WO2023010779A1 - Button cell assembly and electronic device - Google Patents

Button cell assembly and electronic device Download PDF

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Publication number
WO2023010779A1
WO2023010779A1 PCT/CN2021/141437 CN2021141437W WO2023010779A1 WO 2023010779 A1 WO2023010779 A1 WO 2023010779A1 CN 2021141437 W CN2021141437 W CN 2021141437W WO 2023010779 A1 WO2023010779 A1 WO 2023010779A1
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WO
WIPO (PCT)
Prior art keywords
electrode
metal
layer
bonding
button battery
Prior art date
Application number
PCT/CN2021/141437
Other languages
French (fr)
Chinese (zh)
Inventor
张丰学
夏祖见
Original Assignee
国研新能(深圳)技术有限公司
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Publication of WO2023010779A1 publication Critical patent/WO2023010779A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/102Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure
    • H01M50/109Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure of button or coin shape
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/04Construction or manufacture in general
    • H01M10/0422Cells or battery with cylindrical casing
    • H01M10/0427Button cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/147Lids or covers
    • H01M50/148Lids or covers characterised by their shape
    • H01M50/153Lids or covers characterised by their shape for button or coin cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/147Lids or covers
    • H01M50/155Lids or covers characterised by the material
    • H01M50/164Lids or covers characterised by the material having a layered structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/147Lids or covers
    • H01M50/166Lids or covers characterised by the methods of assembling casings with lids
    • H01M50/169Lids or covers characterised by the methods of assembling casings with lids by welding, brazing or soldering
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00Batteries for particular applications
    • H01M2220/30Batteries in portable systems, e.g. mobile phone, laptop
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Definitions

  • the main purpose of the present invention is to propose a button battery assembly, aiming at solving the technical problem of how to reduce the damage of the button battery when it is installed in electric equipment.
  • the wire connection seat includes an external connection plate and a conductive ring
  • the button battery includes an electric core, a metal casing and a cover shell sealedly connected with the metal casing;
  • the external connection plate includes an insulating body, a metal elastic structure, at least one first electrode metal connection area and at least one second electrode metal connection area;
  • the insulating body has a conduction surface and an outer contact surface arranged opposite to each other, the conduction surface is provided with the metal elastic structure for electrically contacting the outer conductive part when elastic compression occurs, and the outer contact surface is provided with at least one said first electrode metal connection area and at least one said second electrode metal connection area;
  • At least one metal connection region of the first electrode is electrically connected to the metal elastic structure
  • At least one metal connection area of the second electrode is electrically connected to the conductive ring.
  • the insulating bonding middle layer is made of one or more of PP, PFA, PVDF, PTFE, ETFE and PVC.
  • the bonding strength between the middle insulating bonding part, the inner bonding middle part, and the outer bonding part is greater than or equal to 1N per square millimeter and less than or equal to 5N per square millimeter.
  • the metal elastic structure is configured as an annular metal spring.
  • the contact position between the metal elastic structure and the conductive outer layer is located at the position corresponding to the bonding side of the insulating bonding middle layer and the welding inner layer.
  • the present invention divides the cover shell of the button battery into a conductive outer layer, an insulating bonding middle layer and a welding inner layer, wherein the conductive outer layer is electrically connected to one pole of the battery cell, and the welding inner layer is electrically connected to the other pole of the battery cell. After the inner welding side part of the welding inner layer is welded to the opening end of the metal shell, the packaging of the electric core can be realized.
  • the metal shell Since the welding inner layer and the conductive outer layer are insulated through the insulating bonding middle layer, the metal shell will also be insulated from the conductive outer layer, thereby preventing the two electrodes of the cell from conducting and short circuiting each other;
  • the layer has been pre-insulated, so when the cover shell is packaged with the metal shell, only the inner layer and the metal shell need to be welded, and there is no need to install an insulating film, which can simplify the battery packaging process and improve packaging efficiency.
  • the insulating body and the conductive ring of the wire connection seat are surrounded to form a mounting groove for the fixed installation of the boss of the button battery.
  • the ring abuts against each other, so that the first electrode metal connection area on the outer contact surface conducts with one electrode of the button battery, and the second electrode metal connection area conducts with the other electrode of the button battery.
  • the first electrode metal connection area and the second electrode metal connection area are used for welding or abutting contact of the positive and negative electrode wires of the electrical equipment, and the electrode wires of the electrical equipment are connected to the first electrode metal connection area and the second electrode metal After the area is welded, it can conduct with the electrode of the button battery, so as to realize the electrical conduction between the electrical equipment and the button battery.
  • the insulating and bonding middle layer of the cover shell is a glue layer structure, if the electrode wires of the electrical equipment are directly welded to the cover shell, the high temperature during the welding process will destroy the insulating and bonding middle layer, resulting in ineffective insulation or bonding.
  • connection seat can reduce the damage of the button battery application to reduce the scrap rate; in addition, the metal elastic structure can exert an inward cover shell pressure F1 on the conductive outer layer, and the metal shell will produce outward support on the welded inner layer Therefore, the pressure F1 of the cover will make the conductive outer layer and the welding inner layer clamp the insulating bonding middle layer, so as to prevent the gas generated inside the button battery from breaking away the bonding between the insulating bonding middle layer and the conductive outer layer or the welding inner layer , Also avoid the separation of the bonding between the insulating bonding middle layer and the conductive outer layer or the welding inner layer due to electrolyte corrosion, which can effectively improve the structural stability of the button battery and further extend the service life of the button battery.
  • Fig. 2 is a schematic cross-sectional view of an embodiment of the button battery assembly of the present invention
  • Fig. 3 is a schematic structural view of an embodiment of the wire connection seat in the present invention.
  • Fig. 4 is a structural schematic view of another embodiment of the wire connecting seat in the present invention.
  • FIG. 6 is a schematic cross-sectional view of an embodiment of a button battery in the present invention.
  • the directional indication is only used to explain the position in a certain posture (as shown in the accompanying drawing). If the specific posture changes, the directional indication will also change accordingly.
  • the present invention provides a button battery assembly, which is used for being installed in the main body of electronic equipment containing electric devices to provide electric energy to the electric devices.
  • the button battery assembly includes a wire connection base 10 and a button battery 20;
  • the wire connection base 10 includes an external connection plate 11 and a conductive ring 12;
  • Described button battery 20 comprises electric core 21, metal shell 22 and the cover shell 23 that is connected with described metal shell 22 sealingly;
  • the cover shell 23 includes a conductive outer layer 24, an insulating bonding middle layer 25 and a welding inner layer 26, the welding inner layer 26, and the welding inner layer 26 includes an inner welding side part 261, an inner bonding middle part 262 and an inner through hole.
  • the hole part 263, the insulating bonding middle layer 25 includes the middle insulating bonding part 251 and the through hole part 252
  • the conductive outer layer 24 includes the outer bonding part 241 and the outer conductive part 242, and the inner welding side part 261
  • the middle insulating bonding part 251 is melted by an insulating and electrolyte-resistant material with a thermal shrinkage rate of 6% or less at a temperature of 100°C or higher, and then bonded to the inner
  • the middle part 262 and the outer bonding part 241 are seamlessly bonded, and the bonding strength between the inner bonding middle part 262 and the outer bonding part 241 is greater than or equal to 0.1 N per square millimeter at room temperature ;
  • One pole of the battery cell 21 is electrically connected to the welding inner layer 26, and the other pole of the battery cell 21 is electrically connected to the outer conductive part 242 through the inner through hole part 263 and the middle through hole part 252. ;
  • the metal shell 22 includes a columnar body 221 and an outwardly protruding boss 222;
  • the external connection plate 11 includes an insulating body 13, a metal elastic structure 14, at least one first electrode metal connection area 15 and at least one second electrode metal connection area 16;
  • the insulating body 13 has a conduction surface 131 and an outer contact surface 132 disposed opposite to each other.
  • the conduction surface 131 is provided with the metal elastic structure 14 for electrically contacting the outer conductive part 242 when elastic compression occurs.
  • the external surface 132 is provided with at least one metal connection region 15 of the first electrode and at least one metal connection region 16 of the second electrode;
  • At least one of the first electrode metal connection regions 15 is electrically connected to the metal elastic structure 14;
  • At least one of the second electrode metal connection regions 16 is electrically connected to the conductive ring 12 .
  • the metal shell 22 can be made of stainless steel plate, and the opening of the metal shell 22 faces upwards to accommodate the battery cell 21 and the electrolyte; wherein, the boss 222 is arranged at the opening end of the columnar body 221 and protrudes from the outer periphery of the columnar body 221 wall, and the boss 222 extends along the circumference of the columnar body 221 .
  • the conductive outer layer 24 and the welding inner layer 26 of the cover shell 23 can be made of stainless steel plates, wherein the outer conductive part 242 of the conductive outer layer 24 will pass through the middle through hole part 252 and the inner through hole part 263 towards the inside of the battery case, and use to be connected to one of the electrodes of the battery cell 21 ; the welding inner layer 26 is connected to the other electrode of the battery cell 21 by being connected to the metal shell 22 . Owing to there is the insulating bonding middle layer 25 between the welding inner layer 26 and the conductive outer layer 24, therefore, the welding inner layer 26 is insulated from the conductive outer layer 24, so that the metal shell 22 and the conductive outer layer 24 can be insulated from each other to prevent electric shock.
  • the two electrodes of the core 21 are connected to each other, thus, the conductive outer layer 24 and the metal shell 22 of the cover shell 23 can be respectively formed into two output electrodes of the button battery 20, and the two output electrodes can be prevented from being connected to each other. short circuit.
  • the inner surface of the outer conductive part 242 will pass through the middle through hole part 252 and the inner through hole part 263 towards the inside of the metal shell 22, so as to contact the electrodes of the power supply core 21; connect.
  • the outer conductive part 242 may be located on the top of the middle through hole part 252 and the inner through hole part 263, or may be recessed toward the inside of the metal shell 22, and pass through the middle through hole part 252 and the inner through hole part 263 in sequence. There is no seat restriction, it only needs to satisfy that the outer conductive part 242 can be in contact with the electrode of the battery cell 21 .
  • the shell of the button battery 20 adopts the upper and lower shells, and the middle is a plastic insulating ring.
  • the middle is a plastic insulating ring.
  • the metal shell 22 side wall of the present application can only be one Layer, in the case of the same size casing, the metal casing 22 of the present application increases the available space inside, which is beneficial to increase the capacity of the entire battery.
  • the middle through hole portion 252 of the insulating bonding middle layer 25 corresponds to the inner through hole portion 263 of the welding inner layer 26, so that the outer conductive portion 242 of the conductive outer layer 24 can pass through the middle through hole portion 252 and the inner through hole portion 263 towards the metal shell 22 inside.
  • the middle through-hole portion 252 and the inner through-hole portion 263 can be opened in the middle of the cover shell 23 so that the outer conductive portion 242 can maintain a sufficient distance from each position in the circumferential direction of the columnar body 221 .
  • the electrodes of the battery cell 21 may directly contact the outer conductive portion 242 of the conductive outer layer 24 .
  • the top surface and the bottom surface of the middle insulating bonding portion 251 are bonded to the outer bonding portion 241 and the inner bonding middle portion 262 respectively, so as to realize the insulating connection between the welding inner layer 26 and the conductive outer layer 24 .
  • the welding inner layer 26 is welded and sealed with the metal shell 22 , and the conductive outer layer 24 and the welding inner layer 26 are seamlessly bonded through the insulating bonding middle layer 25 , so that the metal shell 22 can be closed by the cover shell 23 .
