WO2023249526A1 - Method and system for bleaching pulp from recycled textile material - Google Patents
Method and system for bleaching pulp from recycled textile material Download PDFInfo
- Publication number
- WO2023249526A1 WO2023249526A1 PCT/SE2023/050382 SE2023050382W WO2023249526A1 WO 2023249526 A1 WO2023249526 A1 WO 2023249526A1 SE 2023050382 W SE2023050382 W SE 2023050382W WO 2023249526 A1 WO2023249526 A1 WO 2023249526A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- bleaching
- ozone
- pulp
- stage
- stages
- Prior art date
Links
- 238000004061 bleaching Methods 0.000 title claims abstract description 250
- 238000000034 method Methods 0.000 title claims abstract description 63
- 239000000463 material Substances 0.000 title claims abstract description 32
- 239000004753 textile Substances 0.000 title claims abstract description 25
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 108
- 238000005406 washing Methods 0.000 claims abstract description 36
- 229920002678 cellulose Polymers 0.000 claims abstract description 27
- 239000001913 cellulose Substances 0.000 claims abstract description 27
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims description 36
- 239000000654 additive Substances 0.000 claims description 31
- 239000004155 Chlorine dioxide Substances 0.000 claims description 18
- 235000019398 chlorine dioxide Nutrition 0.000 claims description 18
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 15
- 239000002738 chelating agent Substances 0.000 claims description 11
- 239000007789 gas Substances 0.000 claims description 11
- 238000004537 pulping Methods 0.000 claims description 11
- 239000002516 radical scavenger Substances 0.000 claims description 11
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 10
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- 238000009897 hydrogen peroxide bleaching Methods 0.000 claims description 9
- 230000014759 maintenance of location Effects 0.000 claims description 9
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims description 8
- 239000007844 bleaching agent Substances 0.000 claims description 5
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 5
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 5
- 235000006408 oxalic acid Nutrition 0.000 claims description 5
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 3
- 239000001110 calcium chloride Substances 0.000 claims description 3
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 3
- 238000000605 extraction Methods 0.000 claims description 3
- 229960003330 pentetic acid Drugs 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 230000001419 dependent effect Effects 0.000 claims 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 12
- 238000010790 dilution Methods 0.000 description 7
- 239000012895 dilution Substances 0.000 description 7
- 230000000996 additive effect Effects 0.000 description 4
- 238000007865 diluting Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 230000008719 thickening Effects 0.000 description 3
- 238000011144 upstream manufacturing Methods 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 239000001117 sulphuric acid Substances 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 238000010517 secondary reaction Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/147—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications
- D21C9/153—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications with ozone
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B16/00—Regeneration of cellulose
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
- C08H8/00—Macromolecular compounds derived from lignocellulosic materials
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1026—Other features in bleaching processes
- D21C9/1042—Use of chelating agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1057—Multistage, with compounds cited in more than one sub-group D21C9/10, D21C9/12, D21C9/16
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/12—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds
- D21C9/14—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds with ClO2 or chlorites
- D21C9/144—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds with ClO2 or chlorites with ClO2/Cl2 and other bleaching agents in a multistage process
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/14—Secondary fibres
Definitions
- the invention relates to a method for bleaching pulp formed from recycled textile material comprising cellulose, which method comprises ozone bleaching.
- the invention also relates to a corresponding system.
- Renewcell has developed a process for recycling cellulose from textile material comprising cellulose, see for instance WO2018/073177A1. Recycled cellulose can be used for different purposes, for example for producing viscose.
- the need for de-colorization/bleaching of the recycled textile material is identified, and it is suggested to use a combination of oxygen and ozone bleaching.
- Ozone bleaching of cellulose pulp from wood material is well known in the art, where ozone reacts with and de-composes lignin originating from the wood material.
- the purpose of the ozone bleaching is somewhat different - mainly to bleach or decompose color pigments contained in the pulp, which pulp mainly consists of cellulose and liquid (water).
- pulp mainly consists of cellulose and liquid (water).
- ozone it has however proven challenging to achieve sufficient brightness of the resulting pulp.
- the oxidative properties of ozone will also attack the cellulose fibers and may reduce the viscosity of the resulting pulp to an unsatisfactorily low level.
- SE 544236C2 proposes ozone bleaching of pulp formed from recycled textile material by means of adding ozone at a significantly higher charges (at least 12 kg/odt) than what is normally used.
- An object of the invention is to provide a method and a system for bleaching pulp formed from recycled textile material with further improved performance in terms of brightness and/or ozone consumption and/or viscosity.
- a method for bleaching pulp formed from recycled textile material comprising cellulose.
- the method comprises subjecting the pulp to a first bleaching stage to obtain bleached pulp, washing the bleached pulp from the first bleaching stage to obtain washed and bleached pulp, and subjecting the washed and bleached pulp from the washing to a second bleaching stage, wherein the first and second bleaching stages both comprise ozone bleaching.
- the method comprises two bleaching stages, each comprising ozone bleaching, with an intermediate washing stage.
- the method is a method for bleaching pulp (previously) formed from recycled textile material comprising cellulose i.e. the forming of the pulp (pulping) is not necessarily part of the method according to the first aspect of the invention.
- the method comprises providing pulp formed from recycled textile material comprising cellulose.
- the two bleaching stages both comprise ozone bleaching, one or both of the bleaching stages may comprise additional steps, as will be explained in the embodiments below.
- the method may comprise further stages prior or after the first bleaching stage and/or prior or after the second bleaching stage.
- the pulp may be provided to the first bleaching stage at high consistency (HC), for example at a consistency (by weight) of at least 30%, preferably within a range from 35-42%.
- the pulp may be provided to the first bleaching stage at medium consistency (MC), for example at a consistency (by weight) of 8-16%, preferably 10-12%.
- the pulp may be provided to the second bleaching stage also at high consistency (HC), for example at a consistency (by weight) of at least 30%, preferably within a range from 35-42%.
- Such high consistency to the second bleaching stage may be achieved by providing pulp at high consistency to the first bleaching stage followed by the washing stage and an optional dewatering stage before the second bleaching stage.
- the pulp may be provided to the second bleaching stage at medium consistency (MC), for example at a consistency (by weight) of 8-16%, preferably 10-12%.
