WO2023029411A1 - Moving bed adsorption tower and flue gas purification system having same - Google Patents

Moving bed adsorption tower and flue gas purification system having same Download PDF

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Publication number
WO2023029411A1
WO2023029411A1 PCT/CN2022/078430 CN2022078430W WO2023029411A1 WO 2023029411 A1 WO2023029411 A1 WO 2023029411A1 CN 2022078430 W CN2022078430 W CN 2022078430W WO 2023029411 A1 WO2023029411 A1 WO 2023029411A1
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WIPO (PCT)
Prior art keywords
flue gas
moving bed
adsorption tower
bed adsorption
distributor
Prior art date
Application number
PCT/CN2022/078430
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French (fr)
Chinese (zh)
Inventor
许世森
汪世清
梁鹤涛
郜时旺
肖平
刘练波
牛红伟
黄斌
雷中辉
Original Assignee
中国华能集团有限公司
中国华能集团清洁能源技术研究院有限公司
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Filing date
Publication date
Priority claimed from CN202122240687.4U external-priority patent/CN216149387U/en
Priority claimed from CN202111082803.2A external-priority patent/CN113828110B/en
Application filed by 中国华能集团有限公司, 中国华能集团清洁能源技术研究院有限公司 filed Critical 中国华能集团有限公司
Publication of WO2023029411A1 publication Critical patent/WO2023029411A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/06Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
    • B01D53/08Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds according to the "moving bed" method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/08Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
    • B01J8/12Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by gravity in a downward flow

Definitions

  • the present disclosure relates to the technical field of flue gas treatment, in particular to a moving bed adsorption tower and a flue gas purification system having the same.
  • the present disclosure aims to solve one of the technical problems in the related art at least to a certain extent. For this reason, the embodiment of the present disclosure proposes a moving bed adsorption tower with uniform blanking.
  • Embodiments of the present disclosure also propose a flue gas purification system comprising the above-mentioned moving bed adsorption tower.
  • the moving bed adsorption tower includes a tower body, the tower body has a cavity, and the tower body is provided with a feeding port, a material outlet, a flue gas inlet and a flue gas outlet communicating with the cavity , the cavity has an inlet section, a packing section and a cloth section in the flow direction of the flue gas, and the packing section is used to fill the adsorbent; the distributor, the distributor is arranged in the tower body, the distribution The distributor is provided with several feeding openings arranged at intervals, the distributor is located below the packing section so that the adsorbent in the packing section flows out through the feeding openings, and the several feeding openings include the first part and The second part, the discharge openings in the first part are arranged around the discharge openings in the second part, and the average cross-sectional area of the discharge openings in the first part is larger than the discharge openings in the second part The average cross-sectional area of the mouth.
  • the moving bed adsorption tower according to the embodiment of the present disclosure has the advantages of uniform material dropping speed and uniform adsorption effect.
  • the cross-sectional areas of the several discharge openings increase sequentially from the inside to the outside.
  • the distributor includes a distribution plate, the discharge opening is arranged on the distribution plate, the distribution plate is connected with the peripheral wall of the cavity, and the smoke inlet is located on the distribution plate Below, the distribution plate has a centerline extending in the vertical direction, the farther away from the centerline, the larger the cross-sectional area of the discharge opening.
  • each row of discharge openings includes several of the discharge openings, and the plurality of discharge openings in each row of discharge openings are arranged at intervals along the first direction.
  • the discharge openings are arranged at intervals in the second direction, the first direction and the second direction are perpendicular to each other, and two adjacent rows of discharge openings are aligned in the second direction.
  • the cross-section of the discharge opening is circular or square.
  • the interval between two adjacent blanking ports in the first direction is 20mm-100mm, and the interval between two adjacent blanking ports in the second direction is 20mm-100mm.
  • the moving bed adsorption tower further includes a plurality of downpipes, the plurality of downpipes correspond to the plurality of downholes one by one, the downpipes are located below the distribution plate and There is a space between the distribution plate and the flue gas flow, and the discharge pipe is located above the discharge port.
  • the vertical dimension of the gap between the top end of the drop tube and the lower end surface of the distribution plate is 20mm-100mm.
  • the moving bed adsorption tower also includes a distributor, the distributor is arranged in the tower body, the distributor includes several distribution inlets and several distribution outlets corresponding to the distribution inlets, the distributor Located below the feeding port and above the packing section, so as to distribute the adsorbent entering from the feeding port to the packing section, the flue gas outlet is located below the cloth inlet and the cloth above the exit.
  • the flue gas purification system includes a flue gas cooling device, the flue gas cooling device has a smoke inlet and a smoke outlet, and the flue gas cooling device is used to convert the smoke entering from the smoke inlet into The gas is cooled to room temperature and below; the moving bed adsorption tower, the moving bed adsorption tower is the moving bed adsorption tower according to any one of the above-mentioned embodiments, the smoke outlet of the flue gas cooling device is connected with the moving bed adsorption tower The outlet of the flue gas is connected, and the moving bed adsorption tower is used to adsorb the flue gas.
  • FIG. 1 is a front view of a moving bed adsorption column according to an embodiment of the present disclosure.
  • FIG. 2 is a top view of a moving bed adsorption column according to an embodiment of the disclosure.
  • Fig. 3 is a cross-sectional view at A-A in Fig. 2 .
  • Fig. 4 is a cross-sectional view at B-B in Fig. 3 .
  • FIG. 5 is a cross-sectional view at B-B in FIG. 3 of another embodiment of the present disclosure.
  • FIG. 6 is a front view of the distributor of FIG. 3 .
  • FIG. 7 is a front view of the distributor of FIG. 3 according to another embodiment of the present disclosure.
  • FIG. 8 is a cross-sectional view at A-A in FIG. 2 of another embodiment of the present disclosure.
  • Tower body 1 material distribution section 11; feeding port 111; packing section 12; flue gas outlet 121; air intake section 13; flue gas inlet 131; discharge section 14; discharge port 141;
  • Distributor 2 Distributor 2; distribution plate 21; discharge port 22; distribution pipe 23;
  • a moving bed adsorption tower includes a tower body 1 and a distributor 2 .
  • the tower body 1 is provided with a feed port 111, a discharge port 141, a flue gas inlet 131 and a flue gas outlet 121 communicating with the cavity, and the cavity has an inlet section in the flow direction of the flue gas 13.
  • the packing section 12 and the cloth section 11, the packing section 12 is used for filling the adsorbent.
  • the flue gas inlet 131 communicates with the air inlet section 13
  • the flue gas outlet 121 communicates with the material distribution section 11
  • the feeding port 111 communicates with the material distributing section 11
  • the feeding port 111 and the flue gas outlet 121 are located above the packing section 12, and the discharge The port 141 and the flue gas inlet 131 are located below the packing section 12 .
  • the flue gas flow direction is from the flue gas inlet 131 to the flue gas outlet 121
  • the fabric section 11 , filler section 12 and air intake section 13 are arranged sequentially from top to bottom.
  • the flue gas enters the interior of the tower body 1 from the lower half of the tower body 1 and flows out from the upper side of the tower body 1, and the adsorbent enters the tower body 1 from the upper side of the tower body 1 and flows out from the lower end of the tower body 1 , the flow direction of the flue gas is opposite to that of the adsorbent, the concentration of nitrogen and sulfur in the flue gas gradually decreases as the flue gas rises, the adsorption effect of the adsorbent gradually decreases with the contact time with the flue gas, and the lower nitrogen and sulfur concentrations
  • the flue gas is contacted with an adsorbent with good adsorption effect, which can effectively reduce the concentration of nitrogen and sulfur in the gas discharged from the flue gas outlet 121, and improve the adsorption efficiency.
  • the distributor 2 is arranged in the tower body 1, and the distributor 2 is provided with a plurality of blanking openings 22 arranged at intervals.
  • the distributor 2 is located below the packing section 12 so that the adsorbent in the packing section 12 flows out through the feeding openings 22.
  • the discharge port 22 includes a first part and a second part, the discharge port 22 in the first part is arranged around the discharge port 22 in the second part, and the average cross-sectional area of the discharge port 22 in the first part is larger than that in the second part The average cross-sectional area of the blanking opening 22.
  • the blanking opening 22 is square, which improves the space utilization rate of the blanking opening 22 in the horizontal direction, thereby improving the efficiency of blanking.
  • the discharge opening 22 is a through hole on the distributor 2.
  • the first part is close to the horizontal center of the distributor 2, and the second part is arranged around the first part. This setting can improve the efficiency of the discharge at the edge of the distributor 2, so that the adsorbent particles can be distributed from the distributor 2. It falls evenly in the device 2, avoiding the situation that the center flow is large and the edge flow is small.
  • the distances between the geometric centers of adjacent blanking openings 22 are equal.
