WO2023045115A1 - Nanofeuille de mxène auto-réticulée à haute stabilité, son procédé de préparation et son application - Google Patents
Nanofeuille de mxène auto-réticulée à haute stabilité, son procédé de préparation et son application Download PDFInfo
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- WO2023045115A1 WO2023045115A1 PCT/CN2021/137978 CN2021137978W WO2023045115A1 WO 2023045115 A1 WO2023045115 A1 WO 2023045115A1 CN 2021137978 W CN2021137978 W CN 2021137978W WO 2023045115 A1 WO2023045115 A1 WO 2023045115A1
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- WIPO (PCT)
- Prior art keywords
- mxene
- nanosheets
- layer
- ions
- sulfonic acid
- Prior art date
Links
- 239000002135 nanosheet Substances 0.000 title claims abstract description 154
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 229920001609 Poly(3,4-ethylenedioxythiophene) Polymers 0.000 claims abstract description 85
- 229910001415 sodium ion Inorganic materials 0.000 claims abstract description 60
- 239000000463 material Substances 0.000 claims abstract description 57
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims abstract description 45
- 238000009830 intercalation Methods 0.000 claims abstract description 42
- 230000002687 intercalation Effects 0.000 claims abstract description 42
- 229920001690 polydopamine Polymers 0.000 claims abstract description 29
- 230000004048 modification Effects 0.000 claims abstract description 26
- 238000012986 modification Methods 0.000 claims abstract description 26
- 238000011065 in-situ storage Methods 0.000 claims abstract description 14
- 210000004027 cell Anatomy 0.000 claims abstract description 11
- 210000000578 peripheral nerve Anatomy 0.000 claims abstract description 11
- 230000008439 repair process Effects 0.000 claims abstract description 4
- VYFYYTLLBUKUHU-UHFFFAOYSA-N dopamine Chemical compound NCCC1=CC=C(O)C(O)=C1 VYFYYTLLBUKUHU-UHFFFAOYSA-N 0.000 claims description 96
- 239000000243 solution Substances 0.000 claims description 89
- 229960003638 dopamine Drugs 0.000 claims description 48
- 238000006116 polymerization reaction Methods 0.000 claims description 33
- 230000001590 oxidative effect Effects 0.000 claims description 32
- 239000000017 hydrogel Substances 0.000 claims description 24
- YMMGRPLNZPTZBS-UHFFFAOYSA-N 2,3-dihydrothieno[2,3-b][1,4]dioxine Chemical compound O1CCOC2=C1C=CS2 YMMGRPLNZPTZBS-UHFFFAOYSA-N 0.000 claims description 22
- GKWLILHTTGWKLQ-UHFFFAOYSA-N 2,3-dihydrothieno[3,4-b][1,4]dioxine Chemical compound O1CCOC2=CSC=C21 GKWLILHTTGWKLQ-UHFFFAOYSA-N 0.000 claims description 17
- 239000006185 dispersion Substances 0.000 claims description 17
- 238000006243 chemical reaction Methods 0.000 claims description 15
- HVBSAKJJOYLTQU-UHFFFAOYSA-N Sulfanilic acid Natural products NC1=CC=C(S(O)(=O)=O)C=C1 HVBSAKJJOYLTQU-UHFFFAOYSA-N 0.000 claims description 14
- -1 sulfanilic acid diazonium salts Chemical class 0.000 claims description 13
- 229910052799 carbon Inorganic materials 0.000 claims description 12
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims description 12
- 239000012954 diazonium Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 229920002401 polyacrylamide Polymers 0.000 claims description 11
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 210000005036 nerve Anatomy 0.000 claims description 10
- 239000003054 catalyst Substances 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- 229950000244 sulfanilic acid Drugs 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 235000010288 sodium nitrite Nutrition 0.000 claims description 6
- 239000000758 substrate Substances 0.000 claims description 6
- 239000012670 alkaline solution Substances 0.000 claims description 5
- 239000000919 ceramic Substances 0.000 claims description 5
- 229910052720 vanadium Inorganic materials 0.000 claims description 5
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 claims description 4
- UEUIKXVPXLWUDU-UHFFFAOYSA-O 4-sulfobenzenediazonium Chemical compound OS(=O)(=O)C1=CC=C([N+]#N)C=C1 UEUIKXVPXLWUDU-UHFFFAOYSA-O 0.000 claims description 4
