WO2024080947A1 - The development of a hydrophobic solution comprising boron nitride - Google Patents
The development of a hydrophobic solution comprising boron nitride Download PDFInfo
- Publication number
- WO2024080947A1 WO2024080947A1 PCT/TR2022/051711 TR2022051711W WO2024080947A1 WO 2024080947 A1 WO2024080947 A1 WO 2024080947A1 TR 2022051711 W TR2022051711 W TR 2022051711W WO 2024080947 A1 WO2024080947 A1 WO 2024080947A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- boron nitride
- composition according
- nanoparticles
- boron
- development
- Prior art date
Links
- 230000002209 hydrophobic effect Effects 0.000 title claims abstract description 13
- 229910052582 BN Inorganic materials 0.000 title claims description 13
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 title claims description 13
- 239000000463 material Substances 0.000 claims abstract description 21
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 14
- 238000000576 coating method Methods 0.000 claims abstract description 8
- 239000011248 coating agent Substances 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 15
- 239000002105 nanoparticle Substances 0.000 claims description 11
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 5
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 5
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 5
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 5
- 239000005642 Oleic acid Substances 0.000 claims description 5
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 5
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 5
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical group CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 150000004767 nitrides Chemical class 0.000 claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims description 3
- 150000004706 metal oxides Chemical class 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims 3
- 239000004094 surface-active agent Substances 0.000 claims 3
- 230000006641 stabilisation Effects 0.000 claims 1
- 238000011105 stabilization Methods 0.000 claims 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract description 12
- 229910052796 boron Inorganic materials 0.000 abstract description 10
- 239000002086 nanomaterial Substances 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000005871 repellent Substances 0.000 description 10
- 230000002940 repellent Effects 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000004753 textile Substances 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 238000007654 immersion Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000007790 scraping Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- SKKMWRVAJNPLFY-UHFFFAOYSA-N azanylidynevanadium Chemical compound [V]#N SKKMWRVAJNPLFY-UHFFFAOYSA-N 0.000 description 1
- -1 boron nitride compound Chemical class 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000004807 localization Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- ZVWKZXLXHLZXLS-UHFFFAOYSA-N zirconium nitride Chemical compound [Zr]#N ZVWKZXLXHLZXLS-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/06—Binary compounds of nitrogen with metals, with silicon, or with boron, or with carbon, i.e. nitrides; Compounds of nitrogen with more than one metal, silicon or boron
- C01B21/064—Binary compounds of nitrogen with metals, with silicon, or with boron, or with carbon, i.e. nitrides; Compounds of nitrogen with more than one metal, silicon or boron with boron
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
Definitions
- the present invention relates to the development of a hydrophobic material comprising boron nanomaterials.
- a material with hydrophobic properties and a material with antibacterial properties are offered for use in combination by creating an antibacterial and water-repellent coating for textile products with a boron structure that can be produced from domestic boron mines.
- an antibacterial and water repellent coating for textile products can be created using a boron structure that can be produced from domestic boron mines.
- a material with a high localization rate from the raw material source to the final product will become possible and a material with hydrophobic properties and a material with anti-bacterial properties will also be offered for use in combination.
- This mixture of materials can be coated on the material deemed appropriate as a suspended solution using spray, immersion, or doctor blade (scraping) methods.
- spray, immersion, or doctor blade (scraping) methods In existing systems, there is no precedent product that is both boron-sourced and offers the two features in combination. It is anticipated that the invention will be demanded in the market and will provide added value to the Turkish economy as it is both functional (antibacterial and water repellent) and sustainable.
- BORON NITRIDE (1 mmol): It is used as the main material with its water repellent and antibacterial coating agent properties. Although boron nitride structures with different properties and crystal structures can be used, hexagonal boron nitride (h-BN) is preferably used in the invention. Boron nitride is preferred due to its hydrophobic and antibacterial properties.
- OLEIC ACID (5 mmol): It is used as a hydrophobic (water repellent) property enhancer and as a material surrounding the boron nitride compound.
- 2-propenoic acid can also be used in the same proportions.
- the main reason for preferably using oleic acid is to increase hydrophobicity.
- Oleic acid which is water repellent at the molecular level, is placed around the boron nitride material to improve its water repellency capacity and persistence since the water repellency of boron nitride alone does not reach the desired levels.
- several oil acids or acrylic acid derivatives can be used to increase the water repellency of boron nitride.
- n-HEXANE (10 ml) It is used as a solvent.
