WO2023109051A1 - Method for preparing pcb, and pcb - Google Patents

Method for preparing pcb, and pcb Download PDF

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Publication number
WO2023109051A1
WO2023109051A1 PCT/CN2022/099434 CN2022099434W WO2023109051A1 WO 2023109051 A1 WO2023109051 A1 WO 2023109051A1 CN 2022099434 W CN2022099434 W CN 2022099434W WO 2023109051 A1 WO2023109051 A1 WO 2023109051A1
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WO
WIPO (PCT)
Prior art keywords
copper
layer
hole
board
conductive layer
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PCT/CN2022/099434
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French (fr)
Chinese (zh)
Inventor
焦其正
纪成光
王洪府
王小平
张志远
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生益电子股份有限公司
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Publication of WO2023109051A1 publication Critical patent/WO2023109051A1/en

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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/46Manufacturing multilayer circuits

Definitions

  • the present application relates to the technical field of printed circuit boards, for example, to a method for preparing a PCB and the PCB.
  • the invalid hole copper length of signal vias on PCB (Printed Circuit Boards, printed circuit boards) (commonly referred to as via stubs, via stubs) has a great influence on the signal integrity of signal vias.
  • the length of the stub is reduced by back drilling. If the stub can be completely eliminated (no stub or zero stub), the influence of the stub on signal transmission can be completely eliminated.
  • the present application proposes a method for preparing a PCB and the PCB, which can completely eliminate the influence of stumps on signal transmission.
  • the PCB preparation method proposed by an embodiment of the present application includes: setting a first grommet in the predetermined opening area of the designated core board; setting a water-absorbing resin on the side of the first grommet facing away from the designated core board; The designated core board and the first core board are stacked and pressed together to form a multi-layer board; wherein, the water-absorbing resin is located between the designated core board and the first core board; corresponding to the multi-layer board Drill holes in the preset opening area to form a through hole in the multi-layer board; wherein, the through hole passes through the first annular ring, and the water-absorbing resin is exposed on the hole wall of the through hole; for the The multi-layer board is subjected to electroless copper deposition, so that the water-absorbing resin absorbs water, and a conductive layer is deposited on the hole wall of the through hole; the multi-layer board is baked to make the water-absorbing resin generate water vapor, and the water-absorbing resin The volume of the resin expands and protrudes from the wall surface of
  • the multi-layer board further includes a first copper layer disposed outside the first core board and a second copper layer disposed outside the designated core board, and the removal is located at the first
  • the conductive layer of the core board includes: an isolated copper ring formed on the first copper layer corresponding to the periphery of the through hole.
  • the forming of the isolated copper ring includes: preparing a surface dry film pattern on the first copper layer, where the dry film pattern includes a copper ring area at a predetermined position of the copper ring and an unpredetermined copper ring area. A reserved area at the position of the copper ring is provided, wherein there is a gap between the copper ring area and the reserved area; and the multilayer board is etched to remove the hole copper corresponding to the gap in the first copper layer, An isolated copper ring is formed on the first copper layer.
  • the step of forming an isolated copper ring further includes: tin-plating the multi-layer board, so that the surface of the first copper layer, the surface of the second copper layer, and the forming a tin layer on the surface of the conductive layer of the specified core board; and etching the multi-layer board to remove the isolated copper ring and the conductive layer on the first core board.
  • the preparation method further includes: removing the tin layer.
  • the etching the multi-layer board to remove the hole copper in the first copper layer corresponding to the gap, so as to form an isolated copper ring on the first copper layer includes: removing all described dry film graphics.
  • the disconnecting the conductive layer located on the specified core board from the conductive layer located on the first core board includes at least one of the following steps:
  • the water-absorbing resin includes hydrogel, and the hydrogel includes one or both of sodium polyacrylate and polyacrylamide.
  • An embodiment of the present application also proposes a PCB, which is prepared by the above PCB preparation method; the PCB preparation method includes: setting a first annular ring in the preset opening area of the designated core board; Water-absorbing resin is provided on the side of the first grommet facing away from the designated core board; the designated core board is stacked with the first core board and pressed together to form a multi-layer board; wherein the water-absorbing resin is located on the designated core board Between the first core board; drilling holes corresponding to the preset opening area of the multi-layer board, forming through holes in the multi-layer board; wherein, the through holes pass through the first hole ring, The water-absorbing resin is exposed on the hole wall of the through hole; electroless copper deposition is performed on the multi-layer board to make the water-absorbing resin absorb water, and a conductive layer is deposited on the hole wall of the through hole; The laminate is baked to make the water-absorbing resin generate water vapor, and the water-absorbing resin expands in volume and protrudes from the hole wall of
  • Fig. 1 is a structural schematic diagram of an embodiment of a method for preparing a PCB of the present application
  • Figure 2 is a schematic structural view of an embodiment of the specified core plate, the first annular ring and the water-absorbing resin in the present application;
  • Fig. 3 is a schematic structural view of an embodiment of the multilayer board of the present application.
  • Fig. 4 is a structural schematic diagram of an embodiment after multilayer board drilling of the present application.
  • Fig. 5 is a structural schematic diagram of an embodiment of the electroless copper deposition of the multilayer board of the present application.
  • Fig. 6 is a schematic structural view of an embodiment of the multi-layer board baking plate of the present application.
  • Figure 7 is a schematic structural view of an embodiment of the present application after removing the water-absorbing resin protruding from the hole wall;
  • Figure 8 is a schematic structural view of an embodiment of the present application after washing away the water-absorbing resin in the multi-layer board;
  • Fig. 9 is a schematic structural view of an embodiment of a dry film pattern provided on a multilayer board of the present application.
  • FIG. 10 is a schematic structural view of an embodiment of an isolated copper ring formed by a multilayer board of the present application.
  • Fig. 11 is a structural schematic diagram of an embodiment after removing the dry film pattern of the multilayer board of the present application.
  • Fig. 12 is a structural schematic diagram of an embodiment of the multilayer board of the present application after tinning
  • Fig. 13 is a schematic structural diagram of an embodiment of the present application after removing invalid hole copper
  • FIG. 14 is a schematic structural diagram of an embodiment of the present application after removing the tin layer of the multilayer board.
  • the directional indication is only used to explain the If the relative positional relationship, movement conditions, etc. among the components change, the directional indication will also change accordingly.
  • the present application proposes a method for preparing a PCB.
  • Fig. 1 is a flowchart of the PCB preparation method of the present application
  • Fig. 2 to Fig. 14 are sequential structural schematic diagrams of the PCB preparation process of the present application.
  • the preparation method of the PCB includes:
  • a first grommet 310 is set in the predetermined opening area of the designated core plate 100;
  • a water-absorbent resin 400 is provided on the side of the first annular ring 310 away from the specified core plate 100;
  • the designated core board 100 and the first core board 210 are stacked and pressed together to form a multi-layer board 10; between;
  • the multilayer board 10 is drilled corresponding to the predetermined opening area, and a through hole 10a is formed in the multilayer board 10; wherein, the through hole 10a passes through the first annular ring 310, and the The water-absorbing resin 400 is exposed on the wall of the through-hole 10a;
  • electroless copper deposition is performed on the multi-layer board 10, so that the water-absorbent resin 400 absorbs water, and a conductive layer 500 is deposited on the hole wall of the through hole 10a;
  • the manufacturing method of the specified core board 100 may include: inner layer manufacturing, drilling, desmearing, copper sinking, electroplating, plugging, micro-etching and other process steps, and may also use The method for preparing a PCB in the prior art prepares a specified core board 100 . That is, a circuit may also be formed inside a given core board 100 .
  • the designated core board 100 is used for signal transmission, and the structure of the first core board 210 can be set with reference to the structure of the designated core board 100 , or the structures of the first core board 210 and the designated core board 100 can be different from each other.
  • the first annular ring 310 can be disposed on the designated core board 100 by a method in the related art.
  • the first annular ring 310 is made of metal, and in an embodiment, it can be made of copper foil.
  • the quantity, size and position of the first annular ring 310 can be set according to specific conditions.
  • a core plate pattern can be prepared on the specified core plate 100, and then the first annular ring 310 can be set on the core plate pattern, or the first annular ring 310 and the core plate pattern can be produced at the same time. limit.
  • the first annular ring 310 may be 0.1 mm to 0.2 mm larger than the diameter of the through hole 10 a on one side.
  • the present application attaches the water-absorbent resin 400 on the first annular ring 310 first, and sets the attachment position and size of the water-absorbent resin 400 according to the position of the preset hole and the size of the aperture.
  • the size of the resin 400 is larger than the diameter of the opening, so that after the through-hole 10a is formed, the water-absorbent resin 400 is exposed on the wall of the through-hole 10a.
  • the water-absorbing resin 400 is screen-printed on the first annular ring 310 .
  • first core board 210 on the designated core board 100 , with the water-absorbent resin 400 facing the first core board 210 , stack and press them together to form the multi-layer board 10 .
  • first core board 210 and the designated core board 100 may be a multilayer board 10
  • the multilayer board 10 formed by pressing may only include the first core board 210 and the designated core board 100
  • Fig. 3 may also include other core boards, such as a second core board 220, a third core board, etc., the second core board 220 may be located between the first core board 210 and the specified core board 100, or be located
  • the board 210 faces away from the designated core board 100 .
