WO2023124679A1 - Refrigerator - Google Patents

Refrigerator Download PDF

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Publication number
WO2023124679A1
WO2023124679A1 PCT/CN2022/134345 CN2022134345W WO2023124679A1 WO 2023124679 A1 WO2023124679 A1 WO 2023124679A1 CN 2022134345 W CN2022134345 W CN 2022134345W WO 2023124679 A1 WO2023124679 A1 WO 2023124679A1
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WO
WIPO (PCT)
Prior art keywords
electrolytic
storage compartment
refrigerator
installation
deoxygenation device
Prior art date
Application number
PCT/CN2022/134345
Other languages
French (fr)
Chinese (zh)
Inventor
苗建林
李春阳
Original Assignee
青岛海尔电冰箱有限公司
海尔智家股份有限公司
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Application filed by 青岛海尔电冰箱有限公司, 海尔智家股份有限公司 filed Critical 青岛海尔电冰箱有限公司
Publication of WO2023124679A1 publication Critical patent/WO2023124679A1/en

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D11/00Self-contained movable devices, e.g. domestic refrigerators
    • F25D11/02Self-contained movable devices, e.g. domestic refrigerators with cooling compartments at different temperatures
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D17/00Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces
    • F25D17/04Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces for circulating air, e.g. by convection
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D23/00General constructional features
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D25/00Charging, supporting, and discharging the articles to be cooled
    • F25D25/02Charging, supporting, and discharging the articles to be cooled by shelves

Definitions

  • the invention relates to fresh-keeping technology, in particular to a refrigerator.
  • Hypoxic fresh-keeping is a fresh-keeping technology that has received wide attention, which can effectively extend the shelf life of fruits and vegetables and other ingredients and slow down the loss of nutrients.
  • a deoxygenation device When the refrigerator is equipped with a deoxygenation device, a low-oxygen fresh-keeping atmosphere can be created in the storage space.
  • the inventor realizes that the oxygen removal device has a certain volume. For example, some devices even need to install equipment such as air pumps, which will take up too much volume. However, the internal space of the refrigerator is very limited. Therefore, when the oxygen removal device is installed, It will inevitably affect the effective volume of the refrigerator.
  • An object of the present invention is to overcome at least one technical defect in the prior art and provide a refrigerator.
  • a further object of the present invention is to enable the refrigerator to have the function of keeping fresh in low oxygen while avoiding too much space occupied by the electrolytic deoxygenation device to ensure the effective volume of the refrigerator.
  • a further object of the present invention is to reduce or avoid damage to the electrolytic deoxygenation device during the process of taking and placing items by the user.
  • Another further object of the present invention is to reduce or avoid performance degradation of the electrolytic deoxygenation device due to inclined installation.
  • the present invention provides a refrigerator, comprising: an inner tank, which forms a storage compartment inside; and an electrolytic deoxygenation device, which is installed obliquely at the bottom of the storage compartment, and is used to pass through the storage compartment under the action of electrolysis voltage
  • the electrochemical reaction consumes oxygen in the storage compartment.
  • the refrigerator further includes: a storage container arranged in the storage compartment, and a return air gap is formed between the bottom wall of the storage compartment and the bottom wall of the storage compartment; an installation opening is opened on the bottom wall of the storage container ;
  • the electrolytic oxygen removal device is arranged in the return air gap, and the installation port is closed, and is used for consuming the oxygen in the storage container through electrochemical reaction.
  • a part of the bottom wall of the storage compartment is recessed downward to form a groove located in the return air gap and facing the installation port; the electrolytic deoxidizer is arranged at the groove.
  • the refrigerator further includes: a limit assembly, which is arranged at the groove, and defines a card position for clamping and positioning the electrolytic deoxygenation device. Tilt settings at preset angles.
  • the limiting assembly includes a first limiting rib and a second limiting rib extending upward from the bottom of the groove, and a third limiting rib extending downward from the rear end of the peripheral wall of the installation opening;
  • the first limiting rib is opposite to the third limiting rib, and the gap between it and the third limiting rib forms the first locking position;
  • the second limiting rib is opposite to the front end of the peripheral wall of the installation port , and the gap between it and the front end of the peripheral wall of the installation port forms a second clamping position; and the rear part of the electrolytic deoxygenation device is clamped to the first clamping position, and the front part of the electrolytic deoxygenation device is clamped to the second clamping position.
  • the electrolytic oxygen removal device includes: a housing in the shape of a flat cuboid, and an opening facing the installation port is opened on its wider side; a cathode plate is arranged at the opening to jointly define a The liquid storage chamber containing the electrolyte is used to consume the oxygen in the storage container through electrochemical reaction; and the anode plate is arranged in the liquid storage chamber and is used to provide reactants to the negative plate through electrochemical reaction.
  • the wider side is the top surface of the housing; and the distance between the front end of the opening and the front end of the top surface of the housing is greater than a preset threshold, so that the cathode can be activated when the duration of the electrochemical reaction is within a preset range.
  • the board is immersed in the electrolyte solution.
  • a liquid replenishment port is opened on the front side of the casing, which is used to allow liquid to flow into the liquid storage chamber through it to replenish liquid to the liquid storage chamber; , used to exhaust the oxygen generated during the electrochemical reaction of the anode plate.
  • the storage container is a drawer, which has a cylinder body and a drawer body that can be pulled back and forth on the cylinder body; and there is an airflow channel for airflow to pass between the inner wall of the cylinder body and the peripheral wall of the drawer body; the installation port set on the barrel.
  • the refrigerator further includes: a fan, arranged on the inner wall of the cylinder and located in the airflow channel, for promoting the formation of airflow flowing through or towards the installation opening.
  • a fan arranged on the inner wall of the cylinder and located in the airflow channel, for promoting the formation of airflow flowing through or towards the installation opening.
  • the refrigerator of the present invention utilizes the electrolytic deoxygenation device to consume the oxygen in the storage compartment. Since the electrolytic deoxygenation device has the advantage of being small in size, it does not take up too much space. effective volume. By arranging the electrolytic deoxygenation device obliquely at the bottom of the storage compartment, it is possible to further avoid the influence of the installation of the electrolytic deoxygenation device on the appearance and structure of the refrigerator in the transverse direction and in the depth direction.
  • the electrolytic deoxygenation device can be arranged in the return air gap between the bottom wall of the storage compartment and the bottom wall of the storage container, the electrolytic deoxygenation device will not interfere with the inside of the storage container. Therefore, based on the solution of the present invention, the process of taking and placing items by the user will not cause damage to the electrolytic deoxygenation device, which is conducive to improving the convenience and reliability of the refrigerator in use.
  • the cathode plate can always be immersed in the electrolyte when the duration of the electrochemical reaction is within the preset range. weakened.
  • Fig. 1 is a schematic structural diagram of a refrigerator according to an embodiment of the present invention
  • FIG. 2 is a schematic side view of a refrigerator according to an embodiment of the present invention.
  • Fig. 3 is a partial enlarged view of place A in Fig. 2;
  • Fig. 4 is another partial enlarged view of place A in Fig. 2, in which the electrolytic deoxygenation device is hidden;
  • Fig. 5 is a schematic structural diagram of an electrolytic deoxygenation device of a refrigerator according to an embodiment of the present invention.
  • Fig. 6 is a schematic exploded view of the electrolytic deoxidizer of the refrigerator shown in Fig. 5 .
  • FIG. 1 is a schematic structural diagram of a refrigerator 10 according to an embodiment of the present invention.
  • Fig. 2 is a schematic side view of a refrigerator 10 according to an embodiment of the present invention. In order to better show the internal structure of the refrigerator 10, Fig. 2 is drawn in the form of a perspective view.
  • the refrigerator 10 may generally include an inner container 110 and an electrolytic deoxygenation device 200 .
  • the liner 110 is an integral part of the box body 100 of the refrigerator 10 , for example, can form the box body 100 together with the box shell 120 .
  • the interior of the liner 110 forms a storage compartment 112 .
  • the electrolytic deoxygenation device 200 can be selectively disposed in a storage compartment 112, such as a refrigerator compartment, a freezer compartment or a variable temperature compartment, which is not limited thereto.
  • the electrolytic deoxygenation device 200 is installed obliquely at the bottom of the storage compartment 112, and is used to consume the oxygen in the storage compartment 112 by carrying out an electrochemical reaction under the action of the electrolysis voltage.
  • the electrolytic deoxygenation device 200 may include a cathode electrode and an anode electrode, and by electrifying the cathode electrode and the anode electrode, electrochemical reactions may respectively occur on the two electrodes.
  • the type of electrochemical reaction can be selected arbitrarily, as long as the reactant of a certain electrode is oxygen.
  • the electrochemical reaction at the cathode electrode may be a reduction reaction
  • the electrochemical reaction at the anode electrode may be an oxidation reaction.
  • the refrigerator 10 of this embodiment utilizes the electrolytic deoxygenation device 200 to consume the oxygen in the storage compartment 112. Since the electrolytic deoxygenation device 200 has the advantage of being small in size, it does not take up too much space. function while ensuring the effective volume of the refrigerator 10. By arranging the electrolytic deoxygenation device 200 obliquely at the bottom of the storage compartment 112 , the installation of the electrolytic deoxygenation device 200 can be further prevented from affecting the appearance and structure of the refrigerator 10 in the lateral direction and in the depth direction.
