, by setting the ratio of the length of the shell in the first direction to the maximum dimension of the cross section of the shell perpendicular to the first direction to be less than or equal to 25, the structure of the battery cell that is too slender due to the ratio being too large can be alleviated, so as to reduce the difficulty of manufacturing the battery cell.
在一些实施例中,所述第一活性物质层和所述第二活性物质层均为沿所述导电柱的周向延伸的环形结构。In some embodiments, both the first active material layer and the second active material layer are annular structures extending along the circumference of the conductive column.
在上述技术方案中,通过将第一活性物质层和第二活性物质层设置为均沿导电柱的周向延伸的结构,即第一活性物质层和第二活性物质层均为环绕在导电柱的外侧的环形结构,采用这种结构的电池单体能够进一步增加 第一活性物质层和第二活性物质层的容纳量和第一活性物质层与第二活性物质层相互面向设置的区域的面积,从而能够有效提升电池单体的能量密度,以提升电池单体的使用性能。In the above technical solution, by arranging the first active material layer and the second active material layer to be a structure that both extend along the circumference of the conductive column, that is, the first active material layer and the second active material layer are both annular structures surrounding the outside of the conductive column, the battery cell adopting this structure can further increase the capacity of the first active material layer and the second active material layer and the area of the region where the first active material layer and the second active material layer are arranged facing each other, thereby effectively improving the energy density of the battery cell and improving the performance of the battery cell.
在一些实施例中,所述第一活性物质层沿所述导电柱的周向围合形成供所述导电柱插入的安装通道,所述安装通道的内表面与所述第二活性物质层的外周面相互契合。In some embodiments, the first active material layer surrounds the conductive column along its circumference to form a mounting channel for inserting the conductive column, and an inner surface of the mounting channel fits with an outer circumferential surface of the second active material layer.
在上述技术方案中,通过将第一活性物质层的内表面与第二活性物质层的外周面设置为相互契合的结构,即第二活性物质层插设于第一活性物质层形成的安装通道内,且第二活性物质层面向第一活性物质层的表面的形状与第一活性物质层面向第二活性物质层的表面的形状相同,从而便于将设置有第二活性物质层的导电柱装配至第一活性物质层围合形成的安装通道内,有利于降低电池单体的装配难度,且有利于减少第一活性物质层与第二活性物质层之间的空间浪费,以提升电池单体的能量密度。In the above technical scheme, by setting the inner surface of the first active material layer and the outer peripheral surface of the second active material layer to a mutually fitting structure, that is, the second active material layer is inserted into the installation channel formed by the first active material layer, and the shape of the surface of the second active material layer facing the first active material layer is the same as the shape of the surface of the first active material layer facing the second active material layer, it is convenient to assemble the conductive column provided with the second active material layer into the installation channel formed by the first active material layer, which is beneficial to reduce the difficulty of assembling the battery cell, and is beneficial to reduce the space waste between the first active material layer and the second active material layer, so as to improve the energy density of the battery cell.
在一些实施例中,所述安装通道垂直于所述第一方向的横截面为圆形。In some embodiments, a cross-section of the mounting channel perpendicular to the first direction is circular.
在上述技术方案中,通过将第一活性物质层围合形成的安装通道的横截面设置为圆形,即安装通道为圆形通道,采用这种结构能够在设置第二活性物质层装配至安装通道内时有效缓解第一活性物质层与第二活性物质层之间发生干涉或刮蹭的现象,一方面能够有利于提升电池单体的装配效率,另一方面能够有效提升电池单体的生产质量。In the above technical solution, the cross-section of the installation channel formed by the first active material layer is set to a circle, that is, the installation channel is a circular channel. This structure can effectively alleviate the interference or scratching between the first active material layer and the second active material layer when the second active material layer is assembled into the installation channel. On the one hand, it can be beneficial to improve the assembly efficiency of the battery cell, and on the other hand, it can effectively improve the production quality of the battery cell.
在一些实施例中,所述第一活性物质层包括多个第一反应层,多个所述第一反应层沿所述导电柱的径向层叠设置。In some embodiments, the first active material layer includes a plurality of first reaction layers, and the plurality of first reaction layers are stacked along a radial direction of the conductive pillar.
在上述技术方案中,第一活性物质层由沿导电柱的径向排布的多个第一反应层堆叠而成,采用这种结构的第一活性物质层一方面便于制造,有利于降低第一活性物质层设置在壳体的容纳腔的腔壁面上的制造难度,另一方面能够提升第一活性物质层的电解液的浸润效果,以保证金属离子的在第一活性物质层内的穿透性。In the above technical solution, the first active material layer is stacked by multiple first reaction layers arranged along the radial direction of the conductive column. The first active material layer with such a structure is easy to manufacture on the one hand, which is beneficial to reduce the manufacturing difficulty of setting the first active material layer on the wall surface of the cavity of the shell. On the other hand, it can enhance the wetting effect of the electrolyte of the first active material layer to ensure the penetration of metal ions in the first active material layer.
在一些实施例中,沿所述导电柱的径向,多个所述第一反应层中靠近所述第二活性物质层的所述第一反应层的密度小于其他所述第一反应层的密度。In some embodiments, along the radial direction of the conductive pillar, the density of the first reaction layer close to the second active material layer among the plurality of first reaction layers is smaller than the density of other first reaction layers.
在上述技术方案中,通过将靠近第二活性物质层的第一反应层的密度设置为比其他第一反应层的密度小,使得靠近第二活性物质层的第一反应层的动力学更好,以便于金属离子进行扩散至其他第一反应层内,从而有利于减少内阻,并能够提升电池单体的使用性能,同时还能够缓解电池单体出现极化的现象。In the above technical solution, by setting the density of the first reaction layer close to the second active material layer to be smaller than the density of other first reaction layers, the kinetics of the first reaction layer close to the second active material layer is made better, so that the metal ions can diffuse into other first reaction layers, which is beneficial to reduce the internal resistance and improve the performance of the battery cell, and at the same time can alleviate the polarization phenomenon of the battery cell.
在一些实施例中,沿所述导电柱的径向,多个所述第一反应层中靠近所述第二活性物质层的所述第一反应层的颗粒直径小于其他所述第一反应层的颗粒直径。In some embodiments, along the radial direction of the conductive pillar, a particle diameter of the first reaction layer close to the second active material layer among the plurality of first reaction layers is smaller than a particle diameter of other first reaction layers.
在上述技术方案中,通过将靠近第二活性物质层的第一反应层的颗粒直径设置为比其他第一反应层的颗粒直径小,使得靠近第二活性物质层的第一反应层的动力学更好,以便于金属离子进行扩散至其他第一反应层内,从而有利于减少内阻,并能够提升电池单体的使用性能,同时还能够缓解电池单体出现极化的现象。In the above technical solution, by setting the particle diameter of the first reaction layer close to the second active material layer to be smaller than the particle diameter of other first reaction layers, the kinetics of the first reaction layer close to the second active material layer is made better, so that the metal ions can diffuse into other first reaction layers, which is beneficial to reduce the internal resistance and improve the performance of the battery cell, and at the same time can alleviate the polarization phenomenon of the battery cell.
在一些实施例中,所述第一活性物质层的所述第一反应层的数量为N 1,满足,2≤N 1≤3。 In some embodiments, the number of the first reaction layers of the first active material layer is N 1 , satisfying 2≤N 1 ≤3.
在上述技术方案中,通过将第一活性物质层的第一反应层的数量设置在2个至3个,从而一方面能够缓解因第一反应层的数量过小而造成电解液的浸润效果不佳的现象,以保证电池单体的使用性能,另一方面能够降低因第一反应层的数量过多而导致第一活性物质层的制造难度过大且存在脱落的风险。In the above technical solution, by setting the number of the first reaction layers of the first active material layer to 2 to 3, on the one hand, the phenomenon of poor electrolyte infiltration caused by too small a number of first reaction layers can be alleviated to ensure the performance of the battery cell; on the other hand, the difficulty in manufacturing the first active material layer and the risk of falling off caused by too many first reaction layers can be reduced.
在一些实施例中,所述第二活性物质层包括多个第二反应层,多个所述第二反应层沿所述导电柱的径向层叠设置。In some embodiments, the second active material layer includes a plurality of second reaction layers, and the plurality of second reaction layers are stacked along a radial direction of the conductive pillar.
在上述技术方案中,第二活性物质层由沿导电柱的径向排布的多个第二反应层堆叠而成,采用这种结构的第二活性物质层一方面便于制造,有利于降低第二活性物质层设置在壳体的容纳腔的腔壁面上的制造难度,另一方面能够提升第二活性物质层的电解液的浸润效果,以保证金属离子的在第二活性物质层内的穿透性。In the above technical solution, the second active material layer is stacked by multiple second reaction layers arranged radially along the conductive column. The second active material layer with such a structure is easy to manufacture, which is beneficial to reduce the manufacturing difficulty of setting the second active material layer on the wall surface of the accommodating cavity of the shell. On the other hand, it can enhance the wetting effect of the electrolyte of the second active material layer to ensure the penetrability of metal ions in the second active material layer.
在一些实施例中,沿所述导电柱的径向,多个所述第二反应层中靠近所述第一活性物质层的所述第二反应层的密度小于其他所述第二反应层的密度。In some embodiments, along the radial direction of the conductive pillar, the density of the second reaction layer close to the first active material layer among the plurality of second reaction layers is smaller than the density of other second reaction layers.
在上述技术方案中,通过将靠近第一活性物质层的第二反应层的密度设置为比其他第二反应层的密度小,使得靠近第一活性物质层的第二反应层的动力学更好,以便于金属离子进行扩散至其他第二反应层内,从而有利于减少内阻,并能够提升电池单体的使用性能,同时还能够缓解电池单体出现极化的现象。In the above technical solution, by setting the density of the second reaction layer close to the first active material layer to be smaller than the density of other second reaction layers, the dynamics of the second reaction layer close to the first active material layer is made better, so that the metal ions can diffuse into other second reaction layers, which is beneficial to reduce the internal resistance and improve the performance of the battery cell, and at the same time can alleviate the polarization phenomenon of the battery cell.
在一些实施例中,沿所述导电柱的径向,多个所述第二反应层中靠近所述第一活性物质层的所述第二反应层的颗粒直径小于其他所述第二反应层的颗粒直径。In some embodiments, along the radial direction of the conductive pillar, a particle diameter of the second reaction layer close to the first active material layer among the plurality of second reaction layers is smaller than a particle diameter of other second reaction layers.
在上述技术方案中,通过将靠近第一活性物质层的第二反应层的颗粒直径设置为比其他第二反应层的颗粒直径小,使得靠近第一活性物质层的第二反应层的动力学更好,以便于金属离子进行扩散至其他第二反应层内,从而有利于减少内阻,并能够提升电池单体的使用性能,同时还能够缓解电池单体出现极化的现象。In the above technical solution, by setting the particle diameter of the second reaction layer close to the first active material layer to be smaller than the particle diameter of other second reaction layers, the kinetics of the second reaction layer close to the first active material layer is made better, so that the metal ions can diffuse into other second reaction layers, which is beneficial to reduce the internal resistance and improve the performance of the battery cell, and at the same time can alleviate the polarization phenomenon of the battery cell.
在一些实施例中,所述第二活性物质层的所述第二反应层的数量为N 2,满足,2≤N 2≤3。 In some embodiments, the number of the second reaction layers of the second active material layer is N 2 , satisfying 2≤N 2 ≤3.
在上述技术方案中,通过将第二活性物质层的第二反应层的数量设置在2个至3个,从而一方面能够缓解因第二反应层的数量过小而造成电解液的浸润效果不佳的现象,以保证电池单体的使用性能,另一方面能够降低因第二反应层的数量过多而导致第二活性物质层的制造难度过大且存在脱落的风险。In the above technical solution, by setting the number of the second reaction layers of the second active material layer to 2 to 3, on the one hand, the phenomenon of poor electrolyte infiltration caused by too small a number of second reaction layers can be alleviated to ensure the performance of the battery cell; on the other hand, the difficulty in manufacturing the second active material layer and the risk of falling off caused by too many second reaction layers can be reduced.
在一些实施例中,所述第一活性物质层面向所述第二活性物质层的表面设置有第一刻痕槽,所述第一刻痕槽用于容纳电解液;和/或,所述第二活性物质层面向所述第一活性物质层的表面设置有第二刻痕槽,所述第二刻痕槽用于容纳电解液。In some embodiments, a first notch groove is provided on the surface of the first active material layer facing the second active material layer, and the first notch groove is used to accommodate an electrolyte; and/or a second notch groove is provided on the surface of the second active material layer facing the first active material layer, and the second notch groove is used to accommodate an electrolyte.
在上述技术方案中,通过在第一活性物质层面向第二活性物质层的表面上设置用于容纳电解液的第一刻痕槽,使得这种结构的电池单体能够有效提升第一活性物质层对电解液的保液能力,且能够提升电解液对第一活性物质层的浸润效果,从而有利于提升电池单体的使用性能。同样的,通过在第二活性物质层面向第一活性物质层的表面上设置用于容纳电解液的第二刻痕槽,使得这种结构的电池单体能够有效提升第二活性物质层对电解液的保液 能力,且能够提升电解液对第二活性物质层的浸润效果,从而有利于提升电池单体的使用性能。In the above technical solution, by providing a first notch groove for accommodating the electrolyte on the surface of the first active material layer facing the second active material layer, the battery cell of this structure can effectively improve the first active material layer's ability to retain the electrolyte, and can improve the electrolyte's wetting effect on the first active material layer, thereby helping to improve the battery cell's performance. Similarly, by providing a second notch groove for accommodating the electrolyte on the surface of the second active material layer facing the first active material layer, the battery cell of this structure can effectively improve the second active material layer's ability to retain the electrolyte, and can improve the electrolyte's wetting effect on the second active material layer, thereby helping to improve the battery cell's performance.
在一些实施例中,所述第一活性物质层为沿所述导电柱的周向延伸的环形结构,所述第一刻痕槽沿所述导电柱的周向延伸。In some embodiments, the first active material layer is an annular structure extending along the circumference of the conductive column, and the first notch groove extends along the circumference of the conductive column.
在上述技术方案中,通过将第一刻痕槽设置为沿导电柱的周向延伸的环形结构,也就是说,第一刻痕槽环绕第一活性物质层整周设置,从而有利于提升第一刻痕槽对电解液的容纳量,进而能够有效提升第一活性物质层的保液能力,以保证第一活性物质层的电解液的浸润效果。In the above technical solution, the first notch groove is arranged as an annular structure extending along the circumference of the conductive column, that is, the first notch groove is arranged around the entire circumference of the first active material layer, which is beneficial to increase the capacity of the first notch groove for the electrolyte, and further can effectively improve the liquid retention capacity of the first active material layer to ensure the wetting effect of the electrolyte of the first active material layer.
在一些实施例中,所述第一刻痕槽为多个,多个所述第一刻痕槽沿所述第一方向间隔设置。In some embodiments, there are a plurality of first notch grooves, and the plurality of first notch grooves are spaced apart along the first direction.
在上述技术方案中,通过将设置在第一活性物质层的表面的第一刻痕槽设置为多个,且多个第一刻痕槽沿第一方向间隔设置,从而有利于进一步提升第一活性物质层的保液能力和电解液的浸润效果,以提升电池单体的使用性能。In the above technical solution, by providing a plurality of first notch grooves on the surface of the first active material layer, and the plurality of first notch grooves are spaced apart along the first direction, it is beneficial to further enhance the liquid retention capacity of the first active material layer and the wetting effect of the electrolyte, so as to enhance the performance of the battery cell.
在一些实施例中,所述第二活性物质层为沿所述导电柱的周向延伸的环形结构,所述第二刻痕槽沿所述导电柱的周向延伸。In some embodiments, the second active material layer is an annular structure extending along the circumference of the conductive column, and the second notch groove extends along the circumference of the conductive column.
在上述技术方案中,通过将第二刻痕槽设置为沿导电柱的周向延伸的环形结构,也就是说,第二刻痕槽环绕第二活性物质层整周设置,从而有利于提升第二刻痕槽对电解液的容纳量,进而能够有效提升第一活性物质层的保液能力,以保证第一活性物质层的电解液的浸润效果。In the above technical solution, the second notch groove is arranged as an annular structure extending along the circumference of the conductive column, that is, the second notch groove is arranged around the entire circumference of the second active material layer, which is beneficial to increase the capacity of the second notch groove for the electrolyte, and further can effectively improve the liquid retention capacity of the first active material layer to ensure the wetting effect of the electrolyte of the first active material layer.
在一些实施例中,所述第二刻痕槽为多个,多个所述第二刻痕槽沿所述第一方向间隔设置。In some embodiments, there are a plurality of second scoring grooves, and the plurality of second scoring grooves are spaced apart along the first direction.
在上述技术方案中,通过将设置在第二活性物质层的表面的第二刻痕槽设置为多个,且多个第二刻痕槽沿第一方向间隔设置,从而有利于进一步提升第二活性物质层的保液能力和电解液的浸润效果,以提升电池单体的使用性能。In the above technical solution, by providing a plurality of second notched grooves on the surface of the second active material layer, and the plurality of second notched grooves are spaced apart along the first direction, it is beneficial to further enhance the liquid retention capacity of the second active material layer and the wetting effect of the electrolyte, so as to enhance the performance of the battery cell.
在一些实施例中,所述端盖包括盖本体和极柱;所述盖本体盖合于所述开口;所述极柱绝缘安装于所述盖本体上;其中,所述导电柱连接于所述极柱。In some embodiments, the end cover includes a cover body and a pole; the cover body covers the opening; the pole is insulated and installed on the cover body; wherein the conductive pole is connected to the pole.
在上述技术方案中,通过将导电柱与绝缘安装于盖本体上的极柱相连,以通过极柱实现电池单体的电能的输入或输出,从而能够缓解导电柱通过盖本体与壳体出现短接的现象,进而有利于减少电池单体在使用过程中的安全隐患。In the above technical solution, by connecting the conductive column with the insulated pole installed on the cover body, the input or output of the electric energy of the battery cell can be realized through the pole, thereby alleviating the short circuit phenomenon between the conductive column and the shell through the cover body, which is beneficial to reduce the safety hazards of the battery cell during use.
在一些实施例中,所述导电柱与所述极柱为一体成型结构。In some embodiments, the conductive column and the polar column are an integrally formed structure.
