WO2023024580A1 - Battery monitoring apparatus and battery apparatus - Google Patents

Battery monitoring apparatus and battery apparatus Download PDF

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Publication number
WO2023024580A1
WO2023024580A1 PCT/CN2022/092226 CN2022092226W WO2023024580A1 WO 2023024580 A1 WO2023024580 A1 WO 2023024580A1 CN 2022092226 W CN2022092226 W CN 2022092226W WO 2023024580 A1 WO2023024580 A1 WO 2023024580A1
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WO
WIPO (PCT)
Prior art keywords
battery
monitoring device
processing circuit
port
battery monitoring
Prior art date
Application number
PCT/CN2022/092226
Other languages
French (fr)
Chinese (zh)
Inventor
余爱水
艾超
曹华俊
汤剑涛
Original Assignee
华为技术有限公司
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Publication of WO2023024580A1 publication Critical patent/WO2023024580A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/46Accumulators structurally combined with charging apparatus
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/48Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Definitions

  • the present application relates to the technical field of batteries, in particular to a battery monitoring device and a battery device.
  • lithium-ion battery technology lithium-ion batteries have been widely used in fields such as electric vehicles and electronic products.
  • Lithium-ion batteries are prone to failure due to overheating, over-discharge, over-charging or short-circuit, and the chemical energy of lithium-ion batteries can be quickly converted into thermal energy, which can easily lead to heat accumulation inside the lithium-ion battery, causing thermal runaway, which will eventually lead to Hazardous situations such as fire and explosion occur.
  • thermal runaway of the power battery pack of an electric vehicle are very serious, and often lead to safety accidents such as car crashes and fatalities. Therefore, it is of great significance to monitor the battery status in real time.
  • the present application provides a battery monitoring device and a battery device, which can conveniently realize real-time monitoring of the battery state under the condition of limited influence on the discharge capacity and capacity retention rate of the battery.
  • the embodiment of the present application provides a battery monitoring device, which is used to monitor the state of the cells in the battery device, and the battery monitoring device includes a plurality of sensors, a processor and a processing circuit; the plurality of sensors are used for Sensing various parameters of the electric core; the processor is electrically connected to the multiple sensors, and is used to receive the various parameters, so as to determine the state information of the electric core according to the various parameters; the The processing circuit is electrically connected to the processor, and the processing circuit includes a first processing circuit and a second processing circuit, and both the first processing circuit and the second processing circuit are used to report the status information of the battery cell to an external device.
  • the real-time monitoring of the battery state can be effectively realized under the condition of limited influence on the electrochemical performance of the battery, and the problems existing in the battery cell can be accurately warned.
  • the technical solution of the embodiment of the present application increases the safety and reliability of the battery, and can quickly give feedback and give an alarm before the battery becomes abnormal, so as to protect the life safety of the user.
  • the first processing line is led out from a first lead-out port on the battery device, and the second processing line is led out together with the negative port of the battery device. Based on such a design, the first processing circuit and the second processing circuit can report the status information of the battery cell to an external device.
  • both the first processing line and the second processing line are led out from a coaxial connector on the battery device. Based on such a design, the first processing circuit and the second processing circuit can report the status information of the battery cell to an external device.
  • the first processing circuit is derived from a second outlet port on the battery device, and the second processing circuit is derived from a third outlet port on the battery device. Based on such a design, the first processing circuit and the second processing circuit can report the status information of the battery cell to an external device.
  • the multiple sensors include at least one of a temperature sensor, a pressure sensor, a voltage sensor, a current sensor, a pressure sensor, or a gas sensor.
  • an embodiment of the present application provides a battery device, which includes a plurality of battery cells, a casing, and the battery monitoring device as described above, wherein the battery cells and the battery monitoring device accommodate within the housing.
  • the embodiment of the present application by embedding the battery monitoring device inside the battery device, it is possible to sensitively monitor parameters such as temperature, stress and air pressure inside the battery with limited influence on the discharge capacity and capacity retention rate of the battery, and to Quickly output these signals to external devices, so that real-time monitoring of the battery status can be realized, and the batteries with problems can be accurately notified.
  • the technical solution of the embodiment of the present application increases the safety and reliability of the battery, and can quickly feedback and give an alarm when the battery is abnormal, so as to protect the life safety of the user.
  • the battery cell includes a plurality of sequentially stacked negative pole pieces, separators and positive pole pieces, and the battery monitoring device is arranged on the last negative pole piece of the battery cell.
  • the battery monitoring device is arranged between two battery cells. Based on such a design, the battery monitoring device can monitor the state of the battery cells.
  • the battery monitoring device is arranged between the battery cell and the housing. Based on such a design, the battery monitoring device can monitor the state of the battery cells.
  • the housing includes a cover plate, and a positive port, a negative port, and a safety valve are arranged on the cover plate, and the safety valve is located between the positive port and the negative port, the The safety valve is used to discharge the gas in the battery device.
  • the cover plate is also provided with a first lead-out port, the first processing line of the battery monitoring device is led out from a first lead-out port on the battery device, and the second line processing line Lead out together with the negative terminal of the battery unit. Based on such a design, the first processing circuit and the second processing circuit can report the status information of the battery cell to an external device.
  • a coaxial connector is further provided on the cover, and both the first processing circuit and the second processing circuit of the battery monitoring device are led out from the coaxial connector.
  • the cover plate is further provided with a second outlet port and a third outlet port, the first processing circuit is led out from the second outlet port, and the second processing circuit is exported from the The third lead-out port is exported. Based on such a design, the first processing circuit and the second processing circuit can report the status information of the battery cell to an external device.
  • the battery monitoring device and battery device in the embodiment of the present application by embedding the battery monitoring device inside the battery device, it is possible to sensitively monitor the temperature, stress and air pressure inside the battery with limited influence on the electrochemical performance of the battery parameters, and can quickly output these signals to external devices, so that real-time monitoring of the state of the battery can be realized, and the problem of the battery can be accurately warned.
  • the technical solution of the embodiment of the present application increases the safety and reliability of the battery, and can quickly give feedback and give an alarm before the battery becomes abnormal, so as to protect the life safety of the user.
  • FIG. 1 is a schematic diagram of a battery device according to an embodiment of the present application.
  • FIG. 2 is another schematic diagram of the battery device of the embodiment of the present application.
  • Fig. 3 is a diagram of a specific application scenario of the battery device according to the embodiment of the present application.
  • Fig. 4 is another specific application scenario diagram of the battery device according to the embodiment of the present application.
  • FIG. 5 is a schematic structural diagram of a battery monitoring device according to an embodiment of the present application.
  • Fig. 6 is a diagram of a specific application scenario of the battery monitoring device according to the embodiment of the present application.
  • FIG. 7 is another specific application scenario diagram of the battery monitoring device according to the embodiment of the present application.
  • FIG. 8 is another specific application scenario diagram of the battery monitoring device according to the embodiment of the present application.
  • FIG. 9 is another specific application scenario diagram of the battery monitoring device according to the embodiment of the present application.
  • Fig. 10 is a schematic diagram of the line output of the battery monitoring device according to the embodiment of the present application.
  • Fig. 11 is another schematic diagram of the line output of the battery monitoring device according to the embodiment of the present application.
  • Fig. 12 is another schematic diagram of the line output of the battery monitoring device according to the embodiment of the present application.
  • FIG. 13 is another schematic diagram of the line output of the battery monitoring device according to the embodiment of the present application.
  • Fig. 14 is another schematic diagram of the line output of the battery monitoring device according to the embodiment of the present application.
  • Fig. 15 is another schematic diagram of the line output of the battery monitoring device according to the embodiment of the present application.
  • Fig. 16 is a schematic diagram of the placement of the battery monitoring device and the welding of tabs according to the embodiment of the present application.
  • Fig. 17 is a schematic diagram of welding of tabs and connecting pieces of the battery device according to the embodiment of the present application.
  • FIG. 18 is a schematic diagram of welding the pole connecting piece and the pole of the battery device according to the embodiment of the present application.
  • Fig. 19 is a schematic diagram of welding the pole assembly into the case and the cover plate and the case according to the embodiment of the present application.
  • FIG. 20 is a schematic diagram of the line output and the cover plate of the battery device according to the embodiment of the present application.
  • FIG. 21 is another schematic diagram of the line output and the cover plate of the battery device according to the embodiment of the present application.
  • FIG. 22 is another schematic diagram of the line output and the cover plate of the battery device according to the embodiment of the present application.
  • Thermal runaway can refer to an overheating phenomenon in which the temperature of the battery rises sharply due to a series of exothermic chain reactions inside the battery, and the temperature is no longer controllable, which can lead to dangerous situations such as fire, explosion, and combustion of the battery. Therefore, how to accurately and effectively predict thermal runaway before the battery pack catches fire will be of great significance to ensure the safety of the battery.
  • a Bragg optical fiber temperature sensor can be embedded between the diaphragm and the diaphragm inside the pouch battery to monitor the change of the internal temperature of the battery, and the pouch battery
  • a Bragg fiber optic temperature sensor is attached to the outer surface of the pouch battery. It can be understood that the Bragg fiber optic temperature sensor can monitor the temperature inside and outside the pouch battery.
  • the various performances of the battery will drop sharply, such as the discharge capacity and cycle stability of the battery will all decrease.
  • the internal state of the battery cannot be understood and mastered, and the internal state of the battery cannot be effectively monitored and monitored. manage.
  • the lithium-ion battery can include 8 pieces of graphite anode with a capacity of 330mAh/g, 7 pieces of nickel-manganese-cobalt (NMC) with a capacity of 150mAh/g, and lithium hexafluorophosphate (LiPF 6 ). electrolyte, the battery capacity thus assembled was 5Ah.
  • Eight distributed Bragg optical fiber temperature sensors can be bonded to the surface of the pouch battery with epoxy glue, and the eight sensors can be further bonded with insulating tape, so that the device can monitor the temperature change on the outer surface of the pouch battery.
  • the aluminum-plastic film of the outer packaging has a heat insulation effect, that is, the Bragg optical fiber temperature sensor cannot monitor the temperature change inside the battery in time. Therefore, the above implementation method cannot accurately monitor the safety of the battery and is not practical. high.
  • the anode material, binder, and conductive agent can be mixed and coated on the copper foil anode current collector, and then the Bragg fiber optic temperature sensor (placed in a custom-made tube) is embedded in the slurry, and dry the pole pieces in a vacuum oven. After the pole piece is dried, the Bragg fiber optic temperature sensor can be fixed on the pole piece, and the signal of the Bragg fiber optic temperature sensor is output through the fiber optic line, and the fiber optic line is led out from the middle of the tail of the pouch battery.
  • a layer of polyimide polymer can be coated on its surface.
  • the above-mentioned implementation method can monitor the temperature change inside the battery in time, but the position where the sensor is embedded will reduce the capacity of the battery and also reduce the cycle performance of the battery. In addition, there will be certain challenges to the packaging technology of pouch batteries. If the packaging technology is not good, it will easily lead to the leakage of battery electrolyte.
  • the embodiments of the present application provide a battery monitoring device and a battery device.
  • the sensor can be integrated into the battery, and the battery can be monitored under the condition of limited influence on the discharge capacity and capacity retention rate of the battery. Real-time monitoring of core status, and can quickly output the sensed signal.
  • the battery may include one or more cells, and multiple cells will be used as an example for introduction later.
  • FIG. 1 is a schematic diagram of a battery device 100 provided by an embodiment of the present application.
  • the battery device 100 can be electrically connected to an external device 200 .
  • the battery device 100 may provide power for the external device 200 .
  • the battery device 100 may also output battery status information to the external device 200 .
  • the battery device 100 in this embodiment may include a battery monitoring device 10 and a battery cell 20 .
  • the battery monitoring device 10 in this embodiment can monitor the status of the battery cell 20 and report the monitored status of the battery cell 20 to the external device 200 .
  • the battery monitoring device 10 may transmit the health status or thermal runaway status of the battery device 100 to the external device 200 .
  • the battery monitoring device 10 may report the thermal runaway information of the battery device 100 to the external device 200, and the external device 200 may send an alarm message , to remind the user to deal with it in time.
  • the battery monitoring device 10 may report the health state information of the battery device 100 to the external device 200, and the external device 200 may issue a prompt Information, that is, the battery device 100 is in a safe state at this time.
