WO2023143826A1 - Matériau aggloméré artificiel amélioré - Google Patents
Matériau aggloméré artificiel amélioré Download PDFInfo
- Publication number
- WO2023143826A1 WO2023143826A1 PCT/EP2022/086889 EP2022086889W WO2023143826A1 WO 2023143826 A1 WO2023143826 A1 WO 2023143826A1 EP 2022086889 W EP2022086889 W EP 2022086889W WO 2023143826 A1 WO2023143826 A1 WO 2023143826A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- silane
- agglomerated
- resin
- group
- composition
- Prior art date
Links
- 239000000463 material Substances 0.000 title claims abstract description 145
- 239000000203 mixture Substances 0.000 claims abstract description 227
- 229920005989 resin Polymers 0.000 claims abstract description 116
- 239000011347 resin Substances 0.000 claims abstract description 116
- 239000011256 inorganic filler Substances 0.000 claims abstract description 76
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 76
- 238000004519 manufacturing process Methods 0.000 claims abstract description 41
- 238000000034 method Methods 0.000 claims abstract description 26
- 239000007822 coupling agent Substances 0.000 claims abstract description 22
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 65
- 229910000077 silane Inorganic materials 0.000 claims description 65
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 50
- -1 di-isobutoxy-diacetoxysilane Chemical compound 0.000 claims description 38
- 229920006337 unsaturated polyester resin Polymers 0.000 claims description 30
- 235000012239 silicon dioxide Nutrition 0.000 claims description 29
- 125000000524 functional group Chemical group 0.000 claims description 18
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 18
- 229920002554 vinyl polymer Polymers 0.000 claims description 16
- 125000001424 substituent group Chemical group 0.000 claims description 15
- 229920000178 Acrylic resin Polymers 0.000 claims description 13
- 239000004925 Acrylic resin Substances 0.000 claims description 13
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 13
- 125000003545 alkoxy group Chemical group 0.000 claims description 12
- 229910002026 crystalline silica Inorganic materials 0.000 claims description 12
- 239000003822 epoxy resin Substances 0.000 claims description 12
- 229920000647 polyepoxide Polymers 0.000 claims description 12
- 229910052710 silicon Inorganic materials 0.000 claims description 12
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical group CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 8
- 150000008064 anhydrides Chemical group 0.000 claims description 8
- BKLZXRZFFSHLOS-UHFFFAOYSA-N [acetyloxy-bis(phenylmethoxy)silyl] acetate Chemical compound C=1C=CC=CC=1CO[Si](OC(C)=O)(OC(=O)C)OCC1=CC=CC=C1 BKLZXRZFFSHLOS-UHFFFAOYSA-N 0.000 claims description 7
- OPARTXXEFXPWJL-UHFFFAOYSA-N [acetyloxy-bis[(2-methylpropan-2-yl)oxy]silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)(C)C)OC(C)(C)C OPARTXXEFXPWJL-UHFFFAOYSA-N 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 238000005266 casting Methods 0.000 claims description 5
- 239000004593 Epoxy Chemical group 0.000 claims description 4
- LZMNXXQIQIHFGC-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propyl 2-methylprop-2-enoate Chemical group CO[Si](C)(OC)CCCOC(=O)C(C)=C LZMNXXQIQIHFGC-UHFFFAOYSA-N 0.000 claims description 2
- URDOJQUSEUXVRP-UHFFFAOYSA-N 3-triethoxysilylpropyl 2-methylprop-2-enoate Chemical group CCO[Si](OCC)(OCC)CCCOC(=O)C(C)=C URDOJQUSEUXVRP-UHFFFAOYSA-N 0.000 claims description 2
- NFKAUBUPKYTUPR-UHFFFAOYSA-N [acetyloxy(dibenzyl)silyl] acetate Chemical compound C=1C=CC=CC=1C[Si](OC(C)=O)(OC(=O)C)CC1=CC=CC=C1 NFKAUBUPKYTUPR-UHFFFAOYSA-N 0.000 claims description 2
- CNOSLBKTVBFPBB-UHFFFAOYSA-N [acetyloxy(diphenyl)silyl] acetate Chemical compound C=1C=CC=CC=1[Si](OC(C)=O)(OC(=O)C)C1=CC=CC=C1 CNOSLBKTVBFPBB-UHFFFAOYSA-N 0.000 claims description 2
- BZWVEBHXQQJABL-UHFFFAOYSA-N [acetyloxy(ditert-butyl)silyl] acetate Chemical compound CC(=O)O[Si](C(C)(C)C)(C(C)(C)C)OC(C)=O BZWVEBHXQQJABL-UHFFFAOYSA-N 0.000 claims description 2
- UYEHMPJXRDHGGY-UHFFFAOYSA-N [acetyloxy-bis(2-methylpropyl)silyl] acetate Chemical compound CC(C)C[Si](CC(C)C)(OC(C)=O)OC(C)=O UYEHMPJXRDHGGY-UHFFFAOYSA-N 0.000 claims description 2
- VVEUPQPNIPCUAP-UHFFFAOYSA-N [acetyloxy-di(propan-2-yl)silyl] acetate Chemical compound CC(=O)O[Si](C(C)C)(OC(C)=O)C(C)C VVEUPQPNIPCUAP-UHFFFAOYSA-N 0.000 claims description 2
- ZCDBRVXGHZHBIX-UHFFFAOYSA-N [acetyloxy-di(propan-2-yloxy)silyl] acetate Chemical compound CC(C)O[Si](OC(C)C)(OC(C)=O)OC(C)=O ZCDBRVXGHZHBIX-UHFFFAOYSA-N 0.000 claims description 2
