WO2022252156A1 - Sintering apparatus and sintering process production device - Google Patents

Sintering apparatus and sintering process production device Download PDF

Info

Publication number
WO2022252156A1
WO2022252156A1 PCT/CN2021/097985 CN2021097985W WO2022252156A1 WO 2022252156 A1 WO2022252156 A1 WO 2022252156A1 CN 2021097985 W CN2021097985 W CN 2021097985W WO 2022252156 A1 WO2022252156 A1 WO 2022252156A1
Authority
WO
WIPO (PCT)
Prior art keywords
flue gas
sintering
medium
reaction
circulation pipeline
Prior art date
Application number
PCT/CN2021/097985
Other languages
French (fr)
Chinese (zh)
Inventor
高彦
朱明�
Original Assignee
秦皇岛新特科技有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 秦皇岛新特科技有限公司 filed Critical 秦皇岛新特科技有限公司
Priority to PCT/CN2021/097985 priority Critical patent/WO2022252156A1/en
Publication of WO2022252156A1 publication Critical patent/WO2022252156A1/en

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/56Nitrogen oxides
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B9/00Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity
    • F27B9/14Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity characterised by the path of the charge during treatment; characterised by the means by which the charge is moved during treatment
    • F27B9/20Furnaces through which the charge is moved mechanically, e.g. of tunnel type; Similar furnaces in which the charge moves by gravity characterised by the path of the charge during treatment; characterised by the means by which the charge is moved during treatment the charge moving in a substantially straight path tunnel furnace
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Definitions

  • the invention relates to the technical field of clinker production technology and equipment, in particular to a sintering device and sintering process production equipment.
  • Nitrogen oxides are one of the main sources of air pollution. There are many kinds of nitrogen oxides NO x : N 2 O, NO, NO 2 , N 2 O 3 , N 2 O 4 and N 2 O 5 , among which NO and NO 2 are important air pollutants.
  • the existing nitrogen oxide purification technologies mainly include: SNCR, SCR, activated carbon (coke) and oxidation method.
  • SNCR, SCR, and activated carbon (coke) methods all have the problem of ammonia escape.
  • the SNCR method has the problems of high flue gas temperature requirements and low reaction efficiency. SCR will inevitably generate solid waste.
  • reaction media can be introduced into the sintering material to achieve desulfurization and denitrification of flue gas, but due to the open structure above the sintering trolley, these media are easy to leak after being introduced into the sintering material , unable to control the amount of flux, resulting in poor removal of pollutants, and easy to cause both pollution.
  • the invention discloses a sintering device and a sintering process production equipment, which solves the problem of the removal of pollutants due to the open structure above the sintering trolley, and the reaction medium is easily leaked after being passed into the sintering material, and the amount cannot be controlled. Poor, and it is easy to cause pollution of both.
  • a sintering device including a transport mechanism for transporting sintering materials, and further comprising: a reaction cover, the reaction cover is arranged above the transport mechanism, and the reaction cover is connected to the The transportation mechanism encloses a reaction space, and a medium addition port for adding a medium is opened on the reaction cover, and the medium addition port communicates with the reaction space.
  • the medium addition port is located near the top of the reaction hood.
  • reaction hood is provided with a valve for controlling the amount of medium added.
  • the medium addition port is used for introducing flue gas.
  • the sintering device also includes: a draft mechanism, which is arranged under the transportation mechanism; an ignition mechanism, which is used to ignite and burn the briquette; a first flue gas circulation pipeline, the first The first end of the flue gas circulation pipeline communicates with the sintering flue outlet of the exhaust mechanism, the second end of the first flue gas circulation pipeline communicates with the medium addition port, and part of the smoke generated by the sintering material The gas is circulated into the reaction hood through the first flue gas circulation pipeline.
  • the flue gas includes one or more of carbon dioxide, water vapor, water, sulfur dioxide, nitrogen oxides, carbon monoxide, and dioxins.
  • reaction hood is also provided with an external flue gas addition port for introducing external flue gas.
  • the sintering device further includes: a medium adding mechanism, the discharge port of the medium adding mechanism communicates with the medium adding port, the medium adding mechanism is used to spray reducing medium to the sintering material, and the medium adding mechanism
  • the output reducing medium reacts with the nitrogen oxides in the flue gas or with the carbon in the sintered material to generate a reducing agent and release heat.
  • the transportation mechanism is a sintering trolley, and the sintering material is arranged in the sintering trolley, and the sintering material burns during the movement of the sintering trolley to form a burnt layer and a burning layer distributed from top to bottom. and the sintered material layer, the medium reacts with the burned layer and the sintered material layer after passing through the burned layer and releases heat.
  • the medium adding mechanism transports the medium above the burnt layer of the sintered material, and the medium is sucked into the interior of the sintered material and the carbon in the burning layer and the sintered material layer by the ventilation mechanism.
  • Contact should generate flammable gas, which will undergo oxidation reaction and release heat.
  • the air extraction mechanism includes a fan, a plurality of sintering air boxes and a sintering flue, all the sintering air boxes are arranged under the transportation mechanism, and all the sintering air boxes are connected to the sintering flue, the The fan is arranged on the sintering flue.
  • the sintered wind box includes: a wind box body, which has an inner cavity for collecting smoke, and a smoke inlet connected to the inner cavity is arranged on the wind box body; a reactor, the reaction The reactor has a purification chamber, and the reactor also has a smoke exhaust port communicating with the purification chamber, the purification chamber communicates with the inner chamber, and the purification chamber is used to purify the flue gas in the inner chamber.
  • a sintering process production equipment including the above-mentioned sintering device.
  • the sintering device has a sintering flue outlet
  • the sintering process production equipment also includes: a flue gas purification pipeline, and the flue gas purification pipeline includes correspondingly arranged flue gas heating inlets and flue gas heating outlets, so The flue gas heating inlet communicates with the sintering flue outlet; the sintering material cooling device is arranged between the flue gas heating inlet and the flue gas heating outlet, and the flue gas generated by the sintering device passes through the The flue gas heating inlet enters the sintering material cooling device, the flue gas cools the burned sintering material, and at the same time, the burned sintering material heats the passing flue gas, and the heated flue gas enters the flue gas heating outlet ;
  • the tail reactor the tail reactor communicates with the flue gas heating outlet through a pipeline, and the tail reactor is used for purifying the heated flue gas.
  • the sintering material cooling device includes a cooling zone, the flue gas heating inlet is located below the cooling zone, and the flue gas heating outlet is located above the cooling zone.
  • the sintering process production equipment also includes: a second flue gas circulation pipeline, the first end of the second flue gas circulation pipeline is connected to the flue gas outlet of the tail reactor and/or the flue gas The heating outlet is communicated, and the second end of the second flue gas circulation pipeline is communicated with the medium addition port of the reaction hood.
  • the sintering device further includes: a first flue gas circulation pipeline, the first end of the first flue gas circulation pipeline communicates with the sintering flue outlet of the draft mechanism, and the first flue gas circulation The second end of the pipeline communicates with the inside of the reaction hood, and part of the flue gas generated by the sintering material passes through the first flue gas circulation pipeline into the reaction hood.
  • the flue gas contains one or more of carbon dioxide, water vapor, water, sulfur dioxide, nitrogen oxides, carbon monoxide, and dioxins.
  • the cooling zone includes a first cooling zone and a second cooling zone, the temperature of the second cooling zone is higher than the temperature of the first cooling zone;
  • the flue gas purification pipeline also includes a secondary heating pipeline , the secondary heating pipeline includes a secondary heating inlet and a secondary heating outlet, the secondary heating inlet is located above the first cooling zone, and the secondary heating outlet is located below the second cooling zone; The flue gas heating inlet is located below the first cooling zone, and the flue gas heating outlet is located above the second cooling zone.
  • the secondary heating pipeline is provided with a catalyst adding device and/or a reducing agent adding device.
  • the sintering process production equipment also includes: a second flue gas circulation pipeline, the first end of the second flue gas circulation pipeline is connected to the flue gas outlet of the tail reactor and/or the flue gas The heating outlet is in communication, and the second end of the second flue gas circulation pipeline is in communication with the inside of the reaction hood.
  • the sintering device further includes: a first flue gas circulation pipeline, the first end of the first flue gas circulation pipeline communicates with the sintering flue outlet of the draft mechanism, and the first flue gas circulation The second end of the pipeline communicates with the inside of the reaction hood, and part of the flue gas generated by the sintering material passes through the first flue gas circulation pipeline into the reaction hood.
  • the flue gas contains one or more of carbon dioxide, water vapor, water, sulfur dioxide, nitrogen oxides, carbon monoxide, and dioxins.
  • the sintering device of the present invention can cooperate with the transport mechanism to form a reaction space by setting a reaction hood to prevent the leakage of the medium and the products of the medium combustion. At the same time, during the combustion of the medium, the combustion products can fill the inside of the reaction hood to make the gas distribution more uniform. , Improve the reaction effect of desulfurization and denitrification.
  • Fig. 1 is a schematic structural view of a sintering device according to Embodiment 1 of the present invention
  • Fig. 2 is a schematic structural view of a sintering device according to Embodiment 2 of the present invention.
  • Fig. 3 is a schematic structural view of the exhaust mechanism of the sintering device according to Embodiment 1 of the present invention.
  • Fig. 4 is the schematic structural view of the sintering process production equipment of the third embodiment of the present invention.
  • FIG. 5 is a schematic structural view of the sintering process production equipment of Embodiment 4 of the present invention.
  • FIG. 6 is a schematic structural view of the sintering process production equipment of Embodiment 5 of the present invention.
  • FIG. 7 is a schematic structural view of the sintering process production equipment of Embodiment 6 of the present invention.
  • Fig. 8 is a schematic structural view of the sintering process production equipment of Embodiment 7 of the present invention.
  • Fig. 9 is a schematic structural view of the sintering process production equipment of the eighth embodiment of the present invention.
  • FIG. 10 is a schematic structural view of the sintering material cooling device of the sintering process production equipment of the third embodiment of the present invention.
  • Fig. 11 is a schematic structural view of the sintering process production equipment of Embodiment 9 of the present invention.
  • Fig. 12 is a schematic structural view of the sintering process production equipment of Embodiment 10 of the present invention.
  • Fig. 13 is a schematic structural view of the sintering process production equipment of the eleventh embodiment of the present invention.
  • Fig. 14 is a schematic structural view of the sintering process production equipment of Embodiment 12 of the present invention.
  • Embodiment 1 shown in Figure 1 discloses a sintering device, including a reaction hood 11, a transportation mechanism 12 for transporting sintering material, an air draft mechanism 13 arranged below the transportation mechanism 12, and a sintering mechanism for igniting the sintering material
  • the ignition mechanism 14, the reaction cover 11 cover is arranged on the top and/or side of the transport mechanism 12, the reaction cover 11 and the transport mechanism 12 enclose the reaction space where the medium reacts with the ignited sintering material, and the reaction cover 11 is provided with a A medium addition port 111 for adding a medium, and the medium addition port 111 communicates with the reaction space.
  • the medium is sprayed on the surface of the binder material through the medium addition port 111.
  • the medium can be burned above the sintered material to generate combustion products or the medium itself is the combustion product after burning in other places, and then under the action of the exhaust mechanism, the The combustion products are inhaled into the sintering material.
  • the combustion products and the components in the sintering material undergo oxidation-reduction reactions, and the combustion products are reduced to a reducing medium with reducing properties, such as carbon dioxide in the combustion products and sintering.
  • the carbon in the raw material reacts to form carbon monoxide
  • the water vapor or water in the combustion product reacts with the carbon in the sintered material to generate hydrogen, which can effectively adjust the reducing atmosphere inside the sintered material.
  • the reducing medium can convert nitrogen
  • the oxides are reduced to nitrogen, thereby reducing the emission of nitrogen oxides, and the cost is low.
  • the sintering device of the present invention can cooperate with the transport mechanism to form a reaction space by setting a reaction hood to prevent the leakage of the medium and the products of the medium combustion. Uniform, improve the removal effect of pollutants.
  • the medium addition port 111 is located at the upper middle or side of the reaction hood 11, and the bottom of the reaction hood 11 and the transportation mechanism 12 can be sealed, or a ventilation mechanism 13 can be used to form an internal reaction hood 11.
  • the height of the medium addition can be improved, the reduction medium can be sprayed conveniently, the diffusion of the medium is more conducive, the reaction efficiency is improved, and the waste of the reduction medium is reduced; by connecting the reaction cover 11 with The transportation mechanism 12 is sealed or a slightly negative pressure environment is formed inside the reaction hood 11 through the exhaust mechanism 13, which can more effectively prevent the flue gas from escaping and improve the effect of desulfurization and denitrification.
  • reaction hood 11 is provided with a valve 112 for controlling the amount of medium added, so as to effectively control the combustion atmosphere of the sintering material, such as oxygen content and temperature, and to suppress the generation of nitrogen oxides.