  • the battery device 100 can be applied to mobile terminals, notebook computers, electric vehicles, energy storage systems, underwater battery drive devices, etc., which is not limited in this application.
  • FIG. 2 is a schematic structural diagram of a battery device 100 according to an embodiment of the present application.
  • the battery device 100 may be a prismatic battery.
  • the battery device 100 may further include a casing 30 , and both the battery monitoring device 10 and the battery cell 20 may be accommodated in the casing 30 .
  • the casing 30 may include a cover plate 31 on which a positive port 311 , a negative port 312 , a safety valve 313 , a liquid injection hole 314 and an outlet port 315 may be disposed.
  • the safety valve 313 in this embodiment can discharge the gas in the battery device 100 .
  • the liquid injection hole 314 can be used for injecting electrolyte solution into the battery device 100 .
  • the outgoing port 315 can be used to connect the line of the battery monitoring device 10 with the external device 200 .
  • the positive terminal 311 can be used to electrically connect the positive tab of the battery 20
  • the negative terminal 312 can be used to electrically connect the negative tab of the battery 20 .
  • the battery device 100 is applied to a notebook computer 300 as an example for description.
  • the battery device 100 may be disposed inside the notebook computer 300. It can be understood that the battery device 100 can be used to provide power for the notebook computer 300, and the battery monitoring device 10 can also report the state information of the monitored batteries to the notebook computer 300, so as to provide power for the battery device 300. When the thermal runaway of the battery device 100 occurs, the user can be reminded to deal with it in time, and a prompt message can also be sent to the user when the battery device 100 is in a healthy state.
  • the battery monitoring device 10 may transmit thermal runaway information to the notebook computer 300, the display screen of the notebook computer 300 may display an alarm message, and the notebook computer The loudspeaker of 300 can emit an alarm sound to inform the user that the battery device 100 is in a state of thermal runaway at this time, and the situation needs to be dealt with in time.
  • the battery monitoring device 10 can transmit the health status information to the notebook computer 300, and the display screen of the notebook computer 300 can display the battery safety information to inform the user of the current state of the battery.
  • the device 100 is in a safe state.
  • the battery device 100 is applied to an electric vehicle 400 as an example for description.
  • the battery device 100 may be disposed inside the electric vehicle 400 .
  • the battery device 100 can be a vehicle battery pack, that is, the battery device 100 can be used to provide power for the electric vehicle 400, and the battery monitoring device 10 can report the monitored battery status information to the electric vehicle 400 , so that when thermal runaway occurs in the battery device 100, the vehicle-mounted display screen of the electric vehicle 400 displays warning information to remind the user to deal with it in time, and the vehicle-mounted display screen of the electric vehicle 400 can also , to display the health status of the battery device 100 .
  • the battery monitoring device 10 provided in the embodiment of the present application will be described below with reference to the accompanying drawings and actual application scenarios.
  • FIG. 5 is a schematic structural diagram of a battery monitoring device 10 provided by an embodiment of the present application.
  • the battery monitoring device 10 may include multiple sensors and a processor 40 .
  • the plurality of sensors may include a temperature sensor 12, a pressure sensor 13, a voltage sensor 14, a current sensor 15, and an air pressure sensor 16, a gas sensor (not shown in the figure), and other types of sensors. It can be understood that the aforementioned sensors can all be used to sense parameters of the battery cell 20 .
  • the processor 40 in this embodiment may include a data interface 41 , a control unit 42 , a communication processing unit 44 , a data processing unit 45 and an action execution unit 46 .
  • the processor 40 can communicate with the above-mentioned sensors, and can receive the parameters of the battery cell 20 sensed by multiple sensors, and the processor 40 can determine the parameters based on the various parameters sensed by the multiple sensors. Describe the state of the battery cell 20.
  • the data interface 41 can be electrically connected to the plurality of sensors, that is, the data interface 41 can be electrically connected to the temperature sensor 12, the pressure sensor 13, the voltage sensor 14, the current sensor 15, the air pressure sensor 16, the gas sensor and other types of sensors .
  • the data interface 41 can convert the transmission signals between multiple sensors and the control unit 42, and the data interface 41 can also be used to complete receiving and sending between the multiple sensors and the control unit 42, etc. transfer function, etc.
  • control unit 42 may be the main control module of the processor 40, and the control unit 42 may be electrically connected to the temperature sensor 12, the pressure sensor 13, the air pressure sensor 16, and the gas sensor. and other types of sensors.
  • control unit 42 can control the temperature sensor 12 to collect the temperature signal of the battery cell 20, the control unit 42 can also control the pressure sensor 13 to collect the pressure signal of the battery cell 20, the control The unit 42 can also control the air pressure sensor 16 (such as a gas sensor) to collect the air pressure parameters of the battery cell 20 .
  • the control unit 42 can simulate the temperature signal and the pressure signal through the data interface 41 digital conversion, so as to transmit the converted digital signal to the data processing unit 45.
  • the control unit 42 can also be electrically connected to the voltage sensor 14 and the current sensor 15 .
  • the control unit 42 can also control the voltage sensor 14 to collect the voltage value of the battery cell 20
  • the control unit 42 can also control the current sensor 15 to collect the current value of the battery cell 20 .
  • the control unit 42 can also carry out the voltage signal and the current signal through the data interface 41 Analog-to-digital conversion, so as to transmit the converted digital signal to the data processing unit 45 .
  • the data processing unit 45 may be used to process and analyze the parameters of the multiple sensors. In this manner, the data processing unit 45 can perform analysis and processing based on the relevant parameters collected by the above-mentioned multiple sensors, thereby further determining the state of the battery cell 20 .
  • the communication processing unit 44 can be electrically connected to the external device 200 . Thus, after the data processing unit 45 determines the state of the battery cell 20 , it can send it to the external device 200 through the communication processing unit 44 , and then feed it back to the external device 200 (such as an on-board chip). It can be understood that, in a possible implementation manner, the communication processing unit 44 may transmit information to the external device 200 in a manner of wired communication or wireless communication.
  • the data processing unit 45 may include a micro control unit (Micro Control Unit, MCU) core, wherein the MCU core may be used for data processing.
  • MCU Micro Control Unit
  • the data processing unit 45 can also be used to optimize the control algorithm.
  • the processor 40 in this embodiment can also include a clock unit and a power supply unit. Wherein, the clock unit may be used to control the clock of the processor 40 .
  • the power supply unit can be used to provide power and power management for various units in the processor 40 .
  • the action execution unit 46 may be electrically connected to the control unit 42 , and the action execution unit 46 may be configured to execute control instructions from the control unit 42 . It can be understood that, in some possible designs, the action execution unit 46 can be a protection device for the battery device 100, and the action execution unit 46 can be used to cut off the battery output, cut off the battery input (such as overshoot protection), Temperature rise protection, low temperature protection and overload protection, etc.
  • the temperature sensor 12 , pressure sensor 13 , air pressure sensor 16 , gas sensor and other types of sensors can all be arranged on different surfaces of the battery cell 20 .
  • the embodiment of the present application can design a multi-channel parameter acquisition scheme, and after the analysis and processing by the data processing unit 45, the calculation result can be sent to the on-board chip through the communication processing unit 44. Therefore, the embodiment of the present application can realize high-speed and real-time transmission of signals, and can integrate multiple sensors into the battery monitoring device. In addition, it can also be displayed in real time on the large screen of the vehicle, and an alarm prompt can be issued in case of danger, so as to realize real-time monitoring of the battery status.
  • FIG. 6 is a diagram of a specific application scenario of the battery monitoring device 10 according to an embodiment of the present application.
  • the cell 20 may include a negative pole piece 201 , a separator 202 or a solid electrolyte and a positive pole piece 203 stacked in sequence.
  • the battery monitoring device 10 can be embedded in the battery cell 20, and in a specific implementation process, the battery monitoring device 10 can be embedded in the last of the battery cell 20 On a piece of negative electrode sheet 201 (for example, on the current collector side). Based on such a design, the battery monitoring device 10 can monitor the state of the battery cell 20, for example, the battery monitoring device 10 can obtain various parameters of the battery cell 20, and the battery monitoring device 10 can also be based on A variety of parameters are obtained to determine the state of the battery cell 20 . Among them, various parameters may include the temperature, pressure and air pressure, voltage and current of the battery core.
  • the state of the battery cell 20 may affect the working state of the entire battery device 100 .
  • one of the battery cells 20 has thermal runaway or is about to experience thermal runaway. If it cannot be detected and controlled in time, thermal diffusion may occur in the battery cell 20, causing the entire battery device 100 to burn or even explode. .
  • a corresponding battery monitoring device 10 can be configured on the last negative electrode sheet 201 of each battery cell 20, so that thermal runaway can occur or will occur in one or more battery cells 20.
  • the battery device 100 burns and explodes, it can be detected and controlled in time to avoid dangerous situations such as combustion and explosion of the battery device 100.
  • the battery monitoring device 10 can send the monitored status information of the battery cell 20 to the external device 200 .
  • the external device 200 can obtain thermal runaway information or health status information for one or more battery cells, so as to give an early warning for the one or more battery cells 20 .
  • FIG. 7 is another specific application scenario diagram of the battery monitoring device 10 according to the embodiment of the present application.
  • the battery device 100 may include a plurality of battery cells 20 .
  • the battery monitoring device 10 can be disposed between two battery cells 20 .
  • the battery monitoring device 10 can monitor the parameters of the battery cell 20 and determine the state of the battery cell 20 according to the monitored parameters.
  • the battery device 100 is described by taking five battery cells 20 as an example. In other scenarios, the number of battery cells 20 can be adjusted according to actual conditions.
  • a battery monitoring device 10 may be provided between the first battery cell 20 and the second battery cell 20, and no battery monitoring device 10 is provided between the second battery cell 20 and the third battery cell 20.
  • the battery monitoring device 10 is not provided between the three battery cells 20 and the fourth battery cell 20 , and the battery monitoring device 10 is provided between the fourth battery cell 20 and the fifth battery cell 20 . It can be understood that the placement of the battery monitoring device 10 in the above scenario is only an example.
  • FIG. 9 is another specific application scenario diagram of the battery monitoring device 10 according to the embodiment of the present application.
  • the battery monitoring device 10 may be disposed between the battery cell 20 and the casing 30 . Based on the various placement positions of the battery monitoring device 10 described above, the battery monitoring device 10 can conveniently realize real-time monitoring of the state of the battery device 100 under the condition of limited influence on the electrochemical performance of the battery.
  • FIG. 10 is a schematic structural diagram of the line output of the battery monitoring device 10 provided by an embodiment of the present application.
  • the battery monitoring device 10 may include processing circuitry, wherein the processing circuitry may be electrically connected to the processor 40 .
  • the processing circuit may include a first processing circuit 417 and a second processing circuit 418 .
  • the first processing circuit 417 and the second processing circuit 418 may be electrically connected to the processor 40, for obtaining the status information of the battery device 100 from the processor 40, and converting the obtained The status information is reported to the external device 200 .
  • first processing circuit 417 and the second processing circuit 418 may be electrically connected to the external device 200 .
  • the external device 200 can further know the state of the battery device 100 according to the received state information of the battery device 100 .
  • the external device 200 may include an external communication unit 210 , an external control unit 220 and an application unit 230 .
  • the external communication unit 210 can be electrically connected to the battery monitoring device 10 to obtain status information of the battery device 100 from the battery monitoring device 10 .
  • the external control unit 220 can perform two-way communication with the external communication unit 210, specifically, the external control unit 220 can analyze the acquired state information of the battery device 100, and can determine that the battery cell 20 Whether the temperature, pressure, current, voltage or air pressure, gas, etc. are abnormal.
  • the external control unit 220 can also be used to output control instructions to the battery monitoring device 10 after analyzing and determining the state information.
  • the application unit 230 can be used to output warning information, for example, the application unit 230 can be a central control display screen.
  • the first processing circuit 417 can be led out from an outlet port 315 on the cover plate 31 .
  • the first processing circuit 417 can be led out from the outlet port 315 on the cover plate 31 .
  • the second processing circuit 418 can be exported together with the negative port 312 on the cover plate 31 , that is, the first processing circuit 417 of the battery monitoring device 10 can share an output port with the negative port of the battery device 100 .
  • the outlet port 315 may be located between the positive port 311 of the battery device 100 and the safety valve 313 .
  • FIG. 12 is a schematic structural diagram of the line output of the battery monitoring device 10 provided by another embodiment of the present application.
