WO2023054424A1 - Weld structure, electronic component module, and welding method - Google Patents

Weld structure, electronic component module, and welding method Download PDF

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Publication number
WO2023054424A1
WO2023054424A1 PCT/JP2022/036064 JP2022036064W WO2023054424A1 WO 2023054424 A1 WO2023054424 A1 WO 2023054424A1 JP 2022036064 W JP2022036064 W JP 2022036064W WO 2023054424 A1 WO2023054424 A1 WO 2023054424A1
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Prior art keywords
weld
solidified
welding
solidified portion
heating
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PCT/JP2022/036064
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French (fr)
Japanese (ja)
Inventor
道広 佐々木
満 黒須
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日本ケミコン株式会社
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Publication of WO2023054424A1 publication Critical patent/WO2023054424A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/20Bonding
    • B23K26/21Bonding by welding
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G2/00Details of capacitors not covered by a single one of groups H01G4/00-H01G11/00
    • H01G2/02Mountings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00Fixed capacitors; Processes of their manufacture
    • H01G4/32Wound capacitors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/502Interconnectors for connecting terminals of adjacent batteries; Interconnectors for connecting cells outside a battery casing
    • H01M50/514Methods for interconnecting adjacent batteries or cells
    • H01M50/516Methods for interconnecting adjacent batteries or cells by welding, soldering or brazing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Definitions

  • welded structure is used as a term encompassing the welded structure itself and the welded structure.
  • Welding is used to connect components, such as electrical connections in electronic components.
  • components such as electrical connections in electronic components.
  • electrode terminals of a battery pack are welded to bus bars (for example, Patent Document 1).
  • welding can reduce electrical resistance and suppress energy loss and heat generation compared to fastening with fastening members such as bolts and screws.
  • fastening members such as bolts and screws.
  • welding is less easy to connect or separate than fastening with fastening members.
  • the members used for welding are selected in consideration of selection items such as the use of the member, suitability for welding, and compatibility with the partner member to be welded.
  • selection items such as the use of the member, suitability for welding, and compatibility with the partner member to be welded.
  • the selection of members for example, if the use of the member is set as a priority selection item, it may be necessary to compromise other selection items such as suitability for welding and compatibility with the mating member.
  • Patent Document 1 does not disclose or suggest such problems, and the configuration disclosed in Patent Document 1 cannot solve such problems.
  • the first object of the present disclosure is, for example, to reduce residual stress due to welding and suppress cracks in the welded structure.
  • a second object of the present disclosure is, for example, to reduce residual stress due to welding and expand the types of members that can be used for welding.
  • a third objective of the present disclosure is to improve performance or specifications such as electrical properties, strength, hardness, durability, etc., in welded structures, taking advantage of, for example, expanding the range of usable members.
  • a welded structure includes a first member having a first joint surface, a second member having a second joint surface, and the first member butted together.
  • a weld solidified portion formed by welding on the joint surface portion of the second member, wherein the weld solidified portion includes a first solidified portion arranged on the outside and a second solidified portion arranged on the inside. including.
  • the second member may have a higher strength than the first member, and the welding center portion of the weld solidified portion may be abutting surfaces of the first member and the second member. may be arranged on the side of the first member with respect to.
  • the second member may further include a fastening portion that can be fastened with another member.
  • the cross-sectional width of the second solidified portion may be 10% or more and 70% or less of the cross-sectional width of the weld solidified portion.
  • the weld solidified portion may have an annular shape.
  • the term "ring" denotes an object having a shape obtained by connecting the ends of a line or elongated surface.
  • the ring may be a torus having a circular shape, or may have a shape other than a circular shape.
  • the electronic component module has the welded structure.
  • a welding method melts adjacent portions of a first member and a second member that are adjacent to each other by a first heating to form a melted portion, and and remelting or reheating a part of the molten portion by a second heating to form a first solidified portion arranged outside and a second solidified portion arranged inside forming a weld solidification
  • a first heating to form a melted portion
  • a second heating to form a first solidified portion arranged outside and a second solidified portion arranged inside forming a weld solidification
  • the second member may have a higher strength than the first member, and the first heating may be applied to the abutting surfaces of the first member and the second member. It may be added to the first member side.
  • the welding method may further include forming a fastening portion that can be fastened with another member on the second member.
  • the amount of heat applied by the second heating may be 9% or more and 50% or less of the amount of heat applied by the first heating.
  • the first heating and the second heating may be applied circumferentially, and the weld solidified portion may have an annular shape.
  • the first member may be a terminal of an electronic component or a conductive member connectable to the electronic component.
  • the second member may be an electrical connection member capable of electrically connecting the first member to another member.
  • the weld solidified part includes the first solidified part arranged on the outside and the second solidified part arranged on the inside, the residual stress in the weld solidified part is suppressed, and the butt joint of the welded structure Cracking can be suppressed. Therefore, for example, in an electronic component, it is possible to suppress an increase in electrical resistance due to cracks and heat generation during energization.
  • the members connected by the butt joint can be selected based, for example, on the application of the members, improving the performance or specifications of the welded structure. For example, in the welding structure of electronic components, it is possible to select low-resistance, high-strength members in consideration of electrical conductivity and fastening with other members.
  • FIG. 1 shows an example of a welded structure according to an embodiment.
  • FIG. 2 shows an example of a cross-section of a solidified weld, and shows a cross-section taken along the line II--II in A of FIG.
  • the configurations shown in FIGS. 1 and 2 are examples, and the technology of the present disclosure is not limited to such configurations.
  • the welded structure 2 is formed by a welding technique such as laser welding.
  • the welded structure 2 includes a first member 4 , a second member 6 and a weld solidification 8 .
  • the first member 4 is, for example, a terminal of an electronic component such as a power storage device module, or a conductive member connectable to the electronic component.
  • the electronic component may be a single electronic component, or an electronic component module formed by assembling and connecting a plurality of electronic components.
  • the first member 4 has, for example, a cylindrical shape or a substantially cylindrical shape, and has a first joint surface portion 10 on the end side surface.
  • the first joint surface portion 10 forms a joint surface portion for the weld solidification portion 8 .
  • the 1st member 4 contains metal, such as aluminum, an aluminum alloy, or stainless steel, for example.
  • the first member 4 may be metal such as aluminum, aluminum alloy or stainless steel.
  • Aluminum is, for example, pure aluminum (1000 series material) with a purity of 99.0% or more, and has excellent workability, surface treatability, and corrosion resistance.
  • Aluminum alloys include, for example, aluminum-copper (Al-Cu) alloys (2000 series materials), aluminum-manganese (Al-Mn) alloys (3000 series materials), aluminum-silicon (Al-Si) alloys (4000 series material), aluminum-magnesium (Al-Mg) alloy (5000 series material), aluminum-magnesium-silicon (Al-Mg-Si) alloy (6000 series material), aluminum-zinc-magnesium (Al-Zn-Mg ) series alloys (7000 series materials).
  • Aluminum-copper alloys have high strength and excellent machinability.
  • Aluminum-manganese alloys have workability, corrosion resistance, and higher strength than pure aluminum.
  • Aluminum-silicon alloys have excellent heat resistance and wear resistance, and have a small coefficient of thermal expansion.
  • Aluminum-magnesium alloys have excellent corrosion resistance, workability, and high strength.
  • Aluminum-magnesium-silicon alloys have excellent corrosion resistance and high strength.
  • Aluminum-zinc-magnesium based alloys have high strength.
  • the second member 6 is, for example, an electrical connection member such as a busbar, and can electrically connect the first member 4 to another member, for example.
  • the second member 6 has, for example, a plate shape or approximately plate shape.
  • the second member 6 contains, for example, a metal such as the already-described aluminum alloy or stainless steel.
  • the second member 6 may be made of a metal such as the already-described aluminum alloy or stainless steel.
  • the second member 6 is a member that suppresses deformation due to creep, for example. Creep is a phenomenon in which the deformation of an object increases with time when a constant amount of stress acts on it.
  • the second member 6 may be made of the same material as the first member 4 , or may be made of a material different from the first member 4 , for example, a material having a higher strength than the first member 4 .
  • the second member 6 includes a fusion joint 12 and a fastening portion 14 .
  • the fusion connection 12 includes a second mating surface portion 16 to the weld solidification 8 .
  • the second joint surface 16 is arranged on a ring, such as on a circumference, and the end of the first member 4 is inserted inside the second joint surface 16 .
  • the first joint surface portion 10 of the first member 4 is arranged on the extension of the second member 6 having a plate-like or substantially plate-like shape.
  • the fastening portion 14 includes fastening holes 18, for example, and can be fastened to other members by fastening members such as bolts or screws.
  • the second member 6 has a strength higher than, for example, the extent to which loosening of the fastening member can be suppressed, and suppresses loosening of the fastening member.
  • the weld solidified portion 8 is arranged between the first joint surface portion 10 of the first member 4 and the second joint surface portion 16 of the second member 6, and is located between the first joint surface portion 10 and the second joint surface portion 16. to form a butt joint.
  • the weld-solidified portion 8 is formed by solidifying the first member 4 and the second member 6 (hereinafter referred to as "members 4 and 6") melted during welding, and is a mixed member of the members 4 and 6.
  • the weld solidification 8 has, for example, a semi-elliptical or approximately semi-elliptical cross-sectional shape.
  • the weld solidification 8 includes a first solidification 20 and a second solidification 22 .
  • the weld solidified portion 8 has, for example, an annular shape on the exposed surface, as shown in FIG. 1A.
  • the first solidified portion 20 is arranged outside the weld solidified portion 8, that is, around the weld.
  • the first solidified portion 20 contacts and joins the first joint surface portion 10 and the second joint surface portion 16 to connect the first member 4 to the second member 6 .
  • the first solidified portion 20 is formed by cooling the members 4 and 6 melted by the first heating such as the first laser irradiation. Cooling of the members 4 and 6 may be, for example, natural cooling or mild forced cooling.
  • the second solidified portion 22 is arranged inside the weld solidified portion 8, that is, in the vicinity of the weld center P and the weld center P of the weld.
  • the weld center P is the elliptical center of the weld solidified portion 8 having a semi-elliptical or nearly semi-elliptical cross-sectional shape and coincides or substantially coincides with the heating point of the weld.
  • a part of the members 4 and 6 cooled after melting is re-melted and re-cooled by second heating such as second laser irradiation to form the second solidified portion 22 .
  • Re-cooling after the second heating may be, for example, natural cooling or mild forced cooling.
  • the weld solidified portion 8 has residual stress.
  • Residual stress is stress that remains in an object after the object has been subjected to an external force, even if the external force is removed.
  • residual stress is generated when an object heated in heat treatment is cooled.
  • the composition of the material becomes uneven and residual stress is generated.
  • the heated welded part is cooled from the periphery of the welded part, and finally the central part of the welded part is solidified. Therefore, in general welding, the residual stress (tensile stress) is high at the central portion of the welded portion.
  • the larger the amount of heat applied during welding and the larger the volume of the member to be melted the higher the residual stress.
  • the second amount of heat applied to the members 4, 6 in the second heating is suppressed, and the weld center P and the residual stress in the vicinity of the weld center P are suppressed.
  • the remelting of the members 4 and 6 promotes mixing of the members 4 and 6 and can suppress residual stress due to non-uniformity of materials. . That is, even if the second member 6 and the first member 4 are made of different materials, it is possible to suppress residual stress and maintain a stable connection structure.
  • the cross-sectional width W2 of the second solidified portion 22 is, for example, 10% or more and 70% or less of the cross-sectional width W1 of the weld solidified portion 8 .
  • the cross-sectional area of the second solidified portion 22 is equal to the cross-sectional area of the solidified weld portion 8 as a whole. is suppressed to less than half of The second heat amount is 50% or less of the first heat amount applied to the members 4 and 6 by the first heating from the area ratio.
  • the second heat quantity is smaller than the first heat quantity, and the residual stress in the second solidified portion 22 is suppressed.
  • the residual stress at the weld center P of the weld solidified portion 8 and its vicinity can be suppressed more than the residual stress at the weld center P and its vicinity of the weld solidified portion 8 consisting only of the first solidified portion 20 .
