WO2024031313A1 - Electrode sheet, electrochemical apparatus, and electronic device - Google Patents

Electrode sheet, electrochemical apparatus, and electronic device Download PDF

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Publication number
WO2024031313A1
WO2024031313A1 PCT/CN2022/111078 CN2022111078W WO2024031313A1 WO 2024031313 A1 WO2024031313 A1 WO 2024031313A1 CN 2022111078 W CN2022111078 W CN 2022111078W WO 2024031313 A1 WO2024031313 A1 WO 2024031313A1
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WO
WIPO (PCT)
Prior art keywords
tab
pole
pole piece
current collector
angle
Prior art date
Application number
PCT/CN2022/111078
Other languages
French (fr)
Chinese (zh)
Inventor
陈腾腾
邓道林
陈文�
王冰
Original Assignee
宁德新能源科技有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 宁德新能源科技有限公司 filed Critical 宁德新能源科技有限公司
Priority to CN202280010313.8A priority Critical patent/CN116848721A/en
Priority to PCT/CN2022/111078 priority patent/WO2024031313A1/en
Publication of WO2024031313A1 publication Critical patent/WO2024031313A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/531Electrode connections inside a battery casing
    • H01M50/533Electrode connections inside a battery casing characterised by the shape of the leads or tabs

Definitions

  • the present application relates to the field of battery technology, and in particular to a pole piece, an electrochemical device and an electronic device.
  • Batteries with multi-lug structure pole pieces because the pole pieces lead out tabs in the multiple winding layers of the battery core, greatly shorten the electronic conduction path, can greatly reduce the internal resistance of the battery, thus meeting the needs of mobile phones, laptops, Demand for high-magnification applications such as drones, power tools, electric vehicles, and electric two-wheelers.
  • the present application provides a pole piece, an electrochemical device and an electronic device, which can effectively improve the folding and interpolation phenomenon of the tab during the production process and improve the production efficiency of the electrochemical device.
  • the present application provides a pole piece, including a current collector and a pole tab; the pole tab is connected to the current collector; and an end corner of the pole tab away from the current collector is provided with a chamfered portion. .
  • a chamfered portion at the end corner of the end of the tab away from the current collector, the swing stiffness and torsional stiffness of the tab can be improved, thus suppressing the tab from being folded or interpolated during the winding process of the pole piece, and improving the electrical power. Production excellence rate of chemical plants.
  • chamfered portions are provided at both end corners of the end of the pole tab away from the current collector. Cut corners are provided at both end corners, which is beneficial to improving the swing stiffness and torsional stiffness on both sides of the tab, and further suppresses the phenomenon of folding and interpolation of the tab during the winding process of the pole piece.
  • the outer edge of the chamfered portion is independently selected from any one of a straight line, an outer convex arc, or an inner concave arc.
  • the tab is formed by an extension of the current collector. At this time, on the one hand, the connection strength between the tab and the current collector can be improved and the risk of the tab falling off can be reduced; on the other hand, the manufacturing of the tab can be greatly simplified and the processing efficiency can be improved.
  • the pole piece includes a plurality of the tabs.
  • the pole piece includes a plurality of the pole tabs, which can greatly improve the rate performance of the electrochemical device, thereby better meeting the needs of high-rate applications.
  • the outer edge of the chamfered portion has a first endpoint and a second endpoint;
  • the tab is provided with a first side and a bottom side connected to the current collector, and the first side One end of the side is connected to the bottom side, and the other end of the first side is connected to the first endpoint;
  • the angle between the first side and the bottom side is ⁇ , and the first end
  • ⁇ - ⁇ 9° In some embodiments, ⁇ - ⁇ 15°.
  • the swing and twist of the pole tab at the end can be further restricted, thereby further suppressing the phenomenon of folding and interpolation of the pole tab during the winding process of the pole piece.
  • the first side and the bottom edge are set at an acute angle, and the width of the pole gradually narrows in the direction away from the current collector, which can further increase the swing stiffness and torsional stiffness of the pole at the end, thereby further suppressing the polarity.
  • the ears appear to be folded and interpolated during the winding process of the pole piece.
  • ⁇ - ⁇ 75° In some embodiments, ⁇ - ⁇ 75°.
  • the bottom edge width of the pole tab is L
  • the height of the pole tab is H
  • the top edge width of the pole tab is 2l
  • the width direction of the pole tab is in the same direction as the collector.
  • the length direction of the fluid is parallel
  • the height direction of the pole tab is perpendicular to the length direction of the current collector, satisfying: 0 ⁇ l ⁇ 0.8(L/2-H/tan ⁇ ).
  • the swing and twist of the pole tab at the end can be further restricted, thereby further suppressing the phenomenon of folding and interpolation of the pole tab during the winding process of the pole piece.
  • the length of the first side is h, which satisfies: 0.2H/sin ⁇ h ⁇ 0.8H/sin ⁇ .
  • the swing and twist of the pole tab at the end can be further restricted, thereby further suppressing the phenomenon of folding and interpolation of the pole tab during the winding process of the pole piece.
  • this application also provides a method for preparing an electric core, including the step of winding the pole piece described in any one of the above.
  • the present application also provides an electrochemical device, including the pole piece described in any one of the above or the electric core prepared by the above preparation method.
  • the present application also provides an electronic device, including the electrochemical device described in any one of the above.
  • This application can improve the swing stiffness and torsional stiffness of the pole tab by arranging a chamfered portion at the end corner of the pole tab away from the current collector.
  • the number of pole tab folds during the winding process of the pole piece described in this application Significantly reduced, the corresponding rate of cell production failure is also significantly reduced; therefore, it can effectively improve the folding and interpolation phenomenon of the tabs during the pole piece winding process, and improve the production efficiency of electrochemical devices.
  • Figure 1 is a schematic diagram of the tab structure (base tab) of the prior art
  • Figure 2 is a schematic structural diagram of the cut-angle tab described in this application.
  • Figure 3 is a schematic structural diagram of a straight-line angle cutter in the embodiment of the present application.
  • Figure 4 is a schematic structural diagram of the angle-cut pole tab in the embodiment of the present application, which is a concave arc-shaped angle;
  • Figure 5 is a schematic structural diagram of the angle-cut pole in the embodiment of the present application, which is an external convex arc-shaped angle;
  • Figure 6 is a schematic diagram of parameters in which the angle-cut tab is a straight-line angle cutter in the embodiment of the present application;
  • Figure 7 is a schematic diagram of specific parameters of the angle-cut tab in the embodiment of the present application.
  • Figure 8 is a picture of the modal analysis results of the tab structure (base tab) of the prior art.
  • Figure 1 shows a base tab structure in the prior art. It is usually an isosceles trapezoid tab, that is, the outer contour of the tab is an isosceles trapezoid structure.
  • the inventor of this application has found that during the winding process of the pole piece, the existing base tab is prone to folding and interpolation. Especially for batteries with multi-lug structure pole pieces, there are many poles in the battery core. For pole pieces with tab structures, the probability of tab folding and interpolation during the winding process is greatly increased, seriously affecting the production efficiency.
  • this application proposes a pole piece, an electrochemical device and an electronic device to improve or at least partially solve the above technical problems.
  • the pole piece includes: a current collector 1 and a pole tab 2 (sometimes also called a cut-angle tab in the text); the pole tab 2 is connected to the current collector 1; specifically, the pole tab 2 The end of one side close to the current collector 1 is connected to the current collector 1.
  • the connection can be integrally formed, bonded, welded or other fixed methods, as long as the tab 2 and the current collector can be realized. 1 only needs to be fixedly connected, and this application is not limited to this.
  • the pole tab 2 is formed by extending the current collector 1. At this time, the pole tab 2 and the current collector 1 1 is formed in one piece.
  • the corresponding pole tab 2 can be obtained by cutting the empty foil area on the edge of the current collector 1, which greatly simplifies the manufacturing of pole tab 2 and improves the processing efficiency;
  • a corner cutout 21 is provided at an end corner of the other end of the pole tab 2 away from the current collector 1 .
  • one end corner of the outer end of the pole lug 2 is provided with the chamfered portion 21; or in other examples, both sides of the outer end of the pole lug 2 are The end corners are provided with the chamfered portions 21 .
  • chamfered portions 21 are provided at both corners of the end of the pole tab 2 away from the current collector 1; the two chamfered portions 21 are provided on the The end corners of the outer ends of the pole tabs 2 are centrally symmetrical, which is beneficial to improving the swing stiffness and torsional stiffness on both sides of the pole tabs 2 and further inhibiting the pole tabs 2 from folding or folding during the winding process of the pole pieces. interpolation phenomenon.
  • the outer edge 211 of the chamfered portion 21 is independently selected from any one of a straight line, an outer convex arc, or an inner concave arc.
  • the chamfered portion 21 is provided at an end corner of the end of the pole lug 2 away from the current collector 1 , and the outer edge 211 of the chamfered portion 21 may be a straight line. , it may be an outer convex arc, or it may be an inner concave arc; preferably, the outer edge 211 of the chamfered portion 21 is an inner concave arc. In other examples, chamfered portions 21 are provided at both end corners of the end of the pole lug 2 away from the current collector 1 , and the outer edges 211 of the two chamfered portions 21 are the same.