  • both the first processing circuit 417 and the second processing circuit 418 can be derived from the same coaxial connector 316, thus It can be electrically connected with the external device 200 .
  • the coaxial joint 316 may be disposed between the positive port 311 of the battery device 100 and the safety valve 313 .
  • FIG. 14 is a schematic structural diagram of the line output of the battery monitoring device 10 provided by another embodiment of the present application.
  • the difference from FIG. 10 and FIG. 11 is that, in this embodiment, as shown in FIG. 14 , the first processing circuit 417 and the second processing circuit 418 can be connected from Exported at the ports in between.
  • the cover plate 31 is also provided with an outlet port 317 and an outlet port 318, and the first processing circuit 417 and the second processing circuit 418 can be are exported from the outgoing port 317 and the outgoing port 318 respectively.
  • the outlet port 317 and the outlet port 318 may be located between the anode port 311 and the safety valve 313 . It can be understood that, in some possible implementation manners, both the outgoing port 317 and the outgoing port 318 may be BMA connectors.
  • the temperature inside the battery can be sensitively monitored with limited influence on the electrochemical performance of the battery , stress and air pressure and other parameters, and can quickly output these signals to external devices.
  • the battery monitoring device including multiple sensors and processors
  • the battery device still has good airtightness. Therefore, the interior of the battery device in the embodiment of the present application has characteristics of state measurability, safety and controllability.
  • the following further introduces the manufacturing method of the battery device 100 according to the embodiment of the present application.
  • the battery monitoring device 10 (comprising a plurality of sensors and processors) is placed on the last negative electrode sheet 201 of the negative electrode of the battery cell 20, and the first processing circuit of the battery monitoring device 10 417 and the second processing circuit 418 lead out the lines. Since the battery device 100 has a large number of pole pieces, it is necessary to pre-weld the positive pole tab 211 and the negative pole tab 212 . As shown in FIG. 17 , the positive tab 211 of the battery device 100 is welded to the positive connecting piece 213, and the negative tab 212 is welded to the negative connecting piece 214, wherein the material of the positive connecting piece 213 can be aluminum.
  • the material of the negative electrode connecting sheet 214 may be nickel-plated copper.
  • the positive pole tab 211 and the negative pole tab 212 are then welded to the positive pole pole 321 and the negative pole pole 322 on the cover plate 31 of the battery device 100 .
  • the pole group 50 (including the battery cell and the battery monitoring device) is put into the casing 30 and welded with the cover plate 31 . Then inject the electrolyte from the liquid injection hole 314, form and extract gas, and seal the liquid injection hole (that is, weld the liquid injection hole 314).
  • the embodiment shown in FIG. 7 that is, the battery monitoring device is embedded between the cells
  • the embodiment shown in FIG. 9 that is, the battery monitoring device is embedded between the casing and the cells
  • the manufacturing method of the device can be the same as the above-mentioned manufacturing method, and will not be repeated here.
  • the first line lead-out solution is: as shown in FIG. 20 , the second processing line 418 of the battery monitoring device 10 can be lead out from the negative port 312 of the battery device 100 (leading position 1), and the battery monitor
  • the first processing circuit 417 of the device 10 can be led out from a place located between the positive connecting piece 213 and the negative connecting piece 214 (ie leading out position 2). Then, it can be exported again from the corresponding position.
  • the first processing line 417 can be led out from the outlet port 315
  • the second processing line 418 can be led out together with the negative port 312 of the battery device 100 .
  • the negative terminal 312 of the cover plate 31 may be a perforated port.
  • the design of the negative terminal 312 has a welding position and a hole for the negative tab of the battery core, so that the processor line can be drawn out, and the hole can be provided with a layer of insulating sleeve to prevent the line from contacting.
  • the second line drawing scheme is: as shown in FIG. 21 , the first processing line 417 and the second processing line 418 of the battery monitoring device 10 can be drawn out from the place between the positive connecting piece 213 and the negative connecting piece 214 (that is, lead out position 2). Then, it can be exported again from the corresponding position. For example, the first processing line 417 and the second processing line 418 of the battery monitoring device 10 can be led out from the coaxial connector 316 .
  • the third line drawing scheme is: as shown in FIG. 22 , the first processing line 417 and the second processing line of the battery monitoring device 10 can be drawn out from between the positive connecting piece 213 and the negative connecting piece 214 (that is, the leading out position 2 locations). Then, it can be exported again from the corresponding position.
  • the first processing circuit 417 and the second processing circuit 418 of the battery monitoring device 10 are respectively derived from the outgoing port 317 and the outgoing port 318 .
  • the battery monitoring device and the battery device in the embodiment of the present application by embedding the battery monitoring device (including multiple sensors and processors) inside the battery device, it is possible to sensitively monitor the battery with limited influence on the electrochemical performance of the battery. Internal parameters such as temperature, stress, and air pressure can quickly output these signals to external devices, so that real-time monitoring of the state of the battery can be realized, and real-time warnings of problems with the battery can be realized.
  • the technical solution of the embodiment of the present application increases the safety and reliability of the battery, and can quickly feedback and give an alarm when the battery is abnormal, so as to protect the life safety of the user.

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Abstract

A battery monitoring apparatus and a battery apparatus. The battery apparatus comprises a plurality of cells, a housing, and a battery monitoring apparatus. The cells and the battery monitoring apparatus are both accommodated within the housing. The battery monitoring apparatus is used to monitor the state of the cells. The battery monitoring apparatus comprises a plurality of sensors and a processor. The plurality of sensors are used to sense a plurality of parameters of the cells, and the processor is used to determine state information of the cells according to the plurality of parameters and to report the state information to an external apparatus by means of a first processing line and a second processing line. By integrating the plurality of sensors into the battery apparatus, the real-time monitoring of battery state is effectively implemented under limited impact on the electrochemical performance of a battery.

Description

电池监测装置及电池装置Battery monitoring device and battery device
相关申请的交叉引用Cross References to Related Applications
本申请要求于2021年8月27日提交中国专利局、申请号为202110998017.0、申请名称为“电池监测装置及电池装置”的中国专利的优先权,其全部内容通过引用结合在本申请中。This application claims the priority of a Chinese patent with application number 202110998017.0 and application title "Battery Monitoring Device and Battery Device" filed with the China Patent Office on August 27, 2021, the entire contents of which are incorporated herein by reference.
技术领域technical field
本申请涉及电池技术领域,尤其涉及一种电池监测装置及电池装置。The present application relates to the technical field of batteries, in particular to a battery monitoring device and a battery device.
背景技术Background technique
随着锂离子电池技术的发展,锂离子电池已被广泛应用于电动汽车和电子产品等领域。With the development of lithium-ion battery technology, lithium-ion batteries have been widely used in fields such as electric vehicles and electronic products.
锂离子电池容易过热、过度放电、过度充电或短路而失效,并且锂离子电池的化学能可以迅速转化为热能,由此容易导致锂离子电池内部的热量积聚,从而引起热失控,最终将会导致火灾和爆炸等危险情况发生。例如,电动汽车的动力电池组发生热失控所造成的后果十分严重,往往会导致车毁人亡的安全事故,因此对电池状态进行实时监控具有重要的意义。Lithium-ion batteries are prone to failure due to overheating, over-discharge, over-charging or short-circuit, and the chemical energy of lithium-ion batteries can be quickly converted into thermal energy, which can easily lead to heat accumulation inside the lithium-ion battery, causing thermal runaway, which will eventually lead to Hazardous situations such as fire and explosion occur. For example, the consequences of thermal runaway of the power battery pack of an electric vehicle are very serious, and often lead to safety accidents such as car crashes and fatalities. Therefore, it is of great significance to monitor the battery status in real time.
发明内容Contents of the invention
本申请提供一种电池监测装置以及电池装置,在有限影响电池的放电容量和容量保持率的情况下,可以方便地实现对电池状态的实时监控。The present application provides a battery monitoring device and a battery device, which can conveniently realize real-time monitoring of the battery state under the condition of limited influence on the discharge capacity and capacity retention rate of the battery.
第一方面,本申请的实施例提供一种电池监测装置,用于监测电池装置中电芯的状态,所述电池监测装置包括多个传感器、处理器以及处理线路;所述多个传感器用于感测所述电芯的多种参数;所述处理器电连接所述多个传感器,并用于接收所述多种参数,以根据所述多种参数确定所述电芯的状态信息;所述处理线路电连接于所述处理器,所述处理线路包括第一处理线路和第二处理线路,所述第一处理线路和所述第二处理线路均用于将所述电芯的状态信息上报给外部装置。In the first aspect, the embodiment of the present application provides a battery monitoring device, which is used to monitor the state of the cells in the battery device, and the battery monitoring device includes a plurality of sensors, a processor and a processing circuit; the plurality of sensors are used for Sensing various parameters of the electric core; the processor is electrically connected to the multiple sensors, and is used to receive the various parameters, so as to determine the state information of the electric core according to the various parameters; the The processing circuit is electrically connected to the processor, and the processing circuit includes a first processing circuit and a second processing circuit, and both the first processing circuit and the second processing circuit are used to report the status information of the battery cell to an external device.
采用本申请的实施例,在有限影响电池的电化学性能的情况下,可以有效地实现对电池状态的实时监控,准确预警电芯存在的问题。本申请实施例的技术方案增加了电池的安全性和可靠性,可以在电池发生异常之前,能够迅速反馈并且告警,保护用户的生命安全。By adopting the embodiments of the present application, the real-time monitoring of the battery state can be effectively realized under the condition of limited influence on the electrochemical performance of the battery, and the problems existing in the battery cell can be accurately warned. The technical solution of the embodiment of the present application increases the safety and reliability of the battery, and can quickly give feedback and give an alarm before the battery becomes abnormal, so as to protect the life safety of the user.
在一种可能的设计中,所述第一处理线路从所述电池装置上的一个第一引出端口导出,所述第二处理线路与所述电池装置的负极端口一起导出。基于这样的设计,所述第一处理线路和所述第二处理线路可以将电芯的状态信息上报 给外部装置。In a possible design, the first processing line is led out from a first lead-out port on the battery device, and the second processing line is led out together with the negative port of the battery device. Based on such a design, the first processing circuit and the second processing circuit can report the status information of the battery cell to an external device.
在一种可能的设计中,所述第一处理线路和所述第二处理线路均从所述电池装置上的同轴接头导出。基于这样的设计,所述第一处理线路和所述第二处理线路可以将电芯的状态信息上报给外部装置。In a possible design, both the first processing line and the second processing line are led out from a coaxial connector on the battery device. Based on such a design, the first processing circuit and the second processing circuit can report the status information of the battery cell to an external device.
在一种可能的设计中,所述第一处理线路从所述电池装置上的第二引出端口导出,所述第二处理线路从所述电池装置上的第三引出端口导出。基于这样的设计,所述第一处理线路和所述第二处理线路可以将电芯的状态信息上报给外部装置。In a possible design, the first processing circuit is derived from a second outlet port on the battery device, and the second processing circuit is derived from a third outlet port on the battery device. Based on such a design, the first processing circuit and the second processing circuit can report the status information of the battery cell to an external device.
在一种可能的设计中,所述多个传感器包括温度传感器、压力传感器、电压传感器、电流传感器、气压传感器或气体传感器中的至少一种。In a possible design, the multiple sensors include at least one of a temperature sensor, a pressure sensor, a voltage sensor, a current sensor, a pressure sensor, or a gas sensor.
第二方面,本申请的实施例提供一种电池装置,所述电池装置包括多个电芯、壳体以及如上述所述的电池监测装置,其中,所述电芯及所述电池监测装置收容于所述壳体内。In the second aspect, an embodiment of the present application provides a battery device, which includes a plurality of battery cells, a casing, and the battery monitoring device as described above, wherein the battery cells and the battery monitoring device accommodate within the housing.
采用本申请的实施例,通过将电池监测装置嵌入电池装置的内部,可以在有限影响电池的放电容量和容量保持率的情况下,灵敏的监测电池内部的温度、应力和气压等参数,并能够迅速的将这些信号输出给外部装置,由此可以实现对电芯状态的实时监控,准确告知存在问题的电芯。此外,本申请实施例的技术方案增加了电池的安全性和可靠性,可以在电池发生异常的时候,能够迅速反馈并且告警,保护用户的生命安全。By adopting the embodiment of the present application, by embedding the battery monitoring device inside the battery device, it is possible to sensitively monitor parameters such as temperature, stress and air pressure inside the battery with limited influence on the discharge capacity and capacity retention rate of the battery, and to Quickly output these signals to external devices, so that real-time monitoring of the battery status can be realized, and the batteries with problems can be accurately notified. In addition, the technical solution of the embodiment of the present application increases the safety and reliability of the battery, and can quickly feedback and give an alarm when the battery is abnormal, so as to protect the life safety of the user.
