WO2023220785A1 - In situ recovery in hard rock ore bodies - Google Patents
In situ recovery in hard rock ore bodies Download PDFInfo
- Publication number
- WO2023220785A1 WO2023220785A1 PCT/AU2023/050425 AU2023050425W WO2023220785A1 WO 2023220785 A1 WO2023220785 A1 WO 2023220785A1 AU 2023050425 W AU2023050425 W AU 2023050425W WO 2023220785 A1 WO2023220785 A1 WO 2023220785A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- leach liquor
- resource definition
- holes
- reserve
- valuable metal
- Prior art date
Links
- 239000011435 rock Substances 0.000 title claims abstract description 100
- 238000011084 recovery Methods 0.000 title claims abstract description 47
- 238000011065 in-situ storage Methods 0.000 title claims abstract description 20
- 229910052751 metal Inorganic materials 0.000 claims abstract description 87
- 239000002184 metal Substances 0.000 claims abstract description 87
- 238000000034 method Methods 0.000 claims abstract description 52
- 238000002386 leaching Methods 0.000 claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- 238000005065 mining Methods 0.000 claims description 13
- 238000012545 processing Methods 0.000 claims description 10
- 238000005553 drilling Methods 0.000 claims description 5
- 230000001172 regenerating effect Effects 0.000 claims description 4
- 239000012530 fluid Substances 0.000 description 23
- 238000005516 engineering process Methods 0.000 description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 9
- 229910052802 copper Inorganic materials 0.000 description 9
- 239000010949 copper Substances 0.000 description 9
- 229910052500 inorganic mineral Inorganic materials 0.000 description 9
- 239000011707 mineral Substances 0.000 description 9
- 235000010755 mineral Nutrition 0.000 description 9
- 230000035699 permeability Effects 0.000 description 9
- 238000002347 injection Methods 0.000 description 8
- 239000007924 injection Substances 0.000 description 8
- 229910052770 Uranium Inorganic materials 0.000 description 7
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 7
- 229910052737 gold Inorganic materials 0.000 description 7
- 239000010931 gold Substances 0.000 description 7
- 230000001939 inductive effect Effects 0.000 description 7
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 7
- 239000000243 solution Substances 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000013459 approach Methods 0.000 description 3
- 239000010953 base metal Substances 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000010970 precious metal Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 238000013461 design Methods 0.000 description 2
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- 230000007613 environmental effect Effects 0.000 description 2
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- 230000000737 periodic effect Effects 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 230000000638 stimulation Effects 0.000 description 2
- 241001474033 Acar Species 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
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- 239000010437 gem Substances 0.000 description 1
- 229910001751 gemstone Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010423 industrial mineral Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000006263 metalation reaction Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000004058 oil shale Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000005067 remediation Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
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Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/28—Dissolving minerals other than hydrocarbons, e.g. by an alkaline or acid leaching agent
- E21B43/283—Dissolving minerals other than hydrocarbons, e.g. by an alkaline or acid leaching agent in association with a fracturing process
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21C—MINING OR QUARRYING
- E21C41/00—Methods of underground or surface mining; Layouts therefor
- E21C41/16—Methods of underground mining; Layouts therefor
- E21C41/22—Methods of underground mining; Layouts therefor for ores, e.g. mining placers
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/04—Obtaining noble metals by wet processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0065—Leaching or slurrying
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/045—Leaching using electrochemical processes
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/25—Methods for stimulating production
- E21B43/26—Methods for stimulating production by forming crevices or fractures
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/28—Dissolving minerals other than hydrocarbons, e.g. by an alkaline or acid leaching agent
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B33/00—Sealing or packing boreholes or wells
- E21B33/10—Sealing or packing boreholes or wells in the borehole
- E21B33/13—Methods or devices for cementing, for plugging holes, crevices or the like
- E21B33/138—Plastering the borehole wall; Injecting into the formation
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/11—Perforators; Permeators
- E21B43/116—Gun or shaped-charge perforators
- E21B43/117—Shaped-charge perforators
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/30—Specific pattern of wells, e.g. optimising the spacing of wells
Definitions
- the invention relates to the use of in situ recovery (ISR) technology in hard rock ore bodies.
- ISR in situ recovery
- the invention relates particularly, although by no means exclusively, to the use of ISR technology to recover gold and copper from hard rock ore bodies.
- the invention relates particularly, although by no means exclusively, to a method of in situ recovery of a valuable metal such as gold and copper from a hard rock ore body reserve and to an in situ recovery mine.
- Current ISR technology includes (a) injecting a leach liquor into an ore body so that the leach liquor can extract valuable metals into the leach liquor and (b) removing, typically by pumping, leach liquor with metals in solution from the ore body, (c) extracting metals from the leach liquor, and (d) regenerating to the extent possible and returning regenerated and make-up leach liquor to the ore body.
- ISR technology has been applied to the recovery of uranium and copper.
- Uranium deposits suitable for ISL technology are in permeable sand or sandstone that are confined by adjacent impermeable structures, which facilitate leach liquor injection and leach liquor removal.
- a leach liquor is pumped into the ore body (below the water table) via a borehole and takes uranium in the ore body into solution.
- leach liquors fall into two categories: acids and carbonate reactants.
- Commonly used reactants include sulfuric acid, nitric acid, hydrochloric acid, sodium bicarbonate, and hydrogen peroxide.
- Sulfuric acid offers high leach performance at a relatively low cost but produces residues (e.g., gypsum), which degrade performance.
- uranium is recovered at relatively high recoveries from permeable sands and sandstones.
- hard rock ore bodies is understood herein to mean ore bodies that have a low permeability, typically ⁇ 0.01 mD, more typically ⁇ 0.001 mD. Permeability and porosity are important criteria in the application of ISR.
- permeability is “the ability of a rock to transmit fluids under differential pressure”
- porosity is “the ratio of void space to bulk volume within a rock sample”.
- effective porosity is “the ratio of interconnected pore volume (excluding dead-end or isolated pores)” .
- Permeability is considered to be a more important factor in ISR where a fluid must be able to flow through rock from an injection point to a recovery point.
- High rock porosity will maximize the rock surface area that the fluid will contact during its flow path.
- fluid flow in and out of pores is usually a much slower process that is governed by diffusion.
