WO2023234509A1

WO2023234509A1 - Hot stamping part and manufacturing method therefor

Info

Publication number: WO2023234509A1
Application number: PCT/KR2022/020565
Authority: WO
Inventors: 장민호; 강석현; 박민서; 한성경
Original assignee: 현대제철 주식회사
Priority date: 2022-05-31
Filing date: 2022-12-16
Publication date: 2023-12-07
Also published as: KR20230166779A

Abstract

The present invention provides a hot stamping part, which comprises: a base material; a decarburized layer disposed on the surface of the base material; and an inner oxide layer disposed on the surface of the decarburized layer, wherein the hot stamping part has a tensile strength (TS) of 1680-2000 MPa, and the hardness of the hot stamping part within a depth of 50㎛ from the surface in the plate thickness direction of the hot stamping part and the average hardness of the hot stamping part satisfy relational expression 1. <Relational expression 1> (A / B) ≤ 0.7 (In relational expression 1, A is the hardness (Hv (≤50㎛)) within a depth of 50㎛ in the plate thickness direction of the hot stamping part, and B is the average hardness (Hv (avg.)) of the hot stamping part.)

Description

Hot stamping parts and their manufacturing methods

The present invention relates to hot stamping parts and methods for manufacturing the same.

As environmental and fuel efficiency regulations are strengthened worldwide, the need for lighter vehicle materials is increasing. Accordingly, research and development on ultra-high strength steel and hot stamping steel is being actively conducted.

The hot stamping process generally consists of heating/forming/cooling/trimming, and can take advantage of the phase transformation and microstructure of the material during the process. In order to improve the toughness of hot stamping steel, research is being actively conducted on methods of improving the toughness of the base material, generally using alloy components.

However, if the alloy composition is changed or increased, there is a problem that the cost increases and the economic feasibility decreases.

As a technology related to this, there is Republic of Korea Patent Publication No. 10-2021-0129902 (title of the invention: hot stamping parts and manufacturing method thereof).

Embodiments of the present invention can improve the toughness of manufactured hot stamping parts by appropriately forming a decarburization layer and an internal oxide layer on the surface of the base material, and at the same time, cracks can be prevented from occurring during hot stamping molding.

One embodiment of the present invention is a hot stamping part, comprising: a base material; A decarburization layer disposed on the surface of the base material; and an internal oxide layer disposed on the surface of the decarburization layer, wherein the hot stamping part has a tensile strength (TS) of 1680 MPa to 2000 MPa, and a plate of the hot stamping part is formed on the surface of the hot stamping part. A hot stamping part is provided in which the hardness within a depth of 50 μm in the thickness direction and the average hardness of the hot stamping part satisfy the following relational equation 1.

(A/B) ≤ 0.7

(In the above relational equation 1, A is the hardness (Hv(≤50㎛)) within a depth of 50㎛ in the plate thickness direction of the hot stamping part, and B is the average hardness (Hv(avg.)) of the hot stamping part.)

In this embodiment, the depth of the internal oxide layer may satisfy the following relational equation 2.

C ≤ 5㎛

(In Equation 2 above, C is the depth of the internal oxide layer in the direction of the plate thickness of the hot stamping part.)

In this embodiment, the hot stamping part may have a VDA bending angle of 60° or more.

In this embodiment, the hot stamping part may have a yield stress (YP) of 1150 MPa to 1500 MPa and an elongation (EL) of 4% to 10%.

In this embodiment, the hot stamping part may have a microstructure containing a martensite fraction of 90% or more.

In this embodiment, a plating layer disposed on the surface of the internal oxide layer may be further included.

In this embodiment, the thickness of the plating layer may be 10㎛ to 30㎛.

Another embodiment of the present invention is a method of manufacturing hot stamping parts, comprising the steps of cutting a plated steel sheet with a plating layer formed on at least one surface of a base material to form a blank; and heating the blank in a heating furnace having a plurality of sections having different temperature ranges, wherein the heating of the blank includes a multi-stage heating step of heating the blank in stages; and a crack heating step of heating the multi-stage heated blank to a temperature of Ac3 to 910° C., wherein the hardness within 50 μm depth in the direction of the plate thickness of the hot stamping part from the surface of the hot stamping part and the hot stamping part A method for manufacturing hot stamping parts is provided, wherein the average hardness satisfies the following relational expression 3.

(A/B) ≤ 0.7

(In the above relational equation 3, A is the hardness (Hv (≤50 μm)) within a depth of 50 μm in the plate thickness direction of the hot stamping part, and B is the average hardness (Hv (avg.)) of the hot stamping part.)

In this embodiment, the dew point temperature of the annealing furnace of the base material may be -15°C to +15°C.

In this embodiment, the annealing temperature of the base material may be 750°C to 900°C.

In this embodiment, after heating the blank, transferring the heated blank; Forming a molded body by pressing the transferred blank into a mold; and cooling the molded body.

In this embodiment, a decarburization layer formed on the surface of the base material; And it may further include an internal oxide layer formed on the surface of the decarburization layer.

In this embodiment, the depth of the internal oxide layer may satisfy the following relational equation 4.

C ≤ 5㎛

(In Equation 4 above, C is the depth of the internal oxide layer in the direction of the plate thickness of the hot stamping part.)

Other aspects, features and advantages other than those described above will become apparent from the detailed description, claims and drawings for carrying out the invention below.

According to one embodiment of the present invention as described above, the toughness of the manufactured hot stamping part can be improved by forming a decarburization layer on the surface of the base material.

Additionally, according to one embodiment of the present invention, the internal oxide layer formed on the surface of the decarburization layer is provided below a preset depth, thereby preventing cracks from occurring during the hot stamping process.

1 is a cross-sectional view schematically showing a hot stamping part according to an embodiment of the present invention.

Figure 2 is a flow chart schematically showing a method of manufacturing a hot stamping part according to an embodiment of the present invention.

3 to 5 are cross-sectional views schematically showing a method of manufacturing hot stamping parts according to an embodiment of the present invention.

Figure 6 is a flowchart schematically showing hot stamping steps according to an embodiment of the present invention.

Figure 7 is a flowchart schematically showing a heating step according to an embodiment of the present invention.

Figure 8 is a diagram illustrating a heating furnace having a plurality of sections in the heating step of the method for manufacturing hot stamping parts according to an embodiment of the present invention.

Since the present invention can be modified in various ways and can have various embodiments, specific embodiments will be illustrated in the drawings and described in detail in the detailed description. The effects and features of the present invention and methods for achieving them will become clear by referring to the embodiments described in detail below along with the drawings. However, the present invention is not limited to the embodiments disclosed below and may be implemented in various forms.

In the following embodiments, terms such as first and second are used not in a limiting sense but for the purpose of distinguishing one component from another component.

In the following examples, singular terms include plural terms unless the context clearly dictates otherwise.

In the following embodiments, terms such as include or have mean the presence of features or components described in the specification, and do not exclude in advance the possibility of adding one or more other features or components.

In the following embodiments, when a part of a film, region, component, etc. is said to be on or on another part, it is not only the case where it is directly on top of the other part, but also when another film, region, component, etc. is interposed between them. Also includes cases where there are.

In the drawings, the sizes of components may be exaggerated or reduced for convenience of explanation. For example, the size and thickness of each component shown in the drawings are arbitrarily shown for convenience of explanation, so the present invention is not necessarily limited to what is shown.