- medium consistency to the second bleaching stage may be achieved by providing pulp at high consistency to the first bleaching stage followed by the washing and an optional diluting stage (or pretreating stage which comprises dilution) before the second bleaching stage.
- the pulp may be provided to the first bleaching stage at medium consistency (MC), for example at a consistency (by weight) of 8- 16%, preferably 10-12%.
- the pulp may be provided to the second bleaching stage also at medium consistency (MC), for example at a consistency (by weight) of 8-16%, preferably 10-12%.
- the pulp may be provided to the second bleaching stage at high consistency (HC), for example at a consistency (by weight) of at least 30%, preferably within a range from 35-42%.
- high consistency to the second bleaching stage may be achieved by providing pulp at medium consistency to the first bleaching stage followed by the washing and a dewatering stage before the second bleaching stage.
- Ozone may be added as a gas mixture, for example with 8-14 % ozone by weight in an ozoneair mixture.
- the ozone bleaching of a HC pulp may be performed for a duration of 10 seconds - 5 minutes, for example at a temperature of 40-70°C.
- the invention as defined by the first aspect of the invention is based on the insight that by separating the ozone charge into two ozone bleaching stages, and providing an intermediate washing stage, the washing stage will remove dissolved material resulting from the first bleaching stage that otherwise will consume ozone in the second bleaching stage without being useful for brightness increase of the pulp. In other words, a larger portion of the ozone charge contributes to bleaching of the pulp. Thus, for a given desired brightness of the pulp, overall ozone consumption may be reduced compared with using only one ozone bleaching stage.
- the total ozone charge of the ozone bleaching of the first and second bleaching stages may be less than 12 kg/odt, preferably less than 10 kg/odt, or less than 8 kg/odt.
- a method for bleaching pulp formed from recycled textile material comprising cellulose.
- the method comprises subjecting the pulp to a first bleaching stage, washing the (bleached) pulp obtained from the first bleaching stage, and subjecting the (washed) pulp obtained from the washing to a second bleaching stage.
- the second bleaching stage comprises ozone bleaching.
- the first bleaching stage may comprise ozone bleaching.
- the first bleaching stage may comprise at least one of chlorine dioxide bleaching, hydrogen peroxide bleaching and oxygen bleaching.
- the second aspect of the invention may be advantageous since the washing stage will remove dissolved material resulting from the first bleaching stage that otherwise will consume ozone in the second bleaching stage without being useful for brightness increase of the pulp.
- the ozone charge in the second bleaching stage may be reduced compared to if not preceded by the washing (and the first bleaching stage).
- the ozone bleaching in the first bleaching stage has a shorter retention time than the ozone bleaching in the second bleaching stage.
- the retention times it is understood that the consistency of the pulp fed to the (ozone bleaching of the) first and second bleaching stages must be substantially the same, i.e.
- the pulp is at high consistency (HC), for example at a consistency (by weight) of at least 30%, preferably within a range from 35-42% at both the first and second bleaching stages, or the pulp is at medium consistency (MC), for example at a consistency (by weight) of 8-16%, preferably 10-12% at both the first and second bleaching stages.
- HC high consistency
- MC medium consistency
- fresh ozone gas is supplied to, and counter currently charged in, the ozone bleaching of the first and/or second bleaching stage.
- This may provide advantageous bleaching results, in particular when the pulp subjected to bleaching has a high consistency (typically 30% or more).
- Such counter currently charging is most advantageous when the pulp fed to the ozone bleaching of the first and/or second bleaching stage is at HC (as defined above).
- one or both of the first and second bleaching stages comprises adding one or more additives, the additives comprising at least one chelating agent and/or at least one radical scavenger.
- the first and/or second bleaching stage may be referred to as a Zq-stage.
- the one or more additives may be added directly after the ozone bleaching in the first and/or second bleaching stages, i.e. without any intermediate washing or other step.
- the first/and or second bleaching stage may comprise a dilution step (using a dilution screw for example) directly after the ozone bleaching step in which dilution liquid and the at least one chelating agent and/or at least one radical scavenger is added.
- the one or more additives may alternatively be added before the ozone bleaching of the first and/or second bleaching stages.
- Chelating agents which may also be referred to as complexing agents, provide the effect that selectivity in the ozone bleaching step is improved by reducing the content of metal ions in the pulp, which metal ions catalyze the degradation of ozone to free radicals, which in turn cause cellulose degradation.
- the one or more additives may be chosen from a group comprising oxalic acid, acetic acid, ethylenediaminetetraacetic acid, EDTA, diethylenetriaminepentaacetic acid, DTPA, magnesium sulfate or calcium chloride.
- the additives may be added at charge of 1-20 kg/odt, or more specifically if the additive is EDTA or DTPA at charge of 1-2 kg/odt.
- the first and/or second bleaching stage(s) comprise(s) alkaline extraction after the ozone bleaching.
- the first and/or second bleaching stage may be a Ze-stage.
- the first and/or second bleaching stage(s) comprise(s) ozone bleaching followed by chlorine dioxide bleaching.
- the first and/or second bleaching stage may be a ZD-stage.
- the chlorine dioxide bleaching may follow directly after the ozone bleaching, i.e. without intermediate washing, and may thus be referred to as a (ZD) stage.
- ZD ZD stage.
- This may be advantageous since a combination of chlorine dioxide and ozone results in a synergistic effect regarding brightness level. Therefore, an addition of chlorine dioxide directly after the ozone stage without intermediate washing will reinforce the bleaching effect.
- advantageous effects in terms of viscosity control may be achieved since ozone impacts viscosity while chlorine dioxide does not.
- the chlorine dioxide charge may, if only one of the first and second bleaching stages comprises chlorine dioxide bleaching, correspond to 30 kg active chlorine /odt or less. If both the first and the second bleaching stages comprise chlorine dioxide bleaching, the total chlorine dioxide charge may correspond to 40 kg active chlorine /odt or less
- the first and/or second bleaching stage(s) comprise(s) ozone bleaching followed by hydrogen peroxide bleaching.
- the first and/or second bleaching stage may be a ZP-stage.
- the hydrogen peroxide bleaching may follow directly after the ozone bleaching, i.e. without intermediate washing, and may thus be referred to as a (ZP) stage.
- Hydrogen peroxide is a secondary reactions product in ozone bleaching, therefore an addition of hydrogen peroxide directly after the ozone stage without intermediate washing will reinforce the ozone bleaching stage.