- 239000007853 buffer solution Substances 0.000 claims description 4
- 239000011159 matrix material Substances 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 4
- 239000007800 oxidant agent Substances 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 3
- 238000006845 Michael addition reaction Methods 0.000 claims description 3
- 239000000806 elastomer Substances 0.000 claims description 3
- 229920001971 elastomer Polymers 0.000 claims description 3
- 229910001447 ferric ion Inorganic materials 0.000 claims description 3
- 229910052715 tantalum Inorganic materials 0.000 claims description 3
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 claims description 2
- 102000008186 Collagen Human genes 0.000 claims description 2
- 108010035532 Collagen Proteins 0.000 claims description 2
- 102000009123 Fibrin Human genes 0.000 claims description 2
- 108010073385 Fibrin Proteins 0.000 claims description 2
- BWGVNKXGVNDBDI-UHFFFAOYSA-N Fibrin monomer Chemical compound CNC(=O)CNC(=O)CN BWGVNKXGVNDBDI-UHFFFAOYSA-N 0.000 claims description 2
- 102000008946 Fibrinogen Human genes 0.000 claims description 2
- 108010049003 Fibrinogen Proteins 0.000 claims description 2
- 108010010803 Gelatin Proteins 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 229940072056 alginate Drugs 0.000 claims description 2
- 229920000615 alginic acid Polymers 0.000 claims description 2
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- 238000005530 etching Methods 0.000 claims description 2
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- 239000008273 gelatin Substances 0.000 claims description 2
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- 229920002674 hyaluronan Polymers 0.000 claims description 2
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- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 229920002101 Chitin Polymers 0.000 claims 1
- 229910003178 Mo2C Inorganic materials 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 7
- 230000001537 neural effect Effects 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 59
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 37
- 239000008367 deionised water Substances 0.000 description 17
- 229910021641 deionized water Inorganic materials 0.000 description 17
- 238000000034 method Methods 0.000 description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 239000000499 gel Substances 0.000 description 15
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- 230000003647 oxidation Effects 0.000 description 11
- 238000007254 oxidation reaction Methods 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- QKNYBSVHEMOAJP-UHFFFAOYSA-N 2-amino-2-(hydroxymethyl)propane-1,3-diol;hydron;chloride Chemical compound Cl.OCC(N)(CO)CO QKNYBSVHEMOAJP-UHFFFAOYSA-N 0.000 description 8
- 150000001989 diazonium salts Chemical class 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 238000001069 Raman spectroscopy Methods 0.000 description 7
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 7
- 238000001727 in vivo Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 125000000542 sulfonic acid group Chemical group 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 241000699670 Mus sp. Species 0.000 description 5
- 230000021164 cell adhesion Effects 0.000 description 5
- 238000009792 diffusion process Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 4
- 239000004809 Teflon Substances 0.000 description 4
- 229920006362 Teflon® Polymers 0.000 description 4
- 229910009818 Ti3AlC2 Inorganic materials 0.000 description 4
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- 238000001237 Raman spectrum Methods 0.000 description 2
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 2
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- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 210000000689 upper leg Anatomy 0.000 description 2
- 229920001661 Chitosan Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000699666 Mus <mouse, genus> Species 0.000 description 1
