WO2024045662A1 - Electronic device, housing and manufacturing method therefor - Google Patents

Electronic device, housing and manufacturing method therefor Download PDF

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Publication number
WO2024045662A1
WO2024045662A1 PCT/CN2023/090904 CN2023090904W WO2024045662A1 WO 2024045662 A1 WO2024045662 A1 WO 2024045662A1 CN 2023090904 W CN2023090904 W CN 2023090904W WO 2024045662 A1 WO2024045662 A1 WO 2024045662A1
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WO
WIPO (PCT)
Prior art keywords
resin
fiberglass
layer
board
prepreg
Prior art date
Application number
PCT/CN2023/090904
Other languages
French (fr)
Chinese (zh)
Inventor
沈奎
谭东升
Original Assignee
荣耀终端有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 荣耀终端有限公司 filed Critical 荣耀终端有限公司
Publication of WO2024045662A1 publication Critical patent/WO2024045662A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/02Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/067Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of fibres or filaments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/04Layered products comprising a layer of synthetic resin as impregnant, bonding, or embedding substance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/20Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
    • H01M50/204Racks, modules or packs for multiple batteries or multiple cells
    • H01M50/207Racks, modules or packs for multiple batteries or multiple cells characterised by their shape
    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04MTELEPHONIC COMMUNICATION
    • H04M1/00Substation equipment, e.g. for use by subscribers
    • H04M1/02Constructional features of telephone sets
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K5/00Casings, cabinets or drawers for electric apparatus
    • H05K5/02Details

Definitions

  • the present application relates to the technical field of electronic equipment, and in particular to an electronic equipment, a housing and a manufacturing method thereof.
  • Fiberglass boards are a common material used to make battery covers. Fiberglass boards are usually made from fiberglass prepreg formed by impregnating fiberglass cloth in epoxy resin. However, the surface of this kind of fiberglass board will have a woven texture of glass fiber, which means that the surface flatness of the battery cover made of the fiberglass board will be poor.
  • a hot melt adhesive film is usually attached to the outside of the fiberglass board, and the base fabric and PU (polyurethane) leather are bonded through hot melt adhesive.
  • the PU leather is located on the outside of the base fabric. That is, the woven texture of the glass fiber is blocked by multi-layer pasting, and the PU leather is used as the outer layer to improve the aesthetics of the battery cover.
  • the thickness of the above-mentioned battery cover is relatively large and cannot produce a high-gloss effect.
  • This application provides an electronic device, a casing and a manufacturing method thereof.
  • the casing can exhibit a high-gloss effect and has a small thickness.
  • the manufacturing method of the casing is used to prepare the above-mentioned casing to produce a casing that can exhibit a high-gloss effect and has a relatively small thickness.
  • the battery cover of this kind of electronic device can use the above-mentioned casing to present a high-gloss effect and have a small thickness.
  • the above-mentioned housing can be used as a battery cover, so that the thickness of the battery cover is reduced and the battery cover presents a high-gloss effect.
  • a first aspect of the application provides a shell, including a fiberglass board and a high-gloss decorative layer.
  • the high-gloss decorative layer is provided on the outer side of the fiberglass board.
  • the fiberglass board includes at least one layer of first fiberglass resin. layer, the first fiberglass resin layer includes a first resin and a first fiberglass fabric, and the curing shrinkage of the first resin is less than one percent.
  • the shrinkage of the first resin is less than one percent, the shrinkage of the first resin is reduced when forming the first fiberglass resin layer, that is, the surface smoothness of the first fiberglass resin layer is improved. It is relatively high, so there is no need to set up other additional shields to block the surface texture.
  • a high-gloss decorative layer can be directly placed on the first fiberglass resin layer to form a shell that can exhibit a high-gloss effect. The thickness of the shell is relatively small.
  • the housing provided by this application has a high-gloss effect while being small in thickness.
  • the curing shrinkage of the first resin is less than five thousandths.
  • the first resin is a mixed resin of benzoxazine resin and bismaleimide resin, a benzoxazine resin or a bismaleimide resin, and the benzoxazine resin In mixed resin with bismaleimide resin
  • the mass ratio of benzoxazine resin to bismaleimide resin is 10%-90%.
  • the curing shrinkage of benzoxazine resin and bismaleimide resin is less than one percent, and the curing shrinkage of the mixed resin of benzoxazine resin and bismaleimide resin is between Between the two, therefore, the curing shrinkage of the mixed resin of benzoxazine resin and bismaleimide resin is also less than one percent, and because the above two resin materials and their mixed resin are used to make glass fiber
  • the preparation process of prepreg is similar to the process of making fiberglass prepreg with epoxy resin. That is to say, the shell provided in this application can be prepared using the equipment that originally uses epoxy resin to make fiberglass prepreg. Replace equipment.
  • the first resin is a mixed resin of benzoxazine resin and epoxy resin.
  • the benzoxazine resin and epoxy resin are mixed.
  • the mass ratio of oxygen resin is 10%-90%; or,
  • the first resin is a mixed resin of bismaleimide resin and epoxy resin.
  • the ratio between bismaleimide resin and epoxy resin is The mass ratio is 10%-90%.
  • the curing shrinkage of the mixed resin of benzoxazine resin and epoxy resin, and the curing shrinkage of the mixed resin of bismaleimide resin and epoxy resin are both less than one percent, and can be used
  • the shell provided in this application can be prepared using equipment originally used to make glass fiber prepreg using epoxy resin, without the need to replace the equipment.
  • the preparation efficiency of glass fiber boards can be improved by using a mixed resin of benzoxazine resin and epoxy resin, or a mixed resin of bismaleimide resin and epoxy resin.
  • the fiberglass board includes multiple layers of first fiberglass resin layers, and multiple layers of the first fiberglass resin layers are stacked to form the fiberglass board.
  • multiple first glass fiber resin layers can improve the structural strength and stiffness of the glass fiber board.
  • the production process of the multiple first glass fiber resin layers is the same, which facilitates production and manufacturing.
  • the number of stacks of the first fiberglass resin layer is 3-5.
  • the rigidity and strength of the fiberglass board formed after stacking 3 to 5 layers of first fiberglass resin layers are relatively strong.
  • the thickness of the first fiberglass resin layer is 0.08mm-0.10mm.
  • the first fiberglass resin layer has a certain structural strength and rigidity at a relatively small thickness.
  • the thickness of the high-gloss decorative layer is 0.05mm-0.08mm.
  • the high-gloss decorative layer can block the outer surface of the first fiberglass resin layer to present a better high-gloss effect.
  • the fiberglass board further includes a second fiberglass resin layer, and the curing shrinkage rate of the second fiberglass resin layer is greater than the curing shrinkage rate of the first fiberglass resin layer; the second fiberglass resin layer
  • the fiberglass resin layer includes a second resin and a second fiberglass fabric, and the first fiberglass resin layer is provided between the second fiberglass resin layer and the high-gloss decorative layer.
  • the outermost layer of the fiberglass board that is, the layer used to set the high-gloss decorative layer
  • the first fiberglass resin layer so that the high-gloss decorative layer can be set on a surface with high surface flatness.
  • the surface of the first fiberglass resin layer thus presents a better high-gloss effect, and in other stacks that are not used to provide high-gloss decorative layers, a second fiberglass resin layer made of other materials can be used.
  • a second aspect of this application provides an electronic device, including the housing provided by the above technical solution.
  • the thickness of the above casing is small and can be It can produce high-gloss effect, thus making electronic devices relatively small in thickness and capable of showing high-gloss effect.
  • the third aspect of this application provides a method for making a shell, including:
  • Preparing a first resin to form a first prepolymer glue solution the curing shrinkage of the first resin is less than one percent
  • Prepreg containing at least the first fiberglass prepreg is made into a fiberglass board, the first fiberglass prepreg in the fiberglass board forms a first fiberglass resin layer, and the fiberglass board including at least one layer of said first fiberglass resin layer;
  • a high-gloss decorative layer is provided on the outside of the fiberglass board.
  • the shrinkage of the first resin is less than one percent, the shrinkage of the first resin is reduced when forming the first fiberglass resin layer, that is, the surface smoothness of the first fiberglass resin layer is improved. It is relatively high, so there is no need to set up other additional shields to block the surface texture.
  • a high-gloss decorative layer can be directly placed on the first fiberglass resin layer to form a shell that can exhibit a high-gloss effect. The thickness of the shell is relatively small.
  • the method for manufacturing a casing provided in this application can produce a casing with a high gloss effect and a small thickness.
  • the high-gloss decorative layer is formed by spraying high-gloss paint on the outside of the fiberglass board.
  • the high-gloss decorative layer formed by spraying high-gloss paint does not need to add an adhesive layer, and the thickness is relatively thin.
  • producing a fiberglass board containing at least the first fiberglass prepreg includes:
  • the fiberglass board includes a plurality of first fiberglass resin layers.
  • the fiberglass board includes multiple first fiberglass resin layers, which has higher structural strength.
  • the production method further includes:
  • the manufacturing method of producing a fiberglass board from a prepreg containing at least the first fiberglass prepreg includes:
  • the manufacturing method of providing a high-gloss decorative layer on the outside of the fiberglass board includes:
  • the high-gloss decorative layer is disposed on the outer side of the outermost first fiberglass resin layer.
  • the layer used to set the high-gloss decorative layer in the fiberglass board is the first fiberglass resin layer, so that the high-gloss decorative layer can be set on the first fiberglass resin layer with higher surface flatness. surface, thereby presenting a better high-gloss effect, and in other laminates not used for setting high-gloss decorative layers, a second fiberglass resin layer made of epoxy resin can be used.
  • Figure 1 is a schematic structural diagram of glass fiber prepreg in the prior art
  • Figure 2 is a schematic structural diagram of the first glass fiber resin layer provided by the embodiment of the present application.
  • Figure 3 is a schematic structural diagram of a housing provided by an embodiment of the present application.
  • Figure 4 is a second structural schematic diagram of a housing provided by an embodiment of the present application.
  • Figure 5 is a schematic structural diagram three of the housing provided by the embodiment of the present application.
  • Figure 6 is a schematic structural diagram 4 of a housing provided by an embodiment of the present application.
  • Figure 7 is a schematic structural diagram 5 of the housing provided by the embodiment of the present application.
  • Figure 8 is a schematic structural diagram six of the housing provided by the embodiment of the present application.
  • Figure 9 is a schematic structural diagram of the housing provided by the embodiment of the present application.
  • Figure 10 is a schematic structural diagram of the housing provided by the embodiment of the present application.
  • Figure 11 is a schematic flow chart of a method for manufacturing a casing provided by an embodiment of the present application.
  • FIG. 12 is a schematic flowchart of another method for manufacturing a casing provided by an embodiment of the present application.
  • Fiberglass board 110. First fiberglass resin layer; 111. First resin; 112. First fiberglass fabric; 120. Second fiberglass resin layer; 200. High-gloss decorative layer.
  • glass fiber is the abbreviation of glass fiber.
  • the back cover of an electronic device i.e., battery cover
  • the fiberglass board is made of fiberglass prepreg.
  • the fiberglass prepreg The material is made by impregnating fiberglass cloth 2 with epoxy resin 1. Due to the large curing shrinkage rate of epoxy resin 1 during the thermal curing process, the woven texture of fiberglass cloth 2 leaks out from the surface of the fiberglass board after it is formed. This is not suitable for The appearance and process design of the battery cover poses great challenges. Since the surface flatness of the glass fiber prepreg made of epoxy resin 1 is poor, the outer surface of the battery cover is usually set to a matte effect.
  • the hot melt adhesive film is attached to one side of the fiberglass board, and the base fabric and PU skin are attached to the side of the hot melt adhesive film facing away from the fiberglass board.
  • the PU skin is located on the side of the base fabric facing away from the glass fiber board.
  • One side of the fiberboard, that is, the PU leather is located on the outermost side.
  • the hot-melt adhesive film, base fabric and PU leather are used to block the fiberglass woven texture on the surface of the fiberglass board, and the PU leather is used to form the appearance.
  • this setting method can block the fiberglass woven texture, because the PU leather needs a certain thickness of support, otherwise it will feel hard and the tactile comfort will be relatively poor. Therefore, more shielding is set up to provide sufficient support for the PU leather. layer, resulting in the battery cover being thicker (usually greater than 0.7mm) and heavy, and the PU leather has a matte texture, making it impossible to achieve a high-gloss appearance design.
  • a matte decorative film is bonded to one side of the fiberglass board through OCA (Optically Clear Adhesive). Since the thickness of the matte decorative film is greater than 0.2mm, it can block the fiberglass weave. texture, so the thickness of the battery cover is relatively large, and because the base material of the matte decorative diaphragm is usually PET (Polyethylene terephthalate, polyethylene terephthalate), its hardness is low, which will lead to process Increased difficulty, fit It is prone to wrinkles and blistering, and the manufacturing yield is low. In addition, the matte decorative diaphragm has a matte texture and cannot achieve a high-gloss appearance design.
  • matte paint is sprayed on one side of the fiberglass board, which gives a matte effect and cannot achieve a high-gloss appearance design.
  • the epoxy resin of the glass fiber prepreg is modified to increase the cross-linking degree of the epoxy resin after curing so that more epoxy resin can be retained to cover the glass during the hot pressing process. fiber surface, thereby reducing to a certain extent the visibility of the fiberglass texture caused by curing shrinkage.
  • this modified glass fiber prepreg is used as the outermost layer for appearance decoration.
  • this arrangement increases the thickness of the fiberglass prepreg, which increases the thickness of the battery cover it supports.
  • the overall structural strength of the fiberglass board weakens.
  • the woven glass fiber is prone to slipping during the production process, resulting in poor regional performance.
  • the modification of epoxy resin requires simultaneous improvement of the preparation process of the fiberglass board, making the process more complex.
  • the glass fiber of the fiberglass cloth is improved, and the fiberglass cloth with a smaller diameter is used to weave the fiberglass cloth to increase the weaving density of the fiberglass cloth and reduce the visibility of the fiberglass weaving pattern to the naked eye.
  • the use of glass fiber woven fiberglass cloth with a smaller diameter will lead to a significant increase in production costs, complicated processes, and reduced process efficiency.
  • the thickness of the glass fiber woven fiberglass cloth with a smaller diameter will be reduced, so its The structural strength is reduced, and multiple layers of fiberglass cloth need to be stacked to make fiberglass boards, which reduces manufacturing efficiency.
  • embodiments of the present application provide a housing, a manufacturing method thereof, and electronic equipment to solve the above-mentioned problems that trouble those skilled in the art.
  • the housing, its manufacturing method, and the electronic device provided by the embodiments of the present application will be explained in detail below.
  • this embodiment provides a casing, which is applied to an electronic device and can be used as the casing of the electronic device, or as a part of the casing of the electronic device. For example, it can be used as the casing of the electronic device. battery cover.
  • the shell includes a fiberglass board 100 and a high-gloss decorative layer 200.
  • the high-gloss decorative layer 200 is provided on the outer side of the fiberglass board 100.
  • the fiberglass board 100 includes at least one first fiberglass resin layer 110.
  • the first fiberglass resin layer 110 It is made of a first fiberglass prepreg.
  • the first fiberglass prepreg is formed by impregnating a first fiberglass fabric into a first resin 111.
  • the curing shrinkage rate of the first resin 111 is less than one percent.
  • the fiberglass board 100 is obtained by processing a plurality of first fiberglass prepregs. In the fiberglass board, the structure formed by the original first fiberglass prepregs is called the first fiberglass resin layer. 110.
  • a layer of first fiberglass prepreg is processed to form a layer of first fiberglass resin layer 110 .
  • the first glass fiber prepreg forms a semi-cured structure after being dried for a certain period of time.
  • the semi-cured structure is rolled into a sheet structure, and then dried again through several sheet structures to form a semi-cured structure.
  • a corresponding sheet structure in the fiberglass board is called a first fiberglass resin layer 110, that is, a first fiberglass resin layer is made of the first fiberglass fabric 112 impregnated with the first resin 111.
  • the structure formed after the first glass fiber prepreg is processed in several steps.
  • the shrinkage of the first resin 111 is less than one percent, the shrinkage of the first resin 111 is reduced when forming the first fiberglass resin layer 110 , that is, the first fiberglass resin layer 110
  • the surface flatness is relatively high, so there is no need to set up other additional shields to block the surface texture, directly on the first fiberglass resin layer
  • the high-gloss decorative layer 200 By disposing the high-gloss decorative layer 200 on the housing 110, a shell capable of exhibiting a high-gloss effect can be formed, and the thickness of the shell is relatively small.
  • the housing provided in this embodiment can be used as a battery cover of an electronic device, which means that the battery cover can achieve a high-gloss effect and have a small thickness.
  • the first fiberglass fabric 112 used to manufacture the shell can be a glass fiber woven fiberglass fabric with a conventional thickness, or a glass fiber fabric with a smaller diameter and a higher woven density.
  • the curing shrinkage of the first resin 111 is less than one percent, and is set in such a way that the first fiberglass resin layer 110 is made after processing the first fiberglass prepreg formed by the first resin 111 and the first fiberglass fabric 112
  • the glass fiber woven texture presented on the surface has low visibility, which means that the surface of the fiberglass board 100 including the first fiberglass resin layer 110 has a higher smoothness, which facilitates the formation of the high-gloss decorative layer 200 on the fiberglass board 100 .
  • the curing shrinkage rate of the first resin 111 is less than five thousandths, that is, the impact of the shrinkage of the first resin 111 during the curing process on the surface flatness of the fiberglass plate 100 is further reduced, and also That is, it is more conducive to ensuring that the surface of the fiberglass plate 100 meets higher flatness requirements, so that after the high-gloss decorative layer 200 is formed, a better high-gloss effect can be presented.
  • the first resin 111 is a benzoxazine resin or a modified resin thereof, a bismaleimide resin or a modified resin thereof.
  • the first resin 111 may also be a benzoxazine resin and a modified resin thereof.
  • the first resin 111 can also be other resin materials with a curing shrinkage rate of less than one percent or even less than five thousandths. The curing shrinkage of benzoxazine resin is almost zero, and the curing shrinkage of bismaleimide resin is less than 7 thousandths.
  • the mixed resin formed by mixing benzoxazine resin and bismaleimide resin The curing shrinkage rate is between zero and seven thousandths.
