WO2023198916A1 - Production de carton ou de carton doublure - Google Patents

Production de carton ou de carton doublure Download PDF

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Publication number
WO2023198916A1
WO2023198916A1 PCT/EP2023/059830 EP2023059830W WO2023198916A1 WO 2023198916 A1 WO2023198916 A1 WO 2023198916A1 EP 2023059830 W EP2023059830 W EP 2023059830W WO 2023198916 A1 WO2023198916 A1 WO 2023198916A1
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WO
WIPO (PCT)
Prior art keywords
furnish
dry weight
pulp
middle layer
layer
Prior art date
Application number
PCT/EP2023/059830
Other languages
English (en)
Inventor
Fredrik Nordström
Original Assignee
Billerud Aktiebolag (Publ)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Billerud Aktiebolag (Publ) filed Critical Billerud Aktiebolag (Publ)
Publication of WO2023198916A1 publication Critical patent/WO2023198916A1/fr

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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10—Packing paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • D21F11/02—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines of the Fourdrinier type
    • D21F11/04—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines of the Fourdrinier type paper or board consisting on two or more layers
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F3/00—Press section of machines for making continuous webs of paper
    • D21F3/02—Wet presses
    • D21F3/0209—Wet presses with extended press nip
    • D21F3/0218—Shoe presses
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/02—Chemical or chemomechanical or chemothermomechanical pulp
    • D21H11/04—Kraft or sulfate pulp
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/08—Mechanical or thermomechanical pulp
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/10—Mixtures of chemical and mechanical pulp
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/14—Secondary fibres
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30—Multi-ply
    • D21H27/38—Multi-ply at least one of the sheets having a fibrous composition differing from that of other sheets