  • the second solidified portion 22 is sufficiently arranged on the surface near the central portion where residual stress is high. That is, the second solidified portion 22 can make it difficult for the central portion of the exposed surface where cracks are likely to occur to crack. Assuming that the second solidified portion 22 is substantially similar to the solidified weld portion 8, if the width W2 is 10% or more of the width W1, the cross-sectional area of the second solidified portion 22 is equal to the cross-sectional area of the entire solidified weld portion 8. 9% or more of The second amount of heat is 9% or more of the first amount of heat from the area ratio.
  • the welding center P is arranged, for example, on the first member 4 side with respect to the abutment surface S of the members 4 and 6 .
  • the butting surface S is a surface formed by butting the members 4 and 6 before welding. Welding in which the welding center P is arranged on the side of the first member 4 is performed by irradiating the second member 6 with a higher strength with a laser when the second member 6 has a higher strength than the first member 4.
  • the members 4 and 6 can be welded with a smaller amount of heat than in the case of welding, so residual stress can be suppressed.
  • the second member 6 For welding in which the weld center P is arranged on the side of the first member 4, if the second member 6 has a lower strength than the first member 4, the second member 6 having a lower strength is irradiated with a laser.
  • the difference in the amount of melting between the members 4 and 6 can be made smaller than in the case of doing so.
  • the weld central portion P may overlap the abutment surface S, or may be arranged on the second member 6 side with respect to the abutment surface S. Welding in which the weld center P overlaps the abutment surface S can reduce the difference in the amount of fusion between the members 4 and 6 .
  • Fig. 3 shows an example of the welding method.
  • the inverted triangle symbols shown in B and D of FIG. 3 represent the irradiation of the laser beam, and the arrows shown in C of FIG. It indicates that a tensile stress exists in the weld solidified portion 8 centering on the central portion.
  • the welding method shown in FIG. 3 is an example, and the technology of the present disclosure is not limited to such a method.
  • the second member 6 before welding includes, for example, a circular through hole slightly larger than the end of the first member 4 before welding.
  • the second member 6 may have a plurality of circular through holes. As the number of through-holes increases, a high degree of accuracy is required in arranging the ends of the first member 4 and the through-holes. However, since the through-hole has a diameter about 0.1 to 0.5 mm larger than that of the end of the first member 4, a gap of about 0.1 to 0.5 mm is generated. , the end of the member 4 and the through hole can be arranged. As shown in FIG. 3A, the end of the first member 4 is inserted into, for example, a through hole of the second member 6 so that the first member 4 is adjacent to the second member 6 .
  • first heating such as first laser irradiation to form melted parts 34 .
  • the center of the first heating is arranged on the side of the first member 4 with respect to the abutment surface S of the members 4 and 6 . Therefore, even if there is a gap of about 0.1 to 0.5 mm between the members 4 and 6, stable connection can be achieved.
  • the center of the first heating may overlap the abutting surface S, or may be arranged on the second member 6 side with respect to the abutting surface S.
  • the first heating moves relative to the members 4 and 6, for example, on a circumference, and melts the adjacent portion 32, for example, in an annular shape.
  • the laser irradiation device may move, and the members 4 and 6 may move. Due to the movement of the heating point, the melted portion 34 is naturally cooled, and a solidified portion 36 is formed as shown in FIG. 3C.
  • the heated weld is cooled from the periphery of the weld, and finally the central part of the weld is solidified. Therefore, the residual stress in the solidified portion 36 becomes high at the central portion of the solidified portion 36 and is generated starting from the central portion of the solidified portion 36 .
  • part of the solidified portion 36 is remelted by second heating such as second laser irradiation to form a remelted portion 38 .
  • the second heating is applied, for example, to the center of heating in the first heating, that is, the center of the width of the solidified portion 36 .
  • the second heating may be applied to the first member 4 side or the second member 6 side with respect to the heating center in the first heating.
  • the second heat quantity is controlled to be less than the first heat quantity, and the residual stress of the second solidified portion 22 (E in FIG. 3) formed by the solidification of the remelted portion 38 is reduced to that of the solidified portion before remelting. 36 residual stress. That is, the residual stress can be released by remelting the solidified portion 36 .
  • the second heat amount is adjusted to, for example, 9% or more and 50% or less of the first heat amount, and the width W2 is adjusted to 10% or more and 70% or less of the width W1.
  • the first amount of heat and the second amount of heat are adjusted, for example, by any of the following adjustments (1) to (6).
  • Adjustment (1) Adjusting the outputs of the first laser and the second laser Adjustment (2): Adjusting the distance from the first laser irradiation device and the second laser irradiation device to the members 4 and 6 (3) : Adjusting the incident angles of the first laser and the second laser with respect to the members 4 and 6 (4): Adjusting the heating time of the first heating and the second heating (5): Adjustment of the relative movement speed of the first heating and the second heating Adjustment (6): Combination of multiple adjustments such as Adjustment (1) to Adjustment (5)
  • the second heating moves relative to the members 4 and 6, for example, on the circumference, and remelts the solidified portion 36, for example, in an annular shape. Therefore, the remelt portion 38 is cooled to form a weld solidification 8 including a first solidification 20 and a second solidification 22, as shown in FIG. 3E.
  • the welded structure 2 is manufactured, for example, by the welding method described above.
  • the manufacturing method of the welded structure is the same as the welding method described above, for example, and the description thereof is omitted.
  • Residual stress generated in welds causes cracks in welds. Residual stress is presumed to occur due to, for example, the following factors. Factor (1): In the laser welding of dissimilar members, the melted members were cooled in a state in which they were not sufficiently mixed, resulting in partial differences in contraction speed. Factor (2): In order to connect the members firmly, a high-power laser is irradiated to form a large weld with large strain. Factor (3): Metals that tend to generate residual stress and have high crack susceptibility, such as magnesium-containing alloys, are used. Factor (4): A weld is formed that has a shape that increases residual stress.
  • Factor (5) When a member is surface-treated, the material contained in the surface of the member precipitates during welding, which locally reduces the strength of the member.
  • the welded structure 2 can suppress cracking even if factors (1) to (5) exist, and can suppress cracking even when welding members selected for required performance or specifications.
  • the welded structure 2 includes a second solidification 22 formed by a second heat quantity less than the first heat quantity, the second solidification 22 having a cross-sectional area smaller than that of the weld solidification 8 . It has a small residual stress. Formation of the second solidified portion 22 can release, cancel, or alleviate the residual stress. Therefore, a welded structure 2 that is less likely to crack can be obtained.
  • FIG. 4 shows an example of an electronic component according to the embodiment.
  • FIG. 5 shows an example of an end busbar of an electronic component.
  • the end busbar 64 is, for example, line-symmetrical with respect to the line L shown in FIG. 5A, and FIG. 5A shows the end busbar partially omitted.
  • the configurations shown in FIGS. 4 and 5 are examples, and the technology of the present disclosure is not limited to such configurations. 4 and 5, the same parts as in FIG. 1 are given the same reference numerals.
  • the installation side of the first holder 56 is referred to as the upper side
  • the installation side of the second holder 58 is referred to as the lower side.
  • the electronic component 52 is, for example, an electronic component module such as a power storage device module, and includes a plurality of power storage devices 54, a first holder 56, a second holder 58, a plurality of holder connection members 60, a connecting bus bar 62, an end portion Includes bus bar 64 and weld solidification 8 .
  • the plurality of power storage devices 54 are, for example, 18 power storage devices 54, and are arranged so that 3 rows of 6 power storage devices 54 arranged in a straight line are formed. That is, the plurality of power storage devices 54 are arranged in 6 rows and 3 columns.
  • Electricity storage device 54 has an electricity storage function, and is, for example, an electrolytic capacitor or an electric double layer capacitor.
  • Electricity storage device 54 includes, for example, a cylindrical body portion 66 and two electrode terminals 68 projecting from one end surface of body portion 66 .
  • the electrode terminal 68 is an example of the first member, and is, for example, a metal member made of pure aluminum (alloy number: 1070), and is excellent in workability, corrosion resistance, weldability, and the like.
  • the electrode terminal 68 having excellent corrosion resistance suppresses chemical reaction with the electrolyte, and suppresses the influence of the chemical change of the electrode terminal 68 and the electrolyte on the electrical characteristics.
  • pure aluminum is a suitable material for the electrode terminals 68 .
  • the alloy number is, for example, the alloy number indicated in Japanese Industrial Standard JIS H4000:2014 "Aluminum and aluminum alloy plates and strips".
  • the first holder 56 is arranged on the electricity storage device 54 .
  • the first holder 56 is a resin member containing, for example, thermoplastic resin, and has terminal holes (not shown) at positions corresponding to the plurality of arranged electrode terminals 68 .
  • An electrode terminal 68 passes through the terminal hole, and the end of the electrode terminal 68 protrudes from the upper surface of the first holder 56 .
  • the second holder 58 is arranged below the power storage device 54 .
  • a lower portion of the electricity storage device 54 is fitted into a second holder 58, thereby restricting the movement of the electricity storage device 54.
  • the second holder 58 is a resin member containing thermoplastic resin, for example.
  • the holder connection member 60 is connected to the first holder 56 and the second holder 58, and maintains the separation distance between the first holder 56 and the second holder 58 at a set distance.
  • the first holder 56, the second holder 58, and the holder connecting members 60 at both ends form a frame, and the electrical storage device 54 is arranged in this frame.
  • a central holder connection member 60 maintains a set distance between the first holder 56 and the second holder 58 at the middle of the frame.
  • Holder connection member 60 is a resin member containing, for example, thermoplastic resin.
  • connection bus bar 62 is an example of an electrical connection member, has an elongated plate shape, for example, and is arranged on the first holder 56 so as to traverse the three columns of the electricity storage devices 54 .
  • the connecting busbars 62 are welded, for example, to adjacent electrode terminals 68 in each row to electrically connect adjacent power storage devices 54 in each row.
  • the connecting busbars 62 also connect the welded electrode terminals 68 to the welded electrode terminals 68 in the other rows to electrically connect, for example, six electrical storage devices 54 .
  • the connection bus bar 62 is a member similar to the electrode terminal 68, for example.
  • the end bus bar 64 is an example of a second member, and is an electrical connection member capable of electrically connecting the electrode terminals 68 to other members such as loads.
  • the end busbar 64 has, for example, an elongated plate shape or an elongated substantially plate shape, and is arranged on the first holder 56 so as to traverse the three columns of the electricity storage devices 54 .
  • End busbars 64 are welded to end electrode terminals 68 in each row.
  • End busbars 64 also connect welded electrode terminals 68 to welded electrode terminals 68 in other rows to electrically connect, for example, three electrical storage devices 54 .
  • the end busbar 64 is a metal member made of, for example, an aluminum-magnesium alloy (alloy number: 5052).
  • An aluminum-magnesium alloy (alloy number: 5052) has excellent corrosion resistance and workability, has high strength and hardness, and suppresses deformation due to creep.
  • An aluminum-magnesium alloy (alloy number: 5052) has good distribution and is excellent in terms of cost.
  • the end busbar 64 includes three fusion connections 12 and fastening portions 70 .
  • the fusion joint 12 includes a second mating surface portion 16 as described in the embodiment.
  • the second joint surface portion 16 is arranged on a ring, such as on a circumference, and the ends of the electrode terminals 68 are inserted inside the second joint surface portion 16 .
  • the first joint surface portion 10 of the electrode terminal 68 is arranged on the extension of the end bus bar 64 having a plate shape or a substantially plate shape.
  • the weld solidified portion 8 is arranged between the first joint surface portion 10 of the electrode terminal 68 and the second joint surface portion 16 of the end bus bar 64, and is joined to the first joint surface portion 10 and the second joint surface portion 16. , forming a butt joint.
  • the solidified weld portion 8 is the same as the solidified weld portion 8 described in the embodiment, and the description thereof will be omitted. Electrode terminal 68 , end busbar 64 and weld solidification 8 form welded structure 72 , and electronic component 52 includes welded structure 72 .
  • the fastening portion 70 includes multiple fastening holes 18 and multiple fixing holes 74 .
  • the fastening holes 18 are, for example, five fastening holes 18, and are used for fastening the fastening member to another member.
  • the fixing holes 74 are, for example, two fixing holes 74 and are arranged outside the fastening hole 18 .
  • the fixing holes 74 are used for fixing the end busbars 64 to the first holder 56 . For example, before the end busbars 64 are welded to the electrode terminals 68, the end busbars 64 are fixed to the first holder 56 by fixing holes 74 and fasteners 76 for positioning.