  • the welding inner layer 26 and the conductive outer layer 24 have been insulated and connected in advance, so there is no need to additionally provide an insulating film.
  • the insulating bonding middle layer 25 is made of materials with insulating properties and anti-electrolyte corrosion, and its heat shrinkage rate is less than 6% when it is greater than or equal to 100 ° C.
  • the heat shrinkage rate refers to the thermoplastic material due to its inherent thermal expansion rate. That is to say, when the temperature is greater than or equal to 100°C, the volume change of the insulating and bonding middle layer 25 does not exceed 6% of the original volume, so that the insulating and bonding middle layer 25 can be fully melted and bonded with the conductive outer layer 24 It is fully connected with the welding inner layer 26 to ensure the bonding effect.
  • the bonding strength between the insulating bonding middle layer 25 and the outer bonding part 241 and the inner bonding middle part 262 is greater than or equal to 0.1N per square millimeter at normal cooling temperature, which can ensure that the insulating bonding middle layer 25 and the conductive outer layer 24 and the welding inner layer
  • the bonding stability of the layer 26 specifically, the bonding strength between the middle insulating bonding part 251 and the outer bonding part 241 and the inner bonding middle part 262 is greater than or equal to 1N per square millimeter at normal cooling temperature, And be less than or equal to 5.0N/mm2, so as to prevent the internal stress of the cover shell 23 from being too high, thereby avoiding the damage of the cover shell 23 due to internal force during subsequent processing or use.
  • the present invention divides the cover shell 23 of the button battery 20 into a conductive outer layer 24, an insulating and adhesive middle layer 25 and a welding inner layer 26, wherein the conductive outer layer 24 is electrically connected to one pole of the battery cell 21, and the welding inner layer 26 is connected to the electric core 21.
  • the other pole of the core 21 is electrically connected, and after the inner welding side portion 261 of the inner layer 26 is welded to the open end of the metal shell 22 , the packaging of the battery core 21 can be realized.
  • the metal shell 22 will also be insulated from the conductive outer layer 24, thereby preventing the two electrodes of the electric core 21 from conducting and shorting each other; because the cover shell 23 The conductive outer layer 24 and the welding inner layer 26 have been insulated in advance, so when the cover shell 23 is packaged with the metal shell 22, only the welding inner layer 26 and the metal shell 22 need to be welded, and no insulating film is required, which can simplify The packaging process of the battery improves the packaging efficiency.
  • the metal shell 22 and the cover shell 23 of the present application are sealed by welding, which improves the sealing and stability well, instead of relying on physical force extrusion between the shells for sealing, and Since the cover shell 23 is prepared in advance, the insulation is carried out through the middle insulating adhesive part 251, which can improve the insulation, and at the same time, it can play a protective role under certain conditions.
  • the cover shell 23 of the button battery 20 in the present application adopts a three-layer structure, and the stability and reliability of the structure are strengthened.
  • the middle insulating bonding part 251 is between the two layers of stainless steel, it is waterproof and anti-electrolyte corrosion. The properties are all very strong, and the external contact area between the middle insulating bonding portion 251 and the metal shell 22 is very small, which can effectively prevent external moisture from entering the metal shell 22; while the contact area is small, the middle insulating bonding portion 251
  • the length of the path between the outside and the inside of the metal casing 22 is relatively long, which further avoids the influence of external moisture on the battery cell 21 and the electrolyte inside the metal casing 22 .
  • the middle insulating adhesive portion 251 can only contact the electrolyte solution in the button battery 20 at the edge of the middle through hole portion 252, which can effectively reduce the contact between the electrolyte solution and the middle insulating adhesive portion 251. contact area to effectively protect the middle insulating bonding portion 251 and avoid the influence of the electrolyte on the middle insulating bonding portion 251 such as softening and corrosion, thus effectively improving the service life of the battery. Furthermore, the path of the middle insulating bonding portion 251 from the inside of the button battery 20 to the outside of the button battery 20 is also longer, which can further improve the service life of the battery.
  • the insulating body 13 can be a circular plate or a square plate, which is not specifically limited.
  • the first electrode metal connection area 15 is used for the electrode wire welding activity of the electrical equipment to interfere with the contact electrical conduction.
  • the electrode wire of the electrical equipment can be a positive pole line or a negative pole line, which is not limited here; for specific examples, When the first electrode metal connection area 15 is electrically connected to the positive pole of the button battery 20, the positive line of the power supply equipment is welded or resists the electrical connection with it; when the first electrode metal connection area 15 is electrically connected to the negative electrode of the button battery , the negative wire of the power supply equipment is welded or resists contact with it for electrical conduction.
  • the positive pole abuts against the metal elastic structure 14 through the conductive outer layer 24, and the negative pole abuts against the conductive ring 12 through the metal shell 22, that is, the positive pole of the button battery 20 can be connected to the first pole on the insulating body 13.
  • the insulating and bonding middle layer 25 of the cover shell 23 is an adhesive layer structure, if the electrode wires of the electrical equipment are directly welded to the cover shell 23, the high temperature during the welding process will destroy the insulating and bonding middle layer 25, resulting in ineffective insulation or bonding. Therefore, by setting the wire connection base 10, the damage of the button battery 20 during application can be reduced, so as to reduce the scrap rate.
  • the metal elastic structure 14 can also exert an inward pressure F1 of the cover shell 23 on the conductive outer layer 24, and the metal shell 22 will produce an outward support force on the welded inner layer 26, so the pressure F1 of the cover shell 23 will make the conductive
  • the outer layer 24 and the welding inner layer 26 sandwich the insulating and bonding middle layer 25, so as to prevent the gas generated inside the button battery 20 from breaking away the joint between the insulating and bonding middle layer 25 and the conductive outer layer 24 or the welding inner layer 26, and also avoid insulating
  • the bond between the bonding middle layer 25 and the conductive outer layer 24 or the welding inner layer 26 is separated due to electrolyte corrosion, thereby effectively improving the structural stability of the button battery 20 and further prolonging the service life of the button battery 20 .
  • the conductive ring 12 is connected to the outer surface 132, and the outer surface 132 is provided with a contact point 133, and the contact point 133 is connected to the conductive ring 12. and the contact point 133 is electrically connected to the second electrode metal connection region 16 .
  • Two opposite positions on the circumferential direction of the conductive ring 12 are respectively protruded with pinch plates, and the two pinch plates are fastened to the external surface 132 .
  • the pinch plate is used to realize the fixed connection between the conductive ring 12 and the insulating body 13 , and the pinch plate and the conductive ring 12 can be integrally injection-molded to improve structural strength and reduce processing difficulty.
  • the two gussets are connected to two relative positions in the circumferential direction of the conductive ring 12, which can increase the area of the connection part between the conductive ring 12 and the insulating body 13 and the external contact surface 132, so as to improve the connection strength.
  • the pinch plate not only plays the role of supporting the fixed connection, but also transfers the electrical conduction formed by the contact between the conductive ring 12 and the boss 222 of the button battery 20 to the contact point 133, so as to realize the connection between one pole of the button battery 20 and the second pole of the button battery 20.
  • the electrical conduction of the electrode metal connection region 16 can cooperate to improve the conduction stability.
  • the connection between the gusset plate and the contact point 133 is welding to reduce connection difficulty, effectively reduce contact resistance, and improve connection strength.
  • the material of the insulating adhesive middle layer 25 is PP (polypropylene), PFA (copolymer of a small amount of perfluoropropyl perfluorovinyl ether and polytetrafluoroethylene), PVDF (polyvinylidene fluoride) ), PTFE (polytetrafluoroethylene), ETFE (ethylene-tetrafluoroethylene copolymer), PVC (polyvinyl chloride) in one or more.
  • Polyethylene is a thermoplastic resin obtained by polymerization of ethylene. In industry, it also includes copolymers of ethylene and a small amount of ⁇ -olefins. Polyethylene is odorless, non-toxic, feels like wax, has excellent low temperature resistance, good chemical stability, and can withstand most acids and alkalis. Insoluble in common solvents at room temperature, low water absorption, excellent electrical insulation.
  • the modified PP used in this embodiment is a metal-friendly modified polypropylene resin (Metal Adhesive Polypropylene, hereinafter referred to as metal-friendly modified PP), which can be made in the PP
  • metal-friendly modified PP Metal Adhesive Polypropylene
  • the surface On the basis of chemical modification methods such as copolymerization, grafting or cross-linking, the surface has metalophilic properties, so that it can be fused with the metal surface by heating to form a good bonding seal.
  • the Chinese name of PFA is tetrafluoroethylene-perfluoroalkoxy vinyl ether copolymer (also known as perfluoroalkylate, soluble polytetrafluoroethylene), which is a small amount of perfluoropropyl perfluorovinyl ether and polytetrafluoroethylene. of copolymers.
  • the melt adhesion is enhanced, the melt viscosity is reduced, and the performance is unchanged compared with PTFE.
  • This kind of resin can be directly processed into products by ordinary thermoplastic molding methods.
  • the metal elastic structure 14 is configured as an annular metal spring.
  • the annular metal spring can increase the contact area with the conductive outer layer 24, thereby improving the contact stability and ensuring the stability of electrical conduction.
  • the pressure F1 produced by the ring-shaped metal elasticity on the conductive outer layer 24 can act on the conductive outer layer 24 along the ring, so that multiple positions of the conductive outer layer 24 can be pressed and fixed on the insulating adhesive middle layer 25 to increase the compression.
  • the structural stability of the button battery 20 is further improved.
  • the contact position between the metal elastic structure 14 and the conductive outer layer 24 is located at a position corresponding to the side where the insulating adhesive middle layer 25 and the welding inner layer 26 are bonded.
  • the metal elastic structure 14 is close to the periphery of the middle through hole portion 252, so that the pressure generated by the metal elastic structure 14 on the conductive outer layer 24 can accurately act on the bonding seam between the conductive outer layer 24 and the insulating bonding middle layer 25 to prevent insulation.
  • the joint between the adhesive middle layer 25 and the conductive outer layer 24 is corroded and separated, thereby improving the structural stability of the cover shell 23 in the electrolyte.
  • the outer connection surface 132 is provided with one first electrode metal connection region 15 and two second electrode metal connection regions 16, one of which is the The second electrode metal connection region 16 is adjacent to the first electrode metal connection region 15 , and another second electrode metal connection region 16 is disposed on a side opposite to the first electrode metal connection region 15 .
  • the present invention also proposes an electrical device, which includes an electronic device body containing an electrical device and a button battery assembly.
  • the specific structure of the button battery assembly refers to the above-mentioned embodiments. Since this electrical device adopts all the above-mentioned implementations All the technical solutions of the above-mentioned embodiments, therefore at least have all the beneficial effects brought by the technical solutions of the above-mentioned embodiments, and will not be repeated here.
  • the button battery assembly is located in the main body of the electronic equipment, and one pole of the electrical device is electrically connected to the first electrode metal connection area 15; the other pole is electrically connected to the second electrode metal connection area 15. 16 is electrically conductive.