- RMKZLFMHXZAGTM-UHFFFAOYSA-N [dimethoxy(propyl)silyl]oxymethyl prop-2-enoate Chemical group CCC[Si](OC)(OC)OCOC(=O)C=C RMKZLFMHXZAGTM-UHFFFAOYSA-N 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- 150000004756 silanes Chemical class 0.000 abstract description 20
- 239000002245 particle Substances 0.000 description 44
- 238000006460 hydrolysis reaction Methods 0.000 description 20
- 239000010433 feldspar Substances 0.000 description 19
- 239000008187 granular material Substances 0.000 description 19
- 230000007062 hydrolysis Effects 0.000 description 19
- 239000011521 glass Substances 0.000 description 18
- 239000010453 quartz Substances 0.000 description 17
- 150000001875 compounds Chemical class 0.000 description 15
- 239000004575 stone Substances 0.000 description 15
- 238000001723 curing Methods 0.000 description 13
- 229910052906 cristobalite Inorganic materials 0.000 description 12
- 239000000523 sample Substances 0.000 description 12
- 229910052500 inorganic mineral Inorganic materials 0.000 description 11
- 239000011707 mineral Substances 0.000 description 11
- 239000000654 additive Substances 0.000 description 10
- 239000003054 catalyst Substances 0.000 description 10
- 229910052708 sodium Inorganic materials 0.000 description 10
- 239000011734 sodium Substances 0.000 description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 239000000945 filler Substances 0.000 description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
- 239000000049 pigment Substances 0.000 description 8
- 125000004423 acyloxy group Chemical group 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 150000002978 peroxides Chemical class 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000003086 colorant Substances 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 238000005498 polishing Methods 0.000 description 6
- 230000032683 aging Effects 0.000 description 5
- 239000002969 artificial stone Substances 0.000 description 5
- 238000005253 cladding Methods 0.000 description 5
- 238000005056 compaction Methods 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 239000000428 dust Substances 0.000 description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
- 230000006872 improvement Effects 0.000 description 5
- 238000011002 quantification Methods 0.000 description 5
- 239000005368 silicate glass Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 4
- 125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 239000005388 borosilicate glass Substances 0.000 description 4
- 238000004737 colorimetric analysis Methods 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 238000005034 decoration Methods 0.000 description 4
- 238000000227 grinding Methods 0.000 description 4
- 229910010272 inorganic material Inorganic materials 0.000 description 4
- 239000011147 inorganic material Substances 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 3
- 238000003991 Rietveld refinement Methods 0.000 description 3
- 239000012963 UV stabilizer Substances 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 238000004873 anchoring Methods 0.000 description 3
- 239000004599 antimicrobial Substances 0.000 description 3
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 150000001868 cobalt Chemical class 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000006254 rheological additive Substances 0.000 description 3
- 125000005372 silanol group Chemical group 0.000 description 3
- 150000004760 silicates Chemical class 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 description 3
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229910052656 albite Inorganic materials 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 239000012237 artificial material Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 239000010431 corundum Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000006063 cullet Substances 0.000 description 2
- ZXPDYFSTVHQQOI-UHFFFAOYSA-N diethoxysilane Chemical compound CCO[SiH2]OCC ZXPDYFSTVHQQOI-UHFFFAOYSA-N 0.000 description 2
- YQGOWXYZDLJBFL-UHFFFAOYSA-N dimethoxysilane Chemical compound CO[SiH2]OC YQGOWXYZDLJBFL-UHFFFAOYSA-N 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- SACPKRUZWRIEBW-UHFFFAOYSA-N dipropoxysilane Chemical compound CCCO[SiH2]OCCC SACPKRUZWRIEBW-UHFFFAOYSA-N 0.000 description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
- 239000010459 dolomite Substances 0.000 description 2
- 229910000514 dolomite Inorganic materials 0.000 description 2