  • the end busbars 64 may include other holes, steps, etc., depending on the purpose, as shown in FIG.
  • the electronic component 52 may include additional circuits, such as a balance circuit, a temperature detection circuit, and a voltage detection circuit, which are not shown.
  • the additional circuitry is connected to, for example, connection busbars 62 or end busbars 64 .
  • a butt joint with a solidified weld 8 may be used to connect the additional circuit to the bus bar.
  • the manufacturing process of the electronic component 52 is an example of a manufacturing method and includes, for example, an assembly process and a welding process.
  • the power storage device 54, the first holder 56, the second holder 58, the holder connection member 60, the connecting bus bar 62, the end bus bar 64 and the fixture 76 are combined to form a holder as shown in FIG. module.
  • connection bus bar 62 may be welded to electrode terminal 68 by, for example, the welding method described in the embodiment. Description of the welding method described in the embodiment is omitted.
  • the end busbars 64 having high strength and hardness can suppress loosening of tightening with other members.
  • the thickness of the end bus bar 64 is maintained in a high-temperature environment or over time, so that the axial force of the fastening member is maintained and loosening of the fastening member is suppressed. Therefore, an increase in electrical resistance is suppressed.
  • the solidified weld portion 8 has an annular shape on the exposed surface.
  • the shape of the weld-solidified portion 8 is not limited to an annular shape.
  • the second member 6 or the end bus bar 64 has an arc-shaped recess at the end, and this recess is abutted against the end side surface of the first member 4 or the electrode terminal 68 to form an arc-shaped welding solidification.
  • a portion 8 may be formed.
  • the upper portion of the first member 4 or the electrode terminal 68 may have a shape other than a circular shape, and the solidified weld portion 8 may have a shape corresponding to the shape of the first member 4 or the electrode terminal 68 .
  • the second member 6 includes the fastening portion 14 in the above embodiment, and the end bus bar 64 includes the fastening portion 70 in the above embodiment. However, the second member 6 may not include the fastening portion 14 and the end busbar 64 may not include the fastening portion 70 .
  • the material of the second member 6 or end busbars 64 may be constrained for reasons other than loose fastening, such as stiffness or scratch resistance.
  • the fastening portion 14 of the second member 6 includes the fastening hole 18 .
  • the fastening portion 14 may include a fastening member 118 such as a male screw, and be fastened to another member by the fastening member 118 .
  • the fastening portion 70 of the end bus bar 64 may include the fastening member 118 and may be fastened to another member by the fastening member 118, as in the embodiment.
  • the solidified portion 36 is remelted to form the second solidified portion 22 .
  • the welding method is not limited to the welding methods of the embodiments and examples.
  • a second heating may reheat a portion of melt zone 34 to form reheat zone 138, FIG. D, the reheat zone 138 may solidify to form a second solidified zone 22 .
  • Cooling may be, for example, natural cooling or mild forced cooling. Partial reheating of the melted portion 34 can slow down the cooling rate of the other portion of the melted portion 34 and suppress residual stress in the first solidified portion 20 .
  • the electrode terminal 68 is a metal member made of pure aluminum (alloy number: 1070), and the end bus bar 64 is a metal member made of an aluminum-magnesium alloy (alloy number: 5052). .
  • the electrode terminal 68 is not limited to pure aluminum (alloy number: 1070), and may be a metal member made of other pure aluminum having a purity of 99% or more, for example.
  • the end busbars 64 need only be strong enough to suppress the looseness of the fastening member.
  • the end busbar 64 is made of a metal made of an aluminum alloy that can suppress loosening of the fastening, selected from aluminum alloys of the 2000 series to the 7000 series. It may be a member.
  • the electronic component 52 includes 18 power storage devices 54 .
  • the number of power storage devices 54 may be less than 18 or may be more than 18.
  • the electronic component 52 is not limited to an electricity storage device module including at least one electricity storage device 54, and may be another electronic component such as a balance circuit.
  • the technique of the present disclosure is useful because it can be used not only for welding electronic components such as electrical storage device modules and circuits, but also for welding various members.

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Abstract

The purpose of the present disclosure is, for example, to reduce residual stress from welding and thereby suppress cracking at a weld structure. A weld structure (2) comprises a first member (4) that has a first joining surface part (10), a second member (6) that has a second joining surface part (16), and a weld-solidified part (8) that is formed at the butted joining surface parts of the first member and the second member by welding. The weld-solidified part includes a first solidified part (20) that is on the outside and a second solidified part (22) that is on the inside.

Description

溶接構造、電子部品モジュール、および溶接方法Welded structure, electronic component module and welding method
 本開示の技術は、溶接構造、電子部品モジュール、および溶接方法に関する。本明細書、請求の範囲および要約書において、用語「溶接構造」は、溶接構造そのもの、および溶接構造物を包含する用語として用いられる。
The technology of the present disclosure relates to a welded structure, an electronic component module, and a welding method. In this specification, claims and abstract, the term "welded structure" is used as a term encompassing the welded structure itself and the welded structure.
 溶接は、部材の接続、たとえば電子部品における電気接続に用いられる。たとえば、電池パックの電極端子がバスバーに溶接されることが知られている(たとえば、特許文献1)。電子部品において、溶接は、ボルト、ネジなどの締結部材による締結に比べて電気抵抗を小さくすることができ、エネルギー損失および発熱を抑制することができる。しかしながら、溶接は締結部材による締結に比べて接続または分離の容易性に乏しい。
Welding is used to connect components, such as electrical connections in electronic components. For example, it is known that electrode terminals of a battery pack are welded to bus bars (for example, Patent Document 1). In electronic components, welding can reduce electrical resistance and suppress energy loss and heat generation compared to fastening with fastening members such as bolts and screws. However, welding is less easy to connect or separate than fastening with fastening members.
特開2015-187910号公報JP 2015-187910 A
 ところで、溶接に用いられる部材は、たとえば、部材の用途、溶接への適合性、溶接の相手部材との相性などの選定項目を考慮して選定される。部材の選定において、たとえば部材の用途が優先選定項目に設定されると、溶接への適合性、相手部材との相性などの他の選定項目に関し、妥協が必要な場合がある。 By the way, the members used for welding are selected in consideration of selection items such as the use of the member, suitability for welding, and compatibility with the partner member to be welded. In the selection of members, for example, if the use of the member is set as a priority selection item, it may be necessary to compromise other selection items such as suitability for welding and compatibility with the mating member.
 高い強度を有するバスバーが他の部材にボルトで締結される場合、時間の経過によるバスバーの厚さの変化が小さく、ボルトの緩みが抑制できる。しかしながら、バスバーの強度が高くなると、一般的には溶接による割れが発生し易いという課題がある。尚、この「強度」とは材料が持つ、変形や破壊に対する抵抗力を指す。 When a high-strength busbar is bolted to another member, the change in thickness of the busbar over time is small, and loosening of the bolt can be suppressed. However, when the strength of the bus bar increases, there is generally a problem that cracks are likely to occur due to welding. The term "strength" refers to the resistance of a material to deformation and breakage.
 電子部品において、電気接続を担うバスバーなどの電気接続部材の大きな割れは、電気抵抗の上昇、通電時の発熱などの悪影響を発生させるという課題がある。 In electronic parts, large cracks in electrical connection members such as busbars, which are responsible for electrical connections, have the problem of causing adverse effects such as increased electrical resistance and heat generation when energized.
 特許文献1は、斯かる課題を開示や示唆せず、特許文献1に開示された構成では斯かる課題を解決することができない。 Patent Document 1 does not disclose or suggest such problems, and the configuration disclosed in Patent Document 1 cannot solve such problems.
 そこで、本開示は、たとえば、溶接による残留応力を軽減して、溶接構造における割れを抑制することを第1の目的とする。 Therefore, the first object of the present disclosure is, for example, to reduce residual stress due to welding and suppress cracks in the welded structure.
 本開示は、たとえば、溶接による残留応力を軽減して、溶接に使用可能な部材の種類を拡大することを第2の目的とする。 A second object of the present disclosure is, for example, to reduce residual stress due to welding and expand the types of members that can be used for welding.
 本開示は、たとえば、使用可能な部材の範囲の拡大を活用して、溶接構造において、電気的特性、強度、硬度、耐久性などの性能または仕様を向上させることを第3の目的とする。
A third objective of the present disclosure is to improve performance or specifications such as electrical properties, strength, hardness, durability, etc., in welded structures, taking advantage of, for example, expanding the range of usable members.
 本開示の第1の側面によれば、溶接構造は、第1の接合面部を有する第1の部材と、第2の接合面部を有する第2の部材と、突合せられた前記第1の部材と前記第2の部材の前記接合面部に溶接により形成された溶接凝固部とを備え、前記溶接凝固部は、外側に配置された第1の凝固部と、内側に配置された第2の凝固部とを含む。 According to a first aspect of the present disclosure, a welded structure includes a first member having a first joint surface, a second member having a second joint surface, and the first member butted together. A weld solidified portion formed by welding on the joint surface portion of the second member, wherein the weld solidified portion includes a first solidified portion arranged on the outside and a second solidified portion arranged on the inside. including.
 上記溶接構造において、前記第2の部材は、前記第1の部材よりも強度が高くてもよく、前記溶接凝固部の溶接中心部は、前記第1の部材と前記第2の部材の突合せ面に対して前記第1の部材側に配置されてもよい。 In the above-described welded structure, the second member may have a higher strength than the first member, and the welding center portion of the weld solidified portion may be abutting surfaces of the first member and the second member. may be arranged on the side of the first member with respect to.
 上記溶接構造において、前記第2の部材は、他の部材と締結可能な締結部をさらに含んでもよい。 In the above welded structure, the second member may further include a fastening portion that can be fastened with another member.
 上記溶接構造において、前記第2の凝固部の断面の幅は、前記溶接凝固部の断面の幅の10%以上、70%以下でもよい。 In the above welded structure, the cross-sectional width of the second solidified portion may be 10% or more and 70% or less of the cross-sectional width of the weld solidified portion.
 上記溶接構造において、前記溶接凝固部は、環形状を有してもよい。本明細書および請求の範囲において、用語「環」は、線または細長い面の両端を結ぶことにより得られる形状を有する物を表す。環は、円形を有する円環でもよく、円形以外の形状を有してもよい。 In the above welded structure, the weld solidified portion may have an annular shape. In the specification and claims, the term "ring" denotes an object having a shape obtained by connecting the ends of a line or elongated surface. The ring may be a torus having a circular shape, or may have a shape other than a circular shape.
 本開示の第2の側面によれば、電子部品モジュールは上記溶接構造を有する。 According to the second aspect of the present disclosure, the electronic component module has the welded structure.
 本開示の第3の側面によれば、溶接方法は、互いに隣接された第1の部材および第2の部材の隣接部を第1の加熱により溶融して、溶融部を形成し、該溶融部を冷却する工程と、第2の加熱により、前記溶融部の一部を再溶融または再加熱して、外側に配置された第1の凝固部と内側に配置された第2の凝固部とを含む溶接凝固部を形成する工程とを備える。 According to a third aspect of the present disclosure, a welding method melts adjacent portions of a first member and a second member that are adjacent to each other by a first heating to form a melted portion, and and remelting or reheating a part of the molten portion by a second heating to form a first solidified portion arranged outside and a second solidified portion arranged inside forming a weld solidification comprising:
 上記溶接方法において、前記第2の部材は、前記第1の部材よりも強度が高くてもよく、前記第1の加熱は、前記第1の部材と前記第2の部材の突合せ面に対して前記第1の部材側に加えられてもよい。 In the above welding method, the second member may have a higher strength than the first member, and the first heating may be applied to the abutting surfaces of the first member and the second member. It may be added to the first member side.
 上記溶接方法は、他の部材と締結可能な締結部を前記第2の部材に形成する工程をさらに備えてもよい。 The welding method may further include forming a fastening portion that can be fastened with another member on the second member.
 上記溶接方法において、前記第2の加熱により加えられる熱量は、前記第1の加熱により加えられる熱量の9%以上、50%以下でもよい。 In the above welding method, the amount of heat applied by the second heating may be 9% or more and 50% or less of the amount of heat applied by the first heating.