在上述技术方案中,通过将导电柱与极柱设置为一体成型的结构,即导电柱与极柱为一体式结构,采用这种结构的电池单体一方面有利于提升导电柱与极柱之间的连接稳定性和可靠性,以保证导流面积,另一方面便于将导电柱和端盖整体与壳体进行装配,有利于降低电池单体的装配难度,以提升电池单体的装配效率。In the above technical solution, by setting the conductive column and the pole as an integrally formed structure, that is, the conductive column and the pole are an integrated structure, the battery cell adopting this structure is beneficial to improving the connection stability and reliability between the conductive column and the pole to ensure the conduction area on the one hand, and it is convenient to assemble the conductive column and the end cover as a whole with the shell on the other hand, which is beneficial to reduce the difficulty of assembling the battery cell and improve the assembly efficiency of the battery cell.
在一些实施例中,所述第一活性物质层为负极活性物质层,所述第二活性物质层为正极活性物质层。In some embodiments, the first active material layer is a negative electrode active material layer, and the second active material layer is a positive electrode active material layer.
在上述技术方案中,设置在壳体面向容纳腔的一侧上的第一活性物质层为负极活性物质层,对应的,设置在导电柱的外周面上的第二活性物质层为正极活性物质层,以使负极活性物质层能够包覆在正极活性物质层的外侧,采用这种结构的电池单体能够有效降低析锂的风险,以提升电池单体的使用安全性。In the above technical solution, the first active material layer arranged on the side of the shell facing the accommodating cavity is the negative electrode active material layer, and correspondingly, the second active material layer arranged on the outer peripheral surface of the conductive column is the positive electrode active material layer, so that the negative electrode active material layer can be coated on the outside of the positive electrode active material layer. The battery cell adopting this structure can effectively reduce the risk of lithium plating to improve the safety of the battery cell.
在一些实施例中,所述电池单体还包括隔离膜;所述隔离膜设置于所述第一活性物质层与所述第二活性物质层之间,以分隔所述第一活性物质层和所述第二活性物质层。In some embodiments, the battery cell further includes a separator; the separator is disposed between the first active material layer and the second active material layer to separate the first active material layer from the second active material layer.
在上述技术方案中,电池单体还设置有位于第一活性物质层和第二活性物质层之间的隔离膜,从而能够有效实现第一活性物质层和第二活性物质层之间的绝缘隔离,以降低第一活性物质层和第二活性物质层出现短接的现象,进而有利于降低电极组件在使用过程中的安全隐患。In the above technical solution, the battery cell is also provided with an isolation membrane located between the first active material layer and the second active material layer, so as to effectively realize the insulation isolation between the first active material layer and the second active material layer, so as to reduce the short circuit phenomenon between the first active material layer and the second active material layer, thereby helping to reduce the safety hazards of the electrode assembly during use.
第二方面,本申请实施例还提供一种电池,包括上述的电池单体。In a second aspect, an embodiment of the present application further provides a battery, comprising the above-mentioned battery cell.
第三方面,本申请实施例还提供一种用电装置,包括上述的电池单体,所述电池单体用于提供电能;或包括上述的电池,所述电池用于提供电能。In a third aspect, an embodiment of the present application further provides an electrical device, comprising the above-mentioned battery cell, wherein the battery cell is used to provide electrical energy; or comprising the above-mentioned battery, wherein the battery is used to provide electrical energy.
第四方面,本申请实施例还提供一种电池单体的制造方法,包括:提供壳体、导电柱和端盖,所述壳体的内部形成有容纳腔,沿第一方向,所述壳体的一端设置有与所述容纳腔连通的开口,所述导电柱沿所述第一方向延伸;在所述壳体面向所述容纳腔的一侧设置第一活性物质层;将所述导电柱与所述端盖相连;在所述导电柱的外周面上设置第二活性物质层,所述第二活性物质层与所述第一活性物质层的极性相反;将所述导电柱沿所述第一方向插设于所述壳体的所述容纳腔内,以使所述第一活性物质层与所述第二活性物质层面向设置,并使所述端盖盖合于所述开口。In a fourth aspect, an embodiment of the present application also provides a method for manufacturing a battery cell, comprising: providing a shell, a conductive column and an end cover, the shell having a accommodating cavity formed therein, one end of the shell having an opening connected to the accommodating cavity along a first direction, and the conductive column extending along the first direction; a first active material layer is provided on a side of the shell facing the accommodating cavity; the conductive column is connected to the end cover; a second active material layer is provided on an outer peripheral surface of the conductive column, the second active material layer having an opposite polarity to the first active material layer; the conductive column is inserted into the accommodating cavity of the shell along the first direction so that the first active material layer and the second active material layer are arranged facing each other, and the end cover is covered with the opening.
在上述技术方案中,通过先在壳体面向容纳腔的一侧上设置第一活性物质层,并将导电柱与端盖相连后在导电柱的外周面上设置第二活性物质层,之后再将设置有第二活性物质层的导电柱沿第一方向插设于壳体的容纳腔内,以实现第一活性物质层与第二活性物质层面向设置,并同时将端盖与开口相互盖合,从而完成电池单体的装配制造,采用这种制造方法制造的电池单体无需对极片进行卷绕,且节省了集流构件与极耳相互装配连接的工艺,进而极大地优化了电池单体的生产工艺和生产节拍,有利于提升电池单体的生产效率。In the above technical scheme, a first active material layer is first arranged on a side of the shell facing the accommodating cavity, and a second active material layer is arranged on the outer peripheral surface of the conductive column after the conductive column is connected to the end cover. Then, the conductive column provided with the second active material layer is inserted into the accommodating cavity of the shell along the first direction to realize the facing arrangement of the first active material layer and the second active material layer, and at the same time, the end cover and the opening are covered with each other, thereby completing the assembly and manufacturing of the battery cell. The battery cell manufactured by this manufacturing method does not need to wind the pole piece, and saves the process of assembling and connecting the current collecting component and the pole ear, thereby greatly optimizing the production process and production rhythm of the battery cell, which is beneficial to improving the production efficiency of the battery cell.
在一些实施例中,所述电池单体的制造方法还包括:提供隔离膜;在所述将所述导电柱沿所述第一方向插设于所述壳体的所述容纳腔内,以使所述第一活性物质层与所述第二活性物质层面向设置,并使所述端盖盖合于所述开口之前,所述电池单体的制造方法还包括:将所述隔离膜包覆于所述第二活性物质层的外侧。In some embodiments, the method for manufacturing the battery cell also includes: providing an isolation membrane; before inserting the conductive column into the accommodating cavity of the shell along the first direction so that the first active material layer and the second active material layer are arranged face to face, and the end cover is covered on the opening, the method for manufacturing the battery cell also includes: wrapping the isolation membrane on the outside of the second active material layer.
在上述技术方案中,在将设置有第二活性物质层的导电柱插设于壳体的容纳腔内之前先在第二活性物质层外侧包覆隔离膜,使得导电柱在插设于壳体的容纳腔内时能够同时将隔离膜装配至壳体内,并实现隔离膜设置于第一活性物质层和第二活性物质层之间,采用这种制造方法一方面能够提升隔离膜的装配效率,另一方面有利于降低隔离膜的装配难度。In the above technical solution, before the conductive column provided with the second active material layer is inserted into the accommodating cavity of the shell, the isolation membrane is first coated on the outside of the second active material layer, so that when the conductive column is inserted into the accommodating cavity of the shell, the isolation membrane can be assembled into the shell at the same time, and the isolation membrane is arranged between the first active material layer and the second active material layer. This manufacturing method can improve the assembly efficiency of the isolation membrane on the one hand, and reduce the difficulty of assembling the isolation membrane on the other hand.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
为了更清楚地说明本申请实施例的技术方案,下面将对实施例中所需要使用的附图作简单地介绍,应当理解,以下附图仅示出了本申请的某些实施例,因此不应被看作是对范围的限定,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他相关的附图。In order to more clearly illustrate the technical solutions of the embodiments of the present application, the drawings required for use in the embodiments will be briefly introduced below. It should be understood that the following drawings only show certain embodiments of the present application and therefore should not be regarded as limiting the scope. For ordinary technicians in this field, other related drawings can be obtained based on these drawings without paying creative work.
图1为本申请一些实施例提供的车辆的结构示意图;FIG1 is a schematic diagram of the structure of a vehicle provided in some embodiments of the present application;
图2为本申请一些实施例提供的电池的结构爆炸图;FIG2 is an exploded view of a battery structure provided by some embodiments of the present application;
图3为本申请一些实施例提供的电池单体的结构示意图;FIG3 is a schematic diagram of the structure of a battery cell provided in some embodiments of the present application;
图4为本申请一些实施例提供的电池单体的结构爆炸图;FIG4 is an exploded view of the structure of a battery cell provided in some embodiments of the present application;
图5为本申请一些实施例提供的电池单体的剖视图;FIG5 is a cross-sectional view of a battery cell provided in some embodiments of the present application;
图6为本申请又一些实施例提供的电池单体的结构爆炸图;FIG6 is an exploded view of the structure of a battery cell provided in some other embodiments of the present application;
图7为本申请再一些实施例提供的电池单体的结构爆炸图;FIG7 is an exploded view of the structure of a battery cell provided in some other embodiments of the present application;
图8为本申请另一些实施例提供的电池单体的剖视图;FIG8 is a cross-sectional view of a battery cell provided in some other embodiments of the present application;
图9为图8所示的电池单体的A处的局部放大图;FIG9 is a partial enlarged view of the battery cell A shown in FIG8;
图10为本申请再又一些实施例提供的电池单体的结构爆炸图;FIG10 is an exploded view of the structure of a battery cell provided in yet other embodiments of the present application;
图11为本申请再又一些实施例提供的电池单体的第一活性物质层的剖视图;FIG11 is a cross-sectional view of a first active material layer of a battery cell provided in yet other embodiments of the present application;
图12为本申请一些实施例提供的电池单体的制造方法的流程示意图;FIG12 is a schematic flow chart of a method for manufacturing a battery cell provided in some embodiments of the present application;
图13为本申请又一些实施例提供的电池单体的制造方法的流程示意图。FIG. 13 is a schematic flow chart of a method for manufacturing a battery cell provided in some other embodiments of the present application.
图标:1000-车辆;100-电池;10-箱体;11-第一箱本体;12-第二箱本体;20-电池单体;21-壳体;211-容纳腔;212-开口;22-导电柱;23-端盖;231-盖本体;232-极柱;24-第一活性物质层;241-安装通道;242-第一反应层;243-第一刻痕槽;25-第二活性物质层;251-第二反应层;252-第二刻痕槽;26-隔离膜;200-控制器;300-马达;X-第一方向;Y-导电柱的径向。Icon: 1000-vehicle; 100-battery; 10-box; 11-first box body; 12-second box body; 20-battery cell; 21-shell; 211-accommodating chamber; 212-opening; 22-conductive column; 23-end cover; 231-cover body; 232-pole; 24-first active material layer; 241-installation channel; 242-first reaction layer; 243-first notch groove; 25-second active material layer; 251-second reaction layer; 252-second notch groove; 26-isolation membrane; 200-controller; 300-motor; X-first direction; Y-radial direction of the conductive column.
具体实施方式Detailed ways
为使本申请实施例的目的、技术方案和优点更加清楚,下面将结合本申请实施例中的附图,对本申请实施例中的技术方案进行清楚地描述,显然,所描述的实施例是本申请一部分实施例,而不是全部的实施例。基于本申请中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本申请保护的范围。In order to make the purpose, technical solution and advantages of the embodiments of the present application clearer, the technical solution in the embodiments of the present application will be clearly described below in conjunction with the drawings in the embodiments of the present application. Obviously, the described embodiments are part of the embodiments of the present application, not all of the embodiments. Based on the embodiments in the present application, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of this application.
除非另有定义,本申请所使用的所有的技术和科学术语与属于本申请的技术领域的技术人员通常理解的含义相同;本申请中在申请的说明书中所使用的术语只是为了描述具体的实施例的目的,不是旨在于限制本申请;本申请的说明书和权利要求书及上述附图说明中的术语“包括”和“具有”以及它们的任何变形,意图在于覆盖不排他的包含。本申请的说明书和权利要求书或上述附图中的术语“第一”、“第二”等是用于区别不同对象,而不是用于描述特定顺序或主次关系。Unless otherwise defined, all technical and scientific terms used in this application have the same meaning as those commonly understood by technicians in the technical field of this application; the terms used in the specification of this application are only for the purpose of describing specific embodiments and are not intended to limit this application; the terms "including" and "having" in the specification and claims of this application and the above-mentioned drawings and any variations thereof are intended to cover non-exclusive inclusions. The terms "first", "second", etc. in the specification and claims of this application or the above-mentioned drawings are used to distinguish different objects, rather than to describe a specific order or a primary and secondary relationship.
在本申请中提及“实施例”意味着,结合实施例描述的特定特征、结构或特性可以包含在本申请的至少一个实施例中。在说明书中的各个位置出现该短语并不一定均是指相同的实施例,也不是与其它实施例互斥的独立的或备选的实施例。Reference to "embodiment" in this application means that a particular feature, structure or characteristic described in conjunction with the embodiment may be included in at least one embodiment of the present application. The appearance of the phrase in various places in the specification does not necessarily refer to the same embodiment, nor is it an independent or alternative embodiment that is mutually exclusive with other embodiments.
在本申请的描述中,需要说明的是,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”、“附接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本申请中的具体含义。In the description of this application, it should be noted that, unless otherwise clearly specified and limited, the terms "installed", "connected", "connected", and "attached" should be understood in a broad sense, for example, it can be a fixed connection, a detachable connection, or an integral connection; it can be a direct connection, or an indirect connection through an intermediate medium, or it can be the internal communication of two elements. For ordinary technicians in this field, the specific meanings of the above terms in this application can be understood according to specific circumstances.
本申请中术语“和/或”,仅仅是一种描述关联对象的关联关系,表示可以存在三种关系,例如,A和/或B,可以表示:单独存在A,同时存在A和B,单独存在B这三种情况。另外,本申请中字符“/”,一般表示前后关联对象是一种“或”的关系。The term "and/or" in this application is only a description of the association relationship of associated objects, indicating that there can be three relationships. For example, A and/or B can represent: A exists alone, A and B exist at the same time, and B exists alone. In addition, the character "/" in this application generally indicates that the associated objects before and after are in an "or" relationship.
在本申请的实施例中,相同的附图标记表示相同的部件,并且为了简洁,在不同实施例中,省略对相同部件的详细说明。应理解,附图示出的本申请实施例中的各种部件的厚度、长宽等尺寸,以及集成装置的整体厚度、长宽等尺寸仅为示例性说明,而不应对本申请构成任何限定。In the embodiments of the present application, the same reference numerals represent the same components, and for the sake of brevity, detailed descriptions of the same components are omitted in different embodiments. It should be understood that the thickness, length, width and other dimensions of various components in the embodiments of the present application shown in the drawings, as well as the overall thickness, length, width and other dimensions of the integrated device are only exemplary descriptions and should not constitute any limitation to the present application.
本申请中出现的“多个”指的是两个以上(包括两个)。The term "plurality" used in the present application refers to two or more (including two).
本申请中,电池单体可以包括锂离子二次电池、锂离子一次电池、锂硫电池、钠离子电池或镁离子电池等,本申请实施例对此并不限定。电池单体可呈圆柱体、扁平体、长方体或其它形状等,本申请实施例对此也不限定。电池单体一般按封装的方式分成三种:柱形电池单体、方形电池单体和软包电池单体,本申请实施例对此也不限定。In the present application, battery cells may include lithium-ion secondary batteries, lithium-ion primary batteries, lithium-sulfur batteries, sodium-ion batteries or magnesium-ion batteries, etc., and the embodiments of the present application do not limit this. Battery cells may be cylindrical, flat, rectangular or other shapes, etc., and the embodiments of the present application do not limit this. Battery cells are generally divided into three types according to the packaging method: cylindrical battery cells, square battery cells and soft-pack battery cells, and the embodiments of the present application do not limit this.
本申请的实施例所提到的电池是指包括一个或多个电池单体以提供更高的电压和容量的单一的物理模块。例如,本申请中所提到的电池可以包括电池模块或电池包等。电池一般包括用于封装一个或多个电池单体或多个电池模组的箱体。箱体可以避免液体或其他异物影响电池单体的充电或放电。The battery mentioned in the embodiments of the present application refers to a single physical module including one or more battery cells to provide higher voltage and capacity. For example, the battery mentioned in the present application may include a battery module or a battery pack. The battery generally includes a box for encapsulating one or more battery cells or multiple battery modules. The box can prevent liquid or other foreign matter from affecting the charging or discharging of the battery cells.
电池具有能量密度高、环境污染小、功率密度大、使用寿命长、适应范围广、自放电系数小等突出的优点,是现今新能源发展的重要组成部分。随着电池技术的不断发展,在电池的生产效率方面和制造成本方面也提出了更高的要求。其中,电池由多个电池单体组成,使得电池单体的生产效率和制造成本决定了电池的生产效率和制造成本。Batteries have outstanding advantages such as high energy density, low environmental pollution, high power density, long service life, wide adaptability, and low self-discharge coefficient. They are an important part of the development of new energy today. With the continuous development of battery technology, higher requirements have been put forward in terms of battery production efficiency and manufacturing cost. Among them, the battery is composed of multiple battery cells, so the production efficiency and manufacturing cost of the battery cells determine the production efficiency and manufacturing cost of the battery.
发明人发现,对于一般的电池单体而言,电池单体通常是由正极极片、负极极片和隔膜通过卷绕或者叠片等方式组装成电极组件(裸电芯),之后装入壳体,再盖上端盖,最后注入电解液后得到的。这种结构的电池单 体在生产制造的过程中,需要先对极片进行卷绕或叠片处理,之后还需要将电极组件的极耳与集流构件进行焊接装配,最后再将集流构件与端盖或壳体进行焊接装配,从而导致电池单体的制造工艺较为繁琐且难度较大,且所需的装配部件和电解质等较多,进而导致电池单体的生产效率较低,且制造成本较高。The inventors found that for general battery cells, the battery cells are usually assembled into electrode assemblies (bare cells) by winding or laminating positive electrode sheets, negative electrode sheets and separators, which are then loaded into a housing, covered with end caps, and finally injected with electrolyte. In the manufacturing process of battery cells with this structure, the electrode sheets need to be wound or laminated first, and then the pole ears of the electrode assembly need to be welded and assembled with the current collecting components, and finally the current collecting components need to be welded and assembled with the end caps or housings, which results in a more complicated and difficult manufacturing process for the battery cells, and more assembly parts and electrolytes are required, which leads to lower production efficiency and higher manufacturing costs for the battery cells.