  • Installing the electrolytic deoxygenation device 200 at the bottom of the storage compartment 112 can make full use of the space at the bottom of the compartment. At the bottom of the storage compartment 112, it can reduce space occupation and ensure effective volume. By being inclined, the electrolytic oxygen removal device 200 can be extended in a narrow installation space, so as to ensure that the electrochemical elements (such as the cathode electrode and the anode electrode) have an appropriate active area, thereby ensuring considerable oxygen removal efficiency.
  • the electrochemical elements such as the cathode electrode and the anode electrode
  • the refrigerator 10 may further include a storage container 300 disposed in the storage compartment 112 , and the bottom wall of the storage container 300 and the bottom wall of the storage compartment 112 form a There is a return air gap 114.
  • the return air gap 114 can allow the return air flowing through the storage compartment 112 to pass through.
  • a bottom wall of the storage container 300 defines an installation opening 312 .
  • the installation port 312 serves as a communication port between the electrolytic deoxygenation device 200 and the inner space of the storage container 300 .
  • the electrolytic deoxygenation device 200 is disposed in the return air gap 114 and closes the installation opening 312 , and is used for consuming oxygen in the storage container 300 through an electrochemical reaction.
  • the cathode electrode of the electrolytic deoxygenation device 200 can be covered or clamped on the periphery of the installation opening 312 , so as to close the installation opening 312 while using the oxygen in the storage container 300 as a reactant to perform an electrochemical reaction.
  • the electrolytic deoxygenation device 200 can be arranged in the return air gap 114 between the bottom wall of the storage compartment 112 and the bottom wall of the storage container 300, the electrolytic deoxygenation device 200 will not be directly connected to the inner space of the storage container 300. Therefore, based on the solution of this embodiment, the process of taking and placing items by the user will not cause damage to the electrolytic deoxygenation device 200 , which is conducive to improving the convenience and reliability of the refrigerator 10 during use.
  • the side of the installation port 312 facing the storage container 300 can be provided with a partition net, which has air permeability and has a spacer function, which can prevent items from falling on the side of the electrolytic deoxygenation device 200. on the cathode electrode.
  • FIG. 3 is a partial enlarged view of A in FIG. 2 ;
  • FIG. 4 is another partial enlarged view of A in FIG. 2 .
  • the electrolytic deoxidizer 200 is hidden in FIG. 4 .
  • a portion of the bottom wall of the storage compartment 112 is recessed downward to form a groove 114 a located in the return air gap 114 and facing the installation opening 312 .
  • the electrolytic deoxidizer 200 is disposed at the groove 114a. That is to say, the bottom wall of the storage compartment 112 is deformed to form a groove 114 a, and the groove 114 a can provide sufficient installation space for the electrolytic deoxygenation device 200 .
  • the groove 114a and the storage compartment 112 can be molded in one step.
  • the refrigerator 10 can provide another space for the installation of the electrolytic deoxygenation device 200 , the structure is compact, and the effective volume and aesthetic appearance of the refrigerator 10 will hardly be adversely affected.
  • the refrigerator 10 may further include a limiting component, which is arranged at the groove 114a, and defines a locking position for locking and positioning the electrolytic deoxygenation device 200, and the locking position enables the electrolytic deoxygenation device 200
  • the device 200 is installed obliquely at a preset angle to the horizontal plane while closing the installation opening 312 .
  • the locking position refers to the positioning space of the electrolytic deoxygenation device 200 .
  • the installation opening 312 is just closed and inclined at a preset angle with respect to the horizontal plane.
  • the preset angle is any value within the range of 0-45°, such as 15° or 30°.
  • Using the limit component to position the electrolytic deoxygenation device 200 has a simple method and a simple structure, and can ensure the positioning accuracy of the electrolytic deoxygenation device 200 and prevent problems such as poor sealing of the installation port 312 .
  • the limiting component includes a first limiting rib 410 and a second limiting rib 420 extending upward from the groove bottom of the groove 114a, and extending downward from the rear end of the peripheral wall of the installation opening 312
  • Each limiting rib can be plate-shaped, and the plate surface is respectively extended along the transverse direction of the box body 100 .
  • the card slots defined by the limiting component may include a first card slot 401 and a second card slot 402 .
  • Each clamping position serves as a positioning space for clamping and positioning a part of the electrolytic deoxygenation device 200 .
  • the first limiting rib 410 is opposite to the third limiting rib 430 , and the gap between the first limiting rib 410 and the third limiting rib 430 forms the first locking position 401 .
  • the second limiting rib 420 is opposite to the front end of the peripheral wall of the installation opening 312, and the gap between it and the front end of the peripheral wall of the installation opening 312 forms the second locking position 402.
  • the first limiting rib 410 is lower than the second limiting rib 420 , which makes the electrolytic deoxygenation device 200 inclined downward from front to back.
  • the rear part of the electrolytic deoxygenation device 200 is clamped to the first clamping position 401
  • the front part of the electrolytic deoxygenation device 200 is clamped to the second clamping position 402 .
  • the front part and the rear part of the electrolytic deoxygenation device 200 are respectively positioned by using two clamping positions, which is beneficial to improving the stability of the assembly structure between the electrolytic deoxygenation device 200 and the limiting assembly.
  • Fig. 5 is a schematic structural diagram of the electrolytic deoxygenation device 200 of the refrigerator 10 according to an embodiment of the present invention
  • Fig. 6 is a schematic exploded view of the electrolytic deoxygenation device 200 of the refrigerator 10 shown in Fig. 5 .
  • the electrolytic deoxygenation device 200 includes a casing 210 , a cathode plate 220 and an anode plate 230 .
  • the housing 210 is in the shape of a flat cuboid, and an opening 211 facing the installation opening 312 is opened on a wider side thereof.
  • the cathode plate 220 is used as the cathode electrode of the electrolytic deoxygenation device 200 for reducing oxygen.
  • the cathode plate 220 is disposed at the opening 211 to define together with the casing 210 a liquid storage chamber 214 for containing the electrolyte, and is used for consuming oxygen in the storage container 300 through an electrochemical reaction.
  • oxygen in the air can undergo a reduction reaction at the cathode plate 220 , namely: O 2 +2H 2 O+4e ⁇ ⁇ 4OH ⁇ .
  • the anode plate 230 serves as the anode electrode of the electrolytic deoxidizer 200 for oxidation reaction.
  • the anode plate 230 is disposed in the liquid storage chamber 214 and used to provide reactants, such as electrons, to the cathode plate 220 through an electrochemical reaction.
  • the OH- generated by the cathode plate 220 can undergo an oxidation reaction at the anode plate 230 to generate oxygen, namely: 4OH ⁇ ⁇ O 2 +2H 2 O+4e ⁇ .
  • Oxygen may be exhausted through an exhaust port 218 on housing 210 .
  • the wider side of the housing 210 is the top surface of the housing 210 .
  • the distance between the front end of the opening 211 and the front end of the top surface of the casing 210 is greater than a predetermined threshold, so that the cathode plate 220 is immersed in the electrolyte when the duration of the electrochemical reaction is within a predetermined range.
  • the duration of the electrochemical reaction refers to the cumulative duration of the electrochemical reaction obtained by counting when the liquid storage chamber 214 is filled with the electrolyte as the initial state. As the electrochemical reaction proceeds, the electrolyte solution in the liquid storage chamber 214 will continue to decrease.
  • the cathode plate 220 may partly break away from the electrolyte solution or even completely break away from the electrolyte solution, which will lead to The electrochemical reaction cannot be carried out normally, and will cause air leakage in the cathode plate 220 , and then lead to failure of the electrolytic deoxygenation device 200 .
  • an opening 211 is opened on the top surface of the housing 210 of the electrolytic deoxygenation device 200, and the distance between the front end of the opening 211 and the front end of the top surface of the housing 210 is set
  • the cathode plate 220 can always be immersed in the electrolyte solution when the duration of the electrochemical reaction is within the preset range. setting can lead to performance degradation.
  • the preset range can be set according to the maximum working time of the electrolytic deoxygenation device 200 for deoxygenating the storage space, for example, it can be a multiple of the maximum working time.
  • a liquid replenishment port 216 is opened on the front side of the housing 210 for allowing liquid to flow into the liquid storage chamber 214 through the liquid replenishment port 214 to replenish the liquid storage chamber 214 .
  • a liquid replenishment tube may be connected to the liquid replenishment port 216 , which extends forward so as to facilitate the user to perform liquid replenishment operations.
  • the refrigerator 10 may also include a liquid level sensor disposed in the liquid storage chamber 214 for detecting the liquid level in the liquid storage chamber 214, and the refrigerator 10 is configured such that the liquid level in the liquid storage chamber 214 An alert signal is issued below a preset threshold to instruct the user to refill.