  • the curing shrinkage rate of the mixed resin will be closer to the curing shrinkage rate of the benzoxazine resin; if the mixed resin If the proportion of bismaleimide resin in the resin is higher, the curing shrinkage rate of the mixed resin will be closer to the curing shrinkage rate of the bismaleimide resin. That is to say, by adjusting the mass ratio of benzoxazine resin and cyclobismaleimide resin in the mixed resin, the curing shrinkage of the mixed resin of benzoxazine resin and epoxy resin can be less than one thousandth. five.
  • the first resin 111 can also be a mixed resin mixed with benzoxazine resin and bismaleimide resin
  • the first glass fiber resin The preparation process of the layer 110 is similar to the process of preparing the first fiberglass resin layer 110 using epoxy resin in conventional technology.
  • the original production equipment does not need to be replaced, and the original production equipment can be used to produce this embodiment. In the process flow of the provided shell, it is used as part of the production process to save costs.
  • the mass ratio of benzoxazine resin and bismaleimide resin can be 10%-90%, for example, The resin includes 10 parts of benzoxazine resin and 90 parts of bismaleimide resin; or, the mixed resin includes 20 parts of benzoxazine resin and 80 parts of bismaleimide resin; or, the mixed resin includes Including 40 parts of benzoxazine resin and 60 parts of bismaleimide resin; or, the mixed resin includes 90 parts of benzoxazine resin and 10 parts of bismaleimide resin; or other products that comply with benzoxazine resin
  • the mass ratio of resin and bismaleimide resin is a mixing scheme of 10%-90%.
  • the first resin 111 is a mixed resin of benzoxazine resin and epoxy resin.
  • the curing shrinkage of the mixed resin of benzoxazine resin and epoxy resin is less than one percent.
  • the mass ratio of benzoxazine resin and epoxy resin in the mixed resin can make the curing shrinkage of the mixed resin of benzoxazine resin and epoxy resin less than five thousandths.
  • the mass ratio of benzoxazine resin to epoxy resin can be 10%-90%.
  • the mixed resin includes 10 parts of benzoxazine resin and 90 parts of epoxy resin; or the mixed resin includes 30 parts of benzo oxazine resin and 70 parts epoxy resin; or, the mixed resin includes 60 parts benzoxazine resin and 40 parts epoxy resin; or, the mixed resin includes 90 parts of benzoxazine resin and 10 parts of epoxy resin; or other mixing solutions that meet the mass ratio of benzoxazine resin to epoxy resin of 10%-90%.
  • the mass ratio of benzoxazine resin to epoxy resin is 20%-30%.
  • Using a mixed resin of benzoxazine resin and epoxy resin as the first resin 111 can reduce the hot pressing time when preparing the glass fiber board 100, thereby improving the preparation efficiency.
  • the first resin 111 is a mixed resin of bismaleimide resin and epoxy resin
  • the curing shrinkage rate of the mixed resin of bismaleimide resin and epoxy resin is less than one percent.
  • the curing shrinkage of the mixed resin of bismaleimide resin and epoxy resin can be less than five thousandths.
  • the mass ratio of bismaleimide resin to epoxy resin can be 10%-90%.
  • the mixed resin includes 10 parts of bismaleimide resin and 90 parts of epoxy resin; or the mixed resin includes 25 parts bismaleimide resin and 75 parts epoxy resin; or, the mixed resin includes 50 parts bismaleimide resin and 50 parts epoxy resin; or, the mixed resin includes 90 parts bismaleimide resin Imine resin and 10 parts of epoxy resin; or other mixing solutions that meet the mass ratio of bismaleimide resin and epoxy resin at 10%-90%.
  • the mass ratio of bismaleimide resin to epoxy resin is 20%-30%.
  • Using a mixed resin of bismaleimide resin and epoxy resin as the first resin 111 can reduce the hot pressing time when preparing the glass fiber board 100, thereby improving the preparation efficiency.
  • the high-gloss decorative layer 200 can be a high-gloss film, and the high-gloss film is attached to one side of the fiberglass board 100 .
  • the high-gloss decorative layer 200 may be a high-gloss coating, which is formed by spraying high-gloss paint on one side of the fiberglass board 100 .
  • the fiberglass board 100 may be made of multiple layers of fiberglass prepreg stacks.
  • the multi-layered fiberglass prepregs are all first fiberglass resin layers 110 , that is, the fiberglass board 100 is manufactured by stacking multiple layers of first fiberglass resin layers 110 Become.
  • the multiple first glass fiber resin layers 110 can improve the structural strength and rigidity of the glass fiber board 100.
  • the production process of the multiple first glass fiber resin layers 110 is the same, which facilitates production and manufacturing. That is to say, the first fiberglass resin layer 110 produced by the same prepreg production line can be used as any layer of the fiberglass board 100, and multiple first fiberglass resin layers 110 produced by a prepreg production line can be stacked for use.
  • a prepreg production line takes up relatively little space.
  • the stacking number of the first glass fiber resin layer 110 can be selected according to the glass fiber diameter of the first glass fiber resin layer 110. As the glass fiber diameter decreases, the number of the first glass fiber resin layer 110 can be increased.
  • a glass fiber woven fiberglass fabric of moderate thickness is used to manufacture the first fiberglass resin layer 110 through the fiberglass fabric. Then the number of stacks of the first fiberglass resin layer 110 can be 3-5 layers. , which can make the stiffness and strength of the fiberglass board 100 relatively strong.
  • the thickness of the first fiberglass resin layer 110 is 0.08mm-0.10mm. Within the above thickness range, the first fiberglass resin layer 110 has a certain structural strength and rigidity at a relatively small thickness.
  • the thickness of the high-gloss decorative layer 200 is 0.05mm-0.08mm. Within the above thickness range, the high-gloss decorative layer 200 can block the outer surface of the first fiberglass resin layer 110 to present a better high-gloss effect.
  • the thickness of the high-gloss decorative layer 200 is 0.05mm, the thickness of the first fiberglass resin layer 110 is 0.08mm, and the first fiberglass resin layer 110 is three layers, then the minimum thickness of the housing is 0.29mm. If the thickness of the high-gloss decorative layer 200 is 0.08mm, the thickness of the first fiberglass resin layer 110 is 0.10mm, and the first fiberglass resin layer 110 is three layers, then the minimum thickness of the housing is 0.38mm. If the thickness of the high-gloss decorative layer 200 is 0.05mm, the thickness of the first fiberglass resin layer 110 is 0.08mm, and the first fiberglass resin layer 110 is five layers, then the minimum thickness of the housing is 0.45mm.
  • the thickness of the high-gloss decorative layer 200 is 0.08mm
  • the thickness of the first fiberglass resin layer 110 is 0.10mm
  • the first fiberglass resin layer 110 is five layers
  • the minimum thickness of the shell is 0.58mm.
  • the thickness of each of the above-mentioned cases is 0.12mm-0.41mm thinner than the thickness of the conventional battery cover (0.7mm).
  • the fiberglass board 100 further includes a second fiberglass resin layer 120 , and the curing shrinkage rate of the second fiberglass resin layer 120 is greater than that of the first fiberglass resin layer 110 .
  • Curing shrinkage the second fiberglass resin layer 120 includes a second fiberglass fabric and a second resin, which can optionally be achieved by making the curing shrinkage of the second resin greater than the curing shrinkage of the first resin.
  • the second fiberglass fabric is impregnated in the second resin to form a second fiberglass prepreg, and the fiberglass board 100 is formed by processing a plurality of second fiberglass prepregs and a plurality of first fiberglass prepregs.
  • the part of the structure formed by the first fiberglass prepreg is the first fiberglass resin layer 110
  • the part of the structure formed by the second fiberglass prepreg is the second fiberglass resin layer 120
  • the fiberglass board 100 is formed by processing multiple layers of stacked fiberglass prepregs.
  • the fiberglass board 100 includes at least one first layer of fiberglass resin 110 and at least one layer of second fiberglass resin layer 120.
  • the first fiberglass resin layer 110 is stacked on the outside of the second fiberglass resin layer 120
  • the high-gloss decorative layer 200 is located on the outside of the outermost first fiberglass resin layer 110 .
  • the outermost layer of the fiberglass board 100 that is, the layer used to set the high-gloss decorative layer 200 is the first fiberglass resin layer 110 , so that the high-gloss decorative layer 200 can be placed on a smooth surface.
  • the surface of the first fiberglass resin layer 110 has a higher degree of gloss, thereby presenting a better high-gloss effect.
  • a second fiberglass resin layer made of other materials can be used. 120.
  • the shell will have at least the following configuration:
  • the first arrangement method is: as shown in Figure 4, the first fiberglass resin layer 110 is one layer, and the second fiberglass resin layer 120 is three layers. Then the shell from one side to the other side (the direction shown in Figure 4 is from bottom to top) can be respectively: the first layer and the second fiberglass resin layer 120 - the second layer and the second fiberglass resin layer 120 - the third layer The second fiberglass resin layer 120 - the first fiberglass resin layer 110 - the high-gloss decorative layer 200.
  • the second arrangement mode is: the first fiberglass resin layer 110 and the second fiberglass resin layer 120 are two layers. Then the shell can have the following arrangement from one side to the other: 1 As shown in Figure 5, from bottom to top are the first layer of the first fiberglass resin layer 110 - the first layer of the second fiberglass resin layer 120 - The second layer of the second fiberglass resin layer 120 - the second layer of the first fiberglass resin layer 110 - the high-gloss decorative layer 200. 2As shown in Figure 6, from bottom to top, they are the first layer and the second fiberglass resin layer 120-the first layer of the first fiberglass resin layer 110-the second layer and the second fiberglass resin layer 120-the second layer and the first layer. Glass fiber resin layer 110-high gloss decorative layer 200.
  • the third arrangement mode is: the first fiberglass resin layer 110 is three layers, and the second fiberglass resin layer 120 is one layer. Then the shell can have the following arrangement from one side to the other: 1 As shown in Figure 8, from bottom to top they are the second fiberglass resin layer 120 - the first layer, the first fiberglass resin layer 110 - the second layer. The first fiberglass resin layer 110 - the third layer, the first fiberglass resin layer 110 - the high-gloss decorative layer 200. 2As shown in Figure 9, from bottom to top, they are the first layer of first fiberglass resin layer 110-the second layer of fiberglass resin 120-the second layer of first fiberglass resin layer 110-the third layer of first fiberglass resin. Layer 110 - High gloss decorative layer 200. 3As shown in Figure 10, from bottom to top, they are the first layer of first fiberglass resin layer 110 - the second layer of first fiberglass resin layer 110 - the second layer of fiberglass resin layer 120 - the third layer of first fiberglass resin Layer 110 - High gloss decorative layer 200.
  • the total number of the first fiberglass resin layer 110 and the second fiberglass resin layer 120 may be 3 to 5 layers.
  • the thicknesses of the first fiberglass resin layer 110 and the second fiberglass resin layer 120 are both between 0.05mm and 0.08mm.
  • the number of the first fiberglass resin layer 110 is at least two, and several first fiberglass resin layers 110 are included. After the two glass fiber resin layers 120 are stacked, At least one first fiberglass resin layer 110 is provided on both sides of the stacked second fiberglass resin layers 120 . With this arrangement, the flatness of both sides of the fiberglass plate 100 prepared from the first fiberglass resin layer 110 and the second fiberglass resin layer 120 is relatively high.
  • This embodiment provides a method for manufacturing a casing, which is used to manufacture the casing provided in the first embodiment. Since the housing provided in the above first embodiment can be used as a battery cover of an electronic device, the manufacturing method provided in this embodiment can also be used to manufacture a battery cover.
  • the manufacturing method of the housing provided in this embodiment includes:
  • the first resin is prepared to form a first prepolymer glue solution, and the curing shrinkage of the first resin is less than one percent;
  • Prepreg containing at least a first glass fiber prepreg is made into a fiberglass board, in which the first Boxin prepreg forms a first fiberglass resin layer, and the fiberglass board includes at least one layer of first glass fiber
  • the resin layer that is to say, the fiberglass board is processed by at least one layer of first fiberglass prepreg;
  • the shrinkage of the first resin is less than one percent, the shrinkage of the first resin is reduced when forming the first fiberglass resin layer, that is, the surface smoothness of the first fiberglass resin layer is improved. It is relatively high, so there is no need to set up other additional shields to block the surface texture.
  • a high-gloss decorative layer can be directly placed on the first fiberglass resin layer to form a shell that can exhibit a high-gloss effect. The thickness of the shell is relatively small.
  • the method for manufacturing a casing provided in this application can produce a casing with a high gloss effect and a small thickness.
  • the curing shrinkage of the first resin is less than five thousandths, that is, the impact of the shrinkage of the first resin during the curing process on the surface flatness of the fiberglass board is further reduced, that is, it is more It is beneficial to ensure that the surface of the fiberglass board meets higher flatness requirements, so that after the high-gloss decorative layer is formed, a better high-gloss effect can be presented.
  • the first resin can be benzoxazine resin or its modified resin, bismaleimide resin or its modified resin.
  • the first resin can also be benzoxazine resin and bismaleimide.
  • the first resin can also be For other resin materials whose curing shrinkage is less than one percent or even less than five thousandths.
  • the curing shrinkage of the mixed resin of benzoxazine resin and epoxy resin is less than 1%.
  • the mass ratio of benzoxazine resin and epoxy resin can make the curing shrinkage of the mixed resin of benzoxazine resin and epoxy resin less than five thousandths.
  • the mass ratio of benzoxazine resin to epoxy resin can be 10%-90%.
  • the mixed resin includes 10 parts of benzoxazine resin and 90 parts of epoxy resin; or the mixed resin includes 30 parts of benzo Oxazine resin and 70 parts of epoxy resin; or, the mixed resin includes 60 parts of benzoxazine resin and 40 parts of epoxy resin; or, the mixed resin includes 90 parts of benzoxazine resin and 10 parts of epoxy resin; Or other mixing solutions that meet the mass ratio of benzoxazine resin and epoxy resin between 10% and 90%.
  • the mass ratio of benzoxazine resin to epoxy resin is 20%-30%.
  • Using a mixed resin of benzoxazine resin and epoxy resin as the first resin 111 can reduce the hot pressing time when preparing the glass fiber board 100, thereby improving the preparation efficiency.
  • the curing shrinkage of the mixed resin of bismaleimide resin and epoxy resin is less than 1%.
  • the mass ratio to epoxy resin can make the curing shrinkage of the mixed resin of bismaleimide resin and epoxy resin less than five thousandths.
  • the mass ratio of bismaleimide resin to epoxy resin can be 10%-90%.
  • the mixed resin includes 10 parts of bismaleimide resin and 90 parts of epoxy resin; or the mixed resin includes 25 parts bismaleimide resin and 75 parts epoxy resin; or, the mixed resin includes 50 parts bismaleimide resin and 50 parts epoxy resin; or, the mixed resin includes 90 parts bismaleimide resin Imine resin and 10 parts of epoxy resin; or other mixing solutions that meet the mass ratio of bismaleimide resin and epoxy resin at 10%-90%.
  • the mass ratio of bismaleimide resin to epoxy resin is 20%-30%.
  • Using a mixed resin of bismaleimide resin and epoxy resin as the first resin 111 can reduce the hot pressing time when preparing the glass fiber board 100, thereby improving the preparation efficiency.
  • the process of preparing the first resin to form the first prepolymer glue specifically includes: placing the reaction liquid containing the first resin monomer and the curing agent in a reaction tank, and forming the first prepolymer glue at a set temperature and after a set time. Poly glue liquid.
  • the process of impregnating the first glass fiber fabric into the first prepolymer glue solution to form the first glass fiber prepreg specifically includes: drying the glass fiber fabric, and impregnating the dried glass fiber fabric with the first prepolymer glue solution , the glass fiber fabric impregnated with the first prepolymer glue solution is rolled through a hot roller into a layered structure with a set thickness, and the layered structure is placed in an oven at a set temperature for thermal curing treatment to form a semi-cured The first fiberglass prepreg.
  • producing a fiberglass board containing at least the first fiberglass prepreg includes:
  • first fiberglass prepregs Obtain a plurality of first fiberglass prepregs, stack the plurality of first fiberglass prepregs, and prepare a fiberglass board through the stacked plurality of first fiberglass prepregs, so that the fiberglass board includes a plurality of first fiberglass prepregs.
  • Fiberglass resin layer In the fiberglass board, a first fiberglass prepreg corresponds to a first fiberglass resin layer, and the first fiberglass resin layer is a fully cured first fiberglass prepreg.
  • the process of making the first fiberglass prepreg into a fiberglass board specifically includes: cutting the first fiberglass prepreg into a set size, and stacking multiple layers of the first fiberglass prepreg, The stacked multiple first fiberglass resin layers are put into a hot pressing mold for hot press molding, thereby forming a fiberglass board.
  • the process of providing a high-gloss decorative layer on the outside of the fiberglass board may specifically include: attaching a high-gloss film to the outside of the fiberglass board to form a high-gloss decorative layer, or spraying high-gloss paint on the outside of the fiberglass board to form a high-gloss decorative layer.
  • the casing can serve as a battery cover.
  • five specific embodiments are used to describe the optional process flow of the above-mentioned manufacturing method for manufacturing a battery cover with a high-gloss effect:
  • benzoxazine resin is used as the first resin to make the battery cover.
  • the making method may include:
  • bismaleimide resin is used as the first resin to make the battery cover.
  • the making method may include:
  • reaction solution containing bismaleimide resin monomer and curing agent Place the reaction solution containing bismaleimide resin monomer and curing agent in the reaction tank, and prepolymerize it at a temperature of 130°C-160°C for 3h-6h to form the first prepolymerized glue solution;
  • a mixed resin composed of benzoxazine resin and bismaleimide resin is used as the first resin to manufacture the battery cover.
  • the manufacturing method may include:
  • the reaction solution containing bismaleimide resin monomer, benzoxazine resin monomer and curing agent is placed in the reaction tank, heated and melted to form the first prepolymer glue solution; it is worth mentioning that benzoxazine
  • the mass ratio of oxazine resin monomer and bismaleimide resin monomer can be 10%-90%;
  • the heating temperature is 180°C
  • the pressure is 10MPa
  • the holding time is 3h-4h.
  • a glass fiber board is obtained.