In this specification, “A and/or B” refers to A, B, or A and B. Additionally, in this specification, “at least one of A and B” refers to the case of A, B, or A and B.

In the following embodiments, “on a plane” means when the target part is viewed from above, and “on a cross-section” means when a cross section of the target part is cut vertically and viewed from the side. In the following embodiments, when referring to “overlapping”, this includes “in-plane” and “in-cross-section” overlapping.

Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings, and when described with reference to the drawings, identical or corresponding components will be assigned the same reference numerals.

Referring to FIG. 1, a hot stamping part 1 according to an embodiment may include a base material 100, a decarburization layer 200, an internal oxide layer 300, and a plating layer 400. The base material 100, the decarburization layer 200, the internal oxide layer 300, and the plating layer 400 may be sequentially stacked in the thickness direction of the hot stamping part 1.

In one embodiment, the base material 100 is carbon (C), silicon (Si), manganese (Mn), phosphorus (P), sulfur (S), boron (B), the balance of iron (Fe) and other unavoidable impurities. may include. For example, the base material 100 is, in weight%, about 0.25% by weight or more and about 0.5% by weight or less of carbon (C), about 0.1% by weight or more and about 0.8% by weight or less of silicon (Si), and about 0.3% by weight or more of manganese (Mn). Approximately 3.0% by weight or less, phosphorus (P) exceeding 0 to approximately 0.05% by weight or less, sulfur (S) exceeding 0 to approximately 0.01% by weight or less, boron (B) exceeding approximately 0.0005% by weight to approximately 0.005% by weight or less, the balance of iron (Fe) ) and other unavoidable impurities.

Additionally, the base material 100 may further include one or more of titanium (Ti), niobium (Nb), and vanadium (V). Additionally, the base material 100 may further include chromium (Cr), molybdenum (Mo), and nickel (Ni).

The base material 100 may further include one or more of titanium (Ti), niobium (Nb), and vanadium (V). Titanium (Ti), niobium (Nb), and vanadium included in the base material 100 The sum of one or more components of (V) may be about 0.01% by weight or more and about 0.1% by weight or less. For example, the base material 100 may include titanium (Ti) and niobium (Nb), and the sum of the weight percent of titanium (Ti) and niobium (Nb) contained in the base material 100 is about 0.01 wt% or more. It may be about 0.1% by weight or less.

In addition, the base material 100 contains about 0.01 wt% to about 1.0 wt% of chromium (Cr), about 0.01 wt% to about 1.0 wt% of molybdenum (Mo), and about 0.001 wt% to about 1.0 wt of nickel (Ni). It may further include % or less.

Carbon (C) is a major element that determines the strength and hardness of steel, and can be added for the purpose of securing the tensile strength of steel after the hot stamping (or hot pressing) process. Additionally, carbon (C) may be added for the purpose of securing the hardenability properties of steel. In one embodiment, carbon (C) may be included in an amount of about 0.25% by weight or more and about 0.5% by weight or less based on the total weight of the base material 100. If carbon (C) is included in less than about 0.25% by weight based on the total weight of the base material 100, it may be difficult to achieve the desired mechanical strength. On the other hand, if carbon (C) is included in an amount exceeding about 0.5% by weight based on the total weight of the base material 100, a problem of lowering the toughness of the steel material or a problem of controlling the brittleness of the steel may occur.

Silicon (Si) may act as a ferrite stabilizing element in the base material 100. Silicon (Si) improves ductility by purifying ferrite and can improve carbon concentration in austenite by suppressing the formation of low-temperature carbides. Furthermore, silicon (Si) may be a key element in hot rolling, cold rolling, hot stamping tissue homogenization (perlite, manganese segregation zone control), and ferrite fine dispersion. In one embodiment, silicon (Si) may be included in an amount of about 0.1% by weight or more and about 0.8% by weight or less based on the total weight of the base material 100. If silicon (Si) is included in less than about 0.1% by weight based on the total weight of the base material 100, the above-described function may not be sufficiently performed. On the other hand, when silicon (Si) is included in an amount of more than about 0.8% by weight based on the total weight of the base material 100, hot rolling and cold rolling loads increase, hot rolling red scale may become excessive, and bonding properties may deteriorate.

Manganese (Mn) may be added to increase hardenability and strength during heat treatment. In one embodiment, manganese (Mn) may be included in an amount of about 0.3% by weight or more and about 3.0% by weight or less based on the total weight of the base material 100. If manganese (Mn) is included in an amount of less than about 0.3% by weight based on the total weight of the base material 100, there may be a high possibility that the material will be insufficient (for example, the hard phase fraction will be insufficient) after hot stamping due to insufficient hardenability. On the other hand, if manganese (Mn) is contained in an amount exceeding about 3.0% by weight based on the total weight of the base material 100, ductility and toughness may be reduced due to manganese segregation or pearlite bands, and it may cause a decrease in bending performance. Heterogeneous microstructure may occur.

Phosphorus (P) is an element that is prone to segregation and may be an element that inhibits the toughness of steel. In one embodiment, phosphorus (P) may be included in an amount greater than 0 and less than or equal to about 0.05% by weight based on the total weight of the base material 100. When phosphorus (P) is included in the above-mentioned range with respect to the total weight of the base material 100, deterioration of the toughness of the steel can be prevented. On the other hand, if phosphorus (P) is contained in an amount exceeding about 0.05% by weight based on the total weight of the base material 100, cracks may occur during the process, and iron phosphide compounds may be formed, thereby reducing the toughness of the steel.

Sulfur (S) may be an element that inhibits processability and physical properties. In one embodiment, sulfur (S) may be included in an amount greater than 0 and less than or equal to about 0.01% by weight based on the total weight of the base material 100. If sulfur (S) is contained in an amount exceeding about 0.01% by weight based on the total weight of the base material 100, hot workability may be reduced and surface defects such as cracks may occur due to the creation of large inclusions.

Boron (B) is added for the purpose of securing the hardenability and strength of steel by securing the martensite structure, and can have a grain refining effect by increasing the austenite grain growth temperature. In one embodiment, boron (B) may be included in an amount of about 0.0005% by weight or more and about 0.005% by weight or less based on the total weight of the base material 100. When boron (B) is included in the above-mentioned range with respect to the total weight of the base material 100, hard phase grain boundary embrittlement can be prevented and high toughness and bendability can be secured.

Titanium (Ti) may be added to strengthen hardenability and improve material quality by forming precipitates after hot stamping heat treatment. In addition, titanium (Ti) forms precipitated phases such as Ti(C,N) at high temperatures, which can effectively contribute to austenite grain refinement.

Niobium (Nb) can be added to increase strength and toughness as the martensite packet size decreases.

Vanadium (V) may be added for the purpose of increasing the strength of steel through the precipitation strengthening effect by forming precipitates.

In one embodiment, titanium (Ti), niobium (Nb), and vanadium (V) may be selectively included in the base material 100. At this time, when one or more of titanium (Ti), niobium (Nb), and vanadium (V) is included in the base material 100, one or more of titanium (Ti), niobium (Nb), and vanadium (V) The sum may be about 0.01% by weight or more and about 0.1% by weight or less.

Chromium (Cr) can be added to improve the hardenability and strength of steel. In one embodiment, chromium (Cr) may be included in an amount of about 0.01% by weight or more and about 1.0% by weight or less based on the total weight of the base material 100. When chromium (Cr) is included in the above-mentioned range with respect to the total weight of the base material 100, the hardenability and strength of the steel can be improved, an increase in production costs can be prevented, and the toughness of the steel material can be prevented from decreasing. It can be prevented.