基于上述考虑,为了解决电池单体的生产效率较低且制造成本较高的问题,发明人经过深入研究,设计了一种电池单体,电池单体包括壳体、导电柱和端盖。壳体的内部形成有容纳腔,沿第一方向,壳体的一端设置有与容纳腔连通的开口,壳体面向容纳腔的一侧设置有第一活性物质层。导电柱沿第一方向延伸并插设于容纳腔内,导电柱的外周面上设置有第二活性物质层,第二活性物质层与第一活性物质层面向设置,且第二活性物质层与第一活性物质层的极性相反。端盖盖合于开口,并与导电柱相连。Based on the above considerations, in order to solve the problem of low production efficiency and high manufacturing cost of battery cells, the inventors have designed a battery cell after in-depth research. The battery cell includes a shell, a conductive column and an end cover. A accommodating cavity is formed inside the shell. Along the first direction, one end of the shell is provided with an opening connected to the accommodating cavity, and a first active material layer is provided on the side of the shell facing the accommodating cavity. The conductive column extends along the first direction and is inserted into the accommodating cavity. A second active material layer is provided on the outer peripheral surface of the conductive column. The second active material layer is arranged facing the first active material layer, and the second active material layer has an opposite polarity to the first active material layer. The end cover covers the opening and is connected to the conductive column.
在这种结构的电池单体中,通过在壳体面向容纳腔的一侧和导电柱的外周面上分别设置有极性相反的第一活性物质层和第二活性物质层,并将导电柱沿第一方向插设于壳体的容纳腔内,使得第一活性物质层与第二活性物质层面向设置,从而能够通过壳体和导电柱分别作为电池单体的正负输出极实现电池单体的电能的输入或输出,采用这种结构的电池单体一方面无需对极片进行卷绕,且节省了集流构件与极耳相互装配连接的工艺,进而有利于提升电池单体的生产效率,另一方面无需在壳体内设置大量的电解质,且取消了集流构件等部件,进而有利于降低电池单体的制造成本,且有利于提高电池单体的内部空间利用率,以提升电池单体的能量密度。此外,电池单体的中心位置设置有导电柱,从而缓解了电池单体的中心孔在后期使用过程中存在塌陷的风险,进而有利于提升电池单体的使用稳定性,以提升电池单体的使用安全性。In a battery cell of this structure, a first active material layer and a second active material layer with opposite polarities are respectively arranged on the side of the shell facing the accommodating cavity and on the outer peripheral surface of the conductive column, and the conductive column is inserted into the accommodating cavity of the shell along the first direction, so that the first active material layer and the second active material layer are arranged facing each other, so that the shell and the conductive column can be used as the positive and negative output poles of the battery cell respectively to realize the input or output of the electric energy of the battery cell. On the one hand, the battery cell adopting this structure does not need to wind the pole piece, and saves the process of assembling and connecting the current collecting component and the pole ear, which is conducive to improving the production efficiency of the battery cell. On the other hand, it is not necessary to set a large amount of electrolyte in the shell, and the current collecting component and other components are eliminated, which is conducive to reducing the manufacturing cost of the battery cell, and is conducive to improving the internal space utilization of the battery cell, so as to improve the energy density of the battery cell. In addition, a conductive column is arranged at the center of the battery cell, so as to alleviate the risk of collapse of the center hole of the battery cell during the later use, which is conducive to improving the stability of the battery cell and improving the safety of the battery cell.
本申请实施例公开的电池单体可以但不限用于车辆、船舶或飞行器等用电装置中。可以使用具备本申请公开的电池单体、电池等组成该用电装置的电源系统,这样,有利于优化电池单体的制造工序和电池单体所需的配件,以提升电池单体的生产效率和降低电池单体的制造成本。The battery cells disclosed in the embodiments of the present application can be used, but not limited to, in electrical devices such as vehicles, ships or aircraft. A power supply system comprising the battery cells and batteries disclosed in the present application can be used to form the electrical device, which is conducive to optimizing the manufacturing process of the battery cells and the accessories required for the battery cells, so as to improve the production efficiency of the battery cells and reduce the manufacturing cost of the battery cells.
本申请实施例提供一种使用电池作为电源的用电装置,用电装置可以为但不限于手机、平板、笔记本电脑、电动玩具、电动工具、电瓶车、电动汽车、轮船、航天器等等。其中,电动玩具可以包括固定式或移动式的电动玩具,例如,游戏机、电动汽车玩具、电动轮船玩具和电动飞机玩具等等,航天器可以包括飞机、火箭、航天飞机和宇宙飞船等等。The embodiment of the present application provides an electric device using a battery as a power source, and the electric device may be, but is not limited to, a mobile phone, a tablet, a laptop, an electric toy, an electric tool, a battery car, an electric car, a ship, a spacecraft, etc. Among them, the electric toy may include a fixed or mobile electric toy, for example, a game console, an electric car toy, an electric ship toy, an electric airplane toy, etc., and the spacecraft may include an airplane, a rocket, a space shuttle, a spacecraft, etc.
以下实施例为了方便说明,以本申请一实施例的一种用电装置为车辆1000为例进行说明。For the convenience of description, the following embodiments are described by taking a vehicle 1000 as an example of an electrical device according to an embodiment of the present application.
请参照图1,图1为本申请一些实施例提供的车辆1000的结构示意图。车辆1000可以为燃油汽车、燃气汽车或新能源汽车,新能源汽车可以是纯电动汽车、混合动力汽车或增程式汽车等。车辆1000的内部设置有电池100,电池100可以设置在车辆1000的底部或头部或尾部。电池100可以用于车辆1000的供电,例如,电池100可以作为车辆1000的操作电源。车辆1000还可以包括控制器200和马达300,控制器200用来控制电池100为马达300供电,例如,用于车辆1000的启动、导航和行驶时的工作用电需求。Please refer to Figure 1, which is a schematic diagram of the structure of a vehicle 1000 provided in some embodiments of the present application. The vehicle 1000 may be a fuel vehicle, a gas vehicle or a new energy vehicle, and the new energy vehicle may be a pure electric vehicle, a hybrid vehicle or an extended-range vehicle, etc. A battery 100 is provided inside the vehicle 1000, and the battery 100 may be provided at the bottom, head or tail of the vehicle 1000. The battery 100 may be used to power the vehicle 1000, for example, the battery 100 may be used as an operating power source for the vehicle 1000. The vehicle 1000 may also include a controller 200 and a motor 300, and the controller 200 is used to control the battery 100 to power the motor 300, for example, for the starting, navigation and driving power requirements of the vehicle 1000.
在本申请一些实施例中,电池100不仅可以作为车辆1000的操作电源,还可以作为车辆1000的驱动电源,代替或部分地代替燃油或天然气为车辆1000提供驱动动力。In some embodiments of the present application, the battery 100 can not only serve as an operating power source for the vehicle 1000, but also serve as a driving power source for the vehicle 1000, replacing or partially replacing fuel or natural gas to provide driving power for the vehicle 1000.
请参照图2和图3,图2为本申请一些实施例提供的电池100的结构爆炸图,图3为本申请一些实施例提供的电池单体20的结构示意图。电池100包括箱体10和电池单体20,电池单体20用于容纳于箱体10内。其中,箱体10用于为电池单体20提供装配空间,箱体10可以采用多种结构。在一些实施例中,箱体10可以包括第一箱本体11和第二箱本体12,第一箱本体11与第二箱本体12相互盖合,第一箱本体11和第二箱本体12共同限定出用于容纳电池单体20的装配空间。第二箱本体12可以为一端开放的空心结构,第一箱本体11可以为板状结构,第一箱本体11盖合于第二箱本体12的开放侧,以使第一箱本体11与第二箱本体12共同限定出装配空间;第一箱本体11和第二箱本体12也可以是均为一侧开放的空心结构,第一箱本体11的开放侧盖合于第二箱本体12的开放侧。当然,第一箱本体11和第二箱本体12形成的箱体10可以是多种形状,比如,圆柱体、长方体等。Please refer to Figures 2 and 3. Figure 2 is an exploded view of the structure of the battery 100 provided in some embodiments of the present application, and Figure 3 is a schematic diagram of the structure of the battery cell 20 provided in some embodiments of the present application. The battery 100 includes a box body 10 and a battery cell 20, and the battery cell 20 is used to be accommodated in the box body 10. Among them, the box body 10 is used to provide an assembly space for the battery cell 20, and the box body 10 can adopt a variety of structures. In some embodiments, the box body 10 may include a first box body 11 and a second box body 12, and the first box body 11 and the second box body 12 cover each other, and the first box body 11 and the second box body 12 jointly define an assembly space for accommodating the battery cell 20. The second box body 12 can be a hollow structure with one end open, and the first box body 11 can be a plate-like structure. The first box body 11 covers the open side of the second box body 12, so that the first box body 11 and the second box body 12 jointly define an assembly space; the first box body 11 and the second box body 12 can also be hollow structures with one side open, and the open side of the first box body 11 covers the open side of the second box body 12. Of course, the box body 10 formed by the first box body 11 and the second box body 12 can be in various shapes, such as a cylinder, a cuboid, etc.
在电池100中,电池单体20可以是多个,多个电池单体20之间可串联或并联或混联,混联是指多个电池单体20中既有串联又有并联。多个电池单体20之间可直接串联或并联或混联在一起,再将多个电池单体20构成的整体容纳于箱体10内;当然,电池100也可以是多个电池单体20先串联或并联或混联组成电池模块形式,多个电池模块再串联或并联或混联形成一个整体,并容纳于箱体10内。电池100还可以包括其他结构,例如,该电池100还可以包括汇流部件,用于实现多个电池单体20之间的电连接。In the battery 100, there may be multiple battery cells 20, and the multiple battery cells 20 may be connected in series, in parallel, or in a mixed connection. A mixed connection means that the multiple battery cells 20 are both connected in series and in parallel. The multiple battery cells 20 may be directly connected in series, in parallel, or in a mixed connection, and then the whole formed by the multiple battery cells 20 is accommodated in the box 10; of course, the battery 100 may also be a battery module formed by connecting multiple battery cells 20 in series, in parallel, or in a mixed connection, and then the multiple battery modules are connected in series, in parallel, or in a mixed connection to form a whole, and accommodated in the box 10. The battery 100 may also include other structures, for example, the battery 100 may also include a busbar component for realizing electrical connection between the multiple battery cells 20.
其中,每个电池单体20可以为二次电池或一次电池;还可以是锂硫电池、钠离子电池或镁离子电池,但不局限于此。电池单体20可呈圆柱体、扁平体、长方体或其它形状等。示例性的,在图3中,电池单体20为圆柱体结构。Each battery cell 20 may be a secondary battery or a primary battery; it may also be a lithium-sulfur battery, a sodium-ion battery or a magnesium-ion battery, but is not limited thereto. The battery cell 20 may be cylindrical, flat, rectangular or in other shapes. For example, in FIG3 , the battery cell 20 is a cylindrical structure.
根据本申请的一些实施例,参照图3,并请进一步参照图4和图5,图4为本申请一些实施例提供的电池单体20的结构爆炸图,图5为本申请一些实施例提供的电池单体20的剖视图。本申请提供了一种电池单体20,电池单体20包括壳体21、导电柱22和端盖23。壳体21的内部形成有容纳腔211,沿第一方向X,壳体21的一端设置有与容纳腔211连通的开口212,壳体21面向容纳腔211的一侧设置有第一活性物质层24。导电柱22沿第一方向X延伸并插设于容纳腔211内,导电柱22的外周面上设置有第二活性物质层25,第二活性物质层25与第一活性物质层24面向设置,且第二活性物质层25与第一活性物质层24的极性相反。端盖23盖合于开口212,并与导电柱22相连。According to some embodiments of the present application, with reference to FIG. 3, and further with reference to FIG. 4 and FIG. 5, FIG. 4 is an exploded view of the structure of a battery cell 20 provided in some embodiments of the present application, and FIG. 5 is a cross-sectional view of a battery cell 20 provided in some embodiments of the present application. The present application provides a battery cell 20, and the battery cell 20 includes a shell 21, a conductive column 22, and an end cover 23. A receiving cavity 211 is formed inside the shell 21, and an opening 212 communicating with the receiving cavity 211 is provided at one end of the shell 21 along the first direction X, and a first active material layer 24 is provided on the side of the shell 21 facing the receiving cavity 211. The conductive column 22 extends along the first direction X and is inserted into the receiving cavity 211, and a second active material layer 25 is provided on the outer peripheral surface of the conductive column 22, and the second active material layer 25 is arranged facing the first active material layer 24, and the second active material layer 25 is opposite to the first active material layer 24. The end cover 23 covers the opening 212 and is connected to the conductive column 22.
其中,第一活性物质层24设置于壳体21面向容纳腔211的一侧,第二活性物质层25设置于导电柱22上,且导电柱22与端盖23相连,从而使得壳体21和端盖23分别作为电池单体20的输出极实现电能的输入或输出。Among them, the first active material layer 24 is arranged on the side of the shell 21 facing the accommodating cavity 211, and the second active material layer 25 is arranged on the conductive column 22, and the conductive column 22 is connected to the end cover 23, so that the shell 21 and the end cover 23 respectively serve as the output pole of the battery cell 20 to realize the input or output of electrical energy.
需要说明的是,第一活性物质层24设置于壳体21面向容纳腔211的一侧上的结构可以是多种,第一活性物质层24可以是直接涂覆于壳体21面向容纳腔211的表面上,即第一活性物质层24涂覆于容纳腔211的腔壁 面上,当然,第一活性物质层24也可以是间接设置于壳体21面向容纳腔211的表面上,比如,第一活性物质层24涂覆于金属箔制成的集流体上,再将集流体覆盖并连接于壳体21面向容纳腔211的表面上。It should be noted that the first active material layer 24 can be arranged on the side of the shell 21 facing the accommodating cavity 211 in various structures. The first active material layer 24 can be directly coated on the surface of the shell 21 facing the accommodating cavity 211, that is, the first active material layer 24 is coated on the cavity wall surface of the accommodating cavity 211. Of course, the first active material layer 24 can also be indirectly arranged on the surface of the shell 21 facing the accommodating cavity 211. For example, the first active material layer 24 is coated on a current collector made of metal foil, and then the current collector is covered and connected to the surface of the shell 21 facing the accommodating cavity 211.
在一些实施例中,第一活性物质层24还可以是不与壳体21电连接,即第一活性物质层24绝缘安装于壳体21面向容纳腔211的表面上,比如,第一活性物质层24涂覆于金属箔制成的集流体上,再将集流体覆盖于壳体21面向容纳腔211的表面上,并在集流体与壳体21之间设置绝缘层,也就是说,设置有第一活性物质层24的集流体通过绝缘层与壳体21面向容纳腔211的表面相连,以实现设置有第一活性物质层24的集流体与壳体21之间的绝缘隔离,在这种实施例中,设置有第一活性物质层24的集流体可以与端盖23相连,以使端盖23作为第一活性物质层24的输出极,也可以与绝缘安装于壳体21上的电极端子相连,以使绝缘安装于壳体21上的电极端子作为第一活性物质层24的输出极。In some embodiments, the first active material layer 24 may also be not electrically connected to the shell 21, that is, the first active material layer 24 is insulated and installed on the surface of the shell 21 facing the accommodating cavity 211. For example, the first active material layer 24 is coated on a current collector made of metal foil, and the current collector is then covered on the surface of the shell 21 facing the accommodating cavity 211, and an insulating layer is arranged between the current collector and the shell 21. That is to say, the current collector provided with the first active material layer 24 is connected to the surface of the shell 21 facing the accommodating cavity 211 through the insulating layer to achieve insulation isolation between the current collector provided with the first active material layer 24 and the shell 21. In this embodiment, the current collector provided with the first active material layer 24 can be connected to the end cover 23 so that the end cover 23 serves as the output pole of the first active material layer 24, and can also be connected to the electrode terminal insulated and installed on the shell 21, so that the electrode terminal insulated and installed on the shell 21 serves as the output pole of the first active material layer 24.
第一活性物质层24和第二活性物质层25分别是设置于壳体21和导电柱22上的活性物质,第一活性物质层24和第二活性物质层25是电池单体20内发生化学反应的区域,主要依靠金属离子在第一活性物质层24和第二活性物质层25之间移动来工作。The first active material layer 24 and the second active material layer 25 are active materials disposed on the shell 21 and the conductive column 22 respectively. The first active material layer 24 and the second active material layer 25 are areas where chemical reactions occur in the battery cell 20, and they mainly work by moving metal ions between the first active material layer 24 and the second active material layer 25.
可选地,若第一活性物质层24为正极活性物质层,第一活性物质层24的材质可以为钴酸锂、磷酸铁锂、三元锂或锰酸锂等,对应的,第二活性物质层25则为负极活性物质层,第二活性物质层25的材质可以为碳或硅等;若第一活性物质层24为负极活性物质层,第一活性物质层24的材质可以为碳或硅等,对应的,第二活性物质层25则为正极活性物质层,第二活性物质层25的材质可以为钴酸锂、磷酸铁锂、三元锂或锰酸锂等。Optionally, if the first active material layer 24 is a positive electrode active material layer, the material of the first active material layer 24 may be lithium cobalt oxide, lithium iron phosphate, ternary lithium or lithium manganese oxide, etc., and correspondingly, the second active material layer 25 is a negative electrode active material layer, and the material of the second active material layer 25 may be carbon or silicon, etc.; if the first active material layer 24 is a negative electrode active material layer, the material of the first active material layer 24 may be carbon or silicon, etc., and correspondingly, the second active material layer 25 is a positive electrode active material layer, and the material of the second active material layer 25 may be lithium cobalt oxide, lithium iron phosphate, ternary lithium or lithium manganese oxide, etc.
导电柱22沿第一方向X延伸并插设于容纳腔211内,即导电柱22沿第一方向X插设于壳体21的容纳腔211内。The conductive pillar 22 extends along the first direction X and is inserted into the accommodating cavity 211 , that is, the conductive pillar 22 is inserted into the accommodating cavity 211 of the housing 21 along the first direction X.
导电柱22的外周面上设置有第二活性物质层25,即导电柱22插设于容纳腔211内,第二活性物质层25设置于导电柱22面向壳体21的表面上。The second active material layer 25 is disposed on the outer peripheral surface of the conductive column 22 , that is, the conductive column 22 is inserted into the accommodating cavity 211 , and the second active material layer 25 is disposed on the surface of the conductive column 22 facing the housing 21 .
