Classifications

• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
  • C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B22—CASTING; POWDER METALLURGY
  • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
  • B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
  • B22F3/02—Compacting only
  • B22F3/04—Compacting only by applying fluid pressure, e.g. by cold isostatic pressing [CIP]
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B22—CASTING; POWDER METALLURGY
  • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
  • B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
  • B22F5/10—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of articles with cavities or holes, not otherwise provided for in the preceding subgroups
  • B22F5/106—Tube or ring forms
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B22—CASTING; POWDER METALLURGY
  • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
  • B22F9/00—Making metallic powder or suspensions thereof
  • B22F9/02—Making metallic powder or suspensions thereof using physical processes
  • B22F9/06—Making metallic powder or suspensions thereof using physical processes starting from liquid material
  • B22F9/08—Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying
  • B22F9/082—Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying atomising using a fluid
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C33/00—Making ferrous alloys
  • C22C33/02—Making ferrous alloys by powder metallurgy
  • C22C33/0257—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements
  • C22C33/0278—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5%
  • C22C33/0285—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5% with Cr, Co, or Ni having a minimum content higher than 5%
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/001—Ferrous alloys, e.g. steel alloys containing N
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
• • C—CHEMISTRY; METALLURGY
  • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
  • C22C—ALLOYS
  • C22C38/00—Ferrous alloys, e.g. steel alloys
  • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
  • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
  • C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B22—CASTING; POWDER METALLURGY
  • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
  • B22F9/00—Making metallic powder or suspensions thereof
  • B22F9/02—Making metallic powder or suspensions thereof using physical processes
  • B22F9/06—Making metallic powder or suspensions thereof using physical processes starting from liquid material
  • B22F9/08—Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying
  • B22F9/082—Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying atomising using a fluid
  • B22F2009/0824—Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying atomising using a fluid with a specific atomising fluid
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B22—CASTING; POWDER METALLURGY
  • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
  • B22F2301/00—Metallic composition of the powder or its coating
  • B22F2301/35—Iron
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B22—CASTING; POWDER METALLURGY
  • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
  • B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
  • B22F2998/10—Processes characterised by the sequence of their steps
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B22—CASTING; POWDER METALLURGY
  • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
  • B22F2999/00—Aspects linked to processes or compositions used in powder metallurgy
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B22—CASTING; POWDER METALLURGY
  • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
  • B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
  • B22F3/12—Both compacting and sintering
  • B22F3/14—Both compacting and sintering simultaneously
  • B22F3/15—Hot isostatic pressing

Definitions

• the present disclosure relates to a ferritic iron-chromium-aluminum (FeCrAl) powder which will provide an object composed of said powder with a combination of good formability, form stability, oxidation resistance and creep resistance.
• the present disclosure also relates to a seamless tube comprising a FeCrAl alloy which has been manufactured from said powder.
• Iron-chromium-aluminium (FeCrAl) alloys which are manufactured from FeCrAl powders having a chromium (Cr) content of 15 to 25 wt% and an aluminum (Al) content from 3 to 6 wt% are well known for their ability to form protective a-alumina (AI2O3), aluminum oxide scales when exposed to temperatures between 900 and 1300 °C. These alloys are good in applications wherein there is a need for good oxidation resistance.
• the present disclosure therefore provides a ferritic iron-chromium-aluminum (FeCrAl) powder having a composition which has been optimized for providing an object, such as a tube, such as a seamless tube, with excellent mechanical properties, good creep strength, good oxidation resistance and which will provide for that essentially no cracks are formed during the manufacturing process.
• an object such as a tube, such as a seamless tube
• the FeCrAl powder according to the present disclosure is characterized in that it has the following composition (in weight%):
• the present disclosure relates to a FeCrAl powder characterized in that it has the following composition in weight% (wt%):
• the present disclosure also relates to a FeCrAl powder characterized in that it has the following composition in weight% (wt%):
• the present disclosure also relates to an object comprising an alloy having the following composition in weight% (wt%):
• the present disclosure also relates to an object comprising an alloy having the following composition in weight% (wt%):
• the object may be a tube, such as a seamless tube.