在一种可能的设计中,所述电芯包括多个依次叠加的负极极片、隔膜和正极极片,所述电池监测装置设置于所述电芯的最后一片负极极片上。In a possible design, the battery cell includes a plurality of sequentially stacked negative pole pieces, separators and positive pole pieces, and the battery monitoring device is arranged on the last negative pole piece of the battery cell.
在一种可能的设计中,所述电池监测装置设置于两个电芯之间。基于这样的设计,所述电池监测装置可以对电芯的状态进行监控。In a possible design, the battery monitoring device is arranged between two battery cells. Based on such a design, the battery monitoring device can monitor the state of the battery cells.
在一种可能的设计中,所述电池监测装置设置于所述电芯与所述壳体之间。基于这样的设计,所述电池监测装置可以对电芯的状态进行监控。In a possible design, the battery monitoring device is arranged between the battery cell and the housing. Based on such a design, the battery monitoring device can monitor the state of the battery cells.
在一种可能的设计中,所述壳体包括盖板,所述盖板上设置正极端口、负极端口以及安全阀,所述安全阀位于所述正极端口与所述负极端口之间,所述安全阀用于将所述电池装置内的气体排出。In a possible design, the housing includes a cover plate, and a positive port, a negative port, and a safety valve are arranged on the cover plate, and the safety valve is located between the positive port and the negative port, the The safety valve is used to discharge the gas in the battery device.
在一种可能的设计中,所述盖板还设有第一引出端口,所述电池监测装置的第一处理线路从所述电池装置上的一个第一引出端口导出,所述第二线处理线路与所述电池装置的负极端口一起导出。基于这样的设计,所述第一处理线路和所述第二处理线路可以将电芯的状态信息上报给外部装置。In a possible design, the cover plate is also provided with a first lead-out port, the first processing line of the battery monitoring device is led out from a first lead-out port on the battery device, and the second line processing line Lead out together with the negative terminal of the battery unit. Based on such a design, the first processing circuit and the second processing circuit can report the status information of the battery cell to an external device.
在一种可能的设计中,所述盖板上还设有同轴接头,所述电池监测装置的第一处理线路和第二处理线路均从所述同轴接头导出。In a possible design, a coaxial connector is further provided on the cover, and both the first processing circuit and the second processing circuit of the battery monitoring device are led out from the coaxial connector.
在一种可能的设计中,所述盖板上还设有第二引出端口及第三引出端口,所述第一处理线路从所述第二引出端口导出,所述第二处理线路从所述第三引出端口导出。基于这样的设计,所述第一处理线路和所述第二处理线路可以将电芯的状态信息上报给外部装置。In a possible design, the cover plate is further provided with a second outlet port and a third outlet port, the first processing circuit is led out from the second outlet port, and the second processing circuit is exported from the The third lead-out port is exported. Based on such a design, the first processing circuit and the second processing circuit can report the status information of the battery cell to an external device.
采用本申请实施例中的电池监测装置及电池装置,通过将电池监测装置嵌 入电池装置的内部,可以在有限影响电池的电化学性能的情况下,灵敏的监测电池内部的温度、应力和气压等参数,并能够迅速的将这些信号输出给外部装置,由此可以实现对电芯状态的实时监控,准确预警电芯的存在问题。本申请实施例的技术方案增加了电池的安全性和可靠性,可以在电池发生异常之前,能够迅速反馈并且告警,保护用户的生命安全。Using the battery monitoring device and battery device in the embodiment of the present application, by embedding the battery monitoring device inside the battery device, it is possible to sensitively monitor the temperature, stress and air pressure inside the battery with limited influence on the electrochemical performance of the battery parameters, and can quickly output these signals to external devices, so that real-time monitoring of the state of the battery can be realized, and the problem of the battery can be accurately warned. The technical solution of the embodiment of the present application increases the safety and reliability of the battery, and can quickly give feedback and give an alarm before the battery becomes abnormal, so as to protect the life safety of the user.
附图说明Description of drawings
图1是本申请实施例的电池装置的示意图。FIG. 1 is a schematic diagram of a battery device according to an embodiment of the present application.
图2是本申请实施例的电池装置的另一示意图。FIG. 2 is another schematic diagram of the battery device of the embodiment of the present application.
图3是本申请实施例的电池装置的一个具体应用场景图。Fig. 3 is a diagram of a specific application scenario of the battery device according to the embodiment of the present application.
图4是本申请实施例的电池装置的另一个具体应用场景图。Fig. 4 is another specific application scenario diagram of the battery device according to the embodiment of the present application.
图5是本申请实施例的电池监测装置的结构示意图。FIG. 5 is a schematic structural diagram of a battery monitoring device according to an embodiment of the present application.
图6是本申请实施例的电池监测装置的一个具体应用场景图。Fig. 6 is a diagram of a specific application scenario of the battery monitoring device according to the embodiment of the present application.
图7是本申请实施例的电池监测装置的另一个具体应用场景图。FIG. 7 is another specific application scenario diagram of the battery monitoring device according to the embodiment of the present application.
图8是本申请实施例的电池监测装置的另一个具体应用场景图。FIG. 8 is another specific application scenario diagram of the battery monitoring device according to the embodiment of the present application.
图9是本申请实施例的电池监测装置的另一个具体应用场景图。FIG. 9 is another specific application scenario diagram of the battery monitoring device according to the embodiment of the present application.
图10是本申请的实施例的电池监测装置的线路输出的示意图。Fig. 10 is a schematic diagram of the line output of the battery monitoring device according to the embodiment of the present application.
图11是本申请的实施例的电池监测装置的线路输出的另一示意图。Fig. 11 is another schematic diagram of the line output of the battery monitoring device according to the embodiment of the present application.
图12是本申请的实施例的电池监测装置的线路输出的另一示意图。Fig. 12 is another schematic diagram of the line output of the battery monitoring device according to the embodiment of the present application.
图13是本申请的实施例的电池监测装置的线路输出的另一示意图。FIG. 13 is another schematic diagram of the line output of the battery monitoring device according to the embodiment of the present application.
图14是本申请的实施例的电池监测装置的线路输出的另一示意图。Fig. 14 is another schematic diagram of the line output of the battery monitoring device according to the embodiment of the present application.
图15是本申请的实施例的电池监测装置的线路输出的另一示意图。Fig. 15 is another schematic diagram of the line output of the battery monitoring device according to the embodiment of the present application.
图16是本申请的实施例的电池监测装置的放置以及极耳焊接的示意图。Fig. 16 is a schematic diagram of the placement of the battery monitoring device and the welding of tabs according to the embodiment of the present application.
图17是本申请的实施例的电池装置的极耳与连接片的焊接示意图。Fig. 17 is a schematic diagram of welding of tabs and connecting pieces of the battery device according to the embodiment of the present application.
图18是本申请的实施例的电池装置的极连接片与极柱焊接的示意图。FIG. 18 is a schematic diagram of welding the pole connecting piece and the pole of the battery device according to the embodiment of the present application.
图19是本申请的实施例的极组入壳及盖板与壳体焊接的示意图。Fig. 19 is a schematic diagram of welding the pole assembly into the case and the cover plate and the case according to the embodiment of the present application.
图20是本申请的实施例的电池装置的线路输出与盖板的示意图。FIG. 20 is a schematic diagram of the line output and the cover plate of the battery device according to the embodiment of the present application.
图21是本申请的实施例的电池装置的线路输出与盖板的另一示意图。FIG. 21 is another schematic diagram of the line output and the cover plate of the battery device according to the embodiment of the present application.
图22是本申请的实施例的电池装置的线路输出与盖板的另一示意图。FIG. 22 is another schematic diagram of the line output and the cover plate of the battery device according to the embodiment of the present application.
主要元件符号说明Description of main component symbols
100-电池装置;200-外部装置;210-外部通信单元;220-外部控制单元;230-应用单元;300-笔记本电脑;400-电动汽车;10-电池监测装置;12-温度传感器;13-压力传感器;14-电压传感器;15-电流传感器;16-气压传感器;20-电芯;201-负极极片;202-隔膜;203-正极极片;211-正极极耳;212-负极极耳;213-正极连接片;214-负极连接片;30-壳体;31-盖板;311-正极端口;312-负极端口;313-安全阀;314-注液孔;315,317,318-引出端口;316-同轴接头;321-正 极极柱;322-负极极柱;40-处理器;41-数据接口;42-控制单元;44-通信处理单元;45-数据处理单元;46-动作执行单元;417-第一处理线路;418-第二处理线路;50-极组;100-battery device; 200-external device; 210-external communication unit; 220-external control unit; 230-application unit; 300-notebook computer; 400-electric vehicle; 10-battery monitoring device; 12-temperature sensor; 13- Pressure sensor; 14-voltage sensor; 15-current sensor; 16-air pressure sensor; 20-cell; 201-negative pole piece; 202-diaphragm; 203-positive pole piece; 211-positive pole ear; ; 213-positive connecting piece; 214-negative connecting piece; 30-housing; 31-cover; -coaxial connector; 321-positive pole; 322-negative pole; 40-processor; 41-data interface; 42-control unit; 44-communication processing unit; 45-data processing unit; 46-action execution unit; 417-the first processing circuit; 418-the second processing circuit; 50-pole group;
如下具体实施方式将结合上述附图进一步详细说明本申请。The following specific embodiments will further describe the present application in detail in conjunction with the above-mentioned drawings.
具体实施方式Detailed ways
需要说明的是,当一个元件被认为是“连接”另一个元件,它可以是直接连接到另一个元件或者可能同时存在居中设置的元件。当一个元件被认为是“设置在”另一个元件,它可以是直接设置在另一个元件上或者可能同时存在居中设置的元件。It should be noted that when an element is considered to be "connected" to another element, it may be directly connected to the other element or there may be an intervening element at the same time. When an element is referred to as being "disposed on" another element, it can be directly disposed on the other element or intervening elements may also be present.
除非另有定义,本文所使用的所有的技术和科学术语与属于本申请的技术领域的技术人员通常理解的含义相同。本文中在本申请的说明书中所使用的术语只是为了描述具体的实施例的目的,不是旨在于限制本申请。本文所使用的术语“及/或”包括一个或多个相关的所列项目的任意的和所有的组合。Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the technical field to which this application belongs. The terms used herein in the specification of the application are only for the purpose of describing specific embodiments, and are not intended to limit the application. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items.
热失控可以指电池内部由于一系列的放热连锁反应导致电池温升速率急剧升高,温度不再可控的一种过热现象,可以导致电池发生起火、爆炸、燃烧等危险情况。因此,如何在电池组起火前准确、有效预测热失控,将对保证电池的安全具有重要的意义。Thermal runaway can refer to an overheating phenomenon in which the temperature of the battery rises sharply due to a series of exothermic chain reactions inside the battery, and the temperature is no longer controllable, which can lead to dangerous situations such as fire, explosion, and combustion of the battery. Therefore, how to accurately and effectively predict thermal runaway before the battery pack catches fire will be of great significance to ensure the safety of the battery.
在一种可能的实现方式中,在软包电池叠片时,可以在软包电池内部介于隔膜与隔膜之间处嵌入布拉格光纤温度传感器,来监测电池内部温度的变化,并在软包电池的外表面附着布拉格光纤温度传感器,可以理解,该布拉格光纤温度传感器可以监测软包电池内、外的温度。然而,上述方式中,电池的各项性能将会急剧下降,例如电池的放电容量以及循环稳定性等均会下降,此外不能了解和掌握电池的内部状态,不能对电池内部状态实行有效的监控和管理。In a possible implementation, when the pouch battery is stacked, a Bragg optical fiber temperature sensor can be embedded between the diaphragm and the diaphragm inside the pouch battery to monitor the change of the internal temperature of the battery, and the pouch battery A Bragg fiber optic temperature sensor is attached to the outer surface of the pouch battery. It can be understood that the Bragg fiber optic temperature sensor can monitor the temperature inside and outside the pouch battery. However, in the above method, the various performances of the battery will drop sharply, such as the discharge capacity and cycle stability of the battery will all decrease. In addition, the internal state of the battery cannot be understood and mastered, and the internal state of the battery cannot be effectively monitored and monitored. manage.