- the total hydrogen peroxide charge of the first and/or second bleaching stages may be less than 40 kg hydrogen peroxide /odt.
- the method further comprises pretreating the pulp prior to said first bleaching stage and/or prior to the second bleaching stage (between the washing stage and the second bleaching stage), wherein said pretreating comprises adding at least one acid to reduce the pH of the pulp and/or adding one or more additives.
- the one or more additives may be added together with, or simultaneously with the at least one acid. Alternatively, the one or more additives may be added prior to, or after the at least one acid.
- the at least one acid may comprise sulphuric acid.
- the at least one acid may be added at a charge such that the pH is reduced to within a range from 2 to 3, preferably from 2 to 2.5 or from 2.5 to 3.
- the one or more additives may comprise one or more chelating agents and/or radical scavengers.
- the one or more additives may be chosen from a group comprising oxalic acid, acetic acid, ethylenediaminetetraacetic acid, EDTA, diethylenetriaminepentaacetic acid, DTPA, magnesium sulfate or calcium chloride.
- the additives may be added at charge of 1-20 kg/odt, or more specifically if the additive is EDTA or DTPA at charge of 1-2 kg/odt.
- a method for producing bleached cellulose pulp from recycled textile material comprising cellulose.
- the method comprises pulping the recycled textile material to form cellulose pulp and bleaching the cellulose pulp using a method according to the first or second aspect of the invention or embodiments thereof.
- a system for bleaching pulp formed from recycled textile material comprising cellulose comprising cellulose
- the system comprises a first bleaching arrangement arranged to bleach the pulp, a washing arrangement arranged to wash bleached pulp from the first bleaching arrangement, and a second bleaching arrangement arranged to bleach washed pulp from the washing arrangement, wherein the first and second bleaching arrangement each comprises an ozone bleaching apparatus.
- the second bleaching arrangement is physically separate from the first bleaching arrangement, i.e. the ozone bleaching apparatus and optional additional apparatuses of the second bleaching arrangement is/are separate from the ozone bleaching apparatus and optional additional apparatuses of the first bleaching arrangement.
- the system comprises a pulping arrangement arranged to receive the recycled textile material to produce pulp therefrom, wherein the first bleaching arrangement is arranged to receive pulp from the pulping arrangement.
- a pulping arrangement arranged to receive the recycled textile material to produce pulp therefrom
- the first bleaching arrangement is arranged to receive pulp from the pulping arrangement.
- Such an embodiment may be referred to as a system for producing bleached cellulose pulp from recycled textile material comprising cellulose.
- the ozone bleaching apparatus of at least one of the first and second bleaching arrangements comprises means for supplying fresh ozone gas and counter currently charging the ozone gas in said ozone bleaching apparatus.
- At least one of the first and second bleaching arrangements comprises means for adding one or more additives.
- the additives may comprise at least one chelating agent and/or at least one radical scavenger.
- the means for adding may be arranged downstream of the ozone bleaching apparatus.
- the means for adding may comprise a dilution screw directly after the ozone bleaching step in which dilution liquid and the one or more additives are added.
- the means for adding may be arranged upstream of the ozone bleaching apparatus.
- At least one of the first and second bleaching arrangements comprises an alkaline extraction apparatus downstream of the ozone bleaching apparatus.
- At least one of the first and second bleaching arrangements comprises a bleaching apparatus comprising means for adding chlorine dioxide or hydrogen peroxide, said bleaching apparatus being arranged downstream of the respective ozone bleaching apparatus.
- the bleaching apparatus comprising means for adding chlorine dioxide or hydrogen peroxide may be arranged directly after the ozone bleaching apparatus in the sense that there are no intermediate stages such as diluting or washing.
- the system further comprises at least one pretreating arrangement arranged upstream of the first bleaching arrangement and/or upstream of the second bleaching arrangement (between the washing arrangement and the second bleaching arrangement), the pretreating arrangement being configured to add at least one acid to reduce the pH of the pulp and/or one or more additives, said one or more additives comprising at least one chelating agent and/or at least one radical scavenger.
- fig. 1 schematically illustrates embodiments of the methods according to the first, second and third aspects of the invention
- fig. 2 schematically illustrates other embodiments of the methods according to the first, second and third aspects of the invention.
- Fig. 1-2 also illustrate embodiments of the system according to the fourth aspect of the invention.
- Fig. 1 schematically illustrates an embodiment of the method according to the third aspect of the invention.
- the method comprises pulping 1 the recycled textile material to form cellulose pulp, for instance by swelling the material under reducing conditions as described in WO2018/073177A1.
- the pulping 1 may comprise washing the formed pulp.
- the pulp is pretreated 2 by adding sulphuric acid to reduce the pH of the pulp to within a range from 2 to 3.
- the pretreatment may comprise diluting the pulp to low consistency prior to adding acid.
- the acidified pulp is subjected to an optional dewatering/thickening stage 3 such that the pulp is provided to the first bleaching stage 4 at high consistency (at least 30%, preferably within a range from 35-42%).
- the first bleaching stage 4 comprises ozone bleaching, i.e. bleaching by means of adding ozone to the pulp.
- the first bleaching stage 4 furthermore comprises adding one or more additives, the additives comprising at least one of oxalic acid, EDTA and magnesium sulfate.
- the first bleaching stage may be referred to as a Zq-stage.
- the additive(s) are added directly after the ozone bleaching, for instance in a dilution screw.
- the pulp is washed 5 to remove dissolved material from the first bleaching stage, whereafter it is pretreated/acidified 6 once again in a corresponding manner as described above with reference to stage 2.
- the acidified pulp is subjected to an optional dewatering/thickening stage 7 such that the pulp is provided to the second bleaching stage 8 at a HC consistency of at least 30%, preferably within a range from 35-42%.
- the second bleaching stage 8 corresponds to the first bleaching stage.
- the retention time in the first bleaching stage is shorter than in the second bleaching stage, however.
- fresh ozone gas is supplied to, and counter currently charged.
- Other embodiments correspond to the embodiment in fig.
- pretreating stages 2 and/or 6 may be referred to as aq-stages
- the bleaching stages 4 and/or 8 may be referred to as Z-stages.