  • the medium addition port 111 is used to introduce flue gas, which can be external flue gas, such as: flue gas from ironmaking, boiler combustion, etc., or flue gas generated by the sintering device 10 itself. Or a mixture of the two.
  • flue gas can be external flue gas, such as: flue gas from ironmaking, boiler combustion, etc., or flue gas generated by the sintering device 10 itself. Or a mixture of the two.
  • the dioxins in the external flue gas are decomposed in the high-temperature section of the sintering process, and the carbon monoxide undergoes an oxidation reaction near the combustion layer, which can reduce nitrogen oxides or react with other oxides to provide heat for the sintering material layer.
  • the sulfur dioxide in the external flue gas is adsorbed or reduced to elemental sulfur when passing through the sinter bed.
  • the flue gas generated by the sintering device 10 itself is used as an example.
  • the sintering device 10 further includes a first flue gas circulation pipeline 15, the first end of the first flue gas circulation pipeline 15 communicates with the sintering flue outlet 1331 of the draft mechanism 13, and the first flue gas circulation pipe The second end of the path 15 communicates with the medium addition port 111 , and part of the flue gas generated by the sintering material passes through the first flue gas circulation line 15 into the reaction hood 11 .
  • the generated flue gas (mainly including one or more of carbon dioxide, water vapor, water, sulfur dioxide, nitrogen oxides, and dioxins) is sucked away by the exhaust mechanism 13 , part of the flue gas returns to the reaction hood 11 through the circulation pipeline, and the other part of the flue gas is discharged through the chimney.
  • the carbon dioxide and water vapor in the flue gas react with the carbon element in the carbon additive in the sintering material near the sintering combustion layer. Generate carbon monoxide, hydrogen and other reducing gases, forming a reducing atmosphere near the sintering combustion layer.
  • carbon additives refer to materials that can directly or indirectly make sintered materials form carbon-containing mixtures, such as coke powder, biomass, coal, carbon powder, etc.
  • the oxygen in the circulating flue gas can also be used as a combustion aid. By increasing the combustion aid, the reaction efficiency can be improved and the production of nitrogen oxides can be further reduced.
  • the generated carbon monoxide and hydrogen can reduce nitrogen oxides and sulfides.
  • the nitrogen oxides in the flue gas introduced into the sintering material layer are reduced to nitrogen in the reducing gas near the sintering combustion layer.
  • the nitrogen oxides produced by the sintering material combustion It is also reduced to nitrogen.
  • the sulfur dioxide introduced into the flue gas of the sinter bed is adsorbed by the sinter and/or reduced to elemental sulfur.
  • the monoxide in the flue gas introduced into the sinter bed is oxidized to carbon dioxide.
  • the dioxins introduced into the sinter bed are pyrolyzed when passing through the sinter bed.
  • the flue gas is introduced into the reaction hood 11 through the medium addition port, which effectively overcomes the problem in the prior art that the by-products produced after denitrification need to be treated, and avoids further environmental pollution such as leakage of ammonia or ozone.
  • the sintering device 10 also includes a medium addition mechanism, the outlet of the medium agent addition mechanism communicates with the medium addition port 111, the medium addition mechanism is used to spray the reducing medium to the sintering material, and the medium addition mechanism The output reducing medium and sintering material deflagrate.
  • the medium output by the medium adding mechanism contacts and deflagrates with the sintered material ignited by the ignition mechanism 14, and the ignition mechanism 14 ignites the sintered material, and under the action of the exhaust mechanism 13, the sintered material burns from top to bottom and heats up.
  • the transportation mechanism 12 drives the burning sintering material to move to the medium adding mechanism.
  • the medium adding mechanism adds the medium to the sintering material so that the medium is in contact with the sintering material, and at the same time the medium is sintered. Deflagration is caused by the influence of the temperature of the material.
  • the medium includes materials and/or combustible substances that chemically react with carbon additives in the sintered material and/or combustible substances, that is, the medium can produce flammable substances for chemical reactions with coal and/or coke powder and biomass in the sintered material
  • Any material of a substance which can be one material or a mixture of multiple materials, and the medium can also be a mixture of a material and a flammable substance, or a mixture of a single flammable substance, such as a variety of flammable gases Mixing, flammable gas and flammable liquid mixing etc. can all realize the purpose of the present invention.
  • the medium includes one or more of the following substances: carbon monoxide, methane, propane, acetylene, hydrogen, methanol, ethanol, gas, natural gas, gasoline, heavy oil, coal powder, charcoal, coke, wood chips, hydrogen sulfide, Hydrogen cyanide, phosgene, n-butane, n-hexane, n-heptane, n-pentane, propanol, methyl ethyl ketone, vinyl acetate, silane, cyclohexane, hydrogen chloride, butyne, liquefied petroleum gas, petroleum gas, ether, toluene , benzene, acetone, propyne, ethylene, propylene, butene, butane, coal water slurry, coke, wood chips and other combustible substances, or water and water vapor that can decompose hydrogen at high temperature, and hydrogen can oxidize oxidants or nitrogen undergo a
  • the medium can be water or water vapor.
  • the liquid water is affected by the temperature of the sintered material into water vapor.
  • the water vapor reacts with the coal or coke powder in the sintered material to generate combustible gases (carbon monoxide and hydrogen).
  • Carbon monoxide and hydrogen can reduce the smoke
  • Nitrogen oxides and sulfides in the gas undergo oxidation-reduction reactions to generate water, carbon dioxide, nitrogen, sulfur, etc., and high temperature will decompose dioxins, thereby removing pollutants in the flue gas.
  • the reductant that adopts in the present invention can be a kind of in above-mentioned material, also can be the mixture of multiple above-mentioned materials, as multiple gas mixing, solid mixing, gas and liquid mixing etc. all can realize, and these mixture cost are all very low. Inexpensive and non-polluting.
  • the medium also includes a combustion oxidant including one or more of oxygen, air, or recycled exhaust gas.
  • the transportation mechanism 12 is a sintering trolley, and the sintering material is placed in the sintering trolley, and the sintering material burns during the movement of the sintering trolley to form a burnt layer, a combustion layer and a sintered layer distributed from top to bottom.
  • Material layer after the medium passes through the burned layer, it reacts with the burning layer and the sintered material layer to deflagrate, that is, deflagration is formed inside the sintered material, and the interior of the sintered material can form a relatively closed space, so that when the medium is in contact with the sintered material.
  • Most of the high temperature and high pressure act on the sintered material, increasing the effect of deflagration.
  • the medium adding mechanism is arranged inside the reaction hood 11 to spray the medium above the burned layer of the sintered material, and the medium is sucked into the sintered material by the exhaust mechanism 13 and deflagrates in contact with the burning layer and the sintered material layer to ensure the deflagration effect.
  • the exhaust mechanism 13 includes a fan, a plurality of sintering bellows and a sintering flue 133, all the sintering bellows are arranged under the transport mechanism 12, and all the sintering bellows are connected with the sintering flue 133, and the fans are arranged on the sintering flue 133 ,
  • the fan can discharge the exhaust gas during the combustion process of the sintering material, and can also suck the medium into the sintering material for deflagration.
  • the sintered wind box includes a wind box body 131 and a reactor 132, the wind box body 131 has an inner cavity 1311 for collecting flue gas, and the bellows body 131 is also provided with a smoke inlet communicating with the inner cavity 1311
  • the reactor 132 has a purification chamber 1322, and the reactor 132 also has a smoke outlet 1323 communicating with the purification chamber 1322.
  • the purification chamber 1322 communicates with the inner chamber 1311, and the purification chamber 1322 is used to purify the flue gas in the inner chamber 1311.
  • the flue gas is collected into the inner cavity 1311 through the bellows body 131, and the flue gas is purified for the first time through the reactor 132 communicated with the inner cavity 1311, thereby reducing harmful substances in the flue gas and reducing the pressure of the back-end purification process , improve the purification effect.
  • the reactor 132 includes a shell 1321 and a support 1324.
  • a clean chamber 1322 is formed in the shell 1321.
  • a smoke outlet 1323 is provided on the shell 1321.
  • the support 1324 is arranged in the clean chamber 1322.
  • a flow structure, the support 1324 is provided with a purification layer 1325 for reacting with flue gas. By setting the flow structure on the support member 1324, the flue gas is guided by the flow structure and reacts with the purification layer 1325, thereby achieving a purification effect.
  • the reactor 132 is a desulfurization and denitrification reactor
  • the purification layer 1325 includes alkaline mineral materials or substances capable of reacting with or catalyzing the reaction of sulfur and nitrogen oxides in the flue gas.
  • the purification layer 1325 can chemically react with the substances in the flue gas, especially alkaline substances, nitrogen oxides and sulfides in the flue gas at a certain temperature, thereby reducing the concentration of NOx and sulfides in the flue gas content, so as to effectively reduce the cost of equipment under the premise of ensuring that the NO x and sulfide content in the final flue gas reaches the standard.
  • the support member 1324 is an orifice plate, and the flow-passing structure is an air hole on the orifice plate.
  • the orifice plate is used as the support, and the air holes on the orifice plate are used to guide the flue gas to react with the substances in the purification layer, so as to achieve the purpose of purifying the flue gas.
  • the support member 1324 can also be a screen, and the flow-passing structure is a mesh of the screen.
  • the screen is used as the support, because the sieve hole is small, the flow rate of the flue gas can be reduced, the time for the flue gas to pass through the purification layer is prolonged, and it can fully react with the purification layer to improve the purification effect, and the small sieve hole can play a role The role of dust removal.
  • the smoke outlet 1323 is arranged below the support member 1324, and the support member 1324 is rotatable relative to the inner wall of the purification chamber 1322, and the support member 1324 can separate the purified purification layer 1325 from the support member 1324 by rotating, and Exhausted from the smoke exhaust port 1323.
  • the support member 1324 By making the support member 1324 rotatable relative to the inner wall of the purification chamber 1322, when the purification material of the purification layer needs to be replaced, the purified purification layer 1325 can be separated from the support member 1324 by rotating the support member 1324, and can be removed from the smoke exhaust port 1323 discharge to facilitate the replacement and cleaning of the reactor 132.
  • a hatch for replacing the purification layer 1325 is also provided on the casing 1321.
  • the sintering device adopts a belt-type sintering machine
  • the sintering device can also adopt other sintering machines, for example, an on-machine cooling sintering machine.
  • a sintering process production equipment including the above-mentioned sintering device.
  • the sintering device 10 has a sintering flue outlet 1331, and the sintering process production equipment also includes a flue gas purification pipeline 20, a sintering material cooling device 30 and a tail reactor 40, and the flue gas purification pipe
  • the road 20 includes a corresponding flue gas heating inlet 21 and a flue gas heating outlet 22, the flue gas heating inlet 21 communicates with the sintering flue outlet 1331; the sintering material cooling device 30 is arranged between the flue gas heating inlet 21 and the flue gas heating outlet 22 During the period, the flue gas generated by the sintering device 10 enters the sintering material cooling device 30 through the flue gas heating inlet 21, and the flue gas cools the burned sintering material, and at the same time, the burned sintering material heats the passing flue gas, in order to enhance
  • the denitrification effect can be achieved by spraying reducing media such as carbon monoxide, hydrogen, urea,
  • the reducing medium is oxidized and reduced with the nitrogen oxides in the flue gas under the heating of the sintering material React to generate nitrogen, water and carbon dioxide, thereby enhancing the denitrification effect.
  • the heated flue gas enters the flue gas heating outlet 22; the tail reactor 40 communicates with the flue gas heating outlet 22 through a pipeline, and the tail reactor 40 is used to purify the heated flue gas (mainly dust removal) and waste heat recovery .
  • the flue gas of the sintering material is exchanged with the high-temperature sintering material to be cooled. While cooling the high-temperature sintering material, the high-temperature The sintering material also heats the flue gas, and then purifies the heated flue gas through the tail reactor 40, without adding additional heating equipment to heat the flue gas, thereby reducing costs, improving purification effect and energy utilization rate.
  • the flue gas enters the exhaust mechanism 13 of the sintering device 10, it passes through the sintering flue, the head dust removal device, the sintering fan, the desulfurization tower, the induced draft fan, and then enters the flue gas heating inlet 21, and passes through the sintering material cooling device 30.
  • the blower cooler installed above enters the flue gas heating outlet 22, and finally enters the dust removal device and is discharged from the chimney under the action of the fan downstream of the dust removal device.
  • the sintering material cooling device 30 includes a cooling zone 31 , the flue gas heating inlet 21 is located below the cooling zone 31 , and the flue gas heating outlet 22 is located above the cooling zone 31 .