Abstract

Disclosed in the present invention are a button cell assembly and an electronic device. Since an insulation adhesion middle layer of a cap has an adhesive layer structure, if an electrode line of an electric device is directly welded to the cap, high temperature during the welding will destroy the insulation adhesion middle layer, resulting in ineffective insulation or adhesion; therefore, by means of arranging a wire connection base, the damage to the button cell during use can be reduced to decrease the scrap rate. In addition, a metal elastic structure can apply an inward cap pressure F1 to an electrically conductive outer layer, and a metal housing can provide an outward support force to a welding inner layer, so that under cap pressure F1, the electrically conductive outer layer and the welding inner layer can clamp the insulation adhesion middle layer, which prevents the circumstances of gas generated inside the button cell bursting apart a point of adhesion between the insulation adhesion middle layer and the electrically conductive outer layer or the welding inner layer, and the point of adhesion between the insulation adhesion middle layer and the electrically conductive outer layer or the welding inner layer being separated due to the corrosion of an electrolyte, thereby effectively improving the structural stability of the button cell and further extending the service life of the button cell.

Description

纽扣电池组件和电子设备Coin Cell Components and Electronics 技术领域technical field
本发明涉及电池技术领域,特别涉及一种纽扣电池组件和电子设备。The invention relates to the technical field of batteries, in particular to a button battery assembly and electronic equipment.
背景技术Background technique
科学发展一日千里,许多携带式电子设备不仅日益轻薄短小,且具有的功能也愈来愈复杂,因而对电池的续航力要求也愈来愈高。尤其近年来可穿戴类的3C消费电子市场刮起一阵销售旋风(例如TWS耳机),几乎已成为现代人生活中不可或缺的电子产品。With the rapid development of science, many portable electronic devices are not only becoming thinner, thinner and smaller, but also have more and more complex functions, so the requirements for battery life are also getting higher and higher. Especially in recent years, there has been a whirlwind of sales in the wearable 3C consumer electronics market (such as TWS earphones), which have almost become an indispensable electronic product in modern life.
相关技术中,纽扣电池在应用场景中通常会与用电电路的电极线焊接在一起,以保持纽扣电池与用电电路的导通。目前已有业者直接将用电电路以焊接(例如:点焊阻抗熔接、超音波、激光点焊与导通介值熔接型式的电焊等)的方式衔接纽扣电池。而纽扣电池的外壳是由不锈钢材料制成,不锈钢材料与电极线的焊接固定难度较大,导致焊接效率较低,降低了纽扣电池与用电设备的安装效率,同时,在焊接过程中,容易导致纽扣电池的外壳损坏,进而减少纽扣电池的使用寿命,甚至导致纽扣电池报废。In the related art, the button battery is usually welded together with the electrode wire of the power consumption circuit in the application scene, so as to maintain the conduction between the button battery and the power consumption circuit. At present, the industry has directly connected the electric circuit to the button battery by welding (for example: spot welding impedance welding, ultrasonic wave, laser spot welding and conduction medium welding type electric welding, etc.). The shell of the button battery is made of stainless steel. It is difficult to weld and fix the stainless steel material and the electrode wire, resulting in low welding efficiency and reducing the installation efficiency of the button battery and electrical equipment. At the same time, during the welding process, it is easy to Cause damage to the shell of the button battery, thereby reducing the service life of the button battery, and even causing the button battery to be scrapped.
发明内容Contents of the invention
本发明的主要目的是提出一种纽扣电池组件,旨在解决如何减少纽扣电池在安装于用电设备时损坏的技术问题。The main purpose of the present invention is to propose a button battery assembly, aiming at solving the technical problem of how to reduce the damage of the button battery when it is installed in electric equipment.
为实现上述目的,本发明提出的纽扣电池组件包括导线连接座和纽扣电池;In order to achieve the above object, the button battery assembly proposed by the present invention includes a wire connection seat and a button battery;
所述导线连接座包括外接板和导电环;The wire connection seat includes an external connection plate and a conductive ring;
所述纽扣电池包括电芯、金属外壳和与所述金属外壳密封连接的盖壳;The button battery includes an electric core, a metal casing and a cover shell sealedly connected with the metal casing;
所述盖壳包括导电外层、绝缘粘接中层和焊接内层,所述焊接内层,所述焊接内层包括内焊接侧部、内粘接中部和内通孔部,所述绝缘粘接中层包括中绝缘粘接部和中通孔部,所述导电外层包括外粘接部和外导电部,所述 内焊接侧部与所述金属外壳的开口端焊接,所述中绝缘粘接部由在大于等于100℃时热收缩率为6%以下的绝缘防电解液腐蚀的材料融化后,与所述内粘接中部、所述外粘接部进行无缝粘接,且在冷却常温下与所述内粘接中部、所述外粘接部之间的粘接强度大于等于0.1N每平方毫米;The cover shell includes a conductive outer layer, an insulating bonding middle layer and a welding inner layer, the welding inner layer, the welding inner layer includes an inner welding side part, an inner bonding middle part and an inner through hole part, the insulating bonding The middle layer includes a middle insulating adhesive part and a middle through-hole part, the conductive outer layer includes an outer adhesive part and an outer conductive part, the inner welding side part is welded to the open end of the metal shell, and the middle insulating adhesive The part is made of insulating and anti-electrolyte corrosion-resistant material with a thermal shrinkage rate of 6% or less at 100°C or higher, and then seamlessly bonded with the inner adhesive middle part and the outer adhesive part, and cooled at room temperature The bonding strength between the bottom, the inner bonding middle part, and the outer bonding part is greater than or equal to 0.1N per square millimeter;
所述电芯的一极与所述焊接内层电导通,所述电芯的另外一极通过所述内通孔部和中通孔部与所述外导电部电导通;One pole of the battery cell is electrically connected to the soldered inner layer, and the other pole of the battery cell is electrically connected to the outer conductive part through the inner through hole part and the middle through hole part;
所述金属外壳包括柱状主体和向外凸出的凸台;The metal shell includes a columnar body and an outwardly protruding boss;
所述外接板包括绝缘本体、金属弹性结构、至少一个第一电极金属连接区和至少一个第二电极金属连接区;The external connection plate includes an insulating body, a metal elastic structure, at least one first electrode metal connection area and at least one second electrode metal connection area;
所述绝缘本体具有相背设置的导通面和外接面,所述导通面设置有所述金属弹性结构,用于在发生弹性压缩时电性接触所述外导电部,所述外接面设置至少一个所述第一电极金属连接区和至少一个所述第二电极金属连接区;The insulating body has a conduction surface and an outer contact surface arranged opposite to each other, the conduction surface is provided with the metal elastic structure for electrically contacting the outer conductive part when elastic compression occurs, and the outer contact surface is provided with at least one said first electrode metal connection area and at least one said second electrode metal connection area;
至少一个所述第一电极金属连接区与所述金属弹性结构电导通;At least one metal connection region of the first electrode is electrically connected to the metal elastic structure;
导电环,连接于所述外接板,并位于所述外接板的导通面一侧,所述导电环沿所述外接板的周向延伸,以与所述外接板围合形成安装槽,所述安装槽用以收纳固定所述凸台,并与所述凸台电导通;The conductive ring is connected to the external connection plate and is located on one side of the conduction surface of the external connection plate. The conductive ring extends along the circumference of the external connection plate to form an installation groove surrounded by the external connection plate. The mounting groove is used to accommodate and fix the boss, and is electrically connected to the boss;
至少一个所述第二电极金属连接区与所述导电环电导通。At least one metal connection area of the second electrode is electrically connected to the conductive ring.
可选地,所述导电环连接于所述外接面,所述外接面设有接触点,所述接触点与所述导电环电导通,并且所述接触点与所述第二电极金属连接区电导通。Optionally, the conductive ring is connected to the external surface, the external surface is provided with a contact point, the contact point is electrically connected to the conductive ring, and the contact point is connected to the metal connection area of the second electrode. Electrical conduction.
可选地,所述第一电极金属连接区和所述第二电极金属连接区的材质为铜、镍、锡或这些元素的合金。Optionally, the first electrode metal connection area and the second electrode metal connection area are made of copper, nickel, tin or an alloy of these elements.
可选地,所述绝缘粘接中层的材质为PP、PFA、PVDF、PTFE、ETFE和PVC中的一种或多种。Optionally, the insulating bonding middle layer is made of one or more of PP, PFA, PVDF, PTFE, ETFE and PVC.
可选地,所述纽扣电池为二次可充电电池。Optionally, the button battery is a secondary rechargeable battery.
可选地,所述中绝缘粘接部与所述内粘接中部、所述外粘接部之间的粘接强度大于等于1N每平方毫米,且小于等于5N每平方毫米。Optionally, the bonding strength between the middle insulating bonding part, the inner bonding middle part, and the outer bonding part is greater than or equal to 1N per square millimeter and less than or equal to 5N per square millimeter.
可选地,所述金属弹性结构设置为环形金属弹簧。Optionally, the metal elastic structure is configured as an annular metal spring.
可选地,所述金属弹性结构与所述导电外层的接触位置,位于所述绝缘 粘接中层与焊接内层粘接处边侧对应的位置。Optionally, the contact position between the metal elastic structure and the conductive outer layer is located at the position corresponding to the bonding side of the insulating bonding middle layer and the welding inner layer.
可选地,所述外接面设有一个所述第一电极金属连接区,和两个所述第二电极金属连接区,其中一个所述第二电极金属连接区与所述第一电极金属连接区相邻,另一个所述第二电极金属连接区设置在与所述第一电极金属连接区相对的一侧。Optionally, the outer connection surface is provided with one metal connection area of the first electrode and two metal connection areas of the second electrode, wherein one metal connection area of the second electrode is connected to the metal connection area of the first electrode. The second electrode metal connection region is adjacent to the first electrode metal connection region.
本发明还提出一种电子设备,包括含有用电器件的电子设备主体以及如上所述的纽扣电池组件,所述纽扣电池组件位于所述电子设备主体内,且所述用电器件的其中一极与所述第一电极金属连接区电导通;另外一极与所述第二电极金属连接区电导通。The present invention also proposes an electronic device, which includes an electronic device body containing an electrical device and the above-mentioned button battery assembly, the button battery assembly is located in the electronic device body, and one pole of the electrical device It is electrically connected with the metal connection area of the first electrode; the other electrode is electrically connected with the metal connection area of the second electrode.
本发明将纽扣电池的盖壳分为导电外层、绝缘粘接中层和焊接内层,其中,导电外层与电芯的一极电导通,焊接内层与电芯的另一极电导通,而焊接内层的内焊接侧部与金属外壳的开口端焊接后,可实现对电芯的封装。The present invention divides the cover shell of the button battery into a conductive outer layer, an insulating bonding middle layer and a welding inner layer, wherein the conductive outer layer is electrically connected to one pole of the battery cell, and the welding inner layer is electrically connected to the other pole of the battery cell. After the inner welding side part of the welding inner layer is welded to the opening end of the metal shell, the packaging of the electric core can be realized.
由于焊接内层与导电外层通过绝缘粘接中层绝缘,因此金属外壳也会与导电外层绝缘,从而可防止电芯的两个电极相互导通短路;由于盖壳的导电外层与焊接内层已预先绝缘,因此在将盖壳封装金属外壳时,只需焊接焊接内层与金属外壳即可,无需再设置绝缘膜,由此可简化电池的封装过程,提高封装效率。Since the welding inner layer and the conductive outer layer are insulated through the insulating bonding middle layer, the metal shell will also be insulated from the conductive outer layer, thereby preventing the two electrodes of the cell from conducting and short circuiting each other; The layer has been pre-insulated, so when the cover shell is packaged with the metal shell, only the inner layer and the metal shell need to be welded, and there is no need to install an insulating film, which can simplify the battery packaging process and improve packaging efficiency.