 上記溶接方法において、前記第1の加熱および前記第2の加熱は円周上に加えられてもよく、前記溶接凝固部は環形状を有してもよい。 In the above welding method, the first heating and the second heating may be applied circumferentially, and the weld solidified portion may have an annular shape.
 上記溶接方法において、前記第1の部材は、電子部品の端子でもよく、または電子部品に接続可能な導電性部材でもよい。前記第2の部材は、前記第1の部材を他の部材に電気的に接続可能な電気接続部材でもよい。
In the welding method described above, the first member may be a terminal of an electronic component or a conductive member connectable to the electronic component. The second member may be an electrical connection member capable of electrically connecting the first member to another member.
 本開示の技術によれば、次のいずれかの効果が得られる。 According to the technology of the present disclosure, one of the following effects can be obtained.
 (1) 溶接凝固部が、外側に配置された第1の凝固部と内側に配置された第2の凝固部とを含むので、溶接凝固部における残留応力が抑制され、溶接構造の突合せ継手における割れを抑制することができる。そのため、たとえば電子部品では、割れによる電気抵抗の上昇および通電時の発熱を抑制することができる。 (1) Since the weld solidified part includes the first solidified part arranged on the outside and the second solidified part arranged on the inside, the residual stress in the weld solidified part is suppressed, and the butt joint of the welded structure Cracking can be suppressed. Therefore, for example, in an electronic component, it is possible to suppress an increase in electrical resistance due to cracks and heat generation during energization.
 (2) 溶接凝固部における残留応力が抑制されるので、突合せ継手により接続される部材の種類の自由度を拡大させることができる。 (2) Since the residual stress in the solidified weld zone is suppressed, it is possible to expand the degree of freedom in the types of members connected by the butt joint.
 (3) 突合せ継手により接続される部材をたとえば部材の用途に基づき選択することができ、溶接構造の性能または仕様を向上させることができる。たとえば、電子部品における溶接構造では、導電性および他の部材との締結を考慮して、低抵抗で強度の高い部材を選択することができる。
(3) The members connected by the butt joint can be selected based, for example, on the application of the members, improving the performance or specifications of the welded structure. For example, in the welding structure of electronic components, it is possible to select low-resistance, high-strength members in consideration of electrical conductivity and fastening with other members.
実施の形態に係る溶接構造の一例を示す図である。It is a figure which shows an example of the welding structure which concerns on embodiment. 溶接凝固部の断面の一例を示す図である。It is a figure which shows an example of the cross section of a weld solidification part. 溶接方法の一例を示す図である。It is a figure which shows an example of the welding method. 実施例に係る電子部品の一例を示す図である。It is a figure which shows an example of the electronic component which concerns on an Example. 端部バスバーの一例を示す図である。It is a figure which shows an example of an edge part bus-bar. 変形例に係る溶接構造の一例を示す図である。It is a figure which shows an example of the welding structure which concerns on a modification. 溶接方法の変形例を示す図である。It is a figure which shows the modification of a welding method.
 図1は、実施の形態に係る溶接構造の一例を示している。図2は、溶接凝固部の断面の一例を示し、図1のAにおけるII-II線断面を示している。図1および図2に示す構成は一例であって、斯かる構成に本開示の技術が限定されるものではない。 FIG. 1 shows an example of a welded structure according to an embodiment. FIG. 2 shows an example of a cross-section of a solidified weld, and shows a cross-section taken along the line II--II in A of FIG. The configurations shown in FIGS. 1 and 2 are examples, and the technology of the present disclosure is not limited to such configurations.
 溶接構造2は、レーザー溶接などの溶接手法により形成される。溶接構造2は、第1の部材4、第2の部材6および溶接凝固部8を含む。 The welded structure 2 is formed by a welding technique such as laser welding. The welded structure 2 includes a first member 4 , a second member 6 and a weld solidification 8 .
 第1の部材4は、たとえば、蓄電デバイスモジュールなどの電子部品の端子、または電子部品に接続可能な導電性部材である。電子部品は、単体の電子部品でもよく、複数の電子部品が集合し接続されることで形成される電子部品モジュールでもよい。第1の部材4は、たとえば、円柱形状またはほぼ円柱形状を有し、端部側面に第1の接合面部10を有する。第1の接合面部10は溶接凝固部8に対する接合面部を形成する。第1の部材4は、たとえば、アルミニウム、アルミニウム合金またはステンレスなどの金属を含む。第1の部材4は、アルミニウム、アルミニウム合金またはステンレスなどの金属でもよい。 The first member 4 is, for example, a terminal of an electronic component such as a power storage device module, or a conductive member connectable to the electronic component. The electronic component may be a single electronic component, or an electronic component module formed by assembling and connecting a plurality of electronic components. The first member 4 has, for example, a cylindrical shape or a substantially cylindrical shape, and has a first joint surface portion 10 on the end side surface. The first joint surface portion 10 forms a joint surface portion for the weld solidification portion 8 . The 1st member 4 contains metal, such as aluminum, an aluminum alloy, or stainless steel, for example. The first member 4 may be metal such as aluminum, aluminum alloy or stainless steel.
 アルミニウムは、たとえば99.0%以上の純度を有する純アルミニウム(1000系材料)であって、優れた加工性、表面処理性、耐食性を有する。アルミニウム合金は、たとえばアルミニウム-銅(Al-Cu)系合金(2000系材料)、アルミニウム-マンガン(Al-Mn)系合金(3000系材料)、アルミニウム-ケイ素(Al-Si)系合金(4000系材料)、アルミニウム-マグネシウム(Al-Mg)系合金(5000系材料)、アルミニウム-マグネシウム-ケイ素(Al-Mg-Si)系合金(6000系材料)、アルミニウム-亜鉛-マグネシウム(Al-Zn-Mg)系合金(7000系材料)などである。アルミニウム-銅系合金は、高い強度、優れた切削性を有する。アルミニウム-マンガン系合金は、加工性、耐食性を有し、純アルミニウムよりも高い強度を有する。アルミニウム-ケイ素系合金は、優れた耐熱性、耐摩耗性を有し、小さい熱膨張係数を有する。アルミニウム-マグネシウム系合金は、優れた耐食性、加工性を有し、高い強度を有する。アルミニウム-マグネシウム-ケイ素系合金は、優れた耐食性、高い強度を有する。アルミニウム-亜鉛-マグネシウム系合金は、高い強度を有する。 Aluminum is, for example, pure aluminum (1000 series material) with a purity of 99.0% or more, and has excellent workability, surface treatability, and corrosion resistance. Aluminum alloys include, for example, aluminum-copper (Al-Cu) alloys (2000 series materials), aluminum-manganese (Al-Mn) alloys (3000 series materials), aluminum-silicon (Al-Si) alloys (4000 series material), aluminum-magnesium (Al-Mg) alloy (5000 series material), aluminum-magnesium-silicon (Al-Mg-Si) alloy (6000 series material), aluminum-zinc-magnesium (Al-Zn-Mg ) series alloys (7000 series materials). Aluminum-copper alloys have high strength and excellent machinability. Aluminum-manganese alloys have workability, corrosion resistance, and higher strength than pure aluminum. Aluminum-silicon alloys have excellent heat resistance and wear resistance, and have a small coefficient of thermal expansion. Aluminum-magnesium alloys have excellent corrosion resistance, workability, and high strength. Aluminum-magnesium-silicon alloys have excellent corrosion resistance and high strength. Aluminum-zinc-magnesium based alloys have high strength.
 第2の部材6は、たとえば、バスバーなどの電気接続部材であって、たとえば第1の部材4を他の部材に電気的に接続可能である。第2の部材6は、たとえば板形状、またはほぼ板形状を有する。第2の部材6は、たとえば、既述のアルミニウム合金またはステンレスなどの金属を含む。第2の部材6は、既述のアルミニウム合金またはステンレスなどの金属でもよい。第2の部材6は、たとえばクリープによる変形を抑制する部材である。クリープは、一定の大きさの応力が働いているとき、物体の変形が時間とともに増大していく現象である。一般的に、強度の高い部材のクリープによる変形は小さく、強度の高い部材は、クリープによる変形を抑制する。第2の部材6は、第1の部材4と同じ材質でもよく、第1の部材4とは異なる材質、たとえば第1の部材4よりも強度の高い材質でもよい。 The second member 6 is, for example, an electrical connection member such as a busbar, and can electrically connect the first member 4 to another member, for example. The second member 6 has, for example, a plate shape or approximately plate shape. The second member 6 contains, for example, a metal such as the already-described aluminum alloy or stainless steel. The second member 6 may be made of a metal such as the already-described aluminum alloy or stainless steel. The second member 6 is a member that suppresses deformation due to creep, for example. Creep is a phenomenon in which the deformation of an object increases with time when a constant amount of stress acts on it. In general, the deformation due to creep of a high-strength member is small, and the deformation due to creep is suppressed in a high-strength member. The second member 6 may be made of the same material as the first member 4 , or may be made of a material different from the first member 4 , for example, a material having a higher strength than the first member 4 .
 第2の部材6は溶融接続部12および締結部14を含む。溶融接続部12は、溶接凝固部8に対する第2の接合面部16を含む。第2の接合面部16は、円周上などの環上に配置され、第1の部材4の端部は、第2の接合面部16の内部に挿入される。第1の部材4の第1の接合面部10は、板形状またはほぼ板形状を有する第2の部材6の延長上に配置されている。締結部14は、たとえば締結孔18を含み、ボルトまたはネジなどの締結部材により他の部材に締結可能である。第2の部材6は、たとえば締結部材の緩みを抑制できる程度以上に強度が高く、締結部材の緩みを抑制する。 The second member 6 includes a fusion joint 12 and a fastening portion 14 . The fusion connection 12 includes a second mating surface portion 16 to the weld solidification 8 . The second joint surface 16 is arranged on a ring, such as on a circumference, and the end of the first member 4 is inserted inside the second joint surface 16 . The first joint surface portion 10 of the first member 4 is arranged on the extension of the second member 6 having a plate-like or substantially plate-like shape. The fastening portion 14 includes fastening holes 18, for example, and can be fastened to other members by fastening members such as bolts or screws. The second member 6 has a strength higher than, for example, the extent to which loosening of the fastening member can be suppressed, and suppresses loosening of the fastening member.
 溶接凝固部8は、第1の部材4の第1の接合面部10と第2の部材6の第2の接合面部16の間に配置され、第1の接合面部10および第2の接合面部16に接合して、突合せ継手を形成する。溶接凝固部8は、溶接時に溶融された第1の部材4および第2の部材6(以下「部材4、6」という)の凝固により形成され、部材4、6の混合部材である。溶接凝固部8は、たとえば、半楕円形またはほぼ半楕円形の断面形状を有する。溶接凝固部8は、第1の凝固部20および第2の凝固部22を含む。溶接凝固部8は、図1のAに示されているように、露出面において、たとえば環形状を有する。 The weld solidified portion 8 is arranged between the first joint surface portion 10 of the first member 4 and the second joint surface portion 16 of the second member 6, and is located between the first joint surface portion 10 and the second joint surface portion 16. to form a butt joint. The weld-solidified portion 8 is formed by solidifying the first member 4 and the second member 6 (hereinafter referred to as " members 4 and 6") melted during welding, and is a mixed member of the members 4 and 6. The weld solidification 8 has, for example, a semi-elliptical or approximately semi-elliptical cross-sectional shape. The weld solidification 8 includes a first solidification 20 and a second solidification 22 . The weld solidified portion 8 has, for example, an annular shape on the exposed surface, as shown in FIG. 1A.
 第1の凝固部20は、溶接凝固部8の外側、つまり溶接の周囲部に配置されている。第1の凝固部20は、第1の接合面部10および第2の接合面部16に接触かつ接合し、第1の部材4を第2の部材6に接続する。たとえば、第1のレーザー照射などの第1の加熱により溶融された部材4、6が冷却されて、第1の凝固部20は形成される。部材4、6の冷却はたとえば自然冷却であって、軽度の強制冷却でもよい。 The first solidified portion 20 is arranged outside the weld solidified portion 8, that is, around the weld. The first solidified portion 20 contacts and joins the first joint surface portion 10 and the second joint surface portion 16 to connect the first member 4 to the second member 6 . For example, the first solidified portion 20 is formed by cooling the members 4 and 6 melted by the first heating such as the first laser irradiation. Cooling of the members 4 and 6 may be, for example, natural cooling or mild forced cooling.