  • the flue gas heating inlet 21 and the flue gas heating outlet 22 are respectively above and below the cooling zone 31, so the low-temperature flue gas can be heated more fully after entering the cooling zone 31, and after the heated flue gas rises, it can directly
  • the flue gas enters the tail reactor 40 for purification through the flue gas heating outlet 22 above the cooling zone 31 , so a good reaction temperature can be ensured and the flue gas purification effect can be improved.
  • the cooling zone 31 can also purify carbon monoxide, nitrogen oxides, dioxins, and white smoke plumes in the flue gas when the flue gas passes through.
  • carbon monoxide can reduce nitrogen oxides, and carbon monoxide can also react with oxygen to generate carbon dioxide, and carbon monoxide can also react with iron oxides to generate low-priced iron oxides, even elemental iron , while releasing heat.
  • Dioxin is decomposed when passing through the high-temperature sinter, and the white plume is mainly formed by water vapor. When the temperature of the smoke increases, the white plume disappears. At the same time, the water vapor in the flue gas accelerates the cooling process of the sinter.
  • a reducing medium such as carbon monoxide, hydrogen, urea, ammonia, etc.
  • the reducing medium will undergo redox with the nitrogen oxides in the flue gas under the heating of the sintering material. React to generate nitrogen, water and carbon dioxide, thereby enhancing the denitrification effect.
  • Embodiment 4 shown in FIG. 5 also discloses a sintering process production equipment.
  • the sintering process production equipment also includes a second flue gas circulation pipeline 50, the second The first end of the second flue gas circulation pipeline 50 communicates with the flue gas outlet of the tail reactor 40 , and the second end of the second flue gas circulation pipeline 50 communicates with the medium addition port 111 of the reaction hood 11 .
  • the flue gas purified by the tail reactor 40 includes a large amount of carbon dioxide, water vapor, water, part of the flue gas returns to the reaction hood 11 through the second flue gas circulation pipeline 50, and the other part of the flue gas is discharged through the chimney.
  • Carbon dioxide and water vapor react with the carbon element in the carbon additive in the sintering material near the sintering combustion layer to generate a large amount of reducing gases such as carbon monoxide and hydrogen, forming a reducing atmosphere near the sintering combustion layer.
  • reducing gases such as carbon monoxide and hydrogen
  • first end of the second flue gas circulation pipeline 50 can not only communicate with the flue gas outlet of the tail reactor 40, but also communicate with the flue gas heating outlet (22), or communicate with both connected.
  • carbon additives refer to materials that can directly or indirectly make sintered materials form carbon-containing mixtures, such as coke powder, biomass, coal, carbon powder, etc.
  • the oxygen in the circulating flue gas can also be used as a combustion aid. By increasing the combustion aid, the reaction efficiency can be improved and the production of nitrogen oxides can be further reduced.
  • the generated carbon monoxide and hydrogen can reduce nitrogen oxides and sulfides.
  • the nitrogen oxides in the flue gas introduced into the sintering material layer are reduced to nitrogen in the reducing gas near the sintering combustion layer.
  • the nitrogen oxides produced by the sintering material combustion It is also reduced to nitrogen.
  • the sulfur dioxide introduced into the flue gas of the sinter bed is adsorbed by the sinter and/or reduced to elemental sulfur.
  • the monoxide in the flue gas introduced into the sinter bed is oxidized to carbon dioxide.
  • the dioxins introduced into the sinter bed are pyrolyzed when passing through the sinter bed.
  • the flue gas is introduced into the reaction hood 11 through the medium addition port, which effectively overcomes the problem in the prior art that the by-products produced after denitrification need to be processed, and at the same time avoids further environmental pollution such as leakage of ammonia or ozone.
  • FIG 6 it is Embodiment 5 of the present invention.
  • the sintering device also includes a first flue gas circulation pipeline 15, and the first end of the first flue gas circulation pipeline 15 It communicates with the sintering flue outlet 1331 of the exhaust mechanism 13, and the second end of the first flue gas circulation pipeline 15 communicates with the medium addition port 111. Part of the flue gas generated by the sintering material passes through the first flue gas circulation pipeline 15 to the reaction hood within 11.
  • the flue gas generated in the sintering device 10 can be led back to the reaction hood 11 through the first flue gas circulation pipeline 15, because the flue gas generated in the sintering device 10 has not passed through Subsequent purification, therefore, includes not only carbon dioxide, water vapor, water, but also one or more of sulfur dioxide, nitrogen oxides, and dioxins.
  • the carbon element in the carbon additive reacts near the sintering combustion layer to generate reducing gases such as carbon monoxide and hydrogen, and forms a reducing atmosphere near the sintering combustion layer.
  • the flue gas can be circulated multiple times, and sulfur dioxide, nitrogen oxides, and dioxins in the flue gas can be removed during the multiple circulation process, Carbon dioxide, water vapor, and water are reused repeatedly to generate carbon monoxide and hydrogen, so that a reducing atmosphere is always formed near the sintering material, which can further inhibit the formation of nitrogen oxides, ensure the treatment of nitrogen oxides, and realize denitrification of sintering flue gas
  • the carbon dioxide in the flue gas can be recycled and reused to achieve carbon neutrality.
  • the cooling zone 31 includes a first cooling zone 311 and a second cooling zone 312, the temperature of the second cooling zone 312 is higher than the temperature of the first cooling zone 311;
  • the flue gas purification pipeline 20 also includes a secondary heating pipeline 23, and the secondary heating pipeline 23 includes a secondary heating inlet 231 and a secondary heating outlet 232, the secondary heating inlet 231 is located above the first cooling zone 311, and the secondary heating outlet 232 is located below the second cooling zone 312; the flue gas heating inlet 21 is located below the first cooling zone 311, and the flue gas heating outlet 22 is located at above the second cooling zone 312 .
  • the cooling zone 31 is set as a first cooling zone 311 and a second cooling zone 312.
  • the sintered material that has been cooled for a long time is in the first cooling zone 311, and the sintered material that has been cooled for a short time or has just been heated is in the second cooling zone 312. Therefore, the temperature of the second cooling zone 312 is higher than the temperature of the first cooling zone 311.
  • the low-temperature flue gas is firstly heated through the first cooling zone 311 with a lower temperature, and then passed through the second cooling zone.
  • the heating pipeline 23 transports the initially heated flue gas to the second cooling zone with a higher temperature for further heating. Through secondary heating, the heat exchange efficiency can be greatly improved, and the whitening effect of the flue gas can be ensured.
  • the temperature can reach the temperature at which the reaction occurs, thereby ensuring the effect of removing carbon monoxide and denitrification.
  • the cooling temperature of the clinker can be further reduced, and the flue gas temperature for waste heat recovery can be increased.
  • a reducing medium such as carbon monoxide, hydrogen, urea, ammonia, etc., can be sprayed, and the reducing medium is heated by the sintering material.
  • the nitrogen oxides in the flue gas undergo redox reactions to generate nitrogen, water and carbon dioxide, thereby enhancing the denitrification effect.
  • the secondary heating pipeline 23 is provided with a catalyst adding device and/or a reducing agent adding device.
  • a catalyst adding device By installing a catalyst adding device, the catalyst can be added to increase the reaction efficiency, thereby increasing the effect of desulfurization and denitrification.
  • Embodiment 7 also discloses a sintering process production equipment.
  • the sintering process production equipment also includes a second The flue gas circulation pipeline 50, the first end of the second flue gas circulation pipeline 50 communicates with the flue gas outlet of the tail reactor 40, the second end of the second flue gas circulation pipeline 50 communicates with the medium addition port of the reaction hood 11 111 is connected.
  • the flue gas passes through the first cooling zone 311, the second cooling zone 312 and the secondary heating pipeline 23.
  • the flue gas has undergone a round of desulfurization and denitrification, and the dioxin in the flue gas is also very small, and then passes through the tail reactor 40 Purification, including a large amount of carbon dioxide and water vapor in the flue gas, part of the flue gas returns to the reaction hood 11 through the second flue gas circulation pipeline 50, and the other part of the flue gas is discharged through the chimney, the carbon dioxide and water vapor in the flue gas are combined with the sintering
  • the carbon element in the carbon additive in the material reacts near the sintering combustion layer to generate a large amount of reducing gases such as carbon monoxide and hydrogen, and forms a reducing atmosphere near the sintering combustion layer.
  • the specific chemical equation of the reaction between carbon and combustion products is as follows:
  • first end of the second flue gas circulation pipeline 50 can not only communicate with the flue gas outlet of the tail reactor 40, but also communicate with the flue gas heating outlet 22, or communicate with both at the same time.
  • carbon additives refer to materials that can directly or indirectly make sintered materials form carbon-containing mixtures, such as coke powder, biomass, coal, carbon powder, etc.
  • the oxygen in the circulating flue gas can also be used as a combustion aid. By increasing the combustion aid, the reaction efficiency can be improved and the production of nitrogen oxides can be further reduced.
  • the generated carbon monoxide and hydrogen can reduce nitrogen oxides and sulfides.
  • the nitrogen oxides in the flue gas introduced into the sintering material layer are reduced to nitrogen in the reducing gas near the sintering combustion layer.
  • the nitrogen oxides produced by the sintering material combustion It is also reduced to nitrogen.
  • the sulfur dioxide introduced into the flue gas of the sinter bed is adsorbed by the sinter and/or reduced to elemental sulfur.
  • the monoxide in the flue gas introduced into the sinter bed is oxidized to carbon dioxide.
  • the dioxins introduced into the sinter bed are pyrolyzed when passing through the sinter bed.
  • the flue gas is introduced into the reaction hood 11 through the medium addition port, which effectively overcomes the problem in the prior art that the by-products produced after denitrification need to be treated, and avoids further environmental pollution such as leakage of ammonia or ozone.
  • the sintering device also includes a first flue gas circulation pipeline 15, the first end of the first flue gas circulation pipeline 15 It communicates with the sintering flue outlet 1331 of the exhaust mechanism 13, and the second end of the first flue gas circulation pipeline 15 communicates with the reaction hood. Part of the flue gas generated by the sintering material passes through the first flue gas circulation pipeline 15 into the reaction hood 11. .
  • the flue gas generated in the sintering device 10 can be led back to the reaction hood 11 through the first flue gas circulation pipeline 15, because the flue gas generated in the sintering device 10 has not passed through Subsequent purification, therefore, includes not only carbon dioxide, water vapor, water, but also one or more of sulfur dioxide, nitrogen oxides, and dioxins.
  • the carbon element in the carbon additive reacts near the sintering combustion layer to generate reducing gases such as carbon monoxide and hydrogen, and forms a reducing atmosphere near the sintering combustion layer.
  • the flue gas can be circulated multiple times, and sulfur dioxide, nitrogen oxides, and dioxins in the flue gas can be removed during the multiple circulation process, Carbon dioxide, water vapor, and water are reused repeatedly to generate carbon monoxide and hydrogen, so that a reducing atmosphere is always formed near the sintering material, which can further inhibit the formation of nitrogen oxides and sulfides, ensure the treatment of nitrogen oxides, and realize the sintering process.
  • Shown in Fig. 10 can be a kind of specific structure of sintered material cooling device 30, comprise bearing platform 32, dry mist generator 33 and blower fan 34, sintered material is arranged on the bearing platform 32, coolant is in the dry mist generator 33 After being atomized, it is sent to the carrier platform 32, and the atomized coolant is sprayed or adsorbed onto the carrier platform 32 to exchange heat with the high-temperature sintered material.
  • the loading platform 32 is provided with a flue gas heating inlet 21, the inlet of the dry mist generator 33 communicates with the air inlet of the fan 34, and the air outlet of the fan 34 communicates with the flue gas heating inlet 21.
  • the flue gas heating inlet 21 is connected with the loading platform.
  • the lower part of 32 is connected, and the fan 34 is used to blow the atomized flue gas to the bearing platform 32 or absorb it under negative pressure to facilitate the heat exchange between the flue gas and the high-temperature sintered material, and the shape will naturally rise after absorbing heat.
  • a sintering process production equipment is also disclosed, the reaction principle of which is the same as that of the third embodiment above, the difference is that the sintering process production equipment adopts an on-machine cooling sintering machine, and its sintering device 10 and The sinter cooling device 30 is connected together.
  • the ignition mechanism 14, the reaction hood 11, and the flue gas heating inlet 21 are arranged in sequence, the flue gas heating inlet 21 is located above the cooling area 31 of the cooling device, and the flue gas heating outlet 22 is arranged below the cooling area 31 ,
  • the cooling zone 31 is provided with a draft cooler below, that is to say, after the flue gas enters the sintered material from above, it leaves from the bottom under the action of the draft cooler, which saves more space.
  • the present invention also discloses Embodiment 10.
  • This embodiment also discloses a sintering process production equipment.
  • the sintering process production equipment also includes a second The flue gas circulation pipeline 50 , the first end of the second flue gas circulation pipeline 50 communicates with the flue gas outlet of the tail reactor 40 , and the second end of the second flue gas circulation pipeline 50 communicates with the inside of the reaction hood 11 .