  • the multi-layer board 10 may further include a second annular ring 320, and the second annular ring 320 may be disposed on the first core board 210, or clamped between the first core board 210 and the second Between the core plates 220 ; wherein, the second annular ring 320 is opposite to the first annular ring 310 .
  • a conductive layer 500 is deposited and formed on the wall surface of the through hole 10a, and the thickness of the conductive layer 500 is relatively small, which may be 0.3 micron to 0.5 micron.
  • the multi-layer board 10 is heated at a high temperature by a baking plate, and the moisture absorbed by the water-absorbent resin 400 is heated and evaporated, so that the water-absorbent resin 400 is fluffy, expands and protrudes toward the inner wall of the through hole 10a, and the conductive layer 500 is cracked. It is convenient for the subsequent disconnection operation of the conductive layer 500 .
  • the conductive layer 500 of the chapped part is an incomplete copper layer, and cracks exist, and part of the water-absorbent resin 400 is exposed.
  • the temperature of the baking plate only needs to be higher than the evaporation temperature of water, which can be 100°C to 125°C, and the drying time of the plate is 10 minutes to 20 minutes.
  • the baking temperature of the multilayer board 10 is 110° C., and the baking time is 15 minutes, so as to achieve volume expansion of the water-absorbing resin 400 , reduce energy consumption, and lower production costs.
  • the water-absorbing resin 400 includes hydrogel, which can quickly absorb water, expand in volume after being heated, and protrude from the wall surface of the through hole 10 a.
  • the hydrogel may include one or both of sodium polyacrylate and polyacrylamide.
  • the water-absorbing resin 400 can also be other water-absorbing polymer resins, as long as the volume expands after absorbing water and being heated.
  • the conductive layer 500 of a core board 210 is an invalid hole copper 520, and the effective hole copper 510 is disconnected from the invalid hole copper 520, so that the conductive layer 500 is incoherent, so as to prevent the effective hole copper 510 and the invalid hole copper 520 from conducting, and realize PCB Zero stubs.
  • the technical solution of this application first sets the first grommet 310 on the designated core board 100, attaches the water-absorbing resin 400 to the first grommet 310, and then clamps the water-absorbing resin 400 between the designated core board 100 and the first core board 210 Composite multi-layer board 10 by intermediate pressure; Drill holes in the corresponding preset opening area of multi-layer board 10 to form a through hole 10a, the through hole 10a passes through the first hole ring 310 and the water-absorbent resin 400, and the water-absorbent resin 400 is exposed on the through hole.
  • the conductive layer 500 is chapped; finally, the effective hole copper 510 is disconnected from the invalid hole copper 520, so that the effective hole copper 510 and the invalid hole copper 520 are separated and non-conductive, thereby eliminating the failure of the invalid hole copper 520 (that is, via stubs) to the specified signal transmission of the core board 100 .
  • the water-absorbing resin 400 is installed between the specified core board 100 and the first core board 210, and the water-absorbing resin 400 is used for electroless copper deposition, and the volume expansion is prominent after the water is absorbed and the plate is baked, and then the effective hole copper 510 and the invalid hole copper 520 are disconnected. , so as to completely eliminate the influence of the invalid hole copper 520 on signal transmission.
  • the PCB preparation method does not use materials with special properties, and has good compatibility with existing materials and PCB preparation processes. Moreover, the PCB preparation method is simple, the process is short, and only one pressing is required, and no multiple times are required. Pressing, thereby improving the production efficiency of PCB.
  • step of disconnecting the conductive layer 500 of the board 210 the following step is further included: removing the copper 520 in the invalid hole of the multi-layer board 10 .
  • the multilayer board 10 After the effective hole copper 510 is disconnected from the invalid hole copper 520, by removing the invalid hole copper 520 of the multilayer board 10, the multilayer board 10 has no residual piles, further avoiding the influence of the invalid hole copper 520 on signal transmission, and improving signal transmission reliability and guaranteed product performance.
  • the multilayer board 10 further includes a first copper layer 610 and a second copper layer 620, and the step of forming the multilayer board 10 includes: stacking the The first copper layer 610, the first core board 210, the designated core board 100 and the second copper layer 620 are pressed.
  • the first copper layer 610 is located on the side of the first core board 210 away from the designated core board 100, and the second copper layer 620 is located on the side of the designated core board 100 away from the first core board 210.
  • the first copper layer 610 and the second copper layer 620 are respectively located on the upper and lower surfaces of the multilayer board 10 .
  • the first copper layer 610 can be copper foil, which can be stacked on the first core board 210 during lamination, or can be prepared on the first core board 210 when the first core board 210 is manufactured.
  • the second copper layer 620 can be stacked on the designated core board 100 during lamination, or can be prepared on the surface of the designated core board 100 when the designated core board 100 is manufactured.
  • the multilayer board 10 includes a first copper layer 610 and a second copper layer 620, please refer to FIG. 5 , in the operation of electroless copper deposition, the deposited conductive layer 500 is connected to the first copper layer 610 and the second copper layer 620 respectively. , That is to say, the first copper layer 610 is connected to the second copper layer 620 through the conductive layer 500 .
  • the removal of the conductive layer 500 located on the first core board 210 includes the following Step: forming an isolated copper ring 630 on the first copper layer 610 corresponding to the periphery of the through hole 10a.
  • the copper ring 630 is separated from the first copper layer 610 away from the portion of the through hole 10a.
  • the first copper layer 610 and the copper ring 630 are not electrically conductive. It is connected, and then it is not connected with the copper 520 of the invalid hole. On the one hand, it facilitates the subsequent removal of the copper in the invalid hole 520;
  • the formation of the isolated copper ring 630 includes the following steps:
  • the dry film pattern 700 includes the copper ring area 710 covering the preset copper ring 630 position and the surface pattern area 720 of the non-preset copper ring 630 position, wherein , there is a gap 700a between the copper ring region 710 and the reserved region 720; and the multilayer board 10 is etched to remove the hole copper in the first copper layer 610 corresponding to the gap 700a, so that The first copper layer 610 forms an isolated copper ring 630 .
  • the dry film pattern 700 is arranged on the surface of the first copper layer 610 and the second copper layer 620. Since an isolated copper ring 630 needs to be formed on the first copper layer 610, the dry film pattern 700 includes a preset The copper ring area 710 at the position of the copper ring 630 and the reserved area 720 at the position of the non-preset copper ring 630, the gap 700a between the copper ring area 710 and the reserved area 720 forms a closed ring, so that subsequent etching can be carried out along the annular gap 700a , remove the hole copper of the first copper layer 610 corresponding to the gap 700a, so that the first copper layer 610 forms an isolated copper ring 630 at the periphery of the through hole 10a.
  • the first copper layer 610 that does not need to be etched is protected by the dry film pattern 700, and the first copper layer 610 that is not covered by the dry film pattern 700 is etched, so that in the first An isolated copper ring 630 is formed on the copper layer 610 .
  • the dry film pattern 700 can be produced by conventional dry film methods.
  • the multilayer board 10 is etched to remove the copper hole corresponding to the gap 700a in the first copper layer 610
  • Forming the isolated copper ring 630 on the first copper layer 610 further includes the following step: removing the dry film pattern 700 .
  • an alkaline solution or an organic solvent can be used to completely dissolve and remove the dry film pattern 700 on the surface of the multilayer board 10 , thereby exposing the first copper layer 610 , the second copper layer 620 and the isolated copper ring 630 .
  • the manufacturing method further includes the following steps: tinning the multi-layer board 10, so that the first copper forming a tin layer 800 on the surface of the layer 610, the surface of the second copper layer 620, and the surface of the conductive layer 500 located on the designated core board 100; and etching the multilayer board 10 to remove the isolated copper ring 630 and Inactive hole copper 520.
  • the isolated copper ring 630 since the isolated copper ring 630 is not connected to the first copper layer 610, the invalid hole copper 520 and the effective hole copper 510, and no current passes through, the isolated copper ring 630 and the invalid hole copper 520 cannot be connected.
  • Tin plating thereby forming a tin layer 800 on the surface of the first copper layer 610 , the surface of the second copper layer 620 and the surface of the effective hole copper 510 .
  • the etching protective layer is formed by tin plating to protect the first copper layer 610 , the second copper layer 620 and the effective hole copper 510 so as not to be removed by etching.
  • copper plating may also be performed on the multilayer board 10 to form copper layers on the surface of the first copper layer 610 , the surface of the second copper layer 620 and the surface of the effective hole copper 510 .
  • the tin layer 800 may be removed, or the tin layer 800 may not be removed. Please refer to FIG. 13 and FIG. 14 , in one embodiment, after the etching of the multilayer board 10 , the following steps are further included: removing the tin layer 800 of the multilayer board 10 . By peeling off the protective tin layer 800 , the effective hole copper 510 , the first copper layer 610 and the second copper layer 620 on the inner wall of the through hole 10 a are exposed, so as to facilitate subsequent normal process fabrication.
  • the disconnecting the copper via holes 520 from the copper via holes 510 includes at least one of the following steps: laser ablation of the conductive layer located in the water-absorbent resin 400 500 and/or the water-absorbing resin 400 protruding from the wall of the through-hole 10a to disconnect the copper in the invalid hole 520 and the copper in the effective hole 510; and use an alkaline solution to clean the through-hole 10a to remove the water-absorbing The resin 400 disconnects the invalid copper hole 520 from the valid hole copper 510 .
  • the conductive layer 500 located on the water-absorbing resin 400 is removed by laser ablation, so that the copper holes 520 in invalid holes are disconnected from the copper copper holes 510 in effective holes.