- the description below with reference to pretreating stage 16 applies to pretreating stage 2 and/or 6 in such embodiments.
- Steps 2-8 of fig. 1 also illustrate an embodiment of the method according to the first aspect of the invention. Steps 2-8 of fig. 1 also illustrate an embodiment of the method according to the second aspect of the invention provided with ozone bleaching in the first bleaching stage.
- Fig. 2 schematically illustrates another embodiment of the method according to the third aspect of the invention.
- the method comprises a pulping/washing stage 11 , pretreating stage 12, optional dewatering stages 13/17, a first bleaching stage 14 and a washing stage 15 corresponding to stages 1 , 2, 3/7, 4 and 5, respectively in fig. 1.
- the embodiment in fig. 2 differs in that the second bleaching stage 18 comprises ozone bleaching followed by chlorine dioxide bleaching or hydrogen peroxide bleaching.
- the chlorine dioxide/hydrogen peroxide bleaching follows directly after the ozone bleaching, i.e. without intermediate washing.
- the second bleaching stage is a (ZD)- or (ZP)-stage.
- the embodiment in fig. 2 further differs from fig.
- the pretreating stage 16 comprises not only adding at least one acid to reduce the pH of the pulp in the same manner as in stages 2 and 6 in fig. 1 , but also adding one or more additives, the additives comprising at least one of oxalic acid, EDTA and magnesium sulfate.
- the pretreating stage may be referred to as an aq-stage.
- the additive(s) are added together with, or simultaneously with the at least one acid.
- ozone is added as a gas mixture, for example with 8- 16% ozone by weight in an ozone-air mixture, preferably 10-12% ozone by weight.
- the ozone bleaching of each of the first and second bleaching stages may be performed for a duration of 10 seconds - 5 minutes, such as 30-60 seconds, at a temperature of 40-70°C.
- the overall ozone charge of the first and second bleaching stages combined amounts to less than 8g/odt, typically 5-6 kg/odt.
- Steps 12-18 of fig. 2 also constitute an embodiment of the method according to the first aspect of the invention. Steps 12-18 of fig. 2 also constitute an embodiment of the method according to the second aspect of the invention provided with ozone bleaching in the first bleaching stage.
- pretreating stage 12 is an aq-stage in a corresponding manner as pretreating stage 16, and the bleaching stage 14 is a Z-stage.
- Fig. 1-2 could also be said to illustrate embodiments of the system according to the fourth aspect of the invention, which embodiments comprises a pulping/washing arrangement 1/11 , pretreating arrangements 2/12, 6/16, dewatering/thickening arrangements 3/13, 6/16, ozone bleaching apparatuses 4/14, 8/18 and a washing apparatus 5/15.
- Such arrangements and apparatuses are all well-known in the art and will not be described in further detail here.
- the description above and the appended drawings are to be considered as non-limiting examples of the invention.
- the person skilled in the art realizes that several changes and modifications may be made within the scope of the invention.
- one or more of the bleaching stage(s) prior to or after the first and second bleaching step(s) may be added, or part(s) of the first and second bleaching stages (for example the chlorine dioxide bleaching or hydrogen peroxide bleaching in fig. 2) may be omitted.
- the ozone bleaching of the first bleaching stage may be omitted.
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Abstract
A method for bleaching pulp formed from recycled textile material comprising cellulose. The method comprises subjecting the pulp to a first bleaching stage (4), washing (5) the (bleached) pulp obtained from the first bleaching stage, and subjecting the (washed) pulp obtained from the washing to a second bleaching stage (8), wherein the first and second bleaching stages both comprise ozone bleaching. A corresponding system is also provided.
Description
METHOD AND SYSTEM FOR BLEACHING PULP FROM RECYCLED TEXTILE MATERIAL
TECHNICAL FIELD
The invention relates to a method for bleaching pulp formed from recycled textile material comprising cellulose, which method comprises ozone bleaching. The invention also relates to a corresponding system.
BACKGROUND
Over the recent years, recycling of textile material has gained interest. The company Renewcell has developed a process for recycling cellulose from textile material comprising cellulose, see for instance WO2018/073177A1. Recycled cellulose can be used for different purposes, for example for producing viscose. In the above-mentioned publication, the need for de-colorization/bleaching of the recycled textile material is identified, and it is suggested to use a combination of oxygen and ozone bleaching.
Ozone bleaching of cellulose pulp from wood material is well known in the art, where ozone reacts with and de-composes lignin originating from the wood material. When it comes to bleaching of pulp from textile material, the purpose of the ozone bleaching is somewhat different - mainly to bleach or decompose color pigments contained in the pulp, which pulp mainly consists of cellulose and liquid (water). Despite the use of ozone, it has however proven challenging to achieve sufficient brightness of the resulting pulp. Further, the oxidative properties of ozone will also attack the cellulose fibers and may reduce the viscosity of the resulting pulp to an unsatisfactorily low level.
SE 544236C2 proposes ozone bleaching of pulp formed from recycled textile material by means of adding ozone at a significantly higher charges (at least 12 kg/odt) than what is normally used.
SUMMARY
An object of the invention is to provide a method and a system for bleaching pulp formed from recycled textile material with further improved performance in terms of brightness and/or ozone consumption and/or viscosity.
These and other objects are achieved by the present invention by means of a method and a system according to the independent claims.
According to a first aspect of the invention, there is provided a method for bleaching pulp formed from recycled textile material comprising cellulose. The method comprises subjecting the pulp to a first bleaching stage to obtain bleached pulp, washing the bleached pulp from the first bleaching stage to obtain washed and bleached pulp, and subjecting the washed and bleached pulp from the washing to a second bleaching stage, wherein the first and second bleaching stages both comprise ozone bleaching.
In other words, the method comprises two bleaching stages, each comprising ozone bleaching, with an intermediate washing stage. It is understood that the method is a method for bleaching pulp (previously) formed from recycled textile material comprising cellulose i.e. the forming of the pulp (pulping) is not necessarily part of the method according to the first aspect of the invention. Put differently, the method comprises providing pulp formed from recycled textile material comprising cellulose. It is furthermore understood that although the two bleaching stages both comprise ozone bleaching, one or both of the bleaching stages may comprise additional steps, as will be explained in the embodiments below. It is furthermore understood that the method may comprise further stages prior or after the first bleaching stage and/or prior or after the second bleaching stage.