  • the refrigerator 10 may further include a liquid replenishment container for replenishing liquid to the liquid storage chamber 214 , and the refrigerator 10 may automatically replenish liquid to the liquid storage chamber 214 by using the liquid replenishment container.
  • the liquid replenishment container can communicate with the liquid replenishment port 216, and the liquid replenishment port 216 is provided with a solenoid valve for opening and closing the liquid replenishment port 216.
  • the solenoid valve can be controlled.
  • the liquid replenishment port 216 is opened to allow the liquid in the liquid replenishment container to flow into the liquid storage cavity 214 .
  • An exhaust port 218 is also provided on the front side of the housing 210 , which is spaced apart from the liquid replenishment port 216 , and is used for exhausting the oxygen generated during the electrochemical reaction of the anode plate 230 .
  • the exhausted oxygen may follow the return air flow, or may be guided to the outside of the refrigerator 10 by the exhaust pipe 260 .
  • the storage container 300 is a drawer, which has a cylinder body 310 and a drawer body 320 disposed on the cylinder body 310 so as to be able to be pulled back and forth.
  • the installation port 312 is defined on the cylinder body 310 . In this way, the air in the drawer body 320 can flow through the airflow channel 301 and flow to the installation opening 312 , so as to participate in the electrochemical reaction as a reactant of the cathode plate 220 .
  • the refrigerator 10 further includes a blower 500 disposed on the inner wall of the cylinder body 310 and located in the airflow channel 301 for promoting the formation of airflow flowing through or toward the installation opening 312 .
  • a blower 500 disposed on the inner wall of the cylinder body 310 and located in the airflow channel 301 for promoting the formation of airflow flowing through or toward the installation opening 312 .
  • the air in the storage container 300 is stirred rapidly, and flows through the airflow channel 301 or flows to the installation port 312 (the flow direction of the airflow is shown in FIG. Oxygen efficiency, and ensure the gas uniformity in the storage container 300.
  • the fan 500 is used to promote the formation of the internal circulating airflow in the storage container 300, and its type can be selected arbitrarily according to actual needs, for example, it can be a miniature centrifugal fan 500 or a miniature axial fan 500, etc.
  • the refrigerator 10 may also have an installation cavity 118 located at the rear of the storage compartment 112 , and an air supply port 116 and an air return port 117 are communicated between the installation cavity 118 and the storage compartment 112 .
  • an evaporator 600 and a blower fan 700 may be disposed in the installation cavity 118 , wherein the evaporator 600 is used for exchanging heat with the air flow passing through it.
  • the blower fan 700 is used to promote the formation of an airflow cycle that flows through the evaporator 600, the air supply port 116, the storage compartment 112, the air return port 117 and the evaporator 600 in sequence, thereby providing the heat exchange airflow to the storage compartment 112 to adjust The temperature and air flow direction of the storage compartment 112 are shown in FIG. 2 .
  • the electrolytic deoxygenation device 200 may further include a partition 240 and a fixing component 250 .
  • the separator 240 is disposed in the liquid storage chamber 214 and between the cathode plate 220 and the anode plate 230 for separating the cathode plate 220 from the anode plate 230 and preventing the electrolytic deoxidizer 200 from short circuiting.
  • a plurality of protrusions 242 are formed on the side of the separator 240 facing the anode plate 230, the protrusions 242 are in contact with the anode plate 230, and the cathode plate 220 is attached to a side of the separator 240 away from the protrusions 242. side, so as to form a preset gap between the cathode plate 220 and the anode plate 230 , thereby separating the cathode plate 220 from the anode plate 230 .
  • the fixing component 250 may be disposed on the outside of the cathode plate 220 and configured to fix the cathode plate 220 at the side opening 211 of the casing 210 .
  • the fixing assembly 250 may further include a metal frame 252 and a support 254 .
  • the metal frame 252 is attached to the outside of the cathode plate 220 .
  • the metal frame 252 is in direct contact with the cathode plate 220 and can act to press the cathode plate 220, and the metal frame 252 can also be provided with a cathode power supply terminal 252b of the cathode plate 220 to be connected to an external power source.
  • An anode power supply terminal 232 may be provided on the anode plate 230 to be connected to an external power source.
  • the supporting member 254 is formed with an insertion slot.
  • the metal frame 252 can be fixed and positioned by the support member 254 , so that the metal frame 252 presses the cathode plate 220 .
  • the refrigerator 10 of the above embodiment uses the electrolytic deoxygenation device 200 to consume the oxygen in the storage compartment 112. Since the electrolytic deoxygenation device 200 has the advantage of being small in size, it does not take up too much space. function while ensuring the effective volume of the refrigerator 10. By arranging the electrolytic deoxygenation device 200 obliquely at the bottom of the storage compartment 112 , it is possible to further avoid the influence of the installation of the electrolytic deoxygenation device 200 on the appearance and structure of the refrigerator 10 in the transverse direction and in the depth direction.

Abstract

A refrigerator, comprising: a liner internally provided with a storage compartment; and an electrolytic deoxidization device obliquely arranged at the bottom of the storage compartment and configured to consume oxygen in the storage compartment through an electrochemical reaction under the action of an electrolytic voltage. Since the electrolytic deoxidization device has the advantage of a small size, an excessive amount of space is not occupied, and the refrigerator can have an effective volume while having a hypoxemia fresh-keeping function. The electrolytic deoxidization device is obliquely mounted at the bottom of the storage compartment, such that the influence of mounting of the electrolytic deoxidization device on the appearance and the structure of the refrigerator in a transverse direction and a depth direction can be further avoided.

Description

冰箱refrigerator 技术领域technical field
本发明涉及保鲜技术,特别是涉及冰箱。The invention relates to fresh-keeping technology, in particular to a refrigerator.
背景技术Background technique
低氧保鲜是一种广受关注的保鲜技术,可有效延长果蔬等食材的保存期限,减缓营养流失。当冰箱安装有除氧装置时,可在储物空间内营造低氧保鲜气氛。Hypoxic fresh-keeping is a fresh-keeping technology that has received wide attention, which can effectively extend the shelf life of fruits and vegetables and other ingredients and slow down the loss of nutrients. When the refrigerator is equipped with a deoxygenation device, a low-oxygen fresh-keeping atmosphere can be created in the storage space.
然而,发明人认识到,除氧装置具有一定的体积,例如,有些装置甚至需要安装气泵等设备,会占用过多的容积,然而冰箱的内部空间十分有限,因此,当安装除氧装置时,难免会对冰箱的有效容积产生影响。However, the inventor realizes that the oxygen removal device has a certain volume. For example, some devices even need to install equipment such as air pumps, which will take up too much volume. However, the internal space of the refrigerator is very limited. Therefore, when the oxygen removal device is installed, It will inevitably affect the effective volume of the refrigerator.
本背景技术所公开的上述信息仅仅用于增加对本申请背景技术的理解,因此,其可能包括不构成本领域普通技术人员已知的现有技术。The above information disclosed in this background technology is only for enhancement of understanding of the background technology of the application, and therefore, it may include information that does not constitute the prior art that is already known to a person of ordinary skill in the art.
发明内容Contents of the invention
本发明的一个目的是要克服现有技术中的至少一个技术缺陷,提供一种冰箱。An object of the present invention is to overcome at least one technical defect in the prior art and provide a refrigerator.
本发明的一个进一步的目的是要使冰箱在具备低氧保鲜功能的同时,避免电解除氧装置占用过多空间,保证冰箱的有效容积。A further object of the present invention is to enable the refrigerator to have the function of keeping fresh in low oxygen while avoiding too much space occupied by the electrolytic deoxygenation device to ensure the effective volume of the refrigerator.
本发明的又一个进一步的目的是要减少或避免用户取放物品过程对电解除氧装置造成损伤。A further object of the present invention is to reduce or avoid damage to the electrolytic deoxygenation device during the process of taking and placing items by the user.
本发明的另一个进一步的目的是要减少或避免电解除氧装置因倾斜设置而导致性能弱化。Another further object of the present invention is to reduce or avoid performance degradation of the electrolytic deoxygenation device due to inclined installation.
特别地,本发明提供了一种冰箱,包括:内胆,其内部形成储物间室;和电解除氧装置,倾斜设置于储物间室的底部,并用于在电解电压的作用下通过进行电化学反应消耗储物间室内的氧气。In particular, the present invention provides a refrigerator, comprising: an inner tank, which forms a storage compartment inside; and an electrolytic deoxygenation device, which is installed obliquely at the bottom of the storage compartment, and is used to pass through the storage compartment under the action of electrolysis voltage The electrochemical reaction consumes oxygen in the storage compartment.
可选地,冰箱还包括:储物容器,设置于储物间室内,且其底壁与储物间室的底壁之间形成有回风间隙;储物容器的底壁上开设有安装口;电解除氧装置设置在回风间隙内,且封闭安装口,并用于通过进行电化学反应消耗储物容器内的氧气。Optionally, the refrigerator further includes: a storage container arranged in the storage compartment, and a return air gap is formed between the bottom wall of the storage compartment and the bottom wall of the storage compartment; an installation opening is opened on the bottom wall of the storage container ; The electrolytic oxygen removal device is arranged in the return air gap, and the installation port is closed, and is used for consuming the oxygen in the storage container through electrochemical reaction.