  • the water-absorbing resin 400 protruding from the inner wall of the through hole 10 a is removed, thereby removing the conductive layer 500 located on the water-absorbing resin 400 , and realizing the disconnection of the copper in the invalid hole 520 and the copper in the effective hole 510 .
  • the conductive layer 500 is cracked, and the conductive layer 500 in the cracked part is an incomplete copper layer, exposing part of the water-absorbent resin 400 .
  • the water-absorbing resin 400 located on the multi-layer board 10 is washed away by immersion and cleaning in an alkaline solution, so that the conductive layer 500 located on the water-absorbing resin 400 loses its attached body and falls off, thereby realizing the effective hole copper 520 and the effective hole copper 510. disconnection.
  • laser ablation may be performed first to remove at least one of the conductive layer 500 located on the water-absorbing resin 400 and the water-absorbing resin 400 protruding from the inner wall of the through hole 10a, and then the water-absorbing resin 400 is washed away, thereby completely removing the water-absorbing resin 400. removed, so that the invalid hole copper 520 is completely disconnected from the effective hole copper 510 .
  • the present application also proposes a PCB, which is prepared by the above PCB preparation method.
  • a PCB which is prepared by the above PCB preparation method.
  • the PCB adopts all the technical solutions of the above-mentioned embodiments, it at least has all the beneficial effects brought by the technical solutions of the above-mentioned embodiments, and will not repeat them here.
  • the PCB is a circuit board without stubs, and the stub-free here may mean that there are no stubs, or it may be free from the influence of stubs.

Abstract

Disclosed in the present application are a method for preparing a PCB, and a PCB. The method for preparing a PCB comprises: providing a first hole ring in a preset hole region of a specified core plate; providing a water absorbent resin on a side of the first hole ring facing away from the specified core plate; stacking and pressing the specified core plate and a first core plate to form a multi-layer plate; drilling a hole in a corresponding preset hole area of the multi-layer plate, to form a through hole in the multi-layer plate; chemically depositing copper on the multi-layer plate, such that the water absorbent resin absorbs water, and depositing a conductive layer on a hole wall of the through hole; drying the multi-layer plate to make the water absorbent resin generate water vapor, with the water absorbent resin expanding in size and protruding from a hole wall surface of the through hole; and disconnecting a conductive layer at the specified core plate from a conductive layer at the first core plate.

Description

PCB的制备方法和PCBPreparation method of PCB and PCB
本申请要求申请日为2021年12月14日、申请号为202111528186.4的中国专利申请的优先权,该申请的全部内容通过引用结合在本申请中。This application claims the priority of a Chinese patent application with a filing date of December 14, 2021 and application number 202111528186.4, the entire contents of which are incorporated herein by reference.
技术领域technical field
本申请涉及印制电路板技术领域,例如涉及一种PCB的制备方法和PCB。The present application relates to the technical field of printed circuit boards, for example, to a method for preparing a PCB and the PCB.
背景技术Background technique
PCB(Printed Circuit Boards,印制电路板)上信号过孔的无效孔铜长度(通常称之为过孔stub,过孔残桩)对信号过孔的信号完整性存在较大的影响,相关技术中通过背钻减小残桩的长度,如果能够完全消除残桩(无stub或零stub),则可以完全消除残桩对信号传输的影响。The invalid hole copper length of signal vias on PCB (Printed Circuit Boards, printed circuit boards) (commonly referred to as via stubs, via stubs) has a great influence on the signal integrity of signal vias. Related technologies In this method, the length of the stub is reduced by back drilling. If the stub can be completely eliminated (no stub or zero stub), the influence of the stub on signal transmission can be completely eliminated.
相关技术中,为了实现完全无stub,采用特殊叠层与多次压合工艺,或者采用特殊性能的材料(抗电镀材料压板)来实现。但是,制备方法采用的材料性能普遍特殊,存在与相关技术中的材料兼容性差、与相关技术中的PCB制作流程兼容性差等特点,影响了PCB的制备。In the related art, in order to realize no stub at all, a special lamination and multiple lamination process is adopted, or a material with special properties (a plate of anti-plating material) is used to realize it. However, the properties of materials used in the preparation method are generally special, and there are characteristics such as poor compatibility with materials in related technologies and poor compatibility with PCB manufacturing processes in related technologies, which affects the preparation of PCBs.
发明内容Contents of the invention
本申请提出了一种PCB的制备方法和PCB,能够完全消除残桩对信号传输影响。The present application proposes a method for preparing a PCB and the PCB, which can completely eliminate the influence of stumps on signal transmission.
本申请一实施例提出的PCB的制备方法,包括:在指定芯板的预设开孔区域设置第一孔环;在所述第一孔环背离所述指定芯板的一面设置吸水树脂;将所述指定芯板与第一芯板叠放后压合,形成多层板;其中,所述吸水树脂位于所述指定芯板与所述第一芯板之间;对所述多层板对应预设开孔区域钻孔,在所述多层板形成通孔;其中,所述通孔穿过所述第一孔环,所述吸水树脂显露于所述通孔的孔壁;对所述多层板进行化学沉铜,以使所述吸水树脂吸水,以及在所述通孔的孔壁沉积导电层;对所述多层板进行烘板,使所述吸水树脂产生水汽,所述吸水树脂体积膨胀并突出于所述通孔的孔壁面;及将位于所述指定芯板的导电层与位于所述第一芯板的导电层断开。The PCB preparation method proposed by an embodiment of the present application includes: setting a first grommet in the predetermined opening area of the designated core board; setting a water-absorbing resin on the side of the first grommet facing away from the designated core board; The designated core board and the first core board are stacked and pressed together to form a multi-layer board; wherein, the water-absorbing resin is located between the designated core board and the first core board; corresponding to the multi-layer board Drill holes in the preset opening area to form a through hole in the multi-layer board; wherein, the through hole passes through the first annular ring, and the water-absorbing resin is exposed on the hole wall of the through hole; for the The multi-layer board is subjected to electroless copper deposition, so that the water-absorbing resin absorbs water, and a conductive layer is deposited on the hole wall of the through hole; the multi-layer board is baked to make the water-absorbing resin generate water vapor, and the water-absorbing resin The volume of the resin expands and protrudes from the wall surface of the through hole; and the conductive layer on the specified core board is disconnected from the conductive layer on the first core board.
在一实施例中,所述将位于所述指定芯板的导电层与位于所述第一芯板的 导电层断开的步骤后,还包括:去除位于所述第一芯板的导电层。In one embodiment, after the step of disconnecting the conductive layer located on the specified core board from the conductive layer located on the first core board, further includes: removing the conductive layer located on the first core board.
在一实施例中,所述多层板还包括设于所述第一芯板外侧的第一铜层和设于所述指定芯板外侧的第二铜层,所述去除位于所述第一芯板的导电层包括:在所述第一铜层对应所述通孔周缘形成孤立的铜环。In one embodiment, the multi-layer board further includes a first copper layer disposed outside the first core board and a second copper layer disposed outside the designated core board, and the removal is located at the first The conductive layer of the core board includes: an isolated copper ring formed on the first copper layer corresponding to the periphery of the through hole.
在一实施例中,所述形成孤立的铜环,包括:在所述第一铜层上制备表层干膜图形,在所述干膜图形包括位于预设铜环位置的铜环区和非预设铜环位置的保留区,其中,所述铜环区与所述保留区之间存在间隙;及对所述多层板进行蚀刻,去除所述第一铜层对应所述间隙的孔铜,以在所述第一铜层形成孤立的铜环。In one embodiment, the forming of the isolated copper ring includes: preparing a surface dry film pattern on the first copper layer, where the dry film pattern includes a copper ring area at a predetermined position of the copper ring and an unpredetermined copper ring area. A reserved area at the position of the copper ring is provided, wherein there is a gap between the copper ring area and the reserved area; and the multilayer board is etched to remove the hole copper corresponding to the gap in the first copper layer, An isolated copper ring is formed on the first copper layer.
在一实施例中,所述形成孤立的铜环的步骤后,还包括:对所述多层板镀锡,以在所述第一铜层的表面、所述第二铜层表面以及位于所述指定芯板的导电层表面形成锡层;及对所述多层板蚀刻,去除所述孤立的铜环以及位于所述第一芯板的导电层。In one embodiment, after the step of forming an isolated copper ring, it further includes: tin-plating the multi-layer board, so that the surface of the first copper layer, the surface of the second copper layer, and the forming a tin layer on the surface of the conductive layer of the specified core board; and etching the multi-layer board to remove the isolated copper ring and the conductive layer on the first core board.
在一实施例中,对所述多层板蚀刻的步骤后,制备方法还包括:去除所述锡层。In one embodiment, after the step of etching the multilayer board, the preparation method further includes: removing the tin layer.
在一实施例中,所述对所述多层板进行蚀刻,去除所述第一铜层对应所述间隙的孔铜,以在所述第一铜层形成孤立的铜环,包括:去除所述干膜图形。In an embodiment, the etching the multi-layer board to remove the hole copper in the first copper layer corresponding to the gap, so as to form an isolated copper ring on the first copper layer, includes: removing all described dry film graphics.