在另一种可能的实现方式中,锂离子电池可以包括8片极片容量为330mAh/g的石墨阳极、7片极片容量为150mAh/g的镍锰钴(NMC)以及六氟磷酸锂(LiPF 6)电解液,由此组装的电池容量为5Ah。可以使用环氧树脂胶将8个分布式布拉格光纤温度传感器粘合到软包电池的表面,并使用绝缘胶带将8个传感器进一步进行粘连,以此装置可以监控软包电池外表面的温度变化。然而,上述方式中,外包装的铝塑膜具有隔热效果,即该布拉格光纤温度传感器不能及时监测到电池内部的温度变化,因此,上述实现方式不能精准的监控电池的安全性,实用性不高。 In another possible implementation, the lithium-ion battery can include 8 pieces of graphite anode with a capacity of 330mAh/g, 7 pieces of nickel-manganese-cobalt (NMC) with a capacity of 150mAh/g, and lithium hexafluorophosphate (LiPF 6 ). electrolyte, the battery capacity thus assembled was 5Ah. Eight distributed Bragg optical fiber temperature sensors can be bonded to the surface of the pouch battery with epoxy glue, and the eight sensors can be further bonded with insulating tape, so that the device can monitor the temperature change on the outer surface of the pouch battery. However, in the above method, the aluminum-plastic film of the outer packaging has a heat insulation effect, that is, the Bragg optical fiber temperature sensor cannot monitor the temperature change inside the battery in time. Therefore, the above implementation method cannot accurately monitor the safety of the battery and is not practical. high.
在另一种可能的实现方式中,可以将负极材料、粘结剂和导电剂进行混浆,涂到铜箔负极集流体上,接着再将布拉格光纤温度传感器(放置在定制的管中)嵌入在浆料中,并将所述极片在真空干燥箱中进行烘干。待所述极片烘干后,该布拉格光纤温度传感器可以固定在极片上,所述布拉格光纤温度传感器的信号通过光纤线路进行输出,且光纤线路从软包电池的尾部中间处导出。另外, 为了防止光纤线路被电解液腐蚀,可以在其表面涂覆一层聚酰亚胺聚合物。可以理解,上述的实现方式可以及时的监测电池内部的温度变化,然而传感器嵌入的位置会使得电池的容量的下降,还会降低电池的循环性能。此外,对软包电池的封装技术也会有一定的挑战,若封装技术不好,容易导致电池电解液的泄露。In another possible implementation, the anode material, binder, and conductive agent can be mixed and coated on the copper foil anode current collector, and then the Bragg fiber optic temperature sensor (placed in a custom-made tube) is embedded in the slurry, and dry the pole pieces in a vacuum oven. After the pole piece is dried, the Bragg fiber optic temperature sensor can be fixed on the pole piece, and the signal of the Bragg fiber optic temperature sensor is output through the fiber optic line, and the fiber optic line is led out from the middle of the tail of the pouch battery. In addition, in order to prevent the optical fiber line from being corroded by the electrolyte, a layer of polyimide polymer can be coated on its surface. It can be understood that the above-mentioned implementation method can monitor the temperature change inside the battery in time, but the position where the sensor is embedded will reduce the capacity of the battery and also reduce the cycle performance of the battery. In addition, there will be certain challenges to the packaging technology of pouch batteries. If the packaging technology is not good, it will easily lead to the leakage of battery electrolyte.
针对上述问题,为此,本申请的实施例提供一种电池监测装置及电池装置,可以将该传感器集成到电池中,可以在有限影响电池的放电容量和容量保持率的情况下,实现对电芯状态的实时监控,并可以快速的将感测到的信号进行输出。所述电池可以包括一个或多个电芯,后续以多个电芯为例作介绍。In view of the above problems, the embodiments of the present application provide a battery monitoring device and a battery device. The sensor can be integrated into the battery, and the battery can be monitored under the condition of limited influence on the discharge capacity and capacity retention rate of the battery. Real-time monitoring of core status, and can quickly output the sensed signal. The battery may include one or more cells, and multiple cells will be used as an example for introduction later.
请参阅图1,为本申请的一个实施例提供的电池装置100的示意图。所述电池装置100可以电连接于外部装置200。在一种可能的场景下,所述电池装置100可以为所述外部装置200供电。在另一种可能的场景下,所述电池装置100还可以输出电池状态信息给所述外部装置200。Please refer to FIG. 1 , which is a schematic diagram of a battery device 100 provided by an embodiment of the present application. The battery device 100 can be electrically connected to an external device 200 . In a possible scenario, the battery device 100 may provide power for the external device 200 . In another possible scenario, the battery device 100 may also output battery status information to the external device 200 .
本实施例中的所述电池装置100可以包括电池监测装置10以及电芯20。本实施例中的电池监测装置10可以对电芯20的状态进行监测,并可以将监测到的电芯20的状态上报给外部装置200。例如,所述电池监测装置10可以将电池装置100的健康状态或者热失控状态传输给外部装置200。The battery device 100 in this embodiment may include a battery monitoring device 10 and a battery cell 20 . The battery monitoring device 10 in this embodiment can monitor the status of the battery cell 20 and report the monitored status of the battery cell 20 to the external device 200 . For example, the battery monitoring device 10 may transmit the health status or thermal runaway status of the battery device 100 to the external device 200 .
在一种可能的场景下,若所述电池装置100发生热失控,所述电池监测装置10可以将电池装置100的热失控信息上报给所述外部装置200,所述外部装置200可以发出告警信息,以及时提醒用户进行处理。在另一种可能的场景下,若所述电池装置100处于健康状态,所述电池监测装置10可以将电池装置100的健康状态信息上报给所述外部装置200,所述外部装置200可以发出提示信息,即此时所述电池装置100处于安全状态。In a possible scenario, if thermal runaway occurs in the battery device 100, the battery monitoring device 10 may report the thermal runaway information of the battery device 100 to the external device 200, and the external device 200 may send an alarm message , to remind the user to deal with it in time. In another possible scenario, if the battery device 100 is in a healthy state, the battery monitoring device 10 may report the health state information of the battery device 100 to the external device 200, and the external device 200 may issue a prompt Information, that is, the battery device 100 is in a safe state at this time.
可以理解,所述电池装置100可以应用于手机终端、笔记本电脑、电动汽车、储能系统、水下电池驱动装置等,对此本申请不做限定。It can be understood that the battery device 100 can be applied to mobile terminals, notebook computers, electric vehicles, energy storage systems, underwater battery drive devices, etc., which is not limited in this application.
请参阅图2,为本申请实施例的电池装置100的一个结构示意图。可以理解,在一种可能的实现方式中,所述电池装置100可以为方形电池。具体地,所述电池装置100还可以包括壳体30,所述电池监测装置10和所述电芯20均可以收容在所述壳体30内。所述壳体30可以包括盖板31,所述盖板31上可以设置正极端口311、负极端口312、安全阀313、注液孔314以及引出端口315。Please refer to FIG. 2 , which is a schematic structural diagram of a battery device 100 according to an embodiment of the present application. It can be understood that, in a possible implementation manner, the battery device 100 may be a prismatic battery. Specifically, the battery device 100 may further include a casing 30 , and both the battery monitoring device 10 and the battery cell 20 may be accommodated in the casing 30 . The casing 30 may include a cover plate 31 on which a positive port 311 , a negative port 312 , a safety valve 313 , a liquid injection hole 314 and an outlet port 315 may be disposed.
可以理解,本实施例中的所述安全阀313可以将所述电池装置100内的气体排出。更进一步地,所述注液孔314可以用于为所述电池装置100注入电解液。所述引出端口315可以用于将所述电池监测装置10的线路与所述外部装置200进行相连接。It can be understood that the safety valve 313 in this embodiment can discharge the gas in the battery device 100 . Furthermore, the liquid injection hole 314 can be used for injecting electrolyte solution into the battery device 100 . The outgoing port 315 can be used to connect the line of the battery monitoring device 10 with the external device 200 .
可以理解,所述正极端口311可以用于电连接所述电芯20的正极极耳,所述负极端口312可以用于电连接所述电芯20的负极极耳。It can be understood that the positive terminal 311 can be used to electrically connect the positive tab of the battery 20 , and the negative terminal 312 can be used to electrically connect the negative tab of the battery 20 .
如图3所示,在一种使用场景下,以所述电池装置100应用于笔记本电脑300为例进行说明。As shown in FIG. 3 , in a usage scenario, the battery device 100 is applied to a notebook computer 300 as an example for description.
在一些实施例中,所述电池装置100可以设置于所述笔记本电脑300的内 部。可以理解,所述电池装置100可以用于为所述笔记本电脑300进行供电,并且所述电池监测装置10还可以将监测到的电芯的状态信息上报给所述笔记本电脑300,以在电池装置100发生热失控时,可以及时提醒用户进行处理,也可以在电池装置100处于健康状态时发出提示信息给用户。In some embodiments, the battery device 100 may be disposed inside the notebook computer 300. It can be understood that the battery device 100 can be used to provide power for the notebook computer 300, and the battery monitoring device 10 can also report the state information of the monitored batteries to the notebook computer 300, so as to provide power for the battery device 300. When the thermal runaway of the battery device 100 occurs, the user can be reminded to deal with it in time, and a prompt message can also be sent to the user when the battery device 100 is in a healthy state.
举例说明,若所述电池装置100发生热失控,所述电池监测装置10可以将热失控信息传输给所述笔记本电脑300,所述笔记本电脑300的显示屏幕可以显示告警信息,并且所述笔记本电脑300的扬声器可以发出告警声音,以告知用户此时的电池装置100处于热失控状态,需要及时对该情况进行处理。若所述电池装置100处于安全状态,所述电池监测装置10可以将健康状态信息传输给所述笔记本电脑300,所述笔记本电脑300的显示屏幕可以显示电池安全信息,以告知用户此时的电池装置100处于安全状态。For example, if thermal runaway occurs in the battery device 100, the battery monitoring device 10 may transmit thermal runaway information to the notebook computer 300, the display screen of the notebook computer 300 may display an alarm message, and the notebook computer The loudspeaker of 300 can emit an alarm sound to inform the user that the battery device 100 is in a state of thermal runaway at this time, and the situation needs to be dealt with in time. If the battery device 100 is in a safe state, the battery monitoring device 10 can transmit the health status information to the notebook computer 300, and the display screen of the notebook computer 300 can display the battery safety information to inform the user of the current state of the battery. The device 100 is in a safe state.
如图4所示,在另一种使用场景下,以所述电池装置100应用于电动汽车400为例进行说明。As shown in FIG. 4 , in another usage scenario, the battery device 100 is applied to an electric vehicle 400 as an example for description.
所述电池装置100可以设置于所述电动汽车400内部。所述电池装置100可以为车载电池包,即所述电池装置100可以用于为电动汽车400进行供电,并且所述电池监测装置10可以将监测到的电池的状态信息上报给所述电动汽车400,以在电池装置100发生热失控时,所述电动汽车400的车载显示屏显示告警信息,以及时提醒用户进行处理,所述电动汽车400的车载显示屏也可以在电池装置100处于健康状态时,显示电池装置100的健康状态。The battery device 100 may be disposed inside the electric vehicle 400 . The battery device 100 can be a vehicle battery pack, that is, the battery device 100 can be used to provide power for the electric vehicle 400, and the battery monitoring device 10 can report the monitored battery status information to the electric vehicle 400 , so that when thermal runaway occurs in the battery device 100, the vehicle-mounted display screen of the electric vehicle 400 displays warning information to remind the user to deal with it in time, and the vehicle-mounted display screen of the electric vehicle 400 can also , to display the health status of the battery device 100 .
请参阅图5,以下将结合附图和实际应用场景,对本申请实施例提供的电池监测装置10进行举例说明。Referring to FIG. 5 , the battery monitoring device 10 provided in the embodiment of the present application will be described below with reference to the accompanying drawings and actual application scenarios.
图5所示为本申请的一个实施例提供的电池监测装置10的结构示意图。本实施例中,所述电池监测装置10可以包括多个传感器和处理器40。FIG. 5 is a schematic structural diagram of a battery monitoring device 10 provided by an embodiment of the present application. In this embodiment, the battery monitoring device 10 may include multiple sensors and a processor 40 .