Molybdenum (Mo) can contribute to improving strength by suppressing coarsening of precipitates and increasing hardenability during hot rolling and hot stamping. Molybdenum (Mo) may be included in an amount of about 0.01% by weight or more and about 1.0% by weight or less based on the total weight of the base material 100. When molybdenum (Mo) is included in the above-mentioned range with respect to the total weight of the base material 100, the effect of suppressing coarsening of precipitates and increasing hardenability during hot rolling and hot stamping can be excellent.

Nickel (Ni) may be added to ensure hardenability and strength. Additionally, nickel (Ni) is an austenite stabilizing element and can contribute to improving elongation by controlling austenite transformation. In one embodiment, nickel (Ni) may be included in an amount of about 0.001% by weight or more and about 1.0% by weight or less based on the total weight of the base material 100. If nickel (Ni) is included in less than about 0.001% by weight based on the total weight of the base material 100, it may be difficult to properly implement the above-described effect. If nickel (Ni) is included in an amount exceeding about 1.0% by weight based on the total weight of the base material 100, toughness may be reduced, cold workability may be reduced, and the manufacturing cost of the product may increase.

In one embodiment, the base material 100 may have a microstructure containing a martensite fraction of about 90% or more. Specifically, the base material 100 may have a microstructure containing about 90% or more of marstensite and less than about 10% of remaining unavoidable structures and other precipitates.

In one embodiment, a decarburization layer 200 may be disposed on the base material 100. Specifically, the decarburization layer 200 may be disposed on the surface of the base material 100. When the decarburization layer 200 is disposed on the base material 100, the decarburization layer 200 is a softer layer than the base material 100, so the toughness of the hot stamping part 1 can be improved.

A layer having a hardness of about 70% or less compared to the average hardness at about 1/4 point from the surface of the base material 100 in the thickness direction of the hot stamping part 1 may be defined as the decarburization layer 200. Alternatively, a layer having a hardness of about 70% or less compared to the average hardness at about 1/4 point from the surface of the hot stamping part 1 in the thickness direction of the hot stamping part 1 may be defined as the decarburization layer 200. That is, the average hardness of the decarburization layer 200 is about 70 compared to the average hardness at about 1/4 of the point from the surface of the base material 100 or from the surface of the hot stamping part 1 in the direction of the plate thickness of the hot stamping part 1. It may be less than %. In other words, the average hardness of the decarburization layer 200 is the average hardness of about 1/4 of the point from the surface of the base material 100 or from the surface of the hot stamping part 1 in the direction of the plate thickness of the hot stamping part 1. It may be about 70% or less.

In one embodiment, the internal oxide layer 300 may be disposed on the decarburization layer 200. Specifically, an internal oxide layer 300 may be disposed on the surface of the decarburization layer 200. The internal oxide layer 300 may include silicon (Si), manganese (Mn), chromium (Cr), etc.

In one embodiment, the depth (or thickness t1) of the internal oxide layer 300 may be about 5 μm or less in the thickness direction of the hot stamping part 1. This will be explained in more detail below.

In one embodiment, a plating layer 400 may be disposed on the internal oxide layer 300. Specifically, a plating layer 400 may be disposed on the surface of the internal oxide layer 300. The plating layer 400 may be a zinc (Zn)-based plating layer or an aluminum (Al)-based plating layer. For example, the plating layer 400 may include zinc (Zn) and/or aluminum (Al).

In one embodiment, when the plating layer 400 is provided as a zinc (Zn)-based plating layer, the plating layer 400 includes iron (Fe), aluminum (Al), manganese (Mn), silicon (Si), and the remainder of zinc ( Zn), and other unavoidable impurities. For example, the plating layer 400 contains more than about 10% by weight and less than about 70% by weight of iron (Fe), more than 0% by weight and less than about 5% by weight of aluminum (Al), more than 0% by weight of manganese (Mn) and less than about 1% by weight of silicon (Si). It may contain more than 0% by weight and less than about 1% by weight, with the balance being zinc (Zn) and other unavoidable impurities.

The plating layer 400 may be provided to a depth (or thickness t2) of about 10 μm to about 30 μm in the thickness direction of the hot stamping part 1. If the thickness (t2) of the plating layer 400 is less than about 10 ㎛, the sacrificial anti-corrosion effect unique to zinc may be reduced, and if the thickness (t2) of the plating layer 400 is more than about 30 ㎛, the plating layer 400 If the thickness t2 is too thick, the toughness of the hot stamping part 1 including the plating layer 400 may be reduced. Therefore, when the plating layer 400 is provided with a thickness t2 of about 10 μm to about 30 μm, the surface of the base material (or steel) can be protected, and at the same time, the toughness of the hot stamping part 1 is reduced. can be prevented or minimized.

The decarburization layer 200 is a softer layer than the base material 100, and when the hot stamping part 1 includes the decarburization layer 200, the toughness of the hot stamping part 1 including it can be improved.

However, as described above, when the depth (or thickness (t1)) of the internal oxide layer 300 is too large, the liquid zinc more easily penetrates into the base material 100 due to the internal oxide layer 300, resulting in hot stamping. The possibility of cracks occurring during molding may increase, which may reduce the bendability of the manufactured hot stamping part 1. Specifically, when the depth (or thickness (t1)) of the internal oxide layer 300 is greater than about 5㎛, liquid zinc more easily penetrates into the base material 100 due to the internal oxide layer 300, thereby performing hot stamping forming. The possibility of major cracks occurring may increase, which may lower the bendability of the manufactured hot stamping part 1.

As will be described later in the method of manufacturing hot stamping parts, a decarburization layer 200 may be formed on the base material 100 in the annealing step. At this time, the internal oxide layer 300 may be formed simultaneously on the decarburization layer 200. Specifically, in the annealing step, a decarburization layer 200 may be formed on the surface of the base material 100, and at the same time, an internal oxide layer 300 may be formed on the surface of the decarburization layer 200.

By increasing the dew point temperature of the annealing furnace in which the annealing step is performed, the depth (or thickness) of the decarburization layer 200 may be increased. However, when the depth (or thickness) of the decarburization layer 200 increases, the depth (or thickness) of the internal oxide layer 300 may also increase. That is, in order to increase the toughness of the hot stamping part 1, the depth (or thickness) of the decarburization layer 200 must be increased, but when the depth (or thickness) of the decarburization layer 200 is increased, the internal oxide layer The depth (or thickness) of 300 may also increase, which may increase the possibility of cracks occurring during hot stamping molding, which may lower the bendability of the manufactured hot stamping part 1. Therefore, it is necessary to appropriately adjust the depth (or thickness) of the decarburization layer 200 and the depth (or thickness) of the internal oxide layer 300.

Accordingly, through excessively repeated experiments, the present inventor derived equations 1 and 2 that allow the hot stamping part 1 to have a VDA bending angle of about 60° or more. In one embodiment, hot stamping part 1 may satisfy relation 1 and relation 2. Specifically, the hardness within a depth of about 50㎛ from the surface of the hot stamping part 1 in the direction of the plate thickness of the hot stamping part 1 and the average hardness of the hot stamping part 1 may satisfy relational equation 1, and the internal oxide layer The depth (or thickness) of (300) may satisfy relational equation 2. For example, the hot stamping part 1 may satisfy both Equation 1 and Equation 2.