在一实施例中,所述将位于所述指定芯板的导电层与位于所述第一芯板的导电层断开,包括以下步骤中的至少一个:In one embodiment, the disconnecting the conductive layer located on the specified core board from the conductive layer located on the first core board includes at least one of the following steps:
激光烧蚀位于所述吸水树脂的导电层和突出于所述通孔孔壁的吸水树脂中的至少一个,以断开位于所述指定芯板的导电层与位于所述第一芯板的导电层;及采用碱性溶液对所述通孔进行清洗,以去除所述吸水树脂,使位于所述指定芯板的导电层与位于所述第一芯板的导电层断开。Laser ablation of at least one of the conductive layer located on the water-absorbing resin and the water-absorbing resin protruding from the wall of the through hole, so as to disconnect the conductive layer located on the specified core board from the conductive layer located on the first core board. layer; and cleaning the through hole with an alkaline solution to remove the water-absorbing resin and disconnect the conductive layer located on the specified core board from the conductive layer located on the first core board.
在一实施例中,所述吸水树脂包括水凝胶,所述水凝胶包括聚丙烯酸钠和聚丙烯酰胺中的一种或两种。In one embodiment, the water-absorbing resin includes hydrogel, and the hydrogel includes one or both of sodium polyacrylate and polyacrylamide.
本申请一实施例还提出一种PCB,所述PCB采用上述PCB的制备方法制备得到;所述PCB的制备方法包括:在指定芯板的预设开孔区域设置第一孔环;在所述第一孔环背离所述指定芯板的一面设置吸水树脂;将所述指定芯板与第一芯板叠放后压合,形成多层板;其中,所述吸水树脂位于所述指定芯板与所述第一芯板之间;对所述多层板对应预设开孔区域钻孔,在所述多层板形成通孔;其中,所述通孔穿过所述第一孔环,所述吸水树脂显露于所述通孔的孔壁;对所述多 层板进行化学沉铜,以使所述吸水树脂吸水,以及在所述通孔的孔壁沉积导电层;对所述多层板进行烘板,使所述吸水树脂产生水汽,所述吸水树脂体积膨胀并突出于所述通孔的孔壁面;及将位于所述指定芯板的导电层与位于所述第一芯板的导电层断开。An embodiment of the present application also proposes a PCB, which is prepared by the above PCB preparation method; the PCB preparation method includes: setting a first annular ring in the preset opening area of the designated core board; Water-absorbing resin is provided on the side of the first grommet facing away from the designated core board; the designated core board is stacked with the first core board and pressed together to form a multi-layer board; wherein the water-absorbing resin is located on the designated core board Between the first core board; drilling holes corresponding to the preset opening area of the multi-layer board, forming through holes in the multi-layer board; wherein, the through holes pass through the first hole ring, The water-absorbing resin is exposed on the hole wall of the through hole; electroless copper deposition is performed on the multi-layer board to make the water-absorbing resin absorb water, and a conductive layer is deposited on the hole wall of the through hole; The laminate is baked to make the water-absorbing resin generate water vapor, and the water-absorbing resin expands in volume and protrudes from the hole wall of the through hole; and the conductive layer located on the designated core board and the conductive layer located on the first core board The conductive layer is disconnected.
附图说明Description of drawings
图1为本申请一种PCB的制备方法一实施例的结构示意图;Fig. 1 is a structural schematic diagram of an embodiment of a method for preparing a PCB of the present application;
图2为本申请指定芯板、第一孔环和吸水树脂一实施例的结构示意图;Figure 2 is a schematic structural view of an embodiment of the specified core plate, the first annular ring and the water-absorbing resin in the present application;
图3为本申请多层板一实施例的结构示意图;Fig. 3 is a schematic structural view of an embodiment of the multilayer board of the present application;
图4为本申请多层板钻孔后一实施例的结构示意图;Fig. 4 is a structural schematic diagram of an embodiment after multilayer board drilling of the present application;
图5为本申请多层板化学沉铜后一实施例的结构示意图;Fig. 5 is a structural schematic diagram of an embodiment of the electroless copper deposition of the multilayer board of the present application;
图6为本申请多层板烘板后一实施例的结构示意图;Fig. 6 is a schematic structural view of an embodiment of the multi-layer board baking plate of the present application;
图7为本申请去除突出在孔壁的吸水树脂后一实施例的结构示意图;Figure 7 is a schematic structural view of an embodiment of the present application after removing the water-absorbing resin protruding from the hole wall;
图8为本申请洗去多层板中的吸水树脂后一实施例的结构示意图;Figure 8 is a schematic structural view of an embodiment of the present application after washing away the water-absorbing resin in the multi-layer board;
图9为本申请多层板设置干膜图形一实施例的结构示意图;Fig. 9 is a schematic structural view of an embodiment of a dry film pattern provided on a multilayer board of the present application;
图10为本申请多层板形成孤立的铜环一实施例的结构示意图;FIG. 10 is a schematic structural view of an embodiment of an isolated copper ring formed by a multilayer board of the present application;
图11为本申请多层板去除干膜图形后一实施例的结构示意图;Fig. 11 is a structural schematic diagram of an embodiment after removing the dry film pattern of the multilayer board of the present application;
图12为本申请多层板镀锡后一实施例的结构示意图;Fig. 12 is a structural schematic diagram of an embodiment of the multilayer board of the present application after tinning;
图13为本申请去除无效孔铜后一实施例的结构示意图;Fig. 13 is a schematic structural diagram of an embodiment of the present application after removing invalid hole copper;
图14为本申请去除多层板的锡层后一实施例的结构示意图。FIG. 14 is a schematic structural diagram of an embodiment of the present application after removing the tin layer of the multilayer board.
具体实施方式Detailed ways
若本申请实施例中有涉及方向性指示(诸如上、下、左、右、前、后……),则该方向性指示仅用于解释在某一特定姿态(如附图所示)下各部件之间的相对位置关系、运动情况等,如果该特定姿态发生改变时,则该方向性指示也相应地随之改变。If there is a directional indication (such as up, down, left, right, front, back...) in the embodiment of the present application, the directional indication is only used to explain the If the relative positional relationship, movement conditions, etc. among the components change, the directional indication will also change accordingly.
另外,若本申请实施例中有涉及“第一”、“第二”等的描述,则该“第一”、“第二”等的描述仅用于描述目的,而不能理解为指示或暗示其相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括至少一个该特征。另外,若全文中出现的“和/或”的含义为,包括三个并列的方案,以“A和/或B”为例,包括A方案,或B方案,或A和B同时满足的方案。另外,各个实施例之间的技术方案可以相互结合,但是 必须是以本领域普通技术人员能够实现为基础,当技术方案的结合出现相互矛盾或无法实现时应当认为这种技术方案的结合不存在,也不在本申请要求的保护范围之内。In addition, if there are descriptions involving "first", "second", etc. in the embodiments of the present application, the descriptions of "first", "second", etc. are only for descriptive purposes, and cannot be interpreted as indications or hints Its relative importance or implicitly indicates the number of technical features indicated. Thus, the features defined as "first" and "second" may explicitly or implicitly include at least one of these features. In addition, if the meaning of "and/or" appearing in the whole text includes three parallel schemes, taking "A and/or B" as an example, it includes scheme A, scheme B, or schemes in which both A and B are satisfied . In addition, the technical solutions of the various embodiments can be combined with each other, but it must be based on the realization of those skilled in the art. When the combination of technical solutions is contradictory or cannot be realized, it should be considered that the combination of technical solutions does not exist , nor within the scope of protection required by the present application.
本申请提出一种PCB的制备方法。The present application proposes a method for preparing a PCB.
图1为本申请PCB制备方法的流程图,图2至图14依次为本申请PCB制备过程的结构示意图。Fig. 1 is a flowchart of the PCB preparation method of the present application, and Fig. 2 to Fig. 14 are sequential structural schematic diagrams of the PCB preparation process of the present application.
在本申请实施例中,请参照图1,该PCB的制备方法,包括:In the embodiment of this application, please refer to Figure 1, the preparation method of the PCB includes:
S100中,在指定芯板100的预设开孔区域设置第一孔环310;In S100, a first grommet 310 is set in the predetermined opening area of the designated core plate 100;
S200中,在所述第一孔环310背离所述指定芯板100的一面设置吸水树脂400;In S200, a water-absorbent resin 400 is provided on the side of the first annular ring 310 away from the specified core plate 100;
S300中,将所述指定芯板100与第一芯板210叠放后压合,形成多层板10;其中,所述吸水树脂400位于所述指定芯板100与所述第一芯板210之间;In S300, the designated core board 100 and the first core board 210 are stacked and pressed together to form a multi-layer board 10; between;
S400中,对所述多层板10对应预设开孔区域钻孔,在所述多层板10形成通孔10a;其中,所述通孔10a穿过所述第一孔环310,所述吸水树脂400显露于所述通孔10a的孔壁;In S400, the multilayer board 10 is drilled corresponding to the predetermined opening area, and a through hole 10a is formed in the multilayer board 10; wherein, the through hole 10a passes through the first annular ring 310, and the The water-absorbing resin 400 is exposed on the wall of the through-hole 10a;
S500中,对所述多层板10进行化学沉铜,以使所述吸水树脂400吸水,以及在所述通孔10a的孔壁沉积导电层500;In S500, electroless copper deposition is performed on the multi-layer board 10, so that the water-absorbent resin 400 absorbs water, and a conductive layer 500 is deposited on the hole wall of the through hole 10a;
S600、对所述多层板10进行烘板,使所述吸水树脂400产生水汽,所述吸水树脂400体积膨胀并突出于所述通孔10a的孔壁面;S600, drying the multi-layer board 10, so that the water-absorbent resin 400 generates water vapor, and the water-absorbent resin 400 expands in volume and protrudes from the wall surface of the through hole 10a;
S700、将位于所述指定芯板100的导电层500与位于所述第一芯板210的导电层500断开。S700. Disconnect the conductive layer 500 located on the specified core board 100 from the conductive layer 500 located on the first core board 210 .