其中,导电柱22的结构可以是多种,导电柱22可以是实心结构,即导电柱22为沿第一方向X延伸的实心柱状结构,当然,导电柱22也可以为空心结构,即导电柱22为沿第一方向X延伸的空心柱状结构,以使导电柱22垂直于第一方向X上的横截面为环形。示例性的,在图5中,导电柱22为沿第一方向X延伸的实心柱状结构。The conductive pillar 22 may have a variety of structures. The conductive pillar 22 may be a solid structure, that is, the conductive pillar 22 is a solid columnar structure extending along the first direction X. Of course, the conductive pillar 22 may also be a hollow structure, that is, the conductive pillar 22 is a hollow columnar structure extending along the first direction X, so that the cross section of the conductive pillar 22 perpendicular to the first direction X is annular. For example, in FIG5 , the conductive pillar 22 is a solid columnar structure extending along the first direction X.
可理解的,导电柱22的形状也可以是多种,比如,圆柱状结构、矩形柱状结构、六棱柱结构等。示例性的,在图5中,导电柱22为沿第一方向X延伸的圆柱状结构。It is understandable that the conductive pillar 22 may have various shapes, such as a cylindrical structure, a rectangular cylindrical structure, a hexagonal prism structure, etc. For example, in FIG5 , the conductive pillar 22 is a cylindrical structure extending along the first direction X.
第二活性物质层25与第一活性物质层24面向设置,即在导电柱的径向Y上,第一活性物质层24和第二活性物质层25相对设置,其中,导电柱的径向Y垂直于第一方向X。需要说明的是,导电柱的径向Y为在导电柱22垂直于第一方向X的横截面上的外边缘指向导电柱22的中心轴线的方向或在导电柱22垂直于第一方向X的横截面上导电柱22的中心轴线指向横截面的外边缘的方向。The second active material layer 25 is disposed facing the first active material layer 24, that is, in the radial direction Y of the conductive column, the first active material layer 24 and the second active material layer 25 are disposed opposite to each other, wherein the radial direction Y of the conductive column is perpendicular to the first direction X. It should be noted that the radial direction Y of the conductive column is the direction in which the outer edge of the cross section of the conductive column 22 perpendicular to the first direction X points to the central axis of the conductive column 22 or the direction in which the central axis of the conductive column 22 points to the outer edge of the cross section of the conductive column 22 perpendicular to the first direction X.
在一些实施例中,壳体21还可以用于容纳电解质,例如电解液。壳体21的材质也可以是多种,比如,铜、铁、铝、钢、铝合金等。In some embodiments, the housing 21 may also be used to contain electrolytes, such as electrolytes. The housing 21 may also be made of a variety of materials, such as copper, iron, aluminum, steel, aluminum alloy, and the like.
壳体21可以是多种结构形式。在一些实施例中,壳体21为一侧开口212的空心结构,端盖23盖合于壳体21的开口212处并形成密封连接,以形成用于容纳导电柱22和电解质的密封空间。壳体21可以是多种形状,比如,圆柱体、长方体等。示例性的,在图4中,壳体21为圆柱体结构。The housing 21 can be in various structural forms. In some embodiments, the housing 21 is a hollow structure with an opening 212 on one side, and the end cap 23 covers the opening 212 of the housing 21 and forms a sealed connection to form a sealed space for accommodating the conductive column 22 and the electrolyte. The housing 21 can be in various shapes, such as a cylinder, a cuboid, etc. Exemplarily, in FIG4 , the housing 21 is a cylindrical structure.
在组装电池单体20时,可以先将导电柱22与端盖23相连后,再将涂覆有第二活性物质层25的导电柱22插设于壳体21的容纳腔211内,并向壳体21内填充电解质,最后将端盖23与壳体21相互盖合密封即可。When assembling the battery cell 20, the conductive column 22 can be first connected to the end cover 23, and then the conductive column 22 coated with the second active material layer 25 can be inserted into the accommodating cavity 211 of the shell 21, and the electrolyte is filled into the shell 21, and finally the end cover 23 and the shell 21 are covered and sealed.
可理解的,壳体21并不仅仅局限于上述结构,壳体21也可以是其他结构,比如,壳体21为在第一方向X上相对的两端开口212的空心结构,电池单体20包括两个端盖23,一个端盖23对应盖合于壳体21的一个开口212处并形成密封连接。It is understandable that the shell 21 is not limited to the above structure, and the shell 21 can also be other structures. For example, the shell 21 is a hollow structure with openings 212 at two opposite ends in the first direction X. The battery cell 20 includes two end covers 23, and one end cover 23 corresponds to covering an opening 212 of the shell 21 to form a sealed connection.
在一些实施例中,电池单体20还可以包括泄压机构,泄压机构可以安装于端盖23上,也可以安装于壳体21上。泄压机构用于在电池单体20的内部压力或温度达到预定值时泄放电池单体20内部的压力。In some embodiments, the battery cell 20 may further include a pressure relief mechanism, which may be mounted on the end cap 23 or the housing 21. The pressure relief mechanism is used to release the pressure inside the battery cell 20 when the internal pressure or temperature of the battery cell 20 reaches a predetermined value.
示例性的,泄压机构可以是诸如防爆阀、防爆片、气阀、泄压阀或安全阀等部件。Exemplarily, the pressure relief mechanism may be a component such as an explosion-proof valve, an explosion-proof disk, an air valve, a pressure relief valve or a safety valve.
通过在壳体21面向容纳腔211的一侧和导电柱22的外周面上分别设置有极性相反的第一活性物质层24和第二活性物质层25,并将导电柱22沿第一方向X插设于壳体21的容纳腔211内,使得第一活性物质层24与第二活性物质层25面向设置,从而能够通过壳体21和导电柱22分别作为电池单体20的正负输出极实现电池单体20的电能的输入或输出,采用这种结构的电池单体20一方面无需对极片进行卷绕,且节省了集流构件与极耳相互装配连接的工艺,进而有利于提升电池单体20的生产效率,另一方面无需在壳体21内设置大量的电解质,且取消了集流构件等部件,进而有利于降低电池单体20的制造成本,且有利于提高电池单体20的内部空间利用率,以提升电池单体20的能量密度。此外,电池单体20的中心位置设置有导电柱22,从而缓解了电池单体20的中心孔在后期使用过程中存在塌陷的风险,进而有利于提升电池单体20的使用稳定性,以提升电池单体20的使用安全性。By respectively arranging a first active material layer 24 and a second active material layer 25 with opposite polarities on the side of the shell 21 facing the accommodating cavity 211 and on the outer peripheral surface of the conductive column 22, and inserting the conductive column 22 into the accommodating cavity 211 of the shell 21 along the first direction X, so that the first active material layer 24 and the second active material layer 25 are arranged facing each other, the shell 21 and the conductive column 22 can be used as the positive and negative output electrodes of the battery cell 20 to realize the input or output of electric energy of the battery cell 20. The battery cell 20 adopting such a structure does not need to wind the pole piece, and saves the process of assembling and connecting the current collecting component and the pole ear, which is beneficial to improving the production efficiency of the battery cell 20. On the other hand, there is no need to arrange a large amount of electrolyte in the shell 21, and the current collecting component and other components are eliminated, which is beneficial to reducing the manufacturing cost of the battery cell 20 and improving the internal space utilization of the battery cell 20 to improve the energy density of the battery cell 20. In addition, a conductive column 22 is provided at the center of the battery cell 20 , thereby alleviating the risk of the center hole of the battery cell 20 collapsing during later use, thereby facilitating improving the use stability of the battery cell 20 and improving the use safety of the battery cell 20 .
根据本申请的一些实施例,参见图4和图5所示,第一活性物质层24涂覆于壳体21面向容纳腔211的表面上。According to some embodiments of the present application, referring to FIG. 4 and FIG. 5 , the first active material layer 24 is coated on the surface of the shell 21 facing the accommodating cavity 211 .
其中,第一活性物质层24涂覆于壳体21面向容纳腔211的表面上,即第一活性物质层24直接设置于容纳腔211的腔壁面上。The first active material layer 24 is coated on the surface of the housing 21 facing the accommodating cavity 211 , that is, the first active material layer 24 is directly disposed on the cavity wall surface of the accommodating cavity 211 .
通过将第一活性物质层24涂覆于壳体21面向容纳腔211的表面上,即第一活性物质层24设置于容纳腔211的腔壁面上,从而使得壳体21能够直接作为电池单体20的输出极,采用这种结构无需先将第一活性物质层24设置于集流体上后再将集流体与壳体21相连,从而有利于优化电池单体20的生产工艺,节省电池单体20的制造成本,且能够提升第一活性物质层24设置于壳体21上的连接稳定性和可靠性。By coating the first active material layer 24 on the surface of the shell 21 facing the accommodating cavity 211, that is, the first active material layer 24 is arranged on the cavity wall of the accommodating cavity 211, the shell 21 can be directly used as the output pole of the battery cell 20. This structure does not require the first active material layer 24 to be arranged on the current collector and then the current collector is connected to the shell 21, which is beneficial to optimize the production process of the battery cell 20, save the manufacturing cost of the battery cell 20, and can improve the connection stability and reliability of the first active material layer 24 arranged on the shell 21.
根据本申请的一些实施例,请继续参见图4和图5所示,壳体21为柱状结构,壳体21的中心轴线沿第 一方向X延伸。According to some embodiments of the present application, please continue to refer to Figures 4 and 5, the shell 21 is a columnar structure, and the central axis of the shell 21 extends along the first direction X.
其中,壳体21的中心轴线沿第一方向X延伸,即壳体21为沿第一方向X延伸的柱状结构,壳体21的形状可以是多种,示例性的,在图4中,壳体21为沿第一方向X延伸的圆柱状结构,在一些实施例中,参照图6,图6为本申请又一些实施例提供的电池单体20的结构爆炸图,壳体21还可以为沿第一方向X延伸的六棱柱结构,当然,在其他实施例中,壳体21还可以为三棱柱结构、矩形柱状结构或五边形柱状结构等。Among them, the central axis of the shell 21 extends along the first direction X, that is, the shell 21 is a columnar structure extending along the first direction X. The shape of the shell 21 can be various. For example, in Figure 4, the shell 21 is a cylindrical structure extending along the first direction X. In some embodiments, refer to Figure 6, which is a structural explosion diagram of the battery cell 20 provided in some embodiments of the present application. The shell 21 can also be a hexagonal prism structure extending along the first direction X. Of course, in other embodiments, the shell 21 can also be a triangular prism structure, a rectangular columnar structure or a pentagonal columnar structure, etc.
通过将壳体21设置为沿第一方向X延伸的柱状结构,也就是说,电池单体20为沿第一方向X延伸的柱状结构,采用这种结构的电池单体20的结构较为简单,便于装配,从而有利于降低电池单体20的装配难度,以提升电池单体20的生产效率。By configuring the shell 21 as a columnar structure extending along the first direction X, that is, the battery cell 20 is a columnar structure extending along the first direction X, the battery cell 20 with this structure has a simpler structure and is easy to assemble, thereby helping to reduce the difficulty of assembling the battery cell 20 and improve the production efficiency of the battery cell 20.
根据本申请的一些实施例,请参见图5所示,沿第一方向X,壳体21的长度为L,壳体21垂直于第一方向X的横截面在垂直于第一方向X上的最大尺寸为D 1,满足,L≥D 1According to some embodiments of the present application, as shown in FIG. 5 , along the first direction X, the length of the shell 21 is L, and the maximum dimension of the cross section of the shell 21 perpendicular to the first direction X is D 1 , satisfying L ≥ D 1 .
其中,壳体21垂直于第一方向X的横截面在垂直于第一方向X上的最大尺寸为D 1,即在壳体21垂直于第一方向X上的横截面的外边缘上任取两点,两点之间的最大距离则为D 1,也就是说,若壳体21为圆柱状结构,则D 1为壳体21垂直于第一方向X上的横截面的直径;若壳体21为三棱柱结构,则D 1为壳体21垂直于第一方向X上的横截面的最长的边;若壳体21为矩形柱状结构,则D 1为壳体21垂直于第一方向X上的横截面的对角线。 The maximum dimension of the cross section of the shell 21 perpendicular to the first direction X in the direction perpendicular to the first direction X is D 1 , that is, the maximum distance between any two points on the outer edge of the cross section of the shell 21 perpendicular to the first direction X is D 1 , that is, if the shell 21 is a cylindrical structure, D 1 is the diameter of the cross section of the shell 21 perpendicular to the first direction X; if the shell 21 is a triangular prism structure, D 1 is the longest side of the cross section of the shell 21 perpendicular to the first direction X; if the shell 21 is a rectangular columnar structure, D 1 is the diagonal of the cross section of the shell 21 perpendicular to the first direction X.
通过将壳体21在第一方向X上的长度设置为大于或等于壳体21的横截面在垂直于第一方向X上的最大尺寸,也就是说,壳体21为沿第一方向X延伸的长条状结构,采用这种结构的电池单体20有利于提升第一活性物质层24和第二活性物质层25的容纳量,且能够有效增加第一活性物质层24与第二活性物质层25相互面向设置的区域的面积,从而有利于提升电池单体20的能量密度和使用性能。By setting the length of the shell 21 in the first direction X to be greater than or equal to the maximum dimension of the cross section of the shell 21 in the direction perpendicular to the first direction X, that is, the shell 21 is a long strip structure extending along the first direction X. The battery cell 20 adopting such a structure is beneficial to improving the capacity of the first active material layer 24 and the second active material layer 25, and can effectively increase the area of the region where the first active material layer 24 and the second active material layer 25 are arranged facing each other, thereby helping to improve the energy density and performance of the battery cell 20.
在一些实施例中,1.5≤L/D 1,和/或,L/D 1≤25。 In some embodiments, 1.5≤L/D 1 , and/or, L/D 1 ≤25.
其中,1.5≤L/D 1,也就是说,壳体21在第一方向X上的长度为壳体21的横截面在垂直于第一方向X上的最大尺寸的1.5倍以上。L/D 1≤25,也就是说,壳体21在第一方向X上的长度为壳体21的横截面在垂直于第一方向X上的最大尺寸的25倍以下。 Wherein, 1.5≤L/D 1 , that is, the length of the shell 21 in the first direction X is more than 1.5 times the maximum dimension of the cross section of the shell 21 perpendicular to the first direction X. L/D 1 ≤25, that is, the length of the shell 21 in the first direction X is less than 25 times the maximum dimension of the cross section of the shell 21 perpendicular to the first direction X.
示例性的,壳体21为圆柱体结构,则壳体21的横截面在垂直于第一方向X上的最大尺寸为壳体21的直径。Exemplarily, the shell 21 is a cylindrical structure, and the maximum dimension of the cross section of the shell 21 perpendicular to the first direction X is the diameter of the shell 21 .
需要说明的是,当壳体21在第一方向X上的长度设置为壳体21的直径的1.5倍以上时,电池单体20为在第一方向X的长度大于电池单体20的横截面的尺寸的结构,即电池单体20为沿第一方向X延伸的细长型条状结构。当电池单体20为沿第一方向X延伸的细长型条状结构时,由制造经验可知,则能够增加导电柱22的外周面在第一方向X上的长度,且能够增加壳体21的容纳腔211的腔壁面在第一方向X上的长度,由此能够有效增加第一活性物质层24和第二活性物质层25的涂覆量,且能够增加第一活性物质层24和第二活性物质层25相互面向设置的区域的面积。It should be noted that when the length of the shell 21 in the first direction X is set to be more than 1.5 times the diameter of the shell 21, the battery cell 20 is a structure in which the length in the first direction X is greater than the size of the cross section of the battery cell 20, that is, the battery cell 20 is an elongated strip-shaped structure extending along the first direction X. When the battery cell 20 is an elongated strip-shaped structure extending along the first direction X, it is known from manufacturing experience that the length of the outer peripheral surface of the conductive column 22 in the first direction X can be increased, and the length of the cavity wall surface of the accommodating cavity 211 of the shell 21 in the first direction X can be increased, thereby effectively increasing the coating amount of the first active material layer 24 and the second active material layer 25, and increasing the area of the region where the first active material layer 24 and the second active material layer 25 are arranged facing each other.
优选地,3≤L/D 1。即壳体21在第一方向X上的长度为壳体21的直径的3倍以上,以实现电池单体20为沿第一方向X延伸的细长型结构,从而能够有效保证第一活性物质层24和第二活性物质层25的容纳量,以及第一活性物质层24与第二活性物质层25相互面向设置的区域的面积。 Preferably, 3≤L/D 1 . That is, the length of the shell 21 in the first direction X is more than 3 times the diameter of the shell 21 , so that the battery cell 20 is an elongated structure extending along the first direction X, thereby effectively ensuring the capacity of the first active material layer 24 and the second active material layer 25 , and the area of the region where the first active material layer 24 and the second active material layer 25 are disposed facing each other.
示例性的,壳体21的直径和对应壳体21在第一方向X上的长度可以为:18mm和65mm、18mm和200mm、18mm和300mm、21mm和70mm、21mm和200mm、21mm和310mm等。Exemplarily, the diameter of the shell 21 and the corresponding length of the shell 21 in the first direction X can be: 18 mm and 65 mm, 18 mm and 200 mm, 18 mm and 300 mm, 21 mm and 70 mm, 21 mm and 200 mm, 21 mm and 310 mm, etc.
通过将壳体21在第一方向X上的长度与壳体21的横截面在垂直于第一方向X上的最大尺寸的比值设置为大于或等于1.5,从而在电池单体20的体积相同的情况下能够有效增加导电柱22的外周面与壳体21的内表面相互面向设置的面积,以增加第一活性物质层24与第二活性物质层25的涂覆量,以及第一活性物质层24与第二活性物质层25相互面向设置的区域的面积,进而能够缓解因比值过小而造成第一活性物质层24和第二活性物质层25的容纳量不足,且第一活性物质层24与第二活性物质层25相互面向设置的区域的面积过小的现象。此外,通过将壳体21在第一方向X上的长度与壳体21的横截面在垂直于第一方向X上的最大尺寸的比值设置为小于或等于25,从而能够缓解因比值过大而造成电池单体20为过于细长型的结构,以降低电池单体20的制造难度过大。By setting the ratio of the length of the shell 21 in the first direction X to the maximum dimension of the cross section of the shell 21 perpendicular to the first direction X to be greater than or equal to 1.5, the area where the outer peripheral surface of the conductive column 22 and the inner surface of the shell 21 face each other can be effectively increased when the volume of the battery cell 20 is the same, so as to increase the coating amount of the first active material layer 24 and the second active material layer 25, and the area of the area where the first active material layer 24 and the second active material layer 25 face each other, thereby alleviating the phenomenon that the first active material layer 24 and the second active material layer 25 are insufficient in the amount of the first active material layer 24 and the second active material layer 25 and the area where the first active material layer 24 and the second active material layer 25 face each other due to the ratio being too small. In addition, by setting the ratio of the length of the shell 21 in the first direction X to the maximum dimension of the cross section of the shell 21 perpendicular to the first direction X to be less than or equal to 25, the battery cell 20 can be relieved from being too slender due to the ratio being too large, so as to reduce the difficulty of manufacturing the battery cell 20.