(A/B) ≤ 0.7

In equation 1, A is the hardness (Hv (≤50㎛)) within about 50㎛ depth (or thickness) in the direction of the plate thickness of the hot stamping part (1), and B is the average hardness (Hv) of the hot stamping part (1) (avg.)).

At this time, the hardness within a depth of approximately 50㎛ from the surface of the hot stamping part (1) in the direction of the sheet thickness of the hot stamping part (1) is approximately from the surface of the hot stamping part (1) to the thickness direction of the hot stamping part (1). It may be a hardness value measured with a Vickers hardness meter at a point below 50㎛ depth, and the average hardness (Hv (avg.)) of the hot stamping part (1) is about 1/4 point in the direction of the plate thickness of the hot stamping part (1). It may be a hardness value measured with a Vickers hardness tester.

C ≤ 5㎛

In Equation 2, C is the depth (or thickness) of the internal oxide layer 300 in the plate thickness direction of the hot stamping part 1.

Since the decarburization layer 200 is disposed on the surface of the base material 100, the decarburization layer 200 may be disposed in a portion adjacent to the surface of the hot stamping part 1. Since the decarburization layer 200 corresponds to a softer layer compared to the base material 100, the hardness of the portion adjacent to the surface of the hot stamping part 1 among the hot stamping parts 1 is greater than the average hardness of the hot stamping part 1. It can be low. At this time, when the depth (or thickness) of the decarburization layer 200 increases, the hardness of the portion adjacent to the surface of the hot stamping part 1 among the hot stamping parts 1 and the average hardness of the hot stamping part 1 Differences may increase. On the other hand, when the depth (or thickness) of the decarburization layer 200 is reduced, the hardness of the portion adjacent to the surface of the hot stamping part 1 and the average hardness of the hot stamping part 1 The difference can be reduced.

The ratio of the hardness (Hv (≤50㎛)) within about 50㎛ depth (or thickness) in the direction of the plate thickness of the hot stamping part (1) and the average hardness (Hv (avg.)) of the hot stamping part (1) is 0.7. If it is excessive, the decarburization layer 200 may not be formed (or provided) at a sufficient depth (or thickness), and thus the toughness of the hot stamping part 1 including it may be low. In particular, the VDA bending angle of the hot stamping part 1 may be less than about 60°.

The ratio of the hardness (Hv (≤50㎛)) within about 50㎛ depth (or thickness) in the direction of the plate thickness of the hot stamping part (1) and the average hardness (Hv (avg.)) of the hot stamping part (1) is 0.7. In the following case, it may mean that the decarburization layer 200 is formed (or provided) to a sufficient depth (or thickness). Therefore, the hardness (Hv (≤50㎛)) within about 50㎛ depth (or thickness) in the thickness direction of the hot stamping part (1) and the average hardness (Hv (avg.)) of the hot stamping part (1) When the ratio satisfies 0.7 or less, the decarburization layer 200 is formed (or provided) at a sufficient depth (or thickness), so that the toughness of the hot stamping part 1 including it can be improved. In particular, the hot stamping part 1 may have a VDA bending angle of about 60° or more.

Additionally, as described above, the depth (or thickness) of the internal oxide layer 300 included in the hot stamping part 1 may be about 5 μm or less.

If the plating layer 400 is provided with a zinc (Zn)-based plating layer, liquid metal embrittlement (LME) phenomenon may occur due to the low melting point of zinc, which may cause internal cracks to form in the hot stamping part. The bendability of (1) may decrease. At this time, when the depth (or thickness) of the internal oxide layer 300 is large, the liquid zinc can more easily penetrate into the internal oxide layer 300, increasing the probability of cracks occurring during hot stamping forming. This may result in a decrease in the bendability of the manufactured hot stamping part 1.

If the depth (or thickness) of the internal oxide layer 300 is greater than about 5㎛, liquid zinc can more easily penetrate into the internal oxide layer 300, increasing the probability of cracks occurring during hot stamping forming. There is, and as a result, the bendability of the manufactured hot stamping part 1 may be reduced.

Therefore, when the depth (or thickness) of the internal oxide layer 300 is provided to be about 5 μm or less in the thickness direction of the hot stamping part 1, cracks can be prevented from occurring during hot stamping, Through this, the high-temperature formability of hot stamping parts (or blanks) can be improved.

In one embodiment, the hot stamping part 1 may simultaneously satisfy the above-described equations 1 and 2. When the hot stamping part 1 simultaneously satisfies the above-described equations 1 and 2, the hot stamping part 1 may have high toughness and may have excellent high-temperature formability. Specifically, the hardness within about 50㎛ depth (or thickness) from the surface of the hot stamping part 1 in the direction of the plate thickness of the hot stamping part 1 and the average hardness of the hot stamping part 1 are expressed by the above-mentioned relational equation 1. When the depth (or thickness) of the internal oxide layer 300 satisfies the above-mentioned relational expression 2, the hot stamping part 1 can have high toughness and at the same time, the hot stamping part can have excellent high-temperature formability. there is.

In one embodiment, when the hot stamping part 1 satisfies both Equation 1 and Equation 2 described above, the hot stamping part 1 has a tensile strength (TS) of about 1680 MPa to about 2000 MPa, and about 1150 MPa to about 2000 MPa. It may have a yield stress (YP) of about 1500 MPa, and an elongation (EL) of about 4% to about 10%. Additionally, the hot stamping part 1 may have a VDA bending angle of about 60° or more. At this time, the VDA bending angle can be measured based on the VDA standard (VDA238-100).

Figure 2 is a flow chart schematically showing a method of manufacturing a hot stamping part according to an embodiment of the present invention, and Figures 3 to 5 are schematically showing a method of manufacturing a hot stamping part according to an embodiment of the present invention. These are cross-sectional views.

2 to 5, the manufacturing method of a hot stamping part (1, see FIG. 1) according to an embodiment includes a hot rolling step (S100), a cooling/winding step (S200), a cold rolling step (S300), It may include an annealing step (S400), a plating step (S500), and a hot stamping step (S600).

First, a reheating step of the base material 100 (eg, steel slab) provided with the composition described above in FIG. 1 may be performed. In the steel slab reheating step, the steel slab obtained through a continuous casting process is reheated to a predetermined temperature, so that components segregated during casting can be re-employed. In one embodiment, the slab reheating temperature (SRT) may be about 1,200°C to about 1,400°C. If the slab reheating temperature (SRT) is lower than about 1,200°C, the components segregated during casting are not sufficiently re-dissolved, making it difficult to significantly homogenize the alloy elements and the solid solution effect of titanium (Ti). The higher the slab reheating temperature (SRT), the more advantageous it is for homogenization. However, if the slab reheating temperature (SRT) exceeds about 1,400°C, the austenite crystal grain size increases, making it difficult to secure strength, and the excessive heating process makes it difficult to manufacture steel sheets. Costs may rise.

In the hot rolling step (S100), the reheated base material 100 may be hot rolled at a predetermined finish rolling temperature. A hot rolled steel sheet can be manufactured through the hot rolling step (S100). In one embodiment, the finishing delivery temperature (FDT) may be about 880°C to about 950°C. At this time, if the finish rolling temperature (FDT) is lower than about 880°C, it is difficult to secure the workability of the steel sheet due to the occurrence of a mixed structure due to abnormal region rolling, and there is a problem of deterioration of workability due to microstructure unevenness and rapid phase change. This may cause problems with sheetability during hot rolling. If the finish rolling temperature (FDT) exceeds about 950°C, austenite grains may coarsen and TiC precipitates may coarsen, thereby deteriorating the performance of hot stamping parts.

