CN108511783A - A kind of lithium battery - Google Patents

A kind of lithium battery Download PDF

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Publication number
CN108511783A
CN108511783A CN201710108816.XA CN201710108816A CN108511783A CN 108511783 A CN108511783 A CN 108511783A CN 201710108816 A CN201710108816 A CN 201710108816A CN 108511783 A CN108511783 A CN 108511783A
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CN
China
Prior art keywords
fiber grating
lithium battery
battery
lithium
negative plate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710108816.XA
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Chinese (zh)
Inventor
邱伯谦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changsha Juneng new energy Co.,Ltd.
Original Assignee
Hunan Miaosheng Automobile Power Supply Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hunan Miaosheng Automobile Power Supply Co Ltd filed Critical Hunan Miaosheng Automobile Power Supply Co Ltd
Priority to CN201710108816.XA priority Critical patent/CN108511783A/en
Publication of CN108511783A publication Critical patent/CN108511783A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/41Refractivity; Phase-affecting properties, e.g. optical path length
    • G01N21/43Refractivity; Phase-affecting properties, e.g. optical path length by measuring critical angle
    • G01N21/431Dip refractometers, e.g. using optical fibres
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4285Testing apparatus
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/48Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
    • H01M10/484Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte for measuring electrolyte level, electrolyte density or electrolyte conductivity
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/61Types of temperature control
    • H01M10/615Heating or keeping warm
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/62Heating or cooling; Temperature control specially adapted for specific applications
    • H01M10/623Portable devices, e.g. mobile telephones, cameras or pacemakers
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/41Refractivity; Phase-affecting properties, e.g. optical path length
    • G01N21/43Refractivity; Phase-affecting properties, e.g. optical path length by measuring critical angle
    • G01N21/431Dip refractometers, e.g. using optical fibres
    • G01N2021/432Dip refractometers, e.g. using optical fibres comprising optical fibres
    • G01N2021/433Dip refractometers, e.g. using optical fibres comprising optical fibres with an unclad part on the fibre
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Abstract

A kind of lithium battery, including battery core and shell, battery core are arranged inside the shell, and battery core includes positive plate, negative plate and diaphragm, it is characterised in that fiber grating ion concentration sensor is provided between the positive plate or/and negative plate and diaphragm.The superiority of the present invention is that the charging and discharging state of lithium battery in reaction process is judged with monitoring lithium concentration, can directly and accurately judge the electrochemical process of battery.