The pulp may be provided to the first bleaching stage at high consistency (HC), for example at a consistency (by weight) of at least 30%, preferably within a range from 35-42%. Alternatively, the pulp may be provided to the first bleaching stage at medium consistency (MC), for example at a consistency (by weight) of 8-16%, preferably 10-12%. Furthermore, the pulp may be provided to the second bleaching stage also at high consistency (HC), for example at a consistency (by weight) of at least 30%, preferably within a range from 35-42%. Such high consistency to the second bleaching stage may be achieved by providing pulp at high consistency to the first bleaching stage followed by the washing stage and an optional dewatering stage before the second bleaching stage. Alternatively, the pulp may be provided to the second bleaching stage at medium consistency (MC), for example at a consistency (by weight) of 8-16%, preferably 10-12%. Such medium consistency to the second bleaching stage may be achieved by providing pulp at high consistency to the first bleaching stage followed by the washing and an optional diluting stage (or pretreating stage which comprises dilution) before the second bleaching stage. Alternatively, the pulp may be provided to the first bleaching stage at medium consistency (MC), for example at a consistency (by weight) of 8- 16%, preferably 10-12%. In this case, the pulp may be provided to the second bleaching stage also at medium consistency (MC), for example at a consistency (by weight) of 8-16%, preferably 10-12%. Alternatively, the pulp may be provided to the second bleaching stage at
high consistency (HC), for example at a consistency (by weight) of at least 30%, preferably within a range from 35-42%. Such high consistency to the second bleaching stage may be achieved by providing pulp at medium consistency to the first bleaching stage followed by the washing and a dewatering stage before the second bleaching stage.
Ozone may be added as a gas mixture, for example with 8-14 % ozone by weight in an ozoneair mixture. The ozone bleaching of a HC pulp may be performed for a duration of 10 seconds - 5 minutes, for example at a temperature of 40-70°C.
The invention as defined by the first aspect of the invention is based on the insight that by separating the ozone charge into two ozone bleaching stages, and providing an intermediate washing stage, the washing stage will remove dissolved material resulting from the first bleaching stage that otherwise will consume ozone in the second bleaching stage without being useful for brightness increase of the pulp. In other words, a larger portion of the ozone charge contributes to bleaching of the pulp. Thus, for a given desired brightness of the pulp, overall ozone consumption may be reduced compared with using only one ozone bleaching stage. The total ozone charge of the ozone bleaching of the first and second bleaching stages may be less than 12 kg/odt, preferably less than 10 kg/odt, or less than 8 kg/odt. Thus, a lower overall ozone charge is possible compared to SE544236C2. It is understood that odt = oven dry ton, where 1 ton = 1000kg, i.e. odt = oven dry metric ton (odmt).
According to a second aspect of the invention, there is provided a method for bleaching pulp formed from recycled textile material comprising cellulose. The method comprises subjecting the pulp to a first bleaching stage, washing the (bleached) pulp obtained from the first bleaching stage, and subjecting the (washed) pulp obtained from the washing to a second bleaching stage. The second bleaching stage comprises ozone bleaching. The first bleaching stage may comprise ozone bleaching. Alternatively, or additionally, the first bleaching stage may comprise at least one of chlorine dioxide bleaching, hydrogen peroxide bleaching and oxygen bleaching.
The second aspect of the invention may be advantageous since the washing stage will remove dissolved material resulting from the first bleaching stage that otherwise will consume ozone in the second bleaching stage without being useful for brightness increase of the pulp. In other words, the ozone charge in the second bleaching stage may be reduced compared to if not preceded by the washing (and the first bleaching stage).
In embodiments of the method according to the first aspect of the invention, or in embodiments of the method according to the second aspect of the invention in which the first bleaching stage
comprises ozone bleaching, the ozone bleaching in the first bleaching stage has a shorter retention time than the ozone bleaching in the second bleaching stage. In order for the retention times to be compared in this embodiment, it is understood that the consistency of the pulp fed to the (ozone bleaching of the) first and second bleaching stages must be substantially the same, i.e. the pulp is at high consistency (HC), for example at a consistency (by weight) of at least 30%, preferably within a range from 35-42% at both the first and second bleaching stages, or the pulp is at medium consistency (MC), for example at a consistency (by weight) of 8-16%, preferably 10-12% at both the first and second bleaching stages. Having a shorter retention time in the ozone bleaching of the first bleaching stage may be advantageous since some chemical compounds require rather short retention time while the byproduct require longer retention time. For example, it has been shown that a rather short time is required for ozone to remove reactive black through the, i.e, N=N- chromphoric double bond breaking. Consequently, it may be advantageous to use a shorter retention time in the ozone bleaching of the first bleaching stage to remove dyes such as reactive black which decompose quickly, whereas the remaining dyes which decompose more slowly can, after dissolved material from the first bleaching stage has been removed by means of washing, be efficiently removed in the second bleaching stage (having a longer retention time).
In embodiments of the method according to the first or second aspect of the invention, fresh ozone gas is supplied to, and counter currently charged in, the ozone bleaching of the first and/or second bleaching stage. This may provide advantageous bleaching results, in particular when the pulp subjected to bleaching has a high consistency (typically 30% or more). Such counter currently charging is most advantageous when the pulp fed to the ozone bleaching of the first and/or second bleaching stage is at HC (as defined above).
In embodiments of the method according to the first or second aspect of the invention, one or both of the first and second bleaching stages comprises adding one or more additives, the additives comprising at least one chelating agent and/or at least one radical scavenger. Thus, the first and/or second bleaching stage may be referred to as a Zq-stage. The one or more additives may be added directly after the ozone bleaching in the first and/or second bleaching stages, i.e. without any intermediate washing or other step. The first/and or second bleaching stage may comprise a dilution step (using a dilution screw for example) directly after the ozone bleaching step in which dilution liquid and the at least one chelating agent and/or at least one radical scavenger is added. The one or more additives may alternatively be added before the ozone bleaching of the first and/or second bleaching stages. Chelating agents, which may also be referred to as complexing agents, provide the effect that selectivity in the ozone bleaching step is improved by reducing the content of metal ions in the pulp, which metal ions catalyze
the degradation of ozone to free radicals, which in turn cause cellulose degradation. Radical scavengers have a similar effect by scavenging the metal ions. The one or more additives may be chosen from a group comprising oxalic acid, acetic acid, ethylenediaminetetraacetic acid, EDTA, diethylenetriaminepentaacetic acid, DTPA, magnesium sulfate or calcium chloride. The additives may be added at charge of 1-20 kg/odt, or more specifically if the additive is EDTA or DTPA at charge of 1-2 kg/odt.