导线连接座的绝缘本体和导电环围合形成安装槽,以供纽扣电池的凸台固定安装,纽扣电池的盖壳装入安装槽后,导电外层与金属弹性结构抵接,凸台与导电环抵接,从而使外接面的第一电极金属连接区与纽扣电池的一电极导通,第二电极金属连接区与纽扣电池的另一电极导通。The insulating body and the conductive ring of the wire connection seat are surrounded to form a mounting groove for the fixed installation of the boss of the button battery. The ring abuts against each other, so that the first electrode metal connection area on the outer contact surface conducts with one electrode of the button battery, and the second electrode metal connection area conducts with the other electrode of the button battery.
第一电极金属连接区、第二电极金属连接区用以供用电设备的正、负电极线焊接或者抵接接触,用电设备的电极线与第一电极金属连接区、第二电极金属连接区焊接后,可与纽扣电池的电极导通,从而实现用电设备与纽扣电池的电导通。The first electrode metal connection area and the second electrode metal connection area are used for welding or abutting contact of the positive and negative electrode wires of the electrical equipment, and the electrode wires of the electrical equipment are connected to the first electrode metal connection area and the second electrode metal After the area is welded, it can conduct with the electrode of the button battery, so as to realize the electrical conduction between the electrical equipment and the button battery.
由于盖壳的绝缘粘接中层是胶层结构,如果用电设备的电极线直接焊接于盖壳,焊接过程的高温会破坏绝缘粘接中层,导致无法有效绝缘或粘接,因此,通过设置导线连接座,可减少纽扣电池应用时的损坏,以减少报废率; 此外,金属弹性结构还能对导电外层施加向内的盖壳压力F1,而金属外壳会对焊接内层产生朝外的支撑力,因此,盖壳压力F1会使导电外层与焊接内层夹固绝缘粘接中层,避免纽扣电池内部产生的气体将绝缘粘接中层与导电外层或焊接内层的粘接处冲开,也避免绝缘粘接中层与导电外层或焊接内层的粘接处因电解液腐蚀而分离,从而可有效提高纽扣电池的结构稳定性,进一步延长纽扣电池的使用寿命。Since the insulating and bonding middle layer of the cover shell is a glue layer structure, if the electrode wires of the electrical equipment are directly welded to the cover shell, the high temperature during the welding process will destroy the insulating and bonding middle layer, resulting in ineffective insulation or bonding. Therefore, by setting the wire The connection seat can reduce the damage of the button battery application to reduce the scrap rate; in addition, the metal elastic structure can exert an inward cover shell pressure F1 on the conductive outer layer, and the metal shell will produce outward support on the welded inner layer Therefore, the pressure F1 of the cover will make the conductive outer layer and the welding inner layer clamp the insulating bonding middle layer, so as to prevent the gas generated inside the button battery from breaking away the bonding between the insulating bonding middle layer and the conductive outer layer or the welding inner layer , Also avoid the separation of the bonding between the insulating bonding middle layer and the conductive outer layer or the welding inner layer due to electrolyte corrosion, which can effectively improve the structural stability of the button battery and further extend the service life of the button battery.
附图说明Description of drawings
为了更清楚地说明本发明实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图示出的结构获得其他的附图。In order to more clearly illustrate the technical solutions in the embodiments of the present invention or the prior art, the following will briefly introduce the drawings that need to be used in the description of the embodiments or the prior art. Obviously, the accompanying drawings in the following description are only These are some embodiments of the present invention. For those skilled in the art, other drawings can also be obtained according to the structures shown in these drawings without creative effort.
图1为本发明纽扣电池组件一实施例的结构示意图;Fig. 1 is the structural representation of an embodiment of button cell assembly of the present invention;
图2为本发明纽扣电池组件一实施例的剖面示意图;Fig. 2 is a schematic cross-sectional view of an embodiment of the button battery assembly of the present invention;
图3为本发明中导线连接座一实施例的结构示意图;Fig. 3 is a schematic structural view of an embodiment of the wire connection seat in the present invention;
图4为本发明中导线连接座另一实施例的结构示意图;Fig. 4 is a structural schematic view of another embodiment of the wire connecting seat in the present invention;
图5为本发明中纽扣电池一实施例的结构示意图;Fig. 5 is the structural representation of an embodiment of button cell in the present invention;
图6为本发明中纽扣电池一实施例的剖面示意图。FIG. 6 is a schematic cross-sectional view of an embodiment of a button battery in the present invention.
附图标号说明:Explanation of reference numbers:
标号label 名称name 标号label 名称 name 标号label 名称name
1010 导线连接座 wire connector 2020 纽扣电池Button Battery 1111 外接板 External board
1212 导电环Conductive ring 21twenty one 电芯Batteries 22twenty two 金属外壳metal shell
23twenty three 盖壳Cover shell 24twenty four 导电外层Conductive outer layer 2525 绝缘粘接中层Insulation bonding middle layer
2626 焊接内层Weld inner layer 261261 内焊接侧部 Inner Weld Side 262262 内粘接中部 inner bonding middle
263263 内通孔部Inner through hole 251251 中绝缘粘接部Insulation bonding part 252252 中通孔部Through Hole
241241 外粘接部 Outer bonding 242242 外导电部Outer conductive part 221221 柱状主体 columnar body
222222 凸台 Boss 1313 绝缘本体 Insulation body 1414 金属弹性结构metal elastic structure
1515 第一电极金属连接first electrode metal connection 1616 第二电极金属连接Second electrode metal connection 131131 导通面conduction surface
  the district  the district  the  the
132132 外接面 Outer surface 133133 接触点Contact point  the  the
本发明目的的实现、功能特点及优点将结合实施例,参照附图做进一步说明。The realization of the purpose of the present invention, functional characteristics and advantages will be further described in conjunction with the embodiments and with reference to the accompanying drawings.
具体实施方式Detailed ways
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明的一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The following will clearly and completely describe the technical solutions in the embodiments of the present invention with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of them. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without creative efforts fall within the protection scope of the present invention.
需要说明,若本发明实施例中有涉及方向性指示(诸如上、下、左、右、前、后……),则该方向性指示仅用于解释在某一特定姿态(如附图所示)下各部件之间的相对位置关系、运动情况等,如果该特定姿态发生改变时,则该方向性指示也相应地随之改变。It should be noted that if there is a directional indication (such as up, down, left, right, front, back...) in the embodiment of the present invention, the directional indication is only used to explain the position in a certain posture (as shown in the accompanying drawing). If the specific posture changes, the directional indication will also change accordingly.
另外,若本发明实施例中有涉及“第一”、“第二”等的描述,则该“第一”、“第二”等的描述仅用于描述目的,而不能理解为指示或暗示其相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括至少一个该特征。另外,全文中出现的“和/或”的含义为,包括三个并列的方案,以“A和/或B为例”,包括A方案,或B方案,或A和B同时满足的方案。另外,各个实施例之间的技术方案可以相互结合,但是必须是以本领域普通技术人员能够实现为基础,当技术方案的结合出现相互矛盾或无法实现时应当认为这种技术方案的结合不存在,也不在本发明要求的保护范围之内。In addition, if there are descriptions involving "first", "second" and so on in the embodiments of the present invention, the descriptions of "first", "second" and so on are only for descriptive purposes, and should not be interpreted as indicating or implying Its relative importance or implicitly indicates the number of technical features indicated. Thus, the features defined as "first" and "second" may explicitly or implicitly include at least one of these features. In addition, the meaning of "and/or" appearing in the whole text includes three parallel schemes, taking "A and/or B as an example", including scheme A, scheme B, or schemes satisfying both A and B. In addition, the technical solutions of the various embodiments can be combined with each other, but it must be based on the realization of those skilled in the art. When the combination of technical solutions is contradictory or cannot be realized, it should be considered that the combination of technical solutions does not exist , nor within the scope of protection required by the present invention.
本发明提出一种纽扣电池组件,用以安装于含有用电器件的电子设备主体中,以向用电器件提供电能。The present invention provides a button battery assembly, which is used for being installed in the main body of electronic equipment containing electric devices to provide electric energy to the electric devices.
在本发明实施例中,如图1至图6所示,该纽扣电池组件包括导线连接座10和纽扣电池20;In the embodiment of the present invention, as shown in FIGS. 1 to 6 , the button battery assembly includes a wire connection base 10 and a button battery 20;
所述导线连接座10包括外接板11和导电环12;The wire connection base 10 includes an external connection plate 11 and a conductive ring 12;
所述纽扣电池20包括电芯21、金属外壳22和与所述金属外壳22密封连 接的盖壳23;Described button battery 20 comprises electric core 21, metal shell 22 and the cover shell 23 that is connected with described metal shell 22 sealingly;
所述盖壳23包括导电外层24、绝缘粘接中层25和焊接内层26,所述焊接内层26,所述焊接内层26包括内焊接侧部261、内粘接中部262和内通孔部263,所述绝缘粘接中层25包括中绝缘粘接部251和中通孔部252,所述导电外层24包括外粘接部241和外导电部242,所述内焊接侧部261与所述金属外壳22的开口端焊接,所述中绝缘粘接部251由在大于等于100℃时热收缩率为6%以下的绝缘防电解液腐蚀的材料融化后,与所述内粘接中部262、所述外粘接部241进行无缝粘接,且在冷却常温下与所述内粘接中部262、所述外粘接部241之间的粘接强度大于等于0.1N每平方毫米;The cover shell 23 includes a conductive outer layer 24, an insulating bonding middle layer 25 and a welding inner layer 26, the welding inner layer 26, and the welding inner layer 26 includes an inner welding side part 261, an inner bonding middle part 262 and an inner through hole. The hole part 263, the insulating bonding middle layer 25 includes the middle insulating bonding part 251 and the through hole part 252, the conductive outer layer 24 includes the outer bonding part 241 and the outer conductive part 242, and the inner welding side part 261 Welded with the open end of the metal shell 22, the middle insulating bonding part 251 is melted by an insulating and electrolyte-resistant material with a thermal shrinkage rate of 6% or less at a temperature of 100°C or higher, and then bonded to the inner The middle part 262 and the outer bonding part 241 are seamlessly bonded, and the bonding strength between the inner bonding middle part 262 and the outer bonding part 241 is greater than or equal to 0.1 N per square millimeter at room temperature ;
所述电芯21的一极与所述焊接内层26电导通,所述电芯21的另外一极通过所述内通孔部263和中通孔部252与所述外导电部242电导通;One pole of the battery cell 21 is electrically connected to the welding inner layer 26, and the other pole of the battery cell 21 is electrically connected to the outer conductive part 242 through the inner through hole part 263 and the middle through hole part 252. ;
所述金属外壳22包括柱状主体221和向外凸出的凸台222;The metal shell 22 includes a columnar body 221 and an outwardly protruding boss 222;
所述外接板11包括绝缘本体13、金属弹性结构14、至少一个第一电极金属连接区15和至少一个第二电极金属连接区16;The external connection plate 11 includes an insulating body 13, a metal elastic structure 14, at least one first electrode metal connection area 15 and at least one second electrode metal connection area 16;
所述绝缘本体13具有相背设置的导通面131和外接面132,所述导通面131设置有所述金属弹性结构14,用于在发生弹性压缩时电性接触所述外导电部242,所述外接面132设置至少一个所述第一电极金属连接区15和至少一个所述第二电极金属连接区16;The insulating body 13 has a conduction surface 131 and an outer contact surface 132 disposed opposite to each other. The conduction surface 131 is provided with the metal elastic structure 14 for electrically contacting the outer conductive part 242 when elastic compression occurs. , the external surface 132 is provided with at least one metal connection region 15 of the first electrode and at least one metal connection region 16 of the second electrode;
至少一个所述第一电极金属连接区15与所述金属弹性结构14电导通;At least one of the first electrode metal connection regions 15 is electrically connected to the metal elastic structure 14;
导电环12,连接于所述外接板11,并位于所述外接板11的导通面131一侧,所述导电环12沿所述外接板11的周向延伸,以与所述外接板11围合形成安装槽,所述安装槽用以收纳固定所述凸台222,并与所述凸台222电导通;The conductive ring 12 is connected to the external connection plate 11 and is located on the side of the conducting surface 131 of the external connection plate 11. Enclosing and forming a mounting groove, the mounting groove is used to accommodate and fix the boss 222, and electrically conduct with the boss 222;
至少一个所述第二电极金属连接区16与所述导电环12电导通。At least one of the second electrode metal connection regions 16 is electrically connected to the conductive ring 12 .