Description

A kind of lithium battery
(1) technical field
The present invention relates to a kind of lithium battery, more particularly to a kind of lithium battery of built-in detection ion concentration sensor.
(2) background technology
Lithium battery have many advantages, such as voltage it is high, it is higher than energy, recycle often, storage time it is long, not only portable Such as mobile phone, DV and laptop computer is used widely on formula electronic equipment, and is widely used in electronic In terms of the large and medium-sized electrical equipment such as automobile, electric bicycle and electric tool, therefore the performance requirement of lithium ion battery is got over Come higher.The internal structure of lithium battery is made of positive and negative electrode piece and diaphragm, and battery will produce largely in use Heat influences the cycle life and safety of its battery, is especially affected to high capacity cell, monitors in lithium battery in real time Portion's electrochemical reaction situation is the key that judge battery health.All be in the prior art by react regulation in other Feed back the working condition, such as temperature, voltage etc. of indirect gain lithium battery.Therefore, a kind of novel built-in detection ion is studied Concentration sensor has been to be badly in need of.
(3) invention content
The present invention provide in view of the above shortcomings of the prior art it is a kind of can realize inside battery lithium concentration monitoring Lithium battery.
Used technical solution is the present invention in order to solve the above problem:A kind of lithium battery, including battery core and shell, battery core Inside the shell, battery core includes positive plate, negative plate and diaphragm for setting, it is characterised in that the positive plate or negative plate and diaphragm it Between be provided with fiber grating ion concentration sensor.The superiority of the present invention is to judge reaction process with monitoring lithium concentration The charging and discharging state of middle lithium battery can directly and accurately judge the electrochemical process of battery.
Upon charging and discharging the battery, lithium ion swaps between positive and negative electrode, the microporous membrane between positive/negative plate The charge status of lithium battery can be reacted by lithium ion, the lithium concentration on diaphragm both sides, when its lithium concentration When occurring abnormal, indicates that exception occurs in the cyclic process of battery, also imply the problems such as thermal runaway will occur for battery.Just Setting monitoring ion concentration sensor, can understand the spread condition of lithium ion, judge battery in real time between negative plate and diaphragm Working condition, to the preferably thermal runaway of control battery and other battery events.
As the development of fiber grating and increasingly maturation, the application field of manufacturing technology are more and more extensive.Due to optical fiber Grating is vulnerable to the influence of extraneous refractive index, and its sensitivity is higher, has begun to be applied to solution concentration detection.By optical fiber light Gate sensor is combined with the luminous effect of liquid, realizes the detection to strength of fluid.Fiber grating as concentration sensor be by Sensing grating is with after electrolyte contacts, and in the electrochemical process of the charge and discharge of lithium battery, lithium concentration is between positive and negative anodes Deintercalation process constantly changes, and due to the variation of its concentration, the signal that luminous effect generates changes.By the packet of fiber grating After layer does chemical attack processing, by fluid to be measured directly as the covering of fiber grating, when the refractive index or concentration of fluid to be measured When variation, the variation of reflective optical disc is also resulted in, using this principle, can also realize the measurement of liquid refractivity or concentration, To realize the detection of ion concentration.
The present invention also has the following advantages that and advantageous effect:
1. realizing the real time monitoring to lithium battery group, the working condition of lithium battery can be monitored in real time.
2. realizing the safety management to lithium battery group, battery life is increased.Provide Security Strategies and equilibrium Management makes battery keep preferable consistency, can effectively improve the service life of battery.
The present invention is characterized in that the lithium concentration sensor is arranged between positive plate and diaphragm.In this way, lithium from Sub- concentration sensor is used to monitor the spread condition of the lithium concentration in electrolyte between positive plate and diaphragm, detects positive material The situation of change of material.
The present invention is characterized in that the lithium concentration sensor is arranged between negative plate and diaphragm.In this way, due to Cathode needs to keep certain lithium concentration just to can guarantee the stability of electrode slice structure, and lithium ion is arranged in this side of cathode Concentration sensor obtains lithium concentration value in time, and lithium ion is excessive when can prevent from putting moves out.
The present invention, which is further characterized in that between positive plate or negative plate and diaphragm, is provided with heating component, and heating component includes The one side of the positive plate and negative plate of heating plate, one side coating electrode material, positive plate and the uncoated coating of negative plate is pasted respectively Together in the two sides of heating plate.In this way, when battery temperature is too low, heating component can heat in time.Heating component has structure letter Single, reasonable design, simple production process, fever is uniform, heat converts the advantages that fast, the efficiency of heating surface is high.
The present invention is characterized in that the end of the connecting lead wire of heating component is provided with connector.In this way, in convenient and battery The connection of each component in portion.
The present invention is characterized in that lithium concentration sensor is arranged in heating component.Exist in this way, having saved sensor Space shared by inside battery will be preferably minimized the influence of the electrochemical process of battery.
The present invention is characterized in that the connecting lead wire end of lithium concentration sensor is provided with connector.In this way, facilitating lithium Ion concentration sensor is convenient to be connect with battery other component.
The present invention is characterized in that two-direction closed interface inside and outside the closure part of the shell, built-in end interface is for connecting The connector of lithium concentration sensor or the connector of heating component are connect, external end interface is used to connect with detection and analysis equipment.This Sample facilitates each component to connect.
The present invention is characterized in that lithium concentration sensor is directly placed between positive plate or negative plate and diaphragm.This Sample is easily installed and fixes.
The present invention is characterized in that lithium concentration sensor is fixed on positive plate or negative plate.In this way, can stablize Sensor prevents it from being moved in inside battery.
The present invention is characterized in that the material of positive plate coating layer is LiFePO4, cobalt acid lithium or ternary material.
The present invention is characterized in that the material of negative plate coating layer is graphite material.
(4) it illustrates
Fig. 1 is the structural schematic diagram of the embodiment of the present invention 1.
Fig. 2 is fiber grating ion concentration sensor schematic diagram.
Fig. 3 is position view of the fiber grating ion concentration sensor in lithium battery.
Fig. 4 is the structural schematic diagram of the embodiment of the present invention 2.
Fig. 5 is the vertical view of Fig. 4.
Fig. 6 is the structural schematic diagram of the embodiment of the present invention 3.
In figure, 1, battery core, 2, shell, 3, positive plate, 4, negative plate, 5, diaphragm, 6, fiber grating ion concentration sensor, 7, hush panel, 8, connector, 9, bidirectional interface, end interface built in 10,11, external end interface.
(5) specific implementation mode
Invention is further described in detail below in conjunction with the accompanying drawings.
As shown in Figure 1, 2, 3, a kind of lithium battery, including battery core 1 and shell 2, battery core 1 are arranged in shell 2, and battery core 1 is wrapped Positive plate 3, negative plate 4 and diaphragm 5 are included, diaphragm 5 is separated positive plate 3 and the insulation of negative plate 4 with Z-shaped winding method, positive and negative Lug is provided on pole piece, shell 2 includes shell top and shell, and pole and interface holes are provided at the top of shell.Positive plate 3 described in Fig. 1 Fiber grating ion concentration sensor 6 is provided between diaphragm 5.Fig. 2 is 6 structure of fiber grating ion concentration sensor, Fig. 3 It is shown position of the fiber grating ion concentration sensor in battery core, one end is provided with connector 8.
The present invention be further characterized in that the fiber grating ion concentration sensor 6 setting negative plate 4 and diaphragm 5 it Between.Battery core 1 as shown in Figure 4,5 includes positive plate 3, negative plate 4 and diaphragm 5, and diaphragm 5 is with Z-shaped winding method by 3 He of positive plate The insulation of negative plate 4 separates, and lug is provided on positive/negative plate, fiber grating ion is provided between the negative plate 4 and diaphragm 5 Concentration sensor 6.
The present invention is further characterized in that the shell 2, and shown in Fig. 6, shell 2 includes shell top and shell, the hush panel 7 on shell top It is provided with enclosed bidirectional interface 9, built-in end interface 10 is used to connect the connector 8 of fiber grating ion concentration sensor 6, outside End interface 11 is set for being connect with detection and analysis equipment.
The present invention be further characterized in that fiber grating ion concentration sensor 6 be directly placed at positive plate 3 or negative plate 4 with Between diaphragm 5.
The present invention is further characterized in that fiber grating ion concentration sensor 6 is fixed on positive plate 3 or negative plate 4.
The present invention is further characterized in that the material of positive plate coating layer is LiFePO4, cobalt acid lithium or ternary material.
The present invention is further characterized in that the material of negative plate coating layer is graphite material.