  • the flue gas is purified by the cooling zone 31 and the tail reactor 40, and most of the flue gas has been desulfurized and denitrified, and the content of dioxins is also very small.
  • first end of the second flue gas circulation pipeline 50 can not only communicate with the flue gas outlet of the tail reactor 40, but also communicate with the flue gas heating outlet (22), or communicate with both connected.
  • carbon additives refer to materials that can directly or indirectly make sintered materials form carbon-containing mixtures, such as coke powder, biomass, coal, carbon powder, etc.
  • the oxygen in the circulating flue gas can also be used as a combustion aid. By increasing the combustion aid, the reaction efficiency can be improved and the production of nitrogen oxides can be further reduced.
  • the generated carbon monoxide and hydrogen can reduce nitrogen oxides and sulfides.
  • the nitrogen oxides in the flue gas introduced into the sintering material layer are reduced to nitrogen in the reducing gas near the sintering combustion layer.
  • the nitrogen oxides produced by the sintering material combustion It is also reduced to nitrogen.
  • the sulfur dioxide introduced into the flue gas of the sinter bed is adsorbed by the sinter and/or reduced to elemental sulfur.
  • the monoxide in the flue gas introduced into the sinter bed is oxidized to carbon dioxide.
  • the dioxins introduced into the sinter bed are pyrolyzed when passing through the sinter bed.
  • the flue gas is introduced into the reaction hood 11 through the medium addition port, which effectively overcomes the problem in the prior art that the by-products produced after denitrification need to be treated, and avoids further environmental pollution such as leakage of ammonia or ozone.
  • the sintering device also includes a first flue gas circulation pipeline 15. One end communicates with the sintering flue outlet 1331 of the exhaust mechanism 13, the second end of the first flue gas circulation pipeline 15 communicates with the inside of the reaction hood 11, and part of the flue gas generated by the sintering material passes through the first flue gas circulation pipeline 15 to the reaction chamber. Inside the cover 11.
  • the flue gas generated in the sintering device 10 can be led back to the reaction hood 11 through the first flue gas circulation pipeline 15, because the flue gas generated in the sintering device 10 has not passed through Subsequent purification, therefore, includes not only carbon dioxide, water vapor, water, but also one or more of sulfur dioxide, nitrogen oxides, and dioxins.
  • the carbon element in the carbon additive reacts near the sintering combustion layer to generate reducing gases such as carbon monoxide and hydrogen, and forms a reducing atmosphere near the sintering combustion layer.
  • the flue gas can be circulated multiple times, and sulfur dioxide, nitrogen oxides, and dioxins in the flue gas can be removed during the multiple circulation process, Carbon dioxide, water vapor, and water are reused repeatedly to generate carbon monoxide and hydrogen, so that a reducing atmosphere is always formed near the sintering material, which can further inhibit the formation of nitrogen oxides and sulfides, ensure the treatment of nitrogen oxides, and realize the sintering process.
  • the sintering process production equipment in this embodiment adopts an ordinary sintering machine, which differs from the on-machine cooling sintering machine in that the sintering device 10 and the sintering material cooling device 30 are separated. , its reaction principle and other structures are the same as those of the cooling and sintering machine on the machine.

Abstract

Disclosed are a sintering apparatus and a sintering process production device. The sintering apparatus comprises: a transport mechanism used to convey a sintering material, an air suction mechanism disposed below the transport mechanism, and an ignition mechanism used to ignite the sintering material; the apparatus further comprises a reaction cover, the reaction cover being coveringly disposed above the transport mechanism, a reaction space in which a medium reacts with ignited sintering material being formed between the reaction cover and the transport mechanism, a medium adding port for adding a medium being disposed on the reaction cover, and the medium adding port being in communication with the reaction space. The sintering apparatus of the present invention, by means of providing a reaction cover which can form a reaction space together with the transport mechanism, prevents a medium and combustion products of the medium from leaking out. In addition, during combustion of the medium, combustion products fill the reaction cover such that gas distribution is more uniform, improving a reaction effect of removing pollutants.

Description

烧结装置及烧结工艺生产设备Sintering device and sintering process production equipment 技术领域technical field
本发明涉及熟料生产工艺及设备技术领域,特别是一种烧结装置及烧结工艺生产设备。The invention relates to the technical field of clinker production technology and equipment, in particular to a sintering device and sintering process production equipment.
背景技术Background technique
氮氧化物是造成大气污染的主要污染源之一。通常所说的氮氧化物NO x有多种:N 2O、NO、NO 2、N 2O 3、N 2O 4和N 2O 5,其中NO和NO 2是重要的大气污染物。 Nitrogen oxides are one of the main sources of air pollution. There are many kinds of nitrogen oxides NO x : N 2 O, NO, NO 2 , N 2 O 3 , N 2 O 4 and N 2 O 5 , among which NO and NO 2 are important air pollutants.
现有烧结工艺中,在生产过程中产生的污染物中还存有二氧化硫、一氧化碳、二噁英、二氧化碳、过量的水蒸气和固体颗粒物,这些污染物进入大气后容易形成酸雾、碱雾。In the existing sintering process, there are sulfur dioxide, carbon monoxide, dioxin, carbon dioxide, excessive water vapor and solid particles among the pollutants generated during the production process. These pollutants are easy to form acid mist and alkali mist after entering the atmosphere.
现有的氮氧化物净化技术主要有:SNCR、SCR、活性炭(焦)和氧化法。其中SNCR、SCR、活性炭(焦)法均存在氨逃逸的问题。SNCR法存在烟气温度要求高,反应效率低的问题,SCR不可避免地会产生固体废弃物,大量的固体废弃物对有些地区而言,存在无法消纳处理的问题;SCR法使用的催化剂在使用寿命到期后,大多属于危险废弃物,届时存在回收处理难度;活性炭(焦)法因烟气温度等因素,在运行操作上管理不到位时,存在一定的安全隐患;氧化法只是将NO氧化成NO 2,碱液的吸收效率低,存在假脱硝的问题。而且该方法同样产生大量的脱硫脱硝固体废弃物,大多数企业不好处理。而且现阶段的SNCR、SCR、活性炭(焦)和氧化法还无法将这些污染物协同治理,找到一种绿色的多污染物协同治理技术已经迫在眉睫。 The existing nitrogen oxide purification technologies mainly include: SNCR, SCR, activated carbon (coke) and oxidation method. Among them, SNCR, SCR, and activated carbon (coke) methods all have the problem of ammonia escape. The SNCR method has the problems of high flue gas temperature requirements and low reaction efficiency. SCR will inevitably generate solid waste. For some areas, a large amount of solid waste cannot be digested and treated; the catalyst used in the SCR method is in the After the service life expires, most of them are hazardous wastes, and it will be difficult to recycle them at that time; due to factors such as flue gas temperature, the activated carbon (coke) method has certain potential safety hazards when the operation and operation are not properly managed; the oxidation method only converts NO Oxidized to NO 2 , the absorption efficiency of lye is low, and there is a problem of false denitrification. Moreover, this method also produces a large amount of desulfurization and denitrification solid waste, which is difficult for most enterprises to handle. Moreover, the current SNCR, SCR, activated carbon (coke) and oxidation methods are still unable to co-manage these pollutants, and it is imminent to find a green multi-pollutant co-management technology.
虽然,现有的一些烧结工艺中可以向烧结料中通入特定的反应介质实现对烟气进行脱硫脱硝,但是由于烧结台车上方为开放结构,这些介质通入烧结料中后,容易外泄,无法控制通入量,导致脱除污染物效果差,而且容易造成二者污染。Although, in some existing sintering processes, specific reaction media can be introduced into the sintering material to achieve desulfurization and denitrification of flue gas, but due to the open structure above the sintering trolley, these media are easy to leak after being introduced into the sintering material , unable to control the amount of flux, resulting in poor removal of pollutants, and easy to cause both pollution.
发明内容Contents of the invention
本发明公开了一种烧结装置及烧结工艺生产设备,解决了由于烧结台车上方为开放结构,反应介质通入烧结料中后,容易外泄,无法 控制通入量,导致脱除污染物效果差,而且容易造成二者污染。The invention discloses a sintering device and a sintering process production equipment, which solves the problem of the removal of pollutants due to the open structure above the sintering trolley, and the reaction medium is easily leaked after being passed into the sintering material, and the amount cannot be controlled. Poor, and it is easy to cause pollution of both.
根据本发明的一个方面,公开了一种烧结装置,包括用于运送烧结料的运输机构,还包括:反应罩,所述反应罩罩设在所述运输机构的上方,所述反应罩与所述运输机构围成反应空间,所述反应罩上开设有用于添加介质的介质添加口,所述介质添加口与所述反应空间连通。According to one aspect of the present invention, a sintering device is disclosed, including a transport mechanism for transporting sintering materials, and further comprising: a reaction cover, the reaction cover is arranged above the transport mechanism, and the reaction cover is connected to the The transportation mechanism encloses a reaction space, and a medium addition port for adding a medium is opened on the reaction cover, and the medium addition port communicates with the reaction space.
进一步地,所述介质添加口位置位于所述反应罩的靠近顶部位置处。Further, the medium addition port is located near the top of the reaction hood.
进一步地,所述反应罩上设置有用于控制介质加入量的阀门。Further, the reaction hood is provided with a valve for controlling the amount of medium added.
进一步地,所述介质添加口用于通入烟气。Further, the medium addition port is used for introducing flue gas.
进一步地,所述烧结装置还包括:抽风机构,所述抽风机构设置在所述运输机构下方;点火机构,所述点火机构用于点燃烧结料;第一烟气循环管路,所述第一烟气循环管路的第一端与所述抽风机构的烧结烟道出口连通,所述第一烟气循环管路的第二端与所述介质添加口连通,所述烧结料产生的部分烟气通过所述第一烟气循环管路循环至反应罩内。Further, the sintering device also includes: a draft mechanism, which is arranged under the transportation mechanism; an ignition mechanism, which is used to ignite and burn the briquette; a first flue gas circulation pipeline, the first The first end of the flue gas circulation pipeline communicates with the sintering flue outlet of the exhaust mechanism, the second end of the first flue gas circulation pipeline communicates with the medium addition port, and part of the smoke generated by the sintering material The gas is circulated into the reaction hood through the first flue gas circulation pipeline.
进一步地,所述烟气中包括二氧化碳、水蒸气、水、二氧化硫、氮氧化物、一氧化碳、二噁英中的一种或多种。Further, the flue gas includes one or more of carbon dioxide, water vapor, water, sulfur dioxide, nitrogen oxides, carbon monoxide, and dioxins.
进一步地,所述反应罩上还设置有用于通入外部烟气的外部烟气添加口。Further, the reaction hood is also provided with an external flue gas addition port for introducing external flue gas.
进一步地,所述烧结装置还包括:介质添加机构,所述介质添加机构的出料口与所述介质添加口连通,所述介质添加机构用于向烧结料喷洒还原介质,所述介质添加机构输出的还原介质与烟气中的氮氧化物发生反应或与烧结料中的碳发生反应生成还原剂并放热。Further, the sintering device further includes: a medium adding mechanism, the discharge port of the medium adding mechanism communicates with the medium adding port, the medium adding mechanism is used to spray reducing medium to the sintering material, and the medium adding mechanism The output reducing medium reacts with the nitrogen oxides in the flue gas or with the carbon in the sintered material to generate a reducing agent and release heat.
进一步地,所述运输机构为烧结台车,烧结料设置于所述烧结台车中,且烧结料在所述烧结台车的移动过程中燃烧形成由上至下分布的已燃烧层、燃烧层和烧结料层,所述介质经过所述已燃烧层后与所述燃烧层和烧结料层反应并放热。Further, the transportation mechanism is a sintering trolley, and the sintering material is arranged in the sintering trolley, and the sintering material burns during the movement of the sintering trolley to form a burnt layer and a burning layer distributed from top to bottom. and the sintered material layer, the medium reacts with the burned layer and the sintered material layer after passing through the burned layer and releases heat.
进一步地,所述介质添加机构将所述介质输送至所述烧结料的已燃烧层的上方,且所述介质由所述抽风机构吸入烧结料内部与所述燃烧层和烧结料层中的碳接触应生成可燃性气体,可燃性气体发生氧化 反应并放热。Further, the medium adding mechanism transports the medium above the burnt layer of the sintered material, and the medium is sucked into the interior of the sintered material and the carbon in the burning layer and the sintered material layer by the ventilation mechanism. Contact should generate flammable gas, which will undergo oxidation reaction and release heat.