- 239000011439 engineered stone Substances 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- 239000010438 granite Substances 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 239000002655 kraft paper Substances 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 238000000634 powder X-ray diffraction Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000011435 rock Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- OZWKZRFXJPGDFM-UHFFFAOYSA-N tripropoxysilane Chemical compound CCCO[SiH](OCCC)OCCC OZWKZRFXJPGDFM-UHFFFAOYSA-N 0.000 description 2
- 229920006305 unsaturated polyester Polymers 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 1
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 1
- XYQHCDPZBXIAGW-UHFFFAOYSA-N Andesine Natural products COC(=O)C1=Cc2ccc3c(CCN(C)C)cc(OC)c(O)c3c2C(=O)O1 XYQHCDPZBXIAGW-UHFFFAOYSA-N 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 240000007108 Fuchsia magellanica Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- 201000010001 Silicosis Diseases 0.000 description 1
- 229920004482 WACKER® Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 229910052650 alkali feldspar Inorganic materials 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 description 1
- 229910052658 andesine Inorganic materials 0.000 description 1
- 229910052661 anorthite Inorganic materials 0.000 description 1
- 229910052653 anorthoclase Inorganic materials 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229910052660 bytownite Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 235000019646 color tone Nutrition 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- GWWPLLOVYSCJIO-UHFFFAOYSA-N dialuminum;calcium;disilicate Chemical compound [Al+3].[Al+3].[Ca+2].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] GWWPLLOVYSCJIO-UHFFFAOYSA-N 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 229910052647 feldspar group Inorganic materials 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 238000001033 granulometry Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 125000001145 hydrido group Chemical group *[H] 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000016507 interphase Effects 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 229910052659 labradorite Inorganic materials 0.000 description 1
- 239000011018 labradorite Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052651 microcline Inorganic materials 0.000 description 1
- 230000003278 mimic effect Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229910052657 oligoclase Inorganic materials 0.000 description 1
- 229910052652 orthoclase Inorganic materials 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000019612 pigmentation Effects 0.000 description 1
- 229910052655 plagioclase feldspar Inorganic materials 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 206010035653 pneumoconiosis Diseases 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000010817 post-consumer waste Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000001144 powder X-ray diffraction data Methods 0.000 description 1
- 239000010864 pre-consumer waste Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052654 sanidine Inorganic materials 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010420 shell particle Substances 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 150000004819 silanols Chemical class 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 125000004213 tert-butoxy group Chemical group [H]C([H])([H])C(O*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000001973 tert-pentyl group Chemical group [H]C([H])([H])C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000004684 trihydrates Chemical class 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/40—Compounds containing silicon, titanium or zirconium or other organo-metallic compounds; Organo-clays; Organo-inorganic complexes
- C04B24/42—Organo-silicon compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/18—Polyesters; Polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
- C04B2111/542—Artificial natural stone
Definitions
- the inorganic filler in the agglomerated composition or material may be natural, synthetic or a mixture thereof.
- suitable inorganic fillers include stone, mineral, vitreous and/or ceramic materials, such as quartz, glass (e.g. silicate glass, borosilicate glass, sodium borosilicate glass, glass frit), silica sand, feldspathic sand, feldspar, granite, calcite, basalt, natural or synthetic cristobalite, dolomite, mirror, ceramics, glassceramics, and mixtures thereof.