可选地,储物间室底壁的一部分通过向下凹陷形成位于回风间隙内且正 对安装口的凹槽;电解除氧装置设置在凹槽处。Optionally, a part of the bottom wall of the storage compartment is recessed downward to form a groove located in the return air gap and facing the installation port; the electrolytic deoxidizer is arranged at the groove.
可选地,冰箱还包括:限位组件,设置在凹槽处,并限定出用于卡接定位电解除氧装置的卡位,卡位使电解除氧装置在封闭安装口的同时与水平面呈预设角度地倾斜设置。Optionally, the refrigerator further includes: a limit assembly, which is arranged at the groove, and defines a card position for clamping and positioning the electrolytic deoxygenation device. Tilt settings at preset angles.
可选地,限位组件包括自凹槽的槽底向上延伸的第一限位凸棱和第二限位凸棱、以及自安装口的周壁后端向下延伸的第三限位凸棱;其中,第一限位凸棱与第三限位凸棱与相对,且其与第三限位凸棱之间的空隙形成第一卡位;第二限位凸棱与安装口的周壁前端相对,且其与安装口的周壁前端之间的空隙形成第二卡位;且电解除氧装置的后部卡接于第一卡位,电解除氧装置的前部卡接于第二卡位。Optionally, the limiting assembly includes a first limiting rib and a second limiting rib extending upward from the bottom of the groove, and a third limiting rib extending downward from the rear end of the peripheral wall of the installation opening; Wherein, the first limiting rib is opposite to the third limiting rib, and the gap between it and the third limiting rib forms the first locking position; the second limiting rib is opposite to the front end of the peripheral wall of the installation port , and the gap between it and the front end of the peripheral wall of the installation port forms a second clamping position; and the rear part of the electrolytic deoxygenation device is clamped to the first clamping position, and the front part of the electrolytic deoxygenation device is clamped to the second clamping position.
可选地,电解除氧装置包括:壳体,呈扁平长方体状,且其较宽的侧面上开设有面朝安装口的开口;阴极板,设置于开口处,以与壳体共同限定出用于盛装电解液的储液腔,并用于通过电化学反应消耗储物容器内的氧气;以及阳极板,设置于储液腔内,并用于通过电化学反应向阴极板提供反应物。Optionally, the electrolytic oxygen removal device includes: a housing in the shape of a flat cuboid, and an opening facing the installation port is opened on its wider side; a cathode plate is arranged at the opening to jointly define a The liquid storage chamber containing the electrolyte is used to consume the oxygen in the storage container through electrochemical reaction; and the anode plate is arranged in the liquid storage chamber and is used to provide reactants to the negative plate through electrochemical reaction.
可选地,较宽的侧面为壳体的顶面;且开口的前端与壳体的顶面前端之间的间距大于预设阈值,以在电化学反应的时长处于预设范围内时使阴极板浸于电解液。Optionally, the wider side is the top surface of the housing; and the distance between the front end of the opening and the front end of the top surface of the housing is greater than a preset threshold, so that the cathode can be activated when the duration of the electrochemical reaction is within a preset range. The board is immersed in the electrolyte solution.
可选地,壳体的前侧面开设有补液口,用于允许液体经其流入储液腔从而向储液腔补液;且壳体的前侧面上还开设有排气口,与补液口间隔设置,用于排出阳极板进行电化学反应时生成的氧气。Optionally, a liquid replenishment port is opened on the front side of the casing, which is used to allow liquid to flow into the liquid storage chamber through it to replenish liquid to the liquid storage chamber; , used to exhaust the oxygen generated during the electrochemical reaction of the anode plate.
可选地,储物容器为抽屉,其具有筒体以及可前后抽拉地设置于筒体的抽屉本体;且筒体的内壁与抽屉本体的周壁之间具有供气流通过的气流通道;安装口开设在筒体上。Optionally, the storage container is a drawer, which has a cylinder body and a drawer body that can be pulled back and forth on the cylinder body; and there is an airflow channel for airflow to pass between the inner wall of the cylinder body and the peripheral wall of the drawer body; the installation port set on the barrel.
可选地,冰箱还包括:风机,设置于筒体的内壁上,并位于气流通道内,用于促使形成流经或流向安装口的气流。Optionally, the refrigerator further includes: a fan, arranged on the inner wall of the cylinder and located in the airflow channel, for promoting the formation of airflow flowing through or towards the installation opening.
本发明的冰箱,利用电解除氧装置消耗储物间室内的氧气,由于电解除氧装置具有体积小的优点,因此不会占用过多空间,冰箱在具备低氧保鲜功能的同时,可保证冰箱的有效容积。通过将电解除氧装置倾斜设置于储物间室的底部,可进一步地避免安装电解除氧装置对冰箱横向方向和进深方向的外观以及构造产生影响。The refrigerator of the present invention utilizes the electrolytic deoxygenation device to consume the oxygen in the storage compartment. Since the electrolytic deoxygenation device has the advantage of being small in size, it does not take up too much space. effective volume. By arranging the electrolytic deoxygenation device obliquely at the bottom of the storage compartment, it is possible to further avoid the influence of the installation of the electrolytic deoxygenation device on the appearance and structure of the refrigerator in the transverse direction and in the depth direction.
进一步地,本发明的冰箱,由于可将电解除氧装置设置于储物间室底壁 与储物容器底壁之间的回风间隙内,电解除氧装置并不会与储物容器的内部空间直接接触,因此,基于本发明的方案,用户取放物品过程不会对电解除氧装置造成损伤,这有利于提高冰箱使用过程的便捷性和可靠性。Further, in the refrigerator of the present invention, since the electrolytic deoxygenation device can be arranged in the return air gap between the bottom wall of the storage compartment and the bottom wall of the storage container, the electrolytic deoxygenation device will not interfere with the inside of the storage container. Therefore, based on the solution of the present invention, the process of taking and placing items by the user will not cause damage to the electrolytic deoxygenation device, which is conducive to improving the convenience and reliability of the refrigerator in use.
更进一步地,本发明的冰箱,由于电解除氧装置倾斜设置,通过在电解除氧装置的壳体顶面上开设开口,并将开口的前端与壳体的顶面前端之间的间距设置为大于预设阈值,可使阴极板在电化学反应的时长处于预设范围内时始终浸于电解液,因此,基于本发明的方案,有利于减少或避免电解除氧装置因倾斜设置而导致性能弱化。Furthermore, in the refrigerator of the present invention, since the electrolytic deoxidizer is installed obliquely, an opening is set on the top surface of the housing of the electrolytic deoxygenator, and the distance between the front end of the opening and the front end of the top surface of the housing is set as greater than the preset threshold, the cathode plate can always be immersed in the electrolyte when the duration of the electrochemical reaction is within the preset range. weakened.
根据下文结合附图对本发明具体实施例的详细描述,本领域技术人员将会更加明了本发明的上述以及其他目的、优点和特征。Those skilled in the art will be more aware of the above and other objects, advantages and features of the present invention according to the following detailed description of specific embodiments of the present invention in conjunction with the accompanying drawings.
附图说明Description of drawings
后文将参照附图以示例性而非限制性的方式详细描述本发明的一些具体实施例。附图中相同的附图标记标示了相同或类似的部件或部分。本领域技术人员应该理解,这些附图未必是按比例绘制的。附图中:Hereinafter, some specific embodiments of the present invention will be described in detail by way of illustration and not limitation with reference to the accompanying drawings. The same reference numerals in the drawings designate the same or similar parts or parts. Those skilled in the art will appreciate that the drawings are not necessarily drawn to scale. In the attached picture:
图1是根据本发明一个实施例的冰箱的示意性结构图;Fig. 1 is a schematic structural diagram of a refrigerator according to an embodiment of the present invention;
图2是根据本发明一个实施例的冰箱的示意性侧视图;2 is a schematic side view of a refrigerator according to an embodiment of the present invention;
图3是图2中A处的局部放大图;Fig. 3 is a partial enlarged view of place A in Fig. 2;
图4是图2中A处的另一局部放大图,图中隐去了电解除氧装置;Fig. 4 is another partial enlarged view of place A in Fig. 2, in which the electrolytic deoxygenation device is hidden;
图5是根据本发明一个实施例的冰箱的电解除氧装置的示意性结构图;Fig. 5 is a schematic structural diagram of an electrolytic deoxygenation device of a refrigerator according to an embodiment of the present invention;
图6是图5所示的冰箱的电解除氧装置的示意性分解图。Fig. 6 is a schematic exploded view of the electrolytic deoxidizer of the refrigerator shown in Fig. 5 .
具体实施方式Detailed ways
图1是根据本发明一个实施例的冰箱10的示意性结构图。图2是根据本发明一个实施例的冰箱10的示意性侧视图,为了较好地展现冰箱10内部结构,图2以透视图的形式绘制。FIG. 1 is a schematic structural diagram of a refrigerator 10 according to an embodiment of the present invention. Fig. 2 is a schematic side view of a refrigerator 10 according to an embodiment of the present invention. In order to better show the internal structure of the refrigerator 10, Fig. 2 is drawn in the form of a perspective view.