  • the outer edges 211 of the two chamfered portions 21 are both concave arcs.
  • chamfered portions 21 are provided at both end corners of the end of the pole lug 2 away from the current collector 1 , and the outer edges 211 of the two chamfered portions 21 are different.
  • the outer edge 211 of one of the chamfered portions 21 is a straight line, and the outer edge 211 of the other chamfered portion 21 is a convex arc or a concave arc.
  • chamfered portions 21 are provided at both corners of the outer end of the pole lug 2 , and the outer edges 211 of the two chamfered portions 21 are both straight and centrally symmetrical. , at this time, it can be said that the two end corners of the outer end of the pole tab 2 are provided with straight-line chamfers.
  • the two corners of the outer end of the pole lug 2 are provided with chamfered portions 21, and the outer edges 211 of the two chamfered portions 21 are both concave arcs and are in the shape of a concave arc.
  • the pole tab 2 is arranged symmetrically at the center. At this time, it can be said that the two end corners of the outer end of the pole tab 2 are provided with concave arc-cut corners.
  • chamfered portions 21 are provided at both corners of the outer end of the pole lug 2 , and the outer edges 211 of the two chamfered portions 21 are both convex arcs.
  • the pole tab 2 is arranged symmetrically at the center. At this time, it can be said that the two end corners of the outer end of the pole tab 2 are provided with convex arc-cut corners.
  • the pole lug 2 can be raised to the outer end.
  • the swing stiffness and torsional stiffness are thereby suppressed from the phenomenon of folding and interpolation of the pole tab 2 during the winding process of the pole piece; the horizontal line is a straight line parallel to the bottom edge.
  • the pole piece satisfies ⁇ - ⁇ 9°.
  • ⁇ - ⁇ 9° the swing stiffness and torsional stiffness of the pole tab 2 at the outer end can be improved, thereby further suppressing the phenomenon of folding and interpolation of the pole tab 2 during the pole piece winding process.
  • the ⁇ and ⁇ differences ( ⁇ - ⁇ ) are 9°, 15°, 20°, 25°, 30°, 35°, 40°, 45°, 50°, 55°, 60°, 65° , 70°, 75°, 80° or a range consisting of any two of the above values.
  • the pole piece satisfies ⁇ - ⁇ 15°; at this time, the swing and torsion of the pole tab 2 at the outer end can be further restricted, thereby further suppressing the movement of the pole tab 2 at the pole piece. Folding and interpolation phenomena occur during the winding process.
  • the pole piece satisfies ⁇ - ⁇ 75°.
  • the pole piece satisfies 0° ⁇ 90°.
  • the value range of ⁇ is 10°, 20°, 40°, 60°, 80°, 86°, 90° or a range consisting of any two of the above values.
  • the pole piece satisfies 40° ⁇ 86°; at this time, the first side and the bottom edge are set at an acute angle, and the width of the pole piece gradually narrows in the direction away from the current collector, which can further The swing stiffness of the pole tab 2 at the outer end is increased, thereby further suppressing the phenomenon of folding and interpolation of the pole tab 2 during the winding process of the pole piece.
  • the bottom width of the pole tab 2 is L
  • the height of the pole tab 2 is H
  • the top edge width of the pole tab 2 is 2l, which satisfies: 0 ⁇ l ⁇ 0.8(L/2- H/tan ⁇ ); wherein, the width direction of the pole tab 2 is parallel to the length direction of the current collector 1 , and the height direction of the pole tab 2 is perpendicular to the length direction of the current collector 1 .
  • (L/2-H/tan ⁇ ) is the top half width of the base tab
  • (L/2-H/tan ⁇ ) is recorded as parameter B.
  • the top half-width l of the pole tab 2 ranges from 0 to 0.8B, that is, relative to the top half-width of the base tab, the cut length is B-l (i.e., the top half-width in Figure 6
  • the extension line of one end of the side half-width l extends to the distance when it intersects the extension line of the first side h).
  • the half-width l of the top edge of the pole lug 2 is 0, 0.01B, 0.1B, 0.15B, 0.2B, 0.25B, 0.3B, 0.35B, 0.4B, 0.6B, 0.8B or any of the above A range of two values.
  • the half-width l of the top edge of the pole lug 2 satisfies: 0 ⁇ l ⁇ 0.4(L/2-H/tan ⁇ ); that is, l satisfies: 0 ⁇ l ⁇ 0.4B.
  • the swing and twist of the pole tab 2 at the outer end can be further restricted, thereby further suppressing the phenomenon of folding and interpolation of the pole tab 2 during the winding process of the pole piece.
  • the length of the first side is h, which satisfies: 0.2H/sin ⁇ h ⁇ 0.8H/sin ⁇ .
  • H/sin ⁇ is the length of the hypotenuse of the base tab, one end of the hypotenuse of the base tab is connected to its top edge, and the other end of the hypotenuse of the base tab is connected to its bottom edge.
  • the length of the first side of the tab 2 ranges from 0.2A to 0.8A. That is, the actual cut length of the hypotenuse of the base tab is A-h (that is, the distance when the extension line of the first side h in Figure 6 extends to intersects the extension line of the top half-width l).
  • the length h of the first side is a range of 0.2A, 0.3A, 0.4A, 0.5A, 0.6A, 0.7A, 0.8A or any two of the above values.
  • the length h of the first side satisfies: 0.3H/sin ⁇ h ⁇ 0.7H/sin ⁇ ; that is, h satisfies: 0.3A ⁇ h ⁇ 0.7A.
  • the swing and twist of the pole tab 2 at the outer end can be further restricted, thereby further suppressing the phenomenon of folding and interpolation of the pole tab 2 during the winding process of the pole piece.
  • the pole piece is a positive pole piece. In some examples, the pole piece is a negative pole piece.
  • the pole piece further includes an active material layer located on the surface of the current collector.
  • the active material layer is a positive active material layer, and the positive active material layer includes a positive active material.
  • the active material layer is a negative active material layer, and the negative active material layer includes a negative active material.
  • the electrochemical device includes an electric core, and the electric core includes any of the above-mentioned pole pieces of the present application.
  • the electric core can be prepared according to conventional methods in the art. Specifically, the preparation of the electric core includes the step of winding any one of the above pole pieces.
  • the electrochemical device of the present application may include any device that undergoes an electrochemical reaction, for example, it may be a lithium-ion battery, a sodium-ion battery, etc.; specific examples thereof include all kinds of primary batteries or secondary batteries.
  • the electrochemical device is a lithium secondary battery, including a lithium metal secondary battery, a lithium ion secondary battery, a lithium polymer secondary battery or a lithium ion polymer secondary battery.
  • the electronic device includes any one of the above electrochemical devices of the present application.
  • the electronic device of the present application can be used in, but not limited to, notebook computers, pen input computers, mobile computers, e-book players, portable telephones, portable fax machines, portable copiers, portable printers, stereo headsets, video recorders, LCD TV, portable cleaner, portable CD player, mini CD, transceiver, electronic notepad, calculator, memory card, portable recorder, radio, backup power supply, motor, automobile, motorcycle, power-assisted bicycle, bicycle, lighting equipment , toys, game consoles, clocks, power tools, flashlights, cameras, large household batteries and lithium-ion capacitors, etc.
  • the quantity is 200, and the wound battery core in a large soft-pack battery has 108 die-cut tabs. Count the number of discounted wound batteries.
  • the result is 15.8mm, and the corresponding experimental results are shown in Table 2.
  • the parameters after chamfering the two end angles at the outer end of the base tab are shown in Table 2.
  • the outer edge of the corner-cut portion can be a straight line, a convex arc, or a concave arc.
  • the straight-line corner-cut tab has a ⁇ angle of 45°, and the first side length h is 15 mm.
  • the half-width l of the top edge is 7.45mm; in Example 2-3, the outer convex arc cut angle and the inner concave arc cut angle are obtained according to the change of the straight line cut angle, that is, the positions of the hypotenuse and the top edge are consistent with the straight line cut angle.
  • the vertical distance from the maximum point of curvature radius in convex arc lines and concave arc lines to the straight line tangent angle is 2.5mm; the corresponding dimensions are shown in Figure 7; the test data are shown in Table 1 below:
  • Example 1 It can be seen from the parameter characteristics and test results in Table 1 that compared with Comparative Example 1, Examples 1 to 3 were respectively cut on the base tab to obtain a corner portion.
  • the corner portion after cutting in Example 1 The outer edge of the part is a straight line, that is, a straight-line cut angle is obtained.
  • the number of tabs folded during the test of 200 cells with straight cut-angle tabs is 2, and the corresponding cell production failure rate is 1%;
  • Example 2 The outer edge of the cut corner after cutting is a convex arc, that is, the convex arc cut corner is obtained.
  • the number of tabs folded during the test of 200 cells with convex arc cut corners was 4 , the corresponding cell production failure rate is 2%; the outer edge of the cut corner in Example 3 is a concave arc, that is, a concave arc cut corner is obtained, and 200 concave arc cut corners are obtained.