金属外壳22可采用不锈钢板制成,金属外壳22的开口朝上,用以容纳电芯21和电解液;其中,凸台222设于柱状主体221的开口端并凸出于柱状主体221的外周壁,且凸台222沿柱状主体221的周向延伸。The metal shell 22 can be made of stainless steel plate, and the opening of the metal shell 22 faces upwards to accommodate the battery cell 21 and the electrolyte; wherein, the boss 222 is arranged at the opening end of the columnar body 221 and protrudes from the outer periphery of the columnar body 221 wall, and the boss 222 extends along the circumference of the columnar body 221 .
盖壳23的导电外层24和焊接内层26可采用不锈钢板制成,其中,导电外层24的外导电部242会通过中通孔部252和内通孔部263朝向电池壳内,用以与电芯21的其中一电极连接;焊接内层26通过连接于金属外壳22来与 电芯21的另一电极连接。由于焊接内层26与导电外层24之间具有绝缘粘接中层25,因此,焊接内层26与导电外层24相互绝缘,从而使金属外壳22与导电外层24可相互绝缘,以防止电芯21的两个电极相互导通,由此,既可使盖壳23的导电外层24和金属外壳22分别形成纽扣电池20的两个输出电极,又可避免两个输出电极相互导通而短路。The conductive outer layer 24 and the welding inner layer 26 of the cover shell 23 can be made of stainless steel plates, wherein the outer conductive part 242 of the conductive outer layer 24 will pass through the middle through hole part 252 and the inner through hole part 263 towards the inside of the battery case, and use to be connected to one of the electrodes of the battery cell 21 ; the welding inner layer 26 is connected to the other electrode of the battery cell 21 by being connected to the metal shell 22 . Owing to there is the insulating bonding middle layer 25 between the welding inner layer 26 and the conductive outer layer 24, therefore, the welding inner layer 26 is insulated from the conductive outer layer 24, so that the metal shell 22 and the conductive outer layer 24 can be insulated from each other to prevent electric shock. The two electrodes of the core 21 are connected to each other, thus, the conductive outer layer 24 and the metal shell 22 of the cover shell 23 can be respectively formed into two output electrodes of the button battery 20, and the two output electrodes can be prevented from being connected to each other. short circuit.
可以理解,外导电部242的内表面会通过中通孔部252和内通孔部263朝向金属外壳22内部,以供电芯21的电极接触;而外导电部242的外表面可供外部设备电连接。外导电部242可以位于中通孔部252和内通孔部263的顶部,也可以朝金属外壳22内部的方向下凹,并依次穿过中通孔部252和内通孔部263,在此不座限制,只需满足外导电部242可与电芯21的电极接触即可。It can be understood that the inner surface of the outer conductive part 242 will pass through the middle through hole part 252 and the inner through hole part 263 towards the inside of the metal shell 22, so as to contact the electrodes of the power supply core 21; connect. The outer conductive part 242 may be located on the top of the middle through hole part 252 and the inner through hole part 263, or may be recessed toward the inside of the metal shell 22, and pass through the middle through hole part 252 and the inner through hole part 263 in sequence. There is no seat restriction, it only needs to satisfy that the outer conductive part 242 can be in contact with the electrode of the battery cell 21 .
现有技术中纽扣电池20的壳体采用上下壳体配合,中间为塑料绝缘圈,对于电池壳体侧壁而言,其具有三层结构;而本申请的金属外壳22侧壁仅仅可以为一层,相同大小壳体的情况下,本申请的金属外壳22提高了内部可用的空间,有利于提高整个电池的容量。In the prior art, the shell of the button battery 20 adopts the upper and lower shells, and the middle is a plastic insulating ring. For the side wall of the battery shell, it has a three-layer structure; while the metal shell 22 side wall of the present application can only be one Layer, in the case of the same size casing, the metal casing 22 of the present application increases the available space inside, which is beneficial to increase the capacity of the entire battery.
内焊接侧部261即焊接内层26用于与金属外壳22焊接的位置,内焊接侧部261设于焊接内层26的周壁。内通孔部263即焊接内层26开孔的位置,内粘接中部262用于与绝缘粘接中层25粘接。其中,内焊接侧部261与金属外壳22焊接,既可实现盖壳23与金属外壳22的相互固定,又可实现焊接内层26与金属外壳22的电导通。绝缘粘接中层25的中通孔部252与焊接内层26的内通孔部263对应,从而导电外层24的外导电部242可通过中通孔部252和内通孔部263朝向金属外壳22内部。中通孔部252和内通孔部263可开设于盖壳23的中部,以使外导电部242能与柱状主体221周向上的各个位置均保持足够间距。The inner welding side portion 261 is the position where the welding inner layer 26 is used for welding with the metal shell 22 , and the inner welding side portion 261 is disposed on the peripheral wall of the welding inner layer 26 . The inner through hole portion 263 is the position where the inner layer 26 is opened for welding, and the inner adhesive middle portion 262 is used for bonding with the insulating adhesive middle layer 25 . Wherein, the inner welding side portion 261 is welded to the metal shell 22 , which can not only realize the mutual fixing of the cover shell 23 and the metal shell 22 , but also realize the electrical conduction between the welded inner layer 26 and the metal shell 22 . The middle through hole portion 252 of the insulating bonding middle layer 25 corresponds to the inner through hole portion 263 of the welding inner layer 26, so that the outer conductive portion 242 of the conductive outer layer 24 can pass through the middle through hole portion 252 and the inner through hole portion 263 towards the metal shell 22 inside. The middle through-hole portion 252 and the inner through-hole portion 263 can be opened in the middle of the cover shell 23 so that the outer conductive portion 242 can maintain a sufficient distance from each position in the circumferential direction of the columnar body 221 .
电芯21的电极可以直接与导电外层24的外导电部242接触。中绝缘粘接部251的顶面和底面分别与外粘接部241和内粘接中部262粘固,以实现焊接内层26与导电外层24的绝缘连接。焊接内层26与金属外壳22焊接密封,导电外层24与焊接内层26通过绝缘粘接中层25无缝粘接,可实现盖壳23对金属外壳22的封闭。其中,在焊接内层26与金属外壳22连接时,焊接内层26与导电外层24已预先实现绝缘连接,因此无需再另外设置绝缘膜。The electrodes of the battery cell 21 may directly contact the outer conductive portion 242 of the conductive outer layer 24 . The top surface and the bottom surface of the middle insulating bonding portion 251 are bonded to the outer bonding portion 241 and the inner bonding middle portion 262 respectively, so as to realize the insulating connection between the welding inner layer 26 and the conductive outer layer 24 . The welding inner layer 26 is welded and sealed with the metal shell 22 , and the conductive outer layer 24 and the welding inner layer 26 are seamlessly bonded through the insulating bonding middle layer 25 , so that the metal shell 22 can be closed by the cover shell 23 . Wherein, when the welding inner layer 26 is connected to the metal shell 22, the welding inner layer 26 and the conductive outer layer 24 have been insulated and connected in advance, so there is no need to additionally provide an insulating film.
绝缘粘接中层25采用具有绝缘性能和防电解液腐蚀的材料制成,其在大于等于100℃时的热收缩率为6%以下,热收缩率是指热塑性材料因其固有的热膨胀率而产生的体积变化,也就是说,在温度大于等于100℃时,绝缘粘接中层25的体积变化量不超过原体积的6%,由此可使绝缘粘接中层25充分融化后与导电外层24和焊接内层26充分连接,以保证粘接效果。The insulating bonding middle layer 25 is made of materials with insulating properties and anti-electrolyte corrosion, and its heat shrinkage rate is less than 6% when it is greater than or equal to 100 ° C. The heat shrinkage rate refers to the thermoplastic material due to its inherent thermal expansion rate. That is to say, when the temperature is greater than or equal to 100°C, the volume change of the insulating and bonding middle layer 25 does not exceed 6% of the original volume, so that the insulating and bonding middle layer 25 can be fully melted and bonded with the conductive outer layer 24 It is fully connected with the welding inner layer 26 to ensure the bonding effect.
绝缘粘接中层25在冷却常温下与外粘接部241、内粘接中部262之间的粘接强度大于等于0.1N每平方毫米,可保证绝缘粘接中层25与导电外层24和焊接内层26的粘接稳定性;具体地,中绝缘粘接部251在冷却常温下与所述外粘接部241、所述内粘接中部262之间的粘接强度大于等于1N每平方毫米,且小于等于5.0N/平方毫米,以防止盖壳23内部应力过高,从而可避免在后续的加工或使用过程中盖壳23因内部作用力而破损。The bonding strength between the insulating bonding middle layer 25 and the outer bonding part 241 and the inner bonding middle part 262 is greater than or equal to 0.1N per square millimeter at normal cooling temperature, which can ensure that the insulating bonding middle layer 25 and the conductive outer layer 24 and the welding inner layer The bonding stability of the layer 26; specifically, the bonding strength between the middle insulating bonding part 251 and the outer bonding part 241 and the inner bonding middle part 262 is greater than or equal to 1N per square millimeter at normal cooling temperature, And be less than or equal to 5.0N/mm2, so as to prevent the internal stress of the cover shell 23 from being too high, thereby avoiding the damage of the cover shell 23 due to internal force during subsequent processing or use.
本发明将纽扣电池20的盖壳23分为导电外层24、绝缘粘接中层25和焊接内层26,其中,导电外层24与电芯21的一极电导通,焊接内层26与电芯21的另一极电导通,而焊接内层26的内焊接侧部261与金属外壳22的开口端焊接后,可实现对电芯21的封装。The present invention divides the cover shell 23 of the button battery 20 into a conductive outer layer 24, an insulating and adhesive middle layer 25 and a welding inner layer 26, wherein the conductive outer layer 24 is electrically connected to one pole of the battery cell 21, and the welding inner layer 26 is connected to the electric core 21. The other pole of the core 21 is electrically connected, and after the inner welding side portion 261 of the inner layer 26 is welded to the open end of the metal shell 22 , the packaging of the battery core 21 can be realized.
由于焊接内层26与导电外层24通过绝缘粘接中层25绝缘,因此金属外壳22也会与导电外层24绝缘,从而可防止电芯21的两个电极相互导通短路;由于盖壳23的导电外层24与焊接内层26已预先绝缘,因此在将盖壳23封装金属外壳22时,只需焊接焊接内层26与金属外壳22即可,无需再设置绝缘膜,由此可简化电池的封装过程,提高封装效率。Because the welding inner layer 26 and the conductive outer layer 24 are insulated by the insulating bonding middle layer 25, the metal shell 22 will also be insulated from the conductive outer layer 24, thereby preventing the two electrodes of the electric core 21 from conducting and shorting each other; because the cover shell 23 The conductive outer layer 24 and the welding inner layer 26 have been insulated in advance, so when the cover shell 23 is packaged with the metal shell 22, only the welding inner layer 26 and the metal shell 22 need to be welded, and no insulating film is required, which can simplify The packaging process of the battery improves the packaging efficiency.