 第2の凝固部22は溶接凝固部8の内側、つまり溶接の溶接中心部Pおよび溶接中心部Pの近傍に配置される。溶接中心部Pは、半楕円形またはほぼ半楕円形の断面形状を有する溶接凝固部8の楕円中心であって、溶接の加熱点に一致またはほぼ一致する。たとえば、溶融後に冷却された部材4、6の一部が、第2のレーザー照射などの第2の加熱により再溶融および再冷却されて、第2の凝固部22が形成される。第2の加熱後の再冷却は、たとえば自然冷却であって、軽度の強制冷却でもよい。 The second solidified portion 22 is arranged inside the weld solidified portion 8, that is, in the vicinity of the weld center P and the weld center P of the weld. The weld center P is the elliptical center of the weld solidified portion 8 having a semi-elliptical or nearly semi-elliptical cross-sectional shape and coincides or substantially coincides with the heating point of the weld. For example, a part of the members 4 and 6 cooled after melting is re-melted and re-cooled by second heating such as second laser irradiation to form the second solidified portion 22 . Re-cooling after the second heating may be, for example, natural cooling or mild forced cooling.
 溶接凝固部8は、残留応力を有する。残留応力は、物体が外力の作用を受けた後、外力を取り除いても物体内に残留する応力である。たとえば、熱処理において加熱された物体が冷却されると残留応力が発生する。また、異種部材の熱処理において、異種部材の混合が不均一であると、物質の組成が不均一になり残留応力が発生する。 The weld solidified portion 8 has residual stress. Residual stress is stress that remains in an object after the object has been subjected to an external force, even if the external force is removed. For example, residual stress is generated when an object heated in heat treatment is cooled. Further, in the heat treatment of dissimilar materials, if the dissimilar materials are mixed unevenly, the composition of the material becomes uneven and residual stress is generated.
 加熱された溶接部は、溶接部の周囲から冷却され、最終的に溶接部の中央部が凝固される。そのため、一般的な溶接では、溶接部の中央部で残留応力(引っ張り応力)が高くなる。また、溶接時に加えられる熱量が大きくなり、溶融される部材の体積が大きくなるほど残留応力が高くなる。しかしながら、溶接構造2では、第2の加熱において部材4、6に加えられる第2の熱量が抑制され、溶接中心部Pおよび溶接中心部Pの近傍の残留応力が抑制される。第2の部材6が第1の部材4と異なる材質である場合、部材4、6の再溶融は、部材4、6の混合を促進させ、物質の不均一による残留応力を抑制することができる。つまり、第2の部材6と第1の部材4とが異なる材質であっても残留応力を抑制し安定した接続構造を維持することが可能である。 The heated welded part is cooled from the periphery of the welded part, and finally the central part of the welded part is solidified. Therefore, in general welding, the residual stress (tensile stress) is high at the central portion of the welded portion. In addition, the larger the amount of heat applied during welding and the larger the volume of the member to be melted, the higher the residual stress. However, in the welded structure 2, the second amount of heat applied to the members 4, 6 in the second heating is suppressed, and the weld center P and the residual stress in the vicinity of the weld center P are suppressed. When the second member 6 is made of a material different from that of the first member 4, the remelting of the members 4 and 6 promotes mixing of the members 4 and 6 and can suppress residual stress due to non-uniformity of materials. . That is, even if the second member 6 and the first member 4 are made of different materials, it is possible to suppress residual stress and maintain a stable connection structure.
 第2の凝固部22の断面の幅W2は、溶接凝固部8の断面の幅W1のたとえば10%以上、70%以下である。第2の凝固部22が溶接凝固部8にほぼ相似するとした場合、幅W2が幅W1の70%以下であると、第2の凝固部22の断面積が溶接凝固部8の全体の断面積の半分以下に抑制される。第2の熱量は、面積比から、第1の加熱により部材4、6に加えられる第1の熱量の50%以下になる。第2の熱量が第1の熱量よりも小さく、第2の凝固部22の残留応力が抑制される。溶接凝固部8の溶接中心部Pおよびその近傍の残留応力を、第1の凝固部20のみからなる溶接凝固部8の溶接中心部Pおよびその近傍の残留応力よりも抑制することができる。 The cross-sectional width W2 of the second solidified portion 22 is, for example, 10% or more and 70% or less of the cross-sectional width W1 of the weld solidified portion 8 . Assuming that the second solidified portion 22 is substantially similar to the solidified weld portion 8, if the width W2 is 70% or less of the width W1, the cross-sectional area of the second solidified portion 22 is equal to the cross-sectional area of the solidified weld portion 8 as a whole. is suppressed to less than half of The second heat amount is 50% or less of the first heat amount applied to the members 4 and 6 by the first heating from the area ratio. The second heat quantity is smaller than the first heat quantity, and the residual stress in the second solidified portion 22 is suppressed. The residual stress at the weld center P of the weld solidified portion 8 and its vicinity can be suppressed more than the residual stress at the weld center P and its vicinity of the weld solidified portion 8 consisting only of the first solidified portion 20 .
 幅W2が幅W1のたとえば10%以上であると、第2の凝固部22が、残留応力が高くなる中央部付近の表面に十分に配置されることになる。つまり、第2の凝固部22が、割れが発生し易い露出面の中央部を割れにくくすることができる。第2の凝固部22が溶接凝固部8にほぼ相似するとした場合、幅W2が幅W1の10%以上であると、第2の凝固部22の断面積が溶接凝固部8の全体の断面積の9%以上になる。第2の熱量は、面積比から第1の熱量の9%以上になる。 When the width W2 is, for example, 10% or more of the width W1, the second solidified portion 22 is sufficiently arranged on the surface near the central portion where residual stress is high. That is, the second solidified portion 22 can make it difficult for the central portion of the exposed surface where cracks are likely to occur to crack. Assuming that the second solidified portion 22 is substantially similar to the solidified weld portion 8, if the width W2 is 10% or more of the width W1, the cross-sectional area of the second solidified portion 22 is equal to the cross-sectional area of the entire solidified weld portion 8. 9% or more of The second amount of heat is 9% or more of the first amount of heat from the area ratio.
 溶接中心部Pは、部材4、6の突合せ面Sに対して、たとえば第1の部材4側に配置されている。突合せ面Sは、溶接前の部材4、6の突合せにより形成される面である。溶接中心部Pが第1の部材4側に配置されている溶接は、第2の部材6が第1の部材4よりも強度が高い場合に、強度が高い第2の部材6にレーザーを照射する場合よりも少ない熱量で部材4、6を溶接でき、そのため残留応力を抑制できる。溶接中心部Pが第1の部材4側に配置されている溶接は、第2の部材6が第1の部材4よりも強度が低い場合に、強度が低い第2の部材6にレーザーを照射する場合よりも部材4、6の溶融量の差を小さくできる。 The welding center P is arranged, for example, on the first member 4 side with respect to the abutment surface S of the members 4 and 6 . The butting surface S is a surface formed by butting the members 4 and 6 before welding. Welding in which the welding center P is arranged on the side of the first member 4 is performed by irradiating the second member 6 with a higher strength with a laser when the second member 6 has a higher strength than the first member 4. The members 4 and 6 can be welded with a smaller amount of heat than in the case of welding, so residual stress can be suppressed. For welding in which the weld center P is arranged on the side of the first member 4, if the second member 6 has a lower strength than the first member 4, the second member 6 having a lower strength is irradiated with a laser. The difference in the amount of melting between the members 4 and 6 can be made smaller than in the case of doing so.
 溶接中心部Pは、突合せ面Sに重なっていてもよく、突合せ面Sに対して、第2の部材6側に配置されてもよい。溶接中心部Pが突合せ面Sに重なる溶接は、部材4、6の溶融量の差を小さくできる。 The weld central portion P may overlap the abutment surface S, or may be arranged on the second member 6 side with respect to the abutment surface S. Welding in which the weld center P overlaps the abutment surface S can reduce the difference in the amount of fusion between the members 4 and 6 .
 図3は、溶接方法の一例を示している。図3のBおよび図3のDに示されている逆三角形記号は、レーザー光の照射を表し、図3のCに示されている矢印は、残留応力の向きを表し、溶接凝固部8の中央部を中心に引っ張り応力が溶接凝固部8に存在することを表す。図3に示す溶接方法は一例であって、斯かる方法に本開示の技術が限定されるものではない。 Fig. 3 shows an example of the welding method. The inverted triangle symbols shown in B and D of FIG. 3 represent the irradiation of the laser beam, and the arrows shown in C of FIG. It indicates that a tensile stress exists in the weld solidified portion 8 centering on the central portion. The welding method shown in FIG. 3 is an example, and the technology of the present disclosure is not limited to such a method.
 溶接前の第2の部材6は、たとえば溶接前の第1の部材4の端部よりもわずかに大きい円形の貫通孔を含む。第2の部材6は、この円形の貫通孔を複数備えてもよい。その貫通孔の数が多くなると、第1の部材4の端部と貫通孔との配置に高い精度が要求され、高い精度を実現するには製造コストが高くなる。しかしながら、貫通孔が第1の部材4の端部より0.1~0.5mm程度大きい径を有することによって、0.1~0.5mm程度の隙間が生じるため高い精度を必要とせず第1の部材4の端部と貫通孔とを配置することができる。図3のAに示すように、第1の部材4の端部がたとえば第2の部材6の貫通孔に挿入されて、第1の部材4が第2の部材6に隣接される。 The second member 6 before welding includes, for example, a circular through hole slightly larger than the end of the first member 4 before welding. The second member 6 may have a plurality of circular through holes. As the number of through-holes increases, a high degree of accuracy is required in arranging the ends of the first member 4 and the through-holes. However, since the through-hole has a diameter about 0.1 to 0.5 mm larger than that of the end of the first member 4, a gap of about 0.1 to 0.5 mm is generated. , the end of the member 4 and the through hole can be arranged. As shown in FIG. 3A, the end of the first member 4 is inserted into, for example, a through hole of the second member 6 so that the first member 4 is adjacent to the second member 6 .
 図3のBに示すように、互いに隣接された部材4、6の隣接部32を第1のレーザー照射などの第1の加熱により溶融して、溶融部34を形成する。図3のBでは、第1の加熱の中心が、部材4、6の突合せ面Sに対して、第1の部材4側に配置されている。そのため、仮に部材4、6の間に0.1~0.5mm程度の隙間があったとしても、安定した接続をすることが可能となる。しかしながら、第1の加熱の中心は、突合せ面Sに重なっていてもよく、突合せ面Sに対して、第2の部材6側に配置されてもよい。 As shown in FIG. 3B, adjacent parts 32 of the mutually adjacent members 4 and 6 are melted by first heating such as first laser irradiation to form melted parts 34 . In FIG. 3B, the center of the first heating is arranged on the side of the first member 4 with respect to the abutment surface S of the members 4 and 6 . Therefore, even if there is a gap of about 0.1 to 0.5 mm between the members 4 and 6, stable connection can be achieved. However, the center of the first heating may overlap the abutting surface S, or may be arranged on the second member 6 side with respect to the abutting surface S.
 第1の加熱は、部材4、6に対してたとえば円周上を相対的に移動して、隣接部32をたとえば環状に溶融する。第1の加熱の相対的な移動において、レーザー照射装置が移動してもよく、部材4、6が移動してもよい。加熱箇所の移動により、溶融部34がたとえば自然に冷却されて、図3のCに示されるように、凝固部36が形成される。 The first heating moves relative to the members 4 and 6, for example, on a circumference, and melts the adjacent portion 32, for example, in an annular shape. In the relative movement of the first heating, the laser irradiation device may move, and the members 4 and 6 may move. Due to the movement of the heating point, the melted portion 34 is naturally cooled, and a solidified portion 36 is formed as shown in FIG. 3C.
 既に述べた通り、加熱された溶接部は、溶接部の周囲から冷却され、最終的に溶接の中央部が凝固される。そのため、凝固部36内の残留応力は、凝固部36の中央部で高くなり、凝固部36の中央部を起点に発生する。 As already mentioned, the heated weld is cooled from the periphery of the weld, and finally the central part of the weld is solidified. Therefore, the residual stress in the solidified portion 36 becomes high at the central portion of the solidified portion 36 and is generated starting from the central portion of the solidified portion 36 .