进一步地,所述抽风机构包括风机、多个烧结风箱和烧结烟道,所有所述烧结风箱设置于所述运输机构的下方,且所有所述烧结风箱均与所述烧结烟道连通,所述风机设置于所述烧结烟道上。Further, the air extraction mechanism includes a fan, a plurality of sintering air boxes and a sintering flue, all the sintering air boxes are arranged under the transportation mechanism, and all the sintering air boxes are connected to the sintering flue, the The fan is arranged on the sintering flue.
进一步地,所述烧结风箱包括:风箱本体,所述风箱本体内具有收集烟气的内腔,所述风箱本体上还设置有与所述内腔连通的进烟口;反应器,所述反应器具有净化腔,所述反应器上还具有与所述净化腔连通的排烟口,所述净化腔与所述内腔连通,所述净化腔用于净化所述内腔中的烟气。Further, the sintered wind box includes: a wind box body, which has an inner cavity for collecting smoke, and a smoke inlet connected to the inner cavity is arranged on the wind box body; a reactor, the reaction The reactor has a purification chamber, and the reactor also has a smoke exhaust port communicating with the purification chamber, the purification chamber communicates with the inner chamber, and the purification chamber is used to purify the flue gas in the inner chamber.
根据本发明的另一方面,还公开了一种烧结工艺生产设备,包括上述的烧结装置。According to another aspect of the present invention, a sintering process production equipment is also disclosed, including the above-mentioned sintering device.
进一步地,所述烧结装置具有烧结烟道出口,所述烧结工艺生产设备还包括:烟气净化管路,所述烟气净化管路包括对应设置的烟气加热入口和烟气加热出口,所述烟气加热入口与所述烧结烟道出口连通;烧结料冷却装置,所述烧结料冷却装置设置在烟气加热入口和烟气加热出口之间,所述烧结装置产生的烟气通过所述烟气加热入口进入所述烧结料冷却装置,烟气对燃烧后的烧结料进行冷却,同时,烧后的烧结料对通过的烟气进行加热,加热后的烟气进入所述烟气加热出口;尾部反应器,所述尾部反应器通过管路与所述烟气加热出口连通,所述尾部反应器用于对加热后的烟气进行净化处理。Further, the sintering device has a sintering flue outlet, and the sintering process production equipment also includes: a flue gas purification pipeline, and the flue gas purification pipeline includes correspondingly arranged flue gas heating inlets and flue gas heating outlets, so The flue gas heating inlet communicates with the sintering flue outlet; the sintering material cooling device is arranged between the flue gas heating inlet and the flue gas heating outlet, and the flue gas generated by the sintering device passes through the The flue gas heating inlet enters the sintering material cooling device, the flue gas cools the burned sintering material, and at the same time, the burned sintering material heats the passing flue gas, and the heated flue gas enters the flue gas heating outlet ; The tail reactor, the tail reactor communicates with the flue gas heating outlet through a pipeline, and the tail reactor is used for purifying the heated flue gas.
进一步地,所述烧结料冷却装置包括冷却区,所述烟气加热入口位于所述冷却区的下方,所述烟气加热出口位于所述冷却区的上方。Further, the sintering material cooling device includes a cooling zone, the flue gas heating inlet is located below the cooling zone, and the flue gas heating outlet is located above the cooling zone.
进一步地,所述烧结工艺生产设备还包括:第二烟气循环管路,所述第二烟气循环管路的第一端与所述尾部反应器的烟气出口和/或所述烟气加热出口连通,所述第二烟气循环管路的第二端与所述反应罩的介质添加口连通。Further, the sintering process production equipment also includes: a second flue gas circulation pipeline, the first end of the second flue gas circulation pipeline is connected to the flue gas outlet of the tail reactor and/or the flue gas The heating outlet is communicated, and the second end of the second flue gas circulation pipeline is communicated with the medium addition port of the reaction hood.
进一步地,所述烧结装置还包括:第一烟气循环管路,所述第一烟气循环管路的第一端与所述抽风机构的烧结烟道出口连通,所述第一烟气循环管路的第二端与反应罩内部连通,所述烧结料产生的部分烟气通过所述第一烟气循环管路至反应罩内。Further, the sintering device further includes: a first flue gas circulation pipeline, the first end of the first flue gas circulation pipeline communicates with the sintering flue outlet of the draft mechanism, and the first flue gas circulation The second end of the pipeline communicates with the inside of the reaction hood, and part of the flue gas generated by the sintering material passes through the first flue gas circulation pipeline into the reaction hood.
进一步地,所述烟气中具有二氧化碳、水蒸气、水、二氧化硫、 氮氧化物、一氧化碳、二噁英中的一种或多种。Further, the flue gas contains one or more of carbon dioxide, water vapor, water, sulfur dioxide, nitrogen oxides, carbon monoxide, and dioxins.
进一步地,所述冷却区包括第一冷却区和第二冷却区,所述第二冷却区的温度大于所述第一冷却区的温度;所述烟气净化管路还包括二次加热管路,所述二次加热管路包括二次加热入口和二次加热出口,所述二次加热入口位于第一冷却区的上方,所述二次加热出口位于所述第二冷却区的下方;所述烟气加热入口位于所述第一冷却区的下方,所述烟气加热出口位于所述第二冷却区的上方。Further, the cooling zone includes a first cooling zone and a second cooling zone, the temperature of the second cooling zone is higher than the temperature of the first cooling zone; the flue gas purification pipeline also includes a secondary heating pipeline , the secondary heating pipeline includes a secondary heating inlet and a secondary heating outlet, the secondary heating inlet is located above the first cooling zone, and the secondary heating outlet is located below the second cooling zone; The flue gas heating inlet is located below the first cooling zone, and the flue gas heating outlet is located above the second cooling zone.
进一步地,所述二次加热管路设置有催化剂添加装置和/或还原剂添加装置。Further, the secondary heating pipeline is provided with a catalyst adding device and/or a reducing agent adding device.
进一步地,所述烧结工艺生产设备还包括:第二烟气循环管路,所述第二烟气循环管路的第一端与所述尾部反应器的烟气出口和/或所述烟气加热出口连通,所述第二烟气循环管路的第二端与所述反应罩内部连通。Further, the sintering process production equipment also includes: a second flue gas circulation pipeline, the first end of the second flue gas circulation pipeline is connected to the flue gas outlet of the tail reactor and/or the flue gas The heating outlet is in communication, and the second end of the second flue gas circulation pipeline is in communication with the inside of the reaction hood.
进一步地,所述烧结装置还包括:第一烟气循环管路,所述第一烟气循环管路的第一端与所述抽风机构的烧结烟道出口连通,所述第一烟气循环管路的第二端与反应罩内部连通,所述烧结料产生的部分烟气通过所述第一烟气循环管路至反应罩内。Further, the sintering device further includes: a first flue gas circulation pipeline, the first end of the first flue gas circulation pipeline communicates with the sintering flue outlet of the draft mechanism, and the first flue gas circulation The second end of the pipeline communicates with the inside of the reaction hood, and part of the flue gas generated by the sintering material passes through the first flue gas circulation pipeline into the reaction hood.
进一步地,所述烟气中具有二氧化碳、水蒸气、水、二氧化硫、氮氧化物、一氧化碳、二噁英中的一种或多种。Further, the flue gas contains one or more of carbon dioxide, water vapor, water, sulfur dioxide, nitrogen oxides, carbon monoxide, and dioxins.
本发明的烧结装置通过设置反应罩,可以与运输机构配合形成反应空间,防止介质以及介质燃烧的产物外泄,同时,在介质燃烧过程中,使燃烧产物充满反应罩内部,使气体分布更加均匀,提高脱硫脱硝的反应效果。The sintering device of the present invention can cooperate with the transport mechanism to form a reaction space by setting a reaction hood to prevent the leakage of the medium and the products of the medium combustion. At the same time, during the combustion of the medium, the combustion products can fill the inside of the reaction hood to make the gas distribution more uniform. , Improve the reaction effect of desulfurization and denitrification.
附图说明Description of drawings
图1是本发明实施例一的烧结装置的结构示意图;Fig. 1 is a schematic structural view of a sintering device according to Embodiment 1 of the present invention;
图2是本发明实施例二的烧结装置的结构示意图;Fig. 2 is a schematic structural view of a sintering device according to Embodiment 2 of the present invention;
图3是本发明实施例一的烧结装置的抽风机构的结构示意图;Fig. 3 is a schematic structural view of the exhaust mechanism of the sintering device according to Embodiment 1 of the present invention;
图4是本发明实施例三的烧结工艺生产设备的结构示意图;Fig. 4 is the schematic structural view of the sintering process production equipment of the third embodiment of the present invention;
图5是本发明实施例四的烧结工艺生产设备的结构示意图;5 is a schematic structural view of the sintering process production equipment of Embodiment 4 of the present invention;
图6是本发明实施例五的烧结工艺生产设备的结构示意图;6 is a schematic structural view of the sintering process production equipment of Embodiment 5 of the present invention;
图7是本发明实施例六的烧结工艺生产设备的结构示意图;7 is a schematic structural view of the sintering process production equipment of Embodiment 6 of the present invention;
图8是本发明实施例七的烧结工艺生产设备的结构示意图;Fig. 8 is a schematic structural view of the sintering process production equipment of Embodiment 7 of the present invention;
图9是本发明实施例八的烧结工艺生产设备的结构示意图;Fig. 9 is a schematic structural view of the sintering process production equipment of the eighth embodiment of the present invention;
图10是本发明实施例三的烧结工艺生产设备的烧结料冷却装置的结构示意图;10 is a schematic structural view of the sintering material cooling device of the sintering process production equipment of the third embodiment of the present invention;
图11是本发明实施例九的烧结工艺生产设备的结构示意图;Fig. 11 is a schematic structural view of the sintering process production equipment of Embodiment 9 of the present invention;
图12是本发明实施例十的烧结工艺生产设备的结构示意图;Fig. 12 is a schematic structural view of the sintering process production equipment of Embodiment 10 of the present invention;
图13是本发明实施例十一的烧结工艺生产设备的结构示意图;Fig. 13 is a schematic structural view of the sintering process production equipment of the eleventh embodiment of the present invention;
图14是本发明实施例十二的烧结工艺生产设备的结构示意图;Fig. 14 is a schematic structural view of the sintering process production equipment of Embodiment 12 of the present invention;
图例:10、烧结装置;11、反应罩;111、介质添加口;112、阀门;113、外部烟气添加口;12、运输机构;13、抽风机构;131、风箱本体;1311、内腔;132、反应器;1321、外壳;1322、净化腔;1323、排烟口;1324、支撑件;1325、净化层;133、烧结烟道;1331、烧结烟道出口14、点火机构;15、第一烟气循环管路;20、烟气净化管路;21、烟气加热入口;22、烟气加热出口;23、二次加热管路;231、二次加热入口;232、二次加热出口;30、烧结料冷却装置;31、冷却区;311、第一冷却区;312、第二冷却区;32、承载台;33、风机;34、干雾发生器;40、尾部反应器。Legend: 10, sintering device; 11, reaction hood; 111, medium addition port; 112, valve; 113, external flue gas addition port; 12, transport mechanism; 13, exhaust mechanism; 131, bellows body; 1311, inner cavity; 132. Reactor; 1321. Shell; 1322. Clean chamber; 1323. Smoke outlet; 1324. Support; 1325. Purification layer; 133. Sintering flue; 1331. Sintering flue outlet 14. Ignition mechanism; 15. 1. Flue gas circulation pipeline; 20. Flue gas purification pipeline; 21. Flue gas heating inlet; 22. Flue gas heating outlet; 23. Secondary heating pipeline; 231. Secondary heating inlet; 232. Secondary heating outlet ; 30, sintering material cooling device; 31, cooling zone; 311, the first cooling zone; 312, the second cooling zone; 32, bearing platform; 33, fan;
具体实施方式Detailed ways
下面结合实施例对本发明做进一步说明,但不局限于说明书上的内容。The present invention will be further described below in conjunction with embodiment, but is not limited to the content on the description.