在一实施例中,请参照图2,该指定芯板100的制作方法可以包括:内层制作、钻孔、去钻污、沉铜、电镀、塞孔、微蚀等工艺步骤,也可以采用现有技术中制备PCB的方法制备指定芯板100。也就是说,指定芯板100的内部也可以形成电路。该指定芯板100用于传输信号,该第一芯板210的结构可参照指定芯板100的结构设置,也可以是第一芯板210和指定芯板100的结构互不相同。In one embodiment, please refer to FIG. 2 , the manufacturing method of the specified core board 100 may include: inner layer manufacturing, drilling, desmearing, copper sinking, electroplating, plugging, micro-etching and other process steps, and may also use The method for preparing a PCB in the prior art prepares a specified core board 100 . That is, a circuit may also be formed inside a given core board 100 . The designated core board 100 is used for signal transmission, and the structure of the first core board 210 can be set with reference to the structure of the designated core board 100 , or the structures of the first core board 210 and the designated core board 100 can be different from each other.
请继续参照图2,可以通过相关技术中的方式将第一孔环310设置在指定芯板100上,该第一孔环310为金属材质,在一实施例中可采用铜箔制成。该第一孔环310的数量、大小和位置可以根据具体情况进行设置。在制备第一孔环310前,可以在指定芯板100制备芯板图形,然后在芯板图形上设置第一孔环310,也可以是第一孔环310与芯板图形同时制作,具体不限制。为获得高质量的PCB,第一孔环310可以比通孔10a的孔径单边大0.1mm至0.2mm。Please continue to refer to FIG. 2 , the first annular ring 310 can be disposed on the designated core board 100 by a method in the related art. The first annular ring 310 is made of metal, and in an embodiment, it can be made of copper foil. The quantity, size and position of the first annular ring 310 can be set according to specific conditions. Before preparing the first annular ring 310, a core plate pattern can be prepared on the specified core plate 100, and then the first annular ring 310 can be set on the core plate pattern, or the first annular ring 310 and the core plate pattern can be produced at the same time. limit. In order to obtain a high-quality PCB, the first annular ring 310 may be 0.1 mm to 0.2 mm larger than the diameter of the through hole 10 a on one side.
请参照图2,S200中,本申请通过先在第一孔环310上贴附吸水树脂400,根据预设开孔的位置和孔径的大小,设置吸水树脂400的贴附位置及尺寸,该吸水树脂400的尺寸大于开孔的孔径,以便形成通孔10a后,吸水树脂400显露在通孔10a的孔壁。该吸水树脂400贴附在指定芯板100的方式有多种,在一实施例中,吸水树脂400丝印在第一孔环310上。Please refer to Fig. 2, in S200, the present application attaches the water-absorbent resin 400 on the first annular ring 310 first, and sets the attachment position and size of the water-absorbent resin 400 according to the position of the preset hole and the size of the aperture. The size of the resin 400 is larger than the diameter of the opening, so that after the through-hole 10a is formed, the water-absorbent resin 400 is exposed on the wall of the through-hole 10a. There are many ways to attach the water-absorbing resin 400 to the specified core board 100 . In one embodiment, the water-absorbing resin 400 is screen-printed on the first annular ring 310 .
请参照图3,把第一芯板210放在指定芯板100上面,吸水树脂400朝向第一芯板210,叠好进行压合,形成多层板10。该第一芯板210和指定芯板100的其中一者或两者可以为多层板10,压合形成的多层板10可以仅包括第一芯板210和指定芯板100,请继续参照图3,也可以包括其它芯板,如第二芯板220、第三芯板等等,该第二芯板220可以位于第一芯板210与指定芯板100之间,或者位于第一芯板210远离指定芯板100一面。在一实施例中,该多层板10还可以包括第二孔环320,该第二孔环320可以设置在第一芯板210上,也可以是夹持在第一芯板210与第二芯板220之间;其中,该第二孔环320与第一孔环310相对设置。Please refer to FIG. 3 , put the first core board 210 on the designated core board 100 , with the water-absorbent resin 400 facing the first core board 210 , stack and press them together to form the multi-layer board 10 . One or both of the first core board 210 and the designated core board 100 may be a multilayer board 10, and the multilayer board 10 formed by pressing may only include the first core board 210 and the designated core board 100, please continue to refer to Fig. 3 may also include other core boards, such as a second core board 220, a third core board, etc., the second core board 220 may be located between the first core board 210 and the specified core board 100, or be located The board 210 faces away from the designated core board 100 . In an embodiment, the multi-layer board 10 may further include a second annular ring 320, and the second annular ring 320 may be disposed on the first core board 210, or clamped between the first core board 210 and the second Between the core plates 220 ; wherein, the second annular ring 320 is opposite to the first annular ring 310 .
而后,请参照图4,对多层板10进行钻孔操作,根据开孔的位置及大小在多层板10对应预开孔区域进行钻孔,形成通孔10a,该通孔10a穿过第一孔环310。该通孔10a穿过吸水树脂400,以使吸水树脂400显露在通孔10a的孔壁面,以便吸水树脂400可以与液体接触,使得吸水树脂400可以吸取液体。Then, please refer to Fig. 4, carry out drilling operation to multi-layer board 10, carry out drilling in multi-layer board 10 corresponding pre-opening area according to the position and the size of perforation, form through hole 10a, this through hole 10a passes through the first An annular ring 310. The through-hole 10a passes through the water-absorbent resin 400, so that the water-absorbent resin 400 is exposed on the wall of the through-hole 10a, so that the water-absorbent resin 400 can be in contact with liquid, so that the water-absorbent resin 400 can absorb liquid.
请参照图5,完成钻孔操作后,对多层板10进行化学沉铜操作,把多层板10放入沉铜药水中浸泡,药水通过通孔10a与吸水树脂400接触,吸水树脂400进行吸水。同时,在通孔10a的孔壁面上沉积形成导电层500,该导电层500的厚度比较小,可以是0.3微米至0.5微米。Please refer to Fig. 5. After the drilling operation is completed, the chemical copper deposition operation is performed on the multi-layer board 10, and the multi-layer board 10 is soaked in the copper sinking potion. absorb water. At the same time, a conductive layer 500 is deposited and formed on the wall surface of the through hole 10a, and the thickness of the conductive layer 500 is relatively small, which may be 0.3 micron to 0.5 micron.
在S600中,请参照图6,通过烘板,对多层板10高温加热,吸水树脂400吸收的水分受热蒸发,使得吸水树脂400蓬松,向通孔10a内壁膨胀突出,使得导电层500皲裂,便于后续的导电层500断开操作。该皲裂部分的导电层500为不完整的铜层,存在开裂现象,并露出部分的吸水树脂400。In S600, please refer to FIG. 6 , the multi-layer board 10 is heated at a high temperature by a baking plate, and the moisture absorbed by the water-absorbent resin 400 is heated and evaporated, so that the water-absorbent resin 400 is fluffy, expands and protrudes toward the inner wall of the through hole 10a, and the conductive layer 500 is cracked. It is convenient for the subsequent disconnection operation of the conductive layer 500 . The conductive layer 500 of the chapped part is an incomplete copper layer, and cracks exist, and part of the water-absorbent resin 400 is exposed.
烘板的温度只要大于水的蒸发温度即可,可以是100℃到125℃,烘板时间为10分钟到20分钟。在一实施例中,多层板10的烘板温度为110℃,烘板时间为15分钟,从而实现吸水树脂400体积膨胀,还减少能源的消耗,降低生产成本。The temperature of the baking plate only needs to be higher than the evaporation temperature of water, which can be 100°C to 125°C, and the drying time of the plate is 10 minutes to 20 minutes. In one embodiment, the baking temperature of the multilayer board 10 is 110° C., and the baking time is 15 minutes, so as to achieve volume expansion of the water-absorbing resin 400 , reduce energy consumption, and lower production costs.
该吸水树脂400的材料有多种,在一实施例中,所述吸水树脂400包括水凝胶,通过水凝胶可以迅速吸水,受热后体积膨胀并突出于通孔10a的孔壁面。该水凝胶的种类也有多种,在一实施例中,该水凝胶可以包括聚丙烯酸钠和聚丙 烯酰胺的一种或两种。在一实施例中,该吸水树脂400也可以是其它吸水的高分子树脂,只要吸水并受热后体积膨胀即可。There are many kinds of materials for the water-absorbing resin 400 . In one embodiment, the water-absorbing resin 400 includes hydrogel, which can quickly absorb water, expand in volume after being heated, and protrude from the wall surface of the through hole 10 a. There are many types of the hydrogel, and in one embodiment, the hydrogel may include one or both of sodium polyacrylate and polyacrylamide. In one embodiment, the water-absorbing resin 400 can also be other water-absorbing polymer resins, as long as the volume expands after absorbing water and being heated.