• the main function for iron in the FeCrAl powder is to balance the composition.
• Chromium is an important element since it will improve the corrosion resistance and increase the tensile and yield strength. Further, chromium facilitates the formation of the AI2O3 layer on the surface through the so-called third element effect, i.e., by formation of chromium oxide in the transient oxidation stage. Too low amount of chromium will result in loss of corrosion resistance. Thus, chromium shall be present an amount of at least 19.0 wt%, such as at least 20.0 wt%. Too much chromium will enable a to decompose to a and also enable 475°C embrittlement and will also lead to an increased solid solutioning hardening effect on the ferritic structure.
• the maximum content of chromium is set to 23.0 wt%, such as maximum 22.0 wt %.
• the Cr content is from 19 to 23 wt%, such as from 20 to 22 wt%.
• Aluminum is an important element since aluminum, when exposed to oxygen at high temperatures, will form a dense and thin AI2O3 layer on the surface, which will protect the underlying surface from further oxidation. Further, aluminum increases the electrical resistivity. At too low amounts of aluminum, the electrical resistivity will be reduced, and there will be a loss of the ability for the formation of AI2O3 layer and thereby the oxidation resistance will be reduced. Thus, aluminum shall be present in an amount of at least 4.0 wt%, such as at least 4.5 wt%. Too high content of aluminum will cause brittleness at low temperatures and will also enhance the formation of unwanted brittle aluminides. Thus, the maximum aluminum is set to 6.0 wt%, such as maximum 5.5 wt%. According to embodiments, the Al content is 4.0 to 6.0 wt%, such as from 4.5 to 5.5 wt%.
• Titanium is added in order to bind any free carbon or nitrogen.
• the content is from 0.01 to 0.15 wt%, such as 0.01 to 0.10 wt%.
• Nitrogen is included to increase strength by precipitation hardening. At too high levels, nitrogen may have a negative effect on the corrosion resistance. Therefore, the maximum amount of nitrogen is 0.10 wt%. According to embodiments, the content of N is 0.02 - 0.08 wt%, such as 0.02 to 0,06 wt%.
• Zirconium is an important element as zirconium will reduce the activity of C and N by the formation of ZrC or ZrN precipitates. Zirconium will also improve the high temperature creep strength. Too low amount of Zr will increase the risk of the formation of unwanted carbides. Accordingly, zirconium shall be present in an amount of at least 0.05 wt%, such as at least 0.08 wt%, such as at least 0.10 wt%. On the other hand, too high content of zirconium may have a negative impact on the formation of AI2O3. For these reasons, the maximum content of zirconium is set to 0.20 wt%, such as maximum 0.17 wt%. Yttrium (Y) 0.01 to 0.10 wt%
• Ytrium is added to improve the oxidation resistance.
• too high content of yttrium will cause hot embritlement.
• too high content of yttrium will enhance the formation of clusters of ytrium oxide which will cause embritlement and thus poor hot and cold formability.
• the maximum content of yttrium content is set to 0.10 wt%, such as max 0.07 wt%, such as max 0.06 wt%, such as max 0.05 wt%.
• Carbon is added to increase strength by precipitation hardening. Too high content of carbon may result in difficulties to form the material and will also have a negative effect on the corrosion resistance. Therefore, the maximum amount of carbon is 0.05 wt%.
• Silicon is present in levels of ⁇ 0.50 wt% in order to increase electrical resistivity and corrosion resistance. However, above this level, the hardness will increase and also there will be britleness at low temperatures.
• Oxygen is present in the form of oxides.
• the maximum content allowed is ⁇ 0.04 wt%.
• the maximum content of oxygen is ⁇ 0.03. The inventors have surprisingly found that by having an excess of oxygen in relation to Y, the formation of brittle phases will be reduced which will improve the hot ductility.
• Hafnium is included in the present powder in order to bind any free nitrogen or carbon, which otherwise affect corrosion resistance negatively.
• the content of Hf is 0.05 to 0.30 wt%, such as 0.05 to 0.25 wt%, such as 0.15 to 0.25 wt%.