冰箱10一般性地可包括内胆110和电解除氧装置200。内胆110作为冰箱10箱体100的组成部分,例如可以与箱壳120共同形成箱体100。内胆110的内部形成储物间室112。储物间室112可以为一个或多个。电解除氧装置200可以选择性地设置于一个储物间室112内,例如冷藏间室、冷冻间室或者变温间室,对此不做限定。The refrigerator 10 may generally include an inner container 110 and an electrolytic deoxygenation device 200 . The liner 110 is an integral part of the box body 100 of the refrigerator 10 , for example, can form the box body 100 together with the box shell 120 . The interior of the liner 110 forms a storage compartment 112 . There may be one or more storage compartments 112 . The electrolytic deoxygenation device 200 can be selectively disposed in a storage compartment 112, such as a refrigerator compartment, a freezer compartment or a variable temperature compartment, which is not limited thereto.
电解除氧装置200倾斜设置于储物间室112的底部,并用于在电解电压 的作用下通过进行电化学反应消耗储物间室112内的氧气。例如,电解除氧装置200可包括阴极电极和阳极电极,通过对阴极电极和阳极电极通电,两极上可分别发生电化学反应。电化学反应的类型可以任意选择,只要保证某一电极的反应物为氧气即可。例如,阴极电极的电化学反应可以为还原反应,阳极电极的电化学反应可以为氧化反应。The electrolytic deoxygenation device 200 is installed obliquely at the bottom of the storage compartment 112, and is used to consume the oxygen in the storage compartment 112 by carrying out an electrochemical reaction under the action of the electrolysis voltage. For example, the electrolytic deoxygenation device 200 may include a cathode electrode and an anode electrode, and by electrifying the cathode electrode and the anode electrode, electrochemical reactions may respectively occur on the two electrodes. The type of electrochemical reaction can be selected arbitrarily, as long as the reactant of a certain electrode is oxygen. For example, the electrochemical reaction at the cathode electrode may be a reduction reaction, and the electrochemical reaction at the anode electrode may be an oxidation reaction.
本实施例的冰箱10,利用电解除氧装置200消耗储物间室112内的氧气,由于电解除氧装置200具有体积小的优点,因此不会占用过多空间,冰箱10在具备低氧保鲜功能的同时,可保证冰箱10的有效容积。通过将电解除氧装置200倾斜设置于储物间室112的底部,可进一步地避免电解除氧装置200的安装对冰箱10横向方向和进深方向的外观以及构造产生影响。The refrigerator 10 of this embodiment utilizes the electrolytic deoxygenation device 200 to consume the oxygen in the storage compartment 112. Since the electrolytic deoxygenation device 200 has the advantage of being small in size, it does not take up too much space. function while ensuring the effective volume of the refrigerator 10. By arranging the electrolytic deoxygenation device 200 obliquely at the bottom of the storage compartment 112 , the installation of the electrolytic deoxygenation device 200 can be further prevented from affecting the appearance and structure of the refrigerator 10 in the lateral direction and in the depth direction.
将电解除氧装置200设置于储物间室112的底部,可充分利用间室的底部空间,例如通过对电解除氧装置200的安装姿态进行改进,即可使电解除氧装置200适于安装在储物间室112的底部,从而起到减少空间占用、保证有效容积的作用。通过倾斜设置,电解除氧装置200可以在狭窄的安装空间内进行延伸,从而保证电化学元件(例如阴极电极和阳极电极)具有适当的活性面积,进而保证可观的除氧效率。Installing the electrolytic deoxygenation device 200 at the bottom of the storage compartment 112 can make full use of the space at the bottom of the compartment. At the bottom of the storage compartment 112, it can reduce space occupation and ensure effective volume. By being inclined, the electrolytic oxygen removal device 200 can be extended in a narrow installation space, so as to ensure that the electrochemical elements (such as the cathode electrode and the anode electrode) have an appropriate active area, thereby ensuring considerable oxygen removal efficiency.
在一些可选的实施例中,冰箱10还可以进一步地包括储物容器300,设置于储物间室112内,且储物容器300的底壁与储物间室112的底壁之间形成有回风间隙114。该回风间隙114可允许流经储物间室112的回风气流通过。储物容器300的底壁上开设有安装口312。该安装口312作为电解除氧装置200与储物容器300内部空间的连通口。In some optional embodiments, the refrigerator 10 may further include a storage container 300 disposed in the storage compartment 112 , and the bottom wall of the storage container 300 and the bottom wall of the storage compartment 112 form a There is a return air gap 114. The return air gap 114 can allow the return air flowing through the storage compartment 112 to pass through. A bottom wall of the storage container 300 defines an installation opening 312 . The installation port 312 serves as a communication port between the electrolytic deoxygenation device 200 and the inner space of the storage container 300 .
电解除氧装置200设置在回风间隙114内,且封闭安装口312,并用于通过进行电化学反应消耗储物容器300内的氧气。例如,电解除氧装置200的阴极电极可以覆盖或卡接在安装口312的周缘,从而在封闭安装口312的同时,利用储物容器300内的氧气为反应物进行电化学反应。The electrolytic deoxygenation device 200 is disposed in the return air gap 114 and closes the installation opening 312 , and is used for consuming oxygen in the storage container 300 through an electrochemical reaction. For example, the cathode electrode of the electrolytic deoxygenation device 200 can be covered or clamped on the periphery of the installation opening 312 , so as to close the installation opening 312 while using the oxygen in the storage container 300 as a reactant to perform an electrochemical reaction.
由于可将电解除氧装置200设置于储物间室112底壁与储物容器300底壁之间的回风间隙114内,电解除氧装置200并不会与储物容器300的内部空间直接接触,因此,基于本实施例的方案,用户取放物品过程不会对电解除氧装置200造成损伤,这有利于提高冰箱10使用过程的便捷性和可靠性。在一些实施例中,安装口312的面朝储物容器300内的一侧可以设置有隔网,该隔网具有透气性,且具备间隔作用,可防止物品掉落在电解除氧装置200 的阴极电极上。Since the electrolytic deoxygenation device 200 can be arranged in the return air gap 114 between the bottom wall of the storage compartment 112 and the bottom wall of the storage container 300, the electrolytic deoxygenation device 200 will not be directly connected to the inner space of the storage container 300. Therefore, based on the solution of this embodiment, the process of taking and placing items by the user will not cause damage to the electrolytic deoxygenation device 200 , which is conducive to improving the convenience and reliability of the refrigerator 10 during use. In some embodiments, the side of the installation port 312 facing the storage container 300 can be provided with a partition net, which has air permeability and has a spacer function, which can prevent items from falling on the side of the electrolytic deoxygenation device 200. on the cathode electrode.
通过将电解除氧装置200设置在回风间隙114内,由于回风气流可以流经电解除氧装置200并带走电解除氧装置200的部分热量,因此,可减少或避免电解除氧装置200及其周围部件因温度过高而导致安全事故。By setting the electrolytic deoxygenation device 200 in the return air gap 114, since the return air flow can flow through the electrolytic deoxygenation device 200 and take away part of the heat of the electrolytic deoxygenation device 200, therefore, it is possible to reduce or avoid the exhaustion of the electrolytic deoxidation device 200. And its surrounding parts cause safety accidents due to overheating.
图3是图2中A处的局部放大图;图4是图2中A处的另一局部放大图,与图3相比,图4中隐去了电解除氧装置200。FIG. 3 is a partial enlarged view of A in FIG. 2 ; FIG. 4 is another partial enlarged view of A in FIG. 2 . Compared with FIG. 3 , the electrolytic deoxidizer 200 is hidden in FIG. 4 .
在一些可选的实施例中,储物间室112的底壁的一部分通过向下凹陷形成位于回风间隙114内且正对安装口312的凹槽114a。且电解除氧装置200设置在凹槽114a处。也就是说,储物间室112底壁通过发生形变产生凹槽114a,该凹槽114a可以为电解除氧装置200提供充足的安装空间。例如,通过对内胆110的成型过程进行改进,可使凹槽114a与储物间室112一步成型。In some optional embodiments, a portion of the bottom wall of the storage compartment 112 is recessed downward to form a groove 114 a located in the return air gap 114 and facing the installation opening 312 . And the electrolytic deoxidizer 200 is disposed at the groove 114a. That is to say, the bottom wall of the storage compartment 112 is deformed to form a groove 114 a, and the groove 114 a can provide sufficient installation space for the electrolytic deoxygenation device 200 . For example, by improving the molding process of the inner container 110, the groove 114a and the storage compartment 112 can be molded in one step.
采用上述结构,冰箱10可以为电解除氧装置200的安装另辟空间,结构精巧,且几乎不会对冰箱10的有效容积和外观美感产生不利影响。By adopting the above structure, the refrigerator 10 can provide another space for the installation of the electrolytic deoxygenation device 200 , the structure is compact, and the effective volume and aesthetic appearance of the refrigerator 10 will hardly be adversely affected.