为了实现指定芯板100与第一芯板210不导通(通电后两者不导电,相互独立),请参照图7,定义位于指定芯板100的导电层500为有效孔铜510、位于第一芯板210的导电层500为无效孔铜520,将有效孔铜510与无效孔铜520断开,使得导电层500不连贯,以免有效孔铜510与无效孔铜520导通,实现PCB的零残桩。In order to realize that the designated core board 100 is not connected to the first core board 210 (the two are not conductive after being energized and are independent of each other), please refer to FIG. The conductive layer 500 of a core board 210 is an invalid hole copper 520, and the effective hole copper 510 is disconnected from the invalid hole copper 520, so that the conductive layer 500 is incoherent, so as to prevent the effective hole copper 510 and the invalid hole copper 520 from conducting, and realize PCB Zero stubs.
本申请技术方案先在指定芯板100上设置第一孔环310,在第一孔环310上贴附吸水树脂400,然后将吸水树脂400夹持在指定芯板100与第一芯板210之间压合成多层板10;对多层板10对应预设开孔区域进行钻孔,形成通孔10a,该通孔10a穿过第一孔环310及吸水树脂400,吸水树脂400显露在通孔10a的孔壁;对多层板10化学沉铜后烘板,以使吸水树脂400产生水汽,吸水树脂400体积膨胀并突出在通孔10a的孔壁面,使得沉积在通孔10a孔壁的导电层500皲裂;最后,把有效孔铜510与无效孔铜520断开,实现有效孔铜510与无效孔铜520分离不导通,从而消除无效孔铜520(即过孔残桩)对指定芯板100的信号传输影响。The technical solution of this application first sets the first grommet 310 on the designated core board 100, attaches the water-absorbing resin 400 to the first grommet 310, and then clamps the water-absorbing resin 400 between the designated core board 100 and the first core board 210 Composite multi-layer board 10 by intermediate pressure; Drill holes in the corresponding preset opening area of multi-layer board 10 to form a through hole 10a, the through hole 10a passes through the first hole ring 310 and the water-absorbent resin 400, and the water-absorbent resin 400 is exposed on the through hole. The hole wall of the hole 10a; after the electroless copper plating of the multi-layer board 10, the plate is baked so that the water-absorbent resin 400 generates water vapor, and the water-absorbent resin 400 expands in volume and protrudes on the hole wall surface of the through hole 10a, so that it is deposited on the hole wall of the through hole 10a. The conductive layer 500 is chapped; finally, the effective hole copper 510 is disconnected from the invalid hole copper 520, so that the effective hole copper 510 and the invalid hole copper 520 are separated and non-conductive, thereby eliminating the failure of the invalid hole copper 520 (that is, via stubs) to the specified signal transmission of the core board 100 .
本申请通过在指定芯板100与第一芯板210之间设置吸水树脂400,利用吸水树脂400化学沉铜时吸水和烘板后体积膨胀突出,然后断开有效孔铜510与无效孔铜520,从而完全消除无效孔铜520对信号传输的影响。该PCB的制备方法并未采用特殊性能的材料,与现有材料的兼容性好,与PCB制备流程兼容性好,并且,PCB的制备方法简单,流程短,仅一次压合,不需要多次压合,进而提高了PCB的生产效率。In this application, the water-absorbing resin 400 is installed between the specified core board 100 and the first core board 210, and the water-absorbing resin 400 is used for electroless copper deposition, and the volume expansion is prominent after the water is absorbed and the plate is baked, and then the effective hole copper 510 and the invalid hole copper 520 are disconnected. , so as to completely eliminate the influence of the invalid hole copper 520 on signal transmission. The PCB preparation method does not use materials with special properties, and has good compatibility with existing materials and PCB preparation processes. Moreover, the PCB preparation method is simple, the process is short, and only one pressing is required, and no multiple times are required. Pressing, thereby improving the production efficiency of PCB.
为了保证断开的可靠性,避免无效孔铜520影响信号的传输,请参照图7,在一实施例中,所述将位于所述指定芯板100的导电层500与位于所述第一芯板210的导电层500断开的步骤后,还包括以下步骤:去除所述多层板10的无效孔铜520。In order to ensure the reliability of disconnection and avoid the invalid hole copper 520 from affecting the transmission of signals, please refer to FIG. After the step of disconnecting the conductive layer 500 of the board 210 , the following step is further included: removing the copper 520 in the invalid hole of the multi-layer board 10 .
在有效孔铜510与无效孔铜520断开后,通过去除多层板10的无效孔铜520,使得多层板10无残桩,进一步避免无效孔铜520对信号传输的影响,提高信号传输的可靠性和保证产品性能。After the effective hole copper 510 is disconnected from the invalid hole copper 520, by removing the invalid hole copper 520 of the multilayer board 10, the multilayer board 10 has no residual piles, further avoiding the influence of the invalid hole copper 520 on signal transmission, and improving signal transmission reliability and guaranteed product performance.
请参照图3至图5,在一实施例中,所述多层板10还包括第一铜层610和第二铜层620,形成所述多层板10的步骤包括:依次叠放所述第一铜层610、第一芯板210、指定芯板100和第二铜层620,并进行压板。Please refer to FIG. 3 to FIG. 5 , in one embodiment, the multilayer board 10 further includes a first copper layer 610 and a second copper layer 620, and the step of forming the multilayer board 10 includes: stacking the The first copper layer 610, the first core board 210, the designated core board 100 and the second copper layer 620 are pressed.
请参照图3该第一铜层610位于第一芯板210远离指定芯板100的一面,第二 铜层620位于指定芯板100远离第一芯板210的一面,通过压合后,第一铜层610和第二铜层620分别位于多层板10的上下表面。在一实施例中,该第一铜层610可以是铜箔,可以在压合时叠放在第一芯板210上,也可以是在第一芯板210制作时,制备于第一芯板210的表面;同样地,第二铜层620可以在压合时叠放在指定芯板100上,也可以是在指定芯板100制作时,制备于指定芯板100的表面。Please refer to FIG. 3. The first copper layer 610 is located on the side of the first core board 210 away from the designated core board 100, and the second copper layer 620 is located on the side of the designated core board 100 away from the first core board 210. After lamination, the first The copper layer 610 and the second copper layer 620 are respectively located on the upper and lower surfaces of the multilayer board 10 . In one embodiment, the first copper layer 610 can be copper foil, which can be stacked on the first core board 210 during lamination, or can be prepared on the first core board 210 when the first core board 210 is manufactured. 210; similarly, the second copper layer 620 can be stacked on the designated core board 100 during lamination, or can be prepared on the surface of the designated core board 100 when the designated core board 100 is manufactured.
由于多层板10包括第一铜层610和第二铜层620,请参照图5,在化学沉铜的操作中,沉积的导电层500分别与第一铜层610、第二铜层620连接,也就是说,第一铜层610通过导电层500与第二铜层620连接在一起。Since the multilayer board 10 includes a first copper layer 610 and a second copper layer 620, please refer to FIG. 5 , in the operation of electroless copper deposition, the deposited conductive layer 500 is connected to the first copper layer 610 and the second copper layer 620 respectively. , That is to say, the first copper layer 610 is connected to the second copper layer 620 through the conductive layer 500 .
第一铜层610位于通孔10a周缘的部分和无效孔铜520可以被去除,请参照图11,在一实施例中,所述去除位于所述第一芯板210的导电层500,包括以下步骤:在所述第一铜层610对应所述通孔10a周缘形成孤立的铜环630。The part of the first copper layer 610 located at the periphery of the through hole 10a and the copper 520 of the invalid hole can be removed, please refer to FIG. 11 , in one embodiment, the removal of the conductive layer 500 located on the first core board 210 includes the following Step: forming an isolated copper ring 630 on the first copper layer 610 corresponding to the periphery of the through hole 10a.
请参照图11,该铜环630与远离通孔10a部分的第一铜层610分离,通过在第一铜层610上形成孤立的铜环630,使得第一铜层610与铜环630不导通,进而与无效孔铜520不导通。一方面,利于后续的去除无效孔铜520;另一方面,第一铜层610不受无效孔铜520的影响,保证第一铜层610的功能。Please refer to FIG. 11 , the copper ring 630 is separated from the first copper layer 610 away from the portion of the through hole 10a. By forming an isolated copper ring 630 on the first copper layer 610, the first copper layer 610 and the copper ring 630 are not electrically conductive. It is connected, and then it is not connected with the copper 520 of the invalid hole. On the one hand, it facilitates the subsequent removal of the copper in the invalid hole 520;
形成孤立的铜环630的方式有很多,请参照图9至图10,在一实施例中,所述形成孤立的铜环630,包括以下步骤:There are many ways to form the isolated copper ring 630, please refer to FIG. 9 to FIG. 10. In one embodiment, the formation of the isolated copper ring 630 includes the following steps:
在所述多层板10上制备表层干膜图形700,在所述干膜图形700包括覆盖预设铜环630位置的铜环区710和非预设铜环630位置的表层图形区720,其中,所述铜环区710与所述保留区720之间存在间隙700a;及对所述多层板10进行蚀刻,去除所述第一铜层610对应所述间隙700a的孔铜,以在所述第一铜层610形成孤立的铜环630。Prepare the surface dry film pattern 700 on the multi-layer board 10, and the dry film pattern 700 includes the copper ring area 710 covering the preset copper ring 630 position and the surface pattern area 720 of the non-preset copper ring 630 position, wherein , there is a gap 700a between the copper ring region 710 and the reserved region 720; and the multilayer board 10 is etched to remove the hole copper in the first copper layer 610 corresponding to the gap 700a, so that The first copper layer 610 forms an isolated copper ring 630 .