- dodecan-l-ol can also be used in the same proportions in an alternative embodiment of the invention, n-hexane is preferably used in the said embodiment.
- 1 mmol boron nitride hexagonal (h-BN)
- h-BN hexagonal
- 5 mmol oleic acid or 2-propenoic acid
- Hydrophobe-modified-BN The material comprising these boron nanoparticles is referred to as Hydrophobe-modified-BN.
- This procedure can also be performed using other metal nitrides and metal oxides.
- Alternative or hybrid designs to the invention can also be created with metal nitrites such as vanadium nitride, zirconium nitride, aluminum nitride, etc., and derivatives such as modified silicon oxide, modified aluminum oxide, etc. Although most of these alternatives can be hydrophobic, there is no clear expression for their anti-bacterial properties.
- the produced nanoparticles are dispersed in distilled water / dodecan-l-ol mixture (99/1) (1.75% w/v or different ratios depending on the area of use) and made into a homogeneous mixture. This ratio can be varied to obtain mixtures with different properties or depending on the usage in the application areas. It can then be applied to the intended surface from a distance of 10 cm using a spray gun.
- the application (coating) process can also be performed by immersion or scraping, and the product can be fixed or coated on the intended surface and chemical hardeners can be used in this process.
- the resulting mixture provides a hydrophobic coating comprising boron nitride, which is known to have antibacterial properties in textile products in different usage amounts.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to the development of a hydrophobic and antibacterial coating material comprising boron nanomaterial.
Description
THE DEVELOPMENT OF A HYDROPHOBIC SOLUTION COMPRISING BORON
NITRIDE
Technical Field Related to the Invention
The present invention relates to the development of a hydrophobic material comprising boron nanomaterials. Within the scope of the invention, a material with hydrophobic properties and a material with antibacterial properties are offered for use in combination by creating an antibacterial and water-repellent coating for textile products with a boron structure that can be produced from domestic boron mines.
State of the Art Related to the Invention (Background)
The areas of use of boron minerals are increasing each day and they are frequently used in existing industrial areas. Boron, which addresses a wide range of applications from solar cells to protection layers in technological materials, also stands out with its specific basic properties. In recent years, with the increasing importance of anti-bacterial protection, the use of boron ingredients in combination with silver materials has been observed to increase. These materials, which also have different properties, can have water repellent or oil repellent effects. Coatings have become increasingly important, from cell phone screen technologies to textile materials. Especially the development of water repellent textile materials has become a preferred application due to their ease of use in many areas. Currently used water-repellent coatings have some limiting physicochemical and microbiological effects, as well as some toxic effects in the long term. The idea of alternative applications where these limiting features are eliminated has gained importance in recent years.
Brief Description and Objects of the Invention
Within the scope of the said invention, an antibacterial and water repellent coating for textile products can be created using a boron structure that can be produced from domestic boron mines. Thus, the development of a material with a high localization rate from the raw material
source to the final product will become possible and a material with hydrophobic properties and a material with anti-bacterial properties will also be offered for use in combination. This mixture of materials can be coated on the material deemed appropriate as a suspended solution using spray, immersion, or doctor blade (scraping) methods. In existing systems, there is no precedent product that is both boron-sourced and offers the two features in combination. It is anticipated that the invention will be demanded in the market and will provide added value to the Turkish economy as it is both functional (antibacterial and water repellent) and sustainable.
Detailed Description of the Invention
The components of the hydrophobic and antibacterial material of the invention, the properties of these components, and the method of preparation are detailed below.
BORON NITRIDE (1 mmol): It is used as the main material with its water repellent and antibacterial coating agent properties. Although boron nitride structures with different properties and crystal structures can be used, hexagonal boron nitride (h-BN) is preferably used in the invention. Boron nitride is preferred due to its hydrophobic and antibacterial properties.
OLEIC ACID (5 mmol): It is used as a hydrophobic (water repellent) property enhancer and as a material surrounding the boron nitride compound. In alternative embodiments of the invention, 2-propenoic acid can also be used in the same proportions. The main reason for preferably using oleic acid is to increase hydrophobicity. Oleic acid, which is water repellent at the molecular level, is placed around the boron nitride material to improve its water repellency capacity and persistence since the water repellency of boron nitride alone does not reach the desired levels. In alternative embodiments of the invention, several oil acids or acrylic acid derivatives can be used to increase the water repellency of boron nitride. n-HEXANE (10 ml): It is used as a solvent. Although dodecan-l-ol can also be used in the same proportions in an alternative embodiment of the invention, n-hexane is preferably used in the said embodiment.