在一些可选的实施例中,冰箱10还可以进一步地包括限位组件,设置在凹槽114a处,并限定出用于卡接定位电解除氧装置200的卡位,卡位使电解除氧装置200在封闭安装口312的同时与水平面呈预设角度地倾斜设置。其中,卡位是指电解除氧装置200的定位空间。当电解除氧装置200卡接定位在限位组件所限定出的卡位时,恰好封闭安装口312且与水平面呈预设角度地倾斜设置。其中,预设角度为0~45°范围内的任意值,例如15°或者30°。In some optional embodiments, the refrigerator 10 may further include a limiting component, which is arranged at the groove 114a, and defines a locking position for locking and positioning the electrolytic deoxygenation device 200, and the locking position enables the electrolytic deoxygenation device 200 The device 200 is installed obliquely at a preset angle to the horizontal plane while closing the installation opening 312 . Wherein, the locking position refers to the positioning space of the electrolytic deoxygenation device 200 . When the electrolytic deoxygenation device 200 is clamped and positioned at the position defined by the limiting component, the installation opening 312 is just closed and inclined at a preset angle with respect to the horizontal plane. Wherein, the preset angle is any value within the range of 0-45°, such as 15° or 30°.
利用限位组件定位电解除氧装置200,方法简便,结构简单,且能够保证电解除氧装置200的定位精度,防止发生安装口312密封不严等问题。Using the limit component to position the electrolytic deoxygenation device 200 has a simple method and a simple structure, and can ensure the positioning accuracy of the electrolytic deoxygenation device 200 and prevent problems such as poor sealing of the installation port 312 .
在一些进一步的实施例中,限位组件包括自凹槽114a的槽底向上延伸的第一限位凸棱410和第二限位凸棱420、以及自安装口312的周壁后端向下延伸的第三限位凸棱430。每个限位凸棱分别可以为板状,且板面分别沿箱体100的横向方向延伸设置。In some further embodiments, the limiting component includes a first limiting rib 410 and a second limiting rib 420 extending upward from the groove bottom of the groove 114a, and extending downward from the rear end of the peripheral wall of the installation opening 312 The third limiting rib 430. Each limiting rib can be plate-shaped, and the plate surface is respectively extended along the transverse direction of the box body 100 .
限位组件所限定出的卡位可包括第一卡位401和第二卡位402。每个卡位作为卡接定位电解除氧装置200的一部分的定位空间。第一限位凸棱410与第三限位凸棱430与相对,且其与第三限位凸棱430之间的空隙形成第一卡位401。第二限位凸棱420与安装口312的周壁前端相对,且其与安装口 312的周壁前端之间的空隙形成第二卡位402。本实施例中,第一限位凸棱410低于第二限位凸棱420,这使得电解除氧装置200由前至后地向下倾斜设置。The card slots defined by the limiting component may include a first card slot 401 and a second card slot 402 . Each clamping position serves as a positioning space for clamping and positioning a part of the electrolytic deoxygenation device 200 . The first limiting rib 410 is opposite to the third limiting rib 430 , and the gap between the first limiting rib 410 and the third limiting rib 430 forms the first locking position 401 . The second limiting rib 420 is opposite to the front end of the peripheral wall of the installation opening 312, and the gap between it and the front end of the peripheral wall of the installation opening 312 forms the second locking position 402. In this embodiment, the first limiting rib 410 is lower than the second limiting rib 420 , which makes the electrolytic deoxygenation device 200 inclined downward from front to back.
电解除氧装置200的后部卡接于第一卡位401,电解除氧装置200的前部卡接于第二卡位402。利用两个卡位分别定位电解除氧装置200的前部和后部,有利于提高电解除氧装置200与限位组件之间的装配结构稳定性。The rear part of the electrolytic deoxygenation device 200 is clamped to the first clamping position 401 , and the front part of the electrolytic deoxygenation device 200 is clamped to the second clamping position 402 . The front part and the rear part of the electrolytic deoxygenation device 200 are respectively positioned by using two clamping positions, which is beneficial to improving the stability of the assembly structure between the electrolytic deoxygenation device 200 and the limiting assembly.
其中,“前”“后”“横”“上”“下”等指示方向或位置关系的术语是基于附图所示的方向或位置关系,这仅仅是为了便于描述,而不是指示或暗示所描述的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。Among them, terms such as "front", "rear", "horizontal", "upper" and "lower" indicating direction or positional relationship are based on the direction or positional relationship shown in the drawings, which are only for the convenience of description, rather than indicating or implying the The described devices or elements must have a certain orientation, be constructed and operate in a certain orientation, and therefore should not be construed as limiting the invention.
当然,在另一些可选的实施例中,也可以选择其他安装方式来固定电解除氧装置200,只要保证其能够倾斜设置在凹槽114a处且封闭安装口312即可。Of course, in some other optional embodiments, other installation methods can also be selected to fix the electrolytic deoxygenation device 200 , as long as it can be installed obliquely at the groove 114 a and close the installation opening 312 .
图5是根据本发明一个实施例的冰箱10的电解除氧装置200的示意性结构图,图6是图5所示的冰箱10的电解除氧装置200的示意性分解图。Fig. 5 is a schematic structural diagram of the electrolytic deoxygenation device 200 of the refrigerator 10 according to an embodiment of the present invention, and Fig. 6 is a schematic exploded view of the electrolytic deoxygenation device 200 of the refrigerator 10 shown in Fig. 5 .
在一些可选的实施例中,电解除氧装置200包括壳体210、阴极板220和阳极板230。其中,壳体210呈扁平的长方体状,且其较宽的侧面上开设有面朝安装口312的开口211。In some optional embodiments, the electrolytic deoxygenation device 200 includes a casing 210 , a cathode plate 220 and an anode plate 230 . Wherein, the housing 210 is in the shape of a flat cuboid, and an opening 211 facing the installation opening 312 is opened on a wider side thereof.
阴极板220作为电解除氧装置200的阴极电极,用于发生氧气的还原反应。阴极板220设置于开口211处,以与壳体210共同限定出用于盛装电解液的储液腔214,并用于通过电化学反应消耗储物容器300内的氧气。例如,空气中的氧气可以在阴极板220处发生还原反应,即:O 2+2H 2O+4e -→4OH -The cathode plate 220 is used as the cathode electrode of the electrolytic deoxygenation device 200 for reducing oxygen. The cathode plate 220 is disposed at the opening 211 to define together with the casing 210 a liquid storage chamber 214 for containing the electrolyte, and is used for consuming oxygen in the storage container 300 through an electrochemical reaction. For example, oxygen in the air can undergo a reduction reaction at the cathode plate 220 , namely: O 2 +2H 2 O+4e →4OH .
阳极板230作为电解除氧装置200的阳极电极,用于发生氧化反应。阳极板230设置于储液腔214内,并用于通过电化学反应向阴极板220提供反应物,例如电子。阴极板220产生的OH-可以在阳极板230处可以发生氧化反应,并生成氧气,即:4OH -→O 2+2H 2O+4e -。氧气可以通过壳体210上的排气口218排出。 The anode plate 230 serves as the anode electrode of the electrolytic deoxidizer 200 for oxidation reaction. The anode plate 230 is disposed in the liquid storage chamber 214 and used to provide reactants, such as electrons, to the cathode plate 220 through an electrochemical reaction. The OH- generated by the cathode plate 220 can undergo an oxidation reaction at the anode plate 230 to generate oxygen, namely: 4OH →O 2 +2H 2 O+4e . Oxygen may be exhausted through an exhaust port 218 on housing 210 .
壳体210的较宽的侧面为壳体210的顶面。开口211的前端与壳体210的顶面前端之间的间距大于预设阈值,以在电化学反应的时长处于预设范围内时使阴极板220浸于电解液。其中,电化学反应的时长是指以储液腔214装满电解液时的状态为初始状态开始计时得到的电化学反应的累计时长。随 着电化学反应的进行,储液腔214内的电解液会不断减少,当电解液减少到一定程度时,可能会发生阴极板220部分脱离电解液甚至完全脱离电解液的情况,这会导致电化学反应无法正常进行,且会导致阴极板220发生漏气,进而导致电解除氧装置200失效。The wider side of the housing 210 is the top surface of the housing 210 . The distance between the front end of the opening 211 and the front end of the top surface of the casing 210 is greater than a predetermined threshold, so that the cathode plate 220 is immersed in the electrolyte when the duration of the electrochemical reaction is within a predetermined range. Wherein, the duration of the electrochemical reaction refers to the cumulative duration of the electrochemical reaction obtained by counting when the liquid storage chamber 214 is filled with the electrolyte as the initial state. As the electrochemical reaction proceeds, the electrolyte solution in the liquid storage chamber 214 will continue to decrease. When the electrolyte solution decreases to a certain extent, the cathode plate 220 may partly break away from the electrolyte solution or even completely break away from the electrolyte solution, which will lead to The electrochemical reaction cannot be carried out normally, and will cause air leakage in the cathode plate 220 , and then lead to failure of the electrolytic deoxygenation device 200 .