In embodiments of the method according to the first or second aspect of the invention, the first and/or second bleaching stage(s) comprise(s) alkaline extraction after the ozone bleaching. Thus, the first and/or second bleaching stage may be a Ze-stage.
In embodiments of the method according to the first or second aspect of the invention, the first and/or second bleaching stage(s) comprise(s) ozone bleaching followed by chlorine dioxide bleaching. Thus, the first and/or second bleaching stage may be a ZD-stage. The chlorine dioxide bleaching may follow directly after the ozone bleaching, i.e. without intermediate washing, and may thus be referred to as a (ZD) stage. This may be advantageous since a combination of chlorine dioxide and ozone results in a synergistic effect regarding brightness level. Therefore, an addition of chlorine dioxide directly after the ozone stage without intermediate washing will reinforce the bleaching effect. Furthermore, advantageous effects in terms of viscosity control may be achieved since ozone impacts viscosity while chlorine dioxide does not. The chlorine dioxide charge may, if only one of the first and second bleaching stages comprises chlorine dioxide bleaching, correspond to 30 kg active chlorine /odt or less. If both the first and the second bleaching stages comprise chlorine dioxide bleaching, the total chlorine dioxide charge may correspond to 40 kg active chlorine /odt or less
In embodiments of the method according to the first or second aspect of the invention, the first and/or second bleaching stage(s) comprise(s) ozone bleaching followed by hydrogen peroxide bleaching. Thus, the first and/or second bleaching stage may be a ZP-stage. The hydrogen peroxide bleaching may follow directly after the ozone bleaching, i.e. without intermediate washing, and may thus be referred to as a (ZP) stage. Hydrogen peroxide is a secondary reactions product in ozone bleaching, therefore an addition of hydrogen peroxide directly after the ozone stage without intermediate washing will reinforce the ozone bleaching stage. The total hydrogen peroxide charge of the first and/or second bleaching stages may be less than 40 kg hydrogen peroxide /odt.
In embodiments of the method according to the first or second aspect of the invention, the method further comprises pretreating the pulp prior to said first bleaching stage and/or prior to
the second bleaching stage (between the washing stage and the second bleaching stage), wherein said pretreating comprises adding at least one acid to reduce the pH of the pulp and/or adding one or more additives. The one or more additives may be added together with, or simultaneously with the at least one acid. Alternatively, the one or more additives may be added prior to, or after the at least one acid. The at least one acid may comprise sulphuric acid. The at least one acid may be added at a charge such that the pH is reduced to within a range from 2 to 3, preferably from 2 to 2.5 or from 2.5 to 3. The one or more additives may comprise one or more chelating agents and/or radical scavengers. The one or more additives may be chosen from a group comprising oxalic acid, acetic acid, ethylenediaminetetraacetic acid, EDTA, diethylenetriaminepentaacetic acid, DTPA, magnesium sulfate or calcium chloride. The additives may be added at charge of 1-20 kg/odt, or more specifically if the additive is EDTA or DTPA at charge of 1-2 kg/odt.
According to a third aspect of the invention, there is provided a method for producing bleached cellulose pulp from recycled textile material comprising cellulose. The method comprises pulping the recycled textile material to form cellulose pulp and bleaching the cellulose pulp using a method according to the first or second aspect of the invention or embodiments thereof.
According to a fourth aspect of the invention, there is provided a system for bleaching pulp formed from recycled textile material comprising cellulose, where the system comprises a first bleaching arrangement arranged to bleach the pulp, a washing arrangement arranged to wash bleached pulp from the first bleaching arrangement, and a second bleaching arrangement arranged to bleach washed pulp from the washing arrangement, wherein the first and second bleaching arrangement each comprises an ozone bleaching apparatus. It is understood that the second bleaching arrangement is physically separate from the first bleaching arrangement, i.e. the ozone bleaching apparatus and optional additional apparatuses of the second bleaching arrangement is/are separate from the ozone bleaching apparatus and optional additional apparatuses of the first bleaching arrangement.
In embodiments of the system, the system comprises a pulping arrangement arranged to receive the recycled textile material to produce pulp therefrom, wherein the first bleaching arrangement is arranged to receive pulp from the pulping arrangement. Such an embodiment may be referred to as a system for producing bleached cellulose pulp from recycled textile material comprising cellulose.
In embodiments of the system, the ozone bleaching apparatus of at least one of the first and second bleaching arrangements comprises means for supplying fresh ozone gas and counter currently charging the ozone gas in said ozone bleaching apparatus.
In embodiments of the system, at least one of the first and second bleaching arrangements comprises means for adding one or more additives. The additives may comprise at least one chelating agent and/or at least one radical scavenger. The means for adding may be arranged downstream of the ozone bleaching apparatus. For example, the means for adding may comprise a dilution screw directly after the ozone bleaching step in which dilution liquid and the one or more additives are added. Alternatively, the means for adding may be arranged upstream of the ozone bleaching apparatus.
In embodiments of the system, at least one of the first and second bleaching arrangements comprises an alkaline extraction apparatus downstream of the ozone bleaching apparatus.
In embodiments of the system, at least one of the first and second bleaching arrangements comprises a bleaching apparatus comprising means for adding chlorine dioxide or hydrogen peroxide, said bleaching apparatus being arranged downstream of the respective ozone bleaching apparatus. The bleaching apparatus comprising means for adding chlorine dioxide or hydrogen peroxide may be arranged directly after the ozone bleaching apparatus in the sense that there are no intermediate stages such as diluting or washing.
In embodiments of the system, the system further comprises at least one pretreating arrangement arranged upstream of the first bleaching arrangement and/or upstream of the second bleaching arrangement (between the washing arrangement and the second bleaching arrangement), the pretreating arrangement being configured to add at least one acid to reduce the pH of the pulp and/or one or more additives, said one or more additives comprising at least one chelating agent and/or at least one radical scavenger.