需要说明的是,在将第一活性物质层24设置于壳体21面向容纳腔211的一侧并将第二活性物质层25设置于导电柱22的外周面上的实施例中,通过将1.5≤L/D 1和/或L/D 1≤25,当然,在一些实施例中,比如,在电池单体20的壳体21内容纳有正极极片和负极极片绕第一方向X延伸的轴线卷绕形成的电极组件,以形成圆柱体结构的电池单体20中,也可以将电池单体20设置为1.5≤L/D 1和/或L/D 1≤25的结构。 It should be noted that, in the embodiment in which the first active material layer 24 is arranged on the side of the shell 21 facing the accommodating cavity 211 and the second active material layer 25 is arranged on the outer peripheral surface of the conductive column 22, by setting 1.5≤L/D 1 and/or L/D 1 ≤25, of course, in some embodiments, for example, in the shell 21 of the battery cell 20, an electrode assembly formed by winding the positive electrode sheet and the negative electrode sheet around the axis extending in the first direction X to form a battery cell 20 with a cylindrical structure is accommodated, the battery cell 20 can also be set to a structure of 1.5≤L/D 1 and/or L/D 1 ≤25.
根据本申请的一些实施例,参见图4和图5所示,第一活性物质层24和第二活性物质层25均为沿导电柱22的周向延伸的环形结构。According to some embodiments of the present application, as shown in FIG. 4 and FIG. 5 , the first active material layer 24 and the second active material layer 25 are both annular structures extending along the circumference of the conductive pillar 22 .
其中,第一活性物质层24和第二活性物质层25均为沿导电柱22的周向延伸的环形结构,即第一活性物质层24和第二活性物质层25均为环绕在导电柱22的外侧的环形结构,也就是说,第二活性物质层25环绕于导电柱22的外周侧,第一活性物质层24环绕于第二活性物质层25的外周侧。需要说明的是,导电柱22的周向是指绕导电柱22的中心轴线进行环绕的方向。The first active material layer 24 and the second active material layer 25 are both annular structures extending along the circumferential direction of the conductive column 22, that is, the first active material layer 24 and the second active material layer 25 are both annular structures surrounding the outside of the conductive column 22, that is, the second active material layer 25 surrounds the outer peripheral side of the conductive column 22, and the first active material layer 24 surrounds the outer peripheral side of the second active material layer 25. It should be noted that the circumferential direction of the conductive column 22 refers to the direction of surrounding the central axis of the conductive column 22.
在一些实施例中,沿导电柱的径向Y,第一活性物质层24的厚度为D 2,满足,0.1mm≤D 2≤15mm。 In some embodiments, along the radial direction Y of the conductive pillar, the thickness of the first active material layer 24 is D 2 , satisfying 0.1 mm≤D 2 ≤15 mm.
示例性的,第一活性物质层24在导电柱的径向Y上的厚度可以0.1mm、0.5mm、1mm、2mm、5mm、8mm、10mm或15mm等。For example, the thickness of the first active material layer 24 in the radial direction Y of the conductive pillar may be 0.1 mm, 0.5 mm, 1 mm, 2 mm, 5 mm, 8 mm, 10 mm, or 15 mm.
在一些实施例中,沿导电柱的径向Y,第二活性物质层25的厚度为D 3,满足,0.1mm≤D 3≤15mm。 In some embodiments, along the radial direction Y of the conductive pillar, the thickness of the second active material layer 25 is D 3 , satisfying 0.1 mm≤D 3 ≤15 mm.
示例性的,第二活性物质层25在导电柱的径向Y上的厚度可以0.1mm、0.5mm、1mm、2mm、5mm、8mm、10mm或15mm等。For example, the thickness of the second active material layer 25 in the radial direction Y of the conductive pillar may be 0.1 mm, 0.5 mm, 1 mm, 2 mm, 5 mm, 8 mm, 10 mm, or 15 mm.
通过将第一活性物质层24和第二活性物质层25设置为均沿导电柱22的周向延伸的结构,采用这种结构 的电池单体20能够进一步增加第一活性物质层24和第二活性物质层25的容纳量和第一活性物质层24与第二活性物质层25相互面向设置的区域的面积,从而能够有效提升电池单体20的能量密度,以提升电池单体20的使用性能。By configuring the first active material layer 24 and the second active material layer 25 to extend in the circumferential direction of the conductive column 22, the battery cell 20 using this structure can further increase the capacity of the first active material layer 24 and the second active material layer 25 and the area of the region where the first active material layer 24 and the second active material layer 25 are facing each other, thereby effectively improving the energy density of the battery cell 20 and improving the performance of the battery cell 20.
根据本申请的一些实施例,参见图4、图5和图6所示,第一活性物质层24沿导电柱22的周向围合形成供导电柱22插入的安装通道241,安装通道241的内表面与第二活性物质层25的外周面相互契合。According to some embodiments of the present application, as shown in Figures 4, 5 and 6, the first active material layer 24 surrounds the conductive column 22 along the circumference to form a mounting channel 241 for inserting the conductive column 22, and the inner surface of the mounting channel 241 fits with the outer peripheral surface of the second active material layer 25.
其中,第一活性物质层24沿导电柱22的周向围合形成供导电柱22插入的安装通道241,即第一活性物质层24环绕于第二活性物质层25的外周侧。The first active material layer 24 surrounds the conductive pillar 22 along its circumference to form a mounting channel 241 for the conductive pillar 22 to be inserted into. That is, the first active material layer 24 surrounds the outer circumference of the second active material layer 25 .
安装通道241的内表面与第二活性物质层25的外周面相互契合,即第二活性物质层25插设于第一活性物质层24形成的安装通道241内,且第二活性物质层25面向第一活性物质层24的表面的形状与第一活性物质层24面向第二活性物质层25的表面的形状相同,也就是说,若第一活性物质层24形成的安装通道241垂直于第一方向X的横截面为圆形,则第二活性物质层25的外周面垂直于第一方向X的横截面也为圆形;若第一活性物质层24形成的安装通道241垂直于第一方向X的横截面为多边形,则第二活性物质层25的外周面垂直于第一方向X的横截面也为多边形。The inner surface of the mounting channel 241 and the outer peripheral surface of the second active material layer 25 fit each other, that is, the second active material layer 25 is inserted in the mounting channel 241 formed by the first active material layer 24, and the shape of the surface of the second active material layer 25 facing the first active material layer 24 is the same as the shape of the surface of the first active material layer 24 facing the second active material layer 25. In other words, if the cross-section of the mounting channel 241 formed by the first active material layer 24 perpendicular to the first direction X is circular, then the cross-section of the outer peripheral surface of the second active material layer 25 perpendicular to the first direction X is also circular; if the cross-section of the mounting channel 241 formed by the first active material layer 24 perpendicular to the first direction X is polygonal, then the cross-section of the outer peripheral surface of the second active material layer 25 perpendicular to the first direction X is also polygonal.
通过将第一活性物质层24的内表面与第二活性物质层25的外周面设置为相互契合的结构,从而便于将设置有第二活性物质层25的导电柱22装配至第一活性物质层24围合形成的安装通道241内,有利于降低电池单体20的装配难度,且有利于减少第一活性物质层24与第二活性物质层25之间的空间浪费,以提升电池单体20的能量密度。By setting the inner surface of the first active material layer 24 and the outer peripheral surface of the second active material layer 25 to be a mutually fitting structure, it is convenient to assemble the conductive column 22 provided with the second active material layer 25 into the installation channel 241 formed by the first active material layer 24, which is beneficial to reduce the difficulty of assembling the battery cell 20 and reduce the space waste between the first active material layer 24 and the second active material layer 25, so as to improve the energy density of the battery cell 20.
在一些实施例中,参见图4和图6所示,安装通道241垂直于第一方向X的横截面为圆形。In some embodiments, referring to FIG. 4 and FIG. 6 , a cross section of the mounting channel 241 perpendicular to the first direction X is circular.
其中,安装通道241垂直于第一方向X的横截面为圆形,安装通道241为圆形通道。The cross section of the installation channel 241 perpendicular to the first direction X is circular, and the installation channel 241 is a circular channel.
可理解的,安装通道241垂直于第一方向X的横截面的形状并不局限于此,参照图7,图7为本申请再一些实施例提供的电池单体20的结构爆炸图,安装通道241垂直于第一方向X的横截面为六边形,当然,在其他实施例中,安装通道241垂直于第一方向X的横截面还可以为矩形、五边形等。It can be understood that the shape of the cross-section of the installation channel 241 perpendicular to the first direction X is not limited to this. Referring to Figure 7, Figure 7 is a structural explosion diagram of the battery cell 20 provided in some other embodiments of the present application. The cross-section of the installation channel 241 perpendicular to the first direction X is a hexagon. Of course, in other embodiments, the cross-section of the installation channel 241 perpendicular to the first direction X can also be a rectangle, a pentagon, etc.
需要说明的是,壳体21垂直于第一方向X的横截的形状可以与安装通道241垂直于第一方向X的横截面形状相同,也可以与安装通道241垂直于第一方向X的横截面的形状不同。比如,在图4中,壳体21垂直于第一方向X的横截的形状与安装通道241垂直于第一方向X的横截面形状相同,壳体21垂直于第一方向X的横截的形状和安装通道241垂直于第一方向X的横截面形状均为圆形,同样的,在图7中,壳体21垂直于第一方向X的横截的形状和安装通道241垂直于第一方向X的横截面形状均为六边形;在图6中,壳体21垂直于第一方向X的横截的形状与安装通道241垂直于第一方向X的横截面形状不相同,壳体21垂直于第一方向X的横截的形状为六边形,安装通道241垂直于第一方向X的横截面形状均为圆形,当然,也可以是壳体21垂直于第一方向X的横截的形状为圆形,安装通道241垂直于第一方向X的横截面形状均为六边形。It should be noted that the cross-sectional shape of the shell 21 perpendicular to the first direction X may be the same as or different from the cross-sectional shape of the mounting channel 241 perpendicular to the first direction X. For example, in FIG4 , the cross-sectional shape of the shell 21 perpendicular to the first direction X is the same as the cross-sectional shape of the mounting channel 241 perpendicular to the first direction X, and the cross-sectional shape of the shell 21 perpendicular to the first direction X and the cross-sectional shape of the mounting channel 241 perpendicular to the first direction X are both circular. Similarly, in FIG7 , the cross-sectional shape of the shell 21 perpendicular to the first direction X and the cross-sectional shape of the mounting channel 241 perpendicular to the first direction X are both hexagonal. In FIG6 , the cross-sectional shape of the shell 21 perpendicular to the first direction X is different from the cross-sectional shape of the mounting channel 241 perpendicular to the first direction X, and the cross-sectional shape of the shell 21 perpendicular to the first direction X is a hexagon, and the cross-sectional shape of the mounting channel 241 perpendicular to the first direction X is both circular. Of course, the cross-sectional shape of the shell 21 perpendicular to the first direction X may also be circular, and the cross-sectional shape of the mounting channel 241 perpendicular to the first direction X may be hexagonal.
通过将第一活性物质层24围合形成的安装通道241的横截面设置为圆形,采用这种结构能够在设置第二活性物质层25装配至安装通道241内时有效缓解第一活性物质层24与第二活性物质层25之间发生干涉或刮蹭的现象,一方面能够有利于提升电池单体20的装配效率,另一方面能够有效提升电池单体20的生产质量。By setting the cross-section of the installation channel 241 formed by the first active material layer 24 to be circular, this structure can effectively alleviate the interference or scratching between the first active material layer 24 and the second active material layer 25 when the second active material layer 25 is assembled into the installation channel 241. On the one hand, it can be beneficial to improve the assembly efficiency of the battery cell 20, and on the other hand, it can effectively improve the production quality of the battery cell 20.
根据本申请的一些实施例,参照图8和图9,图8为本申请另一些实施例提供的电池单体20的剖视图,图9为图8所示的电池单体20的A处的局部放大图。第一活性物质层24包括多个第一反应层242,多个第一反应层242沿导电柱的径向Y层叠设置。According to some embodiments of the present application, referring to Figures 8 and 9, Figure 8 is a cross-sectional view of a battery cell 20 provided in other embodiments of the present application, and Figure 9 is a partial enlarged view of the battery cell 20 at A shown in Figure 8. The first active material layer 24 includes a plurality of first reaction layers 242, and the plurality of first reaction layers 242 are stacked along the radial direction Y of the conductive pillar.
其中,多个第一反应层242沿导电柱的径向Y层叠设置,即多个第一反应层242沿导电柱的径向Y层叠于壳体21与第二活性物质层25之间。The plurality of first reaction layers 242 are stacked along the radial direction Y of the conductive pillar, that is, the plurality of first reaction layers 242 are stacked along the radial direction Y of the conductive pillar between the shell 21 and the second active material layer 25 .
第一活性物质层24由沿导电柱的径向Y排布的多个第一反应层242堆叠而成,采用这种结构的第一活性物质层24一方面便于制造,有利于降低第一活性物质层24设置在壳体21的容纳腔211的腔壁面上的制造难度,另一方面能够提升第一活性物质层24的电解液的浸润效果,以保证金属离子的在第一活性物质层24内的穿透性。The first active material layer 24 is formed by stacking multiple first reaction layers 242 arranged along the radial direction Y of the conductive column. The first active material layer 24 with such a structure is easy to manufacture, which is beneficial to reduce the manufacturing difficulty of setting the first active material layer 24 on the cavity wall surface of the accommodating cavity 211 of the shell 21. On the other hand, it can enhance the wetting effect of the electrolyte of the first active material layer 24 to ensure the penetrability of metal ions in the first active material layer 24.
在一些实施例中,参见图8和图9所示,沿导电柱的径向Y,多个第一反应层242中靠近第二活性物质层25的第一反应层242的密度小于其他第一反应层242的密度。In some embodiments, as shown in FIGS. 8 and 9 , along the radial direction Y of the conductive pillar, the density of the first reaction layer 242 close to the second active material layer 25 among the plurality of first reaction layers 242 is less than the density of the other first reaction layers 242 .
其中,多个第一反应层242中靠近第二活性物质层25的第一反应层242的密度小于其他第一反应层242的密度,即多个第一反应层242中最靠近第二活性物质层25的第一反应层242的密度最小。The density of the first reaction layer 242 close to the second active material layer 25 among the multiple first reaction layers 242 is smaller than that of other first reaction layers 242 , that is, the density of the first reaction layer 242 closest to the second active material layer 25 among the multiple first reaction layers 242 is the smallest.
通过将靠近第二活性物质层25的第一反应层242的密度设置为比其他第一反应层242的密度小,使得靠近第二活性物质层25的第一反应层242的动力学更好,以便于金属离子进行扩散至其他第一反应层242内,从而有利于减少内阻,并能够提升电池单体20的使用性能,同时还能够缓解电池单体20出现极化的现象。By setting the density of the first reaction layer 242 close to the second active material layer 25 to be smaller than the density of other first reaction layers 242, the dynamics of the first reaction layer 242 close to the second active material layer 25 is made better, so that the metal ions can diffuse into other first reaction layers 242, which is beneficial to reduce the internal resistance and improve the performance of the battery cell 20, while also alleviating the polarization phenomenon of the battery cell 20.
在一些实施例中,请继续参见图8和图9所示,沿导电柱的径向Y,多个第一反应层242中靠近第二活性物质层25的第一反应层242的颗粒直径小于其他第一反应层242的颗粒直径。In some embodiments, referring to FIGS. 8 and 9 , along the radial direction Y of the conductive pillar, the particle diameter of the first reaction layer 242 close to the second active material layer 25 among the plurality of first reaction layers 242 is smaller than the particle diameters of other first reaction layers 242 .
其中,多个第一反应层242中靠近第二活性物质层25的第一反应层242的颗粒直径小于其他第一反应层242的颗粒直径,即多个第一反应层242中最靠近第二活性物质层25的第一反应层242的材质的颗粒度最小。Among them, the particle diameter of the first reaction layer 242 close to the second active material layer 25 among the multiple first reaction layers 242 is smaller than the particle diameters of other first reaction layers 242, that is, the material particle size of the first reaction layer 242 closest to the second active material layer 25 among the multiple first reaction layers 242 is the smallest.
通过将靠近第二活性物质层25的第一反应层242的颗粒直径设置为比其他第一反应层242的颗粒直径小,使得靠近第二活性物质层25的第一反应层242的动力学更好,以便于金属离子进行扩散至其他第一反应层242内,从而有利于减少内阻,并能够提升电池单体20的使用性能,同时还能够缓解电池单体20出现极化的现象。By setting the particle diameter of the first reaction layer 242 close to the second active material layer 25 to be smaller than the particle diameter of other first reaction layers 242, the dynamics of the first reaction layer 242 close to the second active material layer 25 is made better, so that the metal ions can diffuse into other first reaction layers 242, which is beneficial to reduce the internal resistance and improve the performance of the battery cell 20, while also alleviating the polarization phenomenon of the battery cell 20.
根据本申请的一些实施例,请参见图8和图9所示,第一活性物质层24的第一反应层242的数量为N 1,满足,2≤N 1≤3。 According to some embodiments of the present application, referring to FIG. 8 and FIG. 9 , the number of the first reaction layers 242 of the first active material layer 24 is N 1 , satisfying 2≤N 1 ≤3.
其中,第一活性物质层24的第一反应层242的数量可以是2个,也可以是3个,示例性的,在图9中,第一活性物质层24包括沿导电柱的径向Y层叠设置的两个第一反应层242。The number of the first reaction layers 242 of the first active material layer 24 may be 2 or 3. For example, in FIG. 9 , the first active material layer 24 includes two first reaction layers 242 stacked along the radial direction Y of the conductive column.
通过将第一活性物质层24的第一反应层242的数量设置在2个至3个,从而一方面能够缓解因第一反应层242的数量过小而造成电解液的浸润效果不佳的现象,以保证电池单体20的使用性能,另一方面能够降低因第一反应层242的数量过多而导致第一活性物质层24的制造难度过大且存在脱落的风险。By setting the number of first reaction layers 242 of the first active material layer 24 to 2 to 3, on the one hand, the phenomenon of poor electrolyte infiltration caused by too small a number of first reaction layers 242 can be alleviated to ensure the performance of the battery cell 20; on the other hand, the manufacturing difficulty of the first active material layer 24 and the risk of falling off caused by too many first reaction layers 242 can be reduced.