- Uranium has generally seen widespread is suitable for use of ISR owing to the natural permeability of many of these deposits.
- examples may be found where copper has been extracted via ISR.
- ISR applications tend to be confined to naturally permeable ore bodies or where the ground has been previously broken intentionally or as part of previous mining activity.
- hard rock ore bodies include ore bodies that contain base metals, precious metals, industrial minerals, and precious or semi-precious gemstones.
- Hard rock ore bodies do not usually include coal, oil shale, phosphate, sodium, potassium, or gilsonite deposits.
- the invention is based on a realization that drill holes that were formed in a resource definition program to establish a hard rock ore body reserve, as described herein, are an opportunity for in situ recovery of a valuable metal from hard rock ore bodies.
- resource definition program is understood herein to mean a drilling program and assessing rock samples collected in the program to establish a reserve in a mineral resource, including establishing boundaries of the resource and the geology and mineralogy of the reserve.
- objective of a resource definition program in any given situation is to match a resource confidence level gained from an exploration drilling program to a short-, medium- and long-term mine design and schedule.
- Reserve is understood herein to mean an economically mineable part of an inferred and indicated resource. Reserves are that subgroup of a mineral resource that have been discovered, have a known size, and can be extracted at a profit.
- the term “inferred resource” is understood herein to mean that part of a mineral resource for which quantity and grade or quality can be estimated on the basis of geological evidence and limited sampling and reasonably assumed, but not verified, geological and grade continuity.
- dicated resource (also referred to as measured reserve) is understood herein to mean economic mineral occurrences that have been sampled (from locations such as outcrops, trenches, pits, and drill holes) to a point where an estimate has been made, at a reasonable level of confidence, of their contained metal, grade, tonnage, shape, densities, physical characteristics.
- precious metal is understood herein to mean any precious metal and any base metal that has economic value.
- Gold is an example of a precious metal and copper is an example of a base metal.
- the invention is a method and a mine for in situ recovery of a valuable metal from a hard rock ore body reserve.
- Resource definition holes that were drilled as part of a resource definition program are used as production holes.
- the resource definition holes are located over all or at least a substantial part of an area of the reserve.
- the method includes injecting a leach liquor into a plurality of the resource definition holes.
- the leach liquor penetrates the rock mass surrounding the resource definition holes and dissolves the valuable metal.
- the depleted leach liquor that contains the valuable metal is removed via the same or another plurality of the resource definition holes for downstream recovery of the valuable metal.
- the invention provides a method of in situ recovery of a valuable metal from a hard rock ore body reserve, as described herein, that includes:
- the method of the invention is a comparatively large-scale operation, simultaneously leaching from at least a substantial part of the rock mass of the hard rock reserve and thereby compensating for low leach rates with a large-scale leaching operation, and accepting that full recovery from the rock mass could take a considerable time period, typically years.
- the method provides an opportunity for a low environmental impact mining operation, with a minimal above ground footprint and land disturbance. Conducting leaching operations in hard rock deposits that tend to be not very permeable makes it possible to mine safely, with leach liquor being contained within the reserve.
- the substantial part of the reserve may be at least 85% of the area within a boundary of the reserve.
- the substantial part of the reserve may be at least 90% of the area within a boundary of the reserve.
- the substantial part of the reserve may be at least 95% of the area within the boundary of the reserve.
- the method may include supplying the leach liquor into one group of resource definition holes and removing depleted leach liquor containing dissolved valuable metal from another group of resource definition holes.
- the method may include supplying the leach liquor into and removing depleted leach liquor containing dissolved valuable metal from the same resource definition holes.
- the method may include continuously supplying the leach liquor to the resource definition holes and continuously removing depleted leach liquor containing dissolved valuable metal from the resource definition holes.
- the method may include periodically supplying the leach liquor to the resource definition holes and periodically removing depleted leach liquor containing dissolved valuable metal from the resource definition holes.
- the method may include allowing a residence time of at least 2 hours of the leach liquor in the resource definition holes before removing depleted leach liquor containing dissolved valuable metal from the resource definition holes.
- the method may include installing at the resource definition holes facilities for supplying leach liquor and recovering depleted leach liquor containing dissolved valuable metal.
- the method may include fracturing the rock mass surrounding at least some of the resource definition holes before supplying the liquor into the resource definition holes.
- fracturing the rock mass may not be required.
- the fracturing step may include fracturing at least substantially all of the volume of rock mass in the reserve.
- the fracturing step may include fracturing at least 85% by volume of the rock mass in the reserve.
- the fracturing step may include fracturing at least 90% by volume of the rock mass in the reserve.
- the resource definition holes may be any suitable spacing(s).
- typical hole spacings are between 50- 100m.
- the resource definition holes may be spaced further apart or closer than 50-100m.
- the arrangement of holes may be in any suitable two-dimensional grid pattern.
- the resource definition holes are in a 100m xlOOm, typically a 50m x 50m grid pattern.
- the resource definition holes may be any depth(s).
- the resource definition hole diameters may be any suitable diameter.
- internal hole diameters may be 40- 100mm, more typically 50- 70mm.
- the extent of fracturing required in the fracturing step in any given situation will be a function of a range of factors including, but not limited to the geology of the hard rock ore body, such as permeability and porosity, and the selected recovery step (b).
- the fracturing step may be any suitable step.
- the fracturing step may be NaturaFracTM pulsed gas stimulation inducing fractures in the rock mass.
- the fracturing step may be NaturaFracTM dynamic pulsed fluids injection unit inducing fractures in the rock mass.
- the fracturing step may include injecting a hydraulic fracturing fluid into the drilled holes and inducing fractures in the rock mas.
- the recovery step may be electrokinetic in situ leaching (EK-ISL), i.e. recovering valuable metal from the ore body by using an electric field to induce the migration of a leach liquor through the ore body.
- EK-ISL electrokinetic in situ leaching
- the generation of a current facilitates flow and transport of solutes through different processes (Acar and Alshawabkeh, 1993; Yeung, 2006).
- the method may include drilling additional holes to the existing resource definition holes to cover at least the substantial area of the hard body rock mass in the reserve. For example, it may be found that the spacing and/or depth of the existing resource definition holes are not sufficient for recovering valuable metal from at least the substantial area of the hard rock ore body reserve and additional holes are required to do this.