基于上述结构,由于电解除氧装置200倾斜设置,通过在电解除氧装置200的壳体210顶面上开设开口211,并将开口211的前端与壳体210的顶面前端之间的间距设置为大于预设阈值,可使阴极板220在电化学反应的时长处于预设范围内时始终浸于电解液,因此,基于本实施例的方案,有利于减少或避免电解除氧装置200因倾斜设置而导致性能弱化。预设范围可以根据电解除氧装置200针对储物空间进行除氧的最大工作时长进行设置,例如可以为最大工作时长的倍数。Based on the above structure, since the electrolytic deoxygenation device 200 is installed obliquely, an opening 211 is opened on the top surface of the housing 210 of the electrolytic deoxygenation device 200, and the distance between the front end of the opening 211 and the front end of the top surface of the housing 210 is set In order to be greater than the preset threshold, the cathode plate 220 can always be immersed in the electrolyte solution when the duration of the electrochemical reaction is within the preset range. setting can lead to performance degradation. The preset range can be set according to the maximum working time of the electrolytic deoxygenation device 200 for deoxygenating the storage space, for example, it can be a multiple of the maximum working time.
在一些可选的实施例中,壳体210的前侧面开设有补液口216,用于允许液体经其流入储液腔214从而向储液腔214补液。例如,该补液口216处可以连接有补液管,其向前延伸设置,以便于用户执行补液操作。在一些进一步的实施例中,冰箱10还可以包括液位传感器,设置于储液腔214内,用于检测储液腔214内的液位,冰箱10配置成在储液腔214内的液位低于预设阈值时发出提示信号,以指示用户补液。In some optional embodiments, a liquid replenishment port 216 is opened on the front side of the housing 210 for allowing liquid to flow into the liquid storage chamber 214 through the liquid replenishment port 214 to replenish the liquid storage chamber 214 . For example, a liquid replenishment tube may be connected to the liquid replenishment port 216 , which extends forward so as to facilitate the user to perform liquid replenishment operations. In some further embodiments, the refrigerator 10 may also include a liquid level sensor disposed in the liquid storage chamber 214 for detecting the liquid level in the liquid storage chamber 214, and the refrigerator 10 is configured such that the liquid level in the liquid storage chamber 214 An alert signal is issued below a preset threshold to instruct the user to refill.
当然,在另一些实施例中,冰箱10可以进一步地包括补液容器,用于向储液腔214补液,冰箱10可利用补液容器自动向储液腔214补液。例如,补液容器可以与补液口216连通,补液口216处设置有电磁阀,用于开闭补液口216,当储液腔214内的液位低于预设阈值时,电磁阀可以受控地打开补液口216,以允许补液容器内的液体流入储液腔214。Of course, in some other embodiments, the refrigerator 10 may further include a liquid replenishment container for replenishing liquid to the liquid storage chamber 214 , and the refrigerator 10 may automatically replenish liquid to the liquid storage chamber 214 by using the liquid replenishment container. For example, the liquid replenishment container can communicate with the liquid replenishment port 216, and the liquid replenishment port 216 is provided with a solenoid valve for opening and closing the liquid replenishment port 216. When the liquid level in the liquid storage chamber 214 is lower than a preset threshold value, the solenoid valve can be controlled. The liquid replenishment port 216 is opened to allow the liquid in the liquid replenishment container to flow into the liquid storage cavity 214 .
壳体210的前侧面还开设有排气口218,与补液口216间隔设置,用于排出阳极板230进行电化学反应时生成的氧气。排出的氧气可以跟随回风气流流动,或者可以被排气管260导引至冰箱10外。An exhaust port 218 is also provided on the front side of the housing 210 , which is spaced apart from the liquid replenishment port 216 , and is used for exhausting the oxygen generated during the electrochemical reaction of the anode plate 230 . The exhausted oxygen may follow the return air flow, or may be guided to the outside of the refrigerator 10 by the exhaust pipe 260 .
在一些可选的实施例中,储物容器300为抽屉,其具有筒体310以及可前后抽拉地设置于筒体310的抽屉本体320。且筒体310的内壁与抽屉本体320的周壁之间具有供气流通过的气流通道301。安装口312开设在筒体310上。如此设置,抽屉本体320内的空气可以流经气流通道301并流动至安装口312处,以便于作为阴极板220的反应物参与电化学反应。In some optional embodiments, the storage container 300 is a drawer, which has a cylinder body 310 and a drawer body 320 disposed on the cylinder body 310 so as to be able to be pulled back and forth. In addition, there is an airflow channel 301 between the inner wall of the cylinder body 310 and the peripheral wall of the drawer body 320 for the airflow to pass through. The installation port 312 is defined on the cylinder body 310 . In this way, the air in the drawer body 320 can flow through the airflow channel 301 and flow to the installation opening 312 , so as to participate in the electrochemical reaction as a reactant of the cathode plate 220 .
在一些进一步的实施例中,冰箱10还包括风机500,设置于筒体310 的内壁上,并位于气流通道301内,用于促使形成流经或流向安装口312的气流。在风机500的作用下,储物容器300内的空气快速搅动,并沿气流通道301流经或流向安装口312(气流流动方向如图2所示),从而可提高电解除氧装置200的除氧效率,并保证储物容器300内的气体均匀性。该风机500用于促使形成位于储物容器300内的内循环气流,其类型可以根据实际需要进行任意选择,例如可以为微型离心风机500或者微型轴流风机500等。In some further embodiments, the refrigerator 10 further includes a blower 500 disposed on the inner wall of the cylinder body 310 and located in the airflow channel 301 for promoting the formation of airflow flowing through or toward the installation opening 312 . Under the action of the fan 500, the air in the storage container 300 is stirred rapidly, and flows through the airflow channel 301 or flows to the installation port 312 (the flow direction of the airflow is shown in FIG. Oxygen efficiency, and ensure the gas uniformity in the storage container 300. The fan 500 is used to promote the formation of the internal circulating airflow in the storage container 300, and its type can be selected arbitrarily according to actual needs, for example, it can be a miniature centrifugal fan 500 or a miniature axial fan 500, etc.
在一些实施例中,冰箱10还可以具有位于储物间室112后侧的安装腔118,该安装腔118与储物间室112之间连通有送风口116和回风口117。并且安装腔118内可以设置有蒸发器600和送风风机700,其中,蒸发器600用于与流经其的气流换热。送风风机700用于促使形成依次流经蒸发器600、送风口116、储物间室112、回风口117以及蒸发器600的气流循环,从而向储物间室112提供换热气流,以调节储物间室112的温度,气流流动方向如图2所示。In some embodiments, the refrigerator 10 may also have an installation cavity 118 located at the rear of the storage compartment 112 , and an air supply port 116 and an air return port 117 are communicated between the installation cavity 118 and the storage compartment 112 . Furthermore, an evaporator 600 and a blower fan 700 may be disposed in the installation cavity 118 , wherein the evaporator 600 is used for exchanging heat with the air flow passing through it. The blower fan 700 is used to promote the formation of an airflow cycle that flows through the evaporator 600, the air supply port 116, the storage compartment 112, the air return port 117 and the evaporator 600 in sequence, thereby providing the heat exchange airflow to the storage compartment 112 to adjust The temperature and air flow direction of the storage compartment 112 are shown in FIG. 2 .
在一些实施例中,电解除氧装置200还可以进一步地包括分隔件240和固定组件250。In some embodiments, the electrolytic deoxygenation device 200 may further include a partition 240 and a fixing component 250 .
分隔件240设置于储液腔214内,并位于阴极板220与阳极板230之间,用于分隔阴极板220与阳极板230,防止电解除氧装置200短路。具体地,分隔件240上朝向阳极板230的一侧形成有多个凸起部242,凸起部242抵触于阳极板230上,阴极板220贴靠于分隔件240背离凸起部242的一侧,以在阴极板220与阳极板230形成预设间隙,进而将阴极板220与阳极板230分隔开。The separator 240 is disposed in the liquid storage chamber 214 and between the cathode plate 220 and the anode plate 230 for separating the cathode plate 220 from the anode plate 230 and preventing the electrolytic deoxidizer 200 from short circuiting. Specifically, a plurality of protrusions 242 are formed on the side of the separator 240 facing the anode plate 230, the protrusions 242 are in contact with the anode plate 230, and the cathode plate 220 is attached to a side of the separator 240 away from the protrusions 242. side, so as to form a preset gap between the cathode plate 220 and the anode plate 230 , thereby separating the cathode plate 220 from the anode plate 230 .
固定组件250可以设置于阴极板220的外侧,配置成将阴极板220固定于壳体210的侧向开口211处。具体地,该固定组件250还可以包括金属边框252和支撑件254。The fixing component 250 may be disposed on the outside of the cathode plate 220 and configured to fix the cathode plate 220 at the side opening 211 of the casing 210 . Specifically, the fixing assembly 250 may further include a metal frame 252 and a support 254 .