请参照图10,该干膜图形700设置在第一铜层610和第二铜层620表面,由于需要在第一铜层610上形成孤立的铜环630,该干膜图形700包括位于预设铜环630位置的铜环区710和非预设铜环630位置的保留区720,铜环区710和保留区720之间的间隙700a形成闭合的环形,以便后续可以沿着环形的间隙700a蚀刻,去除第一铜层610对应间隙700a的孔铜,使得第一铜层610在通孔10a的周缘形成孤立的铜环630。Please refer to FIG. 10 , the dry film pattern 700 is arranged on the surface of the first copper layer 610 and the second copper layer 620. Since an isolated copper ring 630 needs to be formed on the first copper layer 610, the dry film pattern 700 includes a preset The copper ring area 710 at the position of the copper ring 630 and the reserved area 720 at the position of the non-preset copper ring 630, the gap 700a between the copper ring area 710 and the reserved area 720 forms a closed ring, so that subsequent etching can be carried out along the annular gap 700a , remove the hole copper of the first copper layer 610 corresponding to the gap 700a, so that the first copper layer 610 forms an isolated copper ring 630 at the periphery of the through hole 10a.
也即,请参照图9至图10,通过干膜图形700对不需要蚀刻部分的第一铜层610进行保护,未被干膜图形700覆盖的第一铜层610被蚀刻,从而在第一铜层610上形成孤立的铜环630。可以理解的是,该干膜图形700可以通过常规的干膜法 来制作。That is, please refer to FIG. 9 to FIG. 10 , the first copper layer 610 that does not need to be etched is protected by the dry film pattern 700, and the first copper layer 610 that is not covered by the dry film pattern 700 is etched, so that in the first An isolated copper ring 630 is formed on the copper layer 610 . It can be understood that the dry film pattern 700 can be produced by conventional dry film methods.
为了便于后续的加工操作,请参照图10至图11,在一实施例中,所述对所述多层板10进行蚀刻,去除所述第一铜层610对应所述间隙700a的孔铜,以在所述第一铜层610形成孤立的铜环630,还包括以下步骤:去除所述干膜图形700。具体的,可采用碱性溶液或者有机溶剂,将多层板10表面的干膜图形700完全溶解去除,从而露出第一铜层610、第二铜层620和孤立的铜环630。In order to facilitate the subsequent processing operations, please refer to FIG. 10 to FIG. 11 , in one embodiment, the multilayer board 10 is etched to remove the copper hole corresponding to the gap 700a in the first copper layer 610, Forming the isolated copper ring 630 on the first copper layer 610 further includes the following step: removing the dry film pattern 700 . Specifically, an alkaline solution or an organic solvent can be used to completely dissolve and remove the dry film pattern 700 on the surface of the multilayer board 10 , thereby exposing the first copper layer 610 , the second copper layer 620 and the isolated copper ring 630 .
请参照图12至图13,在一实施例中,所述形成孤立的铜环630的步骤后,制备方法还包括以下步骤:对所述多层板10镀锡,以在所述第一铜层610的表面、所述第二铜层620表面以及位于所述指定芯板100的导电层500表面形成锡层800;及对所述多层板10蚀刻,去除所述孤立的铜环630和无效孔铜520。Please refer to Fig. 12 to Fig. 13, in one embodiment, after the step of forming the isolated copper ring 630, the manufacturing method further includes the following steps: tinning the multi-layer board 10, so that the first copper forming a tin layer 800 on the surface of the layer 610, the surface of the second copper layer 620, and the surface of the conductive layer 500 located on the designated core board 100; and etching the multilayer board 10 to remove the isolated copper ring 630 and Inactive hole copper 520.
请参照图11至图13,由于孤立的铜环630与第一铜层610、无效孔铜520与有效孔铜510不导通,没有电流通过,孤立的铜环630和无效孔铜520无法进行镀锡,从而在第一铜层610的表面、第二铜层620表面以及有效孔铜510表面形成锡层800。通过镀锡形成蚀刻保护层,对第一铜层610、第二铜层620和有效孔铜510进行保护,以免蚀刻操作被去除。如此,通过蚀刻方式,去除了孤立的铜环630和无效孔铜520,满足产品的不同需要,也实现了产品的无残桩。在一实施例中,除了镀锡,也可以对多层板10进行镀铜,在第一铜层610的表面、第二铜层620表面以及有效孔铜510表面形成铜层。Please refer to FIG. 11 to FIG. 13 , since the isolated copper ring 630 is not connected to the first copper layer 610, the invalid hole copper 520 and the effective hole copper 510, and no current passes through, the isolated copper ring 630 and the invalid hole copper 520 cannot be connected. Tin plating, thereby forming a tin layer 800 on the surface of the first copper layer 610 , the surface of the second copper layer 620 and the surface of the effective hole copper 510 . The etching protective layer is formed by tin plating to protect the first copper layer 610 , the second copper layer 620 and the effective hole copper 510 so as not to be removed by etching. In this way, by means of etching, the isolated copper ring 630 and the ineffective hole copper 520 are removed to meet different needs of the product and also realize the product without stubs. In one embodiment, in addition to tin plating, copper plating may also be performed on the multilayer board 10 to form copper layers on the surface of the first copper layer 610 , the surface of the second copper layer 620 and the surface of the effective hole copper 510 .
去除无效孔铜520和铜环630后,可以去除锡层800,也可以不去除锡层800。请参照图13和图14,在一实施例中,所述蚀刻多层板10后,还包括以下步骤:去除所述多层板10的锡层800。通过褪去保护的锡层800,显露出通孔10a内壁的有效孔铜510、第一铜层610和第二铜层620,以便于后续正常的流程制作。After the copper 520 in the invalid hole and the copper ring 630 are removed, the tin layer 800 may be removed, or the tin layer 800 may not be removed. Please refer to FIG. 13 and FIG. 14 , in one embodiment, after the etching of the multilayer board 10 , the following steps are further included: removing the tin layer 800 of the multilayer board 10 . By peeling off the protective tin layer 800 , the effective hole copper 510 , the first copper layer 610 and the second copper layer 620 on the inner wall of the through hole 10 a are exposed, so as to facilitate subsequent normal process fabrication.
请参照图6至图8,在一实施例中,所述将无效孔铜520与有效孔铜510断开,包括以下步骤中的至少一种:激光烧蚀位于所述吸水树脂400的导电层500和/或突出于所述通孔10a孔壁的吸水树脂400,以断开无效孔铜520与有效孔铜510;及采用碱性溶液对所述通孔10a进行清洗,以去除所述吸水树脂400,使无效孔铜520与有效孔铜510断开。Please refer to FIG. 6 to FIG. 8 , in one embodiment, the disconnecting the copper via holes 520 from the copper via holes 510 includes at least one of the following steps: laser ablation of the conductive layer located in the water-absorbent resin 400 500 and/or the water-absorbing resin 400 protruding from the wall of the through-hole 10a to disconnect the copper in the invalid hole 520 and the copper in the effective hole 510; and use an alkaline solution to clean the through-hole 10a to remove the water-absorbing The resin 400 disconnects the invalid copper hole 520 from the valid hole copper 510 .
请参照图6至图7,通过激光烧蚀的方式,去除位于吸水树脂400的导电层500,使得无效孔铜520与有效孔铜510断开。或者,去除突出于通孔10a内壁的吸水树脂400,从而去除位于吸水树脂400的导电层500,实现无效孔铜520与有效孔铜510的断开。Referring to FIGS. 6 to 7 , the conductive layer 500 located on the water-absorbing resin 400 is removed by laser ablation, so that the copper holes 520 in invalid holes are disconnected from the copper copper holes 510 in effective holes. Alternatively, the water-absorbing resin 400 protruding from the inner wall of the through hole 10 a is removed, thereby removing the conductive layer 500 located on the water-absorbing resin 400 , and realizing the disconnection of the copper in the invalid hole 520 and the copper in the effective hole 510 .
请参照图8,由于吸水树脂400受热后体积膨胀,向通孔10a内突出,使得导电层500发生皲裂,皲裂部分的导电层500为不完整的铜层,露出部分的吸水树脂400。由此,通过碱性溶液浸泡清洗,洗去位于多层板10的吸水树脂400,使得位于吸水树脂400的导电层500失去贴附主体而掉落,从而实现无效孔铜520与有效孔铜510的断开。Please refer to FIG. 8 , since the water-absorbent resin 400 expands in volume after being heated, and protrudes into the through hole 10a, the conductive layer 500 is cracked, and the conductive layer 500 in the cracked part is an incomplete copper layer, exposing part of the water-absorbent resin 400 . Thus, the water-absorbing resin 400 located on the multi-layer board 10 is washed away by immersion and cleaning in an alkaline solution, so that the conductive layer 500 located on the water-absorbing resin 400 loses its attached body and falls off, thereby realizing the effective hole copper 520 and the effective hole copper 510. disconnection.
或者,可以是先进行激光烧蚀操作,去除位于吸水树脂400的导电层500和突出于通孔10a内壁的吸水树脂400中的至少一种,再洗去吸水树脂400,从而将吸水树脂400完全去除,使得无效孔铜520与有效孔铜510完全断开分离。Alternatively, laser ablation may be performed first to remove at least one of the conductive layer 500 located on the water-absorbing resin 400 and the water-absorbing resin 400 protruding from the inner wall of the through hole 10a, and then the water-absorbing resin 400 is washed away, thereby completely removing the water-absorbing resin 400. removed, so that the invalid hole copper 520 is completely disconnected from the effective hole copper 510 .