 図3のDに示されるように、凝固部36の一部が第2のレーザー照射などの第2の加熱により再溶融され、再溶融部38が形成される。第2の加熱は、たとえば第1の加熱における加熱中心、つまり凝固部36の幅中心部に加えられる。第2の加熱は、第1の加熱における加熱中心に対して第1の部材4側または第2の部材6側に加えられてもよい。第2の熱量は、第1の熱量よりも少ない熱量に制御され、再溶融部38の凝固により形成される第2の凝固部22(図3のE)の残留応力を再溶融前の凝固部36の残留応力よりも小さくすることができる。つまり、凝固部36の再溶融により、残留応力を開放することができる。第2の熱量は、第1の熱量のたとえば9%以上、50%以下に調整され、幅W2が、幅W1の10%以上、70%以下に調整される。第1の熱量および第2の熱量は、たとえば、以下の調整(1)から調整(6)のいずれかにより調整される。
調整(1): 第1のレーザーおよび第2のレーザーの出力の調整
調整(2): 第1のレーザー照射装置および第2のレーザー照射装置から部材4、6までの距離の調整
調整(3): 部材4、6に対する第1のレーザーおよび第2のレーザーの入射角の調整
調整(4): 第1の加熱および第2の加熱の加熱時間の調整
調整(5): 部材4、6に対する第1の加熱および第2の加熱の相対的な移動速度の調整
調整(6): 調整(1)から調整(5)などの複数の調整の組み合わせ
As shown in FIG. 3D, part of the solidified portion 36 is remelted by second heating such as second laser irradiation to form a remelted portion 38 . The second heating is applied, for example, to the center of heating in the first heating, that is, the center of the width of the solidified portion 36 . The second heating may be applied to the first member 4 side or the second member 6 side with respect to the heating center in the first heating. The second heat quantity is controlled to be less than the first heat quantity, and the residual stress of the second solidified portion 22 (E in FIG. 3) formed by the solidification of the remelted portion 38 is reduced to that of the solidified portion before remelting. 36 residual stress. That is, the residual stress can be released by remelting the solidified portion 36 . The second heat amount is adjusted to, for example, 9% or more and 50% or less of the first heat amount, and the width W2 is adjusted to 10% or more and 70% or less of the width W1. The first amount of heat and the second amount of heat are adjusted, for example, by any of the following adjustments (1) to (6).
Adjustment (1): Adjusting the outputs of the first laser and the second laser Adjustment (2): Adjusting the distance from the first laser irradiation device and the second laser irradiation device to the members 4 and 6 (3) : Adjusting the incident angles of the first laser and the second laser with respect to the members 4 and 6 (4): Adjusting the heating time of the first heating and the second heating (5): Adjustment of the relative movement speed of the first heating and the second heating Adjustment (6): Combination of multiple adjustments such as Adjustment (1) to Adjustment (5)
 第2の加熱は、部材4、6に対してたとえば円周上を相対的に移動して、凝固部36をたとえば環状に再溶融する。そのため、再溶融部38は冷却されて、図3のEに示されるように、第1の凝固部20および第2の凝固部22を含む溶接凝固部8が形成される。 The second heating moves relative to the members 4 and 6, for example, on the circumference, and remelts the solidified portion 36, for example, in an annular shape. Therefore, the remelt portion 38 is cooled to form a weld solidification 8 including a first solidification 20 and a second solidification 22, as shown in FIG. 3E.
 溶接構造2は、たとえば既述の溶接方法により製造される。溶接構造の製造方法は、たとえば既述の溶接方法と同様であり、その説明を省略する。 The welded structure 2 is manufactured, for example, by the welding method described above. The manufacturing method of the welded structure is the same as the welding method described above, for example, and the description thereof is omitted.
 実施の形態によれば、次のような作用または効果が得られる。 According to the embodiment, the following functions or effects can be obtained.
 (1) 溶接部に生じた残留応力は、溶接部に割れを引き起こす原因となる。残留応力は、たとえば以下の要因により発生すると推測される。
要因(1): 異種部材のレーザー溶接において、溶融された部材が十分に混ざり合わない状態で冷却されたため、部分的な収縮速度の相違が生じる。
要因(2): 部材を強固に接続するため、高出力のレーザーが照射されて、大きな歪を有する大きな溶接部が形成される。
要因(3): 残留応力を発生させ易く高い割れ感受性を有する金属、たとえばマグネシウムを含む合金が用いられる。
要因(4): 残留応力が大きくなるような形状を有する溶接部が形成される。環形状などの湾曲を伴う溶接部は、直線的な溶接部よりも残留応力が大きくなる。
要因(5): 部材を表面処理した場合、部材の表面に含まれる材質が溶接時に析出することにより局所的に部材の強度が低下する。
(1) Residual stress generated in welds causes cracks in welds. Residual stress is presumed to occur due to, for example, the following factors.
Factor (1): In the laser welding of dissimilar members, the melted members were cooled in a state in which they were not sufficiently mixed, resulting in partial differences in contraction speed.
Factor (2): In order to connect the members firmly, a high-power laser is irradiated to form a large weld with large strain.
Factor (3): Metals that tend to generate residual stress and have high crack susceptibility, such as magnesium-containing alloys, are used.
Factor (4): A weld is formed that has a shape that increases residual stress. A weld with a curve, such as an annular shape, has a higher residual stress than a straight weld.
Factor (5): When a member is surface-treated, the material contained in the surface of the member precipitates during welding, which locally reduces the strength of the member.
 要求性能または仕様のために、上記の要因(1)から要因(5)の解消が難しい場合がある。溶接構造2は、要因(1)から要因(5)が存在しても割れを抑制でき、要求性能または仕様のために選択された部材の溶接においても割れを抑制できる。 Due to the required performance or specifications, it may be difficult to eliminate factors (1) to (5) above. The welded structure 2 can suppress cracking even if factors (1) to (5) exist, and can suppress cracking even when welding members selected for required performance or specifications.
 溶接構造2は、第1の熱量よりも小さい第2の熱量により形成された第2の凝固部22を含み、この第2の凝固部22が溶接凝固部8の断面積よりも小さい断面積を有し、小さな残留応力を有する。第2の凝固部22の形成により、残留応力を開放、キャンセル、または緩和できる。そのため、割れにくい溶接構造2が得られる。 The welded structure 2 includes a second solidification 22 formed by a second heat quantity less than the first heat quantity, the second solidification 22 having a cross-sectional area smaller than that of the weld solidification 8 . It has a small residual stress. Formation of the second solidified portion 22 can release, cancel, or alleviate the residual stress. Therefore, a welded structure 2 that is less likely to crack can be obtained.
 (2) 溶接構造2が割れにくいので、部材の組み合わせの自由度を拡大させることができる。 (2) Since the welded structure 2 is hard to break, it is possible to expand the degree of freedom in combining members.
 (3) 溶接構造2が割れにくいので、溶接性よりも、電気的特性、強度、硬度、耐久性などの性能または仕様を重視して、使用部材を選択することができる。つまり、溶接構造2の性能または仕様を向上させることができる。
(3) Since the welded structure 2 is less likely to crack, it is possible to select materials to be used by emphasizing performance or specifications such as electrical characteristics, strength, hardness, and durability rather than weldability. That is, the performance or specifications of the welded structure 2 can be improved.
 図4は、実施例に係る電子部品の一例を示している。図5は、電子部品の端部バスバーの一例を示している。端部バスバー64は、図5のAに示されている線Lに対してたとえば線対称であり、図5のAは、一部省略された端部バスバーを示している。図4および図5に示す構成は一例であって、斯かる構成に本開示の技術が限定されるものではない。図4および図5において、図1と同一部分には同一符号を付してある。この実施例では、第1のホルダー56の設置側を上側と称し、第2のホルダー58の設置側を下側と称する。 FIG. 4 shows an example of an electronic component according to the embodiment. FIG. 5 shows an example of an end busbar of an electronic component. The end busbar 64 is, for example, line-symmetrical with respect to the line L shown in FIG. 5A, and FIG. 5A shows the end busbar partially omitted. The configurations shown in FIGS. 4 and 5 are examples, and the technology of the present disclosure is not limited to such configurations. 4 and 5, the same parts as in FIG. 1 are given the same reference numerals. In this embodiment, the installation side of the first holder 56 is referred to as the upper side, and the installation side of the second holder 58 is referred to as the lower side.
 電子部品52は、たとえば、蓄電デバイスモジュールなどの電子部品モジュールであって、複数の蓄電デバイス54、第1のホルダー56、第2のホルダー58、複数のホルダー接続部材60、連結バスバー62、端部バスバー64および溶接凝固部8を含む。 The electronic component 52 is, for example, an electronic component module such as a power storage device module, and includes a plurality of power storage devices 54, a first holder 56, a second holder 58, a plurality of holder connection members 60, a connecting bus bar 62, an end portion Includes bus bar 64 and weld solidification 8 .
 複数の蓄電デバイス54は、たとえば18個の蓄電デバイス54であって、一直線に並べられた6個の蓄電デバイス54が3列形成されるように配置されている。つまり、複数の蓄電デバイス54は、6行3列に配置されている。蓄電デバイス54は、蓄電機能を有し、たとえば電解コンデンサまたは電気二重層コンデンサである。蓄電デバイス54は、たとえば円筒形の本体部66と、本体部66の一端面から突出する二つの電極端子68とを含む。 The plurality of power storage devices 54 are, for example, 18 power storage devices 54, and are arranged so that 3 rows of 6 power storage devices 54 arranged in a straight line are formed. That is, the plurality of power storage devices 54 are arranged in 6 rows and 3 columns. Electricity storage device 54 has an electricity storage function, and is, for example, an electrolytic capacitor or an electric double layer capacitor. Electricity storage device 54 includes, for example, a cylindrical body portion 66 and two electrode terminals 68 projecting from one end surface of body portion 66 .
 電極端子68は、第1の部材の一例であって、たとえば純アルミニウム(合金番号:1070)の金属部材であり、加工性、耐食性、溶接性などに優れる。耐食性に優れる電極端子68は、電解液との化学反応を抑制し、電極端子68および電解液の化学変化による電気的特性への影響を抑制する。つまり、純アルミニウムは、電極端子68に適する材料である。なお、合金番号は、たとえば日本産業規格JIS H4000:2014「アルミニウム及びアルミニウム合金の板及び条」に示されている合金番号である。 The electrode terminal 68 is an example of the first member, and is, for example, a metal member made of pure aluminum (alloy number: 1070), and is excellent in workability, corrosion resistance, weldability, and the like. The electrode terminal 68 having excellent corrosion resistance suppresses chemical reaction with the electrolyte, and suppresses the influence of the chemical change of the electrode terminal 68 and the electrolyte on the electrical characteristics. In other words, pure aluminum is a suitable material for the electrode terminals 68 . The alloy number is, for example, the alloy number indicated in Japanese Industrial Standard JIS H4000:2014 "Aluminum and aluminum alloy plates and strips".
 第1のホルダー56は、蓄電デバイス54の上に配置されている。第1のホルダー56は、たとえば熱可塑性樹脂を含む樹脂部材であって、配列された複数の電極端子68に対応する位置に、図示しない端子孔を有する。端子孔は電極端子68を通過させ、電極端子68の端部は、第1のホルダー56の上側表面から突出している。 The first holder 56 is arranged on the electricity storage device 54 . The first holder 56 is a resin member containing, for example, thermoplastic resin, and has terminal holes (not shown) at positions corresponding to the plurality of arranged electrode terminals 68 . An electrode terminal 68 passes through the terminal hole, and the end of the electrode terminal 68 protrudes from the upper surface of the first holder 56 .
 第2のホルダー58は、蓄電デバイス54の下に配置されている。蓄電デバイス54の下部は第2のホルダー58にはめ込まれ、これにより蓄電デバイス54の移動が規制されている。第2のホルダー58は、たとえば熱可塑性樹脂を含む樹脂部材である。 The second holder 58 is arranged below the power storage device 54 . A lower portion of the electricity storage device 54 is fitted into a second holder 58, thereby restricting the movement of the electricity storage device 54. As shown in FIG. The second holder 58 is a resin member containing thermoplastic resin, for example.