- the method may include designing the resource definition program and any additional holes having regard to requirements for using the holes to recover the valuable metal from the ore body.
- the method may include regenerating the leach liquor after recovering the valuable metal from the leach liquor/dissolved valuable metal removed from the resource definition holes and returning regenerated leach liquor to the resource definition holes, optionally with make-up leach liquor.
- the leach liquor may be any suitable leach liquor in any suitable concentration having regard to the valuable metal and the mineralogy of the ore body and leach liquor injection/removal conditions.
- key considerations for the fracturing step may include:
- the fracturing step may include casing each resource definition hole.
- the fracturing step may include casing and lining each hole.
- the fracturing step may include perforating each cased and lined hole so that injected hydraulic fracturing fluid flows through the perforations into the rock mass and induces fractures in the rock mass.
- the fracturing step may include perforating the casing of each drilled hole at spaced intervals along a section of the drilled hole.
- the fracturing step may include:
- each resource definition hole (i) lining each resource definition hole with a casing, such as with a metallic casing or a non-metallic casing;
- the perforated holes may be in “frac clusters”, with multiple perforated holes at different heights forming a single cluster.
- the cased and lined hole may be perforated by any suitable perforating apparatus.
- a suitable perforating apparatus is a perforating gun having spaced explosive charges that can be initiated to from a perforate the immediate part of the cased and lined hole.
- the hydraulic fracturing fluid may be any suitable hydraulic fracturing fluid.
- water is the hydraulic fracturing fluid.
- the invention may include selecting hydraulic fracturing fluids that are suitable for forming fractures having different sizes and shapes.
- One option is forming parallel fractures (preferred by miners) - slower flow rate and more viscous hydraulic fracturing fluids.
- Another option is forming complex fractures (preferred by seismologists) - different hydraulic fracturing fluids and higher flow rates.
- the method may include positioning sensors in production holes that are outside the boundary of the reserve and assessing whether there is any escape of leach liquor from the reserve.
- the invention also provides an in situ recovery mine for recovering a valuable metal from a hard rock ore body reserve, as described herein, that includes:
- a recovery unit configured for recovering a valuable metal from the hard rock ore body reserve by: i. supplying, for example by injecting, a leach liquor into a plurality of resource definition holes located over all or at least a substantial part of an area of the reserve and thereby leaching at least a substantial part of the rock mass in the reserve at the same time; ii. removing depleted leach liquor containing dissolved valuable metal from the resource definition holes; and iii. processing the removed leach liquor and recovering the valuable metal.
- the resource definition holes are modified to become production holes.
- the recovery unit may be configured to supply leach liquor to and remove depleted leach liquor containing the valuable metal from the same resource definition hole.
- the recovery unit may be configured to supply leach liquor to a plurality of the resource definition holes and remove depleted leach liquor containing the valuable metal from another plurality of plurality of the resource definition holes.
- the recovery unit may include a fracturing unit configured for fracturing the rock mass of the reserve from the resource definition holes.
- the fracturing unit may be a BachaFracTM pulsed gas stimulation unit for inducing fractures in the rock mass.
- the fracturing unit may be a BachaFracTM dynamic pulsed fluids injection unit for inducing fractures in the rock mass.
- the fracturing unit may be configured for injecting a hydraulic fracturing fluid into the drilled holes and inducing fractures in the rock mas.
- the recovery unit may be an electrokinetic in situ leaching (EK-ISL) unit.
- EK-ISL electrokinetic in situ leaching
- the invention provides a method of mining a valuable metal from a hard rock ore body reserve, as described herein, that includes:
- Figure l is a diagram of one embodiment of an in situ recovery mine and a method of in situ recovery in accordance with the invention.
- Figure 2 illustrates a series of resource definition holes in a section of a mine.
- Figures are from publicly available sources and have been amended to include reference numerals.
- Figure 2 is from a paper entitled “Geometallurgy - A Route to More Resilient Mine Operations” by Simon C Dominy et al, Minerals 2018, 8, 560, and has been amended to include reference numerals.
- the invention is not confined to gold and copper recovery and extends to recovering any valuable metal from a hard rock ore body.
- the embodiment of the mine and mining method shown in the Figures is based on the use of existing resource definition holes 3 in a hard rock ore body in a mine reserve that have been retrofitted to supply a leach liquor to the hard rock ore body and to remove depleted leach liquor containing valuable metal in solution for above-ground recovery of the valuable metal and regeneration and return of the leach liquor to the hard rock ore body.
- the embodiment of the mine and mining method shown in the Figures supplies a leach liquor to a plurality of resource definition holes 3 and removes depleted liquor containing dissolved valuable metal from another plurality of resource definition holes 3.
- the existing resource definition drilled holes 3 cover all or substantially the whole area of the reserve, i.e., the economically mineable part of an inferred and indicated resource, and often extend beyond a boundary of the reserve (not shown).
- the extent of resource definition holes 3 in a typical mine is illustrated in Figure 2. There is a significant number of resource definition holes 3 in the Figure, over a range of depths and drill angles.
- the resource definition holes 3 within the boundary of the reserve are modified to become production holes and the mine is configured to recover valuable metal from large fractions of the ore in a reserve at once rather than via smaller well-field by well-field approach that characterizes known in situ mining operations.
- the slow metal recovery in hard rock is at least partially overcome by leaching all or at least a substantial part of a reserve, albeit at potentially increased significant upfront capital, but longer term lower operating costs and minimal environmental impact and remediation costs.
- sensors for assessing whether there is any escape of leach liquor from the reserve are positioned in resource definition holes 3 that are outside the boundary of the reserve.
- the mine includes:
- a fracturing unit (not shown) configured for fracturing the rock mass of the reserve from the resource definition holes;
- a recovery unit generally identified by the numeral 5 configured for recovering valuable metal from the hard rock ore body reserve by supplying, in this instance, injecting a leach liquor into one group of resource definition holes and removing depleted leach liquor containing dissolved valuable metal from the rock mass from another group of resource definition holes and processing the removed leach liquor and recovering valuable metal.
- the mining method includes the following steps:
- the plurality of resource definition holes 3 have been modified to deliver a hydraulic fluid to the holes 3 to fracture rock mass between the holes 3.