Claims (8)

1. a kind of lithium battery, including battery core (1) and shell (2), in shell (2), battery core (1) includes anode for battery core (1) setting Piece (3), negative plate (4) and diaphragm (5), it is characterised in that set between the positive plate (3) or/and negative plate (4) and diaphragm (5) It is equipped with fiber grating ion concentration sensor (6).
2. lithium battery according to claim 1, it is characterised in that fiber grating ion concentration sensor (6) is fixed on anode On piece (3) or/and negative plate (4).
3. lithium battery according to claim 2, it is characterised in that fiber grating ion concentration sensor (6) setting exists Positive plate (3) or/and negative plate (4) central area.
4. the lithium battery according to any claim in claims 1 to 3, it is characterised in that the fiber grating ion is dense Sensor (6) is spent to be arranged at the hush panel (7) of battery case (2).
5. the lithium battery according to any claim in claims 1 to 3, it is characterised in that fiber grating ion concentration passes The end of sensor (6) is provided with connector (8).
6. lithium battery according to claim 5, it is characterised in that the closure part of the shell (2) is provided with enclosed Bidirectional interface (9), built-in end interface (10) are used to connect the connector (8) of fiber grating ion concentration sensor (6), external termination Mouth (11) is used to connect with detection and analysis equipment.
7. the lithium battery according to any claim in claims 1 to 3, it is characterised in that positive plate (3) coating layer Material is ferric phosphate fiber grating, cobalt acid fiber grating or ternary material.
8. the lithium battery according to any claim in claims 1 to 3, it is characterised in that negative plate (4) coating layer Material is graphite material.
CN201710108816.XA 2017-02-27 2017-02-27 A kind of lithium battery Pending CN108511783A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710108816.XA CN108511783A (en) 2017-02-27 2017-02-27 A kind of lithium battery