  • the moving bed adsorption tower according to the embodiment of the present disclosure has the advantage of uniform material discharge speed, and uniform material discharge speed means that the flow rate of the adsorbent in the adsorption tower is uniform, and the uniform flow rate of the adsorbent is beneficial to the uniform adsorption effect of the flue gas. Therefore, the moving bed adsorption tower according to the embodiment of the present disclosure also has the advantage of uniform adsorption effect.
  • the feeding opening 22 may also be circular.
  • the cross-sectional areas of the several feeding openings 22 increase sequentially from the inside to the outside.
  • the blanking openings 22 are evenly arranged on the distributor 2, the cross-sectional area of the blanking openings 22 near the center of the distributor 2 is relatively small, and the cross-sectional area of the blanking openings 22 near the edge of the distributor 2 is relatively large, so that the arrangement can improve
  • the efficiency of material dropping at the edge of the distributor 2 reduces the efficiency of material dropping at the center of the distributor 2, so that the adsorbent particles fall evenly from the distributor 2, avoiding the situation where the flow rate at the center is large and the flow rate at the edge is small.
  • the distributor 2 includes a distribution plate 21, the discharge opening 22 is arranged on the distribution plate 21, the distribution plate 21 is connected to the peripheral wall of the cavity, and the smoke inlet 131 is located on the side of the distribution plate 21.
  • the distribution plate 21 has a centerline extending in the vertical direction, and the farther it is from the centerline, the larger the cross-sectional area of the discharge opening 22 is.
  • the lower end of the distribution plate 21 is higher than the upper end of the flue gas inlet 131, and the flue gas inlet 131 is completely below the distribution plate 21, so that all the flue gas can pass through the blanking opening 22, which improves the adsorption capacity of the flue gas.
  • the contact time of the agent particles is improved, thereby improving the efficiency of adsorption.
  • each row of blanking openings 22 includes several blanking openings 22, and several blanking openings 22 in each row of blanking openings 22 are arranged at intervals along the first direction, Multiple rows of blanking openings 22 are arranged at intervals in the second direction, the first direction and the second direction are perpendicular to each other, and two adjacent rows of blanking openings 22 are aligned in the second direction.
  • the distribution plate 21 is a perforated flat plate, and the discharge opening 22 is the through hole on the distribution plate 21.
  • the distribution plate 21 is arranged horizontally, and the geometric centers of the adjacent two rows of discharge openings 22 are the same. Each row of discharge openings 22 The distance between the geometric centers of two adjacent blanking openings 22 is the same.
  • the horizontal arrangement of the distribution plate 21 can ensure that the adsorbent is evenly piled up on the top of the distribution plate 21, and the evenly arranged blanking opening 22 ensures that the material is evenly blanked so as to improve the efficiency of the material blanking.
  • the distribution plate 21 is rectangular, and the distribution plate 21
  • the length is 1000mm-3000mm
  • the width of the distribution plate 21 is 500mm-1500mm
  • the first direction is the length direction of the distribution plate 21
  • the second direction is the width direction of the distribution plate 21. It should be noted that, as shown in FIG. 4 , the first direction is the left-right direction, and the second direction is the front-rear direction.
  • the cross-section of the discharge port 22 is circular or square.
  • the section of the blanking opening 22 is circular, and the diameter of the blanking opening 22 is 100mm-300mm. Therefore, on the one hand, enough discharge openings 22 are provided on the distribution plate 21 to make the discharge more uniform; on the other hand, the diameter of the discharge openings 22 within the above range can make the adsorbent particles fall smoothly.
  • the cross section of the discharge opening 22 is square, and the side length of the discharge opening 22 is 150mm-300mm.
  • enough blanking openings 22 are provided on the distribution plate 21 to make the blanking more uniform; Mouth 22.
  • the interval between two adjacent blanking ports 22 in the first direction is 20mm-100mm
  • the interval between two adjacent blanking ports 22 in the second direction is 20mm-100mm. 100mm.
  • the distance between two adjacent blanking openings 22 is the distance between two nearest points of two adjacent blanking openings 22 .
  • the interval between two adjacent blanking ports 22 can be any value between 20mm and 100mm, for example, the interval between two adjacent blanking ports 22 can be 25mm, 30.7mm, 70mm, 86.85m wait. It should be noted that the interval between two adjacent discharge openings 22 in the first direction and the interval between two adjacent discharge openings 22 in the second direction may be the same or different.
  • the moving bed adsorption tower also includes a plurality of downpipes 3 corresponding to a plurality of downholes 22 one by one, and the downpipes 3 are located below the distribution plate 21 and connected to the distribution plate There is an interval between 21 to facilitate the flow of flue gas, and the discharge pipe 3 is located above the discharge port 141 .
  • the geometric center of the blanking opening 22 in the horizontal direction is the same as the geometric center of the blanking tube 3 in the horizontal direction, the upper end of the blanking tube 3 is spaced from the lower end of the distributor 2, and the smoke inlet 131 The upper edge is located below the blanking opening 22 to ensure that the flue gas inlet 131 is completely below the blanking opening 22 .
  • the flue gas enters the tower body 1 from the flue gas inlet 131, it enters the packing section 12 through the space between the blanking pipe 3 and the blanking port 22.
  • the path of the flue gas entering the seasoning section is shorter and smoother, and the smoke
  • the pressure drop caused by energy loss when the gas flows improves the fluency of the flue gas flowing in the packing section 12, thereby improving the adsorption effect.
  • the distributor 2 includes a distribution plate 21 and a plurality of distribution pipes 23, the distribution pipes 23 are connected to the lower end surface of the distribution plate 21 and extend downward from the distribution plate 21, and the distribution pipes 23 It is a square tube, and a plurality of distribution pipes 23 corresponds to a plurality of discharge openings 22 one by one, and a plurality of discharge pipes 3 corresponds to a plurality of distribution pipes 23 one to one.
  • the lower end of the distribution pipe 23 protrudes into the upper end of the corresponding drop pipe 3 , and there is an interval between the distribution pipe 23 and the corresponding drop pipe 3 .
  • the adsorbent passes through the distribution pipe 23 and falls into the discharge pipe 3, it can completely fall into the discharge pipe 3, preventing the adsorbent from splashing out from the gap between the discharge outlet 24 and the discharge pipe 3, thereby Prevent the adsorbent from flowing out of the tower body 1 from the flue gas inlet 131 .
  • the vertical dimension of the gap between the top end of the drop tube 3 and the lower end surface of the distribution plate 21 is 20mm-100m. Specifically, the vertical dimension of the gap between the drop tube 3 and the distribution plate 21 may be any value between 20 mm and 100 mm. In some embodiments, the vertical dimension of the gap between the drop tube 3 and the distribution plate 21 is 75mm, which is conducive to improving the flue gas passing through the gap between the drop tube 3 and the distribution plate 21. traffic.
  • the moving bed adsorption tower also includes a distributor 4, the distributor 4 is arranged in the tower body 1, the distributor 4 includes several distribution inlets and several distribution outlets corresponding to the distribution inlets, and the distributor 4 is located at the feeding port 111 Below and above the packing section 12, in order to distribute the adsorbent entering from the feeding port 111 to the packing section 12, the flue gas outlet 121 is located below the cloth inlet and above the cloth outlet.
  • the cloth inlet 41 corresponds to the cloth outlet 42 one by one, the cloth inlet 41 is above the cloth outlet 42, the cloth inlet 41 is arranged horizontally at equal intervals, the cross section of the cloth inlet 41 and the cloth outlet 42 is circular, and the cloth inlet 41 and Channels are formed between the distribution outlets 42 for the adsorbent particles to pass through the distributor 4 .
  • the distributor 4 makes the adsorbent particles accumulate on the upper side of the distributor 4, and falls into the filler section 12 through the cloth inlet 41 and the cloth outlet 42, and when the adsorbent passes through the uniformly arranged cloth inlet 41 and the cloth outlet
  • the outlet 42 will evenly fall into the packing section 12, and the adsorbent particles are evenly distributed in the packing section 12, so that the moving bed adsorption tower can absorb evenly and improve the adsorption effect.
  • the height of the upper edge of the smoke outlet 121 is lower than the height of the cloth inlet, and the height of the lower edge of the smoke outlet 121 is higher than the height of the cloth outlet, so that the smoke outlet 121 is completely located between the cloth inlet and the cloth outlet in the vertical direction. Between the outlets, on the one hand, the adsorbent particles are prevented from splashing out from the flue gas outlet 121, and on the other hand, the flue gas adsorption is more uniform.
  • the cavity further includes a discharge section 14 located below the cloth section 11 , the discharge section 14 is in an inverted cone shape, and the discharge port 141 communicates with the bottom of the discharge section 14 .
  • the cavity refers to the space inside the tower body 1
  • the discharge section 14 is an inverted quadrangular pyramid
  • the top of the discharge section 14 is connected with the inlet section 13
  • the discharge section 14 is a hollow structure
  • the inside of the discharge section 14 The space is connected with the cavity, the cross-sectional area of the discharge section 14 gradually decreases along the direction from top to bottom, and the discharge port 141 is arranged at the lower end of the discharge section 14 .