 ホルダー接続部材60は、第1のホルダー56および第2のホルダー58に接続され、第1のホルダー56および第2のホルダー58の離間距離を設定距離に維持する。第1のホルダー56、第2のホルダー58および両端のホルダー接続部材60は枠を形成し、蓄電デバイス54は、この枠の中に配置される。中央部のホルダー接続部材60は、枠の中間部で第1のホルダー56および第2のホルダー58の離間距離を設定距離に維持する。ホルダー接続部材60は、たとえば熱可塑性樹脂を含む樹脂部材である。 The holder connection member 60 is connected to the first holder 56 and the second holder 58, and maintains the separation distance between the first holder 56 and the second holder 58 at a set distance. The first holder 56, the second holder 58, and the holder connecting members 60 at both ends form a frame, and the electrical storage device 54 is arranged in this frame. A central holder connection member 60 maintains a set distance between the first holder 56 and the second holder 58 at the middle of the frame. Holder connection member 60 is a resin member containing, for example, thermoplastic resin.
 連結バスバー62は、電気接続部材の一例であって、たとえば細長い板形状を有し、蓄電デバイス54の3つの列を横断するように第1のホルダー56上に配置されている。連結バスバー62は、各列において隣接された電極端子68にたとえば溶接され、各列において隣接する蓄電デバイス54を電気的に接続する。また、連結バスバー62は、溶接された電極端子68を、他の列において溶接された電極端子68に接続し、たとえば6つの蓄電デバイス54を電気的に接続する。連結バスバー62は、たとえば電極端子68と同様の部材である。 The connection bus bar 62 is an example of an electrical connection member, has an elongated plate shape, for example, and is arranged on the first holder 56 so as to traverse the three columns of the electricity storage devices 54 . The connecting busbars 62 are welded, for example, to adjacent electrode terminals 68 in each row to electrically connect adjacent power storage devices 54 in each row. The connecting busbars 62 also connect the welded electrode terminals 68 to the welded electrode terminals 68 in the other rows to electrically connect, for example, six electrical storage devices 54 . The connection bus bar 62 is a member similar to the electrode terminal 68, for example.
 端部バスバー64は、第2の部材の一例であって、電極端子68を負荷などの他の部材に電気的に接続可能な電気接続部材である。端部バスバー64は、たとえば細長い板形状または細長いほぼ板形状を有し、蓄電デバイス54の3つの列を横断するように第1のホルダー56上に配置されている。端部バスバー64は、各列において端の電極端子68に溶接される。また、端部バスバー64は、溶接された電極端子68を、他の列において溶接された電極端子68に接続し、たとえば3つの蓄電デバイス54を電気的に接続する。 The end bus bar 64 is an example of a second member, and is an electrical connection member capable of electrically connecting the electrode terminals 68 to other members such as loads. The end busbar 64 has, for example, an elongated plate shape or an elongated substantially plate shape, and is arranged on the first holder 56 so as to traverse the three columns of the electricity storage devices 54 . End busbars 64 are welded to end electrode terminals 68 in each row. End busbars 64 also connect welded electrode terminals 68 to welded electrode terminals 68 in other rows to electrically connect, for example, three electrical storage devices 54 .
 端部バスバー64は、たとえばアルミニウム-マグネシウム系合金(合金番号:5052)からなる金属部材である。アルミニウム-マグネシウム系合金(合金番号:5052)は、優れた耐食性、加工性を有し、高い強度、硬度を有し、クリープによる変形を抑制する。アルミニウム-マグネシウム系合金(合金番号:5052)は、流通性を有しコスト的に優れている。端部バスバー64がボルト、ネジなどの締結部材で他の部材に締結された場合、高い強度を有する端部バスバー64は、締結部材の緩みを抑制できる。 The end busbar 64 is a metal member made of, for example, an aluminum-magnesium alloy (alloy number: 5052). An aluminum-magnesium alloy (alloy number: 5052) has excellent corrosion resistance and workability, has high strength and hardness, and suppresses deformation due to creep. An aluminum-magnesium alloy (alloy number: 5052) has good distribution and is excellent in terms of cost. When the end bus bar 64 is fastened to another member with a fastening member such as a bolt or screw, the high-strength end bus bar 64 can suppress loosening of the fastening member.
 端部バスバー64は、3つの溶融接続部12および締結部70を含む。溶融接続部12は、実施の形態で記述した第2の接合面部16を含む。第2の接合面部16は、円周上などの環上に配置され、電極端子68の端部は、第2の接合面部16の内部に挿入される。電極端子68の第1の接合面部10は、板形状またはほぼ板形状を有する端部バスバー64の延長上に配置されている。溶接凝固部8が電極端子68の第1の接合面部10と端部バスバー64の第2の接合面部16の間に配置され、第1の接合面部10および第2の接合面部16に接合して、突合せ継手を形成する。溶接凝固部8は実施の形態で記述した溶接凝固部8と同様であり、その説明を省略する。電極端子68、端部バスバー64および溶接凝固部8が溶接構造72を形成し、電子部品52は溶接構造72を含む。 The end busbar 64 includes three fusion connections 12 and fastening portions 70 . The fusion joint 12 includes a second mating surface portion 16 as described in the embodiment. The second joint surface portion 16 is arranged on a ring, such as on a circumference, and the ends of the electrode terminals 68 are inserted inside the second joint surface portion 16 . The first joint surface portion 10 of the electrode terminal 68 is arranged on the extension of the end bus bar 64 having a plate shape or a substantially plate shape. The weld solidified portion 8 is arranged between the first joint surface portion 10 of the electrode terminal 68 and the second joint surface portion 16 of the end bus bar 64, and is joined to the first joint surface portion 10 and the second joint surface portion 16. , forming a butt joint. The solidified weld portion 8 is the same as the solidified weld portion 8 described in the embodiment, and the description thereof will be omitted. Electrode terminal 68 , end busbar 64 and weld solidification 8 form welded structure 72 , and electronic component 52 includes welded structure 72 .
 締結部70は、複数の締結孔18および複数の固定孔74を含む。締結孔18は、たとえば五個の締結孔18であって、締結部材による他の部材との締結に用いられる。固定孔74は、たとえば二個の固定孔74であり、締結孔18の外側に配置されている。固定孔74は、第1のホルダー56に対する端部バスバー64の固定に用いられる。たとえば端部バスバー64が電極端子68に溶接される前に、端部バスバー64は、位置決めのために固定孔74および固定具76により第1のホルダー56に固定される。溶接後に端部バスバー64が固定孔74および固定具76により第1のホルダー56に固定されると、固定時のわずかな端部バスバー64の変形により、応力が溶接凝固部8に加わる可能性がある。溶接前の端部バスバー64の固定は、固定時における溶接凝固部8への加圧可能性を取り去ることができる。 The fastening portion 70 includes multiple fastening holes 18 and multiple fixing holes 74 . The fastening holes 18 are, for example, five fastening holes 18, and are used for fastening the fastening member to another member. The fixing holes 74 are, for example, two fixing holes 74 and are arranged outside the fastening hole 18 . The fixing holes 74 are used for fixing the end busbars 64 to the first holder 56 . For example, before the end busbars 64 are welded to the electrode terminals 68, the end busbars 64 are fixed to the first holder 56 by fixing holes 74 and fasteners 76 for positioning. When the end bus bar 64 is fixed to the first holder 56 by the fixing hole 74 and the fixture 76 after welding, stress may be applied to the solidified weld portion 8 due to slight deformation of the end bus bar 64 during fixation. be. Fixing the end busbars 64 before welding can remove the possibility of pressurizing the weld solidification 8 during fixing.
 端部バスバー64は、図5に示されているように、目的に応じて他の孔および段差などを含んでもよい。 The end busbars 64 may include other holes, steps, etc., depending on the purpose, as shown in FIG.
 電子部品52は、図示されていないバランス回路、温度検知回路、電圧検知回路などの付加回路を含んでいてもよい。付加回路は、たとえば連結バスバー62または端部バスバー64に接続される。この付加回路とバスバーとの接続において、溶接凝固部8による突合せ継手が用いられてもよい。 The electronic component 52 may include additional circuits, such as a balance circuit, a temperature detection circuit, and a voltage detection circuit, which are not shown. The additional circuitry is connected to, for example, connection busbars 62 or end busbars 64 . A butt joint with a solidified weld 8 may be used to connect the additional circuit to the bus bar.
 電子部品52の製造工程は、製造方法の一例であって、たとえば組立工程および溶接工程を含む。 The manufacturing process of the electronic component 52 is an example of a manufacturing method and includes, for example, an assembly process and a welding process.
 組立工程では、蓄電デバイス54、第1のホルダー56、第2のホルダー58、ホルダー接続部材60、連結バスバー62、端部バスバー64および固定具76を組合わせて、図4に示されているようなモジュールを得る。 In the assembly process, the power storage device 54, the first holder 56, the second holder 58, the holder connection member 60, the connecting bus bar 62, the end bus bar 64 and the fixture 76 are combined to form a holder as shown in FIG. module.
 溶接工程では、たとえば実施の形態で記述した溶接方法により端部バスバー64を電極端子68に溶接する。連結バスバー62を電極端子68に溶接する。既述の溶接凝固部8を形成するため、たとえば実施の形態で記述した溶接方法により連結バスバー62を電極端子68に溶接してもよい。実施の形態で記述した溶接方法の説明を省略する。 In the welding process, the end busbars 64 are welded to the electrode terminals 68 by, for example, the welding method described in the embodiment. The connecting bus bar 62 is welded to the electrode terminal 68 . In order to form weld-solidified portion 8 described above, connection bus bar 62 may be welded to electrode terminal 68 by, for example, the welding method described in the embodiment. Description of the welding method described in the embodiment is omitted.
 実施例に係る電子部品によれば、次のような作用または効果が得られる。 According to the electronic component according to the embodiment, the following action or effect can be obtained.
 (1) 実施の形態で記述した作用または効果を得ることができる。 (1) The action or effect described in the embodiment can be obtained.
 (2) 高い強度、硬度を有する端部バスバー64が電極端子68に溶接されても、溶接凝固部8の割れを抑制することができる。 (2) Even if the end bus bar 64 having high strength and hardness is welded to the electrode terminal 68, cracking of the solidified weld portion 8 can be suppressed.
 (3) 割れの抑止により、電気抵抗の上昇および通電時の発熱を抑制することができる。 (3) By suppressing cracking, it is possible to suppress an increase in electrical resistance and heat generation during energization.
 (4) 電子部品52の電気的安定性を高めることができる。 (4) The electrical stability of the electronic component 52 can be enhanced.
 (5) 高い強度、硬度を有する端部バスバー64が他の部材との締締の緩みを抑制できる。つまり、高温環境または時間経過において端部バスバー64の厚さが維持され、そのため締結部材の軸力が維持され、締結部材の緩みが抑制される。したがって、電気抵抗の上昇が抑制される。 (5) The end busbars 64 having high strength and hardness can suppress loosening of tightening with other members. In other words, the thickness of the end bus bar 64 is maintained in a high-temperature environment or over time, so that the axial force of the fastening member is maintained and loosening of the fastening member is suppressed. Therefore, an increase in electrical resistance is suppressed.
 実施の形態または実施例の特徴事項や変形例を以下に列挙する。 The features and modifications of the embodiments or examples are listed below.
 (1) 上記実施の形態および実施例では、溶接凝固部8は、露出面において、環形状を有する。しかしながら、溶接凝固部8の形状は環形状に限定されない。たとえば、第2の部材6または端部バスバー64が端部に円弧形状の凹部を有し、この凹部が第1の部材4または電極端子68の端部側面に突合されて、円弧形状の溶接凝固部8が形成されてもよい。第1の部材4または電極端子68の上部の形状が円形以外の形状を有し、溶接凝固部8が第1の部材4または電極端子68の形状に対応する形状を有してもよい。 (1) In the above embodiments and examples, the solidified weld portion 8 has an annular shape on the exposed surface. However, the shape of the weld-solidified portion 8 is not limited to an annular shape. For example, the second member 6 or the end bus bar 64 has an arc-shaped recess at the end, and this recess is abutted against the end side surface of the first member 4 or the electrode terminal 68 to form an arc-shaped welding solidification. A portion 8 may be formed. The upper portion of the first member 4 or the electrode terminal 68 may have a shape other than a circular shape, and the solidified weld portion 8 may have a shape corresponding to the shape of the first member 4 or the electrode terminal 68 .