The features of the embodiments described above are combinable in any practically realizable way to form embodiments having combinations of these features. Further, all features and advantages of embodiments described above with reference to the first aspect of the invention may be applied in corresponding embodiments of the second, third and fourth aspects of the invention and vice versa.
BRIEF DESCRIPTION OF THE DRAWINGS
Above discussed and other aspects of the present invention will now be described in more detail using the appended drawings, which show presently preferred embodiments of the invention, wherein: fig. 1 schematically illustrates embodiments of the methods according to the first, second and third aspects of the invention, and fig. 2 schematically illustrates other embodiments of the methods according to the first, second and third aspects of the invention.
Fig. 1-2 also illustrate embodiments of the system according to the fourth aspect of the invention.
DETAILED DESCRIPTION
Fig. 1 schematically illustrates an embodiment of the method according to the third aspect of the invention. The method comprises pulping 1 the recycled textile material to form cellulose pulp, for instance by swelling the material under reducing conditions as described in WO2018/073177A1. The pulping 1 may comprise washing the formed pulp. Thereafter, the pulp is pretreated 2 by adding sulphuric acid to reduce the pH of the pulp to within a range from 2 to 3. The pretreatment may comprise diluting the pulp to low consistency prior to adding acid. Depending on the desired consistency, the acidified pulp is subjected to an optional dewatering/thickening stage 3 such that the pulp is provided to the first bleaching stage 4 at high consistency (at least 30%, preferably within a range from 35-42%). The first bleaching stage 4 comprises ozone bleaching, i.e. bleaching by means of adding ozone to the pulp. The first bleaching stage 4 furthermore comprises adding one or more additives, the additives comprising at least one of oxalic acid, EDTA and magnesium sulfate. Thus, the first bleaching stage may be referred to as a Zq-stage. The additive(s) are added directly after the ozone bleaching, for instance in a dilution screw. After, the first bleaching stage 4, the pulp is washed 5 to remove dissolved material from the first bleaching stage, whereafter it is pretreated/acidified 6 once again in a corresponding manner as described above with reference to stage 2. Depending on the desired consistency, the acidified pulp is subjected to an optional dewatering/thickening stage 7 such that the pulp is provided to the second bleaching stage 8 at a HC consistency of at least 30%, preferably within a range from 35-42%. The second bleaching stage 8 corresponds to the first bleaching stage. The retention time in the first bleaching stage is shorter than in the second bleaching stage, however. In the ozone bleaching of the first and second bleaching stages, fresh ozone gas is supplied to, and counter currently charged.
Other embodiments correspond to the embodiment in fig. 1 except in that the one or more additives is added in the pretreating stage 2 instead of the first bleaching stage 4 and/or in that the one or more additives is added in the pretreating stage 6 instead of the second bleaching stage 8. Thus, the pretreating stages 2 and/or 6 may be referred to as aq-stages, and the bleaching stages 4 and/or 8 may be referred to as Z-stages. The description below with reference to pretreating stage 16 applies to pretreating stage 2 and/or 6 in such embodiments.
Other embodiments correspond to the embodiment in fig. 1 except in that the bleaching stages 4, 8 are replaced with Ze-stages.
Other embodiments correspond to the embodiment in fig. 1 except in that the dewatering stages 3, 7 are omitted or replaced with diluting stages such that the pulp is supplied to the bleaching stages 4, 8 at medium consistency (MC). In such embodiments, the ozone gas is not counter currently charged.
Steps 2-8 of fig. 1 also illustrate an embodiment of the method according to the first aspect of the invention. Steps 2-8 of fig. 1 also illustrate an embodiment of the method according to the second aspect of the invention provided with ozone bleaching in the first bleaching stage.
Fig. 2 schematically illustrates another embodiment of the method according to the third aspect of the invention. The method comprises a pulping/washing stage 11 , pretreating stage 12, optional dewatering stages 13/17, a first bleaching stage 14 and a washing stage 15 corresponding to stages 1 , 2, 3/7, 4 and 5, respectively in fig. 1. The embodiment in fig. 2 however differs in that the second bleaching stage 18 comprises ozone bleaching followed by chlorine dioxide bleaching or hydrogen peroxide bleaching. The chlorine dioxide/hydrogen peroxide bleaching follows directly after the ozone bleaching, i.e. without intermediate washing. Thus, the second bleaching stage is a (ZD)- or (ZP)-stage. The embodiment in fig. 2 further differs from fig. 1 in that the pretreating stage 16 comprises not only adding at least one acid to reduce the pH of the pulp in the same manner as in stages 2 and 6 in fig. 1 , but also adding one or more additives, the additives comprising at least one of oxalic acid, EDTA and magnesium sulfate. Thus, the pretreating stage may be referred to as an aq-stage. The additive(s) are added together with, or simultaneously with the at least one acid.
In the above-described embodiments, ozone is added as a gas mixture, for example with 8- 16% ozone by weight in an ozone-air mixture, preferably 10-12% ozone by weight. The ozone bleaching of each of the first and second bleaching stages may be performed for a duration of
10 seconds - 5 minutes, such as 30-60 seconds, at a temperature of 40-70°C. The overall ozone charge of the first and second bleaching stages combined amounts to less than 8g/odt, typically 5-6 kg/odt.
Steps 12-18 of fig. 2 also constitute an embodiment of the method according to the first aspect of the invention. Steps 12-18 of fig. 2 also constitute an embodiment of the method according to the second aspect of the invention provided with ozone bleaching in the first bleaching stage.
Other embodiments correspond to the embodiment in fig. 2 except in that the one or more additives is added in the pretreating stage 12 instead of the first bleaching stage 14. Thus, the pretreating stage 12 is an aq-stage in a corresponding manner as pretreating stage 16, and the bleaching stage 14 is a Z-stage.
Fig. 1-2 could also be said to illustrate embodiments of the system according to the fourth aspect of the invention, which embodiments comprises a pulping/washing arrangement 1/11 , pretreating arrangements 2/12, 6/16, dewatering/thickening arrangements 3/13, 6/16, ozone bleaching apparatuses 4/14, 8/18 and a washing apparatus 5/15. Such arrangements and apparatuses are all well-known in the art and will not be described in further detail here.