如图1所示的实施例一,本发明公开了一种烧结装置,包括反应罩11、用于运送烧结料的运输机构12、设置在运输机构12下方的抽风机构13和用于点燃烧结料的点火机构14,反应罩11罩设在运输机构12的上方和/或侧方,反应罩11与运输机构12围成介质与点燃后的烧结料反应的反应空间,反应罩11上开设有用于添加介质的介质添加口111,介质添加口111与反应空间连通。在烧结生产时,通过介质添加口111向结料料面喷加介质,介质可以在烧结料上方燃烧生成燃烧产物或者介质本身就是在其它地方燃烧后的燃烧产物,然后在抽风机构的作用下将燃烧产物吸入至烧结料内部,在烧结料的温度条件下,燃烧产物与烧结料中的成分发生氧化还原反应,将燃烧产物还原成具有还原性的还原性介质,如燃烧产物中的二氧化碳与烧结料中的碳单质反应生成一 氧化碳,燃烧产物中的水蒸气或水与烧结料中的碳单质反应生成氢气,有效的调节烧结料内部的还原性气氛,与此同时,该还原性介质能够将氮氧化物还原成氮气,从而减少氮氧化物的排放量,成本低廉。Embodiment 1 shown in Figure 1, the present invention discloses a sintering device, including a reaction hood 11, a transportation mechanism 12 for transporting sintering material, an air draft mechanism 13 arranged below the transportation mechanism 12, and a sintering mechanism for igniting the sintering material The ignition mechanism 14, the reaction cover 11 cover is arranged on the top and/or side of the transport mechanism 12, the reaction cover 11 and the transport mechanism 12 enclose the reaction space where the medium reacts with the ignited sintering material, and the reaction cover 11 is provided with a A medium addition port 111 for adding a medium, and the medium addition port 111 communicates with the reaction space. During sintering production, the medium is sprayed on the surface of the binder material through the medium addition port 111. The medium can be burned above the sintered material to generate combustion products or the medium itself is the combustion product after burning in other places, and then under the action of the exhaust mechanism, the The combustion products are inhaled into the sintering material. Under the temperature conditions of the sintering material, the combustion products and the components in the sintering material undergo oxidation-reduction reactions, and the combustion products are reduced to a reducing medium with reducing properties, such as carbon dioxide in the combustion products and sintering. The carbon in the raw material reacts to form carbon monoxide, and the water vapor or water in the combustion product reacts with the carbon in the sintered material to generate hydrogen, which can effectively adjust the reducing atmosphere inside the sintered material. At the same time, the reducing medium can convert nitrogen The oxides are reduced to nitrogen, thereby reducing the emission of nitrogen oxides, and the cost is low.
本发明的烧结装置通过设置反应罩,可以与运输机构配合形成反应空间,防止介质以及介质燃烧的产物外泄,同时,在介质燃烧过程中,使燃烧产物充满反应罩11内部,使气体分布更加均匀,提高污染物的脱除效果。The sintering device of the present invention can cooperate with the transport mechanism to form a reaction space by setting a reaction hood to prevent the leakage of the medium and the products of the medium combustion. Uniform, improve the removal effect of pollutants.
在上述实施例中,介质添加口111位置位于反应罩11的中上部或侧部,反应罩11的底部与运输机构12之间可以密封设置,也可以通过抽风机构13在反应罩11内部形成一个防止烟气部外漏的微负压的环境。通过将介质添加口设置在反应罩11的中上部,可以提高介质添加的高度,可以方便喷洒还原介质,更有利于介质的扩散,提高反应效率,减少还原介质的浪费;通过将反应罩11与运输机构12之间密封或通过抽风机构13在反应罩11内部形成一个微负压的环境,可以更有效地防止烟气逃逸,提高脱硫脱硝的效果。In the above-mentioned embodiments, the medium addition port 111 is located at the upper middle or side of the reaction hood 11, and the bottom of the reaction hood 11 and the transportation mechanism 12 can be sealed, or a ventilation mechanism 13 can be used to form an internal reaction hood 11. A micro-negative pressure environment to prevent leakage of flue gas. By setting the medium addition port on the middle and upper part of the reaction cover 11, the height of the medium addition can be improved, the reduction medium can be sprayed conveniently, the diffusion of the medium is more conducive, the reaction efficiency is improved, and the waste of the reduction medium is reduced; by connecting the reaction cover 11 with The transportation mechanism 12 is sealed or a slightly negative pressure environment is formed inside the reaction hood 11 through the exhaust mechanism 13, which can more effectively prevent the flue gas from escaping and improve the effect of desulfurization and denitrification.
进一步地,反应罩11上设置有用于控制介质的加入量的阀门112,实现烧结料燃烧气氛的有效控制,例如含氧量和温度,达到抑制氮氧化物产生的作用。Further, the reaction hood 11 is provided with a valve 112 for controlling the amount of medium added, so as to effectively control the combustion atmosphere of the sintering material, such as oxygen content and temperature, and to suppress the generation of nitrogen oxides.
更进一步地,介质添加口111用于通入烟气,通入的烟气可以是外部烟气,例如:炼铁、锅炉等燃烧的烟气,也可以是烧结装置10自身产生的烟气,或者是二者的混合烟气。Furthermore, the medium addition port 111 is used to introduce flue gas, which can be external flue gas, such as: flue gas from ironmaking, boiler combustion, etc., or flue gas generated by the sintering device 10 itself. Or a mixture of the two.
外部烟气中的二噁英在通过烧结过程中的高温段被分解,一氧化碳在燃烧层附近发生氧化反应,可还原氮氧化物或与其他氧化物反应为烧结料层提供热量。外部烟气中的二氧化硫通过烧结料层时被吸附,或被还原为单质硫。The dioxins in the external flue gas are decomposed in the high-temperature section of the sintering process, and the carbon monoxide undergoes an oxidation reaction near the combustion layer, which can reduce nitrogen oxides or react with other oxides to provide heat for the sintering material layer. The sulfur dioxide in the external flue gas is adsorbed or reduced to elemental sulfur when passing through the sinter bed.
如图2所示的实施例二中,是以利用烧结装置10自身产生的烟气为例。在本实施例中,烧结装置10还包括第一烟气循环管路15,第一烟气循环管路15的第一端与抽风机构13的烧结烟道出口1331连通,第一烟气循环管路15的第二端与介质添加口111连通,烧结料产生的部分烟气通过第一烟气循环管路15至反应罩11内。In the second embodiment shown in FIG. 2 , the flue gas generated by the sintering device 10 itself is used as an example. In this embodiment, the sintering device 10 further includes a first flue gas circulation pipeline 15, the first end of the first flue gas circulation pipeline 15 communicates with the sintering flue outlet 1331 of the draft mechanism 13, and the first flue gas circulation pipe The second end of the path 15 communicates with the medium addition port 111 , and part of the flue gas generated by the sintering material passes through the first flue gas circulation line 15 into the reaction hood 11 .
在烧结装置10中的烧结料燃烧过程中,产生的烟气(主要包括二 氧化碳、水蒸气、水、二氧化硫、氮氧化物、二噁英中的一种或多种)通过抽风机构13抽走后,部分烟气通过循环管路回到反应罩11中,另一部分烟气通过烟囱排出,烟气中的二氧化碳和水蒸气与烧结料中的碳添加剂中的碳单质在烧结燃烧层附近发生反应,生成一氧化碳,氢气等还原性气体,在烧结燃烧层附近形成还原性气氛。保证对氮氧化物的处理,实现对烧结烟气进行脱硝的目的,其中碳和燃烧产物反应的具体化学方程式举例如下:During the combustion process of the sintering material in the sintering device 10, the generated flue gas (mainly including one or more of carbon dioxide, water vapor, water, sulfur dioxide, nitrogen oxides, and dioxins) is sucked away by the exhaust mechanism 13 , part of the flue gas returns to the reaction hood 11 through the circulation pipeline, and the other part of the flue gas is discharged through the chimney. The carbon dioxide and water vapor in the flue gas react with the carbon element in the carbon additive in the sintering material near the sintering combustion layer. Generate carbon monoxide, hydrogen and other reducing gases, forming a reducing atmosphere near the sintering combustion layer. To ensure the treatment of nitrogen oxides and achieve the purpose of denitrification of sintering flue gas, the specific chemical equation of the reaction between carbon and combustion products is as follows:
C+H 2O(g)→CO+H 2C+H 2 O(g)→CO+H 2 ;
C+CO 2→CO。 C+CO 2 →CO.
需要说明的是,碳添加剂指能够直接或间接使烧结料形成含碳混合物的材料,如焦粉、生物质、煤炭、碳粉等。而循环烟气中的氧气也可以作为助燃剂,通过增加助燃剂,可以提高反应效率,有助于进一步降低氮氧化物的产生。It should be noted that carbon additives refer to materials that can directly or indirectly make sintered materials form carbon-containing mixtures, such as coke powder, biomass, coal, carbon powder, etc. The oxygen in the circulating flue gas can also be used as a combustion aid. By increasing the combustion aid, the reaction efficiency can be improved and the production of nitrogen oxides can be further reduced.
生成的一氧化碳和氢气可以对氮氧化物和硫化物进行还原,引入烧结料层的烟气中的氮氧化物在烧结燃烧层附近的还原性气体被还原为氮气,烧结料燃烧产生的氮氧化物也被还原为氮气。引入烧结料层烟气中的二氧化硫被烧结矿吸附和/或被还原为单质硫。引入烧结料层的烟气中的一氧化他被氧化为二氧化碳。引入烧结料层中的二噁英在穿越烧结料层时被高温分解。The generated carbon monoxide and hydrogen can reduce nitrogen oxides and sulfides. The nitrogen oxides in the flue gas introduced into the sintering material layer are reduced to nitrogen in the reducing gas near the sintering combustion layer. The nitrogen oxides produced by the sintering material combustion It is also reduced to nitrogen. The sulfur dioxide introduced into the flue gas of the sinter bed is adsorbed by the sinter and/or reduced to elemental sulfur. The monoxide in the flue gas introduced into the sinter bed is oxidized to carbon dioxide. The dioxins introduced into the sinter bed are pyrolyzed when passing through the sinter bed.
通过介质添加口向反应罩11内通入烟气,有效的克服了现有技术中需要对脱硝后产生的副产品进行处理的问题,同时避免氨气或臭氧泄露等进一步污染环境。The flue gas is introduced into the reaction hood 11 through the medium addition port, which effectively overcomes the problem in the prior art that the by-products produced after denitrification need to be treated, and avoids further environmental pollution such as leakage of ammonia or ozone.
在图1所示的实施例一中,烧结装置10还包括介质添加机构,介质剂添加机构的出料口与介质添加口111连通,介质添加机构用于向烧结料喷洒还原介质,介质添加机构输出的还原介质与烧结料发生爆燃。In the first embodiment shown in Figure 1, the sintering device 10 also includes a medium addition mechanism, the outlet of the medium agent addition mechanism communicates with the medium addition port 111, the medium addition mechanism is used to spray the reducing medium to the sintering material, and the medium addition mechanism The output reducing medium and sintering material deflagrate.
介质添加机构输出的介质与经过点火机构14引燃后的烧结料发生接触爆燃,点火机构14将烧结料引燃,并且在抽风机构13的作用下,烧结料由上至下燃烧升温,与此同时,运输机构12带动燃烧的烧结料向介质添加机构移动,在燃烧的烧结料移动到反应罩11下方时,介质添加机构向烧结料中添加介质,使介质与烧结料接触,同时介质受到烧结料的温度的影响而产生爆燃。The medium output by the medium adding mechanism contacts and deflagrates with the sintered material ignited by the ignition mechanism 14, and the ignition mechanism 14 ignites the sintered material, and under the action of the exhaust mechanism 13, the sintered material burns from top to bottom and heats up. At the same time, the transportation mechanism 12 drives the burning sintering material to move to the medium adding mechanism. When the burning sintering material moves below the reaction cover 11, the medium adding mechanism adds the medium to the sintering material so that the medium is in contact with the sintering material, and at the same time the medium is sintered. Deflagration is caused by the influence of the temperature of the material.
介质包括与烧结料中碳添加剂发生化学反应产生可燃性物质的材料和/或可燃性物质,也就是说,介质可以为与烧结料中煤和/或焦粉、生物质发生化学反应产生可燃性物质的任意材料,可以为一种材料,也可以为多种材料的混合物,同时介质还可以是材料与可燃性物质的混合物,也可以是单独的可燃性物质的混合物,如多种可燃性气体混合,可燃性气体和可燃性液体混合等均能够实现本发明的目的。The medium includes materials and/or combustible substances that chemically react with carbon additives in the sintered material and/or combustible substances, that is, the medium can produce flammable substances for chemical reactions with coal and/or coke powder and biomass in the sintered material Any material of a substance, which can be one material or a mixture of multiple materials, and the medium can also be a mixture of a material and a flammable substance, or a mixture of a single flammable substance, such as a variety of flammable gases Mixing, flammable gas and flammable liquid mixing etc. can all realize the purpose of the present invention.