金属边框252贴靠于阴极板220的外侧。金属边框252与阴极板220直接接触,可以起到压紧阴极板220的作用,并且金属边框252上还可以设置有阴极板220的阴极供电端子252b,以与外部电源相连。阳极板230上可以设置有阳极供电端子232,以与外部电源相连。The metal frame 252 is attached to the outside of the cathode plate 220 . The metal frame 252 is in direct contact with the cathode plate 220 and can act to press the cathode plate 220, and the metal frame 252 can also be provided with a cathode power supply terminal 252b of the cathode plate 220 to be connected to an external power source. An anode power supply terminal 232 may be provided on the anode plate 230 to be connected to an external power source.
支撑件254形成有插接槽。当金属边框252的围立部252aa进支撑件254的插接槽时,金属边框252可以由支撑件254固定和定位,进而使得金属边框252压紧阴极板220。The supporting member 254 is formed with an insertion slot. When the surrounding portion 252aa of the metal frame 252 enters the insertion slot of the support member 254 , the metal frame 252 can be fixed and positioned by the support member 254 , so that the metal frame 252 presses the cathode plate 220 .
以上实施例的冰箱10,利用电解除氧装置200消耗储物间室112内的氧气,由于电解除氧装置200具有体积小的优点,因此不会占用过多空间,冰箱10在具备低氧保鲜功能的同时,可保证冰箱10的有效容积。通过将电解除氧装置200倾斜设置于储物间室112的底部,可进一步地避免安装电解除氧装置200对冰箱10横向方向和进深方向的外观以及构造产生影响。The refrigerator 10 of the above embodiment uses the electrolytic deoxygenation device 200 to consume the oxygen in the storage compartment 112. Since the electrolytic deoxygenation device 200 has the advantage of being small in size, it does not take up too much space. function while ensuring the effective volume of the refrigerator 10. By arranging the electrolytic deoxygenation device 200 obliquely at the bottom of the storage compartment 112 , it is possible to further avoid the influence of the installation of the electrolytic deoxygenation device 200 on the appearance and structure of the refrigerator 10 in the transverse direction and in the depth direction.
至此,本领域技术人员应认识到,虽然本文已详尽示出和描述了本发明的多个示例性实施例,但是,在不脱离本发明精神和范围的情况下,仍可根据本发明公开的内容直接确定或推导出符合本发明原理的许多其他变型或修改。因此,本发明的范围应被理解和认定为覆盖了所有这些其他变型或修改。So far, those skilled in the art should appreciate that, although a number of exemplary embodiments of the present invention have been shown and described in detail herein, without departing from the spirit and scope of the present invention, the disclosed embodiments of the present invention can still be used. Many other variations or modifications consistent with the principles of the invention are directly identified or derived from the content. Accordingly, the scope of the present invention should be understood and deemed to cover all such other variations or modifications.

Claims (10)

  1. 一种冰箱,包括:A refrigerator comprising:
    内胆,其内部形成储物间室;和a liner, the interior of which forms a storage compartment; and
    电解除氧装置,倾斜设置于所述储物间室的底部,并用于在电解电压的作用下通过进行电化学反应消耗所述储物间室内的氧气。The electrolytic deoxygenation device is installed obliquely at the bottom of the storage compartment, and is used for consuming oxygen in the storage compartment through an electrochemical reaction under the action of electrolysis voltage.
  2. 根据权利要求1所述的冰箱,还包括:The refrigerator according to claim 1, further comprising:
    储物容器,设置于所述储物间室内,且其底壁与所述储物间室的底壁之间形成有回风间隙;所述储物容器的底壁上开设有安装口;The storage container is arranged in the storage compartment, and a return air gap is formed between the bottom wall of the storage compartment and the bottom wall of the storage compartment; an installation opening is opened on the bottom wall of the storage container;
    所述电解除氧装置设置在所述回风间隙内,且封闭所述安装口,并用于通过进行电化学反应消耗所述储物容器内的氧气。The electrolytic deoxygenation device is arranged in the return air gap, closes the installation opening, and is used for consuming oxygen in the storage container through electrochemical reaction.
  3. 根据权利要求2所述的冰箱,其中,The refrigerator according to claim 2, wherein,
    所述储物间室底壁的一部分通过向下凹陷形成位于所述回风间隙内且正对所述安装口的凹槽;所述电解除氧装置设置在所述凹槽处。A part of the bottom wall of the storage compartment is recessed downward to form a groove located in the return air gap and facing the installation opening; the electro-deoxidizer is arranged at the groove.
  4. 根据权利要求3所述的冰箱,还包括:The refrigerator according to claim 3, further comprising:
    限位组件,设置在所述凹槽处,并限定出用于卡接定位所述电解除氧装置的卡位,所述卡位使所述电解除氧装置在封闭所述安装口的同时与水平面呈预设角度地倾斜设置。The limit assembly is arranged at the groove, and defines a card position for clamping and positioning the electro-deoxygenator, and the card position enables the electro-deoxygenator to be connected with the installation port while closing the installation port. The horizontal plane is set obliquely at a predetermined angle.
  5. 根据权利要求4所述的冰箱,其中,The refrigerator according to claim 4, wherein,
    所述限位组件包括自所述凹槽的槽底向上延伸的第一限位凸棱和第二限位凸棱、以及自所述安装口的周壁后端向下延伸的第三限位凸棱;其中,The limiting assembly includes a first limiting rib and a second limiting rib extending upward from the groove bottom of the groove, and a third limiting rib extending downward from the rear end of the peripheral wall of the installation opening. edge; among them,
    所述第一限位凸棱与所述第三限位凸棱与相对,且其与所述第三限位凸棱之间的空隙形成第一卡位;所述第二限位凸棱与所述安装口的周壁前端相对,且其与所述安装口的周壁前端之间的空隙形成第二卡位;且The first limiting rib is opposite to the third limiting rib, and the gap between it and the third limiting rib forms a first locking position; the second limiting rib and The front end of the surrounding wall of the installation port is opposite, and the gap between it and the front end of the surrounding wall of the installation port forms a second locking position; and
    所述电解除氧装置的后部卡接于所述第一卡位,所述电解除氧装置的前部卡接于所述第二卡位。The rear part of the electrolytic deoxygenation device is clamped to the first clamping position, and the front part of the electrolytic deoxygenation device is clamped to the second clamping position.
  6. 根据权利要求2所述的冰箱,其中,The refrigerator according to claim 2, wherein,
    所述电解除氧装置包括:The electrolytic oxygen removal device includes:
    壳体,呈扁平长方体状,且其较宽的侧面上开设有面朝所述安装口的开口;The housing is in the shape of a flat cuboid, and its wider side is provided with an opening facing the installation port;
    阴极板,设置于所述开口处,以与所述壳体共同限定出用于盛装电解液的储液腔,并用于通过电化学反应消耗所述储物容器内的氧气;以及a cathode plate, disposed at the opening, to define together with the casing a liquid storage chamber for containing electrolyte, and to consume oxygen in the storage container through an electrochemical reaction; and
    阳极板,设置于所述储液腔内,并用于通过电化学反应向所述阴极板提供反应物。The anode plate is arranged in the liquid storage chamber and is used to provide reactants to the cathode plate through an electrochemical reaction.
  7. 根据权利要求6所述的冰箱,其中,The refrigerator according to claim 6, wherein,
    所述较宽的侧面为所述壳体的顶面;且所述开口的前端与所述壳体的顶面前端之间的间距大于预设阈值,以在电化学反应的时长处于预设范围内时使所述阴极板浸于所述电解液。The wider side is the top surface of the housing; and the distance between the front end of the opening and the front end of the top surface of the housing is greater than a preset threshold, so that the duration of the electrochemical reaction is within a preset range When inside, the cathode plate is immersed in the electrolyte solution.
  8. 根据权利要求6所述的冰箱,其中,The refrigerator according to claim 6, wherein,
    所述壳体的前侧面开设有补液口,用于允许液体经其流入所述储液腔从而向所述储液腔补液;且A liquid replenishment port is opened on the front side of the housing for allowing liquid to flow into the liquid storage chamber through it to replenish liquid to the liquid storage chamber; and
    所述壳体的前侧面上还开设有排气口,与所述补液口间隔设置,用于排出所述阳极板进行电化学反应时生成的氧气。An exhaust port is also opened on the front side of the casing, which is spaced apart from the liquid replenishment port, and is used to discharge the oxygen generated during the electrochemical reaction of the anode plate.
  9. 根据权利要求2所述的冰箱,其中,The refrigerator according to claim 2, wherein,
    所述储物容器为抽屉,其具有筒体以及可前后抽拉地设置于所述筒体的抽屉本体;且所述筒体的内壁与所述抽屉本体的周壁之间具有供气流通过的气流通道;所述安装口开设在所述筒体上。The storage container is a drawer, which has a cylindrical body and a drawer body that can be pulled back and forth on the cylindrical body; channel; the installation port is opened on the cylinder.
  10. 根据权利要求9所述的冰箱,还包括:The refrigerator according to claim 9, further comprising:
    风机,设置于所述筒体的内壁上,并位于所述气流通道内,用于促使形成流经或流向所述安装口的气流。The blower is arranged on the inner wall of the barrel and is located in the airflow channel, and is used to promote the formation of airflow flowing through or towards the installation opening.
PCT/CN2022/134345 2021-12-31 2022-11-25 Refrigerator WO2023124679A1 (en)

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