- the invention is not confined to the use of hydraulic fluid for fracturing the rock mass and extends to any other suitable options.
- Hydraulic fracturing includes positioning well-heads on the resource definition holes 3 and injecting a suitable hydraulic fluid into the holes 3.
- the resource definition holes 3 are divided into a 1 st group of holes (the injection holes 3) for injecting a leach liquor and a 2 nd group of holes (the discharge holes 3) for discharging the pregnant leach liquor containing a target valuable metal (in this embodiment, gold or copper) in solution.
- the 1 st and 2 nd groups of holes 3 are indicated by the arrows in the Figure.
- the leach liquor is injected continuously into the 1 st group of resource definition holes 3 and depleted leach liquor containing dissolved valuable metal is removed continuously from the 2 nd group of resource definition holes.
- the leach liquor may be any suitable leach liquor depending on the target valuable metal.
- the mine includes a holding tank 11 containing pregnant leach liquor and a network of pipes 7 for delivering leach liquor to the injection holes 3 and a network of pipes 9 for transferring pregnant leach liquor from the discharge holes 3 to the recovery unit 5.
- the recovery unit 5 includes:
- processing units 13, 15 for separating the target valuable metal from the pregnant liquor and regenerating the leach liquor and adding make-up leach liquor (as may be required), and
- the processing units 13, 15, 17 may be any suitable processing units depending on the target valuable metal.
- the above-described embodiment is one embodiment amongst a number of embodiments in accordance with the invention that include fracturing a hard rock ore body of a reserve and recovering valuable metals from the ore body.
- the process of assessing the requirements for any mine and mining method in accordance with the invention includes considering a range of factors, including the following factors.
- Target mineral extraction and recovery o A good understanding of the mineralogy for both target and gangue minerals as this will dictate what chemistries may be applied. o Maximising target mineral extraction and recovery. o Minimising the time to extraction.
- Well design o Building on hydrogeological understanding to include potential flow paths and travel time from the injection to recovery wells for the ore target and this is influenced by the level of liberation that may be imparted.
- the invention is not confined to fracturing a rock mass before supplying the leach liquor to the resource definition holes 3, as described in the embodiment.
- the invention extends to embodiments in which it is not necessary to fracture a rock mass.
- the invention is not confined to gold and copper as target valuable metals, as described in the embodiment.
- the invention injects the leach liquor for the target valuable metal continuously into the 1 st group of resource definition holes 3 and removes depleted leach liquor containing dissolved valuable metal continuously from the 2 nd group of resource definition holes
- the invention is not so limited.
- the invention extends to embodiments in which there is periodic supply of leach liquor into the 1 st group of resource definition holes 3 and periodic removal of depleted leach liquor containing dissolved valuable metal from the 2 nd group of resource definition holes.
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Abstract
A method and a mine for in situ recovery of a valuable metal from a hard rock ore body reserve is disclosed. Resource definition holes that were drilled as part of a resource definition program are used as production holes. The resource definition holes are located over all or at least a substantial part of an area of the reserve. The method includes injecting a leach liquor into a plurality of the resource definition holes. The leach liquor penetrates the rock mass surrounding the resource definition holes and dissolves the valuable metal. The depleted leach liquor that contains the valuable metal is removed via the same or another plurality of the resource definition holes for downstream recovery of the valuable metal. As a consequence, there is leaching of at least a substantial part of the rock mass in the reserve at the same time.
Description
IN SITU RECOVERY IN HARD ROCK ORE BODIES
TECHNICAL FIELD
The invention relates to the use of in situ recovery (ISR) technology in hard rock ore bodies.
The invention relates particularly, although by no means exclusively, to the use of ISR technology to recover gold and copper from hard rock ore bodies.
The invention relates particularly, although by no means exclusively, to a method of in situ recovery of a valuable metal such as gold and copper from a hard rock ore body reserve and to an in situ recovery mine.
BACKGROUND ART
Current ISR technology includes (a) injecting a leach liquor into an ore body so that the leach liquor can extract valuable metals into the leach liquor and (b) removing, typically by pumping, leach liquor with metals in solution from the ore body, (c) extracting metals from the leach liquor, and (d) regenerating to the extent possible and returning regenerated and make-up leach liquor to the ore body.
ISR technology has been applied to the recovery of uranium and copper.
Uranium deposits suitable for ISL technology are in permeable sand or sandstone that are confined by adjacent impermeable structures, which facilitate leach liquor injection and leach liquor removal. A leach liquor is pumped into the ore body (below the water table) via a borehole and takes uranium in the ore body into solution. Typically, leach liquors fall into two categories: acids and carbonate reactants. Commonly used reactants include sulfuric acid, nitric acid, hydrochloric acid, sodium bicarbonate, and hydrogen peroxide. Sulfuric acid offers high leach performance at a relatively low cost but produces residues (e.g., gypsum), which degrade performance.
In current uranium ISR operations, uranium is recovered at relatively high recoveries from permeable sands and sandstones.
The applicant is not aware of ISR technology being applied on a commercially viable basis to hard rock ore bodies.
The term “hard rock ore bodies” is understood herein to mean ore bodies that have a low permeability, typically < 0.01 mD, more typically < 0.001 mD.
Permeability and porosity are important criteria in the application of ISR.
As defined in Jackson, Kuhar, Esteban, and Dai (2017), although interlinked, key differences between the parameters include: permeability is “the ability of a rock to transmit fluids under differential pressure", and porosity is “the ratio of void space to bulk volume within a rock sample". Furthermore, effective porosity is “the ratio of interconnected pore volume (excluding dead-end or isolated pores)” .
Permeability is considered to be a more important factor in ISR where a fluid must be able to flow through rock from an injection point to a recovery point. High rock porosity will maximize the rock surface area that the fluid will contact during its flow path. However, fluid flow in and out of pores is usually a much slower process that is governed by diffusion.
The inherent permeability and porosity of the target ore body will have a significant impact on the extent to which ore body liberation will be required and therefore the cost of a process. Uranium has generally seen widespread is suitable for use of ISR owing to the natural permeability of many of these deposits. Similarly, examples may be found where copper has been extracted via ISR.
In summary, ISR applications tend to be confined to naturally permeable ore bodies or where the ground has been previously broken intentionally or as part of previous mining activity.