  • the structure corresponding to the first layer of glass fiber prepreg is a layer of first layer.
  • a mixed resin of benzoxazine resin and epoxy resin is used as the first resin to make the battery cover.
  • the making method may include:
  • the reaction solution containing benzoxazine resin monomer, epoxy resin monomer and curing agent is placed in the reaction tank, heated and melted to form the first prepolymer glue solution; it is worth mentioning that the benzoxazine resin monomer
  • the mass ratio to the epoxy resin monomer can be 10%-90%, preferably 20%-30%;
  • the heating temperature is 180°C
  • the pressure is 10MPa
  • the pressure holding time is 1h-2h.
  • a glass fiber board is obtained.
  • the structure corresponding to the first layer of glass fiber prepreg is a layer of first layer.
  • a mixed resin mixed with bismaleimide resin and epoxy resin is used as the first resin to make the battery cover.
  • the making method may include:
  • the reaction solution containing bismaleimide resin monomer, epoxy resin monomer and curing agent is placed in the reaction tank, heated and melted to form the first prepolymer glue solution; it is worth mentioning that bismaleimide
  • the mass ratio of amine resin monomer and epoxy resin monomer can be 10%-90%, preferably 20%-30%;
  • the heating temperature is 180°C
  • the pressure is 10MPa
  • the pressure holding time is 1h-2h.
  • a glass fiber board is obtained.
  • the structure corresponding to the first layer of glass fiber prepreg is a layer of first layer.
  • the fiberglass board includes both a first fiberglass resin layer and a second fiberglass resin layer.
  • the manufacturing method of the shell also includes:
  • the production method of making the prepreg containing at least the first fiberglass prepreg into the fiberglass board includes:
  • first fiberglass prepreg Stack at least one layer of first fiberglass prepreg and at least one layer of second fiberglass prepreg so that the outermost fiberglass prepreg is the first fiberglass prepreg; stack the stacked glass fiber prepregs
  • the materials are prepared to form a fiberglass board, the first fiberglass prepreg in the fiberglass board forms a first fiberglass resin layer, and the second fiberglass prepreg forms a second fiberglass resin layer;
  • the production method of setting a high-gloss decorative layer on the outside of the fiberglass board includes:
  • the high-gloss decorative layer is disposed on the outer surface of the outermost first fiberglass resin layer.
  • the production process of the second glass fiber prepreg and the production process of the first glass fiber prepreg can be carried out at the same time; the production process of the first glass fiber prepreg can also be carried out first, and then the second glass fiber prepreg can be carried out.
  • the manufacturing process of fiber prepreg; or the manufacturing process of the second fiberglass prepreg is carried out first, and then the manufacturing process of the first fiberglass prepreg is carried out.
  • the curing shrinkage rate of the second resin is not required to be less than 1%, because the second fiberglass resin layer made of the second resin is located inside the first fiberglass resin layer, and the high-gloss decorative layer is located inside the first fiberglass resin layer.
  • the outer surface of the first fiberglass resin layer has a relatively high smoothness, so the high-gloss decorative layer disposed on the outside thereof can present a better high-gloss effect.
  • the second resin can be epoxy resin. Even if the surface of the second fiberglass resin layer made of epoxy resin exhibits a fiberglass woven texture, it will be blocked by the first fiberglass resin layer located outside it, so it will not It will affect the high-gloss effect of the outer surface of the high-gloss decorative layer provided outside the first fiberglass resin layer.
  • This embodiment provides an electronic device, including the housing provided in the first embodiment.
  • Electronic devices can be electronic paper, mobile phones, tablets, televisions, smart bracelets, smart watches, monitors, Electronic products or components with casings such as notebook computers and electronic photo frames are not limited in this embodiment.
  • the electronic device may include a display screen, a battery, and a housing, which may be the housing or a part of the housing.
  • the casing includes a middle frame and a battery cover, and the casing serves as the battery cover.
  • the middle frame is connected to the casing, the display screen is installed on the middle frame, the display area of the display screen faces away from the casing, and the battery is located between the display screen and the battery cover.
  • the shell of the electronic device provided in this embodiment is made of glass fiber prepreg using the first resin with a curing shrinkage rate of less than 1%, the surface flatness of the first glass fiber resin layer is relatively high, so there is no need to install other components.
  • the additional shielding object blocks the surface texture, and a high-gloss decorative layer is directly placed on the first fiberglass resin layer to form a shell that can exhibit a high-gloss effect.
  • the thickness of the shell is relatively small and the weight is relatively light, thus making the electronics
  • the overall thickness of the device is relatively small and lightweight.
  • the shell achieves the purpose of presenting a high-gloss effect on its surface on the basis of meeting the structural strength requirements, breaks through the technical barriers of shell appearance design, expands the design scope of the shell appearance design, and provides a shell with a high-gloss effect.
  • the structural strength requirement of the casing means that the casing needs to have a certain degree of structural strength and rigidity to provide protection for batteries and other components inside the electronic device.

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Abstract

The present application relates to the technical field of electronic devices, and discloses an electronic device, a housing and a manufacturing method therefor. The housing comprises a glass fiber plate (100) and a highlight decoration layer (200). The highlight decoration layer (200) is arranged on the outer side surface of the glass fiber plate (100). The glass fiber plate (100) comprises at least one first glass fiber resin layer (110). The first glass fiber resin layer (110) comprises a first resin (111) and a first glass fiber fabric (112). The curing shrinkage rate of the first resin (111) is less than one percent. The electronic device comprises the housing, and the housing manufacturing method is used for manufacturing the housing. Since the glass fiber plate (100) in the housing is made of the first resin with the small curing shrinkage rate, the surface flatness of the glass fiber plate (100) is high, and then a flat highlight effect is presented after the highlight decoration layer (200) is provided. Since there is no need to additionally provide a shielding object on the surface of the glass fiber plate (100), the total thickness of the housing is small.

Description

电子设备、壳体及其制作方法Electronic equipment, housing and manufacturing method thereof
本申请要求于2022年8月31日提交国家知识产权局、申请号为202211062444.9、申请名称为“电子设备、壳体及其制作方法”的中国专利申请的优先权,其全部内容通过引用结合在本申请中。This application claims priority to the Chinese patent application submitted to the State Intellectual Property Office on August 31, 2022, with application number 202211062444.9 and the application name "Electronic Equipment, Housings and Manufacturing Methods", the entire content of which is incorporated by reference. in this application.
技术领域Technical field
本申请涉及电子设备技术领域,特别涉及一种电子设备、壳体及其制作方法。The present application relates to the technical field of electronic equipment, and in particular to an electronic equipment, a housing and a manufacturing method thereof.
背景技术Background technique
目前,电子设备的后盖通常也称为电池盖,近年来电池盖逐渐采用非金属材料制成,玻纤板即为常见用于制造电池盖的材料。玻纤板通常为将玻纤布浸渍在环氧树脂中形成的玻纤预浸料制造而成。但是,该种玻纤板的表面会出现玻纤的编织纹理,也即使得由玻纤板制成的电池盖的表面平整度较差。At present, the back cover of electronic equipment is usually also called a battery cover. In recent years, battery covers have gradually been made of non-metallic materials. Fiberglass boards are a common material used to make battery covers. Fiberglass boards are usually made from fiberglass prepreg formed by impregnating fiberglass cloth in epoxy resin. However, the surface of this kind of fiberglass board will have a woven texture of glass fiber, which means that the surface flatness of the battery cover made of the fiberglass board will be poor.
为提高电池盖的美观度,通常在玻纤板的外侧贴合热熔胶膜,并通过热熔胶贴合基布与PU(poly urethane,聚氨酯)皮,其中PU皮位于基布的外侧,也即通过多层粘贴遮挡玻纤的编织纹理,并将PU皮作为外表层以提高电池盖的美观度。上述电池盖的厚度相对较大,且无法呈现高光效果。In order to improve the aesthetics of the battery cover, a hot melt adhesive film is usually attached to the outside of the fiberglass board, and the base fabric and PU (polyurethane) leather are bonded through hot melt adhesive. The PU leather is located on the outside of the base fabric. That is, the woven texture of the glass fiber is blocked by multi-layer pasting, and the PU leather is used as the outer layer to improve the aesthetics of the battery cover. The thickness of the above-mentioned battery cover is relatively large and cannot produce a high-gloss effect.
发明内容Contents of the invention
本申请提供一种电子设备、壳体及其制作方法,此壳体可呈现高光效果且厚度较小,该种壳体的制作方法用于制备上述壳体,以制作能够呈现高光效果且厚度较小的壳体,该种电子设备的电池盖可采用上述壳体,以呈现高光效果且厚度较小。上述壳体可用作电池盖,以使得电池盖厚度减小且呈现高光效果。This application provides an electronic device, a casing and a manufacturing method thereof. The casing can exhibit a high-gloss effect and has a small thickness. The manufacturing method of the casing is used to prepare the above-mentioned casing to produce a casing that can exhibit a high-gloss effect and has a relatively small thickness. Small casing. The battery cover of this kind of electronic device can use the above-mentioned casing to present a high-gloss effect and have a small thickness. The above-mentioned housing can be used as a battery cover, so that the thickness of the battery cover is reduced and the battery cover presents a high-gloss effect.
所述技术方案如下:The technical solutions are as follows:
本申请第一方面提供一种壳体,包括玻纤板和高光装饰层,所述高光装饰层设置于所述玻纤板的外侧面,所述玻纤板包括至少一层第一玻纤树脂层,所述第一玻纤树脂层包括第一树脂和第一玻纤织物,所述第一树脂的固化收缩率小于百分之一。A first aspect of the application provides a shell, including a fiberglass board and a high-gloss decorative layer. The high-gloss decorative layer is provided on the outer side of the fiberglass board. The fiberglass board includes at least one layer of first fiberglass resin. layer, the first fiberglass resin layer includes a first resin and a first fiberglass fabric, and the curing shrinkage of the first resin is less than one percent.
根据上述技术方案,由于第一树脂的固化收缩率小于百分之一,因此使得第一树脂在形成第一玻纤树脂层时收缩度降低,也即使得第一玻纤树脂层的表面平整度较高,因此无需设置其他额外遮挡物对于表面纹理进行遮挡,直接在第一玻纤树脂层上设置高光装饰层即可形成能够呈现高光效果的壳体,壳体的厚度相对较小。综上,本申请提供的壳体在具备高光效果的同时厚度较小。According to the above technical solution, since the curing shrinkage of the first resin is less than one percent, the shrinkage of the first resin is reduced when forming the first fiberglass resin layer, that is, the surface smoothness of the first fiberglass resin layer is improved. It is relatively high, so there is no need to set up other additional shields to block the surface texture. A high-gloss decorative layer can be directly placed on the first fiberglass resin layer to form a shell that can exhibit a high-gloss effect. The thickness of the shell is relatively small. In summary, the housing provided by this application has a high-gloss effect while being small in thickness.
在一些实现方式中,所述第一树脂的固化收缩率小于千分之五。In some implementations, the curing shrinkage of the first resin is less than five thousandths.
在一些实现方式中,所述第一树脂为苯并噁嗪树脂与双马来酰亚胺树脂的混合树脂、苯并噁嗪树脂或双马来酰亚胺树脂,所述苯并噁嗪树脂与双马来酰亚胺树脂的混合树脂中 苯并噁嗪树脂与双马来酰亚胺树脂的质量比为10%-90%。In some implementations, the first resin is a mixed resin of benzoxazine resin and bismaleimide resin, a benzoxazine resin or a bismaleimide resin, and the benzoxazine resin In mixed resin with bismaleimide resin The mass ratio of benzoxazine resin to bismaleimide resin is 10%-90%.
根据上述技术方案,苯并噁嗪树脂和双马来酰亚胺树脂的固化收缩率均小于百分之一,苯并噁嗪树脂和双马来酰亚胺树脂的混合树脂的固化收缩率位于两者之间,因此,苯并噁嗪树脂和双马来酰亚胺树脂的混合树脂的固化收缩率也小于百分之一,且由于上述两种树脂材料以及其混合树脂用于制作玻纤预浸料的制备过程与环氧树脂制作玻纤预浸料的过程相近,也即是说,可采用原本采用环氧树脂制作玻纤预浸料的设备制备本申请提供的壳体,而无需更换设备。According to the above technical solution, the curing shrinkage of benzoxazine resin and bismaleimide resin is less than one percent, and the curing shrinkage of the mixed resin of benzoxazine resin and bismaleimide resin is between Between the two, therefore, the curing shrinkage of the mixed resin of benzoxazine resin and bismaleimide resin is also less than one percent, and because the above two resin materials and their mixed resin are used to make glass fiber The preparation process of prepreg is similar to the process of making fiberglass prepreg with epoxy resin. That is to say, the shell provided in this application can be prepared using the equipment that originally uses epoxy resin to make fiberglass prepreg. Replace equipment.
在一些实现方式中,所述第一树脂为苯并噁嗪树脂与环氧树脂的混合树脂,所述苯并噁嗪树脂与环氧树脂的混合树脂中,所述苯并噁嗪树脂与环氧树脂的质量比为10%-90%;或,In some implementations, the first resin is a mixed resin of benzoxazine resin and epoxy resin. In the mixed resin of benzoxazine resin and epoxy resin, the benzoxazine resin and epoxy resin are mixed. The mass ratio of oxygen resin is 10%-90%; or,
所述第一树脂为双马来酰亚胺树脂与环氧树脂的混合树脂,所述双马来酰亚胺树脂与环氧树脂的混合树脂中双马来酰亚胺树脂与环氧树脂的质量比为10%-90%。The first resin is a mixed resin of bismaleimide resin and epoxy resin. In the mixed resin of bismaleimide resin and epoxy resin, the ratio between bismaleimide resin and epoxy resin is The mass ratio is 10%-90%.
根据上述技术方案,苯并噁嗪树脂和环氧树脂的混合树脂的固化收缩率、双马来酰亚胺树脂和环氧树脂的混合树脂的固化收缩率均小于百分之一,且可采用原本采用环氧树脂制作玻纤预浸料的设备制备本申请提供的壳体,而无需更换设备。此外,采用苯并噁嗪树脂与环氧树脂的混合树脂,或双马来酰亚胺树脂与环氧树脂的混合树脂均可提高玻纤板的制备效率。According to the above technical solution, the curing shrinkage of the mixed resin of benzoxazine resin and epoxy resin, and the curing shrinkage of the mixed resin of bismaleimide resin and epoxy resin are both less than one percent, and can be used The shell provided in this application can be prepared using equipment originally used to make glass fiber prepreg using epoxy resin, without the need to replace the equipment. In addition, the preparation efficiency of glass fiber boards can be improved by using a mixed resin of benzoxazine resin and epoxy resin, or a mixed resin of bismaleimide resin and epoxy resin.
在一些实现方式中,所述玻纤板包括多层第一玻纤树脂层,多层所述第一玻纤树脂层堆叠以形成所述玻纤板。In some implementations, the fiberglass board includes multiple layers of first fiberglass resin layers, and multiple layers of the first fiberglass resin layers are stacked to form the fiberglass board.
根据上述技术方案,多层第一玻纤树脂层可提高玻纤板的结构强度及刚度,多层第一玻纤树脂层的生产工艺相同,便于生产制造。According to the above technical solution, multiple first glass fiber resin layers can improve the structural strength and stiffness of the glass fiber board. The production process of the multiple first glass fiber resin layers is the same, which facilitates production and manufacturing.
在一些实现方式中,所述第一玻纤树脂层的堆叠数量为3-5层。In some implementations, the number of stacks of the first fiberglass resin layer is 3-5.
根据上述技术方案,3层-5层的第一玻纤树脂层堆叠后形成的玻纤板的刚度和强度相对较强。According to the above technical solution, the rigidity and strength of the fiberglass board formed after stacking 3 to 5 layers of first fiberglass resin layers are relatively strong.
在一些实现方式中,所述第一玻纤树脂层的厚度为0.08mm-0.10mm。In some implementations, the thickness of the first fiberglass resin layer is 0.08mm-0.10mm.
根据上述技术方案,在上述厚度范围内,第一玻纤树脂层在相对较小的厚度下,具备一定的结构强度和刚度。According to the above technical solution, within the above thickness range, the first fiberglass resin layer has a certain structural strength and rigidity at a relatively small thickness.
在一些实现方式中,所述高光装饰层的厚度为0.05mm-0.08mm。In some implementations, the thickness of the high-gloss decorative layer is 0.05mm-0.08mm.
根据上述技术方案,在上述厚度范围内,高光装饰层可遮挡第一玻纤树脂层的外表面以呈现更好的高光效果。According to the above technical solution, within the above thickness range, the high-gloss decorative layer can block the outer surface of the first fiberglass resin layer to present a better high-gloss effect.
在一些实现方式中,所述玻纤板还包括第二玻纤树脂层,所述第二玻纤树脂层的固化收缩率大于所述第一玻纤树脂层的固化收缩率;所述第二玻纤树脂层包括第二树脂和第二玻纤织物,所述第一玻纤树脂层设于所述第二玻纤树脂层所述高光装饰层之间。In some implementations, the fiberglass board further includes a second fiberglass resin layer, and the curing shrinkage rate of the second fiberglass resin layer is greater than the curing shrinkage rate of the first fiberglass resin layer; the second fiberglass resin layer The fiberglass resin layer includes a second resin and a second fiberglass fabric, and the first fiberglass resin layer is provided between the second fiberglass resin layer and the high-gloss decorative layer.
根据上述技术方案,只需保证在玻纤板中,位于最外侧也即用于设置高光装饰层的一层为第一玻纤树脂层,即可使得高光装饰层设置在表面平整度较高的第一玻纤树脂层的表面,从而呈现更好的高光效果,而在非用于设置高光装饰层的其他叠层中,可采用其他材料制备的第二玻纤树脂层。According to the above technical solution, it is only necessary to ensure that the outermost layer of the fiberglass board, that is, the layer used to set the high-gloss decorative layer, is the first fiberglass resin layer, so that the high-gloss decorative layer can be set on a surface with high surface flatness. The surface of the first fiberglass resin layer thus presents a better high-gloss effect, and in other stacks that are not used to provide high-gloss decorative layers, a second fiberglass resin layer made of other materials can be used.
本申请第二方面提供一种电子设备,包括上述技术方案提供的壳体。A second aspect of this application provides an electronic device, including the housing provided by the above technical solution.