例如,所述多个传感器可以包括温度传感器12、压力传感器13、电压传感器14、电流传感器15和气压传感器16、气体传感器(图中未示出)以及其他类型的传感器。可以理解,上述的这些传感器均可以用来感测所述电芯20的参数。其中,本实施例中的处理器40可以包括数据接口41、控制单元42、通信处理单元44、数据处理单元45和动作执行单元46。For example, the plurality of sensors may include a temperature sensor 12, a pressure sensor 13, a voltage sensor 14, a current sensor 15, and an air pressure sensor 16, a gas sensor (not shown in the figure), and other types of sensors. It can be understood that the aforementioned sensors can all be used to sense parameters of the battery cell 20 . Wherein, the processor 40 in this embodiment may include a data interface 41 , a control unit 42 , a communication processing unit 44 , a data processing unit 45 and an action execution unit 46 .
可以理解,所述处理器40可以与上述的传感器通信连接,并可以接收多个传感器感测的电芯20的参数,所述处理器40可以基于多个传感器感测的多种参数,确定所述电芯20的状态。It can be understood that the processor 40 can communicate with the above-mentioned sensors, and can receive the parameters of the battery cell 20 sensed by multiple sensors, and the processor 40 can determine the parameters based on the various parameters sensed by the multiple sensors. Describe the state of the battery cell 20.
所述数据接口41可以电连接所述多个传感器,即所述数据接口41可以电连接温度传感器12、压力传感器13、电压传感器14、电流传感器15和气压传感器16、气体传感器以及其他类型的传感器。所述数据接口41可以对多个传感器与所述控制单元42之间传输信号进行转换,所述数据接口41还可以用于完成所述多个传感器与所述控制单元42之间接收与发送等传输功能等。The data interface 41 can be electrically connected to the plurality of sensors, that is, the data interface 41 can be electrically connected to the temperature sensor 12, the pressure sensor 13, the voltage sensor 14, the current sensor 15, the air pressure sensor 16, the gas sensor and other types of sensors . The data interface 41 can convert the transmission signals between multiple sensors and the control unit 42, and the data interface 41 can also be used to complete receiving and sending between the multiple sensors and the control unit 42, etc. transfer function, etc.
本实施例中,所述控制单元42可以是所述处理器40的主控模块,所述控制单元42可以电连接所述温度传感器12、所述压力传感器13和所述气压传感器16、气体传感器以及其他类型的传感器。其中,所述控制单元42可以控制所 述温度传感器12采集所述电芯20的温度信号,所述控制单元42还可以控制所述压力传感器13采集所述电芯20的压力信号,所述控制单元42还可以控制所述气压传感器16等(如气体传感器)采集所述电芯20的气压参数。可以理解,所述温度传感器12和所述压力传感器13采集的温度信号和压力信号均为模拟信号,因此,所述控制单元42可以通过所述数据接口41将所述温度信号和压力信号进行模数转换,以将转换得到的数字信号传输给所述数据处理单元45。In this embodiment, the control unit 42 may be the main control module of the processor 40, and the control unit 42 may be electrically connected to the temperature sensor 12, the pressure sensor 13, the air pressure sensor 16, and the gas sensor. and other types of sensors. Wherein, the control unit 42 can control the temperature sensor 12 to collect the temperature signal of the battery cell 20, the control unit 42 can also control the pressure sensor 13 to collect the pressure signal of the battery cell 20, the control The unit 42 can also control the air pressure sensor 16 (such as a gas sensor) to collect the air pressure parameters of the battery cell 20 . It can be understood that the temperature signal and the pressure signal collected by the temperature sensor 12 and the pressure sensor 13 are all analog signals, therefore, the control unit 42 can simulate the temperature signal and the pressure signal through the data interface 41 digital conversion, so as to transmit the converted digital signal to the data processing unit 45.
所述控制单元42还可以电连接所述电压传感器14和所述电流传感器15。其中,所述控制单元42还可以控制所述电压传感器14采集所述电芯20的电压值,所述控制单元42还可以控制所述电流传感器15采集所述电芯20的电流值。可以理解,所述电压传感器14和所述电流传感器15采集的电压信号和电流信号均为模拟信号,因此,所述控制单元42还可以通过所述数据接口41将所述电压信号和电流信号进行模数转换,以将转换得到的数字信号传输给所述数据处理单元45。The control unit 42 can also be electrically connected to the voltage sensor 14 and the current sensor 15 . Wherein, the control unit 42 can also control the voltage sensor 14 to collect the voltage value of the battery cell 20 , and the control unit 42 can also control the current sensor 15 to collect the current value of the battery cell 20 . It can be understood that the voltage signal and the current signal collected by the voltage sensor 14 and the current sensor 15 are all analog signals, therefore, the control unit 42 can also carry out the voltage signal and the current signal through the data interface 41 Analog-to-digital conversion, so as to transmit the converted digital signal to the data processing unit 45 .
可以理解,本实施例中,所述数据处理单元45可以用于对所述多个传感器的参数进行处理和分析。采用这样的方式,所述数据处理单元45可以基于上述的多个传感器所采集到的相关参数,进行分析处理,由此可以进一步来确定所述电芯20的状态。所述通信处理单元44可以电连接所述外部装置200。由此,所述数据处理单元45在确定所述电芯20的状态后,可以通过所述通信处理单元44发送给所述外部装置200,进而反馈给外部装置200(如车载芯片)。可以理解,在一个可能的实现方式中,所述通信处理单元44可以采用有线通信或者无线通信的方式,来传输信息给所述外部装置200。It can be understood that in this embodiment, the data processing unit 45 may be used to process and analyze the parameters of the multiple sensors. In this manner, the data processing unit 45 can perform analysis and processing based on the relevant parameters collected by the above-mentioned multiple sensors, thereby further determining the state of the battery cell 20 . The communication processing unit 44 can be electrically connected to the external device 200 . Thus, after the data processing unit 45 determines the state of the battery cell 20 , it can send it to the external device 200 through the communication processing unit 44 , and then feed it back to the external device 200 (such as an on-board chip). It can be understood that, in a possible implementation manner, the communication processing unit 44 may transmit information to the external device 200 in a manner of wired communication or wireless communication.
在一种可能的设计中,所述数据处理单元45可以包括微控制单元(Micro Control Unit,MCU)核,其中,所述MCU核可以用于数据处理。所述数据处理单元45还可以用于控制算法优化可以理解,本实施例中处理器40还可以包括时钟单元以及电源单元。其中,所述时钟单元可以用于控制所述处理器40的时钟。所述电源单元可以用于为所述处理器40内的各个单元提供电力和电源管理。In a possible design, the data processing unit 45 may include a micro control unit (Micro Control Unit, MCU) core, wherein the MCU core may be used for data processing. The data processing unit 45 can also be used to optimize the control algorithm. It can be understood that the processor 40 in this embodiment can also include a clock unit and a power supply unit. Wherein, the clock unit may be used to control the clock of the processor 40 . The power supply unit can be used to provide power and power management for various units in the processor 40 .
本实施例中,所述动作执行单元46可以电连接所述控制单元42,所述动作执行单元46可以用于执行来自所述控制单元42的控制指令。可以理解,在一些可能的设计中,所述动作执行单元46可以是所述电池装置100的保护装置,所述动作执行单元46可以用于切断电池输出、切断电池输入(如过冲保护)、温升保护、低温保护以及过载保护等。In this embodiment, the action execution unit 46 may be electrically connected to the control unit 42 , and the action execution unit 46 may be configured to execute control instructions from the control unit 42 . It can be understood that, in some possible designs, the action execution unit 46 can be a protection device for the battery device 100, and the action execution unit 46 can be used to cut off the battery output, cut off the battery input (such as overshoot protection), Temperature rise protection, low temperature protection and overload protection, etc.
在一个可能的实现方式中,所述温度传感器12、压力传感器13和气压传感器16、气体传感器以及其他类型的传感器均可以设置在所述电芯20的不同表面上。In a possible implementation manner, the temperature sensor 12 , pressure sensor 13 , air pressure sensor 16 , gas sensor and other types of sensors can all be arranged on different surfaces of the battery cell 20 .
基于上述这样的设计,即本申请实施例可以通过设计多路参数采集的方案,并经过数据处理单元45的分析及处理,将计算结果通过通信处理单元44发送到车载芯片。因此,本申请实施例可以实现信号的高速传输和实时传输,并且可以将多个传感器集成到电池监控装置中。此外,还可以通过车载大屏实时显示,并可以在出现危险时发出告警提示,以实现对电池状态的实时监控。Based on the above design, the embodiment of the present application can design a multi-channel parameter acquisition scheme, and after the analysis and processing by the data processing unit 45, the calculation result can be sent to the on-board chip through the communication processing unit 44. Therefore, the embodiment of the present application can realize high-speed and real-time transmission of signals, and can integrate multiple sensors into the battery monitoring device. In addition, it can also be displayed in real time on the large screen of the vehicle, and an alarm prompt can be issued in case of danger, so as to realize real-time monitoring of the battery status.
请参阅图6,为本申请的一个实施例的电池监测装置10的一个具体应用场景图。如图6所示,本实施例中,所述电芯20可以包括依次叠加的负极极片201、隔膜202或者固态电解质和正极极片203。Please refer to FIG. 6 , which is a diagram of a specific application scenario of the battery monitoring device 10 according to an embodiment of the present application. As shown in FIG. 6 , in this embodiment, the cell 20 may include a negative pole piece 201 , a separator 202 or a solid electrolyte and a positive pole piece 203 stacked in sequence.
可以理解,在一种可能的实现方式中,所述电池监测装置10可以嵌入至所述电芯20,在具体的实现过程中,所述电池监测装置10可以嵌入在所述电芯20的最后一片负极极片201上(例如集流体侧)。基于这样的设计,所述电池监测装置10可以对该电芯20的状态进行监测,例如,所述电池监测装置10可以获取该电芯20的多种参数,所述电池监测装置10还可以基于获取的多种参数来确定该电芯20的状态。其中,多种参数可以包括电芯的温度、压力以及气压、电压和电流等。It can be understood that, in a possible implementation manner, the battery monitoring device 10 can be embedded in the battery cell 20, and in a specific implementation process, the battery monitoring device 10 can be embedded in the last of the battery cell 20 On a piece of negative electrode sheet 201 (for example, on the current collector side). Based on such a design, the battery monitoring device 10 can monitor the state of the battery cell 20, for example, the battery monitoring device 10 can obtain various parameters of the battery cell 20, and the battery monitoring device 10 can also be based on A variety of parameters are obtained to determine the state of the battery cell 20 . Among them, various parameters may include the temperature, pressure and air pressure, voltage and current of the battery core.
可以理解,该电芯20的状态可能会影响整个电池装置100的工作状态。在一种可能的情况下,其中一个电芯20发生热失控或者将要发生热失控,若不能及时发现和控制,该电芯20将可能发生热扩散,导致整个电池装置100的燃烧,甚至产生爆炸。为此,本申请实施例可以在每一个电芯20的最后一片负极极片201上配置对应的电池监测装置10,由此可以在其中一个或多个电芯20发生热失控或者将要发生热失控时,及时发现和控制,避免电池装置100燃烧和爆炸等危险情况发生。It can be understood that the state of the battery cell 20 may affect the working state of the entire battery device 100 . In a possible situation, one of the battery cells 20 has thermal runaway or is about to experience thermal runaway. If it cannot be detected and controlled in time, thermal diffusion may occur in the battery cell 20, causing the entire battery device 100 to burn or even explode. . For this reason, in the embodiment of the present application, a corresponding battery monitoring device 10 can be configured on the last negative electrode sheet 201 of each battery cell 20, so that thermal runaway can occur or will occur in one or more battery cells 20. When the battery device 100 burns and explodes, it can be detected and controlled in time to avoid dangerous situations such as combustion and explosion of the battery device 100.
所述电池监测装置10可以将监测到的电芯20的状态信息发送给所述外部装置200。所述外部装置200可获得针对具体的一个或多个电芯的热失控信息或健康状态信息,从而针对所述一个或多个电芯20做出预警。The battery monitoring device 10 can send the monitored status information of the battery cell 20 to the external device 200 . The external device 200 can obtain thermal runaway information or health status information for one or more battery cells, so as to give an early warning for the one or more battery cells 20 .