In the cooling/winding step (S200), the hot-rolled base material 100 can be cooled to a predetermined coiling temperature (Coiling Temperature, CT) and then wound. In one embodiment, the coiling temperature of the cooling/winding step (S300) may be about 550°C to about 800°C. The coiling temperature affects the redistribution of carbon (C). If the coiling temperature is less than about 550°C, the low-temperature phase fraction increases due to supercooling, which may increase the strength, and there is a risk that the rolling load during cold rolling may intensify. Ductility may deteriorate rapidly. Conversely, if the coiling temperature exceeds about 800°C, deterioration of formability and strength may occur due to abnormal or excessive crystal grain growth.

In the cold rolling step (S300), the wound base material 100 may be uncoiled, pickled, and then cold rolled. At this time, pickling may be performed for the purpose of removing scale from the wound steel sheet (or base material), that is, the hot rolled coil manufactured through the above hot rolling process. A cold rolled steel sheet can be manufactured through the cold rolling step (S300).

In the annealing step (S400), the cold rolled base material 100 may be annealed at a temperature of about 700° C. or higher. For example, the annealing step (S400) may include heating the cold rolled base material 100 and cooling the heated base material 100 at a predetermined cooling rate.

In one embodiment, the base material may be annealed in the annealing step (S400). The annealing step (S400) may be performed in an annealing furnace.

Annealing of the base material 100 may be performed in a gas atmosphere consisting of about 0.5 volume% to about 25 volume% of hydrogen and the balance nitrogen. At this time, water may be sprayed into the annealing furnace along with hydrogen gas and nitrogen gas. If water is sprayed into the annealing furnace, the dew point temperature of the annealing furnace may increase. Therefore, the dew point temperature of the annealing furnace can be adjusted by controlling the amount of water sprayed into the annealing furnace.

In one embodiment, when the dew point temperature of the annealing furnace increases, a decarburization layer 200 may be formed on the base material 100. For example, carbon may be lost from the surface of the base material 100 to form the decarburization layer 200. Additionally, the internal oxide layer 300 may be formed simultaneously on the decarburization layer 200. That is, the decarburization layer 200 may be formed on the surface of the base material 100, and the internal oxide layer 300 may be formed on the surface of the decarburization layer 200. At this time, the decarburization layer 200 and the internal oxide layer 300 may be a layer in which a portion of the base material 100 is changed.

At this time, a layer whose hardness is about 80% or less compared to the average hardness at about 1/4 of the surface of the base material 100 may be defined as the decarburization layer 200. That is, the average hardness of the decarburization layer 200 may be about 80% or less of the average hardness of about 1/4 of the point from the surface of the base material 100.

In one embodiment, the dew point temperature of the annealing furnace in which annealing of the base material 100 is performed may be about -15°C to about +15°C. For the purpose of improving the toughness of the manufactured hot stamping part 1, a decarburization layer 200 is formed on the base material 100. The depth of the decarburization layer 200 formed when the dew point temperature of the annealing furnace is about -15°C or lower. If the (or thickness) is too thin, the effect of improving the toughness of the manufactured hot stamping part may be minimal. On the other hand, when the dew point temperature of the annealing furnace is about +15°C or higher, the depth (or thickness (t3)) of the internal oxide layer 300 formed is too large, which may cause LME cracks and cause operation damage due to equipment oxidation. Sexuality may be reduced. For example, in order to increase the dew point temperature of the annealing furnace, a large amount of water must be supplied to the annealing furnace. If a large amount of water is supplied to the annealing furnace, the equipment of the annealing furnace may be oxidized, and it takes a lot of time to clean it. operation efficiency may be reduced. In addition, when the dew point temperature of the annealing furnace is high, the depth (or thickness (t3)) of the decarburization layer 200 and the internal oxide layer 300 formed may increase, and the internal oxide layer 300 may increase during high temperature molding. Cracks may occur internally. Therefore, when the dew point temperature of the annealing furnace in which the annealing of the base material 100 is performed satisfies about -15°C to about +15°C, the toughness of the manufactured hot stamping part 1 is improved and the efficiency of the manufacturing process is improved. You can do it.

In one embodiment, the line speed of the annealing furnace in which the base material 100 is annealed may be about 30 meters per minute (mpm) to about 200 mpm. If the line speed of the annealing furnace is 30 mpm or less, the moving speed of the base material 100 is too slow, and productivity may decrease sharply, and if the line speed of the annealing furnace is 200 mpm or more, the residence time in the annealing furnace is too short, resulting in the decarburization layer 200. The depth (or thickness) may be reduced, and as a result, the effect of improving the toughness of the manufactured hot stamping part may be minimal. Therefore, when the line speed of the annealing furnace in which the base material 100 is annealed satisfies about 30 mpm to about 200 mpm, the productivity of hot stamping parts can be improved, and at the same time, the toughness of the manufactured hot stamping parts can be improved. You can do it.

In one embodiment, the annealing temperature of the base material 100 may be about 750°C to about 900°C. If the annealing temperature of the base material 100 is less than about 750°C, the desired structure cannot be obtained and recrystallization may not be sufficiently completed. On the other hand, when the annealing temperature of the base material 100 exceeds about 900° C., the annealing temperature may be too high and the efficiency of the manufacturing process may be reduced. Therefore, when the annealing temperature of the base material 100 satisfies about 750°C to about 900°C, the desired structure can be obtained, recrystallization can be sufficiently completed, and the efficiency of the manufacturing process can be improved.

The plating step (S500) may be a step of forming a plating layer 400 on the annealed base material 100. In one embodiment, the plating layer 400 may be formed on the annealed base material 100 through the plating step (S500). Specifically, the plating layer 400 may be formed on the surface of the internal oxide layer 300 through the plating step (S500). At this time, the plating layer 400 may include a zinc (Zn)-based plating layer or an aluminum (Al)-based plating layer.

Specifically, in the plating step (S500), the annealed base material 100 may be immersed in a plating bath. At this time, the plating bath can maintain a temperature of about 400°C to about 700°C. The plating adhesion amount may be about 40 g/m ² to about 200 g/m ² on both sides of the base material (100, or the internal oxide layer 300).

In one embodiment, the depth (or thickness (t4)) of the plating layer 400 formed on the base material 100 or the decarburization layer 200 is about 5 μm to about 20 μm in the plate thickness direction of the base material 100. You can. If the depth (or thickness t4) of the plating layer 400 is about 5㎛ or less, the sacrificial anti-corrosion ability of the plating layer 400 may be insufficient, and if the depth (or thickness) of the plating layer 400 is about 20㎛ or more. In this case, the cost of forming the plating layer 400 increases, which may reduce economic efficiency. Therefore, when the depth (or thickness t4) of the plating layer 400 satisfies about 5㎛ to about 20㎛, corrosion of the base material 100 of the hot stamping part 1 can be prevented or minimized. .

In one embodiment, the annealing step (S400) and the plating step (S500) may be performed in the same line. Accordingly, the line speed at which the plating step (S500) is performed may be about 30 mpm to about 200 mpm. If the line speed is below about 30 mpm, productivity may be reduced because the line speed is too slow. The plating amount is controlled using an air knife. If the line speed is about 200 mpm or higher, the line speed is too fast to control the plating amount using an air knife. Therefore, when the line speed at which the plating step (S500) is performed satisfies about 30 mpm to about 200 mpm, productivity can be improved and the plating amount can be easily controlled at the same time.