根据上述技术方案,由于电子设备中应用有上述壳体,上述壳体的厚度较小且能够呈 现高光效果,因此使得电子设备厚度相对较小且能够呈现高光效果。According to the above technical solution, since the above casing is used in electronic equipment, the thickness of the above casing is small and can be It can produce high-gloss effect, thus making electronic devices relatively small in thickness and capable of showing high-gloss effect.
本申请第三方面提供一种壳体的制作方法,包括:The third aspect of this application provides a method for making a shell, including:
将第一树脂制备形成第一预聚胶液,所述第一树脂的固化收缩率小于百分之一;Preparing a first resin to form a first prepolymer glue solution, the curing shrinkage of the first resin is less than one percent;
将第一玻纤织物浸渍至所述第一预聚胶液以制备第一玻纤预浸料;Impregnating the first fiberglass fabric into the first prepolymer glue solution to prepare a first fiberglass prepreg;
将至少含有所述第一玻纤预浸料的预浸料制成玻纤板,所述玻纤板中所述第一玻纤预浸料形成第一玻纤树脂层,所述玻纤板包括至少一层所述第一玻纤树脂层;Prepreg containing at least the first fiberglass prepreg is made into a fiberglass board, the first fiberglass prepreg in the fiberglass board forms a first fiberglass resin layer, and the fiberglass board including at least one layer of said first fiberglass resin layer;
在所述玻纤板的外侧设置高光装饰层。A high-gloss decorative layer is provided on the outside of the fiberglass board.
根据上述技术方案,由于第一树脂的固化收缩率小于百分之一,因此使得第一树脂在形成第一玻纤树脂层时收缩度降低,也即使得第一玻纤树脂层的表面平整度较高,因此无需设置其他额外遮挡物对于表面纹理进行遮挡,直接在第一玻纤树脂层上设置高光装饰层即可形成能够呈现高光效果的壳体,壳体的厚度相对较小。综上,本申请提供的壳体的制作方法能够制作具备高光效果的同时厚度较小的壳体。According to the above technical solution, since the curing shrinkage of the first resin is less than one percent, the shrinkage of the first resin is reduced when forming the first fiberglass resin layer, that is, the surface smoothness of the first fiberglass resin layer is improved. It is relatively high, so there is no need to set up other additional shields to block the surface texture. A high-gloss decorative layer can be directly placed on the first fiberglass resin layer to form a shell that can exhibit a high-gloss effect. The thickness of the shell is relatively small. In summary, the method for manufacturing a casing provided in this application can produce a casing with a high gloss effect and a small thickness.
在一些实现方式中,所述高光装饰层由高光涂料在所述玻纤板的外侧喷涂形成。In some implementations, the high-gloss decorative layer is formed by spraying high-gloss paint on the outside of the fiberglass board.
根据上述技术方案,由高光涂料喷涂形成的高光装饰层无需增加黏贴层,厚度相对薄。According to the above technical solution, the high-gloss decorative layer formed by spraying high-gloss paint does not need to add an adhesive layer, and the thickness is relatively thin.
在一些实现方式中,将至少含有所述第一玻纤预浸料制成玻纤板包括:In some implementations, producing a fiberglass board containing at least the first fiberglass prepreg includes:
获得多个所述第一玻纤预浸料,将多个所述第一玻纤预浸料堆叠,通过堆叠的多个所述第一玻纤预浸料制备所述玻纤板,所述玻纤板包括多个所述第一玻纤树脂层。Obtain a plurality of first glass fiber prepregs, stack a plurality of first glass fiber prepregs, and prepare the glass fiber board by stacking a plurality of first glass fiber prepregs, The fiberglass board includes a plurality of first fiberglass resin layers.
根据上述技术方案,玻纤板包括多个第一玻纤树脂层,结构强度更高。According to the above technical solution, the fiberglass board includes multiple first fiberglass resin layers, which has higher structural strength.
在一些实现方式中,所述制作方法还包括:In some implementations, the production method further includes:
将第二树脂制备形成第二预聚胶液;Prepare the second resin to form a second prepolymerized glue solution;
将第二玻纤织物浸渍至所述第二预聚胶液以形成第二玻纤预浸料;Impregnating the second fiberglass fabric into the second prepolymer glue solution to form a second fiberglass prepreg;
所述制作方法的将至少含有所述第一玻纤预浸料的预浸料制成玻纤板包括:The manufacturing method of producing a fiberglass board from a prepreg containing at least the first fiberglass prepreg includes:
将至少一层所述第一玻纤预浸料与至少一层所述第二玻纤预浸料堆叠,且使得最外侧的玻纤预浸料为所述第一玻纤预浸料;将堆叠的玻纤预浸料制备形成所述玻纤板,所述玻纤板中所述第一玻纤预浸料形成所述第一玻纤树脂层,所述第二玻纤预浸料形成第二玻纤树脂层;Stack at least one layer of the first fiberglass prepreg and at least one layer of the second fiberglass prepreg such that the outermost fiberglass prepreg is the first fiberglass prepreg; Stacked fiberglass prepregs are prepared to form the fiberglass board, the first fiberglass prepreg in the fiberglass board forms the first fiberglass resin layer, and the second fiberglass prepreg forms the second fiberglass resin layer;
所述制作方法的在所述玻纤板的外侧设置高光装饰层包括:The manufacturing method of providing a high-gloss decorative layer on the outside of the fiberglass board includes:
所述高光装饰层设置于位于最外侧的所述第一玻纤树脂层的外侧面。The high-gloss decorative layer is disposed on the outer side of the outermost first fiberglass resin layer.
根据上述技术方案,只需保证在玻纤板中用于设置高光装饰层的一层为第一玻纤树脂层,即可使得高光装饰层设置在表面平整度较高的第一玻纤树脂层的表面,从而呈现更好的高光效果,而在非用于设置高光装饰层的其他叠层中,可采用环氧树脂制备的第二玻纤树脂层。According to the above technical solution, it is only necessary to ensure that the layer used to set the high-gloss decorative layer in the fiberglass board is the first fiberglass resin layer, so that the high-gloss decorative layer can be set on the first fiberglass resin layer with higher surface flatness. surface, thereby presenting a better high-gloss effect, and in other laminates not used for setting high-gloss decorative layers, a second fiberglass resin layer made of epoxy resin can be used.
附图说明Description of drawings
图1是现有技术中玻纤预浸料的结构示意图;Figure 1 is a schematic structural diagram of glass fiber prepreg in the prior art;
图2是本申请实施例提供的第一玻纤树脂层的结构示意图;Figure 2 is a schematic structural diagram of the first glass fiber resin layer provided by the embodiment of the present application;
图3是本申请实施例提供的壳体的结构示意图一;Figure 3 is a schematic structural diagram of a housing provided by an embodiment of the present application;
图4是本申请实施例提供的壳体的结构示意图二;Figure 4 is a second structural schematic diagram of a housing provided by an embodiment of the present application;
图5是本申请实施例提供的壳体的结构示意图三; Figure 5 is a schematic structural diagram three of the housing provided by the embodiment of the present application;
图6是本申请实施例提供的壳体的结构示意图四;Figure 6 is a schematic structural diagram 4 of a housing provided by an embodiment of the present application;
图7是本申请实施例提供的壳体的结构示意图五;Figure 7 is a schematic structural diagram 5 of the housing provided by the embodiment of the present application;
图8是本申请实施例提供的壳体的结构示意图六;Figure 8 is a schematic structural diagram six of the housing provided by the embodiment of the present application;
图9是本申请实施例提供的壳体的结构示意图七;Figure 9 is a schematic structural diagram of the housing provided by the embodiment of the present application;
图10是本申请实施例提供的壳体的结构示意图八;Figure 10 is a schematic structural diagram of the housing provided by the embodiment of the present application;
图11是本申请实施例提供的壳体的制作方法的流程示意图;Figure 11 is a schematic flow chart of a method for manufacturing a casing provided by an embodiment of the present application;
图12是本申请实施例提供的另一种壳体的制作方法的流程示意图。FIG. 12 is a schematic flowchart of another method for manufacturing a casing provided by an embodiment of the present application.
其中,各附图标号所代表的含义分别为:Among them, the meanings represented by each drawing symbol are:
1、环氧树脂;2、玻纤布;1. Epoxy resin; 2. Glass fiber cloth;
100、玻纤板;110、第一玻纤树脂层;111、第一树脂;112、第一玻纤织物;120、第二玻纤树脂层;200、高光装饰层。100. Fiberglass board; 110. First fiberglass resin layer; 111. First resin; 112. First fiberglass fabric; 120. Second fiberglass resin layer; 200. High-gloss decorative layer.
具体实施方式Detailed ways
为使本申请的目的、技术方案和优点更加清楚,下面将结合附图对本申请的实施方式作进一步地详细描述。In order to make the purpose, technical solutions and advantages of the present application clearer, the embodiments of the present application will be described in further detail below with reference to the accompanying drawings.
应当理解的是,本申请提及的“多个”是指两个或两个以上。在本申请的描述中,除非另有说明,“/”表示或的意思,比如,A/B可以表示A或B;本文中的“和/或”仅仅是一种描述关联对象的关联关系,表示可以存在三种关系,比如,A和/或B,可以表示:单独存在A,同时存在A和B,单独存在B这三种情况。另外,为了便于清楚描述本申请的技术方案,采用了“第一”、“第二”等字样对功能和作用基本相同的相同项或相似项进行区分。本领域技术人员可以理解“第一”、“第二”等字样并不对数量和执行次序进行限定,并且“第一”、“第二”等字样也并不限定一定不同。It should be understood that "plurality" mentioned in this application means two or more. In the description of this application, unless otherwise stated, "/" means or, for example, A/B can mean A or B; "and/or" in this article is just an association relationship describing related objects, It means that there can be three relationships, for example, A and/or B, which can mean: A exists alone, A and B exist simultaneously, and B exists alone. In addition, in order to facilitate a clear description of the technical solution of the present application, words such as “first” and “second” are used to distinguish identical or similar items with basically the same functions and effects. Those skilled in the art can understand that words such as "first" and "second" do not limit the number and execution order, and words such as "first" and "second" do not limit the number and execution order.
在本申请中,玻纤即为玻璃纤维的简称。In this application, glass fiber is the abbreviation of glass fiber.
在常规技术中,电子设备的后盖(也即电池盖)主要由玻纤板和外观装饰层构成,其中玻纤板由玻纤预浸料制成,如图1所示,玻纤预浸料是通过环氧树脂1浸渍玻纤布2来制作,由于环氧树脂1在热固化的过程中固化收缩率较大,导致玻纤板成型后表面漏出玻纤布2的编织纹理,这对于电池盖的外观工艺设计带来较大的挑战。由于环氧树脂1制成的玻纤预浸料的表面平整度较差,因此使得电池盖的外表面通常设置成哑光效果。In conventional technology, the back cover of an electronic device (i.e., battery cover) is mainly composed of a fiberglass board and an exterior decorative layer. The fiberglass board is made of fiberglass prepreg. As shown in Figure 1, the fiberglass prepreg The material is made by impregnating fiberglass cloth 2 with epoxy resin 1. Due to the large curing shrinkage rate of epoxy resin 1 during the thermal curing process, the woven texture of fiberglass cloth 2 leaks out from the surface of the fiberglass board after it is formed. This is not suitable for The appearance and process design of the battery cover poses great challenges. Since the surface flatness of the glass fiber prepreg made of epoxy resin 1 is poor, the outer surface of the battery cover is usually set to a matte effect.
在一种设置方式中,在玻纤板的一侧贴合热熔胶膜,在热熔胶膜背离玻纤板的一侧贴合基布和PU皮,其中PU皮位于在基布背离玻纤板的一侧,也即PU皮位于最外侧。通过热熔胶膜、基布和PU皮对于玻纤板表面的玻纤编织纹理进行遮挡,并通过PU皮形成外观造型。该种设置方式虽然能够遮挡玻纤编织纹理,但是由于PU皮需要一定的厚度支撑,否则手感偏硬,触感舒适度相对较差,因此为了提供PU皮足够的支撑力而设置了较多的遮挡层,导致电池盖的厚度较大(通常大于0.7mm),重量较大,且PU皮呈现哑光纹路,无法实现高光外观设计。In one arrangement, the hot melt adhesive film is attached to one side of the fiberglass board, and the base fabric and PU skin are attached to the side of the hot melt adhesive film facing away from the fiberglass board. The PU skin is located on the side of the base fabric facing away from the glass fiber board. One side of the fiberboard, that is, the PU leather is located on the outermost side. The hot-melt adhesive film, base fabric and PU leather are used to block the fiberglass woven texture on the surface of the fiberglass board, and the PU leather is used to form the appearance. Although this setting method can block the fiberglass woven texture, because the PU leather needs a certain thickness of support, otherwise it will feel hard and the tactile comfort will be relatively poor. Therefore, more shielding is set up to provide sufficient support for the PU leather. layer, resulting in the battery cover being thicker (usually greater than 0.7mm) and heavy, and the PU leather has a matte texture, making it impossible to achieve a high-gloss appearance design.
在另一种设置方式中,在玻纤板的一侧通过OCA(Optically Clear Adhesive,光学胶)粘接哑光装饰膜片,由于哑光装饰膜片的厚度大于0.2mm才能够遮挡玻纤编织纹理,因此使得电池盖的厚度相对较大,且由于哑光装饰膜片的基材通常采用PET(Polyethylene terephthalate,聚对苯二甲酸乙二醇酯),其硬度较低,这会导致工艺制作难度增加,贴合 容易褶皱、起泡,生产制造良率较低。此外,哑光装饰膜片呈现哑光纹路,无法实现高光外观设计。In another setting method, a matte decorative film is bonded to one side of the fiberglass board through OCA (Optically Clear Adhesive). Since the thickness of the matte decorative film is greater than 0.2mm, it can block the fiberglass weave. texture, so the thickness of the battery cover is relatively large, and because the base material of the matte decorative diaphragm is usually PET (Polyethylene terephthalate, polyethylene terephthalate), its hardness is low, which will lead to process Increased difficulty, fit It is prone to wrinkles and blistering, and the manufacturing yield is low. In addition, the matte decorative diaphragm has a matte texture and cannot achieve a high-gloss appearance design.
在又一种设置方式中,在玻纤板的一侧喷涂哑光涂料,其呈现哑光效果,无法实现高光外观设计。In another setting method, matte paint is sprayed on one side of the fiberglass board, which gives a matte effect and cannot achieve a high-gloss appearance design.
在又一种设置方式中,对玻纤预浸料的环氧树脂进行改性,通过提高环氧树脂的固化后交联程度来使得热压的过程中保留更多的环氧树脂覆盖在玻纤表面,从而一定程度上降低因固化收缩而造成的玻纤纹理的可视程度。最后将此改性后的玻纤预浸料作为最外层进行外观装饰。但是该种设置方式一方面使得玻纤预浸料的厚度增加,也即使得其支撑的电池盖的厚度增加,另一方面由于环氧树脂的含量增加,则玻纤板的整体结构强度减弱。此外,由于树脂含量增加,在制作过程中编织玻纤易产生滑动,造成区域性能不良,且环氧树脂的改性使得玻纤板的制备工艺需同步改进,使得工艺流程更为复杂。In another setting method, the epoxy resin of the glass fiber prepreg is modified to increase the cross-linking degree of the epoxy resin after curing so that more epoxy resin can be retained to cover the glass during the hot pressing process. fiber surface, thereby reducing to a certain extent the visibility of the fiberglass texture caused by curing shrinkage. Finally, this modified glass fiber prepreg is used as the outermost layer for appearance decoration. However, this arrangement increases the thickness of the fiberglass prepreg, which increases the thickness of the battery cover it supports. On the other hand, due to the increased content of epoxy resin, the overall structural strength of the fiberglass board weakens. In addition, due to the increase in resin content, the woven glass fiber is prone to slipping during the production process, resulting in poor regional performance. The modification of epoxy resin requires simultaneous improvement of the preparation process of the fiberglass board, making the process more complex.
在其他设置方式中,对玻纤布的玻纤进行改进,采用直径更小的玻纤编织玻纤布,以提高玻纤布的编织密度,以降低其玻纤编制纹路肉眼可视度。但是,采用直径更小的玻纤编织玻纤布一方面导致生产成本大幅上升,且工艺复杂,制程效率降低,另一方面由于直径更小的玻纤编织的玻纤布的厚度降低,因此其结构强度降低,需要堆叠多层玻纤布以制造玻纤板,降低了生产制造效率。此外,即使提高玻纤板的玻纤纹路的密度,其仍然仅能实现哑光效果。In other setting methods, the glass fiber of the fiberglass cloth is improved, and the fiberglass cloth with a smaller diameter is used to weave the fiberglass cloth to increase the weaving density of the fiberglass cloth and reduce the visibility of the fiberglass weaving pattern to the naked eye. However, the use of glass fiber woven fiberglass cloth with a smaller diameter will lead to a significant increase in production costs, complicated processes, and reduced process efficiency. On the other hand, the thickness of the glass fiber woven fiberglass cloth with a smaller diameter will be reduced, so its The structural strength is reduced, and multiple layers of fiberglass cloth need to be stacked to make fiberglass boards, which reduces manufacturing efficiency. In addition, even if the density of the fiberglass texture of the fiberglass board is increased, it can still only achieve a matte effect.
由上可知,在电池盖的生产过程中,若要采用玻纤板作为基材,则通过多种改进方式仍然无法在满足电池盖的结构强度基础上,实现能够呈现高光表面效果且厚度较小这一目的。It can be seen from the above that in the production process of battery covers, if glass fiber boards are used as the base material, it is still impossible to achieve a high-gloss surface effect and a small thickness on the basis of satisfying the structural strength of the battery cover through various improvement methods. this purpose.
有鉴于此,本申请实施例提供一种壳体及其制作方法、电子设备,用于解决上述困扰本领域技术人员的难题。下面对本申请实施例提供的壳体及其制作方法、电子设备进行详细地解释说明。In view of this, embodiments of the present application provide a housing, a manufacturing method thereof, and electronic equipment to solve the above-mentioned problems that trouble those skilled in the art. The housing, its manufacturing method, and the electronic device provided by the embodiments of the present application will be explained in detail below.