  • the adsorbent completes the adsorption of harmful components in the flue gas, it falls into the discharge section 14 through the discharge pipe 3 and is collected in the discharge section 14.
  • the material port 141 is discharged, and the recovered adsorbent is processed in the next step.
  • the material outlet 141 is closed, the harmful components escaping from the adsorbent flow upward together with the flue gas entering the flue gas inlet 131, and will not be volatilized. to the atmosphere.
  • the flue gas purification system includes a flue gas cooling device, the flue gas cooling device has a smoke inlet and a smoke outlet, and the flue gas cooling device is used to cool the flue gas entering from the smoke inlet to room temperature or below Moving bed adsorption tower, the moving bed adsorption tower is the moving bed adsorption tower according to any one of the above-mentioned embodiments, the smoke outlet of the flue gas cooling device is communicated with the flue gas outlet 121 of the moving bed adsorption tower, and the moving bed adsorption tower is used for Smoke is adsorbed.
  • the temperature of the flue gas entering the flue gas inlet 131 is -100° C. to room temperature (for example, the room temperature is 25° C.).
  • the sorbent is activated coke (carbon).
  • the flue gas purification system provided in this example adopts the low-temperature adsorption method when adsorbing the flue gas, and utilizes the dissolution characteristics and adsorption characteristics of the pollutant components in the flue gas at low temperatures to remove pollutants, and can simultaneously realize desulfurization and denitrification .
  • the sulfur dioxide in the flue gas is mainly physically adsorbed, the desorption temperature is low, the loss of the adsorbent is low, and the replenishment of the adsorbent is low, which reduces the operating cost.
  • the flue gas purification system that adsorbs at low temperature has a large adsorption capacity for pollutants, a small amount of adsorbent loading, and a small footprint for equipment such as moving bed adsorption towers.
  • the flue gas purification system provided in this example performs adsorption and purification of the flue gas
  • the NO x components that are difficult to remove in the flue gas are oxidized to NO by adsorption and removal at a low temperature through the mechanism of oxidation adsorption. It needs to inject NH3 for catalytic reduction, and the operation cost is low.
  • the flue gas purification system provided in this embodiment can absorb more than 99% of NOx in the flue gas, and the denitrification efficiency is obviously better than the 70-80% denitrification efficiency in the prior art.
  • first and second are used for descriptive purposes only, and cannot be interpreted as indicating or implying relative importance or implicitly specifying the quantity of indicated technical features.
  • the features defined as “first” and “second” may explicitly or implicitly include at least one of these features.
  • “plurality” means at least two, such as two, three, etc., unless otherwise specifically defined.
  • a first feature being “on” or “under” a second feature may mean that the first and second features are in direct contact, or that the first and second features are indirect through an intermediary. touch.
  • “above”, “above” and “above” the first feature on the second feature may mean that the first feature is directly above or obliquely above the second feature, or simply means that the first feature is higher in level than the second feature.
  • “Below”, “beneath” and “beneath” the first feature may mean that the first feature is directly below or obliquely below the second feature, or simply means that the first feature is less horizontally than the second feature.
  • the terms “one embodiment,” “some embodiments,” “example,” “specific examples,” or “some examples” mean a specific feature, structure, material, or feature described in connection with the embodiment or example. Features are included in at least one embodiment or example of the present disclosure. In this specification, the schematic representations of the above terms are not necessarily directed to the same embodiment or example. Furthermore, the described specific features, structures, materials or characteristics may be combined in any suitable manner in any one or more embodiments or examples. In addition, those skilled in the art can combine and combine different embodiments or examples and features of different embodiments or examples described in this specification without conflicting with each other.

Abstract

A moving bed adsorption tower. The moving bed adsorption tower comprises a tower body (1) and a distributor (2). A cavity is formed in the tower body (1). The tower body (1) is provided with a feed port (111), a discharge port (141), a flue gas inlet (131) and a flue gas outlet (121) which are in communication with the cavity. The cavity has an air inlet section (13), a material filling section (12) and a material adding section (11) in a flue gas flow direction. The material filling section (12) is used for filling an adsorbent. The distributor (2) is disposed in the tower body (1). The distributor (2) is provided with multiple blanking ports (22) arranged at intervals. The distributor (2) is located below the material packing section (12), such that the adsorbent in the material packing section (12) flows out through the blanking ports (22). The blanking ports (22) comprise a first portion and a second portion. The blanking ports (22) in the first portion are arranged surrounding the blanking ports (22) in the second portion. The average cross-sectional area of the blanking ports (22) in the first portion is greater than the average cross-sectional area of the blanking ports (22) in the second portion. The moving bed adsorption tower has the advantages of uniform blanking speed and uniform adsorption effects.

Description

移动床吸附塔和具有其的烟气净化系统Moving bed adsorption tower and its flue gas purification system
相关申请的交叉引用Cross References to Related Applications
本申请基于申请号为202122114270.3、申请日为2021年9月2日,申请号为202122240687.4、申请日为2021年9月15日,申请号为202111028514.4、申请日为2021年9月2日和申请号为202111082803.2、申请日为2021年9月15日的中国专利申请提出,并要求该中国申请的优先权,该中国专利申请的全部内容在此引入本申请作为参考。This application is based on the application number 202122114270.3, the application date is September 2, 2021, the application number is 202122240687.4, the application date is September 15, 2021, the application number is 202111028514.4, the application date is September 2, 2021 and the application number A Chinese patent application 202111082803.2 with a filing date of September 15, 2021 was filed, and the priority of this Chinese application is claimed. The entire content of this Chinese patent application is hereby incorporated by reference into this application.
技术领域technical field
本公开涉及烟气处理技术领域,具体涉及一种移动床吸附塔和具有其的烟气净化系统。The present disclosure relates to the technical field of flue gas treatment, in particular to a moving bed adsorption tower and a flue gas purification system having the same.
背景技术Background technique
燃煤烟气产生的大量污染物是危害大气环境和人类健康的重要因素之一。烟气净化领域通常采用固定床吸附塔对烟气中的污染物进行吸附以实现净化烟气的目的,但是相关技术中的固定床吸附塔在应用时普遍存在填料层压力与密度不均匀、吸附不均匀、吸附效果差、吸附能力随使用时间延长而降低的问题,而且在需要更换吸附剂时需要停止工作,严重影响吸附效率,提高了操作难度。The large amount of pollutants produced by coal combustion flue gas is one of the important factors that endanger the atmospheric environment and human health. In the field of flue gas purification, fixed bed adsorption towers are usually used to adsorb pollutants in flue gas to achieve the purpose of purifying flue gas. The problem of unevenness, poor adsorption effect, and the decrease of adsorption capacity with the extension of use time, and the need to stop working when the adsorbent needs to be replaced, seriously affects the adsorption efficiency and increases the difficulty of operation.
发明内容Contents of the invention
本公开旨在至少在一定程度上解决相关技术中的技术问题之一。为此,本公开的实施例提出一种落料均匀的移动床吸附塔。The present disclosure aims to solve one of the technical problems in the related art at least to a certain extent. For this reason, the embodiment of the present disclosure proposes a moving bed adsorption tower with uniform blanking.
本公开的实施例还提出一种包括上述移动床吸附塔的烟气净化系统。Embodiments of the present disclosure also propose a flue gas purification system comprising the above-mentioned moving bed adsorption tower.
根据本公开实施例的移动床吸附塔,包括塔体,所述塔体内具有空腔,所述塔体设有与所述空腔连通的加料口、出料口、烟气进口和烟气出口,所述空腔在烟气的流通方向上具有进气段、填料段和布料段,所述填料段用于填充吸附剂;分布器,所述分布器设在所述塔体内,所述分布器设有若干间隔排布的落料口,所述分布器位于所述填料段的下方以便所述填料段中的吸附剂通过所述落料口流出,所述若干落料口包括第一部分和第二部分,所述第一部分中的落料口环绕所述第二部分中的落料口排布,所述第一部分中的落料口的平均截面积大于所述第二部分中的落料口的平均截面积。The moving bed adsorption tower according to an embodiment of the present disclosure includes a tower body, the tower body has a cavity, and the tower body is provided with a feeding port, a material outlet, a flue gas inlet and a flue gas outlet communicating with the cavity , the cavity has an inlet section, a packing section and a cloth section in the flow direction of the flue gas, and the packing section is used to fill the adsorbent; the distributor, the distributor is arranged in the tower body, the distribution The distributor is provided with several feeding openings arranged at intervals, the distributor is located below the packing section so that the adsorbent in the packing section flows out through the feeding openings, and the several feeding openings include the first part and The second part, the discharge openings in the first part are arranged around the discharge openings in the second part, and the average cross-sectional area of the discharge openings in the first part is larger than the discharge openings in the second part The average cross-sectional area of the mouth.