与现有技术相比,本申请的金属外壳22与盖壳23通过焊接密封,这样很好地提高了密封性和稳定性,而不是依靠壳体之间的物理受力挤压进行密封,并且由于盖壳23是提前做好的,通过中绝缘粘接部251来进行绝缘,可以提高绝缘性,同时在一定条件下,可以起到保护作用。Compared with the prior art, the metal shell 22 and the cover shell 23 of the present application are sealed by welding, which improves the sealing and stability well, instead of relying on physical force extrusion between the shells for sealing, and Since the cover shell 23 is prepared in advance, the insulation is carried out through the middle insulating adhesive part 251, which can improve the insulation, and at the same time, it can play a protective role under certain conditions.
进一步,本申请中纽扣电池20的盖壳23采用了三层结构,其结构的稳定性和牢靠性加强,由于中绝缘粘接部251处于两层不锈钢之间,其防水和防电解液腐蚀的性质都很强,中绝缘粘接部251与金属外壳22的外部接触面积很少,可以有效地防止外界的水分进入到金属外壳22内;同时在接触面积小的同时,中绝缘粘接部251在金属外壳22外部与内部之间的路径长度比较长,这样进一步地避免了外界的水分等对金属外壳22内部电芯21和电解液 的影响。Further, the cover shell 23 of the button battery 20 in the present application adopts a three-layer structure, and the stability and reliability of the structure are strengthened. Since the middle insulating bonding part 251 is between the two layers of stainless steel, it is waterproof and anti-electrolyte corrosion. The properties are all very strong, and the external contact area between the middle insulating bonding portion 251 and the metal shell 22 is very small, which can effectively prevent external moisture from entering the metal shell 22; while the contact area is small, the middle insulating bonding portion 251 The length of the path between the outside and the inside of the metal casing 22 is relatively long, which further avoids the influence of external moisture on the battery cell 21 and the electrolyte inside the metal casing 22 .
同理,对于纽扣电池20内部来说,中绝缘粘接部251仅仅在中通孔部252的边缘可与纽扣电池20内的电解液接触,能有效地减少电解液与中绝缘粘接部251的接触面积,以有效地对中绝缘粘接部251进行保护,避免电解液对中绝缘粘接部251的软化、腐蚀等影响,从而有效地提高电池的使用寿命。进一步地,中绝缘粘接部251从纽扣电池20内部至纽扣电池20外部的路径也较长,能够进一步提高电池的使用寿命。Similarly, for the inside of the button battery 20, the middle insulating adhesive portion 251 can only contact the electrolyte solution in the button battery 20 at the edge of the middle through hole portion 252, which can effectively reduce the contact between the electrolyte solution and the middle insulating adhesive portion 251. contact area to effectively protect the middle insulating bonding portion 251 and avoid the influence of the electrolyte on the middle insulating bonding portion 251 such as softening and corrosion, thus effectively improving the service life of the battery. Furthermore, the path of the middle insulating bonding portion 251 from the inside of the button battery 20 to the outside of the button battery 20 is also longer, which can further improve the service life of the battery.
绝缘本体13可为圆形板,也可为方形板,具体不做限制。第一电极金属连接区15用以供用电设备的电极线焊接活动抵触接触电导通,用电设备的电极线可以是正极线,也可以是负极线,在此不做限制;具体举例说明,当第一电极金属连接区15与纽扣电池20的正极电导通,供用电设备的正极线与之进行焊接或者抵触接触电导通;当第一电极金属连接区15与纽扣电池20的负极电导通,供用电设备的负极线与之进行焊接或者抵触接触电导通。The insulating body 13 can be a circular plate or a square plate, which is not specifically limited. The first electrode metal connection area 15 is used for the electrode wire welding activity of the electrical equipment to interfere with the contact electrical conduction. The electrode wire of the electrical equipment can be a positive pole line or a negative pole line, which is not limited here; for specific examples, When the first electrode metal connection area 15 is electrically connected to the positive pole of the button battery 20, the positive line of the power supply equipment is welded or resists the electrical connection with it; when the first electrode metal connection area 15 is electrically connected to the negative electrode of the button battery , the negative wire of the power supply equipment is welded or resists contact with it for electrical conduction.
导电环12的形状与绝缘本体13的形状对应,如圆环或方形环,以使导电环12与绝缘本体13所围合形成的安装槽更加规整,举例而言,绝缘本体13设置为圆形板,导电环12设置为圆环,以使安装槽与圆扣状的纽扣电池20适配。安装槽可用以容置纽扣电池20整体,也可仅容置纽扣电池20的端部,在此不做限制,只需满足纽扣电池20装入安装槽后,盖壳23与绝缘本体13相对即可。盖壳23装入安装槽后,导电外层24抵接于金属弹性结构14,以与导通面131间接接触;导电环12抵接于金属外壳22,以与第二电极金属连接区16导通。The shape of the conductive ring 12 corresponds to the shape of the insulating body 13, such as a circular ring or a square ring, so that the installation groove formed by the conductive ring 12 and the insulating body 13 is more regular. For example, the insulating body 13 is set in a circular shape plate, and the conductive ring 12 is set as a circular ring, so that the mounting groove is adapted to the round button battery 20 . The installation groove can be used to accommodate the button battery 20 as a whole, or only the end of the button battery 20. There is no limitation here, as long as the button battery 20 is loaded into the installation groove, the cover shell 23 is opposite to the insulating body 13. Can. After the cover shell 23 is installed in the installation groove, the conductive outer layer 24 abuts against the metal elastic structure 14 to indirectly contact with the conduction surface 131; Pass.
导通面131与纽扣电池20接触的目的是为了更好地固定纽扣电池20,因此,导通面131与纽扣电池20可以直接接触,也可以间接接触,或者不接触,只需满足能稳定地确定纽扣电池20能够很好地稳固固定在安装槽即可。优选地,导通面131是绝缘的,金属弹性结构14与导电外层24接触后,通过绝缘本体13内部走线与第一电极金属连接区15形成电导通。The purpose of the conduction surface 131 being in contact with the button battery 20 is to better fix the button battery 20. Therefore, the conduction surface 131 and the button battery 20 can be in direct contact, or indirectly, or not in contact, as long as they can be stably It is enough to confirm that the button battery 20 can be well and firmly fixed in the installation slot. Preferably, the conduction surface 131 is insulated, and after the metal elastic structure 14 is in contact with the conductive outer layer 24 , electrical conduction is formed with the first electrode metal connection region 15 through the internal wiring of the insulating body 13 .
第二电极金属连接区16用以供用电设备的电极线焊接或者抵接接触电导通,可以是正极线,也可以是负极线,在此不做限制;具体举例说明,当第二电极金属连接区16与纽扣电池20的正极电导通,供用电设备的正极线与之进行焊接或者抵触接触电导通;当第二电极金属连接区16与纽扣电池20 的负极电导通,供用电设备的负极线与之进行焊接或者抵触接触电导通。The second electrode metal connection area 16 is used for welding or abutting contact electrical conduction of the electrode wires of the electrical equipment. It can be a positive wire or a negative wire, which is not limited here; The connection area 16 is electrically connected to the positive pole of the button battery 20, and the positive wire of the power supply equipment is welded or electrically connected with it; when the second electrode metal connection area 16 is electrically connected to the negative pole of the button battery 20, the power supply equipment The negative wire is welded or resists contact with it for electrical conduction.
纽扣电池20装入安装槽后,正极通过导电外层24抵接于金属弹性结构14,负极通过金属外壳22抵接于导电环12,即纽扣电池20的正极可与绝缘本体13上的第一电极金属连接区15电导通,从而焊接于第一电极金属连接区15的正极线可与纽扣电池20的正极电导通;纽扣电池20的负极可与绝缘本体13上的第二电极金属连接区16电导通,从而焊接于第二电极金属连接区16的负极线可与纽扣电池20的负极电导通,以使纽扣电池20与用电设备可通过电池导线连接座10形成电流回路。After the button battery 20 is loaded into the installation groove, the positive pole abuts against the metal elastic structure 14 through the conductive outer layer 24, and the negative pole abuts against the conductive ring 12 through the metal shell 22, that is, the positive pole of the button battery 20 can be connected to the first pole on the insulating body 13. The electrode metal connection area 15 is electrically connected, so that the positive wire welded to the first electrode metal connection area 15 can be electrically connected to the positive electrode of the button battery 20; the negative electrode of the button battery 20 can be connected to the second electrode metal connection area 16 on the insulating body 13 Electrical conduction, so that the negative electrode wire welded to the second electrode metal connection area 16 can be electrically conductive with the negative electrode of the button battery 20, so that the button battery 20 and the electrical equipment can form a current loop through the battery wire connection seat 10.
由于用电设备的正极线和负极线都可焊接于绝缘本体13,因此可进一步降低用电设备与纽扣电池20的连接难度,提高连接效率和连接强度。与传统焊接在纽扣电池20的两个端面相比,本申请可以直接在一个面进行焊接,特别在自动化焊接的过程中可以一个步骤完成,提高了焊接效率。Since both the positive and negative wires of the electrical equipment can be welded to the insulating body 13, the difficulty of connecting the electrical equipment to the button battery 20 can be further reduced, and the connection efficiency and connection strength can be improved. Compared with traditional welding on the two end faces of the button battery 20, this application can directly weld on one side, especially in one step during the automatic welding process, which improves the welding efficiency.
进一步,绝缘本体13上面的所述第一电极金属连接区15和所述第二电极金属连接区16的材质为铜、镍、锡或这些元素的合金。第一电极金属连接区15和第二电极金属连接区16用以供电极线焊接并导电,而铜、镍、锡能降低焊接时的连接难度,以进一步提高焊接效率。Further, the first electrode metal connection area 15 and the second electrode metal connection area 16 on the insulating body 13 are made of copper, nickel, tin or alloys of these elements. The first electrode metal connection area 15 and the second electrode metal connection area 16 are used for electrode wire welding and conduction, and copper, nickel, and tin can reduce connection difficulty during welding to further improve welding efficiency.
此外,在更换纽扣电池20时,也无需再操作电极线,只需拆卸纽扣电池20即可,进一步提高了纽扣电池20的更换效率。In addition, when replacing the button battery 20 , there is no need to operate the electrode wires, and it is only necessary to disassemble the button battery 20 , which further improves the replacement efficiency of the button battery 20 .
更进一步,由于盖壳23的绝缘粘接中层25是胶层结构,如果用电设备的电极线直接焊接于盖壳23,焊接过程的高温会破坏绝缘粘接中层25,导致无法有效绝缘或粘接,因此,通过设置导线连接座10,可减少纽扣电池20应用时的损坏,以减少报废率。Furthermore, since the insulating and bonding middle layer 25 of the cover shell 23 is an adhesive layer structure, if the electrode wires of the electrical equipment are directly welded to the cover shell 23, the high temperature during the welding process will destroy the insulating and bonding middle layer 25, resulting in ineffective insulation or bonding. Therefore, by setting the wire connection base 10, the damage of the button battery 20 during application can be reduced, so as to reduce the scrap rate.