第一实施例First embodiment
如图2和图3所示,本实施例提供了一种壳体,其应用于电子设备,可作为电子设备的外壳,或作为电子设备的外壳的一部分,例如其可作为电子设备的外壳中的电池盖。As shown in Figures 2 and 3, this embodiment provides a casing, which is applied to an electronic device and can be used as the casing of the electronic device, or as a part of the casing of the electronic device. For example, it can be used as the casing of the electronic device. battery cover.
壳体包括玻纤板100和高光装饰层200,高光装饰层200设置于玻纤板100的外侧面,玻纤板100包括至少一层第一玻纤树脂层110,第一玻纤树脂层110由第一玻纤预浸料制成,第一玻纤预浸料由将第一玻纤织物浸渍至第一树脂111后形成,第一树脂111的固化收缩率小于百分之一。值得说明的是,玻纤板100由若干第一玻纤预浸料处理得到,在玻纤板中,原本的第一玻纤预浸料经处理后形成的结构称为第一玻纤树脂层110。一层第一玻纤预浸料在处理后形成一层第一玻纤树脂层110。举例来说,第一玻纤预浸料在进行一定时间的烘干处理后形成半固化的结构,将半固化的结构辊压处理成片状结构,并通过若干片状结构再次烘干处理以形成玻纤板,在玻纤板中对应一个片状结构称为一个第一玻纤树脂层110,也即一个第一玻纤树脂层为由第一玻纤织物112浸渍至第一树脂111后形成的第一玻纤预浸料经若干步骤处理后形成的结构。The shell includes a fiberglass board 100 and a high-gloss decorative layer 200. The high-gloss decorative layer 200 is provided on the outer side of the fiberglass board 100. The fiberglass board 100 includes at least one first fiberglass resin layer 110. The first fiberglass resin layer 110 It is made of a first fiberglass prepreg. The first fiberglass prepreg is formed by impregnating a first fiberglass fabric into a first resin 111. The curing shrinkage rate of the first resin 111 is less than one percent. It is worth noting that the fiberglass board 100 is obtained by processing a plurality of first fiberglass prepregs. In the fiberglass board, the structure formed by the original first fiberglass prepregs is called the first fiberglass resin layer. 110. A layer of first fiberglass prepreg is processed to form a layer of first fiberglass resin layer 110 . For example, the first glass fiber prepreg forms a semi-cured structure after being dried for a certain period of time. The semi-cured structure is rolled into a sheet structure, and then dried again through several sheet structures to form a semi-cured structure. To form a fiberglass board, a corresponding sheet structure in the fiberglass board is called a first fiberglass resin layer 110, that is, a first fiberglass resin layer is made of the first fiberglass fabric 112 impregnated with the first resin 111. The structure formed after the first glass fiber prepreg is processed in several steps.
根据上述技术方案,由于第一树脂111的固化收缩率小于百分之一,因此使得第一树脂111在形成第一玻纤树脂层110时收缩度降低,也即使得第一玻纤树脂层110的表面平整度较高,因此无需设置其他额外遮挡物对于表面纹理进行遮挡,直接在第一玻纤树脂层 110上设置高光装饰层200即可形成能够呈现高光效果的壳体,壳体的厚度相对较小。本实施例提供的壳体可用作电子设备的电池盖,也即使得电池盖实现高光效果且厚度较小。According to the above technical solution, since the curing shrinkage of the first resin 111 is less than one percent, the shrinkage of the first resin 111 is reduced when forming the first fiberglass resin layer 110 , that is, the first fiberglass resin layer 110 The surface flatness is relatively high, so there is no need to set up other additional shields to block the surface texture, directly on the first fiberglass resin layer By disposing the high-gloss decorative layer 200 on the housing 110, a shell capable of exhibiting a high-gloss effect can be formed, and the thickness of the shell is relatively small. The housing provided in this embodiment can be used as a battery cover of an electronic device, which means that the battery cover can achieve a high-gloss effect and have a small thickness.
值得说明的是,制造壳体所采用的第一玻纤织物112,可采用常规粗细的玻纤编织玻纤织物,也可选择直径更小的玻纤编织密度更大的玻纤织物。It is worth noting that the first fiberglass fabric 112 used to manufacture the shell can be a glass fiber woven fiberglass fabric with a conventional thickness, or a glass fiber fabric with a smaller diameter and a higher woven density.
第一树脂111的固化收缩率小于百分之一,如此设置,使得第一树脂111与第一玻纤织物112形成的第一玻纤预浸料处理后制成的第一玻纤树脂层110的表面呈现的玻纤编织纹理可视度低,也即使得包含第一玻纤树脂层110的玻纤板100的表面平整度更高,便于在玻纤板100上形成高光装饰层200。The curing shrinkage of the first resin 111 is less than one percent, and is set in such a way that the first fiberglass resin layer 110 is made after processing the first fiberglass prepreg formed by the first resin 111 and the first fiberglass fabric 112 The glass fiber woven texture presented on the surface has low visibility, which means that the surface of the fiberglass board 100 including the first fiberglass resin layer 110 has a higher smoothness, which facilitates the formation of the high-gloss decorative layer 200 on the fiberglass board 100 .
在一些可选实现方式中,第一树脂111的固化收缩率小于千分之五,也即进一步减小第一树脂111在固化过程中的收缩对于玻纤板100的表面平整度的影响,也即更有利于保证玻纤板100的表面满足较高的平整度要求,以在形成高光装饰层200后,呈现更好的高光效果。In some optional implementations, the curing shrinkage rate of the first resin 111 is less than five thousandths, that is, the impact of the shrinkage of the first resin 111 during the curing process on the surface flatness of the fiberglass plate 100 is further reduced, and also That is, it is more conducive to ensuring that the surface of the fiberglass plate 100 meets higher flatness requirements, so that after the high-gloss decorative layer 200 is formed, a better high-gloss effect can be presented.
在一些可选实现方式中,第一树脂111为苯并噁嗪树脂或其改性树脂,双马来酰亚胺树脂或其改性树脂,第一树脂111也可为苯并噁嗪树脂和双马来酰亚胺树脂混合而成的混合树脂,当然,第一树脂111还可为其他固化收缩率小于百分之一甚至小于千分之五的树脂材料。苯并噁嗪树脂的固化收缩率几近于零,双马来酰亚胺树脂的固化收缩率小于千分之七,苯并噁嗪树脂和双马来酰亚胺树脂混合后形成的混合树脂的固化收缩率在零至千分之七之间,若混合树脂中苯并噁嗪树脂占比更高,则混合树脂的固化收缩率更为靠近苯并噁嗪树脂的固化收缩率;若混合树脂中双马来酰亚胺树脂的占比更高,则混合树脂的固化收缩率更为靠近双马来酰亚胺树脂的固化收缩率。也即是说,通过调整混合树脂中苯并噁嗪树脂与环双马来酰亚胺树脂的质量比,可使得苯并噁嗪树脂与环氧树脂的混合树脂的固化收缩率小于千分之五。In some optional implementations, the first resin 111 is a benzoxazine resin or a modified resin thereof, a bismaleimide resin or a modified resin thereof. The first resin 111 may also be a benzoxazine resin and a modified resin thereof. A mixed resin composed of bismaleimide resin. Of course, the first resin 111 can also be other resin materials with a curing shrinkage rate of less than one percent or even less than five thousandths. The curing shrinkage of benzoxazine resin is almost zero, and the curing shrinkage of bismaleimide resin is less than 7 thousandths. The mixed resin formed by mixing benzoxazine resin and bismaleimide resin The curing shrinkage rate is between zero and seven thousandths. If the proportion of benzoxazine resin in the mixed resin is higher, the curing shrinkage rate of the mixed resin will be closer to the curing shrinkage rate of the benzoxazine resin; if the mixed resin If the proportion of bismaleimide resin in the resin is higher, the curing shrinkage rate of the mixed resin will be closer to the curing shrinkage rate of the bismaleimide resin. That is to say, by adjusting the mass ratio of benzoxazine resin and cyclobismaleimide resin in the mixed resin, the curing shrinkage of the mixed resin of benzoxazine resin and epoxy resin can be less than one thousandth. five.
由于采用苯并噁嗪树脂或双马来酰亚胺树脂,或者,第一树脂111也可为苯并噁嗪树脂和双马来酰亚胺树脂混合而成的混合树脂进行第一玻纤树脂层110的制备过程,与常规技术中采用环氧树脂制备第一玻纤树脂层110的过程具有一定的相似度,原有生产设备无需更换,可将原有的生产设备应用于生产本实施例提供的壳体的工艺流程中,作为生产环节的一部分进行使用,节约成本。Since benzoxazine resin or bismaleimide resin is used, or the first resin 111 can also be a mixed resin mixed with benzoxazine resin and bismaleimide resin, the first glass fiber resin The preparation process of the layer 110 is similar to the process of preparing the first fiberglass resin layer 110 using epoxy resin in conventional technology. The original production equipment does not need to be replaced, and the original production equipment can be used to produce this embodiment. In the process flow of the provided shell, it is used as part of the production process to save costs.
当采用苯并噁嗪树脂和双马来酰亚胺树脂混合而成的混合树脂时,苯并噁嗪树脂和双马来酰亚胺树脂的质量比可为10%-90%,例如,混合树脂中包括10份苯并噁嗪树脂和90份双马来酰亚胺树脂;或,混合树脂中包括20份苯并噁嗪树脂和80份双马来酰亚胺树脂;或,混合树脂中包括40份苯并噁嗪树脂和60份双马来酰亚胺树脂;或,混合树脂中包括90份苯并噁嗪树脂和10份双马来酰亚胺树脂;或其他符合苯并噁嗪树脂和双马来酰亚胺树脂的质量比为10%-90%的混合方案。When a mixed resin of benzoxazine resin and bismaleimide resin is used, the mass ratio of benzoxazine resin and bismaleimide resin can be 10%-90%, for example, The resin includes 10 parts of benzoxazine resin and 90 parts of bismaleimide resin; or, the mixed resin includes 20 parts of benzoxazine resin and 80 parts of bismaleimide resin; or, the mixed resin includes Including 40 parts of benzoxazine resin and 60 parts of bismaleimide resin; or, the mixed resin includes 90 parts of benzoxazine resin and 10 parts of bismaleimide resin; or other products that comply with benzoxazine resin The mass ratio of resin and bismaleimide resin is a mixing scheme of 10%-90%.
在一些可选实现方式中,第一树脂111为苯并噁嗪树脂与环氧树脂的混合树脂,苯并噁嗪树脂与环氧树脂的混合树脂的固化收缩率小于百分之一,通过调整混合树脂中苯并噁嗪树脂与环氧树脂的质量比,可使得苯并噁嗪树脂与环氧树脂的混合树脂的固化收缩率小于千分之五。苯并噁嗪树脂与环氧树脂的质量比可为10%-90%,例如,混合树脂中包括10份苯并噁嗪树脂和90份环氧树脂;或,混合树脂中包括30份苯并噁嗪树脂和70份环氧树脂;或,混合树脂中包括60份苯并噁嗪树脂和40份环氧树脂;或,混合树脂中包括 90份苯并噁嗪树脂和10份环氧树脂;或其他符合苯并噁嗪树脂和环氧树脂的质量比为10%-90%的混合方案。优选地,苯并噁嗪树脂与环氧树脂的质量比为20%-30%。In some optional implementations, the first resin 111 is a mixed resin of benzoxazine resin and epoxy resin. The curing shrinkage of the mixed resin of benzoxazine resin and epoxy resin is less than one percent. By adjusting The mass ratio of benzoxazine resin and epoxy resin in the mixed resin can make the curing shrinkage of the mixed resin of benzoxazine resin and epoxy resin less than five thousandths. The mass ratio of benzoxazine resin to epoxy resin can be 10%-90%. For example, the mixed resin includes 10 parts of benzoxazine resin and 90 parts of epoxy resin; or the mixed resin includes 30 parts of benzo oxazine resin and 70 parts epoxy resin; or, the mixed resin includes 60 parts benzoxazine resin and 40 parts epoxy resin; or, the mixed resin includes 90 parts of benzoxazine resin and 10 parts of epoxy resin; or other mixing solutions that meet the mass ratio of benzoxazine resin to epoxy resin of 10%-90%. Preferably, the mass ratio of benzoxazine resin to epoxy resin is 20%-30%.
采用苯并噁嗪树脂与环氧树脂的混合树脂作为第一树脂111,可减少制备玻纤板100时的热压时间,从而提高制备效率。Using a mixed resin of benzoxazine resin and epoxy resin as the first resin 111 can reduce the hot pressing time when preparing the glass fiber board 100, thereby improving the preparation efficiency.
在一些可选实现方式中,第一树脂111为双马来酰亚胺树脂与环氧树脂的混合树脂,双马来酰亚胺树脂与环氧树脂的混合树脂固化收缩率小于百分之一,通过调整混合树脂中双马来酰亚胺树脂与环氧树脂的质量比,可使得双马来酰亚胺树脂与环氧树脂的混合树脂的固化收缩率小于千分之五。双马来酰亚胺树脂与环氧树脂的质量比可为10%-90%,例如,混合树脂中包括10份双马来酰亚胺树脂和90份环氧树脂;或,混合树脂中包括25份双马来酰亚胺树脂和75份环氧树脂;或,混合树脂中包括50份双马来酰亚胺树脂和50份环氧树脂;或,混合树脂中包括90份双马来酰亚胺树脂和10份环氧树脂;或其他符合双马来酰亚胺树脂和环氧树脂的质量比为10%-90%的混合方案。优选地,双马来酰亚胺树脂与环氧树脂的质量比为20%-30%。In some optional implementations, the first resin 111 is a mixed resin of bismaleimide resin and epoxy resin, and the curing shrinkage rate of the mixed resin of bismaleimide resin and epoxy resin is less than one percent. , by adjusting the mass ratio of bismaleimide resin and epoxy resin in the mixed resin, the curing shrinkage of the mixed resin of bismaleimide resin and epoxy resin can be less than five thousandths. The mass ratio of bismaleimide resin to epoxy resin can be 10%-90%. For example, the mixed resin includes 10 parts of bismaleimide resin and 90 parts of epoxy resin; or the mixed resin includes 25 parts bismaleimide resin and 75 parts epoxy resin; or, the mixed resin includes 50 parts bismaleimide resin and 50 parts epoxy resin; or, the mixed resin includes 90 parts bismaleimide resin Imine resin and 10 parts of epoxy resin; or other mixing solutions that meet the mass ratio of bismaleimide resin and epoxy resin at 10%-90%. Preferably, the mass ratio of bismaleimide resin to epoxy resin is 20%-30%.
采用双马来酰亚胺树脂与环氧树脂的混合树脂作为第一树脂111,可减少制备玻纤板100时的热压时间,从而提高制备效率。Using a mixed resin of bismaleimide resin and epoxy resin as the first resin 111 can reduce the hot pressing time when preparing the glass fiber board 100, thereby improving the preparation efficiency.
在本实施例中,高光装饰层200可为高光膜片,高光膜片贴合在玻纤板100的一侧。或者,高光装饰层200可为高光涂层,其为高光涂料喷涂在玻纤板100的一侧形成。In this embodiment, the high-gloss decorative layer 200 can be a high-gloss film, and the high-gloss film is attached to one side of the fiberglass board 100 . Alternatively, the high-gloss decorative layer 200 may be a high-gloss coating, which is formed by spraying high-gloss paint on one side of the fiberglass board 100 .
为提高玻纤板100的结构强度,玻纤板100可由多层玻纤预浸料堆叠制成。In order to improve the structural strength of the fiberglass board 100, the fiberglass board 100 may be made of multiple layers of fiberglass prepreg stacks.
在一种可选实施方式中,如图3所示,多层玻纤预浸料均为第一玻纤树脂层110,也即玻纤板100由多层第一玻纤树脂层110堆叠制造而成。根据上述技术方案,多层第一玻纤树脂层110可提高玻纤板100的结构强度及刚度,多层第一玻纤树脂层110的生产工艺相同,便于生产制造。也即同一条预浸料生产线生产出的第一玻纤树脂层110可作为玻纤板100的任意一层,一条预浸料生产线生产出的多个第一玻纤树脂层110堆叠后以用于制备玻纤板100,一条预浸料生产线占用空间相对较小。In an optional embodiment, as shown in FIG. 3 , the multi-layered fiberglass prepregs are all first fiberglass resin layers 110 , that is, the fiberglass board 100 is manufactured by stacking multiple layers of first fiberglass resin layers 110 Become. According to the above technical solution, the multiple first glass fiber resin layers 110 can improve the structural strength and rigidity of the glass fiber board 100. The production process of the multiple first glass fiber resin layers 110 is the same, which facilitates production and manufacturing. That is to say, the first fiberglass resin layer 110 produced by the same prepreg production line can be used as any layer of the fiberglass board 100, and multiple first fiberglass resin layers 110 produced by a prepreg production line can be stacked for use. For preparing the fiberglass board 100, a prepreg production line takes up relatively little space.
第一玻纤树脂层110的堆叠数量可根据第一玻纤树脂层110的玻纤直径进行选择,玻纤直径减小,则可增加第一玻纤树脂层110的数量。The stacking number of the first glass fiber resin layer 110 can be selected according to the glass fiber diameter of the first glass fiber resin layer 110. As the glass fiber diameter decreases, the number of the first glass fiber resin layer 110 can be increased.
在一种可行实施方式中,采用粗细适中的玻纤编织玻纤织物,通过玻纤织物制造第一玻纤树脂层110,则第一玻纤树脂层110的堆叠数量可选为3-5层,即可使得玻纤板100的刚度和强度相对较强。In a possible implementation, a glass fiber woven fiberglass fabric of moderate thickness is used to manufacture the first fiberglass resin layer 110 through the fiberglass fabric. Then the number of stacks of the first fiberglass resin layer 110 can be 3-5 layers. , which can make the stiffness and strength of the fiberglass board 100 relatively strong.
在一种可行实施方式中,第一玻纤树脂层110的厚度为0.08mm-0.10mm。在上述厚度范围内,第一玻纤树脂层110在相对较小的厚度下,具备一定的结构强度和刚度。In a possible implementation, the thickness of the first fiberglass resin layer 110 is 0.08mm-0.10mm. Within the above thickness range, the first fiberglass resin layer 110 has a certain structural strength and rigidity at a relatively small thickness.