根据本公开实施例的移动床吸附塔具有落料速度均匀、吸附效果均匀的优点。The moving bed adsorption tower according to the embodiment of the present disclosure has the advantages of uniform material dropping speed and uniform adsorption effect.
在一些实施例中,若干所述落料口的截面积从内向外依次增大。In some embodiments, the cross-sectional areas of the several discharge openings increase sequentially from the inside to the outside.
在一些实施例中,所述分布器包括分布板,所述落料口设在所述分布板上,所述分布板与所述空腔的周壁相连,所述烟气进口位于所述分布板的下方,所述分布板具有延竖直方向延伸的中心线,距离所述中心线越远,所述落料口的截面积越大。In some embodiments, the distributor includes a distribution plate, the discharge opening is arranged on the distribution plate, the distribution plate is connected with the peripheral wall of the cavity, and the smoke inlet is located on the distribution plate Below, the distribution plate has a centerline extending in the vertical direction, the farther away from the centerline, the larger the cross-sectional area of the discharge opening.
在一些实施例中,若干所述落料口排列为多排,每排落料口包括若干所述落料口,每排落料口中的若干落料口沿第一方向间隔排布,多排落料口在第二方向上间隔排布,所述第一方向和所述第二方向相互垂直,相邻两排落料口在第二方向上对齐。In some embodiments, several of the discharge openings are arranged in multiple rows, each row of discharge openings includes several of the discharge openings, and the plurality of discharge openings in each row of discharge openings are arranged at intervals along the first direction. The discharge openings are arranged at intervals in the second direction, the first direction and the second direction are perpendicular to each other, and two adjacent rows of discharge openings are aligned in the second direction.
在一些实施例中,所述落料口的截面为圆形或方形。In some embodiments, the cross-section of the discharge opening is circular or square.
在一些实施例中,在所述第一方向上相邻的两个落料口之间的间隔为20mm-100mm,在所述第二方向上相邻的两个落料口之间的间隔为20mm-100mm。In some embodiments, the interval between two adjacent blanking ports in the first direction is 20mm-100mm, and the interval between two adjacent blanking ports in the second direction is 20mm-100mm.
在一些实施例中,移动床吸附塔还包括多个落料管,多个所述落料管与多个所述落料口一一对应,所述落料管位于所述分布板的下方并与所述分布板之间具有间隔以便烟气流动,所述落料管位于所述出料口的上方。In some embodiments, the moving bed adsorption tower further includes a plurality of downpipes, the plurality of downpipes correspond to the plurality of downholes one by one, the downpipes are located below the distribution plate and There is a space between the distribution plate and the flue gas flow, and the discharge pipe is located above the discharge port.
在一些实施例中,所述落料管的顶端与所述分布板的下端面之间的缝隙在竖直方向上的尺寸为20mm-100mm。In some embodiments, the vertical dimension of the gap between the top end of the drop tube and the lower end surface of the distribution plate is 20mm-100mm.
在一些实施例中,移动床吸附塔还包括布料器,所述布料器设在所述塔体内,所述布料器包括若干布料入口和若干与所述布料入口对应的布料出口,所述布料器位于所述加料口的下方且位于所述填料段的上方,以便将从所述加料口进入的吸附剂分配到所述填料段,所述烟气出口位于所述布料入口的下方和所述布料出口的上方。In some embodiments, the moving bed adsorption tower also includes a distributor, the distributor is arranged in the tower body, the distributor includes several distribution inlets and several distribution outlets corresponding to the distribution inlets, the distributor Located below the feeding port and above the packing section, so as to distribute the adsorbent entering from the feeding port to the packing section, the flue gas outlet is located below the cloth inlet and the cloth above the exit.
根据本公开实施例的烟气净化系统,包括烟气冷却装置,所述烟气冷却装置具有进烟口和出烟口,所述烟气冷却装置用于将从所述进烟口进入的烟气冷却至室温及以下;移动床吸附塔,所述移动床吸附塔为根据上述任一实施例所述的移动床吸附塔,所述烟气冷却装置的出烟口与所述移动床吸附塔的所述烟气出口连通,所述移动床吸附塔用于对所述烟气进行吸附。The flue gas purification system according to an embodiment of the present disclosure includes a flue gas cooling device, the flue gas cooling device has a smoke inlet and a smoke outlet, and the flue gas cooling device is used to convert the smoke entering from the smoke inlet into The gas is cooled to room temperature and below; the moving bed adsorption tower, the moving bed adsorption tower is the moving bed adsorption tower according to any one of the above-mentioned embodiments, the smoke outlet of the flue gas cooling device is connected with the moving bed adsorption tower The outlet of the flue gas is connected, and the moving bed adsorption tower is used to adsorb the flue gas.
附图说明Description of drawings
图1是根据本公开实施例的移动床吸附塔的正视图。FIG. 1 is a front view of a moving bed adsorption column according to an embodiment of the present disclosure.
图2是根据本公开实施例的移动床吸附塔的俯视图。2 is a top view of a moving bed adsorption column according to an embodiment of the disclosure.
图3是图2中A-A处的剖视图。Fig. 3 is a cross-sectional view at A-A in Fig. 2 .
图4是图3中B-B处的剖视图。Fig. 4 is a cross-sectional view at B-B in Fig. 3 .
图5是本公开另一实施例的图3中B-B处的剖视图。FIG. 5 is a cross-sectional view at B-B in FIG. 3 of another embodiment of the present disclosure.
图6是图3中分布器的正视图。FIG. 6 is a front view of the distributor of FIG. 3 .
图7是本公开另一实施例的图3中分布器的正视图。7 is a front view of the distributor of FIG. 3 according to another embodiment of the present disclosure.
图8是本公开另一实施例的图2中A-A处的剖视图。FIG. 8 is a cross-sectional view at A-A in FIG. 2 of another embodiment of the present disclosure.
附图标记:Reference signs:
塔体1;布料段11;加料口111;填料段12;烟气出口121;进气段13;烟气进口131;出料段14;出料口141; Tower body 1; material distribution section 11; feeding port 111; packing section 12; flue gas outlet 121; air intake section 13; flue gas inlet 131; discharge section 14; discharge port 141;
分布器2;分布板21;落料口22;分布管23; Distributor 2; distribution plate 21; discharge port 22; distribution pipe 23;
落料管3; Blanking pipe 3;
布料器4;布料入口41;布料出口42。 Distributor 4; cloth inlet 41; cloth outlet 42.
具体实施方式Detailed ways
下面详细描述本公开的实施例,所述实施例的示例在附图中示出。下面通过参考附图描述的实施例是示例性的,旨在用于解释本公开,而不能理解为对本公开的限制。Embodiments of the present disclosure are described in detail below, examples of which are illustrated in the accompanying drawings. The embodiments described below by referring to the figures are exemplary and are intended to explain the present disclosure and should not be construed as limiting the present disclosure.
如图1至图3所示,根据本公开实施例的移动床吸附塔,包括塔体1和分布器2。As shown in FIGS. 1 to 3 , a moving bed adsorption tower according to an embodiment of the present disclosure includes a tower body 1 and a distributor 2 .
塔体1内具有空腔,塔体1设有与空腔连通的加料口111、出料口141、烟气进口131和烟气出口121,空腔在烟气的流通方向上具有进气段13、填料段12和布料段11,填料段12用于填充吸附剂。There is a cavity in the tower body 1, and the tower body 1 is provided with a feed port 111, a discharge port 141, a flue gas inlet 131 and a flue gas outlet 121 communicating with the cavity, and the cavity has an inlet section in the flow direction of the flue gas 13. The packing section 12 and the cloth section 11, the packing section 12 is used for filling the adsorbent.
具体地,烟气进口131与进气段13连通,烟气出口121与布料段11连通,加料口111与布料段11连通,加料口111和烟气出口121位于填料段12的上方,出料口141和烟气进口131位于填料段12的下方。需要说明的是,烟气流通方向是从烟气进口131到烟气出口121,布料段11、填料段12和进气段13沿着从上至下的方向依次排布。由此,烟气从塔体1的下半部进入塔体1的内部并从塔体1的上侧流出,吸附剂从塔体1的上侧进入塔体1并从塔体1的下端流出,烟气的流向与吸附剂的流向相反,烟气中氮和硫的浓度随着烟气上升逐渐降低,吸附剂的吸附效果随着与烟气接触的时间逐渐降低,较低氮和硫浓度的烟气较好吸附效果的吸附剂接触,能够有效降低从烟气出口121排出气体中氮和硫的浓度,提高吸附效率。Specifically, the flue gas inlet 131 communicates with the air inlet section 13, the flue gas outlet 121 communicates with the material distribution section 11, the feeding port 111 communicates with the material distributing section 11, the feeding port 111 and the flue gas outlet 121 are located above the packing section 12, and the discharge The port 141 and the flue gas inlet 131 are located below the packing section 12 . It should be noted that the flue gas flow direction is from the flue gas inlet 131 to the flue gas outlet 121 , and the fabric section 11 , filler section 12 and air intake section 13 are arranged sequentially from top to bottom. Thus, the flue gas enters the interior of the tower body 1 from the lower half of the tower body 1 and flows out from the upper side of the tower body 1, and the adsorbent enters the tower body 1 from the upper side of the tower body 1 and flows out from the lower end of the tower body 1 , the flow direction of the flue gas is opposite to that of the adsorbent, the concentration of nitrogen and sulfur in the flue gas gradually decreases as the flue gas rises, the adsorption effect of the adsorbent gradually decreases with the contact time with the flue gas, and the lower nitrogen and sulfur concentrations The flue gas is contacted with an adsorbent with good adsorption effect, which can effectively reduce the concentration of nitrogen and sulfur in the gas discharged from the flue gas outlet 121, and improve the adsorption efficiency.