请参阅图7,为本申请实施例的电池监测装置10的另一个具体应用场景图。如图7所示,本实施例中,所述电池装置100可以包括多个电芯20。所述电池监测装置10可以设置于两个电芯20之间。Please refer to FIG. 7 , which is another specific application scenario diagram of the battery monitoring device 10 according to the embodiment of the present application. As shown in FIG. 7 , in this embodiment, the battery device 100 may include a plurality of battery cells 20 . The battery monitoring device 10 can be disposed between two battery cells 20 .
基于这样的设计,所述电池监测装置10可以监测到所述电芯20的参数,并根据监测到的参数可以确定电芯20的状态。Based on such a design, the battery monitoring device 10 can monitor the parameters of the battery cell 20 and determine the state of the battery cell 20 according to the monitored parameters.
可以理解,在另一种可能的场景下,即所述电池装置100设计的容量较大时,可以采取设置多个电池监测装置10。如图8所示,所述电池装置100以五个电芯20为例进行说明。在其他的场景下,电芯20的数量可以根据实际情况进行调整。It can be understood that in another possible scenario, that is, when the designed capacity of the battery device 100 is relatively large, multiple battery monitoring devices 10 may be provided. As shown in FIG. 8 , the battery device 100 is described by taking five battery cells 20 as an example. In other scenarios, the number of battery cells 20 can be adjusted according to actual conditions.
举例说明,在图8示出的场景下,五个电芯20可以依次并排地设置在所述壳体30中。示例性地,第一个电芯20与第二个电芯20之间可以设置一个电池监测装置10,第二个电芯20与第三个电芯20之间没有设置电池监测装置10,第三个电芯20与第四电芯20之间没有设置电池监测装置10,第四个电芯20与第五个电芯20之间设置有电池监测装置10。可以理解,上述场景中电池监测装置10的放置方式仅是举例说明。For example, in the scenario shown in FIG. 8 , five battery cells 20 may be arranged in the casing 30 in sequence and side by side. Exemplarily, a battery monitoring device 10 may be provided between the first battery cell 20 and the second battery cell 20, and no battery monitoring device 10 is provided between the second battery cell 20 and the third battery cell 20. The battery monitoring device 10 is not provided between the three battery cells 20 and the fourth battery cell 20 , and the battery monitoring device 10 is provided between the fourth battery cell 20 and the fifth battery cell 20 . It can be understood that the placement of the battery monitoring device 10 in the above scenario is only an example.
请参阅图9,为本申请实施例的电池监测装置10的另一个具体应用场景图。如图9所示,本实施例中,所述电池监测装置10可以设置于所述电芯20与所述壳体30之间。基于以上的多种所述电池监测装置10的放置位置,在有限影响电池的电化学性能情况下,所述电池监测装置10可以方便地实现对电池装置 100状态的实时监控。Please refer to FIG. 9 , which is another specific application scenario diagram of the battery monitoring device 10 according to the embodiment of the present application. As shown in FIG. 9 , in this embodiment, the battery monitoring device 10 may be disposed between the battery cell 20 and the casing 30 . Based on the various placement positions of the battery monitoring device 10 described above, the battery monitoring device 10 can conveniently realize real-time monitoring of the state of the battery device 100 under the condition of limited influence on the electrochemical performance of the battery.
请参阅图10,为本申请的一个实施例提供的电池监测装置10的线路输出的结构示意图。所述电池监测装置10可以包括处理线路,其中所述处理线路可以电连接于所述处理器40。具体到本申请的实现方式中,所述处理线路可以包括第一处理线路417和第二处理线路418。所述第一处理线路417和所述第二处理线路418可以电连接于所述处理器40,以用于从所述处理器40获取所述电池装置100的状态信息,并将所获取到的状态信息上报给外部装置200。Please refer to FIG. 10 , which is a schematic structural diagram of the line output of the battery monitoring device 10 provided by an embodiment of the present application. The battery monitoring device 10 may include processing circuitry, wherein the processing circuitry may be electrically connected to the processor 40 . Specifically in the implementation manner of the present application, the processing circuit may include a first processing circuit 417 and a second processing circuit 418 . The first processing circuit 417 and the second processing circuit 418 may be electrically connected to the processor 40, for obtaining the status information of the battery device 100 from the processor 40, and converting the obtained The status information is reported to the external device 200 .
可以理解,所述第一处理线路417和所述第二处理线路418可以电连接于所述外部装置200。所述外部装置200可以根据接收到的所述电池装置100的状态信息,进而得知所述电池装置100的状态。It can be understood that the first processing circuit 417 and the second processing circuit 418 may be electrically connected to the external device 200 . The external device 200 can further know the state of the battery device 100 according to the received state information of the battery device 100 .
在一些可能的实现方式中,所述外部装置200可以包括外部通信单元210、外部控制单元220以及应用单元230。In some possible implementation manners, the external device 200 may include an external communication unit 210 , an external control unit 220 and an application unit 230 .
所述外部通信单元210可以电连接于所述电池监测装置10,以从所述电池监测装置10获取所述电池装置100的状态信息。所述外部控制单元220可以与所述外部通信单元210进行双向通信,具体地,所述外部控制单元220可以对所获取的所述电池装置100的状态信息进行分析,并可以确定所述电芯20的温度、压力、电流、电压或者气压、气体等是否异常。此外,所述外部控制单元220还可以用于在分析和确定状态信息后,再输出控制指令给所述电池监测装置10。所述应用单元230可以用于输出预警信息,例如,所述应用单元230可以为中控显示屏。The external communication unit 210 can be electrically connected to the battery monitoring device 10 to obtain status information of the battery device 100 from the battery monitoring device 10 . The external control unit 220 can perform two-way communication with the external communication unit 210, specifically, the external control unit 220 can analyze the acquired state information of the battery device 100, and can determine that the battery cell 20 Whether the temperature, pressure, current, voltage or air pressure, gas, etc. are abnormal. In addition, the external control unit 220 can also be used to output control instructions to the battery monitoring device 10 after analyzing and determining the state information. The application unit 230 can be used to output warning information, for example, the application unit 230 can be a central control display screen.
所述第一处理线路417可以从所述盖板31上的一个引出端口315导出。The first processing circuit 417 can be led out from an outlet port 315 on the cover plate 31 .
请一并参阅图11所示,本实施例中,所述第一处理线路417可以从所述盖板31上的所述引出端口315导出。所述第二处理线路418可以与所述盖板31上的负极端口312一起导出,即所述电池监测装置10的第一处理线路417可以和所述电池装置100的负极端口共用一个输出端口。Please also refer to FIG. 11 , in this embodiment, the first processing circuit 417 can be led out from the outlet port 315 on the cover plate 31 . The second processing circuit 418 can be exported together with the negative port 312 on the cover plate 31 , that is, the first processing circuit 417 of the battery monitoring device 10 can share an output port with the negative port of the battery device 100 .
可以理解,在一种可能的实现方式中,所述引出端口315可以位于所述电池装置100的正极端口311和所述安全阀313之间。It can be understood that, in a possible implementation manner, the outlet port 315 may be located between the positive port 311 of the battery device 100 and the safety valve 313 .
请一并参阅图12,为本申请的另一个实施例提供的电池监测装置10的线路输出的结构示意图。Please also refer to FIG. 12 , which is a schematic structural diagram of the line output of the battery monitoring device 10 provided by another embodiment of the present application.
与图10及图11的区别在于,本实施例中,如图12所示,所述第一处理线路417和所述第二处理线路418均可以从同一个同轴接头316处导出,由此可以与所述外部装置200进行电连接。The difference from Fig. 10 and Fig. 11 is that in this embodiment, as shown in Fig. 12, both the first processing circuit 417 and the second processing circuit 418 can be derived from the same coaxial connector 316, thus It can be electrically connected with the external device 200 .
更进一步,如图13所示,在一种可能的实现方式中,该同轴接头316可以设置于所述电池装置100的正极端口311与所述安全阀313之间。Furthermore, as shown in FIG. 13 , in a possible implementation manner, the coaxial joint 316 may be disposed between the positive port 311 of the battery device 100 and the safety valve 313 .
请一并参阅图14,为本申请的另一个实施例提供的电池监测装置10的线路输出的结构示意图。Please also refer to FIG. 14 , which is a schematic structural diagram of the line output of the battery monitoring device 10 provided by another embodiment of the present application.
与图10及图11的区别在于,本实施例中,如图14所示,所述第一处理线路417和所述第二处理线路418可以从位于所述正极端口311和所述安全阀313之间端口处导出。The difference from FIG. 10 and FIG. 11 is that, in this embodiment, as shown in FIG. 14 , the first processing circuit 417 and the second processing circuit 418 can be connected from Exported at the ports in between.
更进一步,如图15所示,在一种可能的实现方式中,该盖板31上还设有引出端口317和引出端口318,所述第一处理线路417和所述第二处理线路418可以分别从所述引出端口317和引出端口318导出。具体地,所述引出端口317和引出端口318可以位于所述正极端口311和所述安全阀313之间。可以理解,在一些可能的实现方式中,所述引出端口317和所述引出端口318均可以为BMA接头。Furthermore, as shown in FIG. 15 , in a possible implementation manner, the cover plate 31 is also provided with an outlet port 317 and an outlet port 318, and the first processing circuit 417 and the second processing circuit 418 can be are exported from the outgoing port 317 and the outgoing port 318 respectively. Specifically, the outlet port 317 and the outlet port 318 may be located between the anode port 311 and the safety valve 313 . It can be understood that, in some possible implementation manners, both the outgoing port 317 and the outgoing port 318 may be BMA connectors.
采用本申请的实施例,通过将电池监测装置(包括多个传感器和处理器)嵌入电池装置的内部,可以在有限影响电池的各项电化学性能的情况下,能够灵敏的监测电池内部的温度、应力和气压等参数,并可以迅速的将这些信号输出至外部装置。此外,即使从电池装置的内部引出线路,该电池装置仍然具有良好的密封性。由此,本申请实施例的电池装置的内部具有状态可测且安全可控的特性。Using the embodiments of the present application, by embedding the battery monitoring device (including multiple sensors and processors) inside the battery device, the temperature inside the battery can be sensitively monitored with limited influence on the electrochemical performance of the battery , stress and air pressure and other parameters, and can quickly output these signals to external devices. In addition, even if the wiring is drawn out from the inside of the battery device, the battery device still has good airtightness. Therefore, the interior of the battery device in the embodiment of the present application has characteristics of state measurability, safety and controllability.
以下进一步介绍本申请实施例的电池装置100的制作方法。The following further introduces the manufacturing method of the battery device 100 according to the embodiment of the present application.
如图16所示,首先,将电池监测装置10(包括多个传感器和处理器)放置在电芯20的负极最后一片负极极片201上,并且从所述电池监测装置10的第一处理线路417和第二处理线路418引出线路,由于所述电池装置100的极片的片数较多,因此需将正极极耳211和负极极耳212进行预焊。如图17所示,再将电池装置100的正极极耳211焊接在正极连接片213,所述负极极耳212焊接在负极连接片214,其中,所述正极连接片213的材质可以为铝,所述负极连接片214的材质可以为铜镀镍。如图18所示,接着再将所述正极极耳211和所述负极极耳212与所述电池装置100的盖板31上的正极极柱321与负极极柱322进行焊接。如图19所示,将极组50(包括电芯及电池监测装置)置入所述壳体30,并与所述盖板31进行焊接。接着从所述注液孔314处注入电解液,化成和抽气,并进行密封注液孔(即对注液孔314进行焊接)。可以理解,图7所示的实施例(即电池监测装置嵌入在电芯与电芯之间)与图9所示的实施例(即电池监测装置嵌入在壳体与电芯之间)的电池装置,其制作方法可以和上述的制作方法相同,在此不再赘述。As shown in FIG. 16 , first, the battery monitoring device 10 (comprising a plurality of sensors and processors) is placed on the last negative electrode sheet 201 of the negative electrode of the battery cell 20, and the first processing circuit of the battery monitoring device 10 417 and the second processing circuit 418 lead out the lines. Since the battery device 100 has a large number of pole pieces, it is necessary to pre-weld the positive pole tab 211 and the negative pole tab 212 . As shown in FIG. 17 , the positive tab 211 of the battery device 100 is welded to the positive connecting piece 213, and the negative tab 212 is welded to the negative connecting piece 214, wherein the material of the positive connecting piece 213 can be aluminum. The material of the negative electrode connecting sheet 214 may be nickel-plated copper. As shown in FIG. 18 , the positive pole tab 211 and the negative pole tab 212 are then welded to the positive pole pole 321 and the negative pole pole 322 on the cover plate 31 of the battery device 100 . As shown in FIG. 19 , the pole group 50 (including the battery cell and the battery monitoring device) is put into the casing 30 and welded with the cover plate 31 . Then inject the electrolyte from the liquid injection hole 314, form and extract gas, and seal the liquid injection hole (that is, weld the liquid injection hole 314). It can be understood that the embodiment shown in FIG. 7 (that is, the battery monitoring device is embedded between the cells) and the embodiment shown in FIG. 9 (that is, the battery monitoring device is embedded between the casing and the cells) The manufacturing method of the device can be the same as the above-mentioned manufacturing method, and will not be repeated here.