Definitions

  • the present disclosure relates to the field of production of paper- and linerboard.
  • a machine for producing multi-layered paper- or linerboard has different sections.
  • furnishes are prepared from pulps and additives (added to improve properties such as retention, dewatering and strength).
  • a multi-layered web is then formed from the furnishes.
  • the multi-layered web is dewatered in the press section and dried in the drying section. Downstream the drying section, the multilayered web may be coated and/ or calendered. When the multilayered web is both coated and calendered, calendering can be carried out upstream or downstream the coating step(s) or even between coating steps.
  • the pulps that can be used in the paperboard machine include virgin pulps, recycled pulps (i.e. pulps prepared from recycled paper and/or paperboard) and broke pulps (pulps of fibres recycled from downstream portions of the same process). Further, virgin pulps are typically divided into chemical pulps and mechanical pulps. Sulfate (kraft) pulp and sulfite pulp are examples of chemical pulp. Groundwood pulp, thermomechanical pulp (TMP) and chemi-thermomechanical pulp (CTMP) are examples of mechanical pulp. All these pulps can be made from hardwood, softwood or mixtures thereof. Further, the pulps can be bleached or unbleached.
  • virgin pulps are typically divided into chemical pulps and mechanical pulps.
  • Sulfate (kraft) pulp and sulfite pulp are examples of chemical pulp.
  • Groundwood pulp, thermomechanical pulp (TMP) and chemi-thermomechanical pulp (CTMP) are examples of mechanical pulp. All these pulps can be made from hardwood, softwood or mixtures thereof. Further, the pulps can be
  • a furnish for a particular layer typically comprise a mixture of different pulps.
  • the properties of the final board product are not only a result of the pulp mixture of each furnish; they also depend on the degree of refining of the pulps, the types and amounts of additives and other operating conditions.
  • the process for making paperboard cannot be designed with only the final properties in mind; runnability in the paper machine and energy consumption must also be taken into consideration.
  • the present disclosure aims to provide an efficient method of producing a paper- or linerboard of satisfactory properties.
  • the present disclosure provides a method of producing a paper- or linerboard having a grammage measured according to ISO 536:2019 of 170- 310 g/m 2 and comprising a print layer, a middle layer and a back layer, wherein the middle layer is formed from a middle layer furnish comprising at least 25% by dry weight CTMP and the back layer is formed from a back layer furnish comprising an unbleached pulp, such as an unbleached kraft pulp, said method comprising the step of subjecting a multi-layered web at a speed of at least 600 m/min to pressing in a press section comprising a first and a second double-felted shoe press nip arranged in series, wherein the total press impulse of the double-felted shoe press nips is at least 95 kPa*s, preferably at least 100 kPa*s.
  • this press impulse is high, which increases the press dryness (i.e. the dryness of the multilayered web exiting the press section). As a result, less steam is consumed in the drying section.
  • the skilled person making paperboard is often reluctant to use high press impulses as they can densify the web to such an extent that inferior bending stiffness is obtained.
  • the selection of an unbleached pulp for the back layer furnish and the inclusion of CTMP in the middle layer furnish make the web of the method of the present disclosure relatively insensitive to high press impulses.
  • the press dryness is further increased by both shoe press nips being double-felted.
  • the present disclosure provides a method of producing a paper- or linerboard having a grammage measured according to ISO 536:2019 of 170-310 g/m 2 .
  • the paper- or linerboard comprises a print layer, a middle layer and a back layer.
  • the paper- or linerboard comprises more than one middle layer.
  • the middle layer is formed from a middle layer furnish comprising at least 25% by dry weight CTMP.
  • each middle layer furnish preferably comprise at least 25% by dry weight CTMP.
  • the CTMP of the middle layer(s) preferably has a Canadian Standard Freeness (CSF) measured according to ISO 5267-2:2001 of 525-625 ml, such as 550-600 ml. To reach such a CSF, the CTMP maybe subjected to refining. If the CSF is too low, dewatering is impaired and density increases. If the CSF is too high, strength properties may be insufficient.
  • CSF Canadian Standard Freeness
  • the middle layer furnish comprises at least 30% by dry weight CTMP, preferably at least 35% by dry weight CTMP, such as at least 40% by dry weight CTMP.
  • the middle layer furnish may comprise at least 20% by dry weight broke pulp, such as at least 30% by dry weight broke pulp.
  • the broke pulp of the middle layer furnish preferably has a Schopper-Riegler number (°SR) of less than 35 (such as 26-34), more preferably less than 33 (such as 27-32).
  • °SR is measured according to ISO 5267-1:1999.
  • the CTMP and the broke pulp together constitute at least 65% by dry weight of the middle layer furnish, such as at least 75% by dry weight of the middle furnish.
  • the middle layer furnish may further comprises kraft pulp, such as softwood kraft pulp.
  • This kraft pulp may have a relatively low °SR, such as 18-25, preferably 18-23.
  • the head box consistency of the middle layer furnish may be 0.15% -