  • the number of battery cells that had tabs folded during the test was 1, and the corresponding battery cell production failure rate was 0.5%. It can be seen that the swing and torsional stiffness of the concave arc-shaped tab has the best improvement effect, and its corresponding cell production failure rate is only 0.5%, which is much lower than the 6% cell production failure rate of the base tab.
  • the number of folds in Examples 4 to 8 is less than or equal to 3, and the minimum can be 1; the battery cell production failure rate corresponding to Example 9 is 3.5%, and the battery cell production failure rate corresponding to Examples 4 to 8 does not exceed 1.5%; Moreover, comparing Examples 4 to 6 with Examples 7 to 8, Examples 4 to 6 control the half width l of the top edge of the cut-angle tab to 0 to 0.4B, that is, 0 ⁇ l ⁇ 0.4 ( L/2-H/tan ⁇ ), which has a better effect of limiting folding, and the corresponding cell production failure rate is also lower.
  • the length of the first side h of the cut-angle tab is controlled to 0.2A to 0.8A, that is, 0.2H/sin ⁇ h ⁇ 0.8H/ sin ⁇ , the swing and torsion strength of the cut-angle pole obtained is better than the swing and torsion strength of the cut-angle pole that is not in this range, that is, the length of the first side h is in the range of 0.2A ⁇ 0.8A, which limits the folding The effect is better.
  • the values of the first side h in Example 10 and Example 16 are 0.1A and 0.9A respectively.
  • the number of tabs that occurred in the 200 cells during the test was 6, which is much higher than that in the Example.
  • the number of folds of 11 to 15, the number of folds of Examples 11 to 15 is less than or equal to 4, and the minimum can reach 1; and the battery core production failure rate of Examples 10 and 16 is 3%, while the failure rate of Examples 11 to 15
  • the corresponding cell production failure rate does not exceed 2%; moreover, comparing Examples 12 to 14 with Examples 11 and 15, Examples 12 to 14 control the first side h at 0.3A to 0.7A, that is, 0.3 H/sin ⁇ h ⁇ 0.7H/sin ⁇ has a better effect of limiting folding, and the corresponding cell production failure rate is also lower.
  • Example 9 Comparing Example 9 with other examples, when ⁇ - ⁇ 15° and ⁇ - ⁇ 75° is satisfied, the number of tabs folded during the production of the battery core is significantly reduced, and the failure rate of the battery core production is reduced. The improvement effect is significant.
  • this application uses modal analysis for quantification.
  • the first-order eigenfrequency corresponds to the swing stiffness
  • the second-order eigenfrequency corresponds to the torsional stiffness (as shown in Figure 8);
  • Table 2 below is Comparative Example 1 Modal analysis comparison results of the base tab and the cut-angle tab described in Example 1 of this application:
  • first-order characteristic frequency and the second-order characteristic frequency of the cut-angle tab in Embodiment 1 of the present application are greatly improved.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Connection Of Batteries Or Terminals (AREA)

Abstract

The present application discloses an electrode sheet, an electrochemical apparatus, and an electronic device. The electrode sheet comprises a current collector and a tab; the tab is connected to the current collector; chamfer portions are provided at end corners of the end of the tab facing away from the current collector. According to the present application, the chamfer portions are provided at the end corners of the end of the tab facing away from the current collector, so that the swing rigidity and the torsional rigidity of the tab can be improved, thereby suppressing the folding and inward insertion phenomena of tabs during winding of electrode sheets, and improving the production yield of electrochemical devices.

Description

极片、电化学装置以及电子设备Pole pieces, electrochemical devices and electronic equipment 技术领域Technical field
本申请涉及电池技术领域,尤其涉及一种极片、电化学装置以及电子设备。The present application relates to the field of battery technology, and in particular to a pole piece, an electrochemical device and an electronic device.
背景技术Background technique
具有多极耳结构极片的电池,由于极片在电芯的多个卷绕层中引出了极耳,大幅缩短了电子传导路径,可以大幅降低电池内阻,从而能够满足手机、笔记本电脑、无人机、电动工具、电动汽车、电动两轮车等大倍率应用的需求。Batteries with multi-lug structure pole pieces, because the pole pieces lead out tabs in the multiple winding layers of the battery core, greatly shorten the electronic conduction path, can greatly reduce the internal resistance of the battery, thus meeting the needs of mobile phones, laptops, Demand for high-magnification applications such as drones, power tools, electric vehicles, and electric two-wheelers.
发明内容Contents of the invention
然而,本申请的发明人研究发现,现有的多极耳结构的极片,在卷绕过程中容易出现极耳翻折、内插现象,严重影响生产优率。However, the inventor of the present application has discovered through research that existing pole pieces with multi-pole tab structures are prone to tab folding and interpolation during the winding process, seriously affecting the production yield.
有鉴于此,本申请提供一种极片、电化学装置以及电子设备,能够有效改善极耳在生产过程中的翻折、内插现象,提高电化学装置的生产优率。In view of this, the present application provides a pole piece, an electrochemical device and an electronic device, which can effectively improve the folding and interpolation phenomenon of the tab during the production process and improve the production efficiency of the electrochemical device.
第一方面,本申请提供了一种极片,包括集流体和极耳;所述极耳与所述集流体连接;所述极耳背离所述集流体一端的端角处设置有切角部。通过在极耳背离集流体的一端的端角处设置切角部,可提升极耳的摆动刚度和扭转刚度,从而抑制极耳在极片卷绕过程中出现翻折、内插现象,提高电化学装置的生产优率。In a first aspect, the present application provides a pole piece, including a current collector and a pole tab; the pole tab is connected to the current collector; and an end corner of the pole tab away from the current collector is provided with a chamfered portion. . By arranging a chamfered portion at the end corner of the end of the tab away from the current collector, the swing stiffness and torsional stiffness of the tab can be improved, thus suppressing the tab from being folded or interpolated during the winding process of the pole piece, and improving the electrical power. Production excellence rate of chemical plants.
在一些实施方式中,所述极耳背离所述集流体一端的两个端角处均设置有切角部。在两个端角处均设置切角部,有利于提升极耳两侧的摆动刚度和 扭转刚度,进一步抑制极耳在极片卷绕过程中出现翻折、内插现象。In some embodiments, chamfered portions are provided at both end corners of the end of the pole tab away from the current collector. Cut corners are provided at both end corners, which is beneficial to improving the swing stiffness and torsional stiffness on both sides of the tab, and further suppresses the phenomenon of folding and interpolation of the tab during the winding process of the pole piece.
在一些实施方式中,所述切角部的外边缘独立地选自直线、外凸弧线或者内凹弧线中的任一种。In some embodiments, the outer edge of the chamfered portion is independently selected from any one of a straight line, an outer convex arc, or an inner concave arc.
在一些实施方式中,所述极耳由所述集流体延伸形成。此时,一方面,能够提高极耳与集流体之间的连接强度,降低极耳脱落的风险;另一方面,能够大大简化极耳的制造,提高加工效率。In some embodiments, the tab is formed by an extension of the current collector. At this time, on the one hand, the connection strength between the tab and the current collector can be improved and the risk of the tab falling off can be reduced; on the other hand, the manufacturing of the tab can be greatly simplified and the processing efficiency can be improved.
在一些实施方式中,所述极片包括多个所述极耳。极片包括多个所述极耳,能够大幅提升电化学装置的倍率性能,从而更好的满足大倍率应用的需求。In some embodiments, the pole piece includes a plurality of the tabs. The pole piece includes a plurality of the pole tabs, which can greatly improve the rate performance of the electrochemical device, thereby better meeting the needs of high-rate applications.
在一些实施方式中,所述切角部的外边缘具有第一端点和第二端点;所述极耳设有第一侧边以及与所述集流体连接的底边,所述第一侧边的一端与所述底边连接,所述第一侧边的另一端与所述第一端点连接;所述第一侧边与所述底边的夹角为α,所述第一端点与所述第二端点的连线与所述第一侧边的夹角为λ,β=λ-(180°-α),且满足:β<α。通过满足β<α,可提升极耳于端部处的摆动刚度和扭转刚度,从而抑制极耳在极片卷绕过程中出现翻折、内插现象,提高电化学装置的生产优率。In some embodiments, the outer edge of the chamfered portion has a first endpoint and a second endpoint; the tab is provided with a first side and a bottom side connected to the current collector, and the first side One end of the side is connected to the bottom side, and the other end of the first side is connected to the first endpoint; the angle between the first side and the bottom side is α, and the first end The angle between the line connecting the point and the second endpoint and the first side is λ, β=λ-(180°-α), and satisfies: β<α. By satisfying β<α, the swing stiffness and torsional stiffness of the tip at the end can be improved, thereby suppressing the tip folding and interpolation during the winding process of the pole piece, and improving the production efficiency of the electrochemical device.
在一些实施方式中,α-β≥9°。在一些实施方式中,α-β≥15°。此时,能够进一步限制极耳于端部处的摆动和扭转,从而进一步抑制极耳在极片卷绕过程中出现翻折、内插现象。In some embodiments, α-β≥9°. In some embodiments, α-β≥15°. At this time, the swing and twist of the pole tab at the end can be further restricted, thereby further suppressing the phenomenon of folding and interpolation of the pole tab during the winding process of the pole piece.