 (2) 上記実施の形態では第2の部材6が締結部14を含み、上記実施例では端部バスバー64が締結部70を含んでいる。しかしながら、第2の部材6は締結部14を含んでいなくてもよく、端部バスバー64は締結部70を含んでいなくてもよい。第2の部材6または端部バスバー64の素材は、締結の緩み以外の理由、たとえば剛性または耐擦傷性などの理由により制約されていてもよい。 (2) The second member 6 includes the fastening portion 14 in the above embodiment, and the end bus bar 64 includes the fastening portion 70 in the above embodiment. However, the second member 6 may not include the fastening portion 14 and the end busbar 64 may not include the fastening portion 70 . The material of the second member 6 or end busbars 64 may be constrained for reasons other than loose fastening, such as stiffness or scratch resistance.
 (3) 上記実施の形態では、第2の部材6の締結部14が締結孔18を含んでいる。しかしながら、図6に示されているように、締結部14が雄ねじなどの締結部材118を含み、締結部材118により他の部材と締結されてもよい。上記実施例では、実施の形態と同様に、端部バスバー64の締結部70が締結部材118を含み、締結部材118により他の部材と締結されてもよい。 (3) In the above embodiment, the fastening portion 14 of the second member 6 includes the fastening hole 18 . However, as shown in FIG. 6, the fastening portion 14 may include a fastening member 118 such as a male screw, and be fastened to another member by the fastening member 118 . In the above example, the fastening portion 70 of the end bus bar 64 may include the fastening member 118 and may be fastened to another member by the fastening member 118, as in the embodiment.
 (4) 上記実施の形態および実施例の溶接方法では、凝固部36が再溶融されて第2の凝固部22が形成されている。溶接方法は、実施の形態および実施例の溶接方法に限定されない。たとえば、図7のCに示されているように、溶融部34の冷却途中に第2の加熱が溶融部34の一部を再加熱して再加熱部138を形成してもよく、図7のDに示されているように、再加熱部138が凝固して、第2の凝固部22が形成されてもよい。冷却は、たとえば自然冷却であり、軽度の強制冷却でもよい。溶融部34の一部の再加熱は、溶融部34の他の部分の冷却速度を遅くでき、第1の凝固部20の残留応力を抑制できる。 (4) In the welding methods of the above embodiments and examples, the solidified portion 36 is remelted to form the second solidified portion 22 . The welding method is not limited to the welding methods of the embodiments and examples. For example, as shown in FIG. 7C, during cooling of melt zone 34, a second heating may reheat a portion of melt zone 34 to form reheat zone 138, FIG. D, the reheat zone 138 may solidify to form a second solidified zone 22 . Cooling may be, for example, natural cooling or mild forced cooling. Partial reheating of the melted portion 34 can slow down the cooling rate of the other portion of the melted portion 34 and suppress residual stress in the first solidified portion 20 .
 (5) 上記実施例では、電極端子68が純アルミニウム(合金番号:1070)からなる金属部材であり、端部バスバー64が、アルミニウム-マグネシウム系合金(合金番号:5052)からなる金属部材である。しかしながら、電極端子68は既述の純アルミニウム(合金番号:1070)に限定されず、たとえば99%以上の純度を有する他の純アルミニウムからなる金属部材でもよい。端部バスバー64は、締結部材の緩みを抑制できる程度以上に強度が高ければよく、たとえば2000系材料から7000系材料までのアルミニウム合金から選択された、締結の緩みを抑制できるアルミニウム合金からなる金属部材でもよい。 (5) In the above embodiment, the electrode terminal 68 is a metal member made of pure aluminum (alloy number: 1070), and the end bus bar 64 is a metal member made of an aluminum-magnesium alloy (alloy number: 5052). . However, the electrode terminal 68 is not limited to pure aluminum (alloy number: 1070), and may be a metal member made of other pure aluminum having a purity of 99% or more, for example. The end busbars 64 need only be strong enough to suppress the looseness of the fastening member. For example, the end busbar 64 is made of a metal made of an aluminum alloy that can suppress loosening of the fastening, selected from aluminum alloys of the 2000 series to the 7000 series. It may be a member.
 (6) 上記実施例では、電子部品52が18個の蓄電デバイス54を含んでいる。しかしながら、蓄電デバイス54の数は、18個未満でもよく、18個を超えてもよい。また、電子部品52は、少なくとも一つの蓄電デバイス54を含む蓄電デバイスモジュールに限らず、バランス回路などの他の電子部品でもよい。 (6) In the above embodiment, the electronic component 52 includes 18 power storage devices 54 . However, the number of power storage devices 54 may be less than 18 or may be more than 18. Further, the electronic component 52 is not limited to an electricity storage device module including at least one electricity storage device 54, and may be another electronic component such as a balance circuit.
 以上説明したように、本開示の最も好ましい実施の形態等について説明した。本開示は、上記記載に限定されるものではなく、請求の範囲に記載され、または明細書に開示された発明の要旨に基づき、当業者において様々な変形や変更が可能である。斯かる変形や変更が、本開示の範囲に含まれることは言うまでもない。
As described above, the most preferable embodiment and the like of the present disclosure have been described. The present disclosure is not limited to the above description, and various modifications and changes can be made by those skilled in the art based on the gist of the invention described in the claims or disclosed in the specification. It goes without saying that such variations and modifications are included within the scope of the present disclosure.
 本開示の技術は、蓄電デバイスモジュール、回路などの電子部品における溶接だけでなく様々な部材の溶接に用いることができ、有用である。
The technique of the present disclosure is useful because it can be used not only for welding electronic components such as electrical storage device modules and circuits, but also for welding various members.
 2、72 溶接構造
 4 第1の部材
 6 第2の部材
 8 溶接凝固部
 10 第1の接合面部
 12 溶融接続部
 14、70 締結部
 16 第2の接合面部
 18 締結孔
 20 第1の凝固部
 22 第2の凝固部
 32 隣接部
 34 溶融部
 36 凝固部
 38 再溶融部
 52 電子部品
 54 蓄電デバイス
 56 第1のホルダー
 58 第2のホルダー
 60 ホルダー接続部材
 62 連結バスバー
 64 端部バスバー
 66 本体部
 68 電極端子
 74 固定孔
 76 固定具
 118 締結部材
 138 再加熱部
                                                                                
2, 72 welded structure 4 first member 6 second member 8 solidified welded portion 10 first joint surface portion 12 welded joint portion 14 , 70 fastening portion 16 second joint surface portion 18 fastening hole 20 first solidified portion 22 Second solidified portion 32 Adjacent portion 34 Melted portion 36 Solidified portion 38 Re-melted portion 52 Electronic component 54 Electricity storage device 56 First holder 58 Second holder 60 Holder connection member 62 Connection bus bar 64 End bus bar 66 Body portion 68 Electrode Terminal 74 Fixing hole 76 Fixing tool 118 Fastening member 138 Reheating unit

Claims (12)

  1.  第1の接合面部を有する第1の部材と、
     第2の接合面部を有する第2の部材と、
     突合せられた前記第1の部材と前記第2の部材の前記接合面部に溶接により形成された溶接凝固部と、
    を備え、
     前記溶接凝固部は、外側に配置された第1の凝固部と、内側に配置された第2の凝固部とを含むことを特徴とする溶接構造。
    a first member having a first joint surface;
    a second member having a second joint surface;
    a welded solidified portion formed by welding at the joint surface portion of the first member and the second member that are butted against each other;
    with
    The welded structure, wherein the weld solidified portion includes a first solidified portion arranged outside and a second solidified portion arranged inside.
  2.  前記第2の部材は、前記第1の部材よりも強度が高く、
     前記溶接凝固部の溶接中心部は、前記第1の部材と前記第2の部材の突合せ面に対して前記第1の部材側に配置されていることを特徴とする請求項1に記載の溶接構造。
    The second member has a higher strength than the first member,
    2. Welding according to claim 1, wherein the welding central portion of the weld solidified portion is arranged on the first member side with respect to the abutting surfaces of the first member and the second member. structure.
  3.  前記第2の部材は、他の部材と締結可能な締結部をさらに含むことを特徴とする請求項1または請求項2に記載の溶接構造。 The welded structure according to claim 1 or claim 2, wherein the second member further includes a fastening portion that can be fastened with another member.
  4.  前記第2の凝固部の断面の幅は、前記溶接凝固部の断面の幅の10%以上、70%以下であることを特徴とする請求項1ないし請求項3のいずれか一項に記載の溶接構造。 The width of the cross section of the second solidified portion is 10% or more and 70% or less of the width of the cross section of the weld solidified portion, according to any one of claims 1 to 3. Welded construction.
  5.  前記溶接凝固部は、環形状を有することを特徴とする請求項1ないし請求項4のいずれか一項に記載の溶接構造。 The welded structure according to any one of claims 1 to 4, wherein the weld solidified portion has an annular shape.
  6.  請求項1ないし請求項5のいずれか一項に記載された溶接構造を有する電子部品モジュール。 An electronic component module having the welded structure according to any one of claims 1 to 5.
  7.  互いに隣接された第1の部材および第2の部材の隣接部を第1の加熱により溶融して、溶融部を形成し、該溶融部を冷却する工程と、
     第2の加熱により、前記溶融部の一部を再溶融または再加熱して、外側に配置された第1の凝固部と内側に配置された第2の凝固部とを含む溶接凝固部を形成する工程と
     を備えることを特徴とする溶接方法。
    a step of melting the adjacent portions of the first member and the second member adjacent to each other by the first heating to form a melted portion, and cooling the melted portion;
    The second heating remelts or reheats a portion of the melted portion to form a weld solidified portion including an outer first solidified portion and an inner second solidified portion. A welding method comprising:
  8.  前記第2の部材は、前記第1の部材よりも強度が高く、
     前記第1の加熱は、前記第1の部材と前記第2の部材の突合せ面に対して前記第1の部材側に加えられることを特徴とする請求項7に記載の溶接方法。
    The second member has a higher strength than the first member,
    8. The welding method according to claim 7, wherein the first heating is applied to abutting surfaces of the first member and the second member on the side of the first member.
  9.  他の部材と締結可能な締結部を前記第2の部材に形成する工程をさらに備えることを特徴とする請求項7または請求項8に記載の溶接方法。 The welding method according to claim 7 or 8, further comprising the step of forming a fastening portion that can be fastened with another member on the second member.
  10.  前記第2の加熱により加えられる熱量は、前記第1の加熱により加えられる熱量の9%以上、50%以下であることを特徴とする請求項7ないし請求項9のいずれか一項に記載の溶接方法。 10. The heat quantity applied by the second heating is 9% or more and 50% or less of the heat quantity applied by the first heating. Welding method.
  11.  前記第1の加熱および前記第2の加熱は円周上に加えられ、
     前記溶接凝固部は環形状を有することを特徴とする請求項7ないし請求項10のいずれか一項に記載の溶接方法。
    the first heating and the second heating are applied circumferentially;
    The welding method according to any one of claims 7 to 10, wherein the weld solidified portion has an annular shape.
  12.  前記第1の部材は、電子部品の端子であり、または電子部品に接続可能な導電性部材であり、
     前記第2の部材は、前記第1の部材を他の部材に電気的に接続可能な電気接続部材であることを特徴とする請求項7ないし請求項11のいずれか一項に記載の溶接方法。
                                                                                    
    the first member is a terminal of an electronic component or a conductive member connectable to the electronic component;
    The welding method according to any one of claims 7 to 11, wherein the second member is an electrical connection member capable of electrically connecting the first member to another member. .
PCT/JP2022/036064 2021-09-29 2022-09-28 Weld structure, electronic component module, and welding method WO2023054424A1 (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015228334A (en) * 2014-06-02 2015-12-17 トヨタ自動車株式会社 Secondary battery and method for manufacturing the same
US20180281110A1 (en) * 2017-03-30 2018-10-04 NextEv USA, Inc. Single-position sequential laser welding system
JP6846608B2 (en) * 2015-09-15 2021-03-24 パナソニックIpマネジメント株式会社 Welding structure and welding method for metal parts

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015228334A (en) * 2014-06-02 2015-12-17 トヨタ自動車株式会社 Secondary battery and method for manufacturing the same
JP6846608B2 (en) * 2015-09-15 2021-03-24 パナソニックIpマネジメント株式会社 Welding structure and welding method for metal parts
US20180281110A1 (en) * 2017-03-30 2018-10-04 NextEv USA, Inc. Single-position sequential laser welding system

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