  • the back layer is formed from a back layer furnish comprising an unbleached pulp, such as an unbleached chemical pulp, preferably an unbleached kraft pulp.
  • the unbleached pulp of the back layer preferably has a °SR of 19-26, such as 20-25. To reach such a °SR, the unbleached pulp maybe subjected to refining. If the °SR is too high, dewatering is impaired. If the °SR is too low, strength properties may be insufficient.
  • the unbleached pulp of the back layer is typically a softwood pulp.
  • the back layer furnish comprises at least 50% by dry weight of the unbleached pulp, such as at least 60% by dry weight of the unbleached pulp.
  • the back layer furnish may comprise broke pulp.
  • the broke pulp of the back layer furnish preferably has a °SR of less than 35 (such as 26-34), more preferably less than 33 (such as 27-32). To reach such a °SR, the broke pulp maybe subjected to refining.
  • the unbleached pulp and broke pulp together constitute at least 80 % by dry weight of the back layer furnish, such as at least 90 % by dry weight of the back layer furnish.
  • the head box consistency of the back layer furnish may be 0.12% - 0.25%.
  • the print layer furnish preferably comprises a mixture of hardwood kraft pulp and softwood kraft pulp, such as a mixture of bleached hardwood kraft pulp and bleached softwood kraft pulp. However, the print layer may also be unbleached.
  • Each of the kraft pulps of print layer furnish preferably has a °SR of 21-29.
  • the kraft pulps are typically subjected to refining.
  • hardwood kraft pulp and softwood kraft pulp together constitute at least 80% by dry weight of the print layer furnish, such as at least 90% by dry weight of the print layer furnish.
  • the head box consistency of the print layer furnish may be 0.12% - 0.25%.
  • the above-mentioned furnishes form a multi-layered web in a forming section.
  • a top former may be arranged to aid the dewatering of the middle layer in the forming section.
  • the formation of the middle layer preferably comprises the use of a breast roll shaker.
  • the method of the present disclosure comprises the step of subjecting the multi-layered web to pressing in a press section at a speed of at least 600 m/min, such as at least 650 m/min, such as at least 700 m/min, such as at least 750 m/min.
  • the press section comprises a first and a second double-felted shoe press nip arranged in series.
  • the second double-felted shoe press nip is arranged downstream the first double-felted shoe press nip.
  • the line load of the second double-felted shoe press nip is higher than the line load of the first double-felted shoe press nip.
  • the total press impulse of the double-felted shoe press nips is at least 95 kPa*s, preferably at least 100 kPa*s.
  • An upper limit maybe 150 kPa*s or 200 kPa*s
  • the speed of the multi-layered web is typically lower, which means that the press impulse can be higher, e.g. at least 105 kPa*s, such as at least no kPa*s.
  • the press section comprises a further nip arranged downstream the double-felted shoe press nips.
  • the further nip is preferably a non-felted nip or a single-felted nip, such as a non-felted hard nip or a single-felted shoe press nip.
  • its line load may be in the range of 25-100 kN/m, such as 30-75 kN/m, such as 30-60 kN/m.
  • the main purpose of such a hard nip is to smoothen the print side, which was in contact with a felt in the first and the second double-felted shoe press nip.
  • the felt is preferably contacting the back side.
  • the single-felted shoe press nip not only further dewaters the web, it also smoothens the print side, which - as mentioned above - was in contact with a felt in the first and the second double-felted shoe press nip.
  • the print layer of the paper- or linerboard may be coated with a composition comprising at least one pigment and at least one binder.
  • the method of the present disclosure may further comprise a coating step.
  • the coating step may comprise a plurality of substeps, each applying a sublayer.
  • the total amount (dry weight) of coating applied in the coating step is preferably at least 8 g/m 2 , such as 8-32 g/m 2 , such as 11-30 g/m 2 .
  • the print side of the paper- or linerboard of the present disclosure may have a PPS 1.0 roughness of below 2.0 pm, such as below 1.8 pm.
  • a lower limit for this PPS 1.0 roughness maybe 0.8 pm.
  • PPS 1.0 roughness is measured according to ISO 8791-4:2013 (soft backing & 1000 kPa clamping pressure).
  • the paper- or linerboard Prior to the coating step (but after the drying section), the paper- or linerboard is preferably subjected to calendering to improve the coatability.
  • calendering is preferably hard nip calendering, which may be carried out at an elevated temperature.
  • the surface temperature of a heated roll of the hard nip calender maybe in the range of 100-250 °C.
  • the method of the present disclosure comprises no calendering step after the coating step, which typically saves bulk.
  • the density of the paper- or linerboard of the present disclosure may be below 810 kg/m3. If not coated with a pigment coating, the density maybe below 800 kg/m3. In the present disclosure, density is measured according to ISO 534:2011.
  • a three-layer white-top linerboard was produced in a full-scale paperboard machine.
  • the layer design of the WTL was as follows: a print layer (58 g/m 2 ), a back layer (45 g/m 2 ), a middle layer (77 g/m 2 ) and a pigment coating (20 g/m 2 , applied onto the print layer).
  • NBHK bleached hardwood kraft pulp
  • NBSK bleached softwood kraft pulp
  • LC refining 50 and 120 kWh/ tonne, respectively
  • rosin size 0.5 kg/tonne