以下将介绍本申请实施例的电池装置100的3种线路引出方案。Three wiring schemes of the battery device 100 in the embodiment of the present application will be introduced below.
第一种线路引出方案为:如图20所示,所述电池监测装置10的第二处理线路418可以从所述电池装置100的负极端口312处引出(引出位置1处),所述电池监测装置10的第一处理线路417可以从位于正极连接片213与负极连接片214之间处引出(即引出位置2处)。接着,可以再从相应的位置处导出。例如,该第一处理线路417可以从引出端口315导出,该第二处理线路418可以和该电池装置100的负极端口312一起导出。可以理解,所述盖板31的负极端口312可以是一种带打孔的端口。该负极端口312的设计留有电芯的负极极耳焊接位置和孔,由此可以引出处理器线路,该孔可以带有一层绝缘套,可以防止线路接触。The first line lead-out solution is: as shown in FIG. 20 , the second processing line 418 of the battery monitoring device 10 can be lead out from the negative port 312 of the battery device 100 (leading position 1), and the battery monitor The first processing circuit 417 of the device 10 can be led out from a place located between the positive connecting piece 213 and the negative connecting piece 214 (ie leading out position 2). Then, it can be exported again from the corresponding position. For example, the first processing line 417 can be led out from the outlet port 315 , and the second processing line 418 can be led out together with the negative port 312 of the battery device 100 . It can be understood that the negative terminal 312 of the cover plate 31 may be a perforated port. The design of the negative terminal 312 has a welding position and a hole for the negative tab of the battery core, so that the processor line can be drawn out, and the hole can be provided with a layer of insulating sleeve to prevent the line from contacting.
第二种线路引出方案为:如图21所示,该电池监测装置10的第一处理线路417和第二处理线路418可以从位于正极连接片213与负极连接片214之间 处引出(即引出位置2处)。接着,可以再从相应的位置处导出。例如,该电池监测装置10的第一处理线路417和第二处理线路418可以从该同轴接头316导出。The second line drawing scheme is: as shown in FIG. 21 , the first processing line 417 and the second processing line 418 of the battery monitoring device 10 can be drawn out from the place between the positive connecting piece 213 and the negative connecting piece 214 (that is, lead out position 2). Then, it can be exported again from the corresponding position. For example, the first processing line 417 and the second processing line 418 of the battery monitoring device 10 can be led out from the coaxial connector 316 .
第三种线路引出方案为:如图22所示,该电池监测装置10的第一处理线路417和第二处理线路可以从位于正极连接片213与负极连接片214之间处引出(即引出位置2处)。接着,可以再从相应的位置处导出。例如,该电池监测装置10的第一处理线路417和第二处理线路418分别从引出端口317和引出端口318导出。The third line drawing scheme is: as shown in FIG. 22 , the first processing line 417 and the second processing line of the battery monitoring device 10 can be drawn out from between the positive connecting piece 213 and the negative connecting piece 214 (that is, the leading out position 2 locations). Then, it can be exported again from the corresponding position. For example, the first processing circuit 417 and the second processing circuit 418 of the battery monitoring device 10 are respectively derived from the outgoing port 317 and the outgoing port 318 .
采用本申请实施例中的电池监测装置及电池装置,通过将电池监测装置(包括多个传感器和处理器)嵌入电池装置的内部,可以在有限影响电池的电化学性能情况下,灵敏的监测电池内部的温度、应力和气压等参数,并能够迅速的将这些信号输出给外部装置,由此可以实现对电芯状态的实时监控,实时预警电芯存在的问题。此外,本申请实施例的技术方案增加了电池的安全性和可靠性,可以在电池发生异常的时候,能够迅速反馈并且告警,保护用户的生命安全。By using the battery monitoring device and the battery device in the embodiment of the present application, by embedding the battery monitoring device (including multiple sensors and processors) inside the battery device, it is possible to sensitively monitor the battery with limited influence on the electrochemical performance of the battery. Internal parameters such as temperature, stress, and air pressure can quickly output these signals to external devices, so that real-time monitoring of the state of the battery can be realized, and real-time warnings of problems with the battery can be realized. In addition, the technical solution of the embodiment of the present application increases the safety and reliability of the battery, and can quickly feedback and give an alarm when the battery is abnormal, so as to protect the life safety of the user.
以上所述,仅是本申请的较佳实施方式而已,并非对本申请任何形式上的限制,虽然本申请已是较佳实施方式揭露如上,并非用以限定本申请,任何熟悉本专业的技术人员,在不脱离本申请技术方案范围内,当可利用上述揭示的技术内容做出些许更动或修饰为等同变化的等效实施方式,但凡是未脱离本申请技术方案内容,依据本申请的技术实质对以上实施方式所做的任何简单修改、等同变化与修饰,均仍属于本申请技术方案的范围内。The above is only a preferred implementation mode of the application, and is not intended to limit the application in any form. Although the application is a preferred implementation mode disclosed above, it is not intended to limit the application. Any skilled person familiar with this field , without departing from the scope of the technical solution of the present application, when the technical content disclosed above can be used to make some changes or be modified into equivalent implementations with equivalent changes, but as long as it does not depart from the technical solution of the present application, according to the technical content of the present application In essence, any simple modification, equivalent change and modification made to the above embodiments still fall within the scope of the technical solution of the present application.

Claims (13)

  1. 一种电池监测装置,用于监测电池装置中电芯的状态,其特征在于,所述电池监测装置包括多个传感器、处理器以及处理线路;A battery monitoring device, used for monitoring the state of the battery cell in the battery device, characterized in that the battery monitoring device includes a plurality of sensors, a processor and a processing circuit;
    所述多个传感器用于感测所述电芯的多种参数;The plurality of sensors are used to sense various parameters of the battery cell;
    所述处理器电连接所述多个传感器,并用于接收所述多种参数,以根据所述多种参数确定所述电芯的状态信息;The processor is electrically connected to the plurality of sensors, and is configured to receive the various parameters, so as to determine the state information of the battery cell according to the various parameters;
    所述处理线路电连接于所述处理器,所述处理线路包括第一处理线路和第二处理线路,所述第一处理线路和所述第二处理线路均用于将所述电芯的状态信息上报给外部装置。The processing circuit is electrically connected to the processor, and the processing circuit includes a first processing circuit and a second processing circuit, and both the first processing circuit and the second processing circuit are used to convert the state of the electric core The information is reported to an external device.
  2. 如权利要求1所述的电池监测装置,其特征在于,The battery monitoring device according to claim 1, wherein:
    所述第一处理线路从所述电池装置上的一个第一引出端口导出,所述第二处理线路与所述电池装置的负极端口一起导出。The first processing line is led out from a first lead-out port on the battery device, and the second processing line is led out together with the negative terminal of the battery device.
  3. 如权利要求1所述的电池监测装置,其特征在于,The battery monitoring device according to claim 1, wherein:
    所述第一处理线路和所述第二处理线路均从所述电池装置上的同轴接头导出。Both the first processing line and the second processing line are led out from coaxial connectors on the battery device.
  4. 如权利要求1所述的电池监测装置,其特征在于,The battery monitoring device according to claim 1, wherein:
    所述第一处理线路从所述电池装置上的第二引出端口导出,所述第二处理线路从所述电池装置上的第三引出端口导出。The first processing circuit is derived from a second outlet port on the battery device, and the second processing circuit is derived from a third outlet port on the battery device.
  5. 如权利要求1-4任意一项所述的电池监测装置,其特征在于,The battery monitoring device according to any one of claims 1-4, characterized in that,
    所述多个传感器包括温度传感器、压力传感器、电压传感器、电流传感器、气压传感器或气体传感器中的至少一种。The plurality of sensors includes at least one of a temperature sensor, a pressure sensor, a voltage sensor, a current sensor, a barometric pressure sensor or a gas sensor.
  6. 一种电池装置,其特征在于,所述电池装置包括多个电芯、壳体以及如权利要求1-5任意一项所述的电池监测装置,其中,所述电芯及所述电池监测装置收容于所述壳体内。A battery device, characterized in that the battery device includes a plurality of battery cells, a casing, and the battery monitoring device according to any one of claims 1-5, wherein the battery cells and the battery monitoring device housed in the housing.
  7. 如权利要求6所述的电池装置,其特征在于,The battery device according to claim 6, wherein,
    所述电芯包括多个依次叠加的负极极片、隔膜或者固态电解质和正极极片,所述电池监测装置设置于所述电芯的最后一片负极极片上。The cell includes a plurality of sequentially stacked negative pole pieces, separators or solid electrolytes and positive pole pieces, and the battery monitoring device is arranged on the last negative pole piece of the battery core.
  8. 如权利要求6所述的电池装置,其特征在于,The battery device according to claim 6, wherein,
    所述电池监测装置设置于两个电芯之间。The battery monitoring device is arranged between two batteries.
  9. 如权利要求6所述的电池装置,其特征在于,The battery device according to claim 6, wherein,
    所述电池监测装置设置于所述电芯与所述壳体之间。The battery monitoring device is arranged between the battery core and the casing.
  10. 如权利要求6-9任意一项所述的电池装置,其特征在于,The battery device according to any one of claims 6-9, characterized in that,
    所述壳体包括盖板,所述盖板上设置正极端口、负极端口以及安全阀,所述安全阀位于所述正极端口与所述负极端口之间,所述安全阀用于将所述电池装置内的气体排出。The housing includes a cover plate, on which a positive port, a negative port, and a safety valve are arranged, and the safety valve is located between the positive port and the negative port, and the safety valve is used for disabling the battery The gas in the device is exhausted.
  11. 如权利要求10所述的电池装置,其特征在于,The battery device according to claim 10, wherein,
    所述盖板还设有第一引出端口,所述电池监测装置的第一处理线路从所述 电池装置上的一个第一引出端口导出,所述第二线处理线路与所述电池装置的负极端口一起导出。The cover plate is also provided with a first lead-out port, the first processing line of the battery monitoring device is led out from a first lead-out port on the battery device, and the second line processing line is connected to the negative port of the battery device Export together.
  12. 如权利要求10所述的电池装置,其特征在于,The battery device according to claim 10, wherein,
    所述盖板上还设有同轴接头,所述电池监测装置的第一处理线路和第二处理线路均从所述同轴接头导出。A coaxial connector is also provided on the cover, and the first processing circuit and the second processing circuit of the battery monitoring device are both led out from the coaxial connector.
  13. 如权利要求10所述的电池装置,其特征在于,The battery device according to claim 10, wherein,
    所述盖板上还设有第二引出端口及第三引出端口,所述第一处理线路从所述第二引出端口导出,所述第二处理线路从所述第三引出端口导出。The cover plate is also provided with a second lead-out port and a third lead-out port, the first processing circuit is led out from the second lead-out port, and the second processing circuit is led out from the third lead-out port.
PCT/CN2022/092226 2021-08-27 2022-05-11 Battery monitoring apparatus and battery apparatus WO2023024580A1 (en)

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CN113258147A (en) * 2021-03-30 2021-08-13 清华大学 Intelligent battery

Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
WO2012062574A1 (en) * 2010-11-10 2012-05-18 Continental Automotive Gmbh Battery cell, method for producing a battery cell and use of a battery cell
CN109818091A (en) * 2019-01-25 2019-05-28 深圳瑞隆新能源科技有限公司 A kind of lithium ion battery
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CN113258147A (en) * 2021-03-30 2021-08-13 清华大学 Intelligent battery

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