在一些实施方式中,0°<α≤90°。在一些实施方式中,40°≤α≤86°。此时,第一侧边与底边之间呈锐角设置,极耳的宽度沿远离集流体的方向逐渐变窄,能够进一步提升极耳于端部处的摆动刚度和扭转刚度,从而进一步抑制极耳在极片卷绕过程中出现翻折、内插现象。In some embodiments, 0°<α≤90°. In some embodiments, 40°≤α≤86°. At this time, the first side and the bottom edge are set at an acute angle, and the width of the pole gradually narrows in the direction away from the current collector, which can further increase the swing stiffness and torsional stiffness of the pole at the end, thereby further suppressing the polarity. The ears appear to be folded and interpolated during the winding process of the pole piece.
在一些实施方式中,α-β≤75°。In some embodiments, α-β≤75°.
在一些实施方式中,所述极耳的底边宽度为L,所述极耳的高度为H,所述极耳的顶边宽度为2l;其中,所述极耳的宽度方向与所述集流体的长度方向平行,所述极耳的高度方向与所述集流体的长度方向垂直,满足:0≤l≤0.8(L/2-H/tanα)。In some embodiments, the bottom edge width of the pole tab is L, the height of the pole tab is H, and the top edge width of the pole tab is 2l; wherein, the width direction of the pole tab is in the same direction as the collector. The length direction of the fluid is parallel, and the height direction of the pole tab is perpendicular to the length direction of the current collector, satisfying: 0≤l≤0.8(L/2-H/tanα).
在一些实施方式中,满足:0≤l≤0.4(L/2-H/tanα)。此时,能够进一步限制极耳于端部处的摆动和扭转,从而进一步抑制极耳在极片卷绕过程中出现翻折、内插现象。In some embodiments, it is satisfied: 0≤l≤0.4(L/2-H/tanα). At this time, the swing and twist of the pole tab at the end can be further restricted, thereby further suppressing the phenomenon of folding and interpolation of the pole tab during the winding process of the pole piece.
在一些实施方式中,所述第一侧边的长度为h,满足:0.2H/sinα≤h≤0.8H/sinα。In some embodiments, the length of the first side is h, which satisfies: 0.2H/sinα≤h≤0.8H/sinα.
在一些实施方式中,满足:0.3H/sinα≤h≤0.7H/sinα。此时,能够进一步限制极耳于端部处的摆动和扭转,从而进一步抑制极耳在极片卷绕过程中出现翻折、内插现象。In some embodiments, it is satisfied: 0.3H/sinα≤h≤0.7H/sinα. At this time, the swing and twist of the pole tab at the end can be further restricted, thereby further suppressing the phenomenon of folding and interpolation of the pole tab during the winding process of the pole piece.
第二方面,本申请还提供了一种电芯的制备方法,包括卷绕上述任一项所述的极片的步骤。In a second aspect, this application also provides a method for preparing an electric core, including the step of winding the pole piece described in any one of the above.
第三方面,本申请还提供了一种电化学装置,包括上述任一项所述的极片或上述制备方法制得的电芯。In a third aspect, the present application also provides an electrochemical device, including the pole piece described in any one of the above or the electric core prepared by the above preparation method.
第四方面,本申请还提供了一种电子设备,包括上述任一项所述的电化学装置。In a fourth aspect, the present application also provides an electronic device, including the electrochemical device described in any one of the above.
本申请通过在极耳背离集流体的一端的端角处设置切角部,可提升极耳的摆动刚度以及扭转刚度,本申请所述的极片在卷绕过程中出现极耳翻折的数量明显降低,对应电芯生产失效的比率也大幅下降;因此,其可以有效改善极耳在极片卷绕过程中的翻折、内插现象,提高电化学装置的生产优率。This application can improve the swing stiffness and torsional stiffness of the pole tab by arranging a chamfered portion at the end corner of the pole tab away from the current collector. The number of pole tab folds during the winding process of the pole piece described in this application Significantly reduced, the corresponding rate of cell production failure is also significantly reduced; therefore, it can effectively improve the folding and interpolation phenomenon of the tabs during the pole piece winding process, and improve the production efficiency of electrochemical devices.
附图说明Description of drawings
为了更清楚地说明本申请实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本申请的一些实施例,对于本领域技术人员来讲,还可以根据这些附图获得其他的附图。In order to explain the embodiments of the present application or the technical solutions in the prior art more clearly, the drawings needed to be used in the description of the embodiments or the prior art will be briefly introduced below. Obviously, the drawings in the following description are only These are some embodiments of the present application. For those skilled in the art, other drawings can also be obtained based on these drawings.
图1为现有技术的极耳结构(base极耳)的示意图;Figure 1 is a schematic diagram of the tab structure (base tab) of the prior art;
图2为本申请所述的切角极耳的结构示意图;Figure 2 is a schematic structural diagram of the cut-angle tab described in this application;
图3为本申请实施例中切角极耳为直线切角的结构示意图;Figure 3 is a schematic structural diagram of a straight-line angle cutter in the embodiment of the present application;
图4为本申请实施例中切角极耳为内凹弧线切角的结构示意图;Figure 4 is a schematic structural diagram of the angle-cut pole tab in the embodiment of the present application, which is a concave arc-shaped angle;
图5为本申请实施例中切角极耳为外凸弧线切角的结构示意图;Figure 5 is a schematic structural diagram of the angle-cut pole in the embodiment of the present application, which is an external convex arc-shaped angle;
图6为本申请实施例中切角极耳为直线切角的参数示意图;Figure 6 is a schematic diagram of parameters in which the angle-cut tab is a straight-line angle cutter in the embodiment of the present application;
图7为本申请实施例中切角极耳的具体参数示意图;Figure 7 is a schematic diagram of specific parameters of the angle-cut tab in the embodiment of the present application;
图8为现有技术的极耳结构(base极耳)的模态分析结果图片。Figure 8 is a picture of the modal analysis results of the tab structure (base tab) of the prior art.
具体实施方式Detailed ways
为了使本申请的目的、技术方案及优点更加清楚明白,以下结合附图及实施例,对本申请进行进一步详细说明。应当理解,此处所描述的具体实施例仅仅用以解释本申请,并不用于限定本申请。In order to make the purpose, technical solutions and advantages of the present application more clear, the present application will be further described in detail below with reference to the drawings and embodiments. It should be understood that the specific embodiments described here are only used to explain the present application and are not used to limit the present application.
请参阅图1,为现有技术的base极耳结构,其通常为等腰梯形极耳,即极耳的外轮廓呈等腰梯形结构。Please refer to Figure 1 , which shows a base tab structure in the prior art. It is usually an isosceles trapezoid tab, that is, the outer contour of the tab is an isosceles trapezoid structure.
本申请的发明人研究发现,在极片卷绕过程中,现有base极耳很容易出现翻折、内插现象,特别是对于具有多极耳结构极片的电池,其电芯中的多极耳结构极片在卷绕过程中发生极耳翻折、内插的概率大大增加,严重影响生产优率。The inventor of this application has found that during the winding process of the pole piece, the existing base tab is prone to folding and interpolation. Especially for batteries with multi-lug structure pole pieces, there are many poles in the battery core. For pole pieces with tab structures, the probability of tab folding and interpolation during the winding process is greatly increased, seriously affecting the production efficiency.
有鉴于此,本申请提出一种极片、电化学装置以及电子设备,以改善或 至少部分解决上述技术问题。In view of this, this application proposes a pole piece, an electrochemical device and an electronic device to improve or at least partially solve the above technical problems.
一种极片a pole piece
请参阅图2,所述极片包括:集流体1和极耳2(文中有时也称切角极耳);所述极耳2与所述集流体1连接;具体地,所述极耳2靠近所述集流体1的一侧端部与所述集流体1连接,所述的连接可以是一体成型、粘接、焊接或其他固定方式,只要能够实现所述极耳2与所述集流体1的连接固定即可,本申请对此并无限制,具体地,在一些示例中,所述极耳2由所述集流体1延伸形成,此时,所述极耳2与所述集流体1是一体成型的,在极片裁切过程中,通过对集流体1边缘的空箔区进行裁切即可获得相应的极耳2,大大简化了极耳2的制造,提高了加工效率;所述极耳2背离所述集流体1的另一侧端部的端角处设置有切角部21。通过在所述极耳2背离集流体1的端部(即所述极耳2的外端端部)的一侧端角或者两侧端角设置所述切角部21,可提升极耳2的摆动刚度和扭转刚度,从而抑制极耳2在极片卷绕过程中出现翻折、内插现象。Please refer to Figure 2. The pole piece includes: a current collector 1 and a pole tab 2 (sometimes also called a cut-angle tab in the text); the pole tab 2 is connected to the current collector 1; specifically, the pole tab 2 The end of one side close to the current collector 1 is connected to the current collector 1. The connection can be integrally formed, bonded, welded or other fixed methods, as long as the tab 2 and the current collector can be realized. 1 only needs to be fixedly connected, and this application is not limited to this. Specifically, in some examples, the pole tab 2 is formed by extending the current collector 1. At this time, the pole tab 2 and the current collector 1 1 is formed in one piece. During the pole piece cutting process, the corresponding pole tab 2 can be obtained by cutting the empty foil area on the edge of the current collector 1, which greatly simplifies the manufacturing of pole tab 2 and improves the processing efficiency; A corner cutout 21 is provided at an end corner of the other end of the pole tab 2 away from the current collector 1 . By arranging the chamfered portion 21 at one end corner or both end corners of the end of the pole tab 2 away from the current collector 1 (ie, the outer end of the pole tab 2 ), the pole tab 2 can be lifted. The swing stiffness and torsional stiffness are thereby suppressed from the phenomenon of folding and interpolation of the pole tab 2 during the winding process of the pole piece.