根据本申请的一些实施例,参照图8和图9,第二活性物质层25包括多个第二反应层251,多个第二反应层251沿导电柱的径向Y层叠设置。According to some embodiments of the present application, referring to FIG. 8 and FIG. 9 , the second active material layer 25 includes a plurality of second reaction layers 251 , and the plurality of second reaction layers 251 are stacked along a radial direction Y of the conductive pillar.
其中,多个第二反应层251沿导电柱的径向Y层叠设置,即多个第二反应层251沿导电柱的径向Y层叠于第一活性物质层24与导电柱22之间。The plurality of second reaction layers 251 are stacked along the radial direction Y of the conductive pillars, that is, the plurality of second reaction layers 251 are stacked along the radial direction Y of the conductive pillars between the first active material layer 24 and the conductive pillars 22 .
第二活性物质层25由沿导电柱的径向Y排布的多个第二反应层251堆叠而成,采用这种结构的第二活性物质层25一方面便于制造,有利于降低第二活性物质层25设置在壳体21的容纳腔211的腔壁面上的制造难度,另一方面能够提升第二活性物质层25的电解液的浸润效果,以保证金属离子的在第二活性物质层25内的穿透性。The second active material layer 25 is formed by stacking multiple second reaction layers 251 arranged along the radial direction Y of the conductive column. The second active material layer 25 with such a structure is easy to manufacture, which is beneficial to reduce the manufacturing difficulty of setting the second active material layer 25 on the cavity wall surface of the accommodating cavity 211 of the shell 21. On the other hand, it can enhance the wetting effect of the electrolyte of the second active material layer 25 to ensure the penetrability of metal ions in the second active material layer 25.
在一些实施例中,参见图8和图9所示,沿导电柱的径向Y,多个第二反应层251中靠近第一活性物质层24的第二反应层251的密度小于其他第二反应层251的密度。In some embodiments, as shown in FIGS. 8 and 9 , along the radial direction Y of the conductive pillar, the density of the second reaction layer 251 close to the first active material layer 24 among the plurality of second reaction layers 251 is less than the density of the other second reaction layers 251 .
其中,多个第二反应层251中靠近第一活性物质层24的第二反应层251的密度小于其他第二反应层251的密度,即多个第二反应层251中最靠近第一活性物质层24的第二反应层251的密度最小。The density of the second reaction layer 251 close to the first active material layer 24 among the multiple second reaction layers 251 is lower than the density of other second reaction layers 251 , that is, the density of the second reaction layer 251 closest to the first active material layer 24 among the multiple second reaction layers 251 is the smallest.
通过将靠近第一活性物质层24的第二反应层251的密度设置为比其他第二反应层251的密度小,使得靠近第一活性物质层24的第二反应层251的动力学更好,以便于金属离子进行扩散至其他第二反应层251内,从而有利于减少内阻,并能够提升电池单体20的使用性能,同时还能够缓解电池单体20出现极化的现象。By setting the density of the second reaction layer 251 close to the first active material layer 24 to be smaller than the density of other second reaction layers 251, the dynamics of the second reaction layer 251 close to the first active material layer 24 is made better, so that the metal ions can diffuse into other second reaction layers 251, which is beneficial to reduce the internal resistance and improve the performance of the battery cell 20, while also alleviating the polarization phenomenon of the battery cell 20.
在一些实施例中,请继续参见图8和图9所示,沿导电柱的径向Y,多个第二反应层251中靠近第一活性物质层24的第二反应层251的颗粒直径小于其他第二反应层251的颗粒直径。In some embodiments, referring to FIGS. 8 and 9 , along the radial direction Y of the conductive pillar, the particle diameter of the second reaction layer 251 close to the first active material layer 24 among the plurality of second reaction layers 251 is smaller than the particle diameters of other second reaction layers 251 .
其中,多个第二反应层251中靠近第一活性物质层24的第二反应层251的颗粒直径小于其他第二反应层251的颗粒直径,即多个第二反应层251中最靠近第一活性物质层24的第二反应层251的材质的颗粒度最小。Among them, the particle diameter of the second reaction layer 251 close to the first active material layer 24 among the multiple second reaction layers 251 is smaller than the particle diameters of other second reaction layers 251, that is, the second reaction layer 251 closest to the first active material layer 24 among the multiple second reaction layers 251 has the smallest particle size.
通过将靠近第一活性物质层24的第二反应层251的颗粒直径设置为比其他第二反应层251的颗粒直径小,使得靠近第一活性物质层24的第二反应层251的动力学更好,以便于金属离子进行扩散至其他第二反应层251内,从而有利于减少内阻,并能够提升电池单体20的使用性能,同时还能够缓解电池单体20出现极化的现象。By setting the particle diameter of the second reaction layer 251 close to the first active material layer 24 to be smaller than the particle diameter of other second reaction layers 251, the dynamics of the second reaction layer 251 close to the first active material layer 24 is made better, so that the metal ions can diffuse into other second reaction layers 251, which is beneficial to reduce the internal resistance and improve the performance of the battery cell 20, and at the same time alleviate the polarization phenomenon of the battery cell 20.
根据本申请的一些实施例,请参见图8和图9所示,第二活性物质层25的第二反应层251的数量为N 2,满足,2≤N 2≤3。 According to some embodiments of the present application, referring to FIG. 8 and FIG. 9 , the number of the second reaction layers 251 of the second active material layer 25 is N 2 , satisfying 2≤N 2 ≤3.
其中,第二活性物质层25的第二反应层251的数量可以是2个,也可以是3个,示例性的,在图9中,第二活性物质层25包括沿导电柱的径向Y层叠设置的两个第二反应层251。The number of the second reaction layers 251 of the second active material layer 25 may be 2 or 3. For example, in FIG. 9 , the second active material layer 25 includes two second reaction layers 251 stacked along the radial direction Y of the conductive column.
通过将第二活性物质层25的第二反应层251的数量设置在2个至3个,从而一方面能够缓解因第二反应层251的数量过小而造成电解液的浸润效果不佳的现象,以保证电池单体20的使用性能,另一方面能够降低因第二反应层251的数量过多而导致第二活性物质层25的制造难度过大且存在脱落的风险。By setting the number of second reaction layers 251 of the second active material layer 25 to 2 to 3, on the one hand, the phenomenon of poor electrolyte infiltration caused by too small a number of second reaction layers 251 can be alleviated to ensure the performance of the battery cell 20; on the other hand, the manufacturing difficulty of the second active material layer 25 caused by too many second reaction layers 251 and the risk of falling off can be reduced.
根据本申请的一些实施例,参照图10和图11,图10为本申请再又一些实施例提供的电池单体20的结构爆炸图,图11为本申请再又一些实施例提供的电池单体20的第一活性物质层24的剖视图。第一活性物质层24面向第二活性物质层25的表面设置有第一刻痕槽243,第一刻痕槽243用于容纳电解液。和/或,第二活性物质层25面向第一活性物质层24的表面设置有第二刻痕槽252,第二刻痕槽252用于容纳电解液。According to some embodiments of the present application, referring to FIG. 10 and FIG. 11, FIG. 10 is a structural explosion diagram of a battery cell 20 provided in some other embodiments of the present application, and FIG. 11 is a cross-sectional view of a first active material layer 24 of a battery cell 20 provided in some other embodiments of the present application. A first notch groove 243 is provided on the surface of the first active material layer 24 facing the second active material layer 25, and the first notch groove 243 is used to accommodate an electrolyte. And/or, a second notch groove 252 is provided on the surface of the second active material layer 25 facing the first active material layer 24, and the second notch groove 252 is used to accommodate an electrolyte.
其中,第一活性物质层24面向第二活性物质层25的表面设置有第一刻痕槽243,即第一活性物质层24在面向第二活性物质层25的表面上凹设有用于容纳电解液的凹槽;同样的,第二活性物质层25面向第一活性物质层24的表面设置有第二刻痕槽252,即第二活性物质层25在面向第一活性物质层24的表面上凹设有用于容纳电解液的凹槽。Among them, a first notch groove 243 is provided on the surface of the first active material layer 24 facing the second active material layer 25, that is, the first active material layer 24 is provided with a groove for accommodating the electrolyte on the surface facing the second active material layer 25; similarly, a second notch groove 252 is provided on the surface of the second active material layer 25 facing the first active material layer 24, that is, the second active material layer 25 is provided with a groove for accommodating the electrolyte on the surface facing the first active material layer 24.
可选地,第一刻痕槽243和第二刻痕槽252的结构可以是多种,比如,第一刻痕槽243和第二刻痕槽252为沿导电柱22的周向延伸的环形结构,也可以是沿第一方向X延伸的条状结构。Optionally, the first notch groove 243 and the second notch groove 252 may have various structures. For example, the first notch groove 243 and the second notch groove 252 may be an annular structure extending along the circumference of the conductive pillar 22 , or may be a strip structure extending along the first direction X.
在第一活性物质层24包括沿导电柱的径向Y层叠设置的多个第一反应层242的实施例中,第一刻痕槽243设置于多个第一反应层242中在导电柱的径向Y上最靠近第二活性物质层25的第一反应层242面向第二活性物质层25的表面上。同样的,在第二活性物质层25包括沿导电柱的径向Y层叠设置的多个第二反应层251的实施例中,第二刻痕槽252设置于多个第二反应层251中在导电柱的径向Y上最靠近第一活性物质层24的第二反应层251面向第一活性物质层24的表面上。In the embodiment where the first active material layer 24 includes a plurality of first reaction layers 242 stacked along the radial direction Y of the conductive pillar, the first notch groove 243 is disposed on the surface of the first reaction layer 242 closest to the second active material layer 25 in the radial direction Y of the conductive pillar among the plurality of first reaction layers 242, facing the second active material layer 25. Similarly, in the embodiment where the second active material layer 25 includes a plurality of second reaction layers 251 stacked along the radial direction Y of the conductive pillar, the second notch groove 252 is disposed on the surface of the second reaction layer 251 closest to the first active material layer 24 in the radial direction Y of the conductive pillar among the plurality of second reaction layers 251, facing the first active material layer 24.
需要说明的是,在图10和图11中,电池单体20的第一活性物质层24上设置有第一刻痕槽243,且电池单体20的第二活性物质层25上设置有第二刻痕槽252,当然,电池单体20的结构并不局限于此,在其他实施例中,电池单体20也可以只在第一活性物质层24面向第二活性物质层25的表面设置第一刻痕槽243,也可以是只在第二活性物质层25面向第一活性物质层24的表面设置第二刻痕槽252。It should be noted that in Figures 10 and 11, a first notch groove 243 is provided on the first active material layer 24 of the battery cell 20, and a second notch groove 252 is provided on the second active material layer 25 of the battery cell 20. Of course, the structure of the battery cell 20 is not limited to this. In other embodiments, the battery cell 20 may also only have the first notch groove 243 provided on the surface of the first active material layer 24 facing the second active material layer 25, or may only have the second notch groove 252 provided on the surface of the second active material layer 25 facing the first active material layer 24.
通过在第一活性物质层24面向第二活性物质层25的表面上设置用于容纳电解液的第一刻痕槽243,使得这种结构的电池单体20能够有效提升第一活性物质层24对电解液的保液能力,且能够提升电解液对第一活性物质层24的浸润效果,从而有利于提升电池单体20的使用性能。同样的,通过在第二活性物质层25面向第一活性物质层24的表面上设置用于容纳电解液的第二刻痕槽252,使得这种结构的电池单体20能够有效提升第二活性物质层25对电解液的保液能力,且能够提升电解液对第二活性物质层25的浸润效果,从而有利于提升电池单体20的使用性能。By providing a first notch groove 243 for accommodating an electrolyte on the surface of the first active material layer 24 facing the second active material layer 25, the battery cell 20 of this structure can effectively improve the first active material layer 24's ability to retain the electrolyte, and can improve the electrolyte's infiltration effect on the first active material layer 24, thereby facilitating the improvement of the performance of the battery cell 20. Similarly, by providing a second notch groove 252 for accommodating an electrolyte on the surface of the second active material layer 25 facing the first active material layer 24, the battery cell 20 of this structure can effectively improve the second active material layer 25's ability to retain the electrolyte, and can improve the electrolyte's infiltration effect on the second active material layer 25, thereby facilitating the improvement of the performance of the battery cell 20.
根据本申请的一些实施例,参见图10和图11所示,第一活性物质层24为沿导电柱22的周向延伸的环形结构,第一刻痕槽243沿导电柱22的周向延伸。According to some embodiments of the present application, as shown in FIG. 10 and FIG. 11 , the first active material layer 24 is an annular structure extending along the circumference of the conductive pillar 22 , and the first notch groove 243 extends along the circumference of the conductive pillar 22 .
其中,第一刻痕槽243沿导电柱22的周向延伸,即第一刻痕槽243为沿导电柱22的周向延伸的环形结 构,也就是说,第一刻痕槽243环绕第一活性物质层24面向第二活性物质层25的表面的整周设置。当然,在其他实施例中,第一刻痕槽243也可以为沿第一方向X延伸的结构。The first notched groove 243 extends along the circumference of the conductive pillar 22, that is, the first notched groove 243 is an annular structure extending along the circumference of the conductive pillar 22, that is, the first notched groove 243 is arranged around the entire circumference of the surface of the first active material layer 24 facing the second active material layer 25. Of course, in other embodiments, the first notched groove 243 may also be a structure extending along the first direction X.
通过将第一刻痕槽243设置为沿导电柱22的周向延伸的环形结构,从而有利于提升第一刻痕槽243对电解液的容纳量,进而能够有效提升第一活性物质层24的保液能力,以保证第一活性物质层24的电解液的浸润效果。By setting the first notch groove 243 as an annular structure extending along the circumference of the conductive column 22, it is helpful to increase the capacity of the first notch groove 243 for the electrolyte, thereby effectively improving the liquid retention capacity of the first active material layer 24 to ensure the electrolyte infiltration effect of the first active material layer 24.
在一些实施例中,请继续参见图10和图11所示,第一刻痕槽243为多个,多个第一刻痕槽243沿第一方向X间隔设置。In some embodiments, please continue to refer to FIG. 10 and FIG. 11 , there are a plurality of first notch grooves 243 , and the plurality of first notch grooves 243 are arranged along the first direction X at intervals.
其中,多个第一刻痕槽243沿第一方向X间隔设置,即多个第一刻痕槽243沿第一方向X排布。The plurality of first notch grooves 243 are arranged at intervals along the first direction X, that is, the plurality of first notch grooves 243 are arranged along the first direction X.
需要说明的是,若第一刻痕槽243为沿第一方向X延伸的结构,则多个第一刻痕槽243可以沿导电柱22的周向间隔排布。It should be noted that if the first notch grooves 243 are structures extending along the first direction X, a plurality of first notch grooves 243 may be arranged at intervals along the circumferential direction of the conductive pillar 22 .
通过将设置在第一活性物质层24的表面的第一刻痕槽243设置为多个,且多个第一刻痕槽243沿第一方向X间隔设置,从而有利于进一步提升第一活性物质层24的保液能力和电解液的浸润效果,以提升电池单体20的使用性能。By providing a plurality of first notched grooves 243 disposed on the surface of the first active material layer 24 and the plurality of first notched grooves 243 are spaced apart along the first direction X, the liquid retention capacity of the first active material layer 24 and the electrolyte infiltration effect are further improved, thereby improving the performance of the battery cell 20 .
根据本申请的一些实施例,参见图10所示,第二活性物质层25为沿导电柱22的周向延伸的环形结构,第二刻痕槽252沿导电柱22的周向延伸。According to some embodiments of the present application, as shown in FIG. 10 , the second active material layer 25 is an annular structure extending along the circumference of the conductive pillar 22 , and the second notch groove 252 extends along the circumference of the conductive pillar 22 .
其中,第二刻痕槽252沿导电柱22的周向延伸,即第二刻痕槽252为沿导电柱22的周向延伸的环形结构,也就是说,第二刻痕槽252环绕第二活性物质层25面向第一活性物质层24的表面的整周设置。当然,在其他实施例中,第二刻痕槽252也可以为沿第一方向X延伸的结构。The second notched groove 252 extends along the circumference of the conductive pillar 22, that is, the second notched groove 252 is an annular structure extending along the circumference of the conductive pillar 22, that is, the second notched groove 252 is arranged around the entire circumference of the surface of the second active material layer 25 facing the first active material layer 24. Of course, in other embodiments, the second notched groove 252 may also be a structure extending along the first direction X.
通过将第二刻痕槽252设置为沿导电柱22的周向延伸的环形结构,也就是说,第二刻痕槽252环绕第二活性物质层25整周设置,从而有利于提升第二刻痕槽252对电解液的容纳量,进而能够有效提升第一活性物质层24的保液能力,以保证第一活性物质层24的电解液的浸润效果。By setting the second notch groove 252 as an annular structure extending along the circumference of the conductive column 22, that is, the second notch groove 252 is set around the entire circumference of the second active material layer 25, it is beneficial to increase the capacity of the second notch groove 252 for the electrolyte, and thus can effectively improve the liquid retention capacity of the first active material layer 24, so as to ensure the wetting effect of the electrolyte of the first active material layer 24.
在一些实施例中,请继续参见图10所示,第二刻痕槽252为多个,多个第二刻痕槽252沿第一方向X间隔设置。In some embodiments, please continue to refer to FIG. 10 , there are a plurality of second notched grooves 252 , and the plurality of second notched grooves 252 are arranged along the first direction X at intervals.
其中,多个第二刻痕槽252沿第一方向X间隔设置,即多个第二刻痕槽252沿第一方向X排布。The plurality of second notch grooves 252 are arranged at intervals along the first direction X, that is, the plurality of second notch grooves 252 are arranged along the first direction X.
需要说明的是,若第二刻痕槽252为沿第一方向X延伸的结构,则多个第二刻痕槽252可以沿导电柱22的周向间隔排布。It should be noted that if the second notch grooves 252 are structures extending along the first direction X, a plurality of second notch grooves 252 may be arranged at intervals along the circumferential direction of the conductive pillar 22 .
通过将设置在第二活性物质层25的表面的第二刻痕槽252设置为多个,且多个第二刻痕槽252沿第一方向X间隔设置,从而有利于进一步提升第二活性物质层25的保液能力和电解液的浸润效果,以提升电池单体20的使用性能。By providing a plurality of second notched grooves 252 disposed on the surface of the second active material layer 25 , and the plurality of second notched grooves 252 are spaced apart along the first direction X, the liquid retention capacity of the second active material layer 25 and the electrolyte infiltration effect are further improved, thereby improving the performance of the battery cell 20 .