- 102000003992 Peroxidases Human genes 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910004470 Ta4AlC3 Inorganic materials 0.000 description 1
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- 239000002270 dispersing agent Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000012983 electrochemical energy storage Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 210000000653 nervous system Anatomy 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
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- 210000001428 peripheral nervous system Anatomy 0.000 description 1
- 108040007629 peroxidase activity proteins Proteins 0.000 description 1
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- 230000037048 polymerization activity Effects 0.000 description 1
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- 230000001737 promoting effect Effects 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 239000003642 reactive oxygen metabolite Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- 210000002107 sheath cell Anatomy 0.000 description 1
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- 239000010959 steel Substances 0.000 description 1
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- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/90—Carbides
- C01B32/914—Carbides of single elements
- C01B32/921—Titanium carbide
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N1/00—Electrotherapy; Circuits therefor
- A61N1/02—Details
- A61N1/04—Electrodes
- A61N1/05—Electrodes for implantation or insertion into the body, e.g. heart electrode
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
- A61N1/00—Electrotherapy; Circuits therefor
- A61N1/02—Details
- A61N1/04—Electrodes
- A61N1/05—Electrodes for implantation or insertion into the body, e.g. heart electrode
- A61N1/0551—Spinal or peripheral nerve electrodes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/90—Carbides
- C01B32/914—Carbides of single elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/90—Carbides
- C01B32/914—Carbides of single elements
- C01B32/949—Tungsten or molybdenum carbides
Definitions
- the MXene of the present invention is different from the film-forming ability of MXene in the prior art.
- the MXene materials of the present invention form a stable structure that relies on covalent bonds, while the MXene in the prior art relies on the re-stacking of sheets and sheets.
- the van der Waals force between layers is realized, so the MXene of the present invention has better film-forming stability in water.
- FIG. 13 is the SEM scanning electron microscope morphology of the nanosheets obtained in Example 9.
- MXene-NSD-PEDOT nanosheets with a layer of polymerized dopamine and a layer of non-oxidative polyethylenedioxythiophene, and the intercalation of Na ions and sulfonic acid modified MXene Nanosheets
- the non-oxidizing polyethylene dioxythiophene layer covers the surface of the neutralized and synthesized MXene-NSD in 4).
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Veterinary Medicine (AREA)
- Cardiology (AREA)
- Heart & Thoracic Surgery (AREA)
- Engineering & Computer Science (AREA)
- Biomedical Technology (AREA)
- Public Health (AREA)
- Radiology & Medical Imaging (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Neurology (AREA)
- Neurosurgery (AREA)
- Orthopedic Medicine & Surgery (AREA)
- Carbon And Carbon Compounds (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Abstract