• Tantalum is included in order to bind any free nitrogen or carbon, which otherwise would affect corrosion resistance negatively.
• the content of Ta is 0.01 to 0.20 wt%, such as 0.01 to 0.20 wt%.
• Manganese is an optional alloying element. A too high content of Mn will reduce the formation of the alumina layer. Accordingly, the content of Mn is set at maximum 0.30 wt%.
• the powder or the object may also include minor fractions of one or more of the following impurity elements such as but not limited to; Magnesium (Mg), Nickel (Ni), Cerium (Ce), Calcium (Ca), Phosphorus (P), Tungsten (W), Cobalt (Co), Sulphur (S), Molybdenum (Mo), Niobium (Nb), Vanadium (V) and Copper (Cu).
• impurity elements such as but not limited to; Magnesium (Mg), Nickel (Ni), Cerium (Ce), Calcium (Ca), Phosphorus (P), Tungsten (W), Cobalt (Co), Sulphur (S), Molybdenum (Mo), Niobium (Nb), Vanadium (V) and Copper (Cu).
• impurity elements are meant that they are present due to productions methods and/or material used in the manufacture process but they are present in such small amounts that they do not affect the properties.
• the FeCrAl powder or FeCrAl object as defined hereinabove or hereinafter may comprise the alloying elements mentioned herein in any of the ranges mentioned herein.
• the present powder or object consists of all the alloying elements mentioned herein, in any of the ranges mentioned herein.
• another aspect of the present disclosure is to provide tube, such as a seamless tube, which have good mechanical properties and essentially no cracks and which can be manufactured through rolling.
• the present powder as defined hereinabove or hereinafter may also be used for manufacturing a wire or a sheet or a strip or the like.
• the FeCrAl powder as defined hereinabove or hereinafter may be manufactured through different methods. For example, but not limited to: directly by gas atomization; - heating a powder comprising all the alloying element in the ranges mentioned hereinabove or hereinafter;
• An object such as a tube or a seamless tube is manufactured through conventional processes including the steps of hot and cold working.
• a billet is manufactured by using, e.g. hot isostatic pressing (HIP).
• HIP hot isostatic pressing
• the seamless tube and other objects obtained from the FeCrAl powder as defined hereinabove or hereinafter will operate well in high temperatures up to 1250°C. Furthermore, the present object will have a significant high-temperature corrosion resistance and a high resistance against oxidation, sulphurization and carburization. Additionally, the tube will have significant high-temperature creep strength, form stability and high electrical resistivity and ductility. The tube is especially useful as an electrical heating element or as a component in high temperature applications.
• the tube may be a hot worked tube or a hot worked and cold worked tube, such as a hot worked and cold rolled tube.
• Powders (Table 1 A) with the chemical composition in wt% according to Table 1 were produced using gas atomization and then sieved to suitable fraction so that powders with particle size of less than 750 pm were obtained.
• Powder 1 and Powder 2 are powders within the present disclosure. Table 1A
• Table IB The condition: 2*[Y]-3*[O] ⁇ 0
• the powders (see Table 1 A) were HIP:ed with 3 h holding time at 1150°C and 100 MPa pressure followed by a slow cooling to extrusions billets with a dimension of 0121 mm. From the extrusion billets were sample pieces taken to be used for the Gleeble testing (see Table 2)
• Gleeble tests were performed accordingly: Tensile test specimens are heated to a set temperature with a specific heating profile/rate which are measured by thermocouples in a Gleeble system (Gleeble instrument). The set temperature can be reached by heating to desired temperature (ONH), or by cooling from a higher temperature (ONC). After a specified holding time at the desired temperature tensile tests are conducted by applying a tensile displacement rate of 50 mm/s on a cylindrical specimen having a 40 mm long reduced section. The area reduction of the tensile specimen at the fracture point is then measured which provides a measurement of the hot ductility. The result is shown in Table 2.

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• 2022
  • 2022-11-10 EP EP22893376.8A patent/EP4430221A4/en active Pending
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