- the agglomerated composition or material may comprise at least 10 wt.% glass, or at least 20 wt.% glass, as inorganic filler, based on the weight of the agglomerated composition or material.
- the agglomerated composition or material comprises 10-70 wt.%, preferably 10-60 wt.%, of glass as inorganic filler, based on the weight of the agglomerated composition or material.
- composition or material according to the present invention does not comprise other silanes different from Silane A and Silane B.
- the (unhardened) agglomerated composition obtained after step i) can then be conveyed from the mixers to a distributing device.
- Suitable distributors are known, such as those used for the distribution of (non-hardened) agglomerated mixtures in the manufacture of quartz agglomerated surfaces.
- This distributing device is preferably movable along the length of a temporary mold or a support sheet.
- the distributor device deposits the composition in the temporary mold or on the support sheet, forming with the (unhardened) composition a preform corresponding to the shape of the agglomerated material or article to be produced, with a slight excess in dimensions to compensate for possible shrinkage occurring during compaction and hardening.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2022436753A AU2022436753A1 (en) | 2022-01-27 | 2022-12-20 | Improved artificial agglomerated material |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP22382067 | 2022-01-27 | ||
EP22382067.1 | 2022-01-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2023143826A1 true WO2023143826A1 (fr) | 2023-08-03 |
Family
ID=80682554
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2022/086889 WO2023143826A1 (fr) | 2022-01-27 | 2022-12-20 | Matériau aggloméré artificiel amélioré |
Country Status (2)
Country | Link |
---|---|
AU (1) | AU2022436753A1 (fr) |
WO (1) | WO2023143826A1 (fr) |
Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4204820A (en) | 1977-04-22 | 1980-05-27 | Marcello Toncelli | Slab forming conveying line |
US4220748A (en) * | 1978-03-30 | 1980-09-02 | Toshiba Silicone Co., Ltd. | Room temperature curable polysiloxane composition |
JPS5811560A (ja) * | 1981-07-15 | 1983-01-22 | Toray Ind Inc | 被覆組成物 |
EP1893678A1 (fr) | 2005-06-23 | 2008-03-05 | E.I. Dupont De Nemours And Company | Compositions polymerisables contenant une charge solide, articles ainsi formes et leurs procedes de formation |
US20120283087A1 (en) | 2008-08-25 | 2012-11-08 | Wesley Moore | Synthetic quartz composition and production process therefor |
CN107879676A (zh) | 2017-11-06 | 2018-04-06 | 佛山市欧泊石业有限公司 | 一种高冲击韧性人造石英石板材 |
WO2018185552A1 (fr) | 2017-04-07 | 2018-10-11 | N-Tec Gmbh | Procédé de production de pierre artificielle |
WO2021018996A1 (fr) | 2019-07-31 | 2021-02-04 | Cosentino Research & Development, S.L. | Article en pierre agglomérée artificielle comprenant des granulés de silicate synthétiques |
WO2021019020A1 (fr) | 2019-07-31 | 2021-02-04 | Cosentino Research & Development, S.L. | Article en pierre agglomérée artificielle comprenant des granulés de silicate synthétique |
WO2021069464A1 (fr) | 2019-10-08 | 2021-04-15 | Cosentino Research & Development, S.L. | Article en pierre agglomérée artificielle comprenant des granules de feldspath |
US20210238417A1 (en) * | 2018-04-19 | 2021-08-05 | Wacker Chemie Ag | Polysiloxane composition |
WO2021190751A1 (fr) * | 2020-03-26 | 2021-09-30 | Wacker Chemie Ag | Composition de pierre artificielle comprenant un alpha-silane comme agent adhésif |
US20210383942A1 (en) * | 2020-06-03 | 2021-12-09 | Eikem Silicones USA Corp. | Method and compositions to achieve long-term stable electrical conductivity in silicone material with carbon black as conductive fillers |
-
2022
- 2022-12-20 WO PCT/EP2022/086889 patent/WO2023143826A1/fr active Application Filing