Typically, hard rock ore bodies include ore bodies that contain base metals, precious metals, industrial minerals, and precious or semi-precious gemstones.
Hard rock ore bodies do not usually include coal, oil shale, phosphate, sodium, potassium, or gilsonite deposits.
Challenges for hard rock ISR technology are creating access, leach liquor and redox chemistry, and solution containment.
Another over-arching challenge is to operate on a commercially viable basis in hard rock ore bodies that the applicant believes will only be able to operate at leaching rates that are an order of magnitude slower with lower recoveries than is the case with the use of ISR technology for uranium-containing permeable sands and sandstones.
A concept called “Resource ISR” was presented by the applicant at the 2018 ALTA conference. The concept includes leaching an entire ore body or large parts of the ore body at the same time. This ensures a continuous high metal production rate despite a low rate of metal leaching. This is a very different approach to that adopted in existing ISR operations.
The above description is not an admission of common general knowledge in Australia or elsewhere.
SUMMARY OF THE DISCLOSURE
The invention is based on a realization that drill holes that were formed in a resource definition program to establish a hard rock ore body reserve, as described herein, are an opportunity for in situ recovery of a valuable metal from hard rock ore bodies.
The use of these resource definition drilled holes as production holes for in situ recovery of a valuable metal in a hard rock ore body reserve is an advantage because it does not incur additional drilling costs, which are typically substantial costs, and reduces the time required to commence an ISR operation.
The term “resource definition program” is understood herein to mean a drilling program and assessing rock samples collected in the program to establish a reserve in a mineral resource, including establishing boundaries of the resource and the geology and mineralogy of the reserve. Typically, the objective of a resource definition program in any given situation is to match a resource confidence level gained from an exploration drilling program to a short-, medium- and long-term mine design and schedule.
The term “reserve” is understood herein to mean an economically mineable part of an inferred and indicated resource. Reserves are that subgroup of a mineral resource that have been discovered, have a known size, and can be extracted at a profit.
The term “inferred resource” is understood herein to mean that part of a mineral resource for which quantity and grade or quality can be estimated on the basis of geological evidence and limited sampling and reasonably assumed, but not verified, geological and grade continuity.
The term “indicated resource” (also referred to as measured reserve) is understood herein to mean economic mineral occurrences that have been sampled (from locations such as outcrops, trenches, pits, and drill holes) to a point where an estimate has been made, at a reasonable level of confidence, of their contained metal, grade, tonnage, shape, densities, physical characteristics.
The term “valuable metal” is understood herein to mean any precious metal and any base metal that has economic value. Gold is an example of a precious metal and copper is an example of a base metal.
In general terms, the invention is a method and a mine for in situ recovery of a valuable metal from a hard rock ore body reserve. Resource definition holes that were drilled as part of a resource definition program are used as production holes. The resource definition holes are located over all or at least a substantial part of an area of the reserve. The method
includes injecting a leach liquor into a plurality of the resource definition holes. The leach liquor penetrates the rock mass surrounding the resource definition holes and dissolves the valuable metal. The depleted leach liquor that contains the valuable metal is removed via the same or another plurality of the resource definition holes for downstream recovery of the valuable metal. As a consequence, there is leaching of at least a substantial part of the rock mass in the reserve at the same time.
The invention provides a method of in situ recovery of a valuable metal from a hard rock ore body reserve, as described herein, that includes:
(a) supplying, for example by injecting, a leach liquor into a plurality of resource definition holes as described herein that were drilled as part of a resource definition program for a hard rock ore body reserve and dissolving a valuable metal in the rock mass into the leach liquor, with the resource definition holes being located over all or at least a substantial part of an area of the reserve and thereby leaching at least a substantial part of the rock mass in the reserve at the same time;
(b) removing depleted leach liquor containing dissolved valuable metal from the resource definition holes, and
(c) processing the discharged depleted leach liquor containing and recovering the valuable metal.
In the above-described method, in effect, the resource definition holes are modified to become production holes.
Simultaneously leaching all or at least a substantial part of the rock mass in the reserve provides an opportunity for an economic mining operation in a hard rock mass, where it is usually only possible to achieve low leach rates because of the low permeability of the rock mass and other factors. The use of existing resource definition holes as production holes minimizes capital costs and the time to start production. Unlike known ISL technology that is used in permeable sand or sandstone deposits and is a small-scale well-field by small wellfield approach, the method of the invention is a comparatively large-scale operation, simultaneously leaching from at least a substantial part of the rock mass of the hard rock reserve and thereby compensating for low leach rates with a large-scale leaching operation, and accepting that full recovery from the rock mass could take a considerable time period, typically years. The method provides an opportunity for a low environmental impact mining operation, with a minimal above ground footprint and land disturbance. Conducting leaching
operations in hard rock deposits that tend to be not very permeable makes it possible to mine safely, with leach liquor being contained within the reserve.
The substantial part of the reserve may be at least 85% of the area within a boundary of the reserve.
The substantial part of the reserve may be at least 90% of the area within a boundary of the reserve.
The substantial part of the reserve may be at least 95% of the area within the boundary of the reserve.
The method may include supplying the leach liquor into one group of resource definition holes and removing depleted leach liquor containing dissolved valuable metal from another group of resource definition holes.
The method may include supplying the leach liquor into and removing depleted leach liquor containing dissolved valuable metal from the same resource definition holes.
The method may include continuously supplying the leach liquor to the resource definition holes and continuously removing depleted leach liquor containing dissolved valuable metal from the resource definition holes.
The method may include periodically supplying the leach liquor to the resource definition holes and periodically removing depleted leach liquor containing dissolved valuable metal from the resource definition holes.
The method may include allowing a residence time of at least 2 hours of the leach liquor in the resource definition holes before removing depleted leach liquor containing dissolved valuable metal from the resource definition holes.
The method may include installing at the resource definition holes facilities for supplying leach liquor and recovering depleted leach liquor containing dissolved valuable metal.
In some embodiments, the method may include fracturing the rock mass surrounding at least some of the resource definition holes before supplying the liquor into the resource definition holes.
In other embodiments, fracturing the rock mass may not be required.
The fracturing step may include fracturing at least substantially all of the volume of rock mass in the reserve.