分布器2设在塔体1内,分布器2设有若干间隔排布的落料口22,分布器2位于填料段12的下方以便填料段12中的吸附剂通过落料口22流出,若干落料口22包括第一部分和第二部分,第一部分中的落料口22环绕第二部分中的落料口22排布,第一部分中的落料口22的平均截面积大于第二部分中的落料口22的平均截面积。The distributor 2 is arranged in the tower body 1, and the distributor 2 is provided with a plurality of blanking openings 22 arranged at intervals. The distributor 2 is located below the packing section 12 so that the adsorbent in the packing section 12 flows out through the feeding openings 22. The discharge port 22 includes a first part and a second part, the discharge port 22 in the first part is arranged around the discharge port 22 in the second part, and the average cross-sectional area of the discharge port 22 in the first part is larger than that in the second part The average cross-sectional area of the blanking opening 22.
具体地,如图4所示,落料口22是方形,这样设置提高了落料口22对水平方向的空间利用率,从而提高了落料的效率。落料口22是分布器2上的通孔,第一部分靠近分布器2水平中心,第二部分环绕第一部分布置,这样设置能够提高分布器2边缘处落料的效率,使吸附剂颗粒从分布器2中均匀落下,避免了中心流量大、边缘流量小的情况。相邻落料口22的几何中心之间的距离相等。根据本公开实施例的移动床吸附塔具有落料速度均匀的优点,而落料速度均匀意味着吸附塔内吸附剂的流动速率均匀,吸附剂的流动速率均匀有利于烟气的吸附效果均匀。因此根据本公开实施例的移动床吸附塔还具有吸附效果均匀的优点。Specifically, as shown in FIG. 4 , the blanking opening 22 is square, which improves the space utilization rate of the blanking opening 22 in the horizontal direction, thereby improving the efficiency of blanking. The discharge opening 22 is a through hole on the distributor 2. The first part is close to the horizontal center of the distributor 2, and the second part is arranged around the first part. This setting can improve the efficiency of the discharge at the edge of the distributor 2, so that the adsorbent particles can be distributed from the distributor 2. It falls evenly in the device 2, avoiding the situation that the center flow is large and the edge flow is small. The distances between the geometric centers of adjacent blanking openings 22 are equal. The moving bed adsorption tower according to the embodiment of the present disclosure has the advantage of uniform material discharge speed, and uniform material discharge speed means that the flow rate of the adsorbent in the adsorption tower is uniform, and the uniform flow rate of the adsorbent is beneficial to the uniform adsorption effect of the flue gas. Therefore, the moving bed adsorption tower according to the embodiment of the present disclosure also has the advantage of uniform adsorption effect.
在其它一些实施例中,落料口22也可以是圆形。In some other embodiments, the feeding opening 22 may also be circular.
在一些实施例中,若干落料口22的截面积从内向外依次增大。In some embodiments, the cross-sectional areas of the several feeding openings 22 increase sequentially from the inside to the outside.
具体地,落料口22在分布器2上均匀布置,靠近分布器2中心位置的落料口22截面积较小,靠近分布器2边沿的落料口22截面积较大,这样设置能够提高分布器2边缘处落料的效率,降低分布器2中心处落料的效率,使吸附剂颗粒从分布器2中均匀落下,避免了中心流量大、边缘流量小的情况。Specifically, the blanking openings 22 are evenly arranged on the distributor 2, the cross-sectional area of the blanking openings 22 near the center of the distributor 2 is relatively small, and the cross-sectional area of the blanking openings 22 near the edge of the distributor 2 is relatively large, so that the arrangement can improve The efficiency of material dropping at the edge of the distributor 2 reduces the efficiency of material dropping at the center of the distributor 2, so that the adsorbent particles fall evenly from the distributor 2, avoiding the situation where the flow rate at the center is large and the flow rate at the edge is small.
在一些实施例中,如图6所示,分布器2包括分布板21,落料口22设在分布板21上,分布板21与空腔的周壁相连,烟气进口131位于分布板21的下方,分布板21具有延竖直方向延伸的中心线,距离中心线越远,落料口22的截面积越大。In some embodiments, as shown in FIG. 6 , the distributor 2 includes a distribution plate 21, the discharge opening 22 is arranged on the distribution plate 21, the distribution plate 21 is connected to the peripheral wall of the cavity, and the smoke inlet 131 is located on the side of the distribution plate 21. Below, the distribution plate 21 has a centerline extending in the vertical direction, and the farther it is from the centerline, the larger the cross-sectional area of the discharge opening 22 is.
具体地,分布板21的下端高于烟气进口131的上端,烟气进口131完全处于分布板21的下方,可以使全部烟气都从落料口22中穿过,提高了烟气与吸附剂颗粒的接触时间,从而提高了吸附的效率。Specifically, the lower end of the distribution plate 21 is higher than the upper end of the flue gas inlet 131, and the flue gas inlet 131 is completely below the distribution plate 21, so that all the flue gas can pass through the blanking opening 22, which improves the adsorption capacity of the flue gas. The contact time of the agent particles is improved, thereby improving the efficiency of adsorption.
在一些实施例中,若干落料口22排列为多排,每排落料口22包括若干落料口22,每排落料口22中的若干落料口22沿第一方向间隔排布,多排落料口22在第二方向上间隔排布,第一方向和第二方向相互垂直,相邻两排落料口22在第二方向上对齐。In some embodiments, several blanking openings 22 are arranged in multiple rows, each row of blanking openings 22 includes several blanking openings 22, and several blanking openings 22 in each row of blanking openings 22 are arranged at intervals along the first direction, Multiple rows of blanking openings 22 are arranged at intervals in the second direction, the first direction and the second direction are perpendicular to each other, and two adjacent rows of blanking openings 22 are aligned in the second direction.
具体地,分布板21是多孔平板,落料口22即为分布板21上的通孔,分布板21水平布置,相邻两排落料口22的几何中心间距相同,每排落料口22中相邻的两个落料口22的几何中心间距相同。由此,分布板21水平布置可以保证吸附剂均匀地堆积在分布板21的上方,均匀布置的落料口22保证落料均匀从而提高落料的效率,分布板21为矩形,分布板21的长度为1000mm-3000mm,分布板21的宽度为500mm-1500mm,第一方向为分布板21的长度方向,第二方向为分布板21的宽度方向。需要说明的是,如图4所示,第一方向即为左右方向,第二方向即为前后方向。Specifically, the distribution plate 21 is a perforated flat plate, and the discharge opening 22 is the through hole on the distribution plate 21. The distribution plate 21 is arranged horizontally, and the geometric centers of the adjacent two rows of discharge openings 22 are the same. Each row of discharge openings 22 The distance between the geometric centers of two adjacent blanking openings 22 is the same. Thus, the horizontal arrangement of the distribution plate 21 can ensure that the adsorbent is evenly piled up on the top of the distribution plate 21, and the evenly arranged blanking opening 22 ensures that the material is evenly blanked so as to improve the efficiency of the material blanking. The distribution plate 21 is rectangular, and the distribution plate 21 The length is 1000mm-3000mm, the width of the distribution plate 21 is 500mm-1500mm, the first direction is the length direction of the distribution plate 21, and the second direction is the width direction of the distribution plate 21. It should be noted that, as shown in FIG. 4 , the first direction is the left-right direction, and the second direction is the front-rear direction.
在一些实施例中,落料口22的截面为圆形或方形。In some embodiments, the cross-section of the discharge port 22 is circular or square.
具体地,如图5所示,落料口22的截面是圆形,落料口22的直径为100mm-300mm。由此,一方面使分布板21上设置足够多落料口22,从而使落料更均匀,另一方面落料口22的直径在上述范围内能够使吸附剂颗粒顺利落下。Specifically, as shown in FIG. 5 , the section of the blanking opening 22 is circular, and the diameter of the blanking opening 22 is 100mm-300mm. Therefore, on the one hand, enough discharge openings 22 are provided on the distribution plate 21 to make the discharge more uniform; on the other hand, the diameter of the discharge openings 22 within the above range can make the adsorbent particles fall smoothly.