  • strength agent cationic starch, 5 kg/tonne
  • retention starch 3 kg/tonne
  • retention polymer 75 g/tonne
  • silica 300 g/tonne
  • clay 55 kg/tonne
  • UBK unbleached softwood kraft pulp
  • broke pulp were mixed in a 75:25 dry weight ratio.
  • AKD 0.5 kg/tonne
  • alum 0.4 kg/tonne
  • strength agent cationic starch, 5 kg/tonne
  • retention starch 3 kg/tonne
  • retention polymer 75 g/tonne
  • silica 300 g/tonne
  • a middle layer furnish broke pulp, NBSK and CTMP were mixed in a 45:10:45 dry weight ratio. Before the mixing, the pulps were subjected to LC refining to obtain the following values: °SR 30 for the broke pulp; °SR 20 for the NBSK and CSF 580 ml for the CTMP.
  • AKD 0.5 g/tonne
  • alum 0.3 g/tonne
  • strength agent cationic starch, 4 kg/tonne
  • retention starch 3 kg/tonne
  • retention polymer 150 g/tonne
  • silica silica
  • the wire section 0.7 g/m 2 starch was sprayed to each of the print layer web and the back layer web for ply-bond strength.
  • the three individual webs were couched together to form a three-layered web.
  • the three-layered web was pressed in three nips; a first double-felted shoe press nip followed by a second double-felted shoe press nip and a hard nip.
  • the line load of the first double-felted shoe press nip was 656 kN/m.
  • the line load of the second double-felted shoe press nip was 828 kN/m.
  • the line load of the hard nip was 50 kN/m.
  • the web speed in the press section was 854 m/min, which means that the press impulse of the whole press section was 108 kPa*s and that the total press impulse of the double-felted shoe press nips was 104 kPa*s.
  • the three-layered web was dried in a drying section (the steam consumption in this section was relatively low), subjected to calendering and then coated in a coating section according to the following: in a first blade coater, 8.5 g/m 2 of a pigment coating composition was applied to the surface of the print layer to form a first coating layer; and in a second blade coater, 11.5 g/m 2 of a pigment coating composition was applied to the first coating layer to form a second coating layer.
  • the total (dry) coat weight on the print layer surface was 20 g/m 2 .
  • a very small amount ( ⁇ o.3 g/m 2 ) of starch was applied to the surface of the back layer in the coating section.
  • Table 1 means machine direction. “CD” means cross direction”. “GM” means geometrical. “PS” means print side. “BS” means back side.
  • Process data was collected from the production of three-layered liquid packaging board (LPB) over a period of about ten months.
  • the production was carried out in the same paperboard machine as described in example 1 above, which means that a three-layered web was pressed in three nips: a first double-felted shoe press nip followed by a second double-felted shoe press nip and a hard nip.
  • the production included coating (using two blade coaters) of the print layer with 7.5 + 11.5 g/m 2 of pigment coating composition.
  • the back layer was coated with 0.4 g/m 2 of starch. Prior to coating, the three-layered web was subjected to calendering.
  • the grammage (gsm) was about 70 g/m 2 for the print layer and about 50 g/m 2 for the back layer.
  • starch was sprayed to each of the print layer web and the back layer web for ply-bond strength.
  • the data was clustered into two blocks of data: one block in which the total press impulse (PI) in the double-felted shoe press nips was at least 95 kPa*s and another block in which the press impulse in the double-felted shoe press nips was below 95 kPa*s. Further details are provided in tables 2 and 3 below.
  • the average °SR values of the pulps of the low PI block in table 2 are as follows: 25.6 for the PL BSKP; 28.9 for the PL BHKP; 26.4 for the ML BP; 17.4 for the ML BSKP; and 22.7 for the BL UB.
  • the average CSF value of the ML CTMP of the low PI block was 612.5 ml.
  • the average °SR values of the pulps of the high PI block in table 2 are as follows: 25.3 for the PL BSKP; 28.7 for the PL BHKP; 27.5 for the ML BP; 17.8 for the ML BSKP; and 22.0 for the BL UB.
  • the average CSF value of the ML CTMP of the high PI block was 596.5 ml.
  • Table 3 Median values from the “high PI” (> 95 kPa*s) block and the “low PI” ( ⁇ 95 kPa*s) block.
  • the low PI block is represented by the upper row and the high PI block is represented by the lower row.
  • Both blocks had the same median bulk (1.42 cm3/g) and the same median bending resistance index (12.6 Nm 6 /kg3). The abbreviations are explained in table 1.
  • the median °SR values of the pulps of the low PI block in table 3 are as follows: 25.4 for the PL BSKP; 28.9 for the PL BHKP; 26.5 for the ML BP; 17.6 for the ML BSKP; and 22.7 for the BL UB.
  • the median CSF value of the ML CTMP of the low PI block was 611.8 ml.
  • the median °SR values of the pulps of the high PI block in table 3 are as follows: 25.2 for the PL BSKP; 28.6 for the PL BHKP; 27.5 for the ML BP; 17.9 for the ML BSKP; and 22.0 for the BL UB.
  • the median CSF value of the ML CTMP of the high PI block was 592.1 ml.
  • the median Bendtsen roughness of the print layer was 131 ml/min when the median press impulse over the shoe presses was 93 kPa*s and no ml/min when the median press impulse over the shoe presses was 98 kPa*s. If average values are instead considered, about the same results are obtained (see table 2). Further, an increased press impulse reduces the print layer PPS according to tables 2 and 3. The press impulse increase is thus connected to improved surface properties of the print layer.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Paper (AREA)