本申请还提出一种PCB,该PCB采用上述PCB的制备方法制备得到。该PCB的具体方法参照上述实施例,由于本PCB采用了上述所有实施例的全部技术方案,因此至少具有上述实施例的技术方案所带来的所有有益效果,在此不再一一赘述。其中,该PCB为无残桩的电路板,这里的无残桩可以是不存在残桩,也可以是不受残桩的影响。The present application also proposes a PCB, which is prepared by the above PCB preparation method. For the specific method of the PCB, refer to the above-mentioned embodiments. Since this PCB adopts all the technical solutions of the above-mentioned embodiments, it at least has all the beneficial effects brought by the technical solutions of the above-mentioned embodiments, and will not repeat them here. Wherein, the PCB is a circuit board without stubs, and the stub-free here may mean that there are no stubs, or it may be free from the influence of stubs.

Claims (10)

  1. 一种PCB的制备方法,包括:A method for preparing a PCB, comprising:
    在指定芯板(100)的预设开孔区域设置第一孔环(310);setting a first grommet (310) in the predetermined opening area of the designated core plate (100);
    在所述第一孔环(310)背离所述指定芯板(100)的一面设置吸水树脂(400);setting water-absorbent resin (400) on the side of the first annular ring (310) away from the specified core plate (100);
    将所述指定芯板(100)与第一芯板(210)叠放后压合,形成多层板(10);其中,所述吸水树脂(400)位于所述指定芯板(100)与所述第一芯板(210)之间;The designated core board (100) and the first core board (210) are stacked and pressed together to form a multi-layer board (10); wherein the water-absorbing resin (400) is located between the designated core board (100) and between the first core boards (210);
    对所述多层板(10)对应预设开孔区域钻孔,在所述多层板(10)形成通孔(10a);其中,所述通孔(10a)穿过所述第一孔环(310),所述吸水树脂(400)显露于所述通孔(10a)的孔壁;Drilling holes in the multilayer board (10) corresponding to the predetermined opening area, forming a through hole (10a) in the multilayer board (10); wherein, the through hole (10a) passes through the first hole a ring (310), the water-absorbing resin (400) is exposed on the hole wall of the through hole (10a);
    对所述多层板(10)进行化学沉铜,以使所述吸水树脂(400)吸水,以及在所述通孔(10a)的孔壁沉积导电层(500);performing electroless copper deposition on the multi-layer board (10), so that the water-absorbing resin (400) absorbs water, and depositing a conductive layer (500) on the hole wall of the through-hole (10a);
    对所述多层板(10)进行烘板,使所述吸水树脂(400)产生水汽,所述吸水树脂(400)体积膨胀并突出于所述通孔(10a)的孔壁面;及Baking the multi-layer board (10) so that the water-absorbing resin (400) generates water vapor, and the water-absorbing resin (400) expands in volume and protrudes from the wall surface of the through hole (10a); and
    将位于所述指定芯板(100)的导电层(500)与位于所述第一芯板(210)的导电层(500)断开。Disconnecting the conductive layer (500) on the designated core board (100) from the conductive layer (500) on the first core board (210).
  2. 如权利要求1所述的PCB的制备方法,所述将位于所述指定芯板(100)的导电层(500)与位于所述第一芯板(210)的导电层(500)断开的步骤后,还包括:去除位于所述第一芯板(210)的导电层(500)。The method for preparing PCB according to claim 1, said disconnecting the conductive layer (500) located on said specified core board (100) from the conductive layer (500) located on said first core board (210) After the step, it also includes: removing the conductive layer (500) located on the first core board (210).
  3. 如权利要求2所述的PCB的制备方法,其中,所述多层板(10)还包括设于所述第一芯板(210)外侧的第一铜层(610)和设于所述指定芯板(100)外侧的第二铜层(620),所述去除位于所述第一芯板(210)的导电层(500),包括:在所述第一铜层(610)对应所述通孔(10a)周缘形成孤立的铜环(630)。The preparation method of PCB according to claim 2, wherein, the multi-layer board (10) further comprises a first copper layer (610) arranged on the outside of the first core board (210) and the first copper layer (610) arranged on the specified The second copper layer (620) outside the core board (100), the removal of the conductive layer (500) located on the first core board (210) includes: corresponding to the first copper layer (610) An isolated copper ring (630) is formed around the through hole (10a).
  4. 如权利要求3所述的PCB的制备方法,其中,所述形成孤立的铜环(630),包括:在所述第一铜层(610)上制备表层干膜图形(700),所述干膜图形(700)包括位于预设铜环(630)位置的铜环区(710)和非预设铜环(630)位置的保留区(720),其中,所述铜环区(710)与所述保留区(720)之间存在间隙(700a);及对所述多层板(10)进行蚀刻,去除所述第一铜层(610)对应所述间隙(700a)的孔铜,以在所述第一铜层(610)形成孤立的铜环(630)。The method for preparing PCB according to claim 3, wherein said forming an isolated copper ring (630) comprises: preparing a surface dry film pattern (700) on said first copper layer (610), said dry The film pattern (700) includes a copper ring area (710) at a preset copper ring (630) position and a reserved area (720) at a non-preset copper ring (630) position, wherein the copper ring area (710) and There is a gap (700a) between the reserved regions (720); and etching the multi-layer board (10) to remove the hole copper corresponding to the gap (700a) in the first copper layer (610), so as to Isolated copper rings (630) are formed on the first copper layer (610).
  5. 如权利要求4所述的PCB的制备方法,所述形成孤立的铜环(630)的步骤后,还包括:对所述多层板(10)镀锡,以在所述第一铜层(610)的表面、所述第二铜层(620)表面以及位于所述指定芯板(100)的导电层(500)表面形成锡层(800);及对所述多层板(10)蚀刻,去除所述孤立的铜环(630)以及位于所述第一芯板 (210)的导电层(500)。The preparation method of PCB according to claim 4, after the step of forming the isolated copper ring (630), further comprising: tinning the multi-layer board (10), so as to coat the first copper layer ( 610), the surface of the second copper layer (620) and the surface of the conductive layer (500) located on the designated core board (100) to form a tin layer (800); and etching the multilayer board (10) , removing the isolated copper ring (630) and the conductive layer (500) located on the first core board (210).
  6. 如权利要求5所述的PCB的制备方法,对所述多层板(10)蚀刻的步骤后,还包括:去除所述锡层(800)。The method for preparing a PCB according to claim 5, after the step of etching the multilayer board (10), further comprises: removing the tin layer (800).
  7. 如权利要求5所述的PCB的制备方法,其中,所述对所述多层板(10)进行蚀刻,去除所述第一铜层(610)对应所述间隙(700a)的孔铜,以在所述第一铜层(610)形成孤立的铜环(630),包括:去除所述干膜图形(700)。The method for preparing PCB according to claim 5, wherein said etching the multilayer board (10) removes the hole copper corresponding to the gap (700a) of the first copper layer (610), so as to Forming an isolated copper ring (630) on the first copper layer (610) includes: removing the dry film pattern (700).
  8. 如权利要求1至7中任意一项所述的PCB的制备方法,其中,所述将位于所述指定芯板(100)的导电层(500)与位于所述第一芯板(210)的导电层(500)断开,包括以下步骤中的至少一个:The method for preparing PCB according to any one of claims 1 to 7, wherein the conductive layer (500) to be located on the specified core board (100) and the conductive layer (500) located on the first core board (210) Disconnecting the conductive layer (500) includes at least one of the following steps:
    激光烧蚀位于所述吸水树脂(400)的导电层(500)和突出于所述通孔(10a)孔壁的吸水树脂(400)中的至少一种,以断开位于所述指定芯板(100)的导电层(500)与位于所述第一芯板(210)的导电层(500);和Laser ablation of at least one of the conductive layer (500) located on the water-absorbing resin (400) and the water-absorbing resin (400) protruding from the wall of the through hole (10a), so as to disconnect the conductive layer (500) located on the designated core board The conductive layer (500) of (100) and the conductive layer (500) located on the first core board (210); and
    采用碱性溶液对所述通孔(10a)进行清洗,以去除所述吸水树脂(400),使位于所述指定芯板(100)的导电层(500)与位于所述第一芯板(210)的导电层(500)断开。The through hole (10a) is cleaned with an alkaline solution to remove the water-absorbing resin (400), so that the conductive layer (500) located on the specified core board (100) and the conductive layer (500) located on the first core board ( 210) of the conductive layer (500) is disconnected.
  9. 如权利要求1至7中任意一项所述的PCB的制备方法,其中,所述吸水树脂(400)包括水凝胶,所述水凝胶包括聚丙烯酸钠和聚丙烯酰胺中的一种或两种。The method for preparing PCB according to any one of claims 1 to 7, wherein the water-absorbing resin (400) comprises a hydrogel, and the hydrogel comprises one or more of sodium polyacrylate and polyacrylamide two kinds.
  10. 一种PCB,所述PCB采用如权利要求1至9任意一项的所述PCB的制备方法制备得到。A PCB, which is prepared by the PCB preparation method according to any one of claims 1 to 9.
PCT/CN2022/099434 2021-12-14 2022-06-17 Method for preparing pcb, and pcb WO2023109051A1 (en)

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