在一种可行实施方式中,高光装饰层200的厚度为0.05mm-0.08mm。在上述厚度范围内,高光装饰层200可遮挡第一玻纤树脂层110的外表面以呈现更好的高光效果。In a possible implementation, the thickness of the high-gloss decorative layer 200 is 0.05mm-0.08mm. Within the above thickness range, the high-gloss decorative layer 200 can block the outer surface of the first fiberglass resin layer 110 to present a better high-gloss effect.
举例来说,若高光装饰层200的厚度为0.05mm,第一玻纤树脂层110的厚度为0.08mm,第一玻纤树脂层110为3层,则壳体的厚度最小为0.29mm。若高光装饰层200的厚度为0.08mm,第一玻纤树脂层110的厚度为0.10mm,第一玻纤树脂层110为3层,则壳体的厚度最小为0.38mm。若高光装饰层200的厚度为0.05mm,第一玻纤树脂层110的厚度为0.08mm,第一玻纤树脂层110为5层,则壳体的厚度最小为0.45mm。若高光装饰层200的厚度为0.08mm,第一玻纤树脂层110的厚度为0.10mm,第一玻纤树脂层110为5层, 则壳体的厚度最小为0.58mm。上述各壳体厚度均相对于常规电池盖厚度(0.7mm)减薄0.12mm-0.41mm。For example, if the thickness of the high-gloss decorative layer 200 is 0.05mm, the thickness of the first fiberglass resin layer 110 is 0.08mm, and the first fiberglass resin layer 110 is three layers, then the minimum thickness of the housing is 0.29mm. If the thickness of the high-gloss decorative layer 200 is 0.08mm, the thickness of the first fiberglass resin layer 110 is 0.10mm, and the first fiberglass resin layer 110 is three layers, then the minimum thickness of the housing is 0.38mm. If the thickness of the high-gloss decorative layer 200 is 0.05mm, the thickness of the first fiberglass resin layer 110 is 0.08mm, and the first fiberglass resin layer 110 is five layers, then the minimum thickness of the housing is 0.45mm. If the thickness of the high-gloss decorative layer 200 is 0.08mm, the thickness of the first fiberglass resin layer 110 is 0.10mm, and the first fiberglass resin layer 110 is five layers, The minimum thickness of the shell is 0.58mm. The thickness of each of the above-mentioned cases is 0.12mm-0.41mm thinner than the thickness of the conventional battery cover (0.7mm).
在另一种可选实施方式中,如图4所示,玻纤板100还包括第二玻纤树脂层120,第二玻纤树脂层120的固化收缩率大于第一玻纤树脂层110的固化收缩率,第二玻纤树脂层120包括第二玻纤织物和第二树脂,可选的,可通过使得第二树脂的固化收缩率大于第一树脂的固化收缩率实现。第二玻纤织物浸渍在第二树脂中形成第二玻纤预浸料,通过若干第二玻纤预浸料和若干第一玻纤预浸料处理形成玻纤板100,在玻纤板100中,由第一玻纤预浸料形成的那部分结构即为第一玻纤树脂层110,由第二玻纤预浸料形成的那部分结构即为第二玻纤树脂层120,也即是说,玻纤板100由多层叠设的玻纤预浸料处理形成,玻纤板100中包括至少一层第一玻纤树脂层110和至少一层第二玻纤树脂层120,至少一层第一玻纤树脂层110叠设在第二玻纤树脂层120的外侧,高光装饰层200位于最外侧的第一玻纤树脂层110的外侧。根据上述技术方案,只需保证在玻纤板100中,位于最外侧也即用于设置高光装饰层200的一层为第一玻纤树脂层110,即可使得高光装饰层200设置在表面平整度较高的第一玻纤树脂层110的表面,从而呈现更好的高光效果,而在非用于设置高光装饰层200的其他叠层中,可采用其他材料制备的第二玻纤树脂层120。In another optional embodiment, as shown in FIG. 4 , the fiberglass board 100 further includes a second fiberglass resin layer 120 , and the curing shrinkage rate of the second fiberglass resin layer 120 is greater than that of the first fiberglass resin layer 110 . Curing shrinkage, the second fiberglass resin layer 120 includes a second fiberglass fabric and a second resin, which can optionally be achieved by making the curing shrinkage of the second resin greater than the curing shrinkage of the first resin. The second fiberglass fabric is impregnated in the second resin to form a second fiberglass prepreg, and the fiberglass board 100 is formed by processing a plurality of second fiberglass prepregs and a plurality of first fiberglass prepregs. In the fiberglass board 100 , the part of the structure formed by the first fiberglass prepreg is the first fiberglass resin layer 110, and the part of the structure formed by the second fiberglass prepreg is the second fiberglass resin layer 120, that is That is to say, the fiberglass board 100 is formed by processing multiple layers of stacked fiberglass prepregs. The fiberglass board 100 includes at least one first layer of fiberglass resin 110 and at least one layer of second fiberglass resin layer 120. The first fiberglass resin layer 110 is stacked on the outside of the second fiberglass resin layer 120 , and the high-gloss decorative layer 200 is located on the outside of the outermost first fiberglass resin layer 110 . According to the above technical solution, it is only necessary to ensure that the outermost layer of the fiberglass board 100 , that is, the layer used to set the high-gloss decorative layer 200 is the first fiberglass resin layer 110 , so that the high-gloss decorative layer 200 can be placed on a smooth surface. The surface of the first fiberglass resin layer 110 has a higher degree of gloss, thereby presenting a better high-gloss effect. In other stacks that are not used to provide the high-gloss decorative layer 200, a second fiberglass resin layer made of other materials can be used. 120.
举例来说,若玻纤板100包括4层玻纤树脂层,则壳体至少具有以下设置方式:For example, if the fiberglass board 100 includes four layers of fiberglass resin, the shell will have at least the following configuration:
第一种设置方式为:如图4所示,第一玻纤树脂层110为一层,第二玻纤树脂层120为三层。则壳体由一侧向另一侧(图4所示方向为由下至上)可分别为:第一层第二玻纤树脂层120-第二层第二玻纤树脂层120-第三层第二玻纤树脂层120-第一玻纤树脂层110-高光装饰层200。The first arrangement method is: as shown in Figure 4, the first fiberglass resin layer 110 is one layer, and the second fiberglass resin layer 120 is three layers. Then the shell from one side to the other side (the direction shown in Figure 4 is from bottom to top) can be respectively: the first layer and the second fiberglass resin layer 120 - the second layer and the second fiberglass resin layer 120 - the third layer The second fiberglass resin layer 120 - the first fiberglass resin layer 110 - the high-gloss decorative layer 200.
第二种设置方式为:第一玻纤树脂层110和第二玻纤树脂层120均为两层。则壳体由一侧向另一侧可具有以下设置方式:①如图5所示,由下至上分别为第一层第一玻纤树脂层110-第一层第二玻纤树脂层120-第二层第二玻纤树脂层120-第二层第一玻纤树脂层110-高光装饰层200。②如图6所示,由下至上分别为第一层第二玻纤树脂层120-第一层第一玻纤树脂层110-第二层第二玻纤树脂层120-第二层第一玻纤树脂层110-高光装饰层200。③如图7所示,由下至上分别为第一层第二玻纤树脂层120-第二层第二玻纤树脂层120-第一层第一玻纤树脂层110-第二层第一玻纤树脂层110-高光装饰层200。The second arrangement mode is: the first fiberglass resin layer 110 and the second fiberglass resin layer 120 are two layers. Then the shell can have the following arrangement from one side to the other: ① As shown in Figure 5, from bottom to top are the first layer of the first fiberglass resin layer 110 - the first layer of the second fiberglass resin layer 120 - The second layer of the second fiberglass resin layer 120 - the second layer of the first fiberglass resin layer 110 - the high-gloss decorative layer 200. ②As shown in Figure 6, from bottom to top, they are the first layer and the second fiberglass resin layer 120-the first layer of the first fiberglass resin layer 110-the second layer and the second fiberglass resin layer 120-the second layer and the first layer. Glass fiber resin layer 110-high gloss decorative layer 200. ③As shown in Figure 7, from bottom to top, they are the first layer of the second fiberglass resin layer 120-the second layer of the second fiberglass resin layer 120-the first layer of the first fiberglass resin layer 110-the second layer of the first fiberglass resin layer. Glass fiber resin layer 110-high gloss decorative layer 200.
第三种设置方式为:第一玻纤树脂层110为三层,第二玻纤树脂层120为一层。则壳体由一侧向另一侧可具有以下设置方式:①如图8所示,由下至上分别为第二玻纤树脂层120-第一层第一玻纤树脂层110-第二层第一玻纤树脂层110-第三层第一玻纤树脂层110-高光装饰层200。②如图9所示,由下至上分别为第一层第一玻纤树脂层110-第二玻纤树脂层120-第二层第一玻纤树脂层110-第三层第一玻纤树脂层110-高光装饰层200。③如图10所示,由下至上分别为第一层第一玻纤树脂层110-第二层第一玻纤树脂层110-第二玻纤树脂层120-第三层第一玻纤树脂层110-高光装饰层200。The third arrangement mode is: the first fiberglass resin layer 110 is three layers, and the second fiberglass resin layer 120 is one layer. Then the shell can have the following arrangement from one side to the other: ① As shown in Figure 8, from bottom to top they are the second fiberglass resin layer 120 - the first layer, the first fiberglass resin layer 110 - the second layer. The first fiberglass resin layer 110 - the third layer, the first fiberglass resin layer 110 - the high-gloss decorative layer 200. ②As shown in Figure 9, from bottom to top, they are the first layer of first fiberglass resin layer 110-the second layer of fiberglass resin 120-the second layer of first fiberglass resin layer 110-the third layer of first fiberglass resin. Layer 110 - High gloss decorative layer 200. ③As shown in Figure 10, from bottom to top, they are the first layer of first fiberglass resin layer 110 - the second layer of first fiberglass resin layer 110 - the second layer of fiberglass resin layer 120 - the third layer of first fiberglass resin Layer 110 - High gloss decorative layer 200.
在玻纤板100同时包括第一玻纤树脂层110和第二玻纤树脂层120时,第一玻纤树脂层110和第二玻纤树脂层120的总和可为3层-5层。第一玻纤树脂层110和第二玻纤树脂层120的厚度均处于0.05mm-0.08mm。When the fiberglass board 100 includes the first fiberglass resin layer 110 and the second fiberglass resin layer 120 at the same time, the total number of the first fiberglass resin layer 110 and the second fiberglass resin layer 120 may be 3 to 5 layers. The thicknesses of the first fiberglass resin layer 110 and the second fiberglass resin layer 120 are both between 0.05mm and 0.08mm.
在一种可选实施方式中,在玻纤板100同时包括第一玻纤树脂层110和第二玻纤树脂层120时,第一玻纤树脂层110的数量至少为两个,将若干第二玻纤树脂层120堆叠后, 在堆叠的若干第二玻纤树脂层120的两侧分别设置有至少一个第一玻纤树脂层110。如此设置,使得由第一玻纤树脂层110和第二玻纤树脂层120制备成的玻纤板100的两侧表面的平整度均较高。In an optional embodiment, when the fiberglass board 100 includes both the first fiberglass resin layer 110 and the second fiberglass resin layer 120, the number of the first fiberglass resin layer 110 is at least two, and several first fiberglass resin layers 110 are included. After the two glass fiber resin layers 120 are stacked, At least one first fiberglass resin layer 110 is provided on both sides of the stacked second fiberglass resin layers 120 . With this arrangement, the flatness of both sides of the fiberglass plate 100 prepared from the first fiberglass resin layer 110 and the second fiberglass resin layer 120 is relatively high.
第二实施例Second embodiment
本实施例提供一种壳体的制作方法,用于制作上述第一实施例提供的壳体。由于上述第一实施例提供的壳体可用作电子设备的电池盖,因此本实施例提供的制作方法也可用于制作电池盖。This embodiment provides a method for manufacturing a casing, which is used to manufacture the casing provided in the first embodiment. Since the housing provided in the above first embodiment can be used as a battery cover of an electronic device, the manufacturing method provided in this embodiment can also be used to manufacture a battery cover.
如图11所示,本实施例提供的壳体的制作方法包括:As shown in Figure 11, the manufacturing method of the housing provided in this embodiment includes:
将第一树脂制备形成第一预聚胶液,第一树脂的固化收缩率小于百分之一;The first resin is prepared to form a first prepolymer glue solution, and the curing shrinkage of the first resin is less than one percent;
将第一玻纤织物浸渍至第一预聚胶液以制备第一玻纤预浸料;Impregnating the first fiberglass fabric into the first prepolymer glue solution to prepare the first fiberglass prepreg;
将至少含有第一玻纤预浸料的预浸料制成玻纤板,在玻纤板中第一博信预浸料形成第一玻纤树脂层,玻纤板包括至少一层第一玻纤树脂层,也即说明,玻纤板由至少一层第一玻纤预浸料处理而成;Prepreg containing at least a first glass fiber prepreg is made into a fiberglass board, in which the first Boxin prepreg forms a first fiberglass resin layer, and the fiberglass board includes at least one layer of first glass fiber The resin layer, that is to say, the fiberglass board is processed by at least one layer of first fiberglass prepreg;
在玻纤板的外侧设置高光装饰层。Set a high-gloss decorative layer on the outside of the fiberglass board.
根据上述技术方案,由于第一树脂的固化收缩率小于百分之一,因此使得第一树脂在形成第一玻纤树脂层时收缩度降低,也即使得第一玻纤树脂层的表面平整度较高,因此无需设置其他额外遮挡物对于表面纹理进行遮挡,直接在第一玻纤树脂层上设置高光装饰层即可形成能够呈现高光效果的壳体,壳体的厚度相对较小。综上,本申请提供的壳体的制作方法能够制作具备高光效果的同时厚度较小的壳体。According to the above technical solution, since the curing shrinkage of the first resin is less than one percent, the shrinkage of the first resin is reduced when forming the first fiberglass resin layer, that is, the surface smoothness of the first fiberglass resin layer is improved. It is relatively high, so there is no need to set up other additional shields to block the surface texture. A high-gloss decorative layer can be directly placed on the first fiberglass resin layer to form a shell that can exhibit a high-gloss effect. The thickness of the shell is relatively small. In summary, the method for manufacturing a casing provided in this application can produce a casing with a high gloss effect and a small thickness.
在一些可选实现方式中,第一树脂的固化收缩率小于千分之五,也即进一步减小第一树脂在固化过程中的收缩对于玻纤板的表面平整度的影响,也即更有利于保证玻纤板的表面满足较高的平整度要求,以在形成高光装饰层后,呈现更好的高光效果。In some optional implementations, the curing shrinkage of the first resin is less than five thousandths, that is, the impact of the shrinkage of the first resin during the curing process on the surface flatness of the fiberglass board is further reduced, that is, it is more It is beneficial to ensure that the surface of the fiberglass board meets higher flatness requirements, so that after the high-gloss decorative layer is formed, a better high-gloss effect can be presented.
具体地,第一树脂可采用苯并噁嗪树脂或其改性树脂,双马来酰亚胺树脂或其改性树脂,第一树脂也可为苯并噁嗪树脂和双马来酰亚胺树脂混合而成的混合物,或者苯并噁嗪树脂和环氧树脂混合而成的混合树脂,或环氧树脂和双马来酰亚胺树脂混合而成的混合树脂,当然,第一树脂还可为其他固化收缩率小于百分之一甚至小于千分之五的树脂材料。Specifically, the first resin can be benzoxazine resin or its modified resin, bismaleimide resin or its modified resin. The first resin can also be benzoxazine resin and bismaleimide. A mixture of resins, or a mixture of benzoxazine resin and epoxy resin, or a mixture of epoxy resin and bismaleimide resin. Of course, the first resin can also be For other resin materials whose curing shrinkage is less than one percent or even less than five thousandths.
当第一树脂111采用苯并噁嗪树脂与环氧树脂的混合树脂时,苯并噁嗪树脂与环氧树脂的混合树脂的固化收缩率小于百分之一,通过调整混合树脂中苯并噁嗪树脂与环氧树脂的质量比,可使得苯并噁嗪树脂与环氧树脂的混合树脂的固化收缩率小于千分之五。苯并噁嗪树脂与环氧树脂的质量比可为10%-90%,例如,混合树脂中包括10份苯并噁嗪树脂和90份环氧树脂;或,混合树脂中包括30份苯并噁嗪树脂和70份环氧树脂;或,混合树脂中包括60份苯并噁嗪树脂和40份环氧树脂;或,混合树脂中包括90份苯并噁嗪树脂和10份环氧树脂;或其他符合苯并噁嗪树脂和环氧树脂的质量比为10%-90%的混合方案。优选地,苯并噁嗪树脂与环氧树脂的质量比为20%-30%。When the first resin 111 is a mixed resin of benzoxazine resin and epoxy resin, the curing shrinkage of the mixed resin of benzoxazine resin and epoxy resin is less than 1%. By adjusting the benzoxazine in the mixed resin, The mass ratio of benzoxazine resin and epoxy resin can make the curing shrinkage of the mixed resin of benzoxazine resin and epoxy resin less than five thousandths. The mass ratio of benzoxazine resin to epoxy resin can be 10%-90%. For example, the mixed resin includes 10 parts of benzoxazine resin and 90 parts of epoxy resin; or the mixed resin includes 30 parts of benzo Oxazine resin and 70 parts of epoxy resin; or, the mixed resin includes 60 parts of benzoxazine resin and 40 parts of epoxy resin; or, the mixed resin includes 90 parts of benzoxazine resin and 10 parts of epoxy resin; Or other mixing solutions that meet the mass ratio of benzoxazine resin and epoxy resin between 10% and 90%. Preferably, the mass ratio of benzoxazine resin to epoxy resin is 20%-30%.
采用苯并噁嗪树脂与环氧树脂的混合树脂作为第一树脂111,可减少制备玻纤板100时的热压时间,从而提高制备效率。Using a mixed resin of benzoxazine resin and epoxy resin as the first resin 111 can reduce the hot pressing time when preparing the glass fiber board 100, thereby improving the preparation efficiency.