在其它一些实施例中,如图4所示,落料口22的截面是方形,落料口22的边长为150mm-300mm。由此,一方面使分布板21上设置足够多落料口22,从而使落料更均匀,另一方面落料口22的边长在上述范围内能够使吸附剂颗粒顺利地穿过落料口22。In some other embodiments, as shown in FIG. 4 , the cross section of the discharge opening 22 is square, and the side length of the discharge opening 22 is 150mm-300mm. Thus, on the one hand, enough blanking openings 22 are provided on the distribution plate 21 to make the blanking more uniform; Mouth 22.
在一些实施例中,在第一方向上相邻的两个落料口22之间的间隔为20mm-100mm,在第二方向上相邻的两个落料口22之间的间隔为20mm-100mm。In some embodiments, the interval between two adjacent blanking ports 22 in the first direction is 20mm-100mm, and the interval between two adjacent blanking ports 22 in the second direction is 20mm-100mm. 100mm.
具体地,相邻的两个落料口22之间的间隔即为相邻的两个落料口22最近两点之间的距离。相邻的两个落料口22之间的间隔可以为20mm至100mm之间的任意数值,例如,相 邻的两个落料口22之间的间隔可以为25mm、30.7mm、70mm、86.85m等。需要说明的是,第一方向上相邻的两个落料口22之间的间隔与第二方向上相邻的两个落料口22之间的间隔可以相同也可以不同。Specifically, the distance between two adjacent blanking openings 22 is the distance between two nearest points of two adjacent blanking openings 22 . The interval between two adjacent blanking ports 22 can be any value between 20mm and 100mm, for example, the interval between two adjacent blanking ports 22 can be 25mm, 30.7mm, 70mm, 86.85m wait. It should be noted that the interval between two adjacent discharge openings 22 in the first direction and the interval between two adjacent discharge openings 22 in the second direction may be the same or different.
在一些实施例中,移动床吸附塔还包括多个落料管3,多个落料管3与多个落料口22一一对应,落料管3位于分布板21的下方并与分布板21之间具有间隔以便烟气流动,落料管3位于出料口141的上方。In some embodiments, the moving bed adsorption tower also includes a plurality of downpipes 3 corresponding to a plurality of downholes 22 one by one, and the downpipes 3 are located below the distribution plate 21 and connected to the distribution plate There is an interval between 21 to facilitate the flow of flue gas, and the discharge pipe 3 is located above the discharge port 141 .
具体地,落料口22在水平方向上的几何中心与落料管3在水平方向上的几何中心的位置相同,落料管3的上端与分布器2的下端有间隔,烟气进口131的上沿位于落料口22的下方保证烟气进口131完全位于落料口22的下方。由此,烟气从烟气进口131进入塔体1后,经过落料管3与落料口22之间的间隔进入填料段12中,在烟气进入调料段的路径更短更平顺,烟气流动时由于能量损失而引起的压降低,提高了烟气在填料段12流动的流畅程度,从而提高了吸附效果。Specifically, the geometric center of the blanking opening 22 in the horizontal direction is the same as the geometric center of the blanking tube 3 in the horizontal direction, the upper end of the blanking tube 3 is spaced from the lower end of the distributor 2, and the smoke inlet 131 The upper edge is located below the blanking opening 22 to ensure that the flue gas inlet 131 is completely below the blanking opening 22 . Thus, after the flue gas enters the tower body 1 from the flue gas inlet 131, it enters the packing section 12 through the space between the blanking pipe 3 and the blanking port 22. The path of the flue gas entering the seasoning section is shorter and smoother, and the smoke The pressure drop caused by energy loss when the gas flows improves the fluency of the flue gas flowing in the packing section 12, thereby improving the adsorption effect.
在其它一些实施例中,如图7所示,分布器2包括分布板21和多个分布管23,分布管23与分布板21的下端面相连并从分布板21向下延伸,分布管23为方管,多个分布管23与多个落料口22一一对应,多个落料管3与多个分布管23一一对应。In some other embodiments, as shown in FIG. 7 , the distributor 2 includes a distribution plate 21 and a plurality of distribution pipes 23, the distribution pipes 23 are connected to the lower end surface of the distribution plate 21 and extend downward from the distribution plate 21, and the distribution pipes 23 It is a square tube, and a plurality of distribution pipes 23 corresponds to a plurality of discharge openings 22 one by one, and a plurality of discharge pipes 3 corresponds to a plurality of distribution pipes 23 one to one.
具体地,如图8所示,分布管23的下端部伸入对应的落料管3的上端部内,分布管23与对应的落料管3之间具有间隔。由此,吸附剂在穿过分布管23落入落料管3时,能够完全落入落料管3中,避免吸附剂从落料出口24和落料管3之间的间隙溅出,从而避免吸附剂从烟气进口131流出塔体1。Specifically, as shown in FIG. 8 , the lower end of the distribution pipe 23 protrudes into the upper end of the corresponding drop pipe 3 , and there is an interval between the distribution pipe 23 and the corresponding drop pipe 3 . Thus, when the adsorbent passes through the distribution pipe 23 and falls into the discharge pipe 3, it can completely fall into the discharge pipe 3, preventing the adsorbent from splashing out from the gap between the discharge outlet 24 and the discharge pipe 3, thereby Prevent the adsorbent from flowing out of the tower body 1 from the flue gas inlet 131 .
在一些实施例中,落料管3的顶端与分布板21的下端面之间的缝隙在竖直方向上的尺寸为20mm-100m。具体地,落料管3与分布板21之间的缝隙在竖直方向上的尺寸可以为20mm至100mm之间的任意数值。在一些实施例中,落料管3与分布板21之间的缝隙在竖直方向上的尺寸为75mm,这样设置有利于提高烟气从落料管3与分布板21之间的缝隙通过时的流量。In some embodiments, the vertical dimension of the gap between the top end of the drop tube 3 and the lower end surface of the distribution plate 21 is 20mm-100m. Specifically, the vertical dimension of the gap between the drop tube 3 and the distribution plate 21 may be any value between 20 mm and 100 mm. In some embodiments, the vertical dimension of the gap between the drop tube 3 and the distribution plate 21 is 75mm, which is conducive to improving the flue gas passing through the gap between the drop tube 3 and the distribution plate 21. traffic.
在一些实施例中,移动床吸附塔还包括布料器4,布料器4设在塔体1内,布料器4包括若干布料入口和若干与布料入口对应的布料出口,布料器4位于加料口111的下方且位于填料段12的上方,以便将从加料口111进入的吸附剂分配到填料段12,烟气出口121位于布料入口的下方和布料出口的上方。In some embodiments, the moving bed adsorption tower also includes a distributor 4, the distributor 4 is arranged in the tower body 1, the distributor 4 includes several distribution inlets and several distribution outlets corresponding to the distribution inlets, and the distributor 4 is located at the feeding port 111 Below and above the packing section 12, in order to distribute the adsorbent entering from the feeding port 111 to the packing section 12, the flue gas outlet 121 is located below the cloth inlet and above the cloth outlet.
具体地,布料入口41和布料出口42一一对应,布料入口41在布料出口42的上方,布料入口41等间距水平排布,布料入口41和布料出口42的截面是圆形,布料入口41和布料出口42的之间形成通道供吸附剂颗粒穿过布料器4。由此,布料器4使吸附剂颗粒堆积在布料器4的上侧,并穿过布料入口41和布料出口42落入填料段12中,在吸附剂穿过 均匀排布的布料入口41和布料出口42时会均匀地落入填料段12中,吸附剂颗粒均匀的分布在填料段12中,使本移动床吸附塔吸附均匀、提高了吸附效果。另外,烟气出口121的上沿高度低于布料入口的高度,烟气出口121的下沿高度高于布料出口的高度,这样设置使烟气出口121在竖直方向上完全位于布料入口和布料出口之间,一方面防止吸附剂颗粒从烟气出口121溅出,另一方面使烟气吸附更加均匀。Specifically, the cloth inlet 41 corresponds to the cloth outlet 42 one by one, the cloth inlet 41 is above the cloth outlet 42, the cloth inlet 41 is arranged horizontally at equal intervals, the cross section of the cloth inlet 41 and the cloth outlet 42 is circular, and the cloth inlet 41 and Channels are formed between the distribution outlets 42 for the adsorbent particles to pass through the distributor 4 . Thus, the distributor 4 makes the adsorbent particles accumulate on the upper side of the distributor 4, and falls into the filler section 12 through the cloth inlet 41 and the cloth outlet 42, and when the adsorbent passes through the uniformly arranged cloth inlet 41 and the cloth outlet The outlet 42 will evenly fall into the packing section 12, and the adsorbent particles are evenly distributed in the packing section 12, so that the moving bed adsorption tower can absorb evenly and improve the adsorption effect. In addition, the height of the upper edge of the smoke outlet 121 is lower than the height of the cloth inlet, and the height of the lower edge of the smoke outlet 121 is higher than the height of the cloth outlet, so that the smoke outlet 121 is completely located between the cloth inlet and the cloth outlet in the vertical direction. Between the outlets, on the one hand, the adsorbent particles are prevented from splashing out from the flue gas outlet 121, and on the other hand, the flue gas adsorption is more uniform.