根据本申请的一些实施例,参见图3、图4和图5所示,端盖23包括盖本体231和极柱232。盖本体231盖合于开口212。极柱232绝缘安装于盖本体231上。其中,导电柱22连接于极柱232。According to some embodiments of the present application, as shown in FIG3, FIG4 and FIG5, the end cover 23 includes a cover body 231 and a pole 232. The cover body 231 covers the opening 212. The pole 232 is insulated and installed on the cover body 231. The conductive pole 22 is connected to the pole 232.
其中,端盖23的盖本体231上设置有极柱232,极柱232绝缘安装于盖本体231上,极柱232与导电柱22相连,以通过极柱232作为电池单体20的一个输出极。The cover body 231 of the end cover 23 is provided with a pole 232 , which is insulated and mounted on the cover body 231 . The pole 232 is connected to the conductive column 22 so as to serve as an output pole of the battery cell 20 through the pole 232 .
极柱232绝缘安装于盖本体231上,即极柱232与盖本体231之间未形成电连接,也就是说,极柱232和盖本体231之间设置有绝缘件,使得极柱232与盖本体231之间未形成电连接。The pole 232 is insulated and installed on the cover body 231 , that is, there is no electrical connection between the pole 232 and the cover body 231 , that is, an insulating member is provided between the pole 232 and the cover body 231 , so that there is no electrical connection between the pole 232 and the cover body 231 .
可选地,导电柱22与极柱232可以是一体式结构,也可以是分体式结构。若导电柱22与极柱232为一体式结构,则导电柱22与极柱232可以通过铸造或车削等工艺加工成型;若导电柱22与极柱232为分体式结构,则导电柱22与极柱232可以通过焊接、卡接或螺栓螺接等工艺进行装配连接。Optionally, the conductive column 22 and the pole 232 may be an integrated structure or a split structure. If the conductive column 22 and the pole 232 are an integrated structure, the conductive column 22 and the pole 232 may be formed by a process such as casting or turning; if the conductive column 22 and the pole 232 are a split structure, the conductive column 22 and the pole 232 may be assembled and connected by a process such as welding, clamping or bolting.
通过将导电柱22与绝缘安装于盖本体231上的极柱232相连,以通过极柱232实现电池单体20的电能的输入或输出,从而能够缓解导电柱22通过盖本体231与壳体21出现短接的现象,进而有利于减少电池单体20在使用过程中的安全隐患。By connecting the conductive column 22 with the pole 232 insulated and installed on the cover body 231, the input or output of electrical energy of the battery cell 20 can be realized through the pole 232, thereby alleviating the short circuit phenomenon between the conductive column 22 and the shell 21 through the cover body 231, which is beneficial to reduce the safety hazard of the battery cell 20 during use.
在一些实施例中,导电柱22与极柱232为一体成型结构。In some embodiments, the conductive column 22 and the electrode column 232 are integrally formed.
其中,导电柱22与极柱232为一体成型结构,即导电柱22与极柱232为一体式结构。The conductive column 22 and the pole 232 are an integrally formed structure, that is, the conductive column 22 and the pole 232 are an integrated structure.
在其他实施例中,极柱232与导电柱22也可以是分体式结构,导电柱22连接于极柱232上。示例性的,极柱232与导电柱22的连接方式可以是多种,可以是导电柱22直接连接于极柱232,比如,焊接或抵接等。当然,导电柱22也可以是与极柱232间接连接,比如,导电柱22先与其他部件相互焊接或抵接后,再与极柱232相互焊接或抵接。In other embodiments, the pole 232 and the conductive column 22 may also be a split structure, and the conductive column 22 is connected to the pole 232. Exemplarily, the pole 232 and the conductive column 22 may be connected in a variety of ways, and the conductive column 22 may be directly connected to the pole 232, such as welding or abutting. Of course, the conductive column 22 may also be indirectly connected to the pole 232, such as the conductive column 22 is first welded or abutted with other components, and then welded or abutted with the pole 232.
通过将导电柱22与极柱232设置为一体成型的结构,采用这种结构的电池单体20一方面有利于提升导电柱22与极柱232之间的连接稳定性和可靠性,以保证导流面积,另一方面便于将导电柱22和端盖23整体与壳体21进行装配,有利于降低电池单体20的装配难度,以提升电池单体20的装配效率。By configuring the conductive column 22 and the pole 232 as an integrally formed structure, the battery cell 20 adopting such a structure is beneficial to improving the connection stability and reliability between the conductive column 22 and the pole 232 to ensure the flow conduction area, and is also convenient for assembling the conductive column 22 and the end cover 23 as a whole with the shell 21, which is beneficial to reducing the difficulty of assembling the battery cell 20 and improving the assembly efficiency of the battery cell 20.
根据本申请的一些实施例,参见图4和图5所示,第一活性物质层24为负极活性物质层,第二活性物质层25为正极活性物质层。According to some embodiments of the present application, referring to FIG. 4 and FIG. 5 , the first active material layer 24 is a negative electrode active material layer, and the second active material layer 25 is a positive electrode active material layer.
当然,在其他实施例中,第一活性物质层24也可以为正极活性物质层,对应的,第二活性物质层25为负极活性物质层。Of course, in other embodiments, the first active material layer 24 may also be a positive electrode active material layer, and correspondingly, the second active material layer 25 is a negative electrode active material layer.
设置在壳体21面向容纳腔211的一侧上的第一活性物质层24为负极活性物质层,对应的,设置在导电柱22的外周面上的第二活性物质层25为正极活性物质层,以使负极活性物质层能够包覆在正极活性物质层的外侧,采用这种结构的电池单体20能够有效降低析锂的风险,以提升电池单体20的使用安全性。The first active material layer 24 arranged on the side of the shell 21 facing the accommodating cavity 211 is a negative electrode active material layer, and correspondingly, the second active material layer 25 arranged on the outer peripheral surface of the conductive column 22 is a positive electrode active material layer, so that the negative electrode active material layer can be coated on the outside of the positive electrode active material layer. The battery cell 20 adopting this structure can effectively reduce the risk of lithium plating to improve the safety of the battery cell 20.
根据本申请的一些实施例,请参见图4和图5所示,电池单体20还包括隔离膜26。隔离膜26设置于第一活性物质层24与第二活性物质层25之间,以分隔第一活性物质层24和第二活性物质层25。According to some embodiments of the present application, as shown in FIG4 and FIG5 , the battery cell 20 further includes a separator 26 . The separator 26 is disposed between the first active material layer 24 and the second active material layer 25 to separate the first active material layer 24 and the second active material layer 25 .
其中,在第一活性物质层24和第二活性物质层25均为沿导电柱22的周向延伸的实施例中,隔离膜26则为沿导电柱22的周向延伸的环形结构,即隔离膜26包覆于第二活性物质层25的外周侧,以使隔离膜26能够对第一活性物质层24和第二活性物质层25进行有效分隔。Among them, in the embodiment where both the first active material layer 24 and the second active material layer 25 extend along the circumference of the conductive column 22, the isolation membrane 26 is an annular structure extending along the circumference of the conductive column 22, that is, the isolation membrane 26 is coated on the outer peripheral side of the second active material layer 25, so that the isolation membrane 26 can effectively separate the first active material layer 24 and the second active material layer 25.
示例性的,隔离膜26的材质可以为聚丙烯(polypropylene,PP)或聚乙烯(polyethylene,PE)等。For example, the material of the isolation film 26 may be polypropylene (PP) or polyethylene (PE).
在一些实施例中,隔离膜26的形状与第二活性物质层25的外周面相互契合,即隔离膜26的形状与第二活性物质层25的外周面的形状相同,参见图6所示,若第二活性物质层25的外周面垂直于第一方向X的横截面为圆形,则隔离膜26为圆柱状中空结构;参见图7所示,若第二活性物质层25的外周面垂直于第一方向X的横截面为六边形,则隔离膜26为六棱柱中空结构。In some embodiments, the shape of the isolation membrane 26 matches the outer peripheral surface of the second active material layer 25, that is, the shape of the isolation membrane 26 is the same as the shape of the outer peripheral surface of the second active material layer 25. As shown in FIG6, if the cross-section of the outer peripheral surface of the second active material layer 25 perpendicular to the first direction X is circular, the isolation membrane 26 is a cylindrical hollow structure; as shown in FIG7, if the cross-section of the outer peripheral surface of the second active material layer 25 perpendicular to the first direction X is hexagonal, the isolation membrane 26 is a hexagonal hollow structure.
电池单体20还设置有位于第一活性物质层24和第二活性物质层25之间的隔离膜26,从而能够有效实现第一活性物质层24和第二活性物质层25之间的绝缘隔离,以降低第一活性物质层24和第二活性物质层25出现短接的现象,进而有利于降低电极组件在使用过程中的安全隐患。The battery cell 20 is also provided with an isolation membrane 26 located between the first active material layer 24 and the second active material layer 25, so as to effectively realize the insulation isolation between the first active material layer 24 and the second active material layer 25, so as to reduce the short circuit phenomenon between the first active material layer 24 and the second active material layer 25, thereby helping to reduce the safety hazards of the electrode assembly during use.
根据本申请的一些实施例,本申请实施例还提供了一种电池100,电池100包括以上任一方案的电池单体20。According to some embodiments of the present application, a battery 100 is further provided, and the battery 100 includes a battery cell 20 of any of the above schemes.
根据本申请的一些实施例,本申请实施例还提供了一种用电装置,用电装置包括以上任一方案的电池单体20,并且电池单体20用于为用电装置提供电能;或,用电装置包括以上任一方案的电池100,并且电池100用于为用电装置提供电能。According to some embodiments of the present application, the embodiments of the present application also provide an electrical device, which includes a battery cell 20 of any of the above schemes, and the battery cell 20 is used to provide electrical energy to the electrical device; or, the electrical device includes a battery 100 of any of the above schemes, and the battery 100 is used to provide electrical energy to the electrical device.
用电装置可以是前述任一应用电池单体20或电池100的设备或系统。The electrical device may be any of the aforementioned devices or systems using the battery cell 20 or the battery 100 .
根据本申请的一些实施例,参见图3至图4以及图8至图11所示,本申请提供了一种电池单体20,电池单体20包括壳体21、导电柱22、端盖23、隔离膜26。According to some embodiments of the present application, referring to FIGS. 3 to 4 and 8 to 11 , the present application provides a battery cell 20 , which includes a housing 21 , a conductive column 22 , an end cover 23 , and an isolation membrane 26 .
壳体21的内部形成有容纳腔211,沿第一方向X,壳体21的一端设置有与容纳腔211连通的开口212,壳体21面向容纳腔211的表面设置有第一活性物质层24,第一活性物质层24为负极活性物质层。壳体21为柱状结构,壳体21的中心轴线沿第一方向X延伸,沿第一方向X,壳体21的长度为L,壳体21垂直于第一方向X的横截面在垂直于第一方向X上的最大尺寸为D 1,满足,L≥D 1。导电柱22沿第一方向X延伸并插设于容纳腔211内,导电柱22的外周面上设置有第二活性物质层25,第二活性物质层25与第一活性物质层24面向设置,第二活性物质层25为正极活性物质层。端盖23包括盖本体231和极柱232,盖本体231盖合于开口212,极柱232绝缘安装于盖本体231上,导电柱22与极柱232为一体成型结构。隔离膜26设置于第一活性物质层24与第二活性物质层25之间,以分隔第一活性物质层24和第二活性物质层25。其中,第一活性物质层24和第二活性物质层25均为沿导电柱22的周向延伸的环形结构,第一活性物质层24沿导电柱22的周向围合形成供导电柱22插入的安装通道241,安装通道241垂直于第一方向X的横截面为圆形,安装通道241的内表面与第二活性物质层25的外周面相互契合。第一活性物质层24包括两个第一反应层242,两个第一反应层242沿导电柱的径向Y层叠设置,沿导电柱的径向Y,两个第一反应层242中靠近第二活性物质层25的第一反应层242的密度小于另一个第一反应层242的密度,且两个第一反应层242中靠近第二活性物质层25的第一反应层242的颗粒直径小于另一个第一反应层242的颗粒直径。第二活性物质层25包括两个第二反应层251,两个第二反应层251沿导电柱的径向Y层叠设置,沿导电柱的径向Y,两个第二反应层251中靠近第一活性物质层24的第二反应层251的密度小于另一个第二反应层251的密度,且两个第二反应层251中靠近第一活性物质层24的第二反应层251的颗粒直径小于另一个第二反应层251的颗粒直径。第一活性物质层24面向第二活性物质层25的表面设置有多个第一刻痕槽243,第一刻痕槽243用于容纳电解液,第一活性物质层24为沿导电柱22的周向延伸的环形结构,且多个第一刻痕槽243沿第一方向X间隔设置。第二活性物质层25面向第一活性物质层24的表面设置有多个第二刻痕槽252,第二刻痕槽252用于容纳电解液,第二活性物质层25为沿导电柱22的周向延伸的环形结构,且多个第二刻痕槽252沿第一方向X间隔设置。 The housing 21 has a receiving cavity 211 formed inside. An opening 212 communicating with the receiving cavity 211 is provided at one end of the housing 21 along the first direction X. A first active material layer 24 is provided on the surface of the housing 21 facing the receiving cavity 211. The first active material layer 24 is a negative electrode active material layer. The housing 21 is a columnar structure. The central axis of the housing 21 extends along the first direction X. The length of the housing 21 along the first direction X is L. The maximum dimension of the cross section of the housing 21 perpendicular to the first direction X in the direction perpendicular to the first direction X is D 1 , satisfying L ≥ D 1 . The conductive column 22 extends along the first direction X and is inserted into the receiving cavity 211. A second active material layer 25 is provided on the outer peripheral surface of the conductive column 22. The second active material layer 25 faces the first active material layer 24. The second active material layer 25 is a positive electrode active material layer. The end cover 23 includes a cover body 231 and a pole 232. The cover body 231 covers the opening 212. The pole 232 is insulated and installed on the cover body 231. The conductive column 22 and the pole 232 are an integrally formed structure. The isolation membrane 26 is arranged between the first active material layer 24 and the second active material layer 25 to separate the first active material layer 24 and the second active material layer 25. Among them, the first active material layer 24 and the second active material layer 25 are both annular structures extending along the circumference of the conductive column 22. The first active material layer 24 is surrounded along the circumference of the conductive column 22 to form an installation channel 241 for inserting the conductive column 22. The cross section of the installation channel 241 perpendicular to the first direction X is circular, and the inner surface of the installation channel 241 fits with the outer peripheral surface of the second active material layer 25. The first active material layer 24 includes two first reaction layers 242, which are stacked along the radial direction Y of the conductive column. Along the radial direction Y of the conductive column, the density of the first reaction layer 242 close to the second active material layer 25 of the two first reaction layers 242 is less than the density of the other first reaction layer 242, and the particle diameter of the first reaction layer 242 close to the second active material layer 25 of the two first reaction layers 242 is smaller than the particle diameter of the other first reaction layer 242. The second active material layer 25 includes two second reaction layers 251, which are stacked along the radial direction Y of the conductive column. Along the radial direction Y of the conductive column, the density of the second reaction layer 251 close to the first active material layer 24 of the two second reaction layers 251 is less than the density of the other second reaction layer 251, and the particle diameter of the second reaction layer 251 close to the first active material layer 24 of the two second reaction layers 251 is smaller than the particle diameter of the other second reaction layer 251. A plurality of first notched grooves 243 are provided on the surface of the first active material layer 24 facing the second active material layer 25. The first notched grooves 243 are used to contain electrolyte. The first active material layer 24 is an annular structure extending along the circumference of the conductive pillar 22, and the plurality of first notched grooves 243 are arranged at intervals along the first direction X. A plurality of second notched grooves 252 are provided on the surface of the second active material layer 25 facing the first active material layer 24. The second notched grooves 252 are used to contain electrolyte. The second active material layer 25 is an annular structure extending along the circumference of the conductive pillar 22, and the plurality of second notched grooves 252 are arranged at intervals along the first direction X.
根据本申请的一些实施例,本申请实施例还提供了一种电池单体20的制造方法,参照图12,图12为本申请一些实施例提供的电池单体20的制造方法的流程示意图,该制造方法包括:According to some embodiments of the present application, the present application also provides a method for manufacturing a battery cell 20. Referring to FIG. 12, FIG. 12 is a schematic flow chart of a method for manufacturing a battery cell 20 provided in some embodiments of the present application. The manufacturing method includes:
S100:提供壳体21、导电柱22和端盖23,壳体21的内部形成有容纳腔211,沿第一方向X,壳体21的一端设置有与容纳腔211连通的开口212,导电柱22沿第一方向X延伸;S100: providing a housing 21, a conductive column 22 and an end cover 23, wherein a receiving cavity 211 is formed inside the housing 21, and an opening 212 communicating with the receiving cavity 211 is provided at one end of the housing 21 along a first direction X, and the conductive column 22 extends along the first direction X;
S200:在壳体21面向容纳腔211的一侧设置第一活性物质层24;S200: Disposing a first active material layer 24 on a side of the housing 21 facing the receiving cavity 211;
S300:将导电柱22与端盖23相连;S300: Connect the conductive column 22 to the end cap 23;
S400:在导电柱22的外周面上设置第二活性物质层25,第二活性物质层25与第一活性物质层24的极性相反;S400: Disposing a second active material layer 25 on the outer peripheral surface of the conductive column 22, wherein the second active material layer 25 has a polarity opposite to that of the first active material layer 24;
S500:将导电柱22沿第一方向X插设于壳体21的容纳腔211内,以使第一活性物质层24与第二活性物质层25面向设置,并使端盖23盖合于开口212。S500 : inserting the conductive pillar 22 into the accommodating cavity 211 of the housing 21 along the first direction X so that the first active material layer 24 and the second active material layer 25 face each other, and the end cover 23 covers the opening 212 .
其中,在步骤S200中,第一活性物质层24为直接涂覆于壳体21面向容纳腔211的表面上,即第一活性物质层24涂覆于容纳腔211的腔壁面上。当然,在一些实施例中,也可以是先将第一活性物质层24涂覆于金属箔制成的集流体上,在将涂覆有第一活性物质层24的集流体设置于壳体21的容纳腔211内,并将集流体连接于壳体21面向容纳腔211的表面上。In step S200, the first active material layer 24 is directly coated on the surface of the housing 21 facing the accommodating cavity 211, that is, the first active material layer 24 is coated on the cavity wall of the accommodating cavity 211. Of course, in some embodiments, the first active material layer 24 may be first coated on a current collector made of metal foil, and then the current collector coated with the first active material layer 24 is arranged in the accommodating cavity 211 of the housing 21, and the current collector is connected to the surface of the housing 21 facing the accommodating cavity 211.