在上述实施例中,介质包括以下一种或多种物质:一氧化碳、甲烷、丙烷、乙炔、氢气、甲醇、乙醇、煤气、天然气、汽油、重油、煤粉、木炭、焦炭、木屑、硫化氢、氰化氢、光气、正丁烷、正己烷、正庚烷、正戊烷、丙醇、甲乙酮、醋酸乙烯、硅烷、环己烷、氯化氢、丁炔、液化气、石油气、乙醚、甲苯、苯、丙酮、丙炔、乙烯、丙烯、丁烯、丁烷、水煤浆、焦炭、木屑等可燃烧物质,或高温下可分解出氢气的水、水蒸气,氢气可以对氧化剂或者氮氧化物进行还原反应。除此之外,介质还可以是二氧化碳,二氧化碳在高温下可与焦炭、木屑中的碳单只发生反应生成一氧化碳。In the above embodiments, the medium includes one or more of the following substances: carbon monoxide, methane, propane, acetylene, hydrogen, methanol, ethanol, gas, natural gas, gasoline, heavy oil, coal powder, charcoal, coke, wood chips, hydrogen sulfide, Hydrogen cyanide, phosgene, n-butane, n-hexane, n-heptane, n-pentane, propanol, methyl ethyl ketone, vinyl acetate, silane, cyclohexane, hydrogen chloride, butyne, liquefied petroleum gas, petroleum gas, ether, toluene , benzene, acetone, propyne, ethylene, propylene, butene, butane, coal water slurry, coke, wood chips and other combustible substances, or water and water vapor that can decompose hydrogen at high temperature, and hydrogen can oxidize oxidants or nitrogen undergo a reduction reaction. In addition, the medium can also be carbon dioxide, which can react with the carbon in coke and wood chips at high temperature to form carbon monoxide.
介质可以为水或水蒸气,液态水受到烧结料的温度影响变为水蒸气,水蒸气与烧结料中的煤或焦粉发生化学反应生成可燃气体(一氧化碳和氢气),一氧化碳和氢气可以对烟气中的氮氧化物、硫化物进行氧化还原反应生成水、二氧化碳、氮气、硫单质等,而且高温会将二噁英分解,从而将烟气中的污染物脱除。The medium can be water or water vapor. The liquid water is affected by the temperature of the sintered material into water vapor. The water vapor reacts with the coal or coke powder in the sintered material to generate combustible gases (carbon monoxide and hydrogen). Carbon monoxide and hydrogen can reduce the smoke Nitrogen oxides and sulfides in the gas undergo oxidation-reduction reactions to generate water, carbon dioxide, nitrogen, sulfur, etc., and high temperature will decompose dioxins, thereby removing pollutants in the flue gas.
本发明中采用的还原剂,可以是上述材料中的一种,也可以是多种上述材料的混合物,如多种气体混合,固体混合、气体和液体混合等均能够实现,这些混合物成本都很低廉,而且不会产生污染。The reductant that adopts in the present invention can be a kind of in above-mentioned material, also can be the mixture of multiple above-mentioned materials, as multiple gas mixing, solid mixing, gas and liquid mixing etc. all can realize, and these mixture cost are all very low. Inexpensive and non-polluting.
介质还包括助燃剂,助燃剂包括氧气、空气或循环废气中的一种或多种。The medium also includes a combustion oxidant including one or more of oxygen, air, or recycled exhaust gas.
相对于现有技术中利用氨气、尿素或臭氧对氮氧化物等进行脱硝的技术方案,不仅能够有效的降低成本,而且经过本申请的脱硝处理方法处理后的烧结烟气中只存在二氧化碳、氮气、水蒸气等空气中已经存在的成分,不需要进一步处理即可直接排放,有效的克服了现有技术中需要对脱硝后产生的副产品进行处理的问题,同时避免氨气或臭氧泄露等进一步污染环境。Compared with the technical scheme of using ammonia, urea or ozone to denitrify nitrogen oxides in the prior art, not only can the cost be effectively reduced, but also only carbon dioxide, carbon dioxide, and The components that already exist in the air, such as nitrogen and water vapor, can be directly discharged without further treatment, which effectively overcomes the problem in the prior art that the by-products produced after denitrification need to be treated, and at the same time avoids ammonia or ozone leakage, etc. polluted environment.
在上述实施例中,运输机构12为烧结台车,烧结料设置于烧结台车中,且烧结料在烧结台车的移动过程中燃烧形成由上至下分布的已燃烧层、燃烧层和烧结料层,介质经过已燃烧层后与燃烧层和烧结料层反应爆燃,也即在烧结料内部形成爆燃,并且烧结料的内部能够形成相对密闭的空间,使得在介质与烧结料接触时产生的高温高压绝大多数作用于烧结料上,增加爆燃的效果。In the above-mentioned embodiment, the transportation mechanism 12 is a sintering trolley, and the sintering material is placed in the sintering trolley, and the sintering material burns during the movement of the sintering trolley to form a burnt layer, a combustion layer and a sintered layer distributed from top to bottom. Material layer, after the medium passes through the burned layer, it reacts with the burning layer and the sintered material layer to deflagrate, that is, deflagration is formed inside the sintered material, and the interior of the sintered material can form a relatively closed space, so that when the medium is in contact with the sintered material. Most of the high temperature and high pressure act on the sintered material, increasing the effect of deflagration.
介质添加机构设置在反应罩11的内部,将介质喷洒至烧结料的已燃烧层的上方,且介质由抽风机构13吸入烧结料内部与燃烧层和烧结料层接触爆燃,保证爆燃的效果。The medium adding mechanism is arranged inside the reaction hood 11 to spray the medium above the burned layer of the sintered material, and the medium is sucked into the sintered material by the exhaust mechanism 13 and deflagrates in contact with the burning layer and the sintered material layer to ensure the deflagration effect.
点火机构14和反应罩11之间具有第一设定距离,并且大致形成已燃烧层、燃烧层和烧结料层,在介质在进入烧结料内部并与接触燃烧层和烧结料层的瞬间发生反应或直接爆燃,产生可燃性气体,为烧结料层提供热量,增加烧结反应速率,尽可能降低烧结过程的时间,使爆燃在短时间内形成高温高压,使得烧结料层温度迅速提高,产生大量液相,液相冷却成固相后会能够有效的改善烧结矿粒度组成、提高烧结矿质量的目的,并且能够大量减少了烧结时间,进而提高烧结产量和质量。There is a first set distance between the ignition mechanism 14 and the reaction cover 11, and roughly forms a burned layer, a burning layer and a sintered material layer, and reacts at the moment when the medium enters the sintered material and contacts the burning layer and the sintered material layer Or directly deflagrate to generate flammable gas, provide heat for the sintering material layer, increase the sintering reaction rate, reduce the sintering process time as much as possible, make the deflagration form high temperature and high pressure in a short time, make the sintering material layer temperature increase rapidly, and produce a large amount of liquid After the liquid phase is cooled to the solid phase, it can effectively improve the particle size composition of the sinter and improve the quality of the sinter, and can greatly reduce the sintering time, thereby improving the sintering output and quality.
进一步地,抽风机构13包括风机、多个烧结风箱和烧结烟道133,所有烧结风箱设置于运输机构12的下方,且所有烧结风箱均与烧结烟道133连通,风机设置于烧结烟道133上,风机能够将烧结料燃烧过程中的废气排出,也能够将介质吸入烧结料中进行爆燃。Further, the exhaust mechanism 13 includes a fan, a plurality of sintering bellows and a sintering flue 133, all the sintering bellows are arranged under the transport mechanism 12, and all the sintering bellows are connected with the sintering flue 133, and the fans are arranged on the sintering flue 133 , The fan can discharge the exhaust gas during the combustion process of the sintering material, and can also suck the medium into the sintering material for deflagration.
如图3所示,更进一步地,烧结风箱包括风箱本体131和反应器132,风箱本体131内具有收集烟气的内腔1311,风箱本体131上还设置有与内腔1311连通的进烟口;反应器132具有净化腔1322,反应器132上还具有与净化腔1322连通的排烟口1323,净化腔1322与内腔1311连通,净化腔1322用于净化内腔1311中的烟气。通过风箱本体131将烟气收集至内腔1311中,并通过与内腔1311连通的反应器132对烟气进行第一次净化,从而减少烟气中的有害物质,减少后端净化处理的压力,提高净化效果。As shown in Figure 3, further, the sintered wind box includes a wind box body 131 and a reactor 132, the wind box body 131 has an inner cavity 1311 for collecting flue gas, and the bellows body 131 is also provided with a smoke inlet communicating with the inner cavity 1311 The reactor 132 has a purification chamber 1322, and the reactor 132 also has a smoke outlet 1323 communicating with the purification chamber 1322. The purification chamber 1322 communicates with the inner chamber 1311, and the purification chamber 1322 is used to purify the flue gas in the inner chamber 1311. The flue gas is collected into the inner cavity 1311 through the bellows body 131, and the flue gas is purified for the first time through the reactor 132 communicated with the inner cavity 1311, thereby reducing harmful substances in the flue gas and reducing the pressure of the back-end purification process , improve the purification effect.
反应器132包括外壳1321和支撑件1324,外壳1321内形成有净化腔1322,外壳1321上设置有排烟口1323;支撑件1324设置在净化腔1322 内,支撑件1324上具有通过烟气的过流结构,支撑件1324上设置有用于与烟气反应的净化层1325。通过在支撑件1324上设置过流结构,烟气通过过流结构的引导,与净化层1325发生反应,从而达到净化效果。The reactor 132 includes a shell 1321 and a support 1324. A clean chamber 1322 is formed in the shell 1321. A smoke outlet 1323 is provided on the shell 1321. The support 1324 is arranged in the clean chamber 1322. A flow structure, the support 1324 is provided with a purification layer 1325 for reacting with flue gas. By setting the flow structure on the support member 1324, the flue gas is guided by the flow structure and reacts with the purification layer 1325, thereby achieving a purification effect.
优选地,反应器132为脱硫脱硝反应器,净化层1325包括碱性矿料或能与烟气中硫和氮氧化物发生反应或能对硫和氮氧化物发生反应起催化作用的物质。净化层1325可以与烟气中的在物质特别是碱性物质、烟气中的氮氧化物和硫化物在一定温度的情况下会发生化学反应,从而降低烟气中的NO x和硫化物的含量,从而在保证最终烟气中NO x和硫化物含量达到标准的前提下有效的降低设备成本。 Preferably, the reactor 132 is a desulfurization and denitrification reactor, and the purification layer 1325 includes alkaline mineral materials or substances capable of reacting with or catalyzing the reaction of sulfur and nitrogen oxides in the flue gas. The purification layer 1325 can chemically react with the substances in the flue gas, especially alkaline substances, nitrogen oxides and sulfides in the flue gas at a certain temperature, thereby reducing the concentration of NOx and sulfides in the flue gas content, so as to effectively reduce the cost of equipment under the premise of ensuring that the NO x and sulfide content in the final flue gas reaches the standard.
支撑件1324为孔板,过流结构为孔板上的气孔。采用孔板为支撑件,通过孔板上的气孔引导烟气与净化层中的物质进行反应,从而达到净化烟气的目的。支撑件1324也可以是筛网,过流结构为筛网的筛孔。采用筛网为支撑件,由于筛孔较小,可以减小烟气的流速,使烟气通过净化层的时间延长,充分与净化层反应净化,提高净化效果,而且筛孔较小可以起到除尘的作用。The support member 1324 is an orifice plate, and the flow-passing structure is an air hole on the orifice plate. The orifice plate is used as the support, and the air holes on the orifice plate are used to guide the flue gas to react with the substances in the purification layer, so as to achieve the purpose of purifying the flue gas. The support member 1324 can also be a screen, and the flow-passing structure is a mesh of the screen. The screen is used as the support, because the sieve hole is small, the flow rate of the flue gas can be reduced, the time for the flue gas to pass through the purification layer is prolonged, and it can fully react with the purification layer to improve the purification effect, and the small sieve hole can play a role The role of dust removal.
在上述实施例中,排烟口1323设置在支撑件1324的下方,支撑件1324相对净化腔1322的内壁可转动,支撑件1324可通过转动将净化后的净化层1325从支撑件1324脱离,并从排烟口1323排出。通过使支撑件1324相对净化腔1322的内壁可转动,从而可以在需要更换净化层的净化材料时,通过转动支撑件1324将净化后的净化层1325从支撑件1324脱离,并从排烟口1323排出,方便反应器132的更换和清洁,为了进一步方便更换过程,外壳1321上还设置用于更换净化层1325的舱门。In the above-mentioned embodiment, the smoke outlet 1323 is arranged below the support member 1324, and the support member 1324 is rotatable relative to the inner wall of the purification chamber 1322, and the support member 1324 can separate the purified purification layer 1325 from the support member 1324 by rotating, and Exhausted from the smoke exhaust port 1323. By making the support member 1324 rotatable relative to the inner wall of the purification chamber 1322, when the purification material of the purification layer needs to be replaced, the purified purification layer 1325 can be separated from the support member 1324 by rotating the support member 1324, and can be removed from the smoke exhaust port 1323 discharge to facilitate the replacement and cleaning of the reactor 132. In order to further facilitate the replacement process, a hatch for replacing the purification layer 1325 is also provided on the casing 1321.
在本实施例中,烧结装置采用的是带式烧结机,当然,烧结装置还可以采用其他烧结机,例如:机上冷却烧结机。In this embodiment, the sintering device adopts a belt-type sintering machine, of course, the sintering device can also adopt other sintering machines, for example, an on-machine cooling sintering machine.