In one embodiment, a plated steel sheet with a plating layer 400 formed on at least one surface of the base material 100 may be manufactured through the plating step (S500). At this time, the plated steel sheet includes a base material 100, a decarburization layer 200 formed on the base material 100, an internal oxide layer 300 formed on the decarburization layer 200, and a plating layer formed on the internal oxide layer 300 ( 400). Specifically, the plated steel sheet has a base material 100, a decarburization layer 200 formed on the surface of the base material 100, an internal oxide layer 300 formed on the surface of the decarburization layer 200, and a surface of the internal oxide layer 300. It may include a plating layer 400 formed on.

Figure 6 is a flowchart schematically showing a hot stamping step according to an embodiment of the present invention, and Figure 7 is a flowchart schematically showing a heating step according to an embodiment of the present invention.

Referring to FIGS. 6 and 7 , a hot stamping step (S600) may be performed after the plating step (S500, see FIG. 2). The hot stamping step (S600) may include a heating step (S610), a transfer step (S620), a forming step (S630), and a cooling step (S640).

First, a blank can be formed by cutting a plated steel sheet on which a plating layer (400, see FIG. 5) is formed on at least one side of the base material (100, see FIG. 5). At this time, a decarburization layer (200, see FIG. 5) and an internal oxide layer (300, see FIG. 5) may exist between the base material 100 and the plating layer 400.

In the heating step (S610), the blank may be heated in a heating furnace having a plurality of sections having different temperature ranges. As shown in FIG. 7, the heating step (S610) may include a multi-stage heating step (S611) and a crack heating step (S612). The multi-stage heating step (S611) and the crack heating step (S612) may be steps in which the blank is heated while passing through a plurality of sections provided in the heating furnace.

In one embodiment, the overall furnace temperature may be from about 680°C to about 910°C. Specifically, the overall temperature of the heating furnace where the multi-stage heating step (S611) and the crack heating step (S612) are performed may be about 680°C to about 910°C. At this time, the temperature of the heating furnace where the multi-stage heating step (S611) is performed may be about 680°C to about Ac3, and the temperature of the heating furnace where the crack heating step (S612) is performed may be about Ac3 to about 910°C.

In the multi-stage heating step (S611), the blank may pass through a plurality of sections provided in the heating furnace and be heated (or heated) step by step. Among the plurality of sections provided in the heating furnace, there may be a plurality of sections in which the multi-stage heating step (S611) is performed, and the temperature is increased in the direction from the entrance of the heating furnace where the blank is input to the outlet of the heating furnace where the blank is taken out. The temperature is set for each section, so the blank can be heated (or heated) in stages.

A crack heating step (S612) may be performed after the multi-stage heating step (S611). In the crack heating step (S612), the multi-stage heated blank may be heated (or crack heated) while passing through a section of the heating furnace set to a temperature of about Ac3 to about 910°C. Among the plurality of sections provided in the heating furnace, there may be at least one section in which the crack heating step (S612) is performed.

Referring to FIG. 8, a heating furnace according to an embodiment may include a plurality of sections having different temperature ranges. Specifically, the heating furnace includes a first section (P ₁ ) having a first temperature range (T ₁ ), a second section (P ₂ ) having a second temperature range (T ₂ ), and a third temperature range (T ₃ ). A third section (P ₃ ) having a fourth _section (P ₄ ) having a fourth temperature range (T ₄ ), a fifth section (P 5 ) having a fifth temperature range (T ₅ ), a sixth temperature range It may be provided with a sixth section (P ₆ ) having (T ₆ ), and a seventh section (P ₇ ) having a seventh temperature range (T ₇ ).

In one embodiment, in the multi-stage heating step (S611), the blank may be heated step by step while passing through the first section (P ₁ ) to the fourth section (P ₄ ) defined within the heating furnace. In addition, in the crack heating step (S612), the blank heated in multiple stages in the first section (P ₁ ) to the fourth section (P ₄ ) passes through the fifth section (P ₅ ) to the seventh section (P ₇ ) and is crack heated. It can be.

The first section (P ₁ ) to the seventh section (P ₇ ) may be sequentially arranged in the heating furnace. The first section (P ₁ ) having the first temperature range (T ₁ ) is adjacent to the inlet of the heating furnace into which the blank is input, and the seventh section (P ₇ ) having the seventh temperature range (T ₇ ) is adjacent to the entrance of the heating furnace into which the blank is introduced. It may be adjacent to the outlet of the heating furnace. Therefore, the first section (P ₁ ) having the first temperature range (T ₁ ) may be the first section of the heating furnace, and the seventh section (P ₇ ) having the seventh temperature range (T ₇ ) may be the heating furnace. It may be the last section of .

The temperature of a plurality of sections provided in the heating furnace, for example, the temperature of the first section (P ₁ ) to the seventh section (P ₇ ) increases in the direction from the entrance of the heating furnace where the blank is input to the outlet of the heating furnace where the blank is taken out. can do. However, the temperatures of the fifth section (P ₅ ), the sixth section (P ₆ ), and the seventh section (P ₇ ) may be the same. Additionally, the temperature difference between two adjacent sections among the plurality of sections provided in the heating furnace may be greater than 0°C and less than or equal to about 100°C. For example, the temperature difference between the first section (P ₁ ) and the second section (P ₂ ) may be greater than 0°C and less than or equal to about 100°C.

The heating furnace temperature of the crack heating step (S612) may be about Ac3 to about 910°C. If the furnace temperature of the crack heating step (S612) is about Ac3 or less, the manufactured hot stamping part may not have the desired material. On the other hand, when the heating furnace temperature in the crack heating step (S612) is about 910° C. or higher, zinc (Zn) contained in the plating layer 400 may be vaporized, resulting in loss of the plating layer 400. Therefore, when the heating furnace temperature of the crack heating step (S612) satisfies about Ac3 to about 910°C, the manufactured hot stamping part can be formed of a desired material, and loss of the plating layer 400 can be prevented. .

In Figure 8, the heating furnace according to one embodiment is shown as having seven sections having different temperature ranges, but the present invention is not limited thereto. The heating furnace may be provided with five, six, or eight sections having different temperature ranges.

In one embodiment, the heating step (S610) includes a multi-stage heating step (S611) and a crack heating step (S612), so that the temperature of the heating furnace can be set in stages, thereby improving the energy efficiency of the heating furnace.

In one embodiment, the furnace may have a length of about 20 m to about 40 m along the transport path of the blank. The heating furnace may be provided with a plurality of sections having different temperature ranges, and the ratio of the length of the section in which the blank is heated in multiple stages among the plurality of sections and the length of the section in which the blank is crack-heated among the plurality of sections is about 1:1 to 1:1. Approximately 4:1 can be satisfied. If the length of the section where the blank is crack-heated increases within the heating furnace and the ratio of the length of the section where the blank is multi-stage heated and the length of the section where the blank is crack-heated exceeds approximately 1:1, penetration into the blank from the crack-heated section As the amount of hydrogen increases, delayed rupture may increase. On the other hand, if the length of the section in which the blank is crack-heated decreases and the ratio of the length of the section in which the blank is multi-stage heated to the length of the section in which the blank is crack-heated is less than about 4:1, the crack heating section (or time) is sufficient. Because this is not ensured, the strength of hot stamping parts manufactured by the hot stamping part manufacturing process may be uneven. For example, the length of the uniform heating section among the plurality of sections provided in the heating furnace may be about 20% to about 50% of the total length of the heating furnace.