可选地,在一些示例中,所述极耳2外端端部的一侧端角设置所述切角部21;或者在另一些示例中,所述极耳2外端端部的两侧端角均设置有所述切角部21。Optionally, in some examples, one end corner of the outer end of the pole lug 2 is provided with the chamfered portion 21; or in other examples, both sides of the outer end of the pole lug 2 are The end corners are provided with the chamfered portions 21 .
请参阅图3~5,在一些示例中,所述极耳2背离所述集流体1一端的两个端角处均设置有切角部21;两个所述切角部21设于所述极耳2的外端端部的端角处且呈中心对称,有利于提升所述极耳2两侧的摆动刚度和扭转刚度,进一步抑制极耳2在极片卷绕过程中出现翻折、内插现象。在一些示例中,所述切角部21的外边缘211独立地选自直线、外凸弧线或者内凹弧线中的任一种。Please refer to Figures 3 to 5. In some examples, chamfered portions 21 are provided at both corners of the end of the pole tab 2 away from the current collector 1; the two chamfered portions 21 are provided on the The end corners of the outer ends of the pole tabs 2 are centrally symmetrical, which is beneficial to improving the swing stiffness and torsional stiffness on both sides of the pole tabs 2 and further inhibiting the pole tabs 2 from folding or folding during the winding process of the pole pieces. interpolation phenomenon. In some examples, the outer edge 211 of the chamfered portion 21 is independently selected from any one of a straight line, an outer convex arc, or an inner concave arc.
可选地,在一些示例中,所述极耳2背离所述集流体1的端部的一个端 角处设置有所述切角部21,所述切角部21的外边缘211可以是直线,也可以是外凸弧线,还可以是内凹弧线;优选地,所述切角部21的外边缘211为内凹弧线。在另一些示例中,所述极耳2背离所述集流体1的端部的两个端角处均设置有切角部21,两个所述切角部21的外边缘211均相同,均为直线或者外凸弧线或者内凹弧线;优选地,两个所述切角部21的外边缘211均为内凹弧线。以及在其他示例中,所述极耳2背离所述集流体1的端部的两个端角处均设置有切角部21,两个所述切角部21的外边缘211不相同,两个所述切角部21之一的外边缘211为直线,另一切角部21的外边缘211为外凸弧线或者内凹弧线。Optionally, in some examples, the chamfered portion 21 is provided at an end corner of the end of the pole lug 2 away from the current collector 1 , and the outer edge 211 of the chamfered portion 21 may be a straight line. , it may be an outer convex arc, or it may be an inner concave arc; preferably, the outer edge 211 of the chamfered portion 21 is an inner concave arc. In other examples, chamfered portions 21 are provided at both end corners of the end of the pole lug 2 away from the current collector 1 , and the outer edges 211 of the two chamfered portions 21 are the same. It is a straight line, a convex arc, or a concave arc; preferably, the outer edges 211 of the two chamfered portions 21 are both concave arcs. And in other examples, chamfered portions 21 are provided at both end corners of the end of the pole lug 2 away from the current collector 1 , and the outer edges 211 of the two chamfered portions 21 are different. The outer edge 211 of one of the chamfered portions 21 is a straight line, and the outer edge 211 of the other chamfered portion 21 is a convex arc or a concave arc.
如图3所示,所述极耳2外端端部的两个端角处均设置有切角部21,且两个所述切角部21的外边缘211均为直线且呈中心对称设置,此时,可以称之为所述极耳2外端端部的两个端角处设置有直线切角。As shown in FIG. 3 , chamfered portions 21 are provided at both corners of the outer end of the pole lug 2 , and the outer edges 211 of the two chamfered portions 21 are both straight and centrally symmetrical. , at this time, it can be said that the two end corners of the outer end of the pole tab 2 are provided with straight-line chamfers.
如图4所示,所述极耳2外端端部的两个端角处均设置有切角部21,且两个所述切角部21的外边缘211均为内凹弧线且呈中心对称设置,此时,可以称之为所述极耳2外端端部的两个端角处设置有内凹弧线切角。As shown in Figure 4, the two corners of the outer end of the pole lug 2 are provided with chamfered portions 21, and the outer edges 211 of the two chamfered portions 21 are both concave arcs and are in the shape of a concave arc. The pole tab 2 is arranged symmetrically at the center. At this time, it can be said that the two end corners of the outer end of the pole tab 2 are provided with concave arc-cut corners.
如图5所示,所述极耳2外端端部的两个端角处均设置有切角部21,且两个所述切角部21的外边缘211均为外凸弧线且呈中心对称设置,此时,可以称之为所述极耳2外端端部的两个端角处设置有外凸弧线切角。As shown in FIG. 5 , chamfered portions 21 are provided at both corners of the outer end of the pole lug 2 , and the outer edges 211 of the two chamfered portions 21 are both convex arcs. The pole tab 2 is arranged symmetrically at the center. At this time, it can be said that the two end corners of the outer end of the pole tab 2 are provided with convex arc-cut corners.
请参阅图6,所述切角部21的外边缘211具有第一端点和第二端点;所述极耳2设有第一侧边以及与所述集流体1连接的底边,所述第一侧边的一端与所述底边连接,所述第一侧边的另一端与所述第一端点连接;所述第一侧边与所述底边的夹角为α(坡角),所述第一端点与所述第二端点的连线与所述第一侧边的夹角为λ,β=λ-(180°-α),满足:β<α。通过限制所述切角部21中所述第一端点与所述第二端点的连线与水平线的夹角β,使其 满足:β<α,可提升极耳2于外端端部处的摆动刚度和扭转刚度,从而抑制极耳2在极片卷绕过程中出现翻折、内插现象;所述的水平线是与所述底边平行的直线。Referring to Figure 6, the outer edge 211 of the chamfered portion 21 has a first endpoint and a second endpoint; the pole tab 2 is provided with a first side and a bottom edge connected to the current collector 1. One end of the first side is connected to the bottom edge, and the other end of the first side is connected to the first endpoint; the angle between the first side and the bottom edge is α (slope angle ), the angle between the line connecting the first endpoint and the second endpoint and the first side is λ, β=λ-(180°-α), satisfying: β<α. By limiting the angle β between the line connecting the first endpoint and the second endpoint of the chamfered portion 21 and the horizontal line to satisfy: β<α, the pole lug 2 can be raised to the outer end. The swing stiffness and torsional stiffness are thereby suppressed from the phenomenon of folding and interpolation of the pole tab 2 during the winding process of the pole piece; the horizontal line is a straight line parallel to the bottom edge.
可选地,在一些示例中,所述极片满足α-β≥9°。通过满足α-β≥9°,能够提升极耳2于外端端部处的摆动刚度和扭转刚度,从而进一步抑制极耳2在极片卷绕过程中出现翻折、内插现象。示例性地,α和β差值(α-β)为9°、15°、20°、25°、30°、35°、40°、45°、50°、55°、60°、65°、70°、75°、80°或上述任意两个值组成的范围。可选地,在一些示例中,所述极片满足α-β≥15°;此时,能够进一步限制极耳2于外端端部处的摆动和扭转,从而进一步抑制极耳2在极片卷绕过程中出现翻折、内插现象。在另一些示例中,所述极片满足α-β≤75°。Optionally, in some examples, the pole piece satisfies α-β≥9°. By satisfying α-β≥9°, the swing stiffness and torsional stiffness of the pole tab 2 at the outer end can be improved, thereby further suppressing the phenomenon of folding and interpolation of the pole tab 2 during the pole piece winding process. Illustratively, the α and β differences (α-β) are 9°, 15°, 20°, 25°, 30°, 35°, 40°, 45°, 50°, 55°, 60°, 65° , 70°, 75°, 80° or a range consisting of any two of the above values. Optionally, in some examples, the pole piece satisfies α-β≥15°; at this time, the swing and torsion of the pole tab 2 at the outer end can be further restricted, thereby further suppressing the movement of the pole tab 2 at the pole piece. Folding and interpolation phenomena occur during the winding process. In other examples, the pole piece satisfies α-β≤75°.
在一些示例中,所述极片满足0°<α≤90°。示例性地,α的取值范围为10°、20°、40°、60°、80°、86°、90°或上述任意两个值组成的范围。在一些示例中,所述极片满足40°≤α≤86°;此时,第一侧边与底边之间呈锐角设置,极耳的宽度沿远离集流体的方向逐渐变窄,能够进一步提升极耳2于外端端部处的摆动刚度,从而进一步抑制极耳2在极片卷绕过程中出现翻折、内插现象。In some examples, the pole piece satisfies 0°<α≤90°. For example, the value range of α is 10°, 20°, 40°, 60°, 80°, 86°, 90° or a range consisting of any two of the above values. In some examples, the pole piece satisfies 40°≤α≤86°; at this time, the first side and the bottom edge are set at an acute angle, and the width of the pole piece gradually narrows in the direction away from the current collector, which can further The swing stiffness of the pole tab 2 at the outer end is increased, thereby further suppressing the phenomenon of folding and interpolation of the pole tab 2 during the winding process of the pole piece.