根据本发明的实施例三,还公开了一种烧结工艺生产设备,包括上述的烧结装置。According to the third embodiment of the present invention, a sintering process production equipment is also disclosed, including the above-mentioned sintering device.
如图4所示,在本实施例中,烧结装置10具有烧结烟道出口1331,烧结工艺生产设备还包括烟气净化管路20、烧结料冷却装置30和尾部反应器40,烟气净化管路20包括对应设置的烟气加热入口21和烟气加热出口22,烟气加热入口21与烧结烟道出口1331连通;烧结料冷却装置30设置在烟气加热入口21和烟气加热出口22之间,烧结装置10产生 的烟气通过烟气加热入口21进入烧结料冷却装置30,烟气对燃烧后的烧结料进行冷却,同时,烧后的烧结料对通过的烟气进行加热,为了增强脱硝效果,可以在烟气进入烧结料冷却装置30时,喷加还原性介质,如一氧化碳、氢气、尿素、氨等,还原介质在烧结料的加热下与烟气中的氮氧化物发生氧化还原反应,生成氮气、水和二氧化碳,从而增强脱硝效果。加热后的烟气进入烟气加热出口22;尾部反应器40通过管路与烟气加热出口22连通,尾部反应器40用于对加热后的烟气进行净化处理(主要为除尘)和余热回收。As shown in Figure 4, in this embodiment, the sintering device 10 has a sintering flue outlet 1331, and the sintering process production equipment also includes a flue gas purification pipeline 20, a sintering material cooling device 30 and a tail reactor 40, and the flue gas purification pipe The road 20 includes a corresponding flue gas heating inlet 21 and a flue gas heating outlet 22, the flue gas heating inlet 21 communicates with the sintering flue outlet 1331; the sintering material cooling device 30 is arranged between the flue gas heating inlet 21 and the flue gas heating outlet 22 During the period, the flue gas generated by the sintering device 10 enters the sintering material cooling device 30 through the flue gas heating inlet 21, and the flue gas cools the burned sintering material, and at the same time, the burned sintering material heats the passing flue gas, in order to enhance The denitrification effect can be achieved by spraying reducing media such as carbon monoxide, hydrogen, urea, ammonia, etc. when the flue gas enters the sintering material cooling device 30, and the reducing medium is oxidized and reduced with the nitrogen oxides in the flue gas under the heating of the sintering material React to generate nitrogen, water and carbon dioxide, thereby enhancing the denitrification effect. The heated flue gas enters the flue gas heating outlet 22; the tail reactor 40 communicates with the flue gas heating outlet 22 through a pipeline, and the tail reactor 40 is used to purify the heated flue gas (mainly dust removal) and waste heat recovery .
通过设置烟气净化管路20和尾部反应器40,使烧结料烟气经过烟气净化管路20的引导后,与待冷却的高温烧结料进行热交换,在冷却高温烧结料的同时,高温烧结料也对烟气进行加热,再通过尾部反应器40对加热后的烟气进行净化处理,不用增加额外的加热设备对烟气进行加热,从而降低成本,提高净化效果和能源利用率。By setting the flue gas purification pipeline 20 and the tail reactor 40, after being guided by the flue gas purification pipeline 20, the flue gas of the sintering material is exchanged with the high-temperature sintering material to be cooled. While cooling the high-temperature sintering material, the high-temperature The sintering material also heats the flue gas, and then purifies the heated flue gas through the tail reactor 40, without adding additional heating equipment to heat the flue gas, thereby reducing costs, improving purification effect and energy utilization rate.
需要说明的是,烟气进入烧结装置10的抽风机构13后,依次经过烧结烟道、机头除尘装置、烧结风机、脱硫塔、引风机然后进入烟气加热入口21,通过烧结料冷却装置30上方设置的鼓风冷却机进入烟气加热出口22,最后进入除尘装置并在除尘装置下游的风机作用下从烟囱排出。It should be noted that after the flue gas enters the exhaust mechanism 13 of the sintering device 10, it passes through the sintering flue, the head dust removal device, the sintering fan, the desulfurization tower, the induced draft fan, and then enters the flue gas heating inlet 21, and passes through the sintering material cooling device 30. The blower cooler installed above enters the flue gas heating outlet 22, and finally enters the dust removal device and is discharged from the chimney under the action of the fan downstream of the dust removal device.
在本实施例中,烧结料冷却装置30包括冷却区31,烟气加热入口21位于冷却区31的下方,烟气加热出口22位于冷却区31的上方。通过将烟气加热入口21和烟气加热出口22分别设置在冷却区31的上方和下方,低温烟气进入冷却区31后可以更加充分的进行加热,而且加热后的烟气上升后,可以直接通过冷却区31上方的烟气加热出口22进入尾部反应器40中净化,因此,可以保证良好的反应温度,提高烟气的净化效果。另外,该冷却区31在烟气通过时,还可以净化烟气中的一氧化碳、氮氧化物、二噁英、白色烟羽。在烧结矿的催化作用下,一氧化碳可以还原氮氧化物,同时一氧化碳也可与氧气发生反应生成二氧化碳,一氧化碳也可与铁的氧化物进行反应,生成低价的铁的氧化物,甚至是单质铁,同时放出热量。二噁英在穿越高温烧结矿时被分解,白色烟羽主要由水蒸气形成,烟温提高后,白色烟羽消失。同时烟气中的水蒸汽加速了烧结矿的冷却过程。为了增强脱硝效果,可以在烟 气进入冷却区31时,喷加还原性介质,如一氧化碳、氢气、尿素、氨等,还原介质在烧结料的加热下与烟气中的氮氧化物发生氧化还原反应,生成氮气、水和二氧化碳,从而增强脱硝效果。In this embodiment, the sintering material cooling device 30 includes a cooling zone 31 , the flue gas heating inlet 21 is located below the cooling zone 31 , and the flue gas heating outlet 22 is located above the cooling zone 31 . By setting the flue gas heating inlet 21 and the flue gas heating outlet 22 respectively above and below the cooling zone 31, the low-temperature flue gas can be heated more fully after entering the cooling zone 31, and after the heated flue gas rises, it can directly The flue gas enters the tail reactor 40 for purification through the flue gas heating outlet 22 above the cooling zone 31 , so a good reaction temperature can be ensured and the flue gas purification effect can be improved. In addition, the cooling zone 31 can also purify carbon monoxide, nitrogen oxides, dioxins, and white smoke plumes in the flue gas when the flue gas passes through. Under the catalysis of sinter, carbon monoxide can reduce nitrogen oxides, and carbon monoxide can also react with oxygen to generate carbon dioxide, and carbon monoxide can also react with iron oxides to generate low-priced iron oxides, even elemental iron , while releasing heat. Dioxin is decomposed when passing through the high-temperature sinter, and the white plume is mainly formed by water vapor. When the temperature of the smoke increases, the white plume disappears. At the same time, the water vapor in the flue gas accelerates the cooling process of the sinter. In order to enhance the denitration effect, when the flue gas enters the cooling zone 31, a reducing medium, such as carbon monoxide, hydrogen, urea, ammonia, etc., can be sprayed, and the reducing medium will undergo redox with the nitrogen oxides in the flue gas under the heating of the sintering material. React to generate nitrogen, water and carbon dioxide, thereby enhancing the denitrification effect.
如图5所示的实施例四,同样公开了一种烧结工艺生产设备,与实施例三的区别在于,在本实施例中,烧结工艺生产设备还包括第二烟气循环管路50,第二烟气循环管路50的第一端与尾部反应器40的烟气出口连通,第二烟气循环管路50的第二端与反应罩11的介质添加口111连通。经过尾部反应器40净化的烟气包括大量的二氧化碳、水蒸气、水,部分烟气通过第二烟气循环管路50回到反应罩11中,另一部分烟气通过烟囱排出,烟气中的二氧化碳和水蒸气与烧结料中的碳添加剂中的碳单质在烧结燃烧层附近发生反应,生成大量一氧化碳、氢气等还原性气体,在烧结燃烧层附近形成还原性气氛。保证对氮氧化物的处理,实现对烧结烟气进行脱硝的目的,其中碳和燃烧产物反应的具体化学方程式举例如下:Embodiment 4 shown in FIG. 5 also discloses a sintering process production equipment. The difference from Embodiment 3 is that in this embodiment, the sintering process production equipment also includes a second flue gas circulation pipeline 50, the second The first end of the second flue gas circulation pipeline 50 communicates with the flue gas outlet of the tail reactor 40 , and the second end of the second flue gas circulation pipeline 50 communicates with the medium addition port 111 of the reaction hood 11 . The flue gas purified by the tail reactor 40 includes a large amount of carbon dioxide, water vapor, water, part of the flue gas returns to the reaction hood 11 through the second flue gas circulation pipeline 50, and the other part of the flue gas is discharged through the chimney. Carbon dioxide and water vapor react with the carbon element in the carbon additive in the sintering material near the sintering combustion layer to generate a large amount of reducing gases such as carbon monoxide and hydrogen, forming a reducing atmosphere near the sintering combustion layer. To ensure the treatment of nitrogen oxides and achieve the purpose of denitrification of sintering flue gas, the specific chemical equation of the reaction between carbon and combustion products is as follows:
C+H 2O(g)→CO+H 2C+H 2 O(g)→CO+H 2 ;
C+CO 2→CO。 C+CO 2 →CO.
需要说明的是,第二烟气循环管路50的第一端不仅可以与尾部反应器40的烟气出口连通,还可以与所述烟气加热出口(22)连通,也可以同时与二者连通。It should be noted that the first end of the second flue gas circulation pipeline 50 can not only communicate with the flue gas outlet of the tail reactor 40, but also communicate with the flue gas heating outlet (22), or communicate with both connected.
还需要说明的是,碳添加剂指能够直接或间接使烧结料形成含碳混合物的材料,如焦粉、生物质、煤炭、碳粉等。而循环烟气中的氧气也可以作为助燃剂,通过增加助燃剂,可以提高反应效率,有助于进一步降低氮氧化物的产生。It should also be noted that carbon additives refer to materials that can directly or indirectly make sintered materials form carbon-containing mixtures, such as coke powder, biomass, coal, carbon powder, etc. The oxygen in the circulating flue gas can also be used as a combustion aid. By increasing the combustion aid, the reaction efficiency can be improved and the production of nitrogen oxides can be further reduced.
生成的一氧化碳和氢气可以对氮氧化物和硫化物进行还原,引入烧结料层的烟气中的氮氧化物在烧结燃烧层附近的还原性气体被还原为氮气,烧结料燃烧产生的氮氧化物也被还原为氮气。引入烧结料层烟气中的二氧化硫被烧结矿吸附和/或被还原为单质硫。引入烧结料层的烟气中的一氧化他被氧化为二氧化碳。引入烧结料层中的二噁英在穿越烧结料层时被高温分解。The generated carbon monoxide and hydrogen can reduce nitrogen oxides and sulfides. The nitrogen oxides in the flue gas introduced into the sintering material layer are reduced to nitrogen in the reducing gas near the sintering combustion layer. The nitrogen oxides produced by the sintering material combustion It is also reduced to nitrogen. The sulfur dioxide introduced into the flue gas of the sinter bed is adsorbed by the sinter and/or reduced to elemental sulfur. The monoxide in the flue gas introduced into the sinter bed is oxidized to carbon dioxide. The dioxins introduced into the sinter bed are pyrolyzed when passing through the sinter bed.
通过介质添加口向反应罩11内通入烟气,有效的克服了现有技术中需要对脱硝后产生的副产品进行处理的问题,同时避免氨气或臭氧 泄露等进一步污染环境。如图6所示是本发明的实施例五,本实施例是在实施例四的基础上,烧结装置还包括第一烟气循环管路15,第一烟气循环管路15的第一端与抽风机构13的烧结烟道出口1331连通,第一烟气循环管路15的第二端与介质添加口111连通,烧结料产生的部分烟气通过第一烟气循环管路15至反应罩11内。The flue gas is introduced into the reaction hood 11 through the medium addition port, which effectively overcomes the problem in the prior art that the by-products produced after denitrification need to be processed, and at the same time avoids further environmental pollution such as leakage of ammonia or ozone. As shown in Figure 6, it is Embodiment 5 of the present invention. This embodiment is based on Embodiment 4. The sintering device also includes a first flue gas circulation pipeline 15, and the first end of the first flue gas circulation pipeline 15 It communicates with the sintering flue outlet 1331 of the exhaust mechanism 13, and the second end of the first flue gas circulation pipeline 15 communicates with the medium addition port 111. Part of the flue gas generated by the sintering material passes through the first flue gas circulation pipeline 15 to the reaction hood within 11.
也就是说,在本实施例中,可以将在烧结装置10中产生的烟气通过第一烟气循环管路15引回至反应罩11中,烧结装置10中产生的烟气由于还未经过后续净化,因此,不仅包括二氧化碳、水蒸气、水,还