The description above and the appended drawings are to be considered as non-limiting examples of the invention. The person skilled in the art realizes that several changes and modifications may be made within the scope of the invention. For example, depending on the required brightness of the resulting pulp, one or more of the bleaching stage(s) prior to or after the first and second bleaching step(s) may be added, or part(s) of the first and second bleaching stages (for example the chlorine dioxide bleaching or hydrogen peroxide bleaching in fig. 2) may be omitted. Furthermore, in embodiments of the second aspect of the invention, the ozone bleaching of the first bleaching stage may be omitted.
Claims
1. A method for bleaching pulp formed from recycled textile material comprising cellulose, said method comprising: subjecting the pulp to a first bleaching stage (4; 14); washing the pulp from the first bleaching stage (5; 15); subjecting the pulp from the washing to a second bleaching stage (8; 18), wherein said first and second bleaching stages both comprise ozone bleaching.
2. Method according claim 1 , wherein the pulp is provided to the first bleaching stage (4; 14) at a consistency of at least 30%, preferably within a range from 35-42%.
3. Method according to claim 1 , wherein the pulp is provided to the first bleaching stage (4; 14) at a consistency of 8-16%, preferably 10-12%.
4. Method according to any of the preceding claims, wherein the pulp is provided to the second bleaching stage (8; 18) at a consistency of at least 30%, preferably within a range from 35-42%.
5. Method according to any claims 1-3, wherein the pulp is provided to the second bleaching stage (8; 18) at a consistency of 8-16%, preferably 10-12%.
6. Method according to claim 4 as dependent on claim 2, or according to claim 5 as dependent on claim 3, wherein the ozone bleaching in the first bleaching stage (4; 14) has a shorter retention time than the ozone bleaching in the second bleaching stage (8; 18).
7. Method according to claim 2 or any of claims 4-6 as dependent on claim 2, wherein fresh ozone gas is supplied to, and counter currently charged in, the ozone bleaching of the first bleaching stage (4; 14).
8. Method according to claim 4 or claim 6 as dependent on claim 4, wherein fresh ozone gas is supplied to, and counter currently charged in, the ozone bleaching of the second bleaching stage (8; 18).
9. Method according to any of the preceding claims, wherein the total ozone charge of the ozone bleaching of the first and second bleaching stages (4, 8; 14, 18) is less than 12 kg/odt, preferably less than 10 kg/odt, or less than 8 kg/odt.
10. Method according to any of the preceding claims, wherein at least one of the first and second bleaching stages (4, 8; 14) comprises adding at least one chelating agent and/or at least one radical scavenger.
11. Method according to claim 10, wherein the at least one chelating agent and/or at least one radical scavenger is added after the ozone bleaching in the at least one of the first and second bleaching stages (4, 8; 14).
12. Method according to any of claims 10-11 , wherein said at least one chelating agent and/or at least one radical scavenger is chosen from a group comprising oxalic acid,
acetic acid, ethylenediaminetetraacetic acid, EDTA, diethylenetriaminepentaacetic acid, DTPA, magnesium sulfate or calcium chloride.
13. Method according to any of the preceding claims, wherein at least one of the first and second bleaching stages comprises alkaline extraction after the ozone bleaching.
14. Method according to any of the preceding claims, wherein the first bleaching stage comprises ozone bleaching followed by chlorine dioxide bleaching.
15. Method according to any of the preceding claims, wherein the second bleaching stage comprises ozone bleaching followed by chlorine dioxide bleaching.
16. Method according to claim 14 or 15, wherein the chlorine dioxide bleaching follows directly after the ozone bleaching.
17. Method according to any of the preceding claims, wherein the first bleaching stage comprises ozone bleaching followed by hydrogen peroxide bleaching.
18. Method according to any of the preceding claims, wherein the second bleaching stage (18) comprises ozone bleaching followed by hydrogen peroxide bleaching.
19. Method according to claim 17 or 18, wherein the hydrogen peroxide bleaching follows directly after the ozone bleaching.
20. Method according to claim any of the preceding claims, further comprising pretreating (2, 6; 12, 16) the pulp prior to said first bleaching stage (4; 14) and/or between the washing (5; 15) and the second bleaching stage (8; 18), wherein said pretreating comprises adding at least one acid to reduce the pH of the pulp and/or adding one or more additives, said one or more additives comprising at least one chelating agent and/or at least one radical scavenger.
21. A method for producing bleached cellulose pulp from recycled textile material comprising cellulose, said method comprising: pulping (1 ; 11) the recycled textile material to form cellulose pulp, and bleaching the cellulose pulp using the method according to any of the preceding claims.
22. A system for producing bleached cellulose pulp from recycled textile material comprising cellulose, said system comprising: a pulping arrangement arranged to receive the recycled textile material to produce pulp therefrom; a first bleaching arrangement arranged to bleach pulp obtained from the pulping arrangement; a washing arrangement arranged to wash bleached pulp from the first bleaching arrangement; a second bleaching arrangement arranged to bleach washed pulp from the washing arrangement,
wherein said first and second bleaching arrangement each comprises an ozone bleaching apparatus.
23. System according to claim 22, wherein the ozone bleaching apparatus of at least one of the first and second bleaching arrangements comprises means for supplying fresh ozone gas and counter currently charging the ozone gas in said ozone bleaching apparatus.
24. System according to any claims 22-23, wherein at least one of the first and second bleaching arrangements comprises means for adding one or more additives comprising at least one chelating agent and/or at least one radical scavenger.
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SE2250745-3 | 2022-06-20 | ||
SE2250745A SE2250745A1 (en) | 2022-06-20 | 2022-06-20 | Method for bleaching pulp from recycled textile material |
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WO2016080895A1 (en) * | 2014-11-21 | 2016-05-26 | Innventia Ab | Process for the production of a treated pulp, treated pulp, and textile fibres produced from the treated pulp |
WO2018073177A1 (en) | 2016-10-19 | 2018-04-26 | Re:Newcell Ab | Recycling of cellulosic textiles |
WO2018104330A1 (en) * | 2016-12-06 | 2018-06-14 | Re:Newcell Ab | Cellulose fibers |
SE544236C2 (en) | 2020-12-21 | 2022-03-08 | Valmet Oy | Method for bleaching pulp from recycled textile material |
SE2051513A1 (en) * | 2020-12-21 | 2022-03-08 | Valmet Oy | Method for bleaching pulp from recycled textile material |
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SE2250745A1 (en) | 2023-11-28 |
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