La présente invention concerne une nanofeuille de MXène auto-réticulée à haute stabilité, son procédé de préparation et son application. Plus particulièrement, l'invention concerne une nanofeuille de MXène modifiée en surface. La nanofeuille de MXène comprend des ions Na et une couche d'intercalation d'acide sulfonique, et sa surface comprend une couche de polydopamine et une couche de polyéthylène dioxythiophène, la couche de polydopamine et la couche de polyéthylène dioxythiophène étant fournies séquentiellement ; plus particulièrement, la couche de polydopamine est polymérisée sur la surface de la nanofeuille de MXène comprenant des ions Na et une couche d'intercalation d'acide sulfonique, puis la couche de polyéthylène dioxythiophène est polymérisée in situ. Les modifications de la nanofeuille de MXène interagissent les unes avec les autres, et diverses propriétés, telles que la stabilité physique et chimique, la capacité à former des films et la biocompatibilité, de la nanofeuille de MXène dans un corps biologique sont améliorées. Par conséquent, la nanofeuille de MXène peut être utilisée comme matériau de modification d'électrode, matériau de réparation de cellules nerveuses périphériques, conducteur d'électrode neuronale, site d'électrode nerveuse centrale, etc.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202180009669.5A CN115135351B (zh) | 2021-09-23 | 2021-12-14 | 一种高稳定的自连结MXene纳米片及其制备方法和应用 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111114668.5A CN113800521A (zh) | 2021-09-23 | 2021-09-23 | 一种高稳定的自连结MXene纳米片及其制备方法和应用 |
| CN202111114668.5 | 2021-09-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2023045115A1 true WO2023045115A1 (fr) | 2023-03-30 |
Family
ID=78940279
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/CN2021/137978 WO2023045115A1 (fr) | 2021-09-23 | 2021-12-14 | Nanofeuille de mxène auto-réticulée à haute stabilité, son procédé de préparation et son application |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN113800521A (fr) |
| WO (1) | WO2023045115A1 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116351403A (zh) * | 2023-05-08 | 2023-06-30 | 青岛科技大学 | MXene/rGO气凝胶、PDA/CS/MXene/rGO气凝胶及其制备方法和应用 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115487310A (zh) * | 2022-09-19 | 2022-12-20 | 中南大学湘雅医院 | 一种靶向药物及其制备方法和应用 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20170294546A1 (en) * | 2014-09-25 | 2017-10-12 | Drexel University | Physical Forms of MXene Materials Exhibiting Novel Electrical and Optical Characteristics |
| CN109096754A (zh) * | 2018-07-12 | 2018-12-28 | 大连理工大学 | 一种MXene-聚多巴胺复合材料及其制备方法 |
| CN111447968A (zh) * | 2017-09-15 | 2020-07-24 | 宾夕法尼亚大学理事会 | 使用2D金属碳化物和氮化物(MXene)的植入型器件 |
| CN112490019A (zh) * | 2020-12-09 | 2021-03-12 | 桂林电子科技大学 | 一种聚多巴胺包覆的MXene基复合材料其制备方法和应用 |
| WO2021072320A1 (fr) * | 2019-10-11 | 2021-04-15 | The Trustees Of The University Of Pennsylvania | Fabrication rapide de substrats absorbants pour des capteurs et des conducteurs souples et adaptés |
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| WO2021124958A1 (fr) * | 2019-12-16 | 2021-06-24 | 株式会社村田製作所 | Condensateur électrochimique |
| CN111686585B (zh) * | 2020-06-01 | 2021-07-23 | 天津工业大学 | 一种改性聚合物膜及其制备方法和用途 |
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| US20170294546A1 (en) * | 2014-09-25 | 2017-10-12 | Drexel University | Physical Forms of MXene Materials Exhibiting Novel Electrical and Optical Characteristics |
| CN111447968A (zh) * | 2017-09-15 | 2020-07-24 | 宾夕法尼亚大学理事会 | 使用2D金属碳化物和氮化物(MXene)的植入型器件 |
| CN109096754A (zh) * | 2018-07-12 | 2018-12-28 | 大连理工大学 | 一种MXene-聚多巴胺复合材料及其制备方法 |
| WO2021072320A1 (fr) * | 2019-10-11 | 2021-04-15 | The Trustees Of The University Of Pennsylvania | Fabrication rapide de substrats absorbants pour des capteurs et des conducteurs souples et adaptés |
| CN112490019A (zh) * | 2020-12-09 | 2021-03-12 | 桂林电子科技大学 | 一种聚多巴胺包覆的MXene基复合材料其制备方法和应用 |
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| WUSTONI SHOFARUL; SALEH ABDULELAH; EL-DEMELLAWI JEHAD K.; KOKLU ANIL; HAMA ADEL; DRUET VICTOR; WEHBE NIMER; ZHANG YIZHOU; INAL SAH: "MXene improves the stability and electrochemical performance of electropolymerized PEDOT films", APL MATERIALS, vol. 8, no. 12, 22 December 2020 (2020-12-22), pages 1 - 11, XP012252486, DOI: 10.1063/5.0023187 * |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN116351403A (zh) * | 2023-05-08 | 2023-06-30 | 青岛科技大学 | MXene/rGO气凝胶、PDA/CS/MXene/rGO气凝胶及其制备方法和应用 |
| CN116351403B (zh) * | 2023-05-08 | 2023-10-13 | 青岛科技大学 | MXene/rGO气凝胶、PDA/CS/MXene/rGO气凝胶及其制备方法和应用 |
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