在一些实施例中,空腔还包括位于布料段11下方的出料段14,出料段14呈倒锥型,出料口141与出料段14的底部连通。In some embodiments, the cavity further includes a discharge section 14 located below the cloth section 11 , the discharge section 14 is in an inverted cone shape, and the discharge port 141 communicates with the bottom of the discharge section 14 .
具体地,空腔是指塔体1内部的空间,出料段14是倒四棱锥形,出料段14的顶部与进气段13连接,出料段14是中空结构,出料段14内部的空间与空腔相连,出料段14的截面积沿着从上向下的方向逐渐减小,出料口141设置在出料段14的下端。由此,吸附剂在完成对烟气中有害成分的吸附后,经过落料管3落入出料段14,并在出料段14中进行收集,在收集一定数量的吸附剂后,从出料口141排出,对回收的吸附剂进行下一步的处理,在出料口141封闭时,吸附剂中逸出的有害成分与烟气进口131中进入的烟气一起向上流动,不会挥散到大气中。Specifically, the cavity refers to the space inside the tower body 1, the discharge section 14 is an inverted quadrangular pyramid, the top of the discharge section 14 is connected with the inlet section 13, the discharge section 14 is a hollow structure, and the inside of the discharge section 14 The space is connected with the cavity, the cross-sectional area of the discharge section 14 gradually decreases along the direction from top to bottom, and the discharge port 141 is arranged at the lower end of the discharge section 14 . Thus, after the adsorbent completes the adsorption of harmful components in the flue gas, it falls into the discharge section 14 through the discharge pipe 3 and is collected in the discharge section 14. After a certain amount of adsorbent is collected, it is discharged from the discharge section 14 The material port 141 is discharged, and the recovered adsorbent is processed in the next step. When the material outlet 141 is closed, the harmful components escaping from the adsorbent flow upward together with the flue gas entering the flue gas inlet 131, and will not be volatilized. to the atmosphere.
根据本公开实施例的烟气净化系统,包括烟气冷却装置,烟气冷却装置具有进烟口和出烟口,烟气冷却装置用于将从进烟口进入的烟气冷却至室温及以下;移动床吸附塔,移动床吸附塔为根据上述任一实施例的移动床吸附塔,烟气冷却装置的出烟口与移动床吸附塔的烟气出口121连通,移动床吸附塔用于对烟气进行吸附。The flue gas purification system according to an embodiment of the present disclosure includes a flue gas cooling device, the flue gas cooling device has a smoke inlet and a smoke outlet, and the flue gas cooling device is used to cool the flue gas entering from the smoke inlet to room temperature or below Moving bed adsorption tower, the moving bed adsorption tower is the moving bed adsorption tower according to any one of the above-mentioned embodiments, the smoke outlet of the flue gas cooling device is communicated with the flue gas outlet 121 of the moving bed adsorption tower, and the moving bed adsorption tower is used for Smoke is adsorbed.
在一些实施例中,烟气进口131进入的烟气的温度为-100℃-室温(例如室温为25℃)。在一些实施例中,吸附剂为活性焦(碳)。In some embodiments, the temperature of the flue gas entering the flue gas inlet 131 is -100° C. to room temperature (for example, the room temperature is 25° C.). In some embodiments, the sorbent is activated coke (carbon).
本实施例提供的烟气净化系统在对烟气进行吸附时采用低温吸附的方式,利用烟气中污染物组分在低温下的溶解特性和吸附特性进行污染物的脱出,能够同时实现脱硫脱硝。其中,烟气中的二氧化硫以物理吸附为主,解析温度低,吸附剂损耗低,吸附剂补充量低,降低了运行成本。并且,在低温下进行吸附的烟气净化系统对污染物的吸附量大,吸附剂装填量少,移动床吸附塔等设备的占地面积小。The flue gas purification system provided in this example adopts the low-temperature adsorption method when adsorbing the flue gas, and utilizes the dissolution characteristics and adsorption characteristics of the pollutant components in the flue gas at low temperatures to remove pollutants, and can simultaneously realize desulfurization and denitrification . Among them, the sulfur dioxide in the flue gas is mainly physically adsorbed, the desorption temperature is low, the loss of the adsorbent is low, and the replenishment of the adsorbent is low, which reduces the operating cost. Moreover, the flue gas purification system that adsorbs at low temperature has a large adsorption capacity for pollutants, a small amount of adsorbent loading, and a small footprint for equipment such as moving bed adsorption towers.
需要说明的是,本实施例提供的烟气净化系统在对烟气进行吸附净化时,烟气中难以脱除的NO x组分用过低温氧化吸附机理,氧化成NO 2吸附脱除,不需要喷入NH 3进行催化还原,运行成本低。本实施例提供的烟气净化系统对烟气中NO x的吸附比例大于99%,脱硝效率明显优于现有技术中70~80%的脱硝效率。 It should be noted that when the flue gas purification system provided in this example performs adsorption and purification of the flue gas, the NO x components that are difficult to remove in the flue gas are oxidized to NO by adsorption and removal at a low temperature through the mechanism of oxidation adsorption. It needs to inject NH3 for catalytic reduction, and the operation cost is low. The flue gas purification system provided in this embodiment can absorb more than 99% of NOx in the flue gas, and the denitrification efficiency is obviously better than the 70-80% denitrification efficiency in the prior art.
在本公开的描述中,需要理解的是,术语“中心”、“纵向”、“横向”、“长度”、“宽度”、“厚度”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”“内”、“外”、“顺时针”、“逆时针”、“轴向”、“径向”、“周向”等指示的方位或位置关系为基于 附图所示的方位或位置关系,仅是为了便于描述本公开和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本公开的限制。In describing the present disclosure, it is to be understood that the terms "center", "longitudinal", "transverse", "length", "width", "thickness", "upper", "lower", "front", " Back", "Left", "Right", "Vertical", "Horizontal", "Top", "Bottom", "Inner", "Outer", "Clockwise", "Counterclockwise", "Axial", The orientations or positional relationships indicated by "radial", "circumferential", etc. are based on the orientations or positional relationships shown in the drawings, and are only for the convenience of describing the present disclosure and simplifying the description, rather than indicating or implying the referred devices or elements Must be in a particular orientation, constructed, and operate in a particular orientation, and thus should not be construed as limiting on the present disclosure.
此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括至少一个该特征。在本公开的描述中,“多个”的含义是至少两个,例如两个,三个等,除非另有明确具体的限定。In addition, the terms "first" and "second" are used for descriptive purposes only, and cannot be interpreted as indicating or implying relative importance or implicitly specifying the quantity of indicated technical features. Thus, the features defined as "first" and "second" may explicitly or implicitly include at least one of these features. In the description of the present disclosure, "plurality" means at least two, such as two, three, etc., unless otherwise specifically defined.
在本公开中,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”、“固定”等术语应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或成一体;可以是机械连接,也可以是电连接或彼此可通讯;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通或两个元件的相互作用关系,除非另有明确的限定。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本公开中的具体含义。In this disclosure, terms such as "installation", "connection", "connection" and "fixation" should be interpreted in a broad sense, for example, it can be a fixed connection or a detachable connection unless otherwise clearly defined and limited. , or integrated; can be mechanically connected, can also be electrically connected or can communicate with each other; can be directly connected, can also be indirectly connected through an intermediary, can be the internal communication of two components or the interaction relationship between two components, Unless expressly defined otherwise. Those of ordinary skill in the art can understand the specific meanings of the above terms in the present disclosure according to specific situations.
在本公开中,除非另有明确的规定和限定,第一特征在第二特征“上”或“下”可以是第一和第二特征直接接触,或第一和第二特征通过中间媒介间接接触。而且,第一特征在第二特征“之上”、“上方”和“上面”可是第一特征在第二特征正上方或斜上方,或仅仅表示第一特征水平高度高于第二特征。第一特征在第二特征“之下”、“下方”和“下面”可以是第一特征在第二特征正下方或斜下方,或仅仅表示第一特征水平高度小于第二特征。In the present disclosure, unless otherwise clearly stated and limited, a first feature being "on" or "under" a second feature may mean that the first and second features are in direct contact, or that the first and second features are indirect through an intermediary. touch. Moreover, "above", "above" and "above" the first feature on the second feature may mean that the first feature is directly above or obliquely above the second feature, or simply means that the first feature is higher in level than the second feature. "Below", "beneath" and "beneath" the first feature may mean that the first feature is directly below or obliquely below the second feature, or simply means that the first feature is less horizontally than the second feature.