当第一树脂111采用双马来酰亚胺树脂与环氧树脂的混合树脂时,双马来酰亚胺树脂与环氧树脂的混合树脂固化收缩率小于百分之一,通过调整混合树脂中双马来酰亚胺树脂 与环氧树脂的质量比,可使得双马来酰亚胺树脂与环氧树脂的混合树脂的固化收缩率小于千分之五。双马来酰亚胺树脂与环氧树脂的质量比可为10%-90%,例如,混合树脂中包括10份双马来酰亚胺树脂和90份环氧树脂;或,混合树脂中包括25份双马来酰亚胺树脂和75份环氧树脂;或,混合树脂中包括50份双马来酰亚胺树脂和50份环氧树脂;或,混合树脂中包括90份双马来酰亚胺树脂和10份环氧树脂;或其他符合双马来酰亚胺树脂和环氧树脂的质量比为10%-90%的混合方案。优选地,双马来酰亚胺树脂与环氧树脂的质量比为20%-30%。When the first resin 111 is a mixed resin of bismaleimide resin and epoxy resin, the curing shrinkage of the mixed resin of bismaleimide resin and epoxy resin is less than 1%. By adjusting the mixed resin bismaleimide resin The mass ratio to epoxy resin can make the curing shrinkage of the mixed resin of bismaleimide resin and epoxy resin less than five thousandths. The mass ratio of bismaleimide resin to epoxy resin can be 10%-90%. For example, the mixed resin includes 10 parts of bismaleimide resin and 90 parts of epoxy resin; or the mixed resin includes 25 parts bismaleimide resin and 75 parts epoxy resin; or, the mixed resin includes 50 parts bismaleimide resin and 50 parts epoxy resin; or, the mixed resin includes 90 parts bismaleimide resin Imine resin and 10 parts of epoxy resin; or other mixing solutions that meet the mass ratio of bismaleimide resin and epoxy resin at 10%-90%. Preferably, the mass ratio of bismaleimide resin to epoxy resin is 20%-30%.
采用双马来酰亚胺树脂与环氧树脂的混合树脂作为第一树脂111,可减少制备玻纤板100时的热压时间,从而提高制备效率。Using a mixed resin of bismaleimide resin and epoxy resin as the first resin 111 can reduce the hot pressing time when preparing the glass fiber board 100, thereby improving the preparation efficiency.
将第一树脂制备形成第一预聚胶液的过程具体包括:将含有第一树脂单体和固化剂的反应液置于反应槽中,在设定温度下于设定时间后形成第一预聚胶液。The process of preparing the first resin to form the first prepolymer glue specifically includes: placing the reaction liquid containing the first resin monomer and the curing agent in a reaction tank, and forming the first prepolymer glue at a set temperature and after a set time. Poly glue liquid.
将第一玻纤织物浸渍至第一预聚胶液以形成第一玻纤预浸料的过程具体包括:将玻纤织物烘干,用第一预聚胶液浸渍烘干后的玻纤织物,将浸渍有第一预聚胶液的玻纤织物通过热辊辊压成设定厚度的层状结构,将层状结构置于设定温度的烘箱中进行热固化处理,以形成半固化的第一玻纤预浸料。The process of impregnating the first glass fiber fabric into the first prepolymer glue solution to form the first glass fiber prepreg specifically includes: drying the glass fiber fabric, and impregnating the dried glass fiber fabric with the first prepolymer glue solution , the glass fiber fabric impregnated with the first prepolymer glue solution is rolled through a hot roller into a layered structure with a set thickness, and the layered structure is placed in an oven at a set temperature for thermal curing treatment to form a semi-cured The first fiberglass prepreg.
在一种设置方式中,将至少含有所述第一玻纤预浸料制成玻纤板包括:In one arrangement, producing a fiberglass board containing at least the first fiberglass prepreg includes:
获得多个第一玻纤预浸料,将多个第一玻纤预浸料堆叠,通过堆叠的多个第一玻纤预浸料制备玻纤板,以使得玻纤板包括多个第一玻纤树脂层。在玻纤板中,一个第一玻纤预浸料对应形成一个第一玻纤树脂层,第一玻纤树脂层为完全固化的第一玻纤预浸料。Obtain a plurality of first fiberglass prepregs, stack the plurality of first fiberglass prepregs, and prepare a fiberglass board through the stacked plurality of first fiberglass prepregs, so that the fiberglass board includes a plurality of first fiberglass prepregs. Fiberglass resin layer. In the fiberglass board, a first fiberglass prepreg corresponds to a first fiberglass resin layer, and the first fiberglass resin layer is a fully cured first fiberglass prepreg.
可选地,将第一玻纤预浸料制成玻纤板的过程具体包括:将第一玻纤预浸料裁剪为设定尺寸,并将多层第一玻纤预浸料进行堆叠,将堆叠后的多层第一玻纤树脂层放入热压模具以热压成型,从而形成玻纤板。Optionally, the process of making the first fiberglass prepreg into a fiberglass board specifically includes: cutting the first fiberglass prepreg into a set size, and stacking multiple layers of the first fiberglass prepreg, The stacked multiple first fiberglass resin layers are put into a hot pressing mold for hot press molding, thereby forming a fiberglass board.
在玻纤板的外侧设置高光装饰层的过程具体可包括:在玻纤板的外侧贴合高光膜片以形成高光装饰层,或者,在玻纤板的外侧喷涂高光涂料以形成高光装饰层。The process of providing a high-gloss decorative layer on the outside of the fiberglass board may specifically include: attaching a high-gloss film to the outside of the fiberglass board to form a high-gloss decorative layer, or spraying high-gloss paint on the outside of the fiberglass board to form a high-gloss decorative layer.
本实施例中,壳体可作为电池盖。以下,以五种具体实施例描述上述制作方法用于制作具有高光效果的电池盖的可选工艺流程:In this embodiment, the casing can serve as a battery cover. Below, five specific embodiments are used to describe the optional process flow of the above-mentioned manufacturing method for manufacturing a battery cover with a high-gloss effect:
在第一种具体实施例中,采用苯并噁嗪树脂作为第一树脂制作电池盖,制作方法可包括:In a first specific embodiment, benzoxazine resin is used as the first resin to make the battery cover. The making method may include:
将含有苯并噁嗪树脂单体和固化剂的反应液置于反应槽中,在70℃的温度下搅拌反应液1h以形成第一预聚胶液;Place the reaction solution containing benzoxazine resin monomer and curing agent in the reaction tank, and stir the reaction solution at a temperature of 70°C for 1 hour to form the first prepolymer glue solution;
将玻纤织物烘干,用第一预聚胶液浸渍烘干后的玻纤织物,将浸渍有第一预聚胶液的玻纤织物通过热辊辊压以形成层状结构,通过调整热辊以使得层状结构的厚度为0.08mm-0.1mm,将层状结构置于130℃的烘箱中热固化1h,从而得到半固化的第一玻纤预浸料;Dry the fiberglass fabric, impregnate the dried glass fiber fabric with the first prepolymer glue solution, roll the fiberglass fabric impregnated with the first prepolymer glue solution through a hot roller to form a layered structure, and adjust the heat Roll so that the thickness of the layered structure is 0.08mm-0.1mm, and place the layered structure in an oven at 130°C for thermal curing for 1 hour to obtain the semi-cured first glass fiber prepreg;
将第一玻纤预浸料裁剪为设定尺寸,并将3层-5层第一玻纤预浸料进行堆叠,将堆叠后的多层第一玻纤预浸料放入热压模具以热压成型,加热温度为180℃,压力为10MPa,保压时间为3h-4h,在冷却后获得玻纤板,在玻纤板中,对应一层第一玻纤预浸料的结构为一层第一玻纤树脂层;Cut the first fiberglass prepreg to the set size, stack 3 to 5 layers of the first fiberglass prepreg, and put the stacked multi-layer first fiberglass prepreg into a hot pressing mold. Hot press molding, the heating temperature is 180°C, the pressure is 10MPa, and the holding time is 3h-4h. After cooling, a glass fiber board is obtained. In the glass fiber board, the structure corresponding to the first layer of glass fiber prepreg is The first fiberglass resin layer;
在玻纤板的外侧喷涂高光涂料以形成高光装饰层,最终获得具有高光效果的电池盖。 Spray high-gloss paint on the outside of the fiberglass board to form a high-gloss decorative layer, and finally obtain a battery cover with a high-gloss effect.
在第二种具体实施例中,采用双马来酰亚胺树脂作为第一树脂制作电池盖,制作方法可包括:In a second specific embodiment, bismaleimide resin is used as the first resin to make the battery cover. The making method may include:
将含有双马来酰亚胺树脂单体和固化剂的反应液置于反应槽中,在130℃-160℃的温度下经过3h-6h预聚形成第一预聚胶液;Place the reaction solution containing bismaleimide resin monomer and curing agent in the reaction tank, and prepolymerize it at a temperature of 130°C-160°C for 3h-6h to form the first prepolymerized glue solution;
将玻纤织物烘干,用第一预聚胶液浸渍烘干后的玻纤织物,将浸渍有第一预聚胶液的玻纤织物通过热辊辊压以形成层状结构,通过调整热辊以使得层状结构的厚度为0.08mm-0.1mm,将层状结构置于130℃的烘箱中热固化1h,从而得到第一玻纤预浸料;Dry the fiberglass fabric, impregnate the dried glass fiber fabric with the first prepolymer glue solution, roll the fiberglass fabric impregnated with the first prepolymer glue solution through a hot roller to form a layered structure, and adjust the heat Roll so that the thickness of the layered structure is 0.08mm-0.1mm, and place the layered structure in an oven at 130°C for thermal curing for 1 hour to obtain the first glass fiber prepreg;
将第一玻纤预浸料裁剪为设定尺寸,并将3层-5层第一玻纤预浸料进行堆叠,将堆叠后的多层第一玻纤预浸料放入热压模具以热压成型,加热温度为180℃,压力为10MPa,保压时间为3h-4h,在冷却后获得玻纤板,在玻纤板中,对应一层第一玻纤预浸料的结构为一层第一玻纤树脂层;Cut the first fiberglass prepreg to the set size, stack 3 to 5 layers of the first fiberglass prepreg, and put the stacked multi-layer first fiberglass prepreg into a hot pressing mold. Hot press molding, the heating temperature is 180°C, the pressure is 10MPa, and the holding time is 3h-4h. After cooling, a glass fiber board is obtained. In the glass fiber board, the structure corresponding to the first layer of glass fiber prepreg is The first fiberglass resin layer;
在玻纤板的外侧喷涂高光涂料以形成高光装饰层,最终获得具有高光效果的电池盖。Spray high-gloss paint on the outside of the fiberglass board to form a high-gloss decorative layer, and finally obtain a battery cover with a high-gloss effect.
在第三种具体实施例中,采用苯并噁嗪树脂和双马来酰亚胺树脂混合而成的混合树脂作为第一树脂制作电池盖,制作方法可包括:In a third specific embodiment, a mixed resin composed of benzoxazine resin and bismaleimide resin is used as the first resin to manufacture the battery cover. The manufacturing method may include:
将含有双马来酰亚胺树脂单体、苯并噁嗪树脂单体和固化剂的反应液置于反应槽中,加热熔融以形成第一预聚胶液;值得说明的是,苯并噁嗪树脂单体和双马来酰亚胺树脂单体的质量比可为10%-90%;The reaction solution containing bismaleimide resin monomer, benzoxazine resin monomer and curing agent is placed in the reaction tank, heated and melted to form the first prepolymer glue solution; it is worth mentioning that benzoxazine The mass ratio of oxazine resin monomer and bismaleimide resin monomer can be 10%-90%;
将第一玻纤织物烘干,用第一预聚胶液浸渍烘干后的第一玻纤织物,将浸渍有第一预聚胶液的第一玻纤织物通过热辊辊压以形成层状结构,通过调整热辊以使得层状结构的厚度为0.08mm-0.1mm,将层状结构置于130℃的烘箱中热固化1h,从而得到半固化的第一玻纤预浸料;Dry the first fiberglass fabric, impregnate the dried first fiberglass fabric with the first prepolymer glue solution, and roll the first fiberglass fabric impregnated with the first prepolymer glue solution through a hot roller to form a layer structure, by adjusting the hot roller so that the thickness of the layered structure is 0.08mm-0.1mm, and placing the layered structure in an oven at 130°C for thermal curing for 1 hour to obtain the semi-cured first glass fiber prepreg;
将第一玻纤树脂层裁剪为设定尺寸,并将3层-5层第一玻纤树脂层进行堆叠,将堆叠后的多层第一玻纤树脂层放入热压模具以热压成型,加热温度为180℃,压力为10MPa,保压时间为3h-4h,在冷却后获得玻纤板,在玻纤板中,对应一层第一玻纤预浸料的结构为一层第一玻纤树脂层;Cut the first fiberglass resin layer to a set size, stack 3 to 5 layers of the first fiberglass resin layer, and put the stacked multiple first fiberglass resin layers into a hot pressing mold for hot pressing molding. , the heating temperature is 180°C, the pressure is 10MPa, and the holding time is 3h-4h. After cooling, a glass fiber board is obtained. In the glass fiber board, the structure corresponding to the first layer of glass fiber prepreg is a layer of first layer. Fiberglass resin layer;
在玻纤板的外侧喷涂高光涂料以形成高光装饰层,最终获得具有高光效果的电池盖。Spray high-gloss paint on the outside of the fiberglass board to form a high-gloss decorative layer, and finally obtain a battery cover with a high-gloss effect.
在第四种具体实施例中,采用苯并噁嗪树脂和环氧树脂混合而成的混合树脂作为第一树脂制作电池盖,制作方法可包括:In a fourth specific embodiment, a mixed resin of benzoxazine resin and epoxy resin is used as the first resin to make the battery cover. The making method may include:
将含有苯并噁嗪树脂单体、环氧树脂单体和固化剂的反应液置于反应槽中,加热熔融以形成第一预聚胶液;值得说明的是,苯并噁嗪树脂单体和环氧树脂单体的质量比可为10%-90%,优选为20%-30%;The reaction solution containing benzoxazine resin monomer, epoxy resin monomer and curing agent is placed in the reaction tank, heated and melted to form the first prepolymer glue solution; it is worth mentioning that the benzoxazine resin monomer The mass ratio to the epoxy resin monomer can be 10%-90%, preferably 20%-30%;
将第一玻纤织物烘干,用第一预聚胶液浸渍烘干后的第一玻纤织物,将浸渍有第一预聚胶液的第一玻纤织物通过热辊辊压以形成层状结构,通过调整热辊以使得层状结构的厚度为0.08mm-0.1mm,将层状结构置于130℃的烘箱中热固化1h,从而得到半固化的第一玻纤预浸料;Dry the first fiberglass fabric, impregnate the dried first fiberglass fabric with the first prepolymer glue solution, and roll the first fiberglass fabric impregnated with the first prepolymer glue solution through a hot roller to form a layer structure, by adjusting the hot roller so that the thickness of the layered structure is 0.08mm-0.1mm, and placing the layered structure in an oven at 130°C for thermal curing for 1 hour to obtain the semi-cured first glass fiber prepreg;
将第一玻纤树脂层裁剪为设定尺寸,并将3层-5层第一玻纤树脂层进行堆叠,将堆叠后的多层第一玻纤树脂层放入热压模具以热压成型,加热温度为180℃,压力为10MPa,保压时间为1h-2h,在冷却后获得玻纤板,在玻纤板中,对应一层第一玻纤预浸料的结构为一层第一玻纤树脂层; Cut the first fiberglass resin layer to a set size, stack 3 to 5 layers of the first fiberglass resin layer, and put the stacked multiple first fiberglass resin layers into a hot pressing mold for hot pressing molding , the heating temperature is 180°C, the pressure is 10MPa, and the pressure holding time is 1h-2h. After cooling, a glass fiber board is obtained. In the glass fiber board, the structure corresponding to the first layer of glass fiber prepreg is a layer of first layer. Fiberglass resin layer;
在玻纤板的外侧喷涂高光涂料以形成高光装饰层,最终获得具有高光效果的电池盖。Spray high-gloss paint on the outside of the fiberglass board to form a high-gloss decorative layer, and finally obtain a battery cover with a high-gloss effect.
在第五种具体实施例中,采用双马来酰亚胺树脂和环氧树脂混合而成的混合树脂作为第一树脂制作电池盖,制作方法可包括:In a fifth specific embodiment, a mixed resin mixed with bismaleimide resin and epoxy resin is used as the first resin to make the battery cover. The making method may include:
将含有双马来酰亚胺树脂单体、环氧树脂单体和固化剂的反应液置于反应槽中,加热熔融以形成第一预聚胶液;值得说明的是,双马来酰亚胺树脂单体和环氧树脂单体的质量比可为10%-90%,优选为20%-30%;The reaction solution containing bismaleimide resin monomer, epoxy resin monomer and curing agent is placed in the reaction tank, heated and melted to form the first prepolymer glue solution; it is worth mentioning that bismaleimide The mass ratio of amine resin monomer and epoxy resin monomer can be 10%-90%, preferably 20%-30%;
将第一玻纤织物烘干,用第一预聚胶液浸渍烘干后的第一玻纤织物,将浸渍有第一预聚胶液的第一玻纤织物通过热辊辊压以形成层状结构,通过调整热辊以使得层状结构的厚度为0.08mm-0.1mm,将层状结构置于130℃的烘箱中热固化1h,从而得到半固化的第一玻纤预浸料;Dry the first fiberglass fabric, impregnate the dried first fiberglass fabric with the first prepolymer glue solution, and roll the first fiberglass fabric impregnated with the first prepolymer glue solution through a hot roller to form a layer structure, by adjusting the hot roller so that the thickness of the layered structure is 0.08mm-0.1mm, and placing the layered structure in an oven at 130°C for thermal curing for 1 hour to obtain the semi-cured first glass fiber prepreg;
将第一玻纤树脂层裁剪为设定尺寸,并将3层-5层第一玻纤树脂层进行堆叠,将堆叠后的多层第一玻纤树脂层放入热压模具以热压成型,加热温度为180℃,压力为10MPa,保压时间为1h-2h,在冷却后获得玻纤板,在玻纤板中,对应一层第一玻纤预浸料的结构为一层第一玻纤树脂层;Cut the first fiberglass resin layer to a set size, stack 3 to 5 layers of the first fiberglass resin layer, and put the stacked multiple first fiberglass resin layers into a hot pressing mold for hot pressing molding , the heating temperature is 180°C, the pressure is 10MPa, and the pressure holding time is 1h-2h. After cooling, a glass fiber board is obtained. In the glass fiber board, the structure corresponding to the first layer of glass fiber prepreg is a layer of first layer. Fiberglass resin layer;
在玻纤板的外侧喷涂高光涂料以形成高光装饰层,最终获得具有高光效果的电池盖。Spray high-gloss paint on the outside of the fiberglass board to form a high-gloss decorative layer, and finally obtain a battery cover with a high-gloss effect.