In one embodiment, the total heating time during which the heating step (S610) is performed may be about 2 min to about 20 min. That is, the total time the blank stays in the heating furnace may be about 2 min to about 20 min. If the total heating time for which the heating step (S610) is performed is about 2 min or less, the hot stamping part 1 manufactured may not have the desired material due to insufficient heating time. On the other hand, if the total heating time during which the heating step (S610) is performed is about 20 minutes or more, the heating time may be too long and the production speed may decrease, thereby reducing economic efficiency. Therefore, when the total heating time for which the heating step (S610) is performed satisfies about 2 min to about 20 min, the manufactured hot stamping part 1 can have the desired material, and at the same time, the economic efficiency of the manufacturing process is prevented from being reduced. Or it can be minimized.

After the heating step (S610), a transfer step (S620), a forming step (S630), and a cooling step (S640) may be further performed.

In one embodiment, the transfer step (S620) may be a step of transferring the heated blank from the heating furnace to the mold. At this time, in the transfer step (S620), the heated blank may be cooled at atmospheric temperature (or room temperature). That is, the heated blank can be air-cooled during transport. If the heated blank is not cooled in air, the mold entry temperature (eg, molding start temperature) may increase and wrinkles (or bends) may occur on the surface of the manufactured hot stamping part 1. Additionally, since the use of a coolant may affect the subsequent process (hot stamping), it may be desirable for the heated blank to be air-cooled during transport.

In one embodiment, the forming step (S630) may be a step of forming a molded body by hot stamping the transferred blank. Specifically, in the forming step (S400), the molded body may be formed by pressing the blank with a mold.

In one embodiment, the molding start temperature may be about 500°C or more and about 700°C or less. If the forming start temperature| is less than about 500°C, the forming start temperature is too low, so the formability of the blank may deteriorate, and the manufactured hot stamping part 1 may not have the target structure and physical properties. On the other hand, when the molding start temperature is greater than about 700°C, wrinkles (or bends) may occur on the surface of the manufactured hot stamping part 1. Additionally, the plating layer 400 may be adhered to the mold. Therefore, when the forming start temperature is about 500°C or more and about 700°C or less, the formability of the blank can be improved, the manufactured hot stamping part (1) can have the target structure and physical properties, and the manufactured hot stamping part ( 1) The occurrence of wrinkles (or bends) on the surface can be prevented or minimized.

In one embodiment, the cooling step (S500) may be a step of cooling the molded body. The cooling step (S500) may be performed within a mold in which the blank is pressed.

Specifically, the final product can be formed by cooling the molded body at the same time as molding it into the final part shape in a mold. The mold may be provided with cooling channels through which refrigerant circulates inside. The molded body can be rapidly cooled by circulation in the refrigerant supplied through the cooling channel provided in the mold. At this time, in order to prevent the spring back phenomenon of the plate and maintain the desired shape, rapid cooling can be performed while pressing while the mold is closed. When forming and cooling the molded body, the average cooling rate can be at least about 10°C/s to the martensite end temperature.

In one embodiment, the cooling end temperature at which the cooling step (S640) ends may be about room temperature or higher and about 200°C or lower. If the cooling end temperature is below room temperature, the productivity of the manufacturing process may decrease. On the other hand, if the cooling end temperature exceeds about 200℃, the manufactured hot stamping part (1) is cooled in air at room temperature. At this time, distortion may occur in the hot stamping part (1), and it may be difficult to secure the target material. there is. Therefore, when the cooling end temperature at which the cooling step (S640) is completed satisfies the range of about 200°C or higher above room temperature, the productivity of the manufacturing process can be improved and distortion of the manufactured hot stamping part 1 can be prevented. can be prevented or minimized.

Accordingly, the present inventor derived equations 3 and 4 that ensure that the hot stamping part 1 manufactured through excessively repeated experiments has a VDA bending angle of about 60° or more. In one embodiment, the manufactured hot stamping part 1 may satisfy relation 3 and relation 4. Specifically, the hardness within about 50㎛ depth (or thickness) from the surface of the hot stamping part 1 in the direction of the plate thickness of the hot stamping part 1 and the average hardness of the hot stamping part 1 satisfy the following relational equation 3. and the depth (or thickness) of the internal oxide layer 300 may satisfy the following relational equation 4. For example, the hot stamping part 1 may satisfy both equations 3 and 4.

(A/B) ≤ 0.7

In equation 3, A is the hardness (Hv (≤50㎛)) within about 50㎛ depth (or thickness) in the direction of the plate thickness of the hot stamping part (1), and B is the average hardness (Hv) of the hot stamping part (1) (avg.)).

C ≤ 5㎛

In Equation 4, C is the depth (or thickness) of the internal oxide layer 300 in the plate thickness direction of the hot stamping part 1.

In one embodiment, when the manufactured hot stamping part 1 satisfies the above-described equations 3 and 4, the toughness of the hot stamping part 1 manufactured through the hot stamping part manufacturing method may be improved. For example, a hot stamping part 1 manufactured through a hot stamping part manufacturing method may have a VDA bending angle of about 60° or more. In addition, the hot stamping part 1 manufactured through the hot stamping part manufacturing method has a tensile strength (TS) of about 1680 MPa to about 2000 MPa, a yield stress (YP) of about 1150 MPa to about 1500 MPa, and a yield stress of about 4%. It may have an elongation (EL) of from about 10%.

Below, the present invention will be described in more detail through experimental examples. However, the following experimental examples are intended to illustrate the present invention in more detail, and the scope of the present invention is not limited by the following experimental examples. The following experimental examples can be appropriately modified and changed by those skilled in the art within the scope of the present invention.

성분(wt%)Composition (wt%)
CC	SiSi	MnMn	PP	SS	BB	TiTi	CrCr
0.290.29	0.20.2	1.51.5	0.02 이하0.02 or less	0.015 이하0.015 or less	0.00250.0025	0.0350.035	0.20.2

	SRT (℃)SRT (℃)	FDT (℃)FDT (℃)	CT (℃)CT (℃)	소둔 온도 (℃)Annealing Temperature (℃)	소둔로 이슬점 (℃)Annealing furnace dew point (℃)	가열 온도 (℃)heating temperature (℃)	가열 시간 (min)heating time (min)
실시예 1Example 1	12151215	900900	713713	820820	00	870870	55
실시예 2Example 2	12151215	900900	713713	820820	1414	870870	55
비교예 1Comparative Example 1	12151215	900900	713713	820820	2020	870870	55
비교예 2Comparative Example 2	12151215	900900	713713	820820	-30-30	870870	55

Example 1, Example 2, Comparative Example 1, and Comparative Example 2 are hot stamping parts (specimens) manufactured from slabs having the compositions listed in Table 1 through the process conditions listed in Table 2.