此外,金属弹性结构14还能对导电外层24施加向内的盖壳23压力F1,而金属外壳22会对焊接内层26产生朝外的支撑力,因此,盖壳23压力F1会使导电外层24与焊接内层26夹固绝缘粘接中层25,避免纽扣电池20内部产生的气体将绝缘粘接中层25与导电外层24或焊接内层26的粘接处冲开,也避免绝缘粘接中层25与导电外层24或焊接内层26的粘接处因电解液腐蚀而分离,从而可有效提高纽扣电池20的结构稳定性,进一步延长纽扣电池20的使用寿命。In addition, the metal elastic structure 14 can also exert an inward pressure F1 of the cover shell 23 on the conductive outer layer 24, and the metal shell 22 will produce an outward support force on the welded inner layer 26, so the pressure F1 of the cover shell 23 will make the conductive The outer layer 24 and the welding inner layer 26 sandwich the insulating and bonding middle layer 25, so as to prevent the gas generated inside the button battery 20 from breaking away the joint between the insulating and bonding middle layer 25 and the conductive outer layer 24 or the welding inner layer 26, and also avoid insulating The bond between the bonding middle layer 25 and the conductive outer layer 24 or the welding inner layer 26 is separated due to electrolyte corrosion, thereby effectively improving the structural stability of the button battery 20 and further prolonging the service life of the button battery 20 .
在一实施例中,如图1和图3所示,所述导电环12连接于所述外接面132, 所述外接面132设有接触点133,所述接触点133与所述导电环12电导通,并且所述接触点133与所述第二电极金属连接区16电导通。In one embodiment, as shown in FIGS. 1 and 3 , the conductive ring 12 is connected to the outer surface 132, and the outer surface 132 is provided with a contact point 133, and the contact point 133 is connected to the conductive ring 12. and the contact point 133 is electrically connected to the second electrode metal connection region 16 .
所述导电环12周向上的两相对位置分别凸设有扣板,两所述扣板扣接于所述外接面132。扣板用以实现导电环12与绝缘本体13的固定连接,扣板可与导电环12一体注塑成型,以提高结构强度,且降低加工难度。两扣板连接于导电环12周向上的两相对位置,可增加导电环12与绝缘本体13的连接部位和外接面132积,以提高连接强度。Two opposite positions on the circumferential direction of the conductive ring 12 are respectively protruded with pinch plates, and the two pinch plates are fastened to the external surface 132 . The pinch plate is used to realize the fixed connection between the conductive ring 12 and the insulating body 13 , and the pinch plate and the conductive ring 12 can be integrally injection-molded to improve structural strength and reduce processing difficulty. The two gussets are connected to two relative positions in the circumferential direction of the conductive ring 12, which can increase the area of the connection part between the conductive ring 12 and the insulating body 13 and the external contact surface 132, so as to improve the connection strength.
扣板不仅仅起到支撑固定连接的作用,还用以将导电环12与纽扣电池20的凸台222抵触接触形成的电导通传递到接触点133,以实现纽扣电池20的一极与第二电极金属连接区16的电导通,从而可配合提高导通稳定性。扣板与接触点133之间的连接方式为焊接,以降低连接难度,能够有效的减少接触电阻,并提高连接强度。The pinch plate not only plays the role of supporting the fixed connection, but also transfers the electrical conduction formed by the contact between the conductive ring 12 and the boss 222 of the button battery 20 to the contact point 133, so as to realize the connection between one pole of the button battery 20 and the second pole of the button battery 20. The electrical conduction of the electrode metal connection region 16 can cooperate to improve the conduction stability. The connection between the gusset plate and the contact point 133 is welding to reduce connection difficulty, effectively reduce contact resistance, and improve connection strength.
在一实施例中,所述绝缘粘接中层25的材质为PP(聚丙烯)、PFA(少量全氟丙基全氟乙烯基醚与聚四氟乙烯的共聚物)、PVDF(聚偏氟乙烯)、PTFE(聚四氟乙烯)、ETFE(乙烯-四氟乙烯共聚物)、PVC(聚氯乙烯)中的一种或多种。In one embodiment, the material of the insulating adhesive middle layer 25 is PP (polypropylene), PFA (copolymer of a small amount of perfluoropropyl perfluorovinyl ether and polytetrafluoroethylene), PVDF (polyvinylidene fluoride) ), PTFE (polytetrafluoroethylene), ETFE (ethylene-tetrafluoroethylene copolymer), PVC (polyvinyl chloride) in one or more.
聚乙烯(polyethylene,简称PE)是乙烯经聚合制得的一种热塑性树脂。在工业上,也包括乙烯与少量α-烯烃的共聚物。聚乙烯无臭,无毒,手感似蜡,具有优良的耐低温性能,化学稳定性好,能耐大多数酸碱的侵蚀。常温下不溶于一般溶剂,吸水性小,电绝缘性优良。Polyethylene (PE for short) is a thermoplastic resin obtained by polymerization of ethylene. In industry, it also includes copolymers of ethylene and a small amount of α-olefins. Polyethylene is odorless, non-toxic, feels like wax, has excellent low temperature resistance, good chemical stability, and can withstand most acids and alkalis. Insoluble in common solvents at room temperature, low water absorption, excellent electrical insulation.
聚丙烯是丙烯加聚反应而成的聚合物(Polypropylene,简称PP),系白色蜡状材料,外观透明而轻,易燃,熔点165℃,在155℃左右软化,使用温度范围为-30℃~140℃。改性PP是在PP的基础上改性得到,例如本实施例使用的改性PP是亲金属改性聚丙烯树脂(Metal Adhesive Polypropylene,以下简称亲金属改性PP),其可以是在PP的基础上通过共聚、接枝或者交联等化学改性的方法使其表面具备亲金属特性,从而可以与金属表面通过加热熔合,形成良好的结合密封。Polypropylene is a polymer formed by addition polymerization of propylene (Polypropylene, referred to as PP). It is a white waxy material with a transparent and light appearance, flammable, a melting point of 165°C, and softens at about 155°C. The operating temperature range is -30°C. ~140°C. Modified PP is modified on the basis of PP. For example, the modified PP used in this embodiment is a metal-friendly modified polypropylene resin (Metal Adhesive Polypropylene, hereinafter referred to as metal-friendly modified PP), which can be made in the PP On the basis of chemical modification methods such as copolymerization, grafting or cross-linking, the surface has metalophilic properties, so that it can be fused with the metal surface by heating to form a good bonding seal.
PFA中文名四氟乙烯—全氟烷氧基乙烯基醚共聚物(又名过氟烷基化物、可溶性聚四氟乙烯),其为少量全氟丙基全氟乙烯基醚与聚四氟乙烯的共聚物。熔融粘结性增强,溶体粘度下降,而性能与聚四氟乙烯相比无变化。此种树 脂可以直接采用普通热塑性成型方法加工成制品。PFA长期使用温度-200℃至260℃,有卓越的耐化学腐蚀性,对所有化学品都耐腐蚀,摩擦系数在塑料中最低,还有很好的电性能,其电绝缘性不受温度影响,有“塑料王”之称。PFA耐化学药品性与聚四氟乙烯相似,比偏氟乙烯好,抗蠕变性和压缩强度均比聚四氟乙烯好,拉伸强度高,伸长率可达100-300%;介电性好,耐辐射性能优异;阻燃性大;无毒害,具有生理惰性,可植入人体内。The Chinese name of PFA is tetrafluoroethylene-perfluoroalkoxy vinyl ether copolymer (also known as perfluoroalkylate, soluble polytetrafluoroethylene), which is a small amount of perfluoropropyl perfluorovinyl ether and polytetrafluoroethylene. of copolymers. The melt adhesion is enhanced, the melt viscosity is reduced, and the performance is unchanged compared with PTFE. This kind of resin can be directly processed into products by ordinary thermoplastic molding methods. PFA has a long-term service temperature of -200°C to 260°C, has excellent chemical corrosion resistance, is corrosion-resistant to all chemicals, has the lowest friction coefficient among plastics, and has good electrical properties, and its electrical insulation is not affected by temperature. , known as the "King of Plastics". PFA chemical resistance is similar to polytetrafluoroethylene, better than vinylidene fluoride, creep resistance and compressive strength are better than polytetrafluoroethylene, high tensile strength, elongation can reach 100-300%; dielectric Good resistance, excellent radiation resistance; high flame retardancy; non-toxic, physiologically inert, and can be implanted in the human body.
在一实施例中,所述纽扣电池20为二次可充电电池,以通过充电来实现重复使用,从而提高纽扣电池20的使用寿命。在需要对纽扣电池20充电时,只需将纽扣电池20从电池导线连接座10拆下即可,由此可降低纽扣电池2020的重复使用难度,提高重复使用率。In one embodiment, the button battery 20 is a secondary rechargeable battery, so as to achieve repeated use through charging, thereby increasing the service life of the button battery 20 . When the button battery 20 needs to be charged, it is only necessary to remove the button battery 20 from the battery wire connecting seat 10 , thereby reducing the difficulty of reusing the button battery 2020 and increasing the reusability.
在一实施例中,如图2和图3所示,所述金属弹性结构14设置为环形金属弹簧。环形金属弹簧可增大与导电外层24的接触面积,从而提高接触稳定性,以保证电导通稳定性。In one embodiment, as shown in FIG. 2 and FIG. 3 , the metal elastic structure 14 is configured as an annular metal spring. The annular metal spring can increase the contact area with the conductive outer layer 24, thereby improving the contact stability and ensuring the stability of electrical conduction.
此外,环形金属弹性对导电外层24产生的压力F1可沿环形作用于导电外层24,从而可使导电外层24的多个位置被压固于绝缘粘接中层25上,以增加压固面,进一步提高纽扣电池20的结构稳定性。In addition, the pressure F1 produced by the ring-shaped metal elasticity on the conductive outer layer 24 can act on the conductive outer layer 24 along the ring, so that multiple positions of the conductive outer layer 24 can be pressed and fixed on the insulating adhesive middle layer 25 to increase the compression. On the other hand, the structural stability of the button battery 20 is further improved.
在一实施例中,所述金属弹性结构14与所述导电外层24的接触位置,位于所述绝缘粘接中层25与焊接内层26粘接处边侧对应的位置。In one embodiment, the contact position between the metal elastic structure 14 and the conductive outer layer 24 is located at a position corresponding to the side where the insulating adhesive middle layer 25 and the welding inner layer 26 are bonded.
绝缘粘接中层25在中通孔部252的周缘会暴露于电解液中,即电解液容易从中通孔部252对绝缘粘接中层25进行腐蚀,使得绝缘粘接中层25与导电外层24的粘接处被腐蚀分离。The insulating bonding middle layer 25 will be exposed to the electrolyte at the periphery of the through hole 252, that is, the electrolyte is easy to corrode the insulating bonding middle layer 25 from the middle through hole 252, so that the insulating bonding middle layer 25 and the conductive outer layer 24 The bond is separated by corrosion.
金属弹性结构14临近中通孔部252的周沿,从而金属弹性结构14对导电外层24产生的压力可准确作用于导电外层24与绝缘粘接中层25的粘接缝处,以防止绝缘粘接中层25与导电外层24的粘接处被腐蚀分离,从而提高盖壳23在电解液中的结构稳定性。The metal elastic structure 14 is close to the periphery of the middle through hole portion 252, so that the pressure generated by the metal elastic structure 14 on the conductive outer layer 24 can accurately act on the bonding seam between the conductive outer layer 24 and the insulating bonding middle layer 25 to prevent insulation. The joint between the adhesive middle layer 25 and the conductive outer layer 24 is corroded and separated, thereby improving the structural stability of the cover shell 23 in the electrolyte.