在本公开中,术语“一个实施例”、“一些实施例”、“示例”、“具体示例”、或“一些示例”等意指结合该实施例或示例描述的具体特征、结构、材料或者特点包含于本公开的至少一个实施例或示例中。在本说明书中,对上述术语的示意性表述不必须针对的是相同的实施例或示例。而且,描述的具体特征、结构、材料或者特点可以在任一个或多个实施例或示例中以合适的方式结合。此外,在不相互矛盾的情况下,本领域的技术人员可以将本说明书中描述的不同实施例或示例以及不同实施例或示例的特征进行结合和组合。In this disclosure, the terms "one embodiment," "some embodiments," "example," "specific examples," or "some examples" mean a specific feature, structure, material, or feature described in connection with the embodiment or example. Features are included in at least one embodiment or example of the present disclosure. In this specification, the schematic representations of the above terms are not necessarily directed to the same embodiment or example. Furthermore, the described specific features, structures, materials or characteristics may be combined in any suitable manner in any one or more embodiments or examples. In addition, those skilled in the art can combine and combine different embodiments or examples and features of different embodiments or examples described in this specification without conflicting with each other.
尽管上面已经示出和描述了本公开的实施例,可以理解的是,上述实施例是示例性的,不能理解为对本公开的限制,本领域的普通技术人员在本公开的范围内可以对上述实施例进行变化、修改、替换和变型。Although the embodiments of the present disclosure have been shown and described above, it can be understood that the above embodiments are exemplary and should not be construed as limitations on the present disclosure, and those skilled in the art can understand the above-mentioned embodiments within the scope of the present disclosure. The embodiments are subject to changes, modifications, substitutions and variations.

Claims (10)

  1. 一种移动床吸附塔,其特征在于,包括:A moving bed adsorption tower is characterized in that it comprises:
    塔体,所述塔体内具有空腔,所述塔体设有与所述空腔连通的加料口、出料口、烟气进口和烟气出口,所述空腔在烟气的流通方向上具有进气段、填料段和布料段,所述填料段用于填充吸附剂;A tower body, the tower body has a cavity, the tower body is provided with a feeding port, a material outlet, a flue gas inlet and a flue gas outlet communicating with the cavity, and the cavity is in the flow direction of the flue gas It has an air inlet section, a packing section and a cloth section, and the packing section is used for filling the adsorbent;
    分布器,所述分布器设在所述塔体内,所述分布器设有若干间隔排布的落料口,所述分布器位于所述填料段的下方以便所述填料段中的吸附剂通过所述落料口流出,所述若干落料口包括第一部分和第二部分,所述第一部分中的落料口环绕所述第二部分中的落料口排布,所述第一部分中的落料口的平均截面积大于所述第二部分中的落料口的平均截面积。A distributor, the distributor is arranged in the tower body, the distributor is provided with a number of blanking openings arranged at intervals, the distributor is located below the packing section so that the adsorbent in the packing section can pass through The discharge port flows out, and the several discharge ports include a first part and a second part, the discharge ports in the first part are arranged around the discharge ports in the second part, and the discharge ports in the first part The average cross-sectional area of the feed openings is larger than the average cross-sectional area of the feed openings in the second portion.
  2. 根据权利要求1所述的移动床吸附塔,其特征在于,若干所述落料口的截面积从内向外依次增大。The moving bed adsorption tower according to claim 1, characterized in that, the cross-sectional areas of the several feeding openings increase sequentially from the inside to the outside.
  3. 根据权利要求1或2所述的移动床吸附塔,其特征在于,所述分布器包括分布板,所述落料口设在所述分布板上,所述分布板与所述空腔的周壁相连,所述烟气进口位于所述分布板的下方,所述分布板具有延竖直方向延伸的中心线,距离所述中心线越远,所述落料口的截面积越大。The moving bed adsorption tower according to claim 1 or 2, wherein the distributor comprises a distribution plate, the discharge opening is arranged on the distribution plate, and the distribution plate and the surrounding wall of the cavity Connected, the flue gas inlet is located below the distribution plate, the distribution plate has a centerline extending in the vertical direction, the farther away from the centerline, the larger the cross-sectional area of the discharge opening.
  4. 根据权利要求1至3中任一项所述的移动床吸附塔,其特征在于,若干所述落料口排列为多排,每排落料口包括若干所述落料口,每排落料口中的若干落料口沿第一方向间隔排布,多排落料口在第二方向上间隔排布,所述第一方向和所述第二方向相互垂直,相邻两排落料口在第二方向上对齐。According to the moving bed adsorption tower described in any one of claims 1 to 3, it is characterized in that several of the blanking ports are arranged in multiple rows, and each row of blanking ports includes a plurality of the blanking ports, and each row of blanking ports Several blanking openings in the mouth are arranged at intervals along the first direction, and multiple rows of blanking openings are arranged at intervals in the second direction, the first direction and the second direction are perpendicular to each other, and two adjacent rows of blanking openings are in the Align in the second direction.
  5. 根据权利要求1至4中任一项所述的移动床吸附塔,其特征在于,所述落料口的截面为圆形或方形。The moving bed adsorption tower according to any one of claims 1 to 4, characterized in that, the section of the discharge opening is circular or square.
  6. 根据权利要求4所述的移动床吸附塔,其特征在于,在所述第一方向上相邻的两个落料口之间的间隔为20mm-100mm,在所述第二方向上相邻的两个落料口之间的间隔为20mm-100mm。The moving bed adsorption tower according to claim 4, characterized in that, the interval between two adjacent blanking ports in the first direction is 20mm-100mm, and the interval between the adjacent two blanking ports in the second direction is The interval between the two feeding ports is 20mm-100mm.
  7. 根据权利要求3所述的移动床吸附塔,其特征在于,还包括多个落料管,多个所述落料管与多个所述落料口一一对应,所述落料管位于所述分布板的下方并与所述分布板之间具有间隔以便烟气流动,所述落料管位于所述出料口的上方。The moving bed adsorption tower according to claim 3, characterized in that it also includes a plurality of downpipes, a plurality of said downpipes correspond to a plurality of said downholes one by one, and said downpipes are located at said There is a gap between the distribution plate and the distribution plate for flue gas flow, and the discharge pipe is located above the discharge port.
  8. 根据权利要求7所述的移动床吸附塔,其特征在于,所述落料管的顶端与所述分布板的下端面之间的缝隙在竖直方向上的尺寸为20mm-100mm。The moving bed adsorption tower according to claim 7, characterized in that the vertical dimension of the gap between the top of the downcomer and the lower end surface of the distribution plate is 20mm-100mm.
  9. 根据权利要求1至8中任一项所述的移动床吸附塔,其特征在于,还包括布料器,所述布料器设在所述塔体内,所述布料器包括若干布料入口和若干与所述布料入口对应的 布料出口,所述布料器位于所述加料口的下方且位于所述填料段的上方,以便将从所述加料口进入的吸附剂分配到所述填料段,所述烟气出口位于所述布料入口的下方和所述布料出口的上方。According to the moving bed adsorption tower described in any one of claims 1 to 8, it is characterized in that it also includes a distributor, the distributor is arranged in the tower body, and the distributor includes several distribution inlets and several The cloth outlet corresponding to the cloth inlet, the distributor is located below the feeding port and above the packing section, so as to distribute the adsorbent entering from the feeding port to the packing section, and the flue gas An outlet is located below the cloth inlet and above the cloth outlet.
  10. 一种烟气净化系统,其特征在于,包括:A flue gas purification system is characterized in that it comprises:
    烟气冷却装置,所述烟气冷却装置具有进烟口和出烟口,所述烟气冷却装置用于将从所述进烟口进入的烟气冷却至室温及以下;A flue gas cooling device, the flue gas cooling device has a smoke inlet and a smoke outlet, and the flue gas cooling device is used to cool the flue gas entering from the smoke inlet to room temperature or below;
    移动床吸附塔,所述移动床吸附塔为根据权利要求1至9中任一项所述的移动床吸附塔,所述烟气冷却装置的出烟口与所述移动床吸附塔的所述烟气出口连通,所述移动床吸附塔用于对所述烟气进行吸附。A moving bed adsorption tower, the moving bed adsorption tower is the moving bed adsorption tower according to any one of claims 1 to 9, the smoke outlet of the flue gas cooling device is connected to the moving bed adsorption tower of the moving bed adsorption tower The flue gas outlet is connected, and the moving bed adsorption tower is used to adsorb the flue gas.
PCT/CN2022/078430 2021-09-02 2022-02-28 Moving bed adsorption tower and flue gas purification system having same WO2023029411A1 (en)

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CN202122240687.4U CN216149387U (en) 2021-09-02 2021-09-15 Moving bed adsorption tower and flue gas purification system with same
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