	A / BA/B	C(㎛)C(㎛)	VDA 굽힘각(°)VDA bending angle (°)	균열 깊이(㎛)Crack depth (㎛)
실시예 1Example 1	0.560.56	1.51.5	71.0871.08	33
실시예 2Example 2	0.410.41	55	73.5673.56	55
비교예 1Comparative Example 1	0.350.35	77	55.6355.63	1515
비교예 2Comparative Example 2	0.890.89	0.10.1	53.8453.84	1One

In Table 3, A is the hardness (Hv(≤50㎛)) within about 50㎛ depth (or thickness) in the direction of the plate thickness of the hot stamping part, and B is the average hardness (Hv(avg.)) of the hot stamping part. , C is the depth (or thickness) of the internal oxide layer 300 in the plate thickness direction of the hot stamping part. At this time, the hardness within a depth of approximately 50㎛ from the surface of the hot stamping part (1) in the direction of the sheet thickness of the hot stamping part (1) is approximately from the surface of the hot stamping part (1) to the thickness direction of the hot stamping part (1). It may be a hardness value measured with a Vickers hardness meter at a point below 50㎛ depth, and the average hardness (Hv (avg.)) of the hot stamping part (1) is about 1/4 point in the direction of the plate thickness of the hot stamping part (1). It may be a hardness value measured with a Vickers hardness tester.

In Table 3, the VDA bending angle was evaluated using the VDA standard (VDA238-100), and the crack depth was measured using a scanning electron microscope. At this time, the crack depth corresponds to the deepest crack depth measured through a scanning electron microscope.

The VDA bending angle of the hot stamping part required in the present invention is about 60° or more. Additionally, if the crack depth within the hot stamping part is large, the VDA bending angle of the hot stamping part may become small and the toughness of the hot stamping part may deteriorate. Accordingly, the crack depth in the hot stamping part required in the present invention is about 10 μm or less. If it falls outside the above-mentioned range, it constitutes a case where the required conditions are not met.

In the case of Examples 1 and 2, both relational expressions 1 ((A / B) ≤ 0.7) and 2 (C ≤ 5) are satisfied, and Comparative Example 1 satisfies relational expression 2 (C ≤ 5). This corresponds to the case where this is not done, and Comparative Example 2 corresponds to the case where relational expression 1 ((A / B) ≤ 0.7) is not satisfied. Example 1, Example 2, Comparative Example 1, and Comparative Example 2 correspond to specimens manufactured from a base material (100, or steel sheet) satisfying the composition described above in FIG. 1 according to a hot stamping part manufacturing method. However, Comparative Examples 1 and 2 are specimens that do not satisfy equation 1 ((A / B) ≤ 0.7) and/or equation 2 (C ≤ 5) due to differences in process control conditions.

If both Equation 1 ((A / B) ≤ 0.7) and Equation 2 (C ≤ 5) are satisfied, it can be confirmed that the VDA bending angle and crack depth satisfy the required conditions. Specifically, when both Equation 1 ((A / B) ≤ 0.7) and Equation 2 (C ≤ 5) are satisfied, it can be confirmed that the VDA bending angle is 60° or more and the crack depth is 10 ㎛ or less.

However, if Relation 2 (C≤5) is not satisfied, it can be confirmed that the VDA bending angle and crack depth do not satisfy the required conditions. Specifically, when relational equation 2 (C≤5) is not satisfied, it can be confirmed that the VDA bending angle is less than 60° and the crack depth is more than 10 ㎛.

In addition, if relational expression 1 ((A / B) ≤ 0.7) is not satisfied, it can be confirmed that the VDA bending angle does not satisfy the required conditions. Specifically, when relational equation 1 ((A / B) ≤ 0.7) is not satisfied, it can be confirmed that the VDA bending angle is less than 60°.

Therefore, if the hot stamping part 1 satisfies both relation 1 ((A / B) ≤ 0.7) and relation 2 (C ≤ 5), the hot stamping part 1 can have the required VDA bending angle, and , the depth of the crack in the hot stamping part 1 may be formed below a preset value. In other words, if the hot stamping part (1) satisfies both relational expression 1 ((A / B) ≤ 0.7) and relational expression 2 (C ≤ 5), both the toughness and high temperature formability of the hot stamping part (1) will be excellent. You can.

The present invention has been described with reference to the embodiments shown in the drawings, but these are merely exemplary, and those skilled in the art will understand that various modifications and equivalent other embodiments are possible therefrom. Therefore, the true scope of technical protection of the present invention should be determined by the technical spirit of the attached patent claims.

Claims

As a hot stamping part,

Base material;

A decarburization layer disposed on the base material; and

An internal oxide layer disposed on the decarburization layer;

Including,

The hot stamping part has a tensile strength (TS) of 1680 MPa to 2000 MPa,

A hot stamping part, wherein the hardness within a depth of 50㎛ from the surface of the hot stamping part in the direction of the plate thickness of the hot stamping part and the average hardness of the hot stamping part satisfy the following relational expression 1.

<Relational Expression 1>

(A/B) ≤ 0.7

(In the above relational equation 1, A is the hardness (Hv (≤50 μm)) within a depth of 50 μm in the plate thickness direction of the hot stamping part, and B is the average hardness (Hv (avg.)) of the hot stamping part. .)
According to paragraph 1,

A hot stamping part, wherein the depth of the internal oxide layer satisfies the following equation 2.

<Relationship 2>

C ≤ 5㎛

(In Equation 2 above, C is the depth of the internal oxide layer in the direction of the plate thickness of the hot stamping part.)
According to paragraph 1,

The hot stamping part has a VDA bending angle of 60° or more.
According to paragraph 1,

The hot stamping part has a yield stress (YP) of 1150 MPa to 1500 MPa and an elongation (EL) of 4% to 10%.
According to paragraph 1,

The hot stamping part has a microstructure containing a martensite fraction of 90% or more.
According to paragraph 1,

A hot stamping part further comprising a plating layer disposed on the inner oxide layer.
According to clause 6,

A hot stamping part where the thickness of the plating layer is 10㎛ to 30㎛.
A method for manufacturing hot stamping parts, comprising:

Forming a blank by cutting a plated steel sheet on which a plating layer is formed on at least one side of the base material; and

A step of heating the blank in a heating furnace having a plurality of sections having different temperature ranges,

The step of heating the blank is,

A multi-stage heating step of heating the blank in stages; and

It includes a crack heating step of heating the multi-stage heated blank to a temperature of Ac3 to 910°C,

A method of manufacturing a hot stamping part, wherein the hardness within a depth of 50 μm from the surface of the hot stamping part in the direction of the plate thickness of the hot stamping part and the average hardness of the hot stamping part satisfy the following relational equation 3.

<Relational Expression 3>

(A/B) ≤ 0.7

(In the above relational equation 3, A is the hardness (Hv (≤50 μm)) within a depth of 50 μm in the plate thickness direction of the hot stamping part, and B is the average hardness (Hv (avg.)) of the hot stamping part. .)
According to clause 8,

A method of manufacturing a hot stamping part, wherein the dew point temperature of the annealing furnace of the base material is -15°C to +15°C.
According to clause 8,

A method of manufacturing a hot stamping part, wherein the annealing temperature of the base material is 750°C to 900°C.
According to clause 8,

After heating the blank,

transferring the heated blank;

Forming a molded body by pressing the transferred blank into a mold; and

Cooling the molded body;

A method for manufacturing hot stamping parts, further comprising:
According to clause 11,

A decarburization layer formed on the base material; and

An internal oxide layer formed on the decarburization layer;

A method for manufacturing hot stamping parts, further comprising:
According to clause 12,

A method of manufacturing a hot stamping part, wherein the depth of the internal oxide layer satisfies the following relational expression 4.

<Relational Equation 4>

C ≤ 5㎛

(In Equation 4, C is the depth of the internal oxide layer in the direction of the plate thickness of the hot stamping part.)