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Application Number Priority Date Filing Date Title
CN201710108816.XA CN108511783A (en) 2017-02-27 2017-02-27 A kind of lithium battery

Publications (1)

Publication Number Publication Date
CN108511783A true CN108511783A (en) 2018-09-07

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109830770A (en) * 2019-02-18 2019-05-31 中南大学 Vast capacity energy storage lithium ion battery with monitoring function
CN110007241A (en) * 2019-05-07 2019-07-12 中国科学技术大学 Lithium ion battery thermal runaway jet stream experimental provision
CN112054254A (en) * 2020-08-18 2020-12-08 暨南大学 Battery optical fiber in-situ detection system and method
CN113258182A (en) * 2020-02-12 2021-08-13 比亚迪股份有限公司 Battery, battery module, battery pack and electric vehicle
CN113346199A (en) * 2021-04-13 2021-09-03 华中科技大学 Integrated optical fiber tab, preparation method and application

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101355180A (en) * 2008-09-09 2009-01-28 吉安市优特利科技有限公司 Electric core construct for lithium ion power cell
CN204705615U (en) * 2015-06-11 2015-10-14 石河子开发区智睿博创科技有限公司 A kind of sensor automatically can monitoring potassium concentration in feedback solution
CN105762401A (en) * 2016-01-07 2016-07-13 小牛动力(武汉)新能源技术有限公司 Lithium ion power battery and utilization method thereof
CN105789525A (en) * 2016-05-18 2016-07-20 小牛动力(武汉)新能源技术有限公司 Optical fiber sensor embedded type battery diaphragm and usage thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101355180A (en) * 2008-09-09 2009-01-28 吉安市优特利科技有限公司 Electric core construct for lithium ion power cell
CN204705615U (en) * 2015-06-11 2015-10-14 石河子开发区智睿博创科技有限公司 A kind of sensor automatically can monitoring potassium concentration in feedback solution
CN105762401A (en) * 2016-01-07 2016-07-13 小牛动力(武汉)新能源技术有限公司 Lithium ion power battery and utilization method thereof
CN105789525A (en) * 2016-05-18 2016-07-20 小牛动力(武汉)新能源技术有限公司 Optical fiber sensor embedded type battery diaphragm and usage thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109830770A (en) * 2019-02-18 2019-05-31 中南大学 Vast capacity energy storage lithium ion battery with monitoring function
CN110007241A (en) * 2019-05-07 2019-07-12 中国科学技术大学 Lithium ion battery thermal runaway jet stream experimental provision
CN113258182A (en) * 2020-02-12 2021-08-13 比亚迪股份有限公司 Battery, battery module, battery pack and electric vehicle
WO2021159995A1 (en) * 2020-02-12 2021-08-19 比亚迪股份有限公司 Battery, battery module, battery pack and electric vehicle
CN113258182B (en) * 2020-02-12 2022-10-18 比亚迪股份有限公司 Battery, battery module, battery pack and electric vehicle
CN112054254A (en) * 2020-08-18 2020-12-08 暨南大学 Battery optical fiber in-situ detection system and method
CN112054254B (en) * 2020-08-18 2022-02-18 暨南大学 Battery optical fiber in-situ detection system and method
CN113346199A (en) * 2021-04-13 2021-09-03 华中科技大学 Integrated optical fiber tab, preparation method and application
CN113346199B (en) * 2021-04-13 2022-10-04 华中科技大学 Integrated optical fiber tab, preparation method and application

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Effective date of registration: 20210121

Address after: Room 702, superstar entrepreneurial base, No.8 Lujing Road, Changsha high tech Development Zone, Changsha City, Hunan Province, 410205

Applicant after: Changsha Juneng new energy Co.,Ltd.

Address before: Room 706, superstar entrepreneurial base, No.8 Lujing Road, high tech Development Zone, Changsha City, Hunan Province, 410205

Applicant before: HUNAN MIAOSHENG AUTOMOBILE POWER Co.,Ltd.