Abstract

L'invention concerne un procédé de production d'un carton ou d'un carton doublure dont le grammage de 170 à 310 g/m2 est mesuré conformément à la norme ISO 536 : 2019 et comprenant une couche d'impression, une couche intermédiaire et une couche de fond, la couche intermédiaire étant formée à partir d'un support comprenant au moins 25 % en poids sec de pâte chimico-thermomécanique (PCTM) et la couche de fond étant formée à partir d'un support comprenant une pâte écrue, telle qu'une pâte à papier kraft écrue, ledit procédé comprenant une étape consistant à soumettre une feuille multicouche à une vitesse d'au moins 600 m/min à un pressage dans une section de presse comprenant une première et une seconde pince de presse à sabot doublement feutrée disposées en série, l'impulsion de pressage totale des pinces de presse à sabot doublement feutrées étant d'au moins 95 kPa*s, de préférence d'au moins 100 kPa*s.
PCT/EP2023/059830 2022-04-14 2023-04-14 Production de carton ou de carton doublure WO2023198916A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP22168616.5 2022-04-14
EP22168616.5A EP4261346A1 (fr) 2022-04-14 2022-04-14 Production de papier ou de carton doublure

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Publication Number Publication Date
WO2023198916A1 true WO2023198916A1 (fr) 2023-10-19

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080053634A1 (en) * 2004-07-12 2008-03-06 Voith Patent Gmbh Method for the Application of an Application Medium and Method and Machine for Production of a Fiber Web
CN106948208A (zh) * 2017-03-09 2017-07-14 华南理工大学 一种环保低定量灰底白板纸及其制备方法
CN110904734A (zh) * 2019-12-11 2020-03-24 亚太森博（山东）浆纸有限公司 一种暗纹防伪纸板的制备方法
EP3739115A1 (fr) * 2019-05-14 2020-11-18 BillerudKorsnäs AB Production optimisée d'un carton-caisse destiné à être utilisé en tant que cannelure
DE102019116602A1 (de) * 2019-06-19 2020-12-24 Voith Patent Gmbh Maschine zur herstellung einer faserstoffbahn
WO2021124040A1 (fr) * 2019-12-19 2021-06-24 Stora Enso Oyj Carton double léger pour un carton ondulé
US20210221114A1 (en) * 2018-06-27 2021-07-22 Stora Enso Oyj Ply of a linerboard and a light weight linerboard for corrugated board

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080053634A1 (en) * 2004-07-12 2008-03-06 Voith Patent Gmbh Method for the Application of an Application Medium and Method and Machine for Production of a Fiber Web
CN106948208A (zh) * 2017-03-09 2017-07-14 华南理工大学 一种环保低定量灰底白板纸及其制备方法
US20210221114A1 (en) * 2018-06-27 2021-07-22 Stora Enso Oyj Ply of a linerboard and a light weight linerboard for corrugated board
EP3739115A1 (fr) * 2019-05-14 2020-11-18 BillerudKorsnäs AB Production optimisée d'un carton-caisse destiné à être utilisé en tant que cannelure
DE102019116602A1 (de) * 2019-06-19 2020-12-24 Voith Patent Gmbh Maschine zur herstellung einer faserstoffbahn
CN110904734A (zh) * 2019-12-11 2020-03-24 亚太森博（山东）浆纸有限公司 一种暗纹防伪纸板的制备方法
WO2021124040A1 (fr) * 2019-12-19 2021-06-24 Stora Enso Oyj Carton double léger pour un carton ondulé

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