结合图6,所述极耳2的底边宽度为L,所述极耳2的高度为H,所述极耳2的顶边宽度为2l,满足:0≤l≤0.8(L/2-H/tanα);其中,所述极耳2的宽度方向与所述集流体1的长度方向平行,所述极耳2的高度方向与所述集流体1的长度方向垂直。其中,(L/2-H/tanα)为base极耳的顶边半宽,将(L/2-H/tanα)记为参数B,裁切极耳时,相当于对base极耳的顶边宽度进行裁切,所述极耳2的顶边半宽l的范围为0至0.8B,即相对于base极耳的顶边半宽,裁切掉的长度为B-l(即图6中顶边半宽l的一端延长线延长至与 第一侧边h的延长线相交时的距离)。Referring to Figure 6, the bottom width of the pole tab 2 is L, the height of the pole tab 2 is H, and the top edge width of the pole tab 2 is 2l, which satisfies: 0≤l≤0.8(L/2- H/tanα); wherein, the width direction of the pole tab 2 is parallel to the length direction of the current collector 1 , and the height direction of the pole tab 2 is perpendicular to the length direction of the current collector 1 . Among them, (L/2-H/tanα) is the top half width of the base tab, and (L/2-H/tanα) is recorded as parameter B. When cutting the tab, it is equivalent to cutting the top edge of the base tab. The edge width is cut. The top half-width l of the pole tab 2 ranges from 0 to 0.8B, that is, relative to the top half-width of the base tab, the cut length is B-l (i.e., the top half-width in Figure 6 The extension line of one end of the side half-width l extends to the distance when it intersects the extension line of the first side h).
示例性地,所述极耳2的顶边半宽l为0、0.01B、0.1B、0.15B、0.2B、0.25B、0.3B、0.35B、0.4B、0.6B、0.8B或上述任意两个值组成的范围。Illustratively, the half-width l of the top edge of the pole lug 2 is 0, 0.01B, 0.1B, 0.15B, 0.2B, 0.25B, 0.3B, 0.35B, 0.4B, 0.6B, 0.8B or any of the above A range of two values.
优选地,所述极耳2的顶边半宽l满足:0≤l≤0.4(L/2-H/tanα);即l满足:0≤l≤0.4B。此时,能够进一步限制极耳2于外端端部处的摆动和扭转,从而进一步抑制极耳2在极片卷绕过程中出现翻折、内插现象。Preferably, the half-width l of the top edge of the pole lug 2 satisfies: 0≤l≤0.4(L/2-H/tanα); that is, l satisfies: 0≤l≤0.4B. At this time, the swing and twist of the pole tab 2 at the outer end can be further restricted, thereby further suppressing the phenomenon of folding and interpolation of the pole tab 2 during the winding process of the pole piece.
而且,结合图6,所述第一侧边的长度为h,满足:0.2H/sinα≤h≤0.8H/sinα。其中,H/sinα为base极耳的斜边长度,所述base极耳的斜边的一端与其顶边相连,所述base极耳的斜边的另一端与其底边相连。将(H/sinα)记为参数A,裁切极耳时,相当于对base极耳的斜边进行裁切,所述极耳2的第一侧边的长度范围为0.2A至0.8A,即base极耳的斜边实际裁切掉的长度为A-h(即图6中第一侧边h的延长线延长至与顶边半宽l的延长线相交时的距离)。Moreover, with reference to Figure 6, the length of the first side is h, which satisfies: 0.2H/sinα≤h≤0.8H/sinα. Wherein, H/sinα is the length of the hypotenuse of the base tab, one end of the hypotenuse of the base tab is connected to its top edge, and the other end of the hypotenuse of the base tab is connected to its bottom edge. Record (H/sinα) as parameter A. When cutting the tab, it is equivalent to cutting the hypotenuse of the base tab. The length of the first side of the tab 2 ranges from 0.2A to 0.8A. That is, the actual cut length of the hypotenuse of the base tab is A-h (that is, the distance when the extension line of the first side h in Figure 6 extends to intersects the extension line of the top half-width l).
示例性地,所述第一侧边的长度h为0.2A、0.3A、0.4A、0.5A、0.6A、0.7A、0.8A或上述任意两个值组成的范围。For example, the length h of the first side is a range of 0.2A, 0.3A, 0.4A, 0.5A, 0.6A, 0.7A, 0.8A or any two of the above values.
优选地,所述第一侧边的长度h满足:0.3H/sinα≤h≤0.7H/sinα;即h满足:0.3A≤h≤0.7A。此时,能够进一步限制极耳2于外端端部处的摆动和扭转,从而进一步抑制极耳2在极片卷绕过程中出现翻折、内插现象。Preferably, the length h of the first side satisfies: 0.3H/sinα≤h≤0.7H/sinα; that is, h satisfies: 0.3A≤h≤0.7A. At this time, the swing and twist of the pole tab 2 at the outer end can be further restricted, thereby further suppressing the phenomenon of folding and interpolation of the pole tab 2 during the winding process of the pole piece.
在一些示例中,所述极片为正极极片。在一些示例中,所述极片为负极极片。In some examples, the pole piece is a positive pole piece. In some examples, the pole piece is a negative pole piece.
在一些示例中,所述极片还包括位于所述集流体表面的活性材料层。在一些示例中,所述活性材料层为正极活性材料层,所述正极活性材料层包括正极活性材料。在一些示例中,所述活性材料层为负极活性材料层,所述负极活性材料层包括负极活性材料。In some examples, the pole piece further includes an active material layer located on the surface of the current collector. In some examples, the active material layer is a positive active material layer, and the positive active material layer includes a positive active material. In some examples, the active material layer is a negative active material layer, and the negative active material layer includes a negative active material.
一种电化学装置an electrochemical device
所述电化学装置包括电芯,所述电芯包括本申请的上述任一种所述的极片。所述电芯可以按照本领域常规方法制备,具体地,所述电芯的制备包括卷绕上述任一种所述的极片的步骤。The electrochemical device includes an electric core, and the electric core includes any of the above-mentioned pole pieces of the present application. The electric core can be prepared according to conventional methods in the art. Specifically, the preparation of the electric core includes the step of winding any one of the above pole pieces.
本申请的电化学装置可以包括发生电化学反应的任何装置,例如,可以是锂离子电池、钠离子电池等;它的具体实例包括所有种类的一次电池或二次电池。特别地,该电化学装置是锂二次电池,包括锂金属二次电池、锂离子二次电池、锂聚合物二次电池或锂离子聚合物二次电池。The electrochemical device of the present application may include any device that undergoes an electrochemical reaction, for example, it may be a lithium-ion battery, a sodium-ion battery, etc.; specific examples thereof include all kinds of primary batteries or secondary batteries. In particular, the electrochemical device is a lithium secondary battery, including a lithium metal secondary battery, a lithium ion secondary battery, a lithium polymer secondary battery or a lithium ion polymer secondary battery.
一种电子设备an electronic device
所述电子设备包括本申请的上述任一种的电化学装置。本申请的电子设备置可用于,但不限于,笔记本电脑、笔输入型计算机、移动电脑、电子书播放器、便携式电话、便携式传真机、便携式复印机、便携式打印机、头戴式立体声耳机、录像机、液晶电视、手提式清洁器、便携CD机、迷你光盘、收发机、电子记事本、计算器、存储卡、便携式录音机、收音机、备用电源、电机、汽车、摩托车、助力自行车、自行车、照明器具、玩具、游戏机、钟表、电动工具、闪光灯、照相机、家庭用大型蓄电池和锂离子电容器等。The electronic device includes any one of the above electrochemical devices of the present application. The electronic device of the present application can be used in, but not limited to, notebook computers, pen input computers, mobile computers, e-book players, portable telephones, portable fax machines, portable copiers, portable printers, stereo headsets, video recorders, LCD TV, portable cleaner, portable CD player, mini CD, transceiver, electronic notepad, calculator, memory card, portable recorder, radio, backup power supply, motor, automobile, motorcycle, power-assisted bicycle, bicycle, lighting equipment , toys, game consoles, clocks, power tools, flashlights, cameras, large household batteries and lithium-ion capacitors, etc.
以下,举出实施例及对比例来对本申请的实施方式进行更具体地说明。Hereinafter, embodiments of the present application will be described in more detail with reference to Examples and Comparative Examples.
以多极耳大软包电池为例进行生产优率改善效果对比,数量为200个,一个大软包电池中的卷绕电芯有108个模切极耳,对卷绕成型工序中出现极耳打折的卷绕电芯数量进行统计。Taking multi-lug large soft-pack batteries as an example to compare the effect of improving production efficiency, the quantity is 200, and the wound battery core in a large soft-pack battery has 108 die-cut tabs. Count the number of discounted wound batteries.