在一实施例中,如图1和图3所示,所述外接面132设有一个所述第一电极金属连接区15,和两个所述第二电极金属连接区16,其中一个所述第二电极金属连接区16与所述第一电极金属连接区15相邻,另一个所述第二电极金属连接区16设置在与所述第一电极金属连接区15相对的一侧。In one embodiment, as shown in FIG. 1 and FIG. 3 , the outer connection surface 132 is provided with one first electrode metal connection region 15 and two second electrode metal connection regions 16, one of which is the The second electrode metal connection region 16 is adjacent to the first electrode metal connection region 15 , and another second electrode metal connection region 16 is disposed on a side opposite to the first electrode metal connection region 15 .
可以理解为设置一个正极金属连接区和两个负极金属连接区,或两个正 极金属连接区和一个负极金属连接区,其中一个正极金属连接区和一个负极金属连接区设置同侧相邻位置,另外一个正极金属连接区或负极金属连接区设置在另外一侧相对的位置,具体使用过程中,如果外接用电设备采用焊接的方式,可以优选的选择使用同侧相邻的正极金属连接区和负极金属连接区可以便于焊接;如果是进行抵触电导通的方式,可以优选的选择使用两侧相对的正极金属连接区和负极金属连接区可以便于抵触电导通受力的时候均匀性,进而提高稳定性。It can be understood as setting one positive metal connection area and two negative metal connection areas, or two positive metal connection areas and one negative metal connection area, wherein one positive metal connection area and one negative metal connection area are arranged adjacent to the same side, Another positive metal connection area or negative metal connection area is set at the opposite position on the other side. In the specific use process, if the external electrical equipment is welded, you can preferably choose to use the positive metal connection area adjacent to the same side and The negative metal connection area can facilitate welding; if it is a way of resisting electrical conduction, it is preferable to use the positive and negative metal connecting areas on opposite sides to facilitate the uniformity of the resistance to electrical conduction and improve stability. sex.
本发明还提出一种用电设备,该用电设备包括含有用电器件的电子设备主体和纽扣电池组件,该纽扣电池组件的具体结构参照上述实施例,由于本用电设备采用了上述所有实施例的全部技术方案,因此至少具有上述实施例的技术方案所带来的所有有益效果,在此不再一一赘述。其中,所述纽扣电池组件位于所述电子设备主体内,且所述用电器件的其中一极与所述第一电极金属连接区15电导通;另外一极与所述第二电极金属连接区16电导通。The present invention also proposes an electrical device, which includes an electronic device body containing an electrical device and a button battery assembly. The specific structure of the button battery assembly refers to the above-mentioned embodiments. Since this electrical device adopts all the above-mentioned implementations All the technical solutions of the above-mentioned embodiments, therefore at least have all the beneficial effects brought by the technical solutions of the above-mentioned embodiments, and will not be repeated here. Wherein, the button battery assembly is located in the main body of the electronic equipment, and one pole of the electrical device is electrically connected to the first electrode metal connection area 15; the other pole is electrically connected to the second electrode metal connection area 15. 16 is electrically conductive.
以上所述仅为本发明的可选实施例,并非因此限制本发明的专利范围,凡是在本发明的发明构思下,利用本发明说明书及附图内容所作的等效结构变换,或直接/间接运用在其他相关的技术领域均包括在本发明的专利保护范围内。The above descriptions are only optional embodiments of the present invention, and do not limit the patent scope of the present invention. Under the inventive concept of the present invention, the equivalent structural transformation made by using the description of the present invention and the contents of the accompanying drawings, or direct/indirect Application in other related technical fields is included in the patent protection scope of the present invention.

Claims (10)

  1. 一种纽扣电池组件,其特征在于,包括导线连接座和纽扣电池;A button battery assembly, characterized in that it includes a wire connection seat and a button battery;
    所述导线连接座包括外接板和导电环;The wire connection seat includes an external connection plate and a conductive ring;
    所述纽扣电池包括电芯、金属外壳和与所述金属外壳密封连接的盖壳;The button battery includes an electric core, a metal casing and a cover shell sealedly connected with the metal casing;
    所述盖壳包括导电外层、绝缘粘接中层和焊接内层,所述焊接内层包括内焊接侧部、内粘接中部和内通孔部,所述绝缘粘接中层包括中绝缘粘接部和中通孔部,所述导电外层包括外粘接部和外导电部,所述内焊接侧部与所述金属外壳的开口端焊接,所述中绝缘粘接部由在大于等于100℃时热收缩率为6%以下的绝缘防电解液腐蚀的材料融化后,与所述内粘接中部、所述外粘接部进行无缝粘接,且在冷却常温下与所述内粘接中部、所述外粘接部之间的粘接强度大于等于0.1N每平方毫米;The cover shell includes a conductive outer layer, an insulating bonding middle layer and a welding inner layer, the welding inner layer includes an inner welding side part, an inner bonding middle part and an inner through hole part, and the insulating bonding middle layer includes a middle insulating bonding part and a through-hole part, the conductive outer layer includes an outer bonding part and an outer conductive part, the inner welding side part is welded to the open end of the metal shell, and the middle insulating bonding part is formed at a value greater than or equal to 100 After melting the insulating and anti-electrolyte corrosion material with a thermal shrinkage rate of 6% or less at ℃, it is seamlessly bonded to the middle part of the inner bonding part and the outer bonding part, and is bonded to the inner bonding part at room temperature under cooling. The bonding strength between the middle part and the outer bonding part is greater than or equal to 0.1N per square millimeter;
    所述电芯的一极与所述焊接内层电导通,所述电芯的另外一极通过所述内通孔部和中通孔部与所述外导电部电导通;One pole of the battery cell is electrically connected to the soldered inner layer, and the other pole of the battery cell is electrically connected to the outer conductive part through the inner through hole part and the middle through hole part;
    所述金属外壳包括柱状主体和向外凸出的凸台;The metal shell includes a columnar body and an outwardly protruding boss;
    所述外接板包括绝缘本体、金属弹性结构、至少一个第一电极金属连接区和至少一个第二电极金属连接区;The external connection plate includes an insulating body, a metal elastic structure, at least one first electrode metal connection area and at least one second electrode metal connection area;
    所述绝缘本体具有相背设置的导通面和外接面,所述导通面设置有所述金属弹性结构,用于在发生弹性压缩时电性接触所述外导电部,所述外接面设置至少一个所述第一电极金属连接区和至少一个所述第二电极金属连接区;The insulating body has a conduction surface and an outer contact surface arranged opposite to each other, the conduction surface is provided with the metal elastic structure for electrically contacting the outer conductive part when elastic compression occurs, and the outer contact surface is provided with at least one said first electrode metal connection area and at least one said second electrode metal connection area;
    至少一个所述第一电极金属连接区与所述金属弹性结构电导通;At least one metal connection region of the first electrode is electrically connected to the metal elastic structure;
    导电环,连接于所述外接板,并位于所述外接板的导通面一侧,所述导电环沿所述外接板的周向延伸,以与所述外接板围合形成安装槽,所述安装槽用以收纳固定所述凸台,并与所述凸台电导通;The conductive ring is connected to the external connection plate and is located on one side of the conduction surface of the external connection plate. The conductive ring extends along the circumference of the external connection plate to form an installation groove surrounded by the external connection plate. The mounting groove is used to accommodate and fix the boss, and is electrically connected to the boss;
    至少一个所述第二电极金属连接区与所述导电环电导通。At least one metal connection area of the second electrode is electrically connected to the conductive ring.
  2. 如权利要求1所述的纽扣电池组件,其特征在于,所述导电环连接于所述外接面,所述外接面设有接触点,所述接触点与所述导电环电导通,并且所述接触点与所述第二电极金属连接区电导通。The button battery assembly according to claim 1, wherein the conductive ring is connected to the external surface, the external surface is provided with a contact point, and the contact point is electrically connected to the conductive ring, and the The contact point is electrically connected to the metal connection area of the second electrode.
  3. 如权利要求1所述的纽扣电池组件,其特征在于,所述第一电极金属连接区和所述第二电极金属连接区的材质为铜、镍、锡或这些元素的合金。The button cell assembly according to claim 1, wherein the material of the first electrode metal connection area and the second electrode metal connection area is copper, nickel, tin or an alloy of these elements.
  4. 如权利要求1所述的纽扣电池组件,其特征在于,所述绝缘粘接中层的材质为PP、PFA、PVDF、PTFE、ETFE和PVC中的一种或多种。The button cell assembly according to claim 1, wherein the material of the insulating adhesive middle layer is one or more of PP, PFA, PVDF, PTFE, ETFE and PVC.
  5. 如权利要求1所述的纽扣电池组件,其特征在于,所述纽扣电池为二次可充电电池。The button battery assembly according to claim 1, wherein the button battery is a secondary rechargeable battery.
  6. 如权利要求1至5任一项所述的纽扣电池组件,其特征在于,所述中绝缘粘接部与所述内粘接中部、所述外粘接部之间的粘接强度大于等于1N每平方毫米,且小于等于5N每平方毫米。The button battery assembly according to any one of claims 1 to 5, wherein the bonding strength between the middle insulating bonding part, the inner bonding middle part, and the outer bonding part is greater than or equal to 1N per square millimeter, and less than or equal to 5N per square millimeter.
  7. 如权利要求1至5任一项所述的纽扣电池组件,其特征在于,所述金属弹性结构设置为环形金属弹簧。The button cell assembly according to any one of claims 1 to 5, wherein the metal elastic structure is configured as an annular metal spring.
  8. 如权利要求1至5任一项所述的纽扣电池组件,其特征在于,所述金属弹性结构与所述导电外层的接触位置,位于所述绝缘粘接中层与焊接内层粘接处边侧对应的位置。The button battery assembly according to any one of claims 1 to 5, wherein the contact position between the metal elastic structure and the conductive outer layer is located at the edge of the bonding place between the insulating bonding middle layer and the welding inner layer The corresponding position on the side.
  9. 如权利要求1至5任一项所述的纽扣电池组件,其特征在于,所述外接面设有一个所述第一电极金属连接区,和两个所述第二电极金属连接区,其中一个所述第二电极金属连接区与所述第一电极金属连接区相邻,另一个所述第二电极金属连接区设置在与所述第一电极金属连接区相对的一侧。The button battery assembly according to any one of claims 1 to 5, wherein the outer surface is provided with one metal connection area of the first electrode and two metal connection areas of the second electrode, one of which is The second electrode metal connection area is adjacent to the first electrode metal connection area, and another second electrode metal connection area is disposed on a side opposite to the first electrode metal connection area.
  10. 一种电子设备,其特征在于,包括含有用电器件的电子设备主体以及如权利要求1至9任一项所述的纽扣电池组件,所述纽扣电池组件位于所述电子设备主体内,且所述用电器件的其中一极与所述第一电极金属连接区电导通;另外一极与所述第二电极金属连接区电导通。An electronic device, characterized in that it includes an electronic device body containing electrical devices and a button battery assembly according to any one of claims 1 to 9, the button battery assembly is located in the electronic device body, and the One pole of the electrical device is electrically connected to the metal connection area of the first electrode; the other pole is electrically connected to the metal connection area of the second electrode.
PCT/CN2021/141437 2021-08-06 2021-12-27 Button cell assembly and electronic device WO2023010779A1 (en)

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