In the experiment to prepare the hydrophobic and antibacterial material of the invention, 1 mmol boron nitride (hexagonal (h-BN)) is added to the reactor with 10 ml n-hexane (or dodecan-l-ol) and stirred at 800 rpm for 5 min with a heated magnetic stirrer. 5 mmol oleic acid (or 2-propenoic acid) is added to it and the reaction is refluxed for 1 hour. At the end of the process, the heater is turned off and the mixture continues to mix until it reaches room temperature. The resulting mixture is then centrifuged for 15 minutes, and the resulting boron nanoparticles are dried in an oven at 50°C. The material comprising these boron nanoparticles is referred to as Hydrophobe-modified-BN. This procedure can also be performed using other metal nitrides and metal oxides. Alternative or hybrid designs to the invention can also be created with metal nitrites such as vanadium nitride, zirconium nitride, aluminum nitride, etc., and derivatives such as modified silicon oxide, modified aluminum oxide, etc. Although most of these alternatives can be hydrophobic, there is no clear expression for their anti-bacterial properties. The produced nanoparticles (Hydrophobe-modified-BN) are dispersed in distilled water / dodecan-l-ol mixture (99/1) (1.75% w/v or different ratios depending on the area of use) and made into a homogeneous mixture. This ratio can be varied to obtain mixtures with different properties or depending on the usage in the application areas. It can then be applied to the intended surface from a distance of 10 cm using a spray gun. The application (coating) process can also be performed by immersion or scraping, and the product can be fixed or coated on the intended surface and chemical hardeners can be used in this process.
The resulting mixture provides a hydrophobic coating comprising boron nitride, which is known to have antibacterial properties in textile products in different usage amounts.
Claims
1. A composition, characterized in that it comprises;
• metal nitride and/or metal oxide nanoparticles with antibacterial and hydrophobic properties,
• at least one dispersing agent that disperses nanoparticles,
• at least one surfactant that provides stabilization of nanoparticles.
2. A composition according to claim 1, characterized in that said metal nitride and/or metal oxide nanoparticles are boron nitride nanoparticles.
3. A composition according to claim 2, characterized in that the boron nitride nanoparticles are smaller than 100 nm.
4. A composition according to claim 2, characterized in that the boron nitride nanoparticles are hexagonal (h-BN).
5. A composition according to claim 1, characterized in that said dispersing agent is dodecan-l-ol.
6. A composition according to claims 1 or 5, characterized in that the weight ratio of nanoparticles is 1.75% w/v in the dispersing agent.
7. A composition according to claim 1, characterized in that said surfactant is oil acid or acrylic acid derivatives.
8. A composition according to claims 1 or 6, characterized in that said surfactant is oleic acid.
9. A coating material, characterized in that it comprises a composition according to any one of the preceding claims.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TR2022/015648 TR2022015648A1 (en) | 2022-10-14 | DEVELOPMENT OF A HYDROPHOBIC SOLUTION CONTAINING BORNITRIDE | |
| TR2022015648 | 2022-10-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2024080947A1 true WO2024080947A1 (en) | 2024-04-18 |
Family
ID=90669737
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/TR2022/051711 WO2024080947A1 (en) | 2022-10-14 | 2022-12-30 | The development of a hydrophobic solution comprising boron nitride |
Country Status (1)
| Country | Link |
|---|---|
| WO (1) | WO2024080947A1 (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106758167A (en) * | 2016-11-29 | 2017-05-31 | 陕西聚洁瀚化工有限公司 | The method that organic precursor method method prepares boron nitride coating modified glass fibre dimensional fabric |
| WO2017213596A1 (en) * | 2016-06-07 | 2017-12-14 | Ozyegin Universitesi | Nano-boron for textiles |
| CN210886735U (en) * | 2019-10-18 | 2020-06-30 | 海宁杰特玻纤布业有限公司 | Boron nitride coating modified glass fiber fabric |
-
2022
- 2022-12-30 WO PCT/TR2022/051711 patent/WO2024080947A1/en unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017213596A1 (en) * | 2016-06-07 | 2017-12-14 | Ozyegin Universitesi | Nano-boron for textiles |
| CN106758167A (en) * | 2016-11-29 | 2017-05-31 | 陕西聚洁瀚化工有限公司 | The method that organic precursor method method prepares boron nitride coating modified glass fibre dimensional fabric |
| CN210886735U (en) * | 2019-10-18 | 2020-06-30 | 海宁杰特玻纤布业有限公司 | Boron nitride coating modified glass fiber fabric |
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