此次验证的base极耳的高度H=24mm,底边宽度L=35mm,坡角α=86°, 侧边长度(参数A)计算可得为24.06mm,顶边宽度(参数B)计算可得为15.8mm,对应实验结果如表2所示。The height of the base tab for this verification is H = 24mm, the bottom width L = 35mm, the slope angle α = 86°, the side length (parameter A) is calculated to be 24.06mm, and the top edge width (parameter B) is calculated to be 24.06mm. The result is 15.8mm, and the corresponding experimental results are shown in Table 2.
将base极耳外端端部的两个端角进行切角后的各参数如表2所示。切角部的外边缘可以是直线也可以是外凸弧线还可以是内凹弧线,实施例1中直线切角极耳,其β角为45°,第一侧边长度h为15mm,顶边半宽l为7.45mm;实施例2-3中外凸弧线切角和内凹弧线切角均根据直线切角变化得到,即斜边和顶边的位置与直线切角一致,外凸弧线和内凹弧线中曲率半径最大点到直线切角的垂直距离为2.5mm;对应尺寸如图7所示;试验数据如下表1所示:The parameters after chamfering the two end angles at the outer end of the base tab are shown in Table 2. The outer edge of the corner-cut portion can be a straight line, a convex arc, or a concave arc. In Embodiment 1, the straight-line corner-cut tab has a β angle of 45°, and the first side length h is 15 mm. The half-width l of the top edge is 7.45mm; in Example 2-3, the outer convex arc cut angle and the inner concave arc cut angle are obtained according to the change of the straight line cut angle, that is, the positions of the hypotenuse and the top edge are consistent with the straight line cut angle. The vertical distance from the maximum point of curvature radius in convex arc lines and concave arc lines to the straight line tangent angle is 2.5mm; the corresponding dimensions are shown in Figure 7; the test data are shown in Table 1 below:
表1Table 1
Figure PCTCN2022111078-appb-000001
Figure PCTCN2022111078-appb-000001
从表1的参数特征以及测试结果可以看出,与对比例1相比,实施例1~3分别在base极耳上进行裁切得到切角部,其中,实施例1裁切后的切角部的外边缘为直线,即得到直线切角,200个直线切角极耳的电芯在测试中发生极耳翻折的数量为2,对应的电芯生产失效比率为1%;实施例2裁切后的切角部的外边缘为外凸弧线,即得到外凸弧线切角,200个外凸弧线切角极耳的电芯在测试中发生极耳翻折的数量为4,对应的电芯生产失效比率为2%;实施例3裁切后的切角部的外边缘为内凹弧线,即得到内凹弧线切角,200个内凹弧线切角极耳的电芯在测试中发生极耳翻折的数量为1,对应的电芯生产失效比率为0.5%。可见,内凹弧线切角极耳的摆动和扭转刚度的提升效果最好,其对应的电芯生产失效比率仅为0.5%,远低于base极耳的电芯生产失效比率6%。It can be seen from the parameter characteristics and test results in Table 1 that compared with Comparative Example 1, Examples 1 to 3 were respectively cut on the base tab to obtain a corner portion. Among them, the corner portion after cutting in Example 1 The outer edge of the part is a straight line, that is, a straight-line cut angle is obtained. The number of tabs folded during the test of 200 cells with straight cut-angle tabs is 2, and the corresponding cell production failure rate is 1%; Example 2 The outer edge of the cut corner after cutting is a convex arc, that is, the convex arc cut corner is obtained. The number of tabs folded during the test of 200 cells with convex arc cut corners was 4 , the corresponding cell production failure rate is 2%; the outer edge of the cut corner in Example 3 is a concave arc, that is, a concave arc cut corner is obtained, and 200 concave arc cut corners are obtained. The number of battery cells that had tabs folded during the test was 1, and the corresponding battery cell production failure rate was 0.5%. It can be seen that the swing and torsional stiffness of the concave arc-shaped tab has the best improvement effect, and its corresponding cell production failure rate is only 0.5%, which is much lower than the 6% cell production failure rate of the base tab.
从实施例4~8与实施例9的比较可以看出,将切角极耳的顶边半宽l控制在0~0.8B,即0≤l≤0.8(L/2-H/tanα),得到的切角极耳的强度优于不在该范围的切角极耳的强度,即顶边半宽l在0~0.8B范围内,其限制翻折效果较好。例如,实施例9中l的取值为0.9(L/2-H/tanα),200个电芯在测试中发生极耳翻折的数量为7,远高于实施例4~8的翻折数量,实施例4~8的翻折数量小于等于3,且最小可至1;实施例9对应的电芯生产失效比率为3.5%,而实施例4~8对应的电芯生产失效比率不超过1.5%;而且,将实施例4~6与实施例7~8相比,实施例4~6将切角极耳的顶边半宽l控制在0~0.4B,即0≤l≤0.4(L/2-H/tanα),其限制翻折的效果更好,对应的电芯生产失效比率也更低。From the comparison between Examples 4 to 8 and Example 9, it can be seen that the half width l of the top edge of the cut-angle tab is controlled between 0 and 0.8B, that is, 0≤l≤0.8(L/2-H/tanα), The strength of the obtained cut-angle tab is better than that of the cut-angle tab that is not in this range, that is, the half-width l of the top edge is in the range of 0 to 0.8B, and its folding limiting effect is better. For example, the value of l in Example 9 is 0.9 (L/2-H/tanα), and the number of tab folds in 200 cells during the test is 7, which is much higher than that in Examples 4 to 8. Quantity, the number of folds in Examples 4 to 8 is less than or equal to 3, and the minimum can be 1; the battery cell production failure rate corresponding to Example 9 is 3.5%, and the battery cell production failure rate corresponding to Examples 4 to 8 does not exceed 1.5%; Moreover, comparing Examples 4 to 6 with Examples 7 to 8, Examples 4 to 6 control the half width l of the top edge of the cut-angle tab to 0 to 0.4B, that is, 0 ≤ l ≤ 0.4 ( L/2-H/tanα), which has a better effect of limiting folding, and the corresponding cell production failure rate is also lower.
从实施例11~15与实施例10和16的比较可以看出,将切角极耳的第一侧边h的长度控制在0.2A~0.8A,即0.2H/sinα≤h≤0.8H/sinα,得到的切角极耳的摆动和扭转强度优于不在该范围的切角极耳的摆动和扭转强度,即第 一侧边h的长度在0.2A~0.8A范围内,其限制翻折的效果较好。例如,实施例10和实施例16中第一侧边h的取值分别为0.1A和0.9A,它们200个电芯在测试中发生极耳翻折的数量均为6,远高于实施例11~15的翻折数量,实施例11~15的翻折数量小于等于4,最小可达1;且实施例10和实施例16的电芯生产失效比率为3%,而实施例11~15对应的电芯生产失效比率不超过2%;而且,将实施例12~14与实施例11和15相比,实施例12~14将第一侧边h控制在0.3A~0.7A,即0.3H/sinα≤h≤0.7H/sinα,其限制翻折的效果更好,对应的电芯生产失效比率也更低。From the comparison between Examples 11 to 15 and Examples 10 and 16, it can be seen that the length of the first side h of the cut-angle tab is controlled to 0.2A to 0.8A, that is, 0.2H/sinα≤h≤0.8H/ sinα, the swing and torsion strength of the cut-angle pole obtained is better than the swing and torsion strength of the cut-angle pole that is not in this range, that is, the length of the first side h is in the range of 0.2A ~ 0.8A, which limits the folding The effect is better. For example, the values of the first side h in Example 10 and Example 16 are 0.1A and 0.9A respectively. The number of tabs that occurred in the 200 cells during the test was 6, which is much higher than that in the Example. The number of folds of 11 to 15, the number of folds of Examples 11 to 15 is less than or equal to 4, and the minimum can reach 1; and the battery core production failure rate of Examples 10 and 16 is 3%, while the failure rate of Examples 11 to 15 The corresponding cell production failure rate does not exceed 2%; moreover, comparing Examples 12 to 14 with Examples 11 and 15, Examples 12 to 14 control the first side h at 0.3A to 0.7A, that is, 0.3 H/sinα≤h≤0.7H/sinα has a better effect of limiting folding, and the corresponding cell production failure rate is also lower.
将实施例9和其他实施例相比较,当α-β≥15°且满足α-β≤75°时,电芯在生产中出现极耳翻折的数量明显下降,电芯生产失效比率下降,改善效果显著。Comparing Example 9 with other examples, when α-β≥15° and α-β≤75° is satisfied, the number of tabs folded during the production of the battery core is significantly reduced, and the failure rate of the battery core production is reduced. The improvement effect is significant.