The fracturing step may include fracturing at least 85% by volume of the rock mass in the reserve.
The fracturing step may include fracturing at least 90% by volume of the rock mass in the reserve.
The resource definition holes may be any suitable spacing(s).
For example, typical hole spacings are between 50- 100m.
The resource definition holes may be spaced further apart or closer than 50-100m.
The arrangement of holes may be in any suitable two-dimensional grid pattern.
Typically, the resource definition holes are in a 100m xlOOm, typically a 50m x 50m grid pattern.
The resource definition holes may be any depth(s).
The resource definition hole diameters may be any suitable diameter.
By way of example, internal hole diameters may be 40- 100mm, more typically 50- 70mm.
The extent of fracturing required in the fracturing step in any given situation will be a function of a range of factors including, but not limited to the geology of the hard rock ore body, such as permeability and porosity, and the selected recovery step (b).
The fracturing step may be any suitable step.
The fracturing step may be NaturaFrac™ pulsed gas stimulation inducing fractures in the rock mass.
The fracturing step may be NaturaFrac™ dynamic pulsed fluids injection unit inducing fractures in the rock mass.
The fracturing step may include injecting a hydraulic fracturing fluid into the drilled holes and inducing fractures in the rock mas.
The recovery step may be electrokinetic in situ leaching (EK-ISL), i.e. recovering valuable metal from the ore body by using an electric field to induce the migration of a leach liquor through the ore body. In electrokinetics, the generation of a current facilitates flow and transport of solutes through different processes (Acar and Alshawabkeh, 1993; Yeung, 2006).
The method may include drilling additional holes to the existing resource definition holes to cover at least the substantial area of the hard body rock mass in the reserve. For example, it may be found that the spacing and/or depth of the existing resource definition holes are not sufficient for recovering valuable metal from at least the substantial area of the hard rock ore body reserve and additional holes are required to do this.
The method may include designing the resource definition program and any additional holes having regard to requirements for using the holes to recover the valuable metal from the ore body.
The method may include regenerating the leach liquor after recovering the valuable metal from the leach liquor/dissolved valuable metal removed from the resource definition holes and returning regenerated leach liquor to the resource definition holes, optionally with make-up leach liquor.
The leach liquor may be any suitable leach liquor in any suitable concentration having regard to the valuable metal and the mineralogy of the ore body and leach liquor injection/removal conditions.
In any given situation, key considerations for the fracturing step may include:
(i) forming fractures that provide pathways for leach liquor to penetrate the ore body including, for example, forming pathways for leach liquor to flow between resource definition holes; and
(ii) forming a network of fractures that facilitates a target recovery rate and recovery from the rock mass in the reserve.
The fracturing step may include casing each resource definition hole.
The fracturing step may include casing and lining each hole.
The fracturing step may include perforating each cased and lined hole so that injected hydraulic fracturing fluid flows through the perforations into the rock mass and induces fractures in the rock mass.
The fracturing step may include perforating the casing of each drilled hole at spaced intervals along a section of the drilled hole.
The fracturing step may include:
(i) lining each resource definition hole with a casing, such as with a metallic casing or a non-metallic casing;
(ii) pumping cement or any other suitable lining material down the cased hole to a lower end, i.e., toe, of the hole and then up into an annular space between a hole wall and the casing to form a lining between the hole wall and the casing;
(iii) positioning a well head on the cased and lined hole that closes the hole;
(iv) perforating the casing and the outer lining at spaced intervals along a section of the drilled hole with a perforating apparatus, such as a perforating gun having spaced explosive charges that is lowered down and raised from the cased and lined hole on a wire line;
(v) injecting a hydraulic fracturing fluid into the cased, lined, and perforated hole via the well head and forcing hydraulic fracturing fluid through the perforations into the rock mass and inducing fractures in the rock mass; and
(vi) carrying out the series of steps (i) to (v) for each of a plurality of resource definition holes.
The perforated holes may be in “frac clusters”, with multiple perforated holes at different heights forming a single cluster.
The cased and lined hole may be perforated by any suitable perforating apparatus.
One example of a suitable perforating apparatus is a perforating gun having spaced explosive charges that can be initiated to from a perforate the immediate part of the cased and lined hole.
The hydraulic fracturing fluid may be any suitable hydraulic fracturing fluid. Typically, water is the hydraulic fracturing fluid.
The invention may include selecting hydraulic fracturing fluids that are suitable for forming fractures having different sizes and shapes.
Different hydraulic fracturing fluids may be required in different situations.
One option is forming parallel fractures (preferred by miners) - slower flow rate and more viscous hydraulic fracturing fluids.
Another option is forming complex fractures (preferred by seismologists) - different hydraulic fracturing fluids and higher flow rates.
The method may include positioning sensors in production holes that are outside the boundary of the reserve and assessing whether there is any escape of leach liquor from the reserve.
The invention also provides an in situ recovery mine for recovering a valuable metal from a hard rock ore body reserve, as described herein, that includes:
(a) a plurality of resource definition holes as described herein;
(b) a recovery unit configured for recovering a valuable metal from the hard rock ore body reserve by: i. supplying, for example by injecting, a leach liquor into a plurality of resource definition holes located over all or at least a substantial part of an area of the reserve and thereby leaching at least a substantial part of the rock mass in the reserve at the same time; ii. removing depleted leach liquor containing dissolved valuable metal from the resource definition holes; and iii. processing the removed leach liquor and recovering the valuable metal.
In the above-described mine, the resource definition holes are modified to become production holes.
The recovery unit may be configured to supply leach liquor to and remove depleted leach liquor containing the valuable metal from the same resource definition hole.
The recovery unit may be configured to supply leach liquor to a plurality of the resource definition holes and remove depleted leach liquor containing the valuable metal from another plurality of plurality of the resource definition holes.
The recovery unit may include a fracturing unit configured for fracturing the rock mass of the reserve from the resource definition holes.
The fracturing unit may be a NaturaFrac™ pulsed gas stimulation unit for inducing fractures in the rock mass.
The fracturing unit may be a NaturaFrac™ dynamic pulsed fluids injection unit for inducing fractures in the rock mass.
The fracturing unit may be configured for injecting a hydraulic fracturing fluid into the drilled holes and inducing fractures in the rock mas.