在步骤S500中,将导电柱22沿第一方向X插设于壳体21的容纳腔211内,即将设置有第二活性物质层25的导电柱22沿第一方向X插设于壳体21的容纳腔211内,以使第一活性物质层24与第二活性物质层25在导电柱的径向Y上面向设置。In step S500, the conductive column 22 is inserted into the accommodating cavity 211 of the shell 21 along the first direction X, that is, the conductive column 22 provided with the second active material layer 25 is inserted into the accommodating cavity 211 of the shell 21 along the first direction X, so that the first active material layer 24 and the second active material layer 25 are arranged facing each other in the radial direction Y of the conductive column.
示例性的,第一活性物质层24采用干法涂覆工艺涂覆于壳体21面向容纳腔211的表面上。同样的,第二活性物质层25采用干法涂覆工艺涂覆于导电柱22的外周面上。Exemplarily, the first active material layer 24 is coated on the surface of the housing 21 facing the receiving cavity 211 by a dry coating process. Similarly, the second active material layer 25 is coated on the outer peripheral surface of the conductive column 22 by a dry coating process.
在上述制造方法中,通过先在壳体21面向容纳腔211的一侧上设置第一活性物质层24,并将导电柱22 与端盖23相连后在导电柱22的外周面上设置第二活性物质层25,之后再将设置有第二活性物质层25的导电柱22沿第一方向X插设于壳体21的容纳腔211内,以实现第一活性物质层24与第二活性物质层25面向设置,并同时将端盖23与开口212相互盖合,从而完成电池单体20的装配制造,采用这种制造方法制造的电池单体20无需对极片进行卷绕,且节省了集流构件与极耳相互装配连接的工艺,进而极大地优化了电池单体20的生产工艺和生产节拍,有利于提升电池单体20的生产效率。In the above manufacturing method, a first active material layer 24 is firstly arranged on a side of the shell 21 facing the accommodating cavity 211, and the second active material layer 25 is arranged on the outer peripheral surface of the conductive column 22 after the conductive column 22 is connected to the end cover 23. Then, the conductive column 22 provided with the second active material layer 25 is inserted into the accommodating cavity 211 of the shell 21 along the first direction X, so that the first active material layer 24 and the second active material layer 25 are arranged facing each other, and at the same time, the end cover 23 and the opening 212 are covered with each other, thereby completing the assembly and manufacturing of the battery cell 20. The battery cell 20 manufactured by this manufacturing method does not need to wind the pole piece, and saves the process of assembling and connecting the current collecting component and the pole ear, thereby greatly optimizing the production process and production rhythm of the battery cell 20, which is conducive to improving the production efficiency of the battery cell 20.
根据本申请的一些实施例,参照图13,图13为本申请又一些实施例提供的电池单体20的制造方法的流程示意图。电池单体20的制造方法还包括:According to some embodiments of the present application, referring to FIG. 13 , FIG. 13 is a schematic flow chart of a method for manufacturing a battery cell 20 provided in some embodiments of the present application. The method for manufacturing the battery cell 20 further includes:
S600:提供隔离膜26;S600: providing an isolation film 26;
在步骤S500将导电柱22沿第一方向X插设于壳体21的容纳腔211内,以使第一活性物质层24与第二活性物质层25面向设置,并使端盖23盖合于开口212之前,电池单体20的制造方法还包括:Before the conductive pillar 22 is inserted into the receiving cavity 211 of the housing 21 along the first direction X in step S500 so that the first active material layer 24 and the second active material layer 25 face each other and the end cover 23 is covered on the opening 212, the manufacturing method of the battery cell 20 further includes:
S700:将隔离膜26包覆于第二活性物质层25的外侧。S700 : Covering the separator 26 on the outer side of the second active material layer 25 .
其中,在步骤S700之后进行步骤S500,即表示将设置有第二活性物质层25并包覆有隔离膜26的导电柱22沿第一方向X插设于壳体21的容纳腔211内,以使第一活性物质层24与第二活性物质层25面向设置,且使得隔离膜26位于第一活性物质层24和第二活性物质层25之间。Among them, step S500 is performed after step S700, which means that the conductive column 22 provided with the second active material layer 25 and coated with the isolation film 26 is inserted into the accommodating cavity 211 of the shell 21 along the first direction X, so that the first active material layer 24 and the second active material layer 25 are arranged facing each other, and the isolation film 26 is located between the first active material layer 24 and the second active material layer 25.
需要说明的是,在图13中,步骤S600设置于步骤S400之后,当然,在一些实施例中,步骤S600可以是在步骤S700之前的任一步骤的前后均可。It should be noted that, in FIG. 13 , step S600 is arranged after step S400 . Of course, in some embodiments, step S600 may be arranged before or after any step before step S700 .
在上述的制造方法中,在将设置有第二活性物质层25的导电柱22插设于壳体21的容纳腔211内之前先在第二活性物质层25外侧包覆隔离膜26,使得导电柱22在插设于壳体21的容纳腔211内时能够同时将隔离膜26装配至壳体21内,并实现隔离膜26设置于第一活性物质层24和第二活性物质层25之间,采用这种制造方法一方面能够提升隔离膜26的装配效率,另一方面有利于降低隔离膜26的装配难度。In the above-mentioned manufacturing method, before the conductive column 22 provided with the second active material layer 25 is inserted into the accommodating cavity 211 of the shell 21, the isolation membrane 26 is first coated on the outside of the second active material layer 25, so that when the conductive column 22 is inserted into the accommodating cavity 211 of the shell 21, the isolation membrane 26 can be assembled into the shell 21 at the same time, and the isolation membrane 26 can be arranged between the first active material layer 24 and the second active material layer 25. This manufacturing method can improve the assembly efficiency of the isolation membrane 26 on the one hand, and reduce the difficulty of assembling the isolation membrane 26 on the other hand.
需要说明的是,通过上述各实施例提供的制造方法制造的电池单体20的相关结构,可参见前述各实施例提供的电池单体20,在此不再赘述。It should be noted that the relevant structure of the battery cell 20 manufactured by the manufacturing method provided by the above embodiments can refer to the battery cell 20 provided by the above embodiments, and will not be described again here.
需要说明的是,在不冲突的情况下,本申请中的实施例及实施例中的特征可以相互结合。It should be noted that, in the absence of conflict, the embodiments and features in the embodiments of the present application may be combined with each other.
以上仅为本申请的优选实施例而已,并不用于限制本申请,对于本领域的技术人员来说,本申请可以有各种更改和变化。凡在本申请的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本申请的保护范围之内。The above are only preferred embodiments of the present application and are not intended to limit the present application. For those skilled in the art, the present application may have various modifications and variations. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present application shall be included in the protection scope of the present application.

Claims (29)

  1. 一种电池单体,包括:A battery cell, comprising:
    壳体,内部形成有容纳腔,沿第一方向,所述壳体的一端设置有与所述容纳腔连通的开口,所述壳体面向所述容纳腔的一侧设置有第一活性物质层;A shell having a receiving cavity formed therein, one end of the shell being provided with an opening communicating with the receiving cavity along a first direction, and a first active material layer being provided on a side of the shell facing the receiving cavity;
    导电柱,沿所述第一方向延伸并插设于所述容纳腔内,所述导电柱的外周面上设置有第二活性物质层,所述第二活性物质层与所述第一活性物质层面向设置,且所述第二活性物质层与所述第一活性物质层的极性相反;以及a conductive column extending along the first direction and inserted into the accommodating cavity, wherein a second active material layer is disposed on an outer peripheral surface of the conductive column, the second active material layer and the first active material layer are disposed facing each other, and the second active material layer and the first active material layer have opposite polarities; and
    端盖,盖合于所述开口,并与所述导电柱相连。The end cover covers the opening and is connected to the conductive column.
  2. 根据权利要求1所述的电池单体,其中,所述第一活性物质层涂覆于所述壳体面向所述容纳腔的表面上。The battery cell according to claim 1, wherein the first active material layer is coated on a surface of the shell facing the accommodating cavity.
  3. 根据权利要求1或2所述的电池单体,其中,所述壳体为柱状结构,所述壳体的中心轴线沿所述第一方向延伸。The battery cell according to claim 1 or 2, wherein the shell is a columnar structure, and the central axis of the shell extends along the first direction.
  4. 根据权利要求3所述的电池单体,其中,沿所述第一方向,所述壳体的长度为L,所述壳体垂直于所述第一方向的横截面在垂直于所述第一方向上的最大尺寸为D 1,满足,L≥D 1The battery cell according to claim 3, wherein along the first direction, the length of the shell is L, the maximum dimension of the cross section of the shell perpendicular to the first direction is D 1 , and L ≥ D 1 is satisfied.
  5. 根据权利要求4所述的电池单体,其中,1.5≤L/D 1;和/或 The battery cell according to claim 4, wherein 1.5≤L/D 1 ; and/or
    L/D 1≤25。 L/ D1 ≤25.
  6. 根据权利要求1-5任一项所述的电池单体,其中,所述第一活性物质层和所述第二活性物质层均为沿所述导电柱的周向延伸的环形结构。The battery cell according to any one of claims 1 to 5, wherein the first active material layer and the second active material layer are both annular structures extending along the circumference of the conductive column.
  7. 根据权利要求6所述的电池单体,其中,所述第一活性物质层沿所述导电柱的周向围合形成供所述导电柱插入的安装通道,所述安装通道的内表面与所述第二活性物质层的外周面相互契合。The battery cell according to claim 6, wherein the first active material layer surrounds the conductive column along the circumference to form a mounting channel for inserting the conductive column, and the inner surface of the mounting channel fits with the outer circumferential surface of the second active material layer.
  8. 根据权利要求7所述的电池单体,其中,所述安装通道垂直于所述第一方向的横截面为圆形。The battery cell according to claim 7, wherein a cross section of the mounting channel perpendicular to the first direction is circular.
  9. 根据权利要求1-8任一项所述的电池单体,其中,所述第一活性物质层包括多个第一反应层,多个所述第一反应层沿所述导电柱的径向层叠设置。The battery cell according to any one of claims 1 to 8, wherein the first active material layer comprises a plurality of first reaction layers, and the plurality of first reaction layers are stacked along the radial direction of the conductive column.
  10. 根据权利要求9所述的电池单体,其中,沿所述导电柱的径向,多个所述第一反应层中靠近所述第二活性物质层的所述第一反应层的密度小于其他所述第一反应层的密度。The battery cell according to claim 9, wherein along the radial direction of the conductive column, the density of the first reaction layer close to the second active material layer among the plurality of first reaction layers is less than the density of the other first reaction layers.
  11. 根据权利要求9或10所述的电池单体,其中,沿所述导电柱的径向,多个所述第一反应层中靠近所述第二活性物质层的所述第一反应层的颗粒直径小于其他所述第一反应层的颗粒直径。The battery cell according to claim 9 or 10, wherein, along the radial direction of the conductive column, a particle diameter of the first reaction layer close to the second active material layer among the plurality of first reaction layers is smaller than a particle diameter of other first reaction layers.
  12. 根据权利要求9-11任一项所述的电池单体,其中,所述第一活性物质层的所述第一反应层的数量为N 1,满足,2≤N 1≤3。 The battery cell according to any one of claims 9 to 11, wherein the number of the first reaction layers of the first active material layer is N 1 , satisfying 2≤N 1 ≤3.
  13. 根据权利要求1-12任一项所述的电池单体,其中,所述第二活性物质层包括多个第二反应层,多个所述第二反应层沿所述导电柱的径向层叠设置。The battery cell according to any one of claims 1 to 12, wherein the second active material layer comprises a plurality of second reaction layers, and the plurality of second reaction layers are stacked along the radial direction of the conductive column.
  14. 根据权利要求13所述的电池单体,其中,沿所述导电柱的径向,多个所述第二反应层中靠近所述第一活性物质层的所述第二反应层的密度小于其他所述第二反应层的密度。The battery cell according to claim 13, wherein, along the radial direction of the conductive column, the density of the second reaction layer close to the first active material layer among the plurality of second reaction layers is less than the density of other second reaction layers.
  15. 根据权利要求13或14所述的电池单体,其中,沿所述导电柱的径向,多个所述第二反应层中靠近所述第一活性物质层的所述第二反应层的颗粒直径小于其他所述第二反应层的颗粒直径。The battery cell according to claim 13 or 14, wherein, along the radial direction of the conductive column, a particle diameter of the second reaction layer close to the first active material layer among the plurality of second reaction layers is smaller than a particle diameter of other second reaction layers.
  16. 根据权利要求13-15任一项所述的电池单体,其中,所述第二活性物质层的所述第二反应层的数量为N 2,满足,2≤N 2≤3。 The battery cell according to any one of claims 13 to 15, wherein the number of the second reaction layers in the second active material layer is N 2 , satisfying 2≤N 2 ≤3.
  17. 根据权利要求1-16任一项所述的电池单体,其中,所述第一活性物质层面向所述第二活性物质层的表面设置有第一刻痕槽,所述第一刻痕槽用于容纳电解液;和/或The battery cell according to any one of claims 1 to 16, wherein a first notch groove is provided on a surface of the first active material layer facing the second active material layer, and the first notch groove is used to accommodate an electrolyte; and/or
    所述第二活性物质层面向所述第一活性物质层的表面设置有第二刻痕槽,所述第二刻痕槽用于容纳电解液。A second notch groove is provided on a surface of the second active material layer facing the first active material layer, and the second notch groove is used to contain an electrolyte.
  18. 根据权利要求17所述的电池单体,其中,所述第一活性物质层为沿所述导电柱的周向延伸的环形结构,所述第一刻痕槽沿所述导电柱的周向延伸。The battery cell according to claim 17, wherein the first active material layer is an annular structure extending along the circumference of the conductive column, and the first notch groove extends along the circumference of the conductive column.
  19. 根据权利要求18所述的电池单体,其中,所述第一刻痕槽为多个,多个所述第一刻痕槽沿所述第一方向间隔设置。The battery cell according to claim 18, wherein the number of the first notch grooves is plural, and the plurality of the first notch grooves are spaced apart along the first direction.
  20. 根据权利要求17-19任一项所述的电池单体,其中,所述第二活性物质层为沿所述导电柱的周向延伸的环形结构,所述第二刻痕槽沿所述导电柱的周向延伸。The battery cell according to any one of claims 17 to 19, wherein the second active material layer is an annular structure extending along the circumference of the conductive column, and the second notch groove extends along the circumference of the conductive column.
  21. 根据权利要求20所述的电池单体,其中,所述第二刻痕槽为多个,多个所述第二刻痕槽沿所述第一方向间隔设置。The battery cell according to claim 20, wherein the number of the second notch grooves is plural, and the plurality of the second notch grooves are spaced apart along the first direction.
  22. 根据权利要求1-21任一项所述的电池单体,其中,所述端盖包括:The battery cell according to any one of claims 1 to 21, wherein the end cover comprises:
    盖本体,盖合于所述开口;A cover body, covering the opening;
    极柱,绝缘安装于所述盖本体上;A pole, insulated and mounted on the cover body;
    其中,所述导电柱连接于所述极柱。Wherein, the conductive column is connected to the pole.
  23. 根据权利要求22所述的电池单体,其中,所述导电柱与所述极柱为一体成型结构。The battery cell according to claim 22, wherein the conductive column and the electrode column are an integrally formed structure.
  24. 根据权利要求1-23任一项所述的电池单体,其中,所述第一活性物质层为负极活性物质层,所述第二活性物质层为正极活性物质层。The battery cell according to any one of claims 1 to 23, wherein the first active material layer is a negative electrode active material layer, and the second active material layer is a positive electrode active material layer.
  25. 根据权利要求1-24任一项所述的电池单体,其中,所述电池单体还包括:The battery cell according to any one of claims 1 to 24, wherein the battery cell further comprises:
    隔离膜,设置于所述第一活性物质层与所述第二活性物质层之间,以分隔所述第一活性物质层和所述第二活性物质层。The isolation film is disposed between the first active material layer and the second active material layer to separate the first active material layer from the second active material layer.
  26. 一种电池,包括如权利要求1-25任一项所述的电池单体。A battery comprising the battery cell according to any one of claims 1 to 25.
  27. 一种用电装置,包括如权利要求1-25任一项所述的电池单体,所述电池单体用于提供电能;或An electrical device, comprising a battery cell according to any one of claims 1 to 25, wherein the battery cell is used to provide electrical energy; or
    包括如权利要求26所述的电池,所述电池用于提供电能。Comprising a battery as claimed in claim 26, the battery is used to provide electrical energy.
  28. 一种电池单体的制造方法,包括:A method for manufacturing a battery cell, comprising:
    提供壳体、导电柱和端盖,所述壳体的内部形成有容纳腔,沿第一方向,所述壳体的一端设置有与所述容纳腔连通的开口,所述导电柱沿所述第一方向延伸;A housing, a conductive column and an end cover are provided, wherein a receiving cavity is formed inside the housing, an opening communicating with the receiving cavity is provided at one end of the housing along a first direction, and the conductive column extends along the first direction;
    在所述壳体面向所述容纳腔的一侧设置第一活性物质层;A first active material layer is disposed on a side of the shell facing the accommodating cavity;
    将所述导电柱与所述端盖相连;connecting the conductive column to the end cap;
    在所述导电柱的外周面上设置第二活性物质层,所述第二活性物质层与所述第一活性物质层的极性相反;Disposing a second active material layer on the outer peripheral surface of the conductive column, wherein the second active material layer has a polarity opposite to that of the first active material layer;
    将所述导电柱沿所述第一方向插设于所述壳体的所述容纳腔内,以使所述第一活性物质层与所述第二活性物质层面向设置,并使所述端盖盖合于所述开口。The conductive column is inserted into the accommodating cavity of the shell along the first direction, so that the first active material layer and the second active material layer are arranged facing each other, and the end cover is covered on the opening.
  29. 根据权利要求28所述的电池单体的制造方法,其中,所述电池单体的制造方法还包括:The method for manufacturing a battery cell according to claim 28, wherein the method for manufacturing a battery cell further comprises:
    提供隔离膜;Provide isolation film;
    在所述将所述导电柱沿所述第一方向插设于所述壳体的所述容纳腔内,以使所述第一活性物质层与所述第二活性物质层面向设置,并使所述端盖盖合于所述开口之前,所述电池单体的制造方法还包括:Before inserting the conductive column into the accommodating cavity of the housing along the first direction so that the first active material layer and the second active material layer are arranged facing each other and the end cover is closed on the opening, the manufacturing method of the battery cell further includes:
    将所述隔离膜包覆于所述第二活性物质层的外侧。The isolation film is coated on the outer side of the second active material layer.
PCT/CN2022/127083 2022-10-24 2022-10-24 Battery cell and manufacturing method therefor, battery, and electrical device WO2024086981A1 (en)

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