进一步地,为了进行刚度对比,本申请采用模态分析进行量化,模态分析中,一阶特征频率对应摆动刚度,二阶特征频率对于扭转刚度(如图8);下表2是对比例1的base极耳和本申请实施例1所述的切角极耳的模态分析对比结果:Furthermore, in order to compare the stiffness, this application uses modal analysis for quantification. In the modal analysis, the first-order eigenfrequency corresponds to the swing stiffness, and the second-order eigenfrequency corresponds to the torsional stiffness (as shown in Figure 8); Table 2 below is Comparative Example 1 Modal analysis comparison results of the base tab and the cut-angle tab described in Example 1 of this application:
表2Table 2
组别Group 一阶特征频率first-order eigenfrequency 二阶特征频率second-order eigenfrequency
Base极耳Base tab 5.855.85 7.647.64
切角极耳chamfered tabs 6.216.21 9.139.13
可以看出,本申请实施例1切角极耳的一阶特征频率和二阶特征频率均有较大程度的提升,一阶频率越高,越不容易出现上下摆动,二阶频率越高越不容易左右角摆动;可见,切角极耳的摆动和扭转刚度均有提升,从而能够抑制极耳在极片卷绕过程中出现翻折、内插现象。It can be seen that the first-order characteristic frequency and the second-order characteristic frequency of the cut-angle tab in Embodiment 1 of the present application are greatly improved. The higher the first-order frequency, the less likely it is to swing up and down, and the higher the second-order frequency, the less likely it is to swing up and down. It is not easy to swing left and right angles; it can be seen that the swing and torsional stiffness of the angle-cut pole tabs are improved, which can suppress the folding and interpolation of the pole tabs during the pole piece winding process.
本实施例的附图中相同或相似的标号对应相同或相似的部件;在本申请的描述中,需要理解的是,若有术语“上”、“下”、“左”、“右”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本申请和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此附图中描述位置关系的用语仅用于示例性说明,不能理解为对本专利的限制,对于本领域的普通技术人员而言,可以根据具体情况理解上述术语的具体含义。In the drawings of this embodiment, the same or similar numbers correspond to the same or similar components; in the description of this application, it should be understood that if there are terms such as "upper", "lower", "left", "right", etc. The indicated orientation or positional relationship is based on the orientation or positional relationship shown in the drawings. It is only for the convenience of describing the present application and simplifying the description. It does not indicate or imply that the device or element referred to must have a specific orientation or a specific orientation. Construction and operation, therefore the terms describing the positional relationships in the drawings are only for illustrative purposes and cannot be understood as limitations of the patent. For those of ordinary skill in the art, the specific meanings of the above terms can be understood according to specific circumstances.
以上所述仅为本申请的较佳实施例而已,并不用以限制本申请,凡在本申请的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本申请的保护范围之内。The above are only preferred embodiments of the present application and are not intended to limit the present application. Any modifications, equivalent substitutions and improvements made within the spirit and principles of the present application shall be included in the protection of the present application. within the range.

Claims (10)

  1. 一种极片,包括:集流体和极耳;所述极耳与所述集流体连接;其特征在于,所述极耳背离所述集流体一端的端角处设置有切角部。A pole piece includes: a current collector and a pole tab; the pole tab is connected to the current collector; and it is characterized in that an end corner of the pole tab away from the current collector is provided with a chamfered portion.
  2. 根据权利要求1所述的极片,其特征在于,所述极片满足下列条件中的至少一者:The pole piece according to claim 1, characterized in that the pole piece meets at least one of the following conditions:
    (1)所述极耳背离所述集流体一端的两个端角处均设置有切角部;(1) The two end corners of the end of the pole tab away from the current collector are provided with cut corners;
    (2)所述切角部的外边缘独立地选自直线、外凸弧线或者内凹弧线中的任一种;(2) The outer edge of the chamfered portion is independently selected from any one of straight lines, convex arcs, or concave arcs;
    (3)所述极耳由所述集流体延伸形成;(3) The pole tab is formed by extending from the current collector;
    (4)所述极片包括多个所述极耳。(4) The pole piece includes a plurality of pole tabs.
  3. 根据权利要求1所述的极片,其特征在于,所述切角部的外边缘具有第一端点和第二端点;The pole piece according to claim 1, wherein the outer edge of the chamfered portion has a first endpoint and a second endpoint;
    所述极耳设有第一侧边以及与所述集流体连接的底边,所述第一侧边的一端与所述底边连接,所述第一侧边的另一端与所述第一端点连接;The pole tab is provided with a first side and a bottom connected to the current collector, one end of the first side is connected to the bottom, and the other end of the first side is connected to the first endpoint connection;
    所述第一侧边与所述底边的夹角为α,所述第一端点与所述第二端点的连线与所述第一侧边的夹角为λ,β=λ-(180°-α),满足:β<α。The angle between the first side and the bottom is α, the angle between the line connecting the first endpoint and the second endpoint and the first side is λ, β=λ-( 180°-α), satisfying: β<α.
  4. 根据权利要求3所述的极片,其特征在于,所述极片满足下列条件中的至少一者:The pole piece according to claim 3, characterized in that the pole piece meets at least one of the following conditions:
    (1)α-β≥9°;(1)α-β≥9°;
    (2)0°<α≤90°。(2)0°<α≤90°.
  5. 根据权利要求4所述的极片,其特征在于,所述极片满足下列条件中的至少一者:The pole piece according to claim 4, characterized in that the pole piece meets at least one of the following conditions:
    (1)α-β≥15°;(1)α-β≥15°;
    (2)α-β≤75°;(2)α-β≤75°;
    (3)40°≤α≤86°。(3)40°≤α≤86°.
  6. 根据权利要求3所述的极片,其特征在于,所述极耳的底边宽度为L,所述极耳的高度为H,所述极耳的顶边宽度为2l,所述第一侧边的长度为h,其中,所述极耳的宽度方向与所述集流体的长度方向平行,所述极耳的高度方向与所述集流体的长度方向垂直,所述极片满足下列条件中的至少一者:The pole piece according to claim 3, characterized in that the bottom edge width of the pole tab is L, the height of the pole tab is H, the top edge width of the pole tab is 2l, and the first side The length of the side is h, where the width direction of the pole tab is parallel to the length direction of the current collector, the height direction of the pole tab is perpendicular to the length direction of the current collector, and the pole piece satisfies the following conditions: At least one of:
    (1)0≤l≤0.8(L/2-H/tanα);(1)0≤l≤0.8(L/2-H/tanα);
    (2)0.2H/sinα≤h≤0.8H/sinα。(2)0.2H/sinα≤h≤0.8H/sinα.
  7. 根据权利要求6所述的极片,其特征在于,所述极片满足下列条件中的至少一者:The pole piece according to claim 6, characterized in that the pole piece meets at least one of the following conditions:
    (1)0≤l≤0.4(L/2-H/tanα);(1)0≤l≤0.4(L/2-H/tanα);
    (2)0.3H/sinα≤h≤0.7H/sinα。(2)0.3H/sinα≤h≤0.7H/sinα.
  8. 一种电芯的制备方法,其特征在于,包括卷绕根据权利要求1~7中任一项所述的极片的步骤。A method for preparing an electric core, characterized in that it includes the step of winding the pole piece according to any one of claims 1 to 7.
  9. 一种电化学装置,其特征在于,包括权利要求1~7中任一项所述的极片或根据权利要求8所述的制备方法制得的电芯。An electrochemical device, characterized by comprising the pole piece according to any one of claims 1 to 7 or an electric core prepared according to the preparation method according to claim 8.
  10. 一种电子设备,其特征在于,包括权利要求9所述的电化学装置。An electronic device, characterized by comprising the electrochemical device according to claim 9.
PCT/CN2022/111078 2022-08-09 2022-08-09 Electrode sheet, electrochemical apparatus, and electronic device WO2024031313A1 (en)

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PCT/CN2022/111078 WO2024031313A1 (en) 2022-08-09 2022-08-09 Electrode sheet, electrochemical apparatus, and electronic device

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CN202977579U (en) * 2012-11-26 2013-06-05 东莞新能源科技有限公司 Soft package polymer lithium ion battery capable of avoiding liquid leakage
JP5470922B2 (en) * 2009-03-09 2014-04-16 新神戸電機株式会社 Lead-acid battery and method for manufacturing the same
CN207441852U (en) * 2017-11-29 2018-06-01 宁德时代新能源科技股份有限公司 Pole piece coiled material, electrode assembly and secondary cell
CN208225978U (en) * 2018-05-09 2018-12-11 合肥国轩高科动力能源有限公司 A kind of lithium battery pole piece structure of anti-lug bending
CN112038566A (en) * 2020-08-04 2020-12-04 江苏塔菲尔新能源科技股份有限公司 Preparation method of battery cell and battery cell

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5470922B2 (en) * 2009-03-09 2014-04-16 新神戸電機株式会社 Lead-acid battery and method for manufacturing the same
CN102437306A (en) * 2011-12-02 2012-05-02 苏州冠硕新能源有限公司 Pole piece of secondary battery, manufacturing method for pole piece of secondary battery and secondary battery using pole piece
CN202977579U (en) * 2012-11-26 2013-06-05 东莞新能源科技有限公司 Soft package polymer lithium ion battery capable of avoiding liquid leakage
CN207441852U (en) * 2017-11-29 2018-06-01 宁德时代新能源科技股份有限公司 Pole piece coiled material, electrode assembly and secondary cell
CN208225978U (en) * 2018-05-09 2018-12-11 合肥国轩高科动力能源有限公司 A kind of lithium battery pole piece structure of anti-lug bending
CN112038566A (en) * 2020-08-04 2020-12-04 江苏塔菲尔新能源科技股份有限公司 Preparation method of battery cell and battery cell

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