在一些实现方式中,玻纤板同时包括第一玻纤树脂层和第二玻纤树脂层,如图12所示,壳体的制作方法还包括:In some implementations, the fiberglass board includes both a first fiberglass resin layer and a second fiberglass resin layer. As shown in Figure 12, the manufacturing method of the shell also includes:
将第二树脂制备形成第二预聚胶液;Prepare the second resin to form a second prepolymer glue solution;
将第二玻纤织物浸渍至第二预聚胶液以形成第二玻纤预浸料;Impregnating the second fiberglass fabric into the second prepolymer glue solution to form a second fiberglass prepreg;
制作方法的将至少含有第一玻纤预浸料的预浸料制成玻纤板包括:The production method of making the prepreg containing at least the first fiberglass prepreg into the fiberglass board includes:
将至少一层第一玻纤预浸料与至少一层第二玻纤预浸料堆叠,且使得最外侧的玻纤预浸料为第一玻纤预浸料;将堆叠的玻纤预浸料制备形成玻纤板,玻纤板中第一玻纤预浸料形成第一玻纤树脂层,第二玻纤预浸料形成第二玻纤树脂层;Stack at least one layer of first fiberglass prepreg and at least one layer of second fiberglass prepreg so that the outermost fiberglass prepreg is the first fiberglass prepreg; stack the stacked glass fiber prepregs The materials are prepared to form a fiberglass board, the first fiberglass prepreg in the fiberglass board forms a first fiberglass resin layer, and the second fiberglass prepreg forms a second fiberglass resin layer;
制作方法的在玻纤板的外侧设置高光装饰层包括:The production method of setting a high-gloss decorative layer on the outside of the fiberglass board includes:
高光装饰层设置于位于最外侧的第一玻纤树脂层的外侧面。The high-gloss decorative layer is disposed on the outer surface of the outermost first fiberglass resin layer.
值得说明的是,第二玻纤预浸料的制作过程与第一玻纤预浸料的制作过程可同时进行;也可先进行第一玻纤预浸料的制作过程,后进行第二玻纤预浸料的制作过程;或者先进行第二玻纤预浸料的制作过程,后进行第一玻纤预浸料的制作过程。It is worth noting that the production process of the second glass fiber prepreg and the production process of the first glass fiber prepreg can be carried out at the same time; the production process of the first glass fiber prepreg can also be carried out first, and then the second glass fiber prepreg can be carried out. The manufacturing process of fiber prepreg; or the manufacturing process of the second fiberglass prepreg is carried out first, and then the manufacturing process of the first fiberglass prepreg is carried out.
第二树脂的固化收缩率并不要求在百分之一以下,由于第二树脂制成的第二玻纤树脂层位于第一玻纤树脂层的内侧,而高光装饰层位于第一玻纤树脂层的外侧面,而第一玻纤树脂层的外表面平整度相对较高,因此设置于其外侧的高光装饰层能够呈现较好的高光效果。The curing shrinkage rate of the second resin is not required to be less than 1%, because the second fiberglass resin layer made of the second resin is located inside the first fiberglass resin layer, and the high-gloss decorative layer is located inside the first fiberglass resin layer. The outer surface of the first fiberglass resin layer has a relatively high smoothness, so the high-gloss decorative layer disposed on the outside thereof can present a better high-gloss effect.
举例来说,第二树脂可选用环氧树脂,即使环氧树脂制成的第二玻纤树脂层的表面呈现玻纤编织纹理,也由位于其外侧的第一玻纤树脂层遮挡,因此不会影响设置在第一玻纤树脂层外侧的高光装饰层的外表面的高光效果。For example, the second resin can be epoxy resin. Even if the surface of the second fiberglass resin layer made of epoxy resin exhibits a fiberglass woven texture, it will be blocked by the first fiberglass resin layer located outside it, so it will not It will affect the high-gloss effect of the outer surface of the high-gloss decorative layer provided outside the first fiberglass resin layer.
第三实施例Third embodiment
本实施例提供一种电子设备,包括上述第一实施例提供的壳体。This embodiment provides an electronic device, including the housing provided in the first embodiment.
电子设备可以为电子纸、手机、平板电脑、电视机、智能手环、智能手表、显示器、 笔记本电脑、电子相框等具有壳体的电子产品或部件,本实施例对此不做限定。Electronic devices can be electronic paper, mobile phones, tablets, televisions, smart bracelets, smart watches, monitors, Electronic products or components with casings such as notebook computers and electronic photo frames are not limited in this embodiment.
电子设备可包括显示屏、电池和外壳,壳体可作为外壳或者外壳的一部分。举例来说,外壳包括中框和电池盖,壳体作为电池盖。中框与壳体相连,显示屏安装于中框,显示屏的显示区朝向背离壳体的方向,电池位于显示屏与电池盖之间。The electronic device may include a display screen, a battery, and a housing, which may be the housing or a part of the housing. For example, the casing includes a middle frame and a battery cover, and the casing serves as the battery cover. The middle frame is connected to the casing, the display screen is installed on the middle frame, the display area of the display screen faces away from the casing, and the battery is located between the display screen and the battery cover.
本实施例提供的电子设备,由于其壳体采用固化收缩率小于百分之一的第一树脂制造玻纤预浸料,因此第一玻纤树脂层的表面平整度较高,因此无需设置其他额外遮挡物对于表面纹理进行遮挡,直接在第一玻纤树脂层上设置高光装饰层即可形成能够呈现高光效果的壳体,壳体的厚度相对较小,且重量相对较轻,从而使得电子设备整体厚度相对较小,且重量较轻。壳体在满足结构强度需求的基础上实现了在其表面呈现高光效果的目的,突破了壳体外观设计的技术壁垒,扩展了壳体外观设计的设计范畴,提供了具有高光效果的壳体。值得说明的是,壳体的结构强度需求也即壳体需具有一定程度的结构强度和刚度,以对于电子设备内部的电池等元器件提供防护作用。Since the shell of the electronic device provided in this embodiment is made of glass fiber prepreg using the first resin with a curing shrinkage rate of less than 1%, the surface flatness of the first glass fiber resin layer is relatively high, so there is no need to install other components. The additional shielding object blocks the surface texture, and a high-gloss decorative layer is directly placed on the first fiberglass resin layer to form a shell that can exhibit a high-gloss effect. The thickness of the shell is relatively small and the weight is relatively light, thus making the electronics The overall thickness of the device is relatively small and lightweight. The shell achieves the purpose of presenting a high-gloss effect on its surface on the basis of meeting the structural strength requirements, breaks through the technical barriers of shell appearance design, expands the design scope of the shell appearance design, and provides a shell with a high-gloss effect. It is worth mentioning that the structural strength requirement of the casing means that the casing needs to have a certain degree of structural strength and rigidity to provide protection for batteries and other components inside the electronic device.
以上所述实施例仅用以说明本申请的技术方案,而非对其限制;尽管参照前述实施例对本申请进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本申请各实施例技术方案的精神和范围,均应包含在本申请的保护范围之内。 The above-described embodiments are only used to illustrate the technical solutions of the present application, but not to limit them; although the present application has been described in detail with reference to the foregoing embodiments, those of ordinary skill in the art should understand that they can still implement the above-mentioned implementations. The technical solutions described in the examples are modified, or some of the technical features are equivalently replaced; and these modifications or substitutions do not cause the essence of the corresponding technical solutions to deviate from the spirit and scope of the technical solutions in the embodiments of this application, and should be included in within the protection scope of this application.

Claims (14)

  1. 一种壳体,其特征在于,包括玻纤板和高光装饰层,所述高光装饰层设置于所述玻纤板的外侧面,所述玻纤板包括至少一层第一玻纤树脂层,所述第一玻纤树脂层包括第一树脂和第一玻纤织物,所述第一树脂的固化收缩率小于百分之一。A shell, characterized in that it includes a fiberglass board and a high-gloss decorative layer, the high-gloss decorative layer is provided on the outer side of the fiberglass board, and the fiberglass board includes at least one first fiberglass resin layer, The first fiberglass resin layer includes a first resin and a first fiberglass fabric, and the curing shrinkage of the first resin is less than one percent.
  2. 如权利要求1所述的壳体,其特征在于,所述第一树脂的固化收缩率小于千分之五。The shell of claim 1, wherein the curing shrinkage of the first resin is less than five thousandths.
  3. 如权利要求1或2所述的壳体,其特征在于,所述第一树脂为苯并噁嗪树脂与双马来酰亚胺树脂的混合树脂、苯并噁嗪树脂或双马来酰亚胺树脂,所述苯并噁嗪树脂与双马来酰亚胺树脂的混合树脂中苯并噁嗪树脂与双马来酰亚胺树脂的质量比为10%-90%。The shell of claim 1 or 2, wherein the first resin is a mixed resin of benzoxazine resin and bismaleimide resin, benzoxazine resin or bismaleimide resin. Amine resin, the mass ratio of benzoxazine resin to bismaleimide resin in the mixed resin of benzoxazine resin and bismaleimide resin is 10%-90%.
  4. 如权利要求1或2所述的壳体,其特征在于,所述第一树脂为苯并噁嗪树脂与环氧树脂的混合树脂,所述苯并噁嗪树脂与环氧树脂的混合树脂中,所述苯并噁嗪树脂与环氧树脂的质量比为10%-90%;或,The shell of claim 1 or 2, wherein the first resin is a mixed resin of benzoxazine resin and epoxy resin, and the mixed resin of benzoxazine resin and epoxy resin is , the mass ratio of the benzoxazine resin to the epoxy resin is 10%-90%; or,
    所述第一树脂为双马来酰亚胺树脂与环氧树脂的混合树脂,所述双马来酰亚胺树脂与环氧树脂的混合树脂中双马来酰亚胺树脂与环氧树脂的质量比为10%-90%。The first resin is a mixed resin of bismaleimide resin and epoxy resin. In the mixed resin of bismaleimide resin and epoxy resin, the ratio between bismaleimide resin and epoxy resin is The mass ratio is 10%-90%.
  5. 如权利要求1或2所述的壳体,其特征在于,所述玻纤板包括多层第一玻纤树脂层,多层所述第一玻纤树脂层堆叠以形成所述玻纤板。The shell of claim 1 or 2, wherein the fiberglass board includes multiple first fiberglass resin layers, and multiple layers of the first fiberglass resin layers are stacked to form the fiberglass board.
  6. 如权利要求5所述的壳体,其特征在于,所述第一玻纤树脂层的堆叠数量为3层-5层。The shell of claim 5, wherein the number of stacks of the first fiberglass resin layers is 3-5 layers.
  7. 如权利要求5所述的壳体,其特征在于,所述第一玻纤树脂层的厚度为0.08mm-0.10mm。The shell of claim 5, wherein the thickness of the first fiberglass resin layer is 0.08mm-0.10mm.
  8. 如权利要求1或2所述的壳体,其特征在于,所述高光装饰层的厚度为0.05mm-0.08mm。The shell according to claim 1 or 2, characterized in that the thickness of the high-gloss decorative layer is 0.05mm-0.08mm.
  9. 如权利要求1或2所述的壳体,其特征在于,所述玻纤板还包括第二玻纤树脂层,所述第二玻纤树脂层的固化收缩率大于所述第一玻纤树脂层的固化收缩率;所述第二玻纤树脂层包括第二树脂和第二玻纤织物,所述第一玻纤树脂层设于所述第二玻纤树脂层所述高光装饰层之间。The shell of claim 1 or 2, wherein the fiberglass board further includes a second fiberglass resin layer, and the curing shrinkage of the second fiberglass resin layer is greater than that of the first fiberglass resin. The curing shrinkage of the layer; the second fiberglass resin layer includes a second resin and a second fiberglass fabric, and the first fiberglass resin layer is provided between the second fiberglass resin layer and the high-gloss decorative layer .
  10. 一种电子设备,其特征在于,所述电子设备包括如权利要求1-9任一项所述的壳体。An electronic device, characterized in that the electronic device includes the housing according to any one of claims 1-9.
  11. 一种壳体的制作方法,其特征在于,适用于如权利要求1-9任一项所述的壳体,所述制作方法包括:A method for manufacturing a shell, which is suitable for the shell according to any one of claims 1 to 9, and the manufacturing method includes:
    将第一树脂制备形成第一预聚胶液,所述第一树脂的固化收缩率小于百分之一;Preparing a first resin to form a first prepolymer glue solution, the curing shrinkage of the first resin is less than one percent;
    将第一玻纤织物浸渍至所述第一预聚胶液以制备第一玻纤预浸料;Impregnating the first fiberglass fabric into the first prepolymer glue solution to prepare a first fiberglass prepreg;
    将至少含有所述第一玻纤预浸料的预浸料制成玻纤板,所述玻纤板中所述第一玻纤预浸料形成第一玻纤树脂层,所述玻纤板包括至少一层所述第一玻纤树脂层;Prepreg containing at least the first fiberglass prepreg is made into a fiberglass board, the first fiberglass prepreg in the fiberglass board forms a first fiberglass resin layer, and the fiberglass board Includes at least one layer of said first fiberglass resin layer;
    在所述玻纤板的外侧设置高光装饰层。A high-gloss decorative layer is provided on the outside of the fiberglass board.
  12. 如权利要求11所述的制作方法,其特征在于,所述高光装饰层由高光涂料在所述玻纤板的外侧喷涂形成。The manufacturing method according to claim 11, wherein the high-gloss decorative layer is formed by spraying high-gloss paint on the outside of the fiberglass board.
  13. 如权利要求11所述的制作方法,其特征在于,将至少含有所述第一玻纤预浸料制成玻纤板包括:The manufacturing method according to claim 11, characterized in that producing a glass fiber board containing at least the first glass fiber prepreg includes:
    获得多个所述第一玻纤预浸料,将多个所述第一玻纤预浸料堆叠,通过堆叠的多个所 述第一玻纤预浸料制备所述玻纤板,所述玻纤板包括多个所述第一玻纤树脂层。Obtain a plurality of first glass fiber prepregs, stack a plurality of first glass fiber prepregs, and pass the stacked plurality of first glass fiber prepregs The first fiberglass prepreg is used to prepare the fiberglass board, and the fiberglass board includes a plurality of first fiberglass resin layers.
  14. 如权利要求11所述的制作方法,其特征在于,所述制作方法还包括:The manufacturing method according to claim 11, characterized in that, the manufacturing method further includes:
    将第二树脂制备形成第二预聚胶液;Prepare the second resin to form a second prepolymer glue solution;
    将第二玻纤织物浸渍至所述第二预聚胶液以形成第二玻纤预浸料;Impregnating the second fiberglass fabric into the second prepolymer glue solution to form a second fiberglass prepreg;
    所述制作方法的将至少含有所述第一玻纤预浸料的预浸料制成玻纤板包括:The manufacturing method of producing a fiberglass board from a prepreg containing at least the first fiberglass prepreg includes:
    将至少一层所述第一玻纤预浸料与至少一层所述第二玻纤预浸料堆叠,且使得最外侧的玻纤预浸料为所述第一玻纤预浸料;将堆叠的玻纤预浸料制备形成所述玻纤板,所述玻纤板中所述第一玻纤预浸料形成所述第一玻纤树脂层,所述第二玻纤预浸料形成第二玻纤树脂层;Stack at least one layer of the first fiberglass prepreg and at least one layer of the second fiberglass prepreg such that the outermost fiberglass prepreg is the first fiberglass prepreg; Stacked fiberglass prepregs are prepared to form the fiberglass board, the first fiberglass prepreg in the fiberglass board forms the first fiberglass resin layer, and the second fiberglass prepreg forms the second fiberglass resin layer;
    所述制作方法的在所述玻纤板的外侧设置高光装饰层包括:The manufacturing method of providing a high-gloss decorative layer on the outside of the fiberglass board includes:
    所述高光装饰层设置于位于最外侧的所述第一玻纤树脂层的外侧面。 The high-gloss decorative layer is disposed on the outer side of the outermost first fiberglass resin layer.
PCT/CN2023/090904 2022-08-31 2023-04-26 Electronic device, housing and manufacturing method therefor WO2024045662A1 (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN205915763U (en) * 2016-07-13 2017-02-01 深圳正峰印刷有限公司 Casing for electronic equipment
CN106928478A (en) * 2016-10-20 2017-07-07 蓝星(成都)新材料有限公司 A kind of preparation method of benzoxazine colophony laminate
CN108638729A (en) * 2018-04-13 2018-10-12 Oppo广东移动通信有限公司 Shell and preparation method thereof, mobile terminal
JP2019077158A (en) * 2017-10-27 2019-05-23 凸版印刷株式会社 Decorative sheet, decorative plate, method for producing decorative sheet, and method for producing decorative plate
CN215897772U (en) * 2021-08-13 2022-02-22 惠州市众力电子科技有限公司 Take fine 3D cell-phone shell of transparent glass of texture
CN114899539A (en) * 2022-04-29 2022-08-12 华为技术有限公司 Shell assembly, preparation method of shell assembly and electronic equipment

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN205915763U (en) * 2016-07-13 2017-02-01 深圳正峰印刷有限公司 Casing for electronic equipment
CN106928478A (en) * 2016-10-20 2017-07-07 蓝星(成都)新材料有限公司 A kind of preparation method of benzoxazine colophony laminate
JP2019077158A (en) * 2017-10-27 2019-05-23 凸版印刷株式会社 Decorative sheet, decorative plate, method for producing decorative sheet, and method for producing decorative plate
CN108638729A (en) * 2018-04-13 2018-10-12 Oppo广东移动通信有限公司 Shell and preparation method thereof, mobile terminal
CN215897772U (en) * 2021-08-13 2022-02-22 惠州市众力电子科技有限公司 Take fine 3D cell-phone shell of transparent glass of texture
CN114899539A (en) * 2022-04-29 2022-08-12 华为技术有限公司 Shell assembly, preparation method of shell assembly and electronic equipment

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