- 2022-12-20 AU AU2022436753A patent/AU2022436753A1/en active Pending
Patent Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4204820A (en) | 1977-04-22 | 1980-05-27 | Marcello Toncelli | Slab forming conveying line |
US4220748A (en) * | 1978-03-30 | 1980-09-02 | Toshiba Silicone Co., Ltd. | Room temperature curable polysiloxane composition |
JPS5811560A (ja) * | 1981-07-15 | 1983-01-22 | Toray Ind Inc | 被覆組成物 |
EP1893678A1 (fr) | 2005-06-23 | 2008-03-05 | E.I. Dupont De Nemours And Company | Compositions polymerisables contenant une charge solide, articles ainsi formes et leurs procedes de formation |
US20120283087A1 (en) | 2008-08-25 | 2012-11-08 | Wesley Moore | Synthetic quartz composition and production process therefor |
WO2018185552A1 (fr) | 2017-04-07 | 2018-10-11 | N-Tec Gmbh | Procédé de production de pierre artificielle |
CN107879676A (zh) | 2017-11-06 | 2018-04-06 | 佛山市欧泊石业有限公司 | 一种高冲击韧性人造石英石板材 |
US20210238417A1 (en) * | 2018-04-19 | 2021-08-05 | Wacker Chemie Ag | Polysiloxane composition |
WO2021018996A1 (fr) | 2019-07-31 | 2021-02-04 | Cosentino Research & Development, S.L. | Article en pierre agglomérée artificielle comprenant des granulés de silicate synthétiques |
WO2021019020A1 (fr) | 2019-07-31 | 2021-02-04 | Cosentino Research & Development, S.L. | Article en pierre agglomérée artificielle comprenant des granulés de silicate synthétique |
WO2021069464A1 (fr) | 2019-10-08 | 2021-04-15 | Cosentino Research & Development, S.L. | Article en pierre agglomérée artificielle comprenant des granules de feldspath |
WO2021190751A1 (fr) * | 2020-03-26 | 2021-09-30 | Wacker Chemie Ag | Composition de pierre artificielle comprenant un alpha-silane comme agent adhésif |
US20210383942A1 (en) * | 2020-06-03 | 2021-12-09 | Eikem Silicones USA Corp. | Method and compositions to achieve long-term stable electrical conductivity in silicone material with carbon black as conductive fillers |
Also Published As
Publication number | Publication date |
---|---|
AU2022436753A1 (en) | 2024-07-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
AU2020362305B2 (en) | Artificial agglomerate stone article comprising feldspar granules | |
EP1648673B1 (fr) | Materiau composite presentant l'apparence de la pierre naturelle | |
AU2020323709B2 (en) | Artificial agglomerate stone article comprising synthetic silicate granules | |
JP2016508089A (ja) | 層状及び塊状の人造石物 | |
AU2020319840A1 (en) | Artificial agglomerate stone article comprising synthetic silicate granules | |
US20080296795A1 (en) | Process to create decorative pattern in engineered stone | |
WO2023143826A1 (fr) | Matériau aggloméré artificiel amélioré | |
US20230234888A1 (en) | Artificial agglomerated material | |
KR20180118775A (ko) | 합성석을 위한 조성물 | |
EP4389718A1 (fr) | Article en pierre artificielle agglomérée comprenant des granulés de matériau vitreux et procédé de fabrication de celui-ci | |
EP4389717A1 (fr) | Article en pierre artificielle agglomérée comprenant du materiau vitreux blanc opaque granule et procede de fabrication dudit article | |
EP4175922B1 (fr) | Pierre agglomérée artificielle | |
KR20090059901A (ko) | 다양한 색상으로 코팅된 유리칩과 거울칩을 활용한 인조석 | |
US11708292B1 (en) | Glass/quartz composite surface | |
US20230002284A1 (en) | Glass/quartz composite surface | |
US20240067556A1 (en) | Glass/quartz composite surface | |
EP4431479A1 (fr) | Pierre synthétique et procédés de formation de pierre synthétique | |
JPH04280884A (ja) | 人造石 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 22840675 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: AU2022436753 Country of ref document: AU |
|
ENP | Entry into the national phase |
Ref document number: 2022436753 Country of ref document: AU Date of ref document: 20221220 Kind code of ref document: A |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 2022840675 Country of ref document: EP Effective date: 20240827 |