The recovery unit may be an electrokinetic in situ leaching (EK-ISL) unit.
The invention provides a method of mining a valuable metal from a hard rock ore body reserve, as described herein, that includes:
(a) conducting a resource definition program to establish a hard rock ore body reserve, the program including drilling a plurality of resource definition holes as described herein and assessing rock samples collected in the program;
(b) the above-described method of in situ recovery of the valuable metal from the hard rock ore body reserve.
BRIEF DESCRIPTION OF THE DRAWING
The invention is described further below by way of example only with reference to the accompanying drawings, of which:
Figure l is a diagram of one embodiment of an in situ recovery mine and a method of in situ recovery in accordance with the invention; and
Figure 2 illustrates a series of resource definition holes in a section of a mine.
It is noted that the Figures are from publicly available sources and have been amended to include reference numerals.
By way of example, Figure 2 is from a paper entitled “Geometallurgy - A Route to More Resilient Mine Operations” by Simon C Dominy et al, Minerals 2018, 8, 560, and has been amended to include reference numerals.
DESCRIPTION OF EMBODIMENT
The following description is in the context of in situ recovery of gold and copper from a hard rock ore body.
The invention is not confined to gold and copper recovery and extends to recovering any valuable metal from a hard rock ore body.
The embodiment of the mine and mining method shown in the Figures is based on the use of existing resource definition holes 3 in a hard rock ore body in a mine reserve that have been retrofitted to supply a leach liquor to the hard rock ore body and to remove depleted leach liquor containing valuable metal in solution for above-ground recovery of the valuable metal and regeneration and return of the leach liquor to the hard rock ore body.
The embodiment of the mine and mining method shown in the Figures supplies a leach liquor to a plurality of resource definition holes 3 and removes depleted liquor containing dissolved valuable metal from another plurality of resource definition holes 3.
Other embodiments of the mine and mining method supply leach liquor to a plurality of resource definition holes 3 and remove depleted liquor containing dissolved valuable metal from the same resource definition holes 3.
With reference to the Figures, the existing resource definition drilled holes 3 cover all or substantially the whole area of the reserve, i.e., the economically mineable part of an inferred and indicated resource, and often extend beyond a boundary of the reserve (not shown). The extent of resource definition holes 3 in a typical mine is illustrated in Figure 2. There is a significant number of resource definition holes 3 in the Figure, over a range of depths and drill angles.
In the embodiment, the resource definition holes 3 within the boundary of the reserve are modified to become production holes and the mine is configured to recover valuable metal from large fractions of the ore in a reserve at once rather than via smaller well-field by well-field approach that characterizes known in situ mining operations. In this way, the slow metal recovery in hard rock is at least partially overcome by leaching all or at least a substantial part of a reserve, albeit at potentially increased significant upfront capital, but longer term lower operating costs and minimal environmental impact and remediation costs.
In addition, in the embodiment, sensors for assessing whether there is any escape of leach liquor from the reserve are positioned in resource definition holes 3 that are outside the boundary of the reserve.
With reference to Figure 1, the mine includes:
(a) a plurality of resource definition holes 3 that were drilled as part of a resource definition program to establish the hard rock ore body reserve;
(b) a fracturing unit (not shown) configured for fracturing the rock mass of the reserve from the resource definition holes; and
(c) a recovery unit generally identified by the numeral 5 configured for recovering valuable metal from the hard rock ore body reserve by supplying, in this instance, injecting a leach liquor into one group of resource definition holes and removing depleted leach liquor containing dissolved valuable metal from the rock mass from another group of resource definition holes and processing the removed leach liquor and recovering valuable metal.
The mining method includes the following steps:
(a) fracturing the rock mass of the reserve from the resource definition holes 3 that were drilled as part of a resource definition program to establish the hard rock ore body reserve; and
(b) recovering valuable metal from the hard rock ore body reserve by supplying, in this instance, injecting a leach liquor into one group of resource definition holes 3 and removing depleted leach liquor containing dissolved valuable metal from the rock mass from another group of resource definition holes 3 and processing the removed leach liquor and recovering valuable metal, with the resource definition holes 3 covering all or substantially all of the whole area of the reserve.
In the embodiment described in relation to Figure 1, the plurality of resource definition holes 3 have been modified to deliver a hydraulic fluid to the holes 3 to fracture rock mass between the holes 3.
The invention is not confined to the use of hydraulic fluid for fracturing the rock mass and extends to any other suitable options.
Hydraulic fracturing includes positioning well-heads on the resource definition holes 3 and injecting a suitable hydraulic fluid into the holes 3.
International application PCT/AU2021/050932 in the name of the applicant describes a method of hydraulic fracturing a rock mass as part of a method of establishing a block cave mine or extending an existing block cave mine. The hydraulic fracturing steps described in
the international application, whilst for a different purpose, are suitable steps for use in the subject mining method. The disclosure in the international application is incorporated herein by cross reference.
After the hydraulic fracturing has been completed, the resource definition holes 3 are divided into a 1st group of holes (the injection holes 3) for injecting a leach liquor and a 2nd group of holes (the discharge holes 3) for discharging the pregnant leach liquor containing a target valuable metal (in this embodiment, gold or copper) in solution. The 1st and 2nd groups of holes 3 are indicated by the arrows in the Figure. The leach liquor is injected continuously into the 1st group of resource definition holes 3 and depleted leach liquor containing dissolved valuable metal is removed continuously from the 2nd group of resource definition holes.
The leach liquor may be any suitable leach liquor depending on the target valuable metal.
The mine includes a holding tank 11 containing pregnant leach liquor and a network of pipes 7 for delivering leach liquor to the injection holes 3 and a network of pipes 9 for transferring pregnant leach liquor from the discharge holes 3 to the recovery unit 5.
The recovery unit 5 includes:
(a) the holding tank 11 containing pregnant leach liquor,
(b) processing units 13, 15 for separating the target valuable metal from the pregnant liquor and regenerating the leach liquor and adding make-up leach liquor (as may be required), and
(c) a final processing unit 17 for producing separate marketable target valuable metal product.
The processing units 13, 15, 17 may be any suitable processing units depending on the target valuable metal.
The above-described embodiment is one embodiment amongst a number of embodiments in accordance with the invention that include fracturing a hard rock ore body of a reserve and recovering valuable metals from the ore body.
