WO2023065238A1 - Insecticidal composition containing alkylphenyl thioether derivative, and application thereof - Google Patents

Insecticidal composition containing alkylphenyl thioether derivative, and application thereof Download PDF

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WO2023065238A1
WO2023065238A1 PCT/CN2021/125382 CN2021125382W WO2023065238A1 WO 2023065238 A1 WO2023065238 A1 WO 2023065238A1 CN 2021125382 W CN2021125382 W CN 2021125382W WO 2023065238 A1 WO2023065238 A1 WO 2023065238A1
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component
insecticidal composition
present application
composition according
components
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PCT/CN2021/125382
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French (fr)
Chinese (zh)
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罗昌炎
布里斯托·詹姆斯·蒂莫西
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江苏龙灯化学有限公司
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Priority to CN202180095942.0A priority Critical patent/CN117042607A/en
Priority to PCT/CN2021/125382 priority patent/WO2023065238A1/en
Publication of WO2023065238A1 publication Critical patent/WO2023065238A1/en

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/10Sulfones; Sulfoxides
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/30Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/34Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01PBIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P7/00Arthropodicides
    • A01P7/02Acaricides
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01PBIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P7/00Arthropodicides
    • A01P7/04Insecticides

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  • Life Sciences & Earth Sciences (AREA)
  • Plant Pathology (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Pest Control & Pesticides (AREA)
  • Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Chemical & Material Sciences (AREA)
  • Insects & Arthropods (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present application relates to an insecticidal composition containing an alkylphenyl thioether derivative, and an application thereof in controlling animal pests. The present application also relates to a method for preventing and/or treating a pest infestation in a plant, a plant part and/or a surrounding environment by the insecticidal composition. When the insecticidal composition in the present application is applied to plants, plant parts and/or the surrounding environments thereof, especially when applied on cotton, citrus, vegetables, soybeans, potatoes and fruit trees, excellent and synergistic effects in preventing and treating pest infestation can be observed.

Description

含有烷基苯基硫醚衍生物的杀虫组合物及其用途Insecticidal compositions containing alkylphenyl sulfide derivatives and uses thereof 技术领域technical field
本申请涉及含有烷基苯基硫醚衍生物的杀虫组合物及其用于防治动物害虫的用途。本申请还涉及所述的杀虫组合物来预防和/或处理植物、植物部分和/或周围环境中害虫感染的方法。The present application relates to pesticidal compositions containing alkylphenyl sulfide derivatives and their use for controlling animal pests. The present application also relates to methods for preventing and/or treating pest infestations in plants, plant parts and/or the surrounding environment with said pesticidal composition.
背景技术Background technique
害虫感染对重要经济农作物(例如大豆和棉花)而言是主要威胁。作物的产量受到害虫侵袭的负面影响。化学控制是防止和控制农业中害虫的重要方式。但是,但由世界上使用单一活性的杀虫剂直接制剂的经验指出,存在产生抗性害虫亚群的高风险。世界上已报道越来越多的农作物、果实、蔬菜等的害虫产生抗性。此外,目前对杀虫剂的环境和经济要求(例如在作用谱、毒性、选择性、施用率、残余物的形成以及良好的制备能力方面)不断增多。Pest infestation is a major threat to commercially important crops such as soybeans and cotton. Crop yields are negatively affected by pest infestation. Chemical control is an important way to prevent and control pests in agriculture. However, world experience with direct formulations of insecticides with single activity points to a high risk of developing resistant subpopulations of pests. It has been reported that more and more crops, fruits, vegetables and other pests have developed resistance in the world. In addition, the environmental and economic requirements placed on pesticides (for example with regard to spectrum of action, toxicity, selectivity, application rates, formation of residues and good preparation capabilities) are currently constantly increasing.
由下式(I)表示的烷基苯基硫醚衍生物,其在专利文献WO2013157229A1被描述,并且记载了其对各种有害生物,特别是对二斑叶螨、神泽氏叶螨、桔全爪螨等为代表的叶螨类显示出卓越的效果。该物质的活性很好,但在低施用量时有时仍有不足之处。The alkylphenyl sulfide derivative represented by the following formula (I) is described in the patent document WO2013157229A1, and it is recorded that it is effective against various harmful organisms, especially against Tetranychus urticae, Tetranychus kamizawa, Tetranychus represented by Panonychus and the like show excellent effects. The activity of this substance is very good, but sometimes still insufficient at low application rates.
Figure PCTCN2021125382-appb-000001
Figure PCTCN2021125382-appb-000001
发明内容Contents of the invention
本申请涉及一种包含组分(A)和(B)的杀虫组合物,组分(A)是选自烷基苯基硫醚衍生物的式I化合物,组分(B)是选自阿维菌素、丁醚脲、虱螨脲中的至少一种化合物。The application relates to a pesticidal composition comprising components (A) and (B), wherein component (A) is a compound of formula I selected from alkylphenyl sulfide derivatives, and component (B) is selected from At least one compound among abamectin, diafenthiuron and lufenuron.
Figure PCTCN2021125382-appb-000002
Figure PCTCN2021125382-appb-000002
本申请的杀虫组合物可优选地包含如下组分的组合:The pesticidal composition of the present application may preferably comprise the combination of following components:
(A)式I化合物和(B)阿维菌素;(A) formula I compound and (B) Abamectin;
(A)式I化合物和(B)丁醚脲;以及(A) a compound of formula I and (B) diafenthiuron; and
(A)式I化合物和(B)虱螨脲。(A) a compound of formula I and (B) lufenuron.
当组分(A)和(B)以特定重量比存在时,表现出特别明显的改善效果。具体而言,本申请的组合物中的组分(A)和(B)的重量比优选是约50:1至约1:50,更优选约25:1至约1:25,或约15:1至约1:15或约10:1至约1:10。A particularly pronounced improvement is exhibited when components (A) and (B) are present in a specific weight ratio. Specifically, the weight ratio of components (A) and (B) in the composition of the present application is preferably about 50:1 to about 1:50, more preferably about 25:1 to about 1:25, or about 15 :1 to about 1:15 or about 10:1 to about 1:10.
通常本申请活性成分组合包含(A)式I化合物和(B)下表所给出的优选和特别优选的混合比的混合配对物。The active ingredient combinations according to the application generally comprise (A) the compound of the formula I and (B) the mixing partners in the preferred and particularly preferred mixing ratios given in the table below.
组分(B)Component (B) 优选的混合比preferred mixing ratio 更加优选的混合比more preferred mixing ratio 特别优选的混合比Particularly preferred mixing ratios
阿维菌素Avermectin 25:1至1:2525:1 to 1:25 10:1至1:110:1 to 1:1 5:1至1:15:1 to 1:1
丁醚脲Diafenthiuron 50:1至1:5050:1 to 1:50 10:1至1:4010:1 to 1:40 1:1至1:201:1 to 1:20
虱螨脲Lufenuron 10:1至1:1010:1 to 1:10 5:1至1:55:1 to 1:5 2:1至1:22:1 to 1:2
*混合比基于重量比。该比理解为式组分(A):组分(B)。*Mix ratios are based on weight ratios. This ratio is understood as the formula component (A):component (B).
本申请进一步涉及本申请的杀虫组合物在预防和/或处理植物、植物部分和/或其周围环境中害虫侵袭方面的用途。The present application further relates to the use of the pesticidal composition of the present application for the prevention and/or treatment of pest infestation in plants, plant parts and/or their surroundings.
所述杀虫组合物对于保护作物免受害虫侵袭方面是非常有效的。所述害虫例如但不限于:直翅目害虫、缨翅目害虫、半翅目害虫、鞘翅目害虫、双翅目害虫、鳞翅目害虫、膜翅目害虫、等翅目害虫、植物寄生性螨类等有害生物。作为这样的有害生物的例子,示出如下。The pesticidal composition is very effective in protecting crops from pests. The pests are for example but not limited to: Orthoptera pests, Thysanoptera pests, Hemiptera pests, Coleoptera pests, Diptera pests, Lepidoptera pests, Hymenoptera pests, Isoptera pests, plant parasitic pests such as mites. Examples of such harmful organisms are shown below.
鳞翅目害虫:螟蛾科(Pyralidae)例如二化螟(chilosuppressalis(walker)、 三化螟(Tryporyzaincertulas(walker))、稻纵卷叶螟(cnaphalocrocismedinalis Guenee)、菜心螟(hellullaundalis)、桃蛀螟(conogethes punctiferlis);粉蝶科(Pieridae)例如菜粉蝶(Pieris rapae))、柑桔凤蝶(papilioxuthus)、白粉蝶(pierisrapaecrucivora)、直纹稻弄蝶(parnaraguttata);灯蛾科(Arctiidae)如美国白蛾(hyphantriacunea);夜蛾科(Noctuidae)如粉纹夜蛾(trichoplusiani)、甘蓝夜蛾(mamestrabrassicae)、甜菜夜蛾(spodopteraexigua)、斜纹夜蛾(spodopteralitura)、棉铃虫(helicoverpa armigera)、东方粘虫(Pseudaletia separate)、小地老虎(Agrotis ipsilon);卷蛾科(Tortricidae)如茶小卷叶蛾(adoxophyes orana fasciata)、杏黄卷蛾(archipsfuscocureanus)、茶长卷蛾(homona magnanima);菜蛾科(Plutellidae)如小菜蛾(plutellaxylotella);麦蛾科(Gelechiidae)如棉红铃虫(pectinophora gossypiella)、红铃麦蛾(Pink bollworm);Lepidoptera pests: Pyralidae, such as chilosuppressalis (walker), tryporyzaincertulas (walker), rice leaf roller (cnaphalocrocismedinalis Guenee), cabbage borer (hellullaundalis), peach borer Borer (conogethes punctiferlis); Pieridae such as Pieris rapae), citrus swallowtail (papilioxuthus), white butterfly (pierisrapaecrucivora), straight-grained rice butterfly (parnaraguttata); Arctiidae such as American white moth (hyphantriacuunea); family Noctuidae such as trichoplusiani, cabbage armyworm (mamestrabrassicae), beet armyworm (spodoptera exigua), litura armyworm (spodoptera litura), cotton bollworm (helicoverpa armigera), Eastern armyworm (Pseudaletia separate), small cutworm (Agrotis ipsilon); Tortricidae such as adoxophyes orana fasciata, apricot yellow tortrix (archipsfuscocureanus), tea long tortrix (homona magnanima); (Plutellidae) such as diamondback moth (plutellaxylotella); Gelechiidae (Gelechiidae) such as cotton pink bollworm (pectinophora gossypiella), red bollworm (Pink bollworm);
半翅目害虫,例如:如蚜科(Aphididae)、球蚜科(Adelgidae)或根瘤蚜科(Phylloxeridae),如烟蚜(Myzus persicae)、棉蚜(Aphis gossypii)、黑豆蚜(Aphis fabae)、玉米蚜(Aphis maidis)(玉米叶蚜)、豌豆蚜(Acyrthosiphon pisum)、茄无网蚜(Aulacorthum solani)、豆蚜(Aphis craccivora)、大戟长管蚜(Macrosiphum euphorbiae)、麦长管蚜(Macrosiphum avenae)、麦无网长管蚜(Metopolophium dirhodum)、禾谷缢管蚜(Rhopalosiphum padi)、麦二叉蚜(Schizaphis graminum)、甘蓝蚜(Brevicoryne brassicae)、萝卜蚜(Lipaphis erysimi)、绣线菊蚜(Aphis citricola)、玫瑰苹果蚜(Rosy apple aphid)、苹果绵蚜(Eriosoma lanigerum)、桔二叉蚜(Toxoptera aurantii)和大桔蚜(Toxoptera citricidus);叶蝉科(Cicadellidae),如黑尾叶蝉(Nephotettix cincticeps);飞虱科(Delphacidae),如灰飞虱(Laodelphax striatellus)、褐飞虱(Nilaparvata lugens)和白背飞虱(Sogatella furcifera);蝽科(Pentatomidae),例如白星蝽象(Eysarcoris ventralis)、稻绿蝽(Nezara viridula);粉虱科(Aleyrodidae),例如烟粉虱(Bemisia tabaci)和温室粉虱(Trialeurodes vaporariorum);盾蚧科(Diaspididae)、蛛蚧科(Margarodidae)、旌蚧科(Ortheziidae)、Aclerdiae、胭蚧科(Dactylopiidae)、胶蚧科(Kerridae)、粉蚧科(Pseudocoddidae);蜡蚧科(Coccidae);绒蚧科(Eriococcidae);链蚧科(Asterolecaniidae)、球链蚧科(Lecanodiaspididae);或壶蚧科(Cerococcidae),例如康氏粉蚧(Pseudococcus comstocki)和柑橘粉介壳虫(Planococcus citri Risso);木虱科(Psyllidae)如梨木虱(psyllapyrisuga)、 柑橘木虱(diaphorinatabaci);Pests of the order Hemiptera, e.g. such as Aphididae, Adelgidae or Phylloxeridae, such as Myzus persicae, Aphis gossypii, Aphis fabae, Aphis maidis (maize leaf aphid), pea aphid (Acyrthosiphon pisum), eggplant aphid (Aulacorthum solani), bean aphid (Aphis craccivora), euphorbia aphid (Macrosiphum euphorbiae), wheat aphid ( Macrosiphum avenae), Metopolophium dirhodum, Rhopalosiphum padi, Schizaphis graminum, Brevicoryne brassicae, Lipaphis erysimi Aphis citricola, Rosy apple aphid, Eriosoma lanigerum, Toxoptera aurantii, and Toxoptera citricidus; leafhoppers (Cicadellidae), such as black Nephotettix cincticeps; Delphacidae such as the gray planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens) and white-backed planthopper (Sogatella furcifera); Pentatomidae such as the white star bug ( Eysarcoris ventralis), Nezara viridula; Aleyrodidae, such as Bemisia tabaci and Trialeurodes vaporariorum; Diaspididae, Margarodidae, Ortheziidae, Aclerdiae, Dactylopiidae, Kerridae, Pseudocoddidae; Coccidae; Eriococcidae; Asterolecaniidae , Lecanodiaspididae; or Cerococcidae such as Pseudococcus comstocki and Planococcus citri Risso; Psyllidae such as psyllapyrisuga, Citrus psyllid (diaphorinatabaci);
鞘翅目害虫,例如:米象(sitophilus oryzae linne)、柑橘潜叶甲(PodagricomelanigricollisChe)、玉米象(S.zeamails)、谷象(S.granarius)、大猿叶虫(Cabbageleafbeetle)、小猿叶虫(Daikon leaf beele),跳甲(fleabeetle)、葡萄跳甲(Alticachalybea)、曲条跳甲(phyllotretastriolata)、黄瓜跳甲(Epitrixcucumeris)、烟草跳甲(Ehirtipennis)、茄跳甲(E.fuscula)、黄守瓜(Aulacophoraindica(Gemlin)、稻水象甲(Lissorhoptrus oryzophilus)、Callosobruchuys chienensis、黄粉虫(Tenebrio molitor)、玉米根萤叶甲(Diabrotica virgifera virgifera)、黄瓜甲虫(Diabrotica undecimpunctata howardi)、铜绿金龟(Anomala cuprea)、红铜丽金龟(Anomala rufocuprea)、黄曲条菜跳甲(Phyllotreta striolata)、黄守瓜(Aulacophora femoralis)、马铃薯甲虫(Leptinotarsa decemlineata)、稻负泥虫(Oulema oryzae)、bostrychidae和天牛科(Cerambycidae);Coleopteran pests such as: rice weevil (sitophilus oryzae linne), citrus leafminer (Podagricomelanigricollis Che), corn weevil (S. zeamails), grain weevil (S. granarius), great ape leaf beetle (Cabbageleafbeetle), lesser ape beetle (Daikon leaf beele), Fleabeetle, Alticachalybea, Phyllottretastriolata, Epitrixcucumeris, Ehirtipennis, E.fuscula, Aulacophora indica (Gemlin), Lissorhoptrus oryzophilus, Callosobruchuys chienensis, Tenebrio molitor, Diabrotica virgifera virgifera, Cucumber beetle (Diabrotica undecimpunctata howardi), Anomala cuprea ), Anomala rufocuprea, Phyllotreta striolata, Aulacophora femoralis, Potato beetle (Leptinotarsa decemlineata), Oulema oryzae, bostrychidae and Beetles ( Cerambycidae);
双翅目害虫,例如:稻潜蝇(agromyzaoryzae)、大麦水蝇(hydrelliagriseola)、非洲菊斑潜蝇(liriomyzatrifolii)、豌豆叶潜蝇(chromatomyiahorticola)、番茄斑潜蝇(liriomyzabryoniae)、灰地种蝇(deliaplatura)、葱地种蝇(deliaantiqua)地中海实蝇(ceratitiscapiata wiedgman)、苹果实蝇(Rhagoletis pomonella)、樱桃实蝇(R.cingulata);Pests of the order Diptera, for example: agromyzaoryzae, barley waterfly (hydrelliagriseola), gerbera leafminer (liriomyzatrifolii), pea leafminer (chromatomyiahorticola), tomato leafminer (liriomyzabryoniae), gray field fly (deliaplatura), onion fruit fly (delia antiqua), Mediterranean fruit fly (ceratitis scapiata wiedgman), apple fruit fly (Rhagoletis pomonella), cherry fruit fly (R. cingulata);
鞘翅目(Coleoptera)害虫,例如稻水象甲(Lissorhoptrus oryzophilus)、Callosobruchuys chienensis、黄粉虫(Tenebrio molitor)、玉米根萤叶甲(Diabrotica virgifera virgifera)、黄瓜甲虫(Diabrotica undecimpunctata howardi)、铜绿金龟(Anomala cuprea)、红铜丽金龟(Anomala rufocuprea)、黄曲条菜跳甲(Phyllotreta striolata)、黄守瓜(Aulacophora femoralis)、马铃薯甲虫(Leptinotarsa decemlineata)、稻负泥虫(Oulema oryzae)、bostrychidae和天牛科(Cerambycidae);Coleoptera pests such as rice water weevil (Lissorhoptrus oryzophilus), Callosobruchuys chienensis, mealworm (Tenebrio molitor), corn root firefly beetle (Diabrotica virgifera virgifera), cucumber beetle (Diabrotica undecimpunctata howardi), verdant beetle (Anomala cuprea), Anomala rufocuprea, Phyllotreta striolata, Aulacophora femoralis, Potato beetle (Leptinotarsa decemlineata), Oulema oryzae, bostrychidae, and the family Beetleidae (Cerambycidae);
蜱螨目的害虫,例如柑橘全爪螨(panonychus citri)、朱砂叶螨(Tetranychus cinnabarinus)、苹果全爪螨(panony ulmi)、二斑叶螨(tetranychus urticae)、山楂叶螨(tetranychus viennensis)、针叶小爪螨(oligonychus ununguis)柑橘始叶螨(eotetranychus kankitus)、紫红短须螨(brevipalpus phoenicis)、苜蓿苔螨(beyrobia redikorzeri)、小麦卷叶螨(aceria tulipae)、葡萄瘿螨(colomerus vitis)、茶叶瘿螨(calacarus carinatus)、茶黄螨(polyphagotarsonemus latus)、长毛根螨 (rhizoglyphus rostochiensis)、粗脚粉螨(Acarussiro)、柑橘瘤瘿螨(Aceriasheldoni)、斯氏针刺瘿螨(Aculusschlechtendali)、柑橘锈螨(Phyllocoptes oleiverus ashmead)等;Pests of the order Acarina e.g. Panonychus citri, Tetranychus cinnabarinus, Panonychus ulmi, Tetranychus urticae, Tetranychus viennensis, Tetranychus viennensis Oligonychus ununguis Eotetranychus kankitus, Brevipalpus phoenicis, Beyrobia redikorzeri, Aceria tulipae, Colomerus vitis , tea gall mite (calacarus carinatus), tea yellow mite (polyphagotarsonemus latus), long-haired root mite (rhizoglyphus rostochiensis), rough-legged meal mite (Acarussiro), citrus tumor gall mite (Aceriasheldoni), citrus tumor gall mite (Aculus schlechtendali) , citrus rust mite (Phyllocoptes oleiverus ashmead), etc.;
缨翅目(Thysanopteran)害虫,例如棕榈蓟马(Thrips palmi)、西花蓟马(Frankliniella occidentalis)、烟蓟马(Thrips alliorum(Priesner))、黄胸蓟马(Thrips hawaiiensis(Morgan)、茶黄蓟马(Scirtothrips dorsalis Hood)、花蓟马(Frankliniella intonsa(Trybom)等;以及Thysanopteran pests such as Thrips palmi (Thrips palmi), Western flower thrips (Frankliniella occidentalis), tobacco thrips (Thrips alliorum (Priesner)), yellow-breasted thrips (Thrips hawaiiensis (Morgan) Thrips (Scirtothrips dorsalis Hood), Frankliniella intonsa (Trybom), etc.; and
直翅目(Orthopteran)害虫,例如剑角蝗科(Acrididae);臭蝽(megacoptapunctatissimum)、菜蝽(eurydemarugosum)、大刺白星蝽(eysarcorislewisi)、白星蝽(eysarcorisparvus)、稻绿蝽(nezaraviridula)、斯氏珀蝽(plautiastali)、臭梧桐蝽(halymorphamista)、稻棘缘蝽(cletuspunctiger)、中华稻缘蝽(leptocorisachinensis)、杜鹃网蝽(stephantispyrioides)、赤须盲蝽(trigonotyluscoelestialium)。Pests of the order Orthopteran, for example Acrididae; megacopta punctatissimum, eurydemarugosum, eysarcorislewisi, eysarcorisparvus, nezaraviridula, Plautiastali, halymorphamista, cletus punctiger, leptocoris achinensis, stephantispyrioides, trigonotyluscoelestialium.
本申请的杀虫组合物优选对鳞翅目、半翅目、双翅目、缨翅目、蜱螨目害虫特别有效。特别是蜱螨目害虫。特别的,本申请的杀虫组合物对以下害虫特别有效,具体包括:The pesticidal composition of the present application is preferably particularly effective against pests of the orders Lepidoptera, Hemiptera, Diptera, Thysanoptera and Acarina. Especially acarids. In particular, the pesticidal composition of the present application is particularly effective against the following pests, specifically including:
夜蛾科(Noctuidae)如粉纹夜蛾(trichoplusia ni)、甘蓝夜蛾(mamestra brassicae)、甜菜夜蛾(spodoptera exigua)、斜纹夜蛾(spodoptera litura)、棉铃虫(helicoverpaarmigera)、东方粘虫(Pseudaletia separate)、小地老虎(Agrotis ipsilon);Noctuidae such as Trichoplusia ni, Mamestra brassicae, Spodoptera exigua, Spodoptera litura, Helicoverpa armigera, Eastern armyworm ( Pseudaletia separate), lesser cutworm (Agrotis ipsilon);
卷蛾科(Tortricidae)如茶小卷叶蛾(adoxophyes orana fasciata)、杏黄卷蛾(archipsfuscocureanus)、茶长卷蛾(homonamagnanima);Tortricidae such as adoxophyes orana fasciata, archips fuscocureanus, homomagnanima;
菜蛾科(Plutellidae)如小菜蛾(plutellaxylotella);Diamondback moth (Plutellidae) such as diamondback moth (plutellaxylotella);
粉虱科如甘蓝粉虱(Aleurodes brassicae)、烟粉虱(Bemisia tabaci)、温室白粉虱(Trialeurodes vaporariorum);Whitefly family such as cabbage whitefly (Aleurodes brassicae), tobacco whitefly (Bemisia tabaci), greenhouse whitefly (Trialeurodes vaporariorum);
飞虱科(Delphacidae),如灰飞虱(Laodelphax striatellus)、褐飞虱(Nilaparvata lugens)和白背飞虱(Sogatella furcifera);Planthoppers (Delphacidae), such as the brown planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens) and white-backed planthopper (Sogatella furcifera);
叶螨科(Tetranychidae)如朱砂叶螨(Tetranychus cinnabarinus)、二斑叶螨(tetranychus urticae)、山楂叶螨(tetranychus viennensis)、针叶小爪螨(oligonychus ununguis)、柑橘始叶螨(eotetranychus kankitus);Tetranychidae (Tetranychidae), such as Tetranychus cinnabarinus, Tetranychus urticae, Tetranychus viennensis, Oligonychus ununguis, Eotetranychus kankitus;
全爪螨科(Panonychus spp.)如柑橘全爪螨(panonychus citri)、苹果全爪螨(panonychus ulmi);Panonychus spp. such as citrus panonychus citri, apple panonychus ulmi;
瘿螨科((Eriophyoidea)如葡萄瘿螨(colomerusvitis)、茶叶瘿螨(calacaruscarinatus)、柑橘锈壁虱(Phyllocoptes oleivora Ashmead)、柑橘瘤瘿螨(Aceriasheldoni)、斯氏针刺瘿螨(Aculusschlechtendali);Eriophyoidea (e.g. colomerus vitis, calacarus carinatus, Phyllocoptes oleivora Ashmead, Aceriasheldoni, Aculus schlechtendali;
蓟马科(Thripidae)如棕榈蓟马(Thrips palmi)、西花蓟马(Frankliniella occidentalis)、烟蓟马(Thrips alliorum(Priesner))、黄胸蓟马(Thrips hawaiiensis(Morgan)、茶黄蓟马(Scirtothrips dorsalis Hood)、花蓟马(Frankliniella intonsa(Trybom)等;Thrips family (Thripidae) such as Thrips palmi (Thrips palmi), Western flower thrips (Frankliniella occidentalis), tobacco thrips (Thrips alliorum (Priesner)), yellow-breasted thrips (Thrips hawaiiensis (Morgan), (Scirtothrips dorsalis Hood), flower thrips (Frankliniella intonsa (Trybom), etc.;
蚜科如烟蚜(Myzus persicae)、棉蚜(Aphis gossypii)、甘蓝蚜(Brevicoryne brassicae)、禾谷缢管蚜(Rhopalosiphum padi);以及Aphids such as Myzus persicae, Aphis gossypii, Brevicoryne brassicae, Rhopalosiphum padi; and
壶蚧科(Cerococcidae),例如康氏粉蚧(Pseudococcus comstocki)和柑橘粉介壳虫(Planococcus citri Risso)。Cerococcidae, eg Pseudococcus comstocki and Planococcus citri Risso.
特别地,本申请的杀虫组合物对预防或控制菜蛾科、卷蛾科、夜蛾科、飞虱科、粉虱科、叶螨科、全爪螨科、蓟马科、瘿螨科、蚜科、壶蚧科害虫及其幼虫和卵显示令人惊喜的“增效”作用。In particular, the insecticidal composition of the present application is effective for preventing or controlling Plutella, Tortriidae, Noctuidae, Planthoppers, Amyridae, Tetranychidae, Panonychus, Thrips, Eriodidae, Aphids Pests of the family Pyrididae and Coccidae, as well as their larvae and eggs, showed surprising "synergistic" effects.
更特别地,本申请的杀虫组合物对预防或控制柑橘全爪螨、柑橘锈壁虱、朱砂叶螨、二斑叶螨有特别的防效。More particularly, the insecticidal composition of the present application has a special control effect on preventing or controlling Panonychus citrus, citrus rust tick, Tetranychus cinnabarinus, and Tetranychus urticae.
本申请的杀虫组合物适合于农作物植物:谷类(小麦、大麦、黑麦、燕麦、玉米、稻谷、高粱、黑小麦和相关农作物);水果,例如梨果、核果和无核小水果,例如苹果、葡萄、梨子、李子、桃子、杏、樱桃,和浆果,例如草莓、覆盆子和黑莓;豆科植物(豆、小扁豆、豌豆、大豆);产油植物(油菜、芥菜、向日葵);葫芦科(葫芦、黄瓜、西瓜);纤维植物(棉花、亚麻、大麻、黄麻);柑橘,例如橘子、柠檬、柚子和柑橘;蔬菜(菠菜、莴苣、芦笋、甘蓝、胡萝卜、洋葱、番茄、马铃薯、红辣椒);咖啡;甘蔗;以及观赏植物(花,例如玫瑰、灌木、阔叶树和常绿植物,例如松柏类)。优选地,将本申请的组合物施用在棉花、柑橘、蔬菜、大豆、马铃薯、果树上。The insecticidal composition of the present application is suitable for crop plants: cereals (wheat, barley, rye, oats, corn, rice, sorghum, triticale and related crops); fruits, such as pome fruit, drupe fruit and seedless fruit, such as Apples, grapes, pears, plums, peaches, apricots, cherries, and berries such as strawberries, raspberries, and blackberries; legumes (beans, lentils, peas, soybeans); oil-producing plants (canola, mustard, sunflower); Cucurbitaceae (cucurbits, cucumbers, watermelons); fibrous plants (cotton, flax, hemp, jute); citrus fruits such as oranges, lemons, grapefruits, and mandarins; vegetables (spinach, lettuce, asparagus, kale, carrots, onions, tomatoes, potatoes , red pepper); coffee; sugar cane; and ornamental plants (flowers such as roses, shrubs, deciduous trees and evergreens such as conifers). Preferably, the composition of the present application is applied on cotton, citrus, vegetable, soybean, potato, fruit trees.
已惊讶地发现当在植物、植物部分和/或其周围环境施用本申请的杀虫组合物时特别是在棉花、柑橘、蔬菜、大豆、马铃薯、果树上施用时,可观察到在防止和处理害虫侵袭方面的卓越且协同的性能。It has been surprisingly found that when the insecticidal composition of the present application is applied to plants, plant parts and/or their surroundings, especially when applied on cotton, citrus, vegetables, soybeans, potatoes, fruit trees, an increase in the prevention and treatment of Excellent and synergistic performance in pest attack.
本申请所述的组分(A)和(B)可以纯的形式作为固体活性化合物施用和使用,例如以具体的粒径使用,或优选地以常规制剂技术形式与至少一种助剂一起使用,例如一种或多种惰性填料或表面活性剂。通常,组分(A)和(B)以与一种或多种的常规助剂一起形成的制剂形式使用。用于预混合组合物的制剂类型的例子有:可溶液剂(SL)、乳油(EC)、水乳剂(EW)、微乳剂(ME)、油型悬浮剂(OD)、悬浮种衣剂(a flowable suspension)(FS)、水分散粒剂(WG)、可溶粒剂(SG)、可湿性粉剂(WP)、可溶粉剂(SP)、颗粒剂(GR)、微囊粒剂(CG)、细颗粒(FG)、粗颗粒(GG)、悬乳剂(SE)、微囊悬浮剂(CS)、微颗粒(MG)、或优选悬浮剂(SC)。Components (A) and (B) described herein can be applied and used in pure form as solid active compounds, for example in specific particle sizes, or preferably in customary formulation techniques together with at least one auxiliary , such as one or more inert fillers or surfactants. In general, components (A) and (B) are used in the form of formulations together with one or more customary auxiliaries. Examples of formulation types for premix compositions are: soluble concentrate (SL), emulsifiable concentrate (EC), emulsion in water (EW), microemulsion (ME), oily suspension (OD), suspension coating ( a flowable suspension) (FS), water dispersible granules (WG), soluble granules (SG), wettable powder (WP), soluble powder (SP), granules (GR), microencapsulated granules (CG ), fine granules (FG), coarse granules (GG), suspoemulsions (SE), microcapsule suspensions (CS), microparticles (MG), or preferably suspensions (SC).
适用的惰性填料是本领域已知的并且市售可得。合适的固体惰性填料包括,例如,粘土类(高岭土、硅藻土、膨润土、酸性白土等)、滑石及其衍生物、陶瓷、其它无机矿物(钙铁石、石英、活性碳、碳酸钙、水合氧化硅等)、化学肥料(硫酸铵、磷酸铵、硝酸铵、尿素、氯化铵等)等的微粉末或粒状物等。合适的液体惰性填料包括,例如,水;乙酸乙酯、乙酸丁酯等酯类;N,N-二甲基甲酰胺、N,N-二甲基乙酰胺等酰胺类;二甲亚砜;大豆油、棉子油等植物油等。Suitable inert fillers are known in the art and are commercially available. Suitable solid inert fillers include, for example, clays (kaolin, diatomaceous earth, bentonite, acid clay, etc.), talc and its derivatives, ceramics, other inorganic minerals (andrite, quartz, activated carbon, calcium carbonate, hydrous oxide silicon, etc.), chemical fertilizers (ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, ammonium chloride, etc.) Suitable liquid inert fillers include, for example, water; esters such as ethyl acetate and butyl acetate; amides such as N,N-dimethylformamide and N,N-dimethylacetamide; dimethylsulfoxide; Vegetable oils such as soybean oil, cottonseed oil, etc.
本申请所述杀虫组合物还可任选地包含一种或多种表面活性剂。所述表面活性剂可以是离子型或非离子型的乳化剂、分散剂或润湿剂。可用的示例有聚丙烯酸的盐、木质素磺酸的盐、苯磺酸或萘磺酸的盐、环氧乙烷与脂肪醇或与脂肪酸或与脂肪胺的缩聚物、经取代的酚(尤其是烷基酚)、磺基琥珀酸酯的盐、牛磺酸衍生物(尤其是烷基牛磺酸盐),或聚乙氧基化的酚或醇的磷酸酯。The pesticidal compositions described herein may also optionally contain one or more surfactants. The surfactant may be an ionic or nonionic emulsifier, dispersant or wetting agent. Usable examples are salts of polyacrylic acid, lignosulfonic acid, benzenesulfonic acid or naphthalenesulfonic acid, polycondensates of ethylene oxide with fatty alcohols or with fatty acids or with fatty amines, substituted phenols (especially are alkylphenols), salts of sulfosuccinates, taurine derivatives (especially alkyl taurates), or polyethoxylated phosphate esters of phenols or alcohols.
本申请所述的组分(A)和(B)可共同以合适的量存在于所述杀虫组合物中,并且通常存在的量为所述组合物的约1至约70重量%,例如1重量%、5重量%、10重量%、20重量%、25重量%、30重量%、35重量%、40重量%、45重量%、50重量%、60重量%或70重量%,优选为所述组合物的约1至约40重量%,更优选为所述组合物的约1至约20重量%。Components (A) and (B) described herein may be present together in the pesticidal composition in suitable amounts, and are generally present in an amount of about 1 to about 70% by weight of the composition, e.g. 1% by weight, 5% by weight, 10% by weight, 20% by weight, 25% by weight, 30% by weight, 35% by weight, 40% by weight, 45% by weight, 50% by weight, 60% by weight or 70% by weight, preferably From about 1 to about 40% by weight of the composition, more preferably from about 1 to about 20% by weight of the composition.
本申请还涉及提供一种通过在植物、植物部分和/或周围环境施用本申请的杀虫组合物来控制植物、植物部分和/或周围环境的害虫侵袭的方法。所述组合物可在被害虫感染前施用或对抗已经存在的害虫感染,且可通过涂覆而在植物的繁殖部分、特别是种子上施用该组合物。施用方法包括被覆、喷洒、浸蘸、浸湿、注射、灌溉等。The present application also relates to providing a method for controlling pest infestation of plants, plant parts and/or surroundings by applying the pesticidal composition of the present application to the plants, plant parts and/or surroundings. The composition can be applied prior to pest infestation or against an existing pest infestation, and can be applied by coating on reproductive parts of plants, especially seeds. Application methods include covering, spraying, dipping, soaking, injection, irrigation and the like.
组分(A)和组分(B)可以任何所需次序、任何组合,连续或同时施用。另外,在组分(A)和(B)同时施用的情况中,其可以作为包含组分(A)和(B)的组合物来施用。在该情况中,组分(A)和(B)可获自分开的制剂来源并混合在一起(称为罐混型(tank-mix)、即用型、喷汤型或浆料型),任选伴随其它农药,或组分(A)和(B)可作为单一制剂混合物来源获得(称为预混型、浓缩型、配方化合物(或产品)),并任选与其它农药混合在一起。Component (A) and component (B) may be administered in any desired order, in any combination, sequentially or simultaneously. In addition, in the case of simultaneous administration of components (A) and (B), it may be administered as a composition comprising components (A) and (B). In this case, components (A) and (B) may be obtained from separate formulation sources and mixed together (known as tank-mix, ready-to-use, soup spray or slurry), Optionally with other pesticides, or components (A) and (B) can be obtained as a single formulation mixture source (known as premix, concentrate, formulated compound (or product)), and optionally mixed together with other pesticides .
本申请的组合物的施用(应用)率可根据如下因素而变化,例如,根据应用类型、作物类型、组合物中特定活性化合物、植物类型,但需要使所述组合物中的活性成分以提供所需作用(例如害虫或害虫控制)的有效量施用。通常,制剂可用水以约1至约300克总活性成分每公顷的比例稀释,优选比例为约5至约200克总活性成分每公顷,最优选比例为约10至约100克总活性成分每公顷。The rate of application (application) of the compositions of the present application may vary depending on factors such as the type of application, the type of crop, the specific active compound in the composition, the type of plant, but it is necessary for the active ingredients in the composition to provide An effective amount for the desired effect (eg pest or pest control) is applied. Generally, formulations can be diluted with water at a rate of about 1 to about 300 grams of total active ingredient per hectare, preferably at a rate of about 5 to about 200 grams of total active ingredient per hectare, and most preferably at a rate of about 10 to about 100 grams of total active ingredient per hectare. hectare.
本文中所用的“植物”,指的是所有植物和植物种群,例如需要或不需要的野生植物或作物植物。"Plant", as used herein, refers to all plants and plant populations, such as desired or undesired wild plants or crop plants.
本文所用的“植物部分”,指的是植物的所有部分和器官,例如枝条、叶、针叶、茎、干、子实体、果实、种子、根、块茎和根茎。还包括收获的材料,以及无性繁殖材料和有性繁殖材料,例如,插枝、块茎、分生组织、根茎、侧枝、种子、单植物细胞和多植物细胞,以及任何其它植物组织。"Plant parts" as used herein refers to all parts and organs of plants, such as shoots, leaves, needles, stems, trunks, fruiting bodies, fruits, seeds, roots, tubers and rhizomes. Also included are harvested material, and vegetative and generative propagation material, for example cuttings, tubers, meristems, rhizomes, lateral shoots, seeds, single and multiple plant cells, and any other plant tissue.
术语“周围环境”指的是所述植物生长的地点、所述植物的植物繁殖材料播种的地点、或者所述植物的植物繁殖材料将被播种的地点。The term "surrounding environment" refers to the location where the plant grows, the location where plant propagation material of the plant is sown, or the location where plant propagation material of the plant is to be sown.
具体实施方式Detailed ways
为便于理解本申请,本申请列举实施例如下。本领域技术人员应该明了,所述实施例仅仅是帮助理解本申请,不应视为对本申请的具体限制。In order to facilitate understanding of the present application, the present application enumerates the following examples. It should be clear to those skilled in the art that the embodiments are only for helping to understand the present application, and should not be regarded as a specific limitation on the present application.
当组分(A)和(B)以特定重量比存在时,表现出特别明显的改善效果。具体而言,本申请的组合物中的组分(A)和(B)的重量比优选是约50:1至约1:50,例如50:1、45:1、40:1、35:1、30:1、25:1、20:1、15:1、10:1、5:1、1:1、1:5、1:10、1:15、1:20、1:25、1:30、1:35、1:40、1:45、1:50,更优选约25:1至约1:25,或约15:1至约1:15或约10:1至约1:10。A particularly pronounced improvement is exhibited when components (A) and (B) are present in a specific weight ratio. Specifically, the weight ratio of components (A) and (B) in the composition of the present application is preferably from about 50:1 to about 1:50, such as 50:1, 45:1, 40:1, 35: 1, 30:1, 25:1, 20:1, 15:1, 10:1, 5:1, 1:1, 1:5, 1:10, 1:15, 1:20, 1:25, 1:30, 1:35, 1:40, 1:45, 1:50, more preferably about 25:1 to about 1:25, or about 15:1 to about 1:15 or about 10:1 to about 1 :10.
本申请的含有烷基苯基硫醚衍生物的杀虫组合物,所述组分(B)选自阿维 菌素,且所述组分(A)和(B)的重量比是25:1至1:25,例如25:1、20:1、15:1、10:1、5:1、1:1、1:5、1:10、1:15、1:20、1:25,优选10:1至1:1,更优选5:1至1:1。The insecticidal composition containing alkylphenyl sulfide derivatives of the present application, said component (B) is selected from Abamectin, and the weight ratio of said components (A) and (B) is 25: 1 to 1:25, e.g. 25:1, 20:1, 15:1, 10:1, 5:1, 1:1, 1:5, 1:10, 1:15, 1:20, 1:25 , preferably 10:1 to 1:1, more preferably 5:1 to 1:1.
本申请的含有烷基苯基硫醚衍生物的杀虫组合物,所述组分(B)选自丁醚脲,且所述组分(A)和(B)的重量比是50:1至1:50,例如50:1、45:1、40:1、35:1、30:1、25:1、20:1、15:1、10:1、5:1、1:1、1:5、1:10、1:15、1:20、1:25、1:30、1:35、1:40、1:45、1:50,优选10:1至1:40,更优选1:1至1:20。In the insecticidal composition containing alkylphenyl sulfide derivatives of the present application, the component (B) is selected from diafenthiuron, and the weight ratio of the components (A) and (B) is 50:1 to 1:50, such as 50:1, 45:1, 40:1, 35:1, 30:1, 25:1, 20:1, 15:1, 10:1, 5:1, 1:1, 1:5, 1:10, 1:15, 1:20, 1:25, 1:30, 1:35, 1:40, 1:45, 1:50, preferably 10:1 to 1:40, more Preferably 1:1 to 1:20.
本申请的含有烷基苯基硫醚衍生物的杀虫组合物,所述组分(B)选自虱螨脲,且所述组分(A)和(B)的重量比是10:1至1:10,例如10:1、5:1、1:1、1:5、1:10,优选5:1至1:5,更优选2:1至1:2。In the insecticidal composition containing alkylphenyl sulfide derivatives of the present application, the component (B) is selected from lufenuron, and the weight ratio of the components (A) and (B) is 10:1 to 1:10, such as 10:1, 5:1, 1:1, 1:5, 1:10, preferably 5:1 to 1:5, more preferably 2:1 to 1:2.
生物测试:Biological test:
实施例A褐飞虱试验Embodiment A brown planthopper test
将式(I)化合物、阿维菌素的原药分别用溶剂溶解配制单剂的母液,再用含0.1%的Tween-80的水溶液稀释至所需的浓度。Dissolve the compound of formula (I) and the original drug of avermectin in a solvent to prepare a single-dose mother solution, and then dilute to the required concentration with an aqueous solution containing 0.1% Tween-80.
采用稻苗浸渍法进行试验。供试稻苗选用分蘖盛期的无虫TN1苗,试验前1周移栽于小泥盆,置于无虫环境,待稻苗成活后洗净备用。试验时,去除枯黄叶片和多余分蘖(每盆留2~3个有效分蘖),剪去上部,留下部20~25cm植株,浸入配制好的药液内10s,取出晾干稻株表面药液后接虫。选低龄(2~3龄)若虫,每盆苗接入同虫态若虫20头。接虫后罩上开有透气孔的塑料笼罩。每处理重复4次,每盆为1重复。全部试验均在温度27℃±1℃、湿度75%±5%的阳光温室(自然光照)条件下进行。4d后观察、记录每盆苗中的活虫数,评价各药剂处理的杀虫活性。以含有溶剂和乳化剂的清水为对照。The experiment was carried out by rice seedling dipping method. The rice seedlings for the test were insect-free TN1 seedlings at the peak tillering stage, transplanted in small mud pots one week before the test, placed in an insect-free environment, and washed after the rice seedlings survived for later use. During the test, remove the withered yellow leaves and redundant tillers (leave 2 to 3 effective tillers in each pot), cut off the upper part, leave a 20-25 cm plant, immerse in the prepared medicinal solution for 10 seconds, take out the medicinal solution on the surface of the rice plant and dry it. Infestation. Select young (2-3 instar) nymphs, and insert 20 nymphs of the same stage into each pot of seedlings. There is a plastic cover with ventilation holes on the cover after picking up the worms. Each treatment was repeated 4 times, and each pot was 1 repetition. All tests were carried out under the conditions of a sunny greenhouse (natural light) with a temperature of 27°C±1°C and a humidity of 75%±5%. After 4 days, observe and record the number of live insects in each pot of seedlings, and evaluate the insecticidal activity of each chemical treatment. Water containing solvents and emulsifiers was used as a control.
各处理的活虫减退率和防治效果按照下列公式计算获得:The live insect reduction rate and control effect of each treatment were calculated according to the following formula:
活虫减退率(%)=(施药前活虫数-施药后活虫数)/施药前活虫数*100Reduction rate of live insects (%) = (number of live insects before application - number of live insects after application) / number of live insects before application * 100
防治效果(%)=(药剂处理区活虫减退率-对照区活虫减退率)/(100-对照区活虫减退率)*100Control effect (%) = (reduction rate of live insects in chemical treatment area - reduction rate of live insects in control area) / (100 - reduction rate of live insects in control area) * 100
另外,理论防治效果(%)可由Colby公式计算。当实际防治效果(%)高于理论防治效果(%)时,本申请的组合物具有协同增效效果。In addition, the theoretical control effect (%) can be calculated by Colby's formula. When the actual control effect (%) is higher than the theoretical control effect (%), the composition of the present application has a synergistic effect.
表1Table 1
Figure PCTCN2021125382-appb-000003
Figure PCTCN2021125382-appb-000003
*实测值=实测活性*Measured value = measured activity
**计算值=利用Colby公式计算的活性** Calculated value = activity calculated using Colby's formula
实施例B柑橘锈螨试验(抗性)Embodiment B citrus rust mite test (resistance)
将式(I)化合物、丁醚脲、虱螨脲、阿维菌素的原药分别用溶剂溶解配制单剂的母液,再用含0.1%的Tween-80的水溶液稀释至所需的浓度。Dissolve the original drugs of the compound of formula (I), diafenthiuron, lufenuron and avermectin in a solvent to prepare a single-dose mother solution, and then dilute to the required concentration with an aqueous solution containing 0.1% Tween-80.
供试锈螨选取大小一致、健康活泼的雌成螨。供试叶片为健康、完整、大小一致的柑橘。用打孔器将柑橘叶片打成叶面直径为2cm的叶盘。在培养皿内放置湿海绵块,其上放滤纸,滤纸上放叶蝶,备用。接入柑橘锈螨成螨。每个叶盘上接种20头雌成螨。For the rust mites to be tested, healthy and active adult females of the same size were selected. The tested leaves were healthy, complete and uniform citrus. The citrus leaves are punched into leaf disks with a leaf diameter of 2 cm with a punch. Place the wet sponge block in the petri dish, put the filter paper on it, put the leaf butterfly on the filter paper, set aside. Access citrus rust mite adult mites. Each leaf disc was inoculated with 20 female adult mites.
采用POTTER喷雾塔进行处理。每处理的喷药量为2mL。处理后将柑橘叶片置于温度为(25±1)℃,相对湿度(70±10)%,光照比例L:D为16:8的恒温室培养。每个处理重复3次。2天后观察成螨的死亡情况。用小毛笔尖触动叶螨的足和口器,无反应者视为死亡。以含有溶剂和乳化剂的清水为对照。Use POTTER spray tower for treatment. The spray volume of each treatment is 2mL. After the treatment, the citrus leaves were cultured in a constant temperature room with a temperature of (25±1)°C, a relative humidity of (70±10)%, and a light ratio L:D of 16:8. Each treatment was repeated 3 times. After 2 days, the death of adult mites was observed. Touch the feet and mouthparts of the spider mite with the tip of a small brush, and those who do not respond are considered dead. Water containing solvents and emulsifiers was used as a control.
各处理的活螨减退率和防治效果按照下列公式计算获得:The live mite reduction rate and control effect of each treatment were calculated according to the following formula:
活螨减退率(%)=(施药前活螨数-施药后活螨数)/施药前活螨数*100Reduction rate of live mites (%) = (number of live mites before application - number of live mites after application) / number of live mites before application * 100
防治效果(%)=(药剂处理区活螨减退率-对照区活螨减退率)/(100-对照区活螨减退率)*100Control effect (%) = (the reduction rate of live mites in the chemical treatment area - the reduction rate of live mites in the control area) / (100 - the reduction rate of live mites in the control area) * 100
另外,理论防治效果(%)可由Colby公式计算。当实际防治效果(%)高于理论防治效果(%)时,本申请的组合物具有协同增效效果。In addition, the theoretical control effect (%) can be calculated by Colby's formula. When the actual control effect (%) is higher than the theoretical control effect (%), the composition of the present application has a synergistic effect.
表2Table 2
Figure PCTCN2021125382-appb-000004
Figure PCTCN2021125382-appb-000004
从表1-表2明显可以看出,用式(I)化合物和阿维菌素、丁醚脲或虱螨脲的组合显著地增强了害虫控制效果,超出本领域的技术人员的预测。It can be clearly seen from Table 1-Table 2 that the combination of the compound of formula (I) and avermectin, diafenthiuron or lufenuron significantly enhanced the pest control effect, beyond the prediction of those skilled in the art.

Claims (11)

  1. 一种含有烷基苯基硫醚衍生物的杀虫组合物,其含有组分(A)和(B),其中,所述组分(A)是选自烷基苯基硫醚衍生物的式I化合物,组分(B)是选自阿维菌素、丁醚脲、虱螨脲的至少一种化合物;且所述组分(A)和(B)的重量比是50:1至1:50;A pesticidal composition containing alkylphenyl sulfide derivatives, which contains components (A) and (B), wherein, the component (A) is selected from the group consisting of alkylphenyl sulfide derivatives Formula I compound, component (B) is at least one compound selected from abamectin, diafenthiuron, lufenuron; and the weight ratio of said components (A) and (B) is 50:1 to 1:50;
    Figure PCTCN2021125382-appb-100001
    Figure PCTCN2021125382-appb-100001
  2. 根据权利要求1所述的杀虫组合物,其中,所述组分(B)选自阿维菌素,且所述组分(A)和(B)的重量比是25:1至1:25,优选10:1至1:1,更优选5:1至1:1。The insecticidal composition according to claim 1, wherein, said component (B) is selected from Abamectin, and the weight ratio of said component (A) and (B) is 25:1 to 1: 25, preferably 10:1 to 1:1, more preferably 5:1 to 1:1.
  3. 根据权利要求1所述的杀虫组合物,其中,所述组分(B)选自丁醚脲,且所述组分(A)和(B)的重量比是50:1至1:50,优选10:1至1:40,更优选1:1至1:20。The insecticidal composition according to claim 1, wherein the component (B) is selected from diafenthiuron, and the weight ratio of the components (A) and (B) is 50:1 to 1:50 , preferably 10:1 to 1:40, more preferably 1:1 to 1:20.
  4. 根据权利要求1所述的杀虫组合物,其中,所述组分(B)选自虱螨脲,且所述组分(A)和(B)的重量比是10:1至1:10,优选5:1至1:5,更优选2:1至1:2。The insecticidal composition according to claim 1, wherein the component (B) is selected from lufenuron, and the weight ratio of the components (A) and (B) is 10:1 to 1:10 , preferably 5:1 to 1:5, more preferably 2:1 to 1:2.
  5. 权利要求1所述的杀虫组合物用于预防和/或处理植物、植物部分和/或其周围环境中害虫侵袭的用途。Use of the pesticidal composition according to claim 1 for preventing and/or treating pest attacks in plants, plant parts and/or their surroundings.
  6. 根据权利要求5所述的用途,其中,所述害虫选自菜蛾科、卷蛾科、夜蛾科、飞虱科、粉虱科、叶螨科、全爪螨科、蓟马科、瘿螨科、蚜科或壶蚧科。The use according to claim 5, wherein the pests are selected from the group consisting of Plutellalidae, Tortriidae, Noctuidae, Planthoppers, Whiteflyidae, Tetranychidae, Panonychiidae, Thripidae, Eriodidae , Aphididae, or Coccidae.
  7. 根据权利要求5所述的用途,其中,所述害虫选自柑橘全爪螨、柑橘锈壁虱、朱砂叶螨或二斑叶螨。The use according to claim 5, wherein the pest is selected from the group consisting of Panonychus citrus, rust tick, Tetranychus cinnabarinus or Tetranychus urticae.
  8. 根据权利要求5所述的用途,其中,所述害虫选自褐飞虱。The use according to claim 5, wherein the pest is selected from brown planthopper.
  9. 根据权利要求5所述的用途,其中,所述植物选自棉花、柑橘、蔬菜、大豆、马铃薯或果树。The use according to claim 5, wherein the plant is selected from cotton, citrus, vegetables, soybeans, potatoes or fruit trees.
  10. 一种预防和/或处理植物、植物部分和/或周围环境中害虫感染的方法,其中,施用权利要求1所述的杀虫组合物。A method of preventing and/or treating pest infestation in plants, plant parts and/or the surrounding environment, wherein the pesticidal composition according to claim 1 is applied.
  11. 根据权利要求10所述的方法,其中,通过被覆、喷洒、浸蘸、浸湿、 注射、灌溉的方法施用权利要求1所述的杀虫组合物。The method according to claim 10, wherein the pesticidal composition according to claim 1 is applied by coating, spraying, dipping, soaking, injection, or irrigation.
PCT/CN2021/125382 2021-10-21 2021-10-21 Insecticidal composition containing alkylphenyl thioether derivative, and application thereof WO2023065238A1 (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104350039A (en) * 2012-04-20 2015-02-11 组合化学工业株式会社 Alkylphenylsulphide derivative and pest control agent
JP2015160813A (en) * 2014-02-26 2015-09-07 クミアイ化学工業株式会社 Pest control agent composition and method for controlling pest
CN113693074A (en) * 2021-08-25 2021-11-26 陕西上格之路生物科学有限公司 Acaricidal composition containing abamectin and application thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104350039A (en) * 2012-04-20 2015-02-11 组合化学工业株式会社 Alkylphenylsulphide derivative and pest control agent
JP2015160813A (en) * 2014-02-26 2015-09-07 クミアイ化学工業株式会社 Pest control agent composition and method for controlling pest
CN113693074A (en) * 2021-08-25 2021-11-26 陕西上格之路生物科学有限公司 Acaricidal composition containing abamectin and application thereof

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