The process of assessing the requirements for any mine and mining method in accordance with the invention includes considering a range of factors, including the following factors.
• Natural porosity and permeability of the ore body itself versus the effort required to liberate via artificial means.
• The ore body texture (veins, brecciated, stockwork etc.).
• The mineral dissemination across the ore body texture.
• Rock mass stability pre-post access creation.
• Target mineral extraction and recovery: o A good understanding of the mineralogy for both target and gangue minerals as this will dictate what chemistries may be applied. o Maximising target mineral extraction and recovery. o Minimising the time to extraction.
• Containment of the applied chemical fluid and metal-enriched pregnant leach liquor: o The hydrogeology of the target area needs to be well understood, including natural fluid flow through the ore body prior to access creation and location of the water table in relation to the target ISR zone. o Any major or minor faulting that may lead to losses need to be identified and assessed to determine whether barrier technology may be a solution or whether they represent fatal flaws in project execution.
• Well design: o Building on hydrogeological understanding to include potential flow paths and travel time from the injection to recovery wells for the ore target and this is influenced by the level of liberation that may be imparted.
Many modifications may be made to the above-described embodiment of a mine and a mining method without departing from the spirit and scope of the invention.
By way of example, the invention is not confined to fracturing a rock mass before supplying the leach liquor to the resource definition holes 3, as described in the embodiment. The invention extends to embodiments in which it is not necessary to fracture a rock mass.
In addition, the invention is not confined to gold and copper as target valuable metals, as described in the embodiment.
In addition, whilst the embodiment injects the leach liquor for the target valuable metal continuously into the 1st group of resource definition holes 3 and removes depleted leach liquor containing dissolved valuable metal continuously from the 2nd group of resource definition holes, the invention is not so limited.
For example, the invention extends to embodiments in which there is periodic supply of leach liquor into the 1st group of resource definition holes 3 and periodic removal of depleted leach liquor containing dissolved valuable metal from the 2nd group of resource definition holes.
Claims
1. A method of in situ recovery of a valuable metal from a hard rock ore body reserve, as described herein, that includes:
(a) supplying a leach liquor into a plurality of resource definition holes that were drilled as part of a resource definition program for a hard rock ore body reserve and dissolving a valuable metal in the rock mass into the leach liquor, with the resource definition holes being located over all or at least a substantial part of an area of the reserve and thereby leaching at least a substantial part of the rock mass in the reserve at the same time;
(b) removing depleted leach liquor containing dissolved valuable metal from the resource definition holes, and
(c) processing the discharged depleted leach liquor containing and recovering the valuable metal.
2. The method defined in claim 1 wherein the substantial part of the reserve includes at least 85% of the area within a boundary of the reserve.
3. The method defined in claim 1 or claim 2 includes supplying the leach liquor into one group of resource definition holes and removing depleted leach liquor containing dissolved valuable metal from another group of resource definition holes.
4. The method defined in claim 1 or claim 2 includes supplying the leach liquor into and removing depleted leach liquor containing dissolved valuable metal from the same resource definition holes.
5. The method defined in any one of the preceding claims includes continuously supplying the leach liquor to the resource definition holes and continuously removing depleted leach liquor containing dissolved valuable metal from the resource definition holes.
6. The method defined in any one of claims 1 to 4 includes periodically supplying the leach liquor to the resource definition holes and periodically removing depleted leach liquor containing dissolved valuable metal from the resource definition holes.
7. The method defined in any one of the preceding claims includes allowing a residence time of at least 2 hours of the leach liquor in the resource definition holes before removing depleted leach liquor containing dissolved valuable metal from the resource definition holes
8. The method defined in any one of the preceding claims includes installing at the resource definition holes facilities for supplying leach liquor and recovering depleted leach liquor containing dissolved valuable metal.
9. The method defined in any one of the preceding claims includes fracturing the rock mass surrounding at least some of the resource definition holes before supplying the liquor into the resource definition holes.
10. The method defined in claim 9 wherein the fracturing step includes fracturing at least substantially all of the volume of rock mass in the reserve.
11. The method defined in claim 9 wherein the fracturing step includes fracturing at least 85% by volume of the rock mass in the reserve.
12. The method defined in any one of the preceding claims includes drilling additional holes to the existing resource definition holes to cover at least the substantial area of the hard body rock mass in the reserve.
13. The method defined in any one of the preceding claims includes regenerating the leach liquor after recovering the valuable metal from the leach liquor/dissolved valuable metal removed from the resource definition holes and returning regenerated leach liquor to the resource definition holes, optionally with make-up leach liquor.
14. The method defined in any one of the preceding claims includes positioning sensors in production holes that are outside the boundary of the reserve and assessing whether there is any escape of leach liquor from the reserve.
15. An in situ recovery mine for recovering a valuable metal from a hard rock ore body reserve that includes:
(a) a plurality of resource definition holes as described herein;
(b) a recovery unit configured for recovering a valuable metal from the hard rock ore body reserve by: i. supplying a leach liquor into a plurality of resource definition holes located over all or at least a substantial part of an area of the reserve and thereby leaching at least a substantial part of the rock mass in the reserve at the same time; ii. removing depleted leach liquor containing dissolved valuable metal from the resource definition holes; and iii. processing the removed leach liquor and recovering the valuable metal.
16. The mine defined in claim 15 wherein the recovery unit is configured to supply leach liquor to and remove depleted leach liquor containing the valuable metal from the same resource definition hole.
17. The mine defined in claim 15 wherein the recovery unit is configured to supply leach liquor to a plurality of the resource definition holes and remove depleted leach liquor containing the valuable metal from another plurality of plurality of the resource definition holes.
18. The mine defined in any one of claims 15 to 17 wherein the recovery unit includes a fracturing unit configured for fracturing the rock mass of the reserve from the resource definition holes.
19. A method of mining a valuable metal from a hard rock ore body reserve that includes: (a) conducting a resource definition program to establish a hard rock ore body reserve, the program including drilling a plurality of resource definition holes and assessing rock samples collected in the program; and (b) the method of in situ recovery of the valuable metal from the hard rock ore body reserve as defined in any one of claims 1 to 14.
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WO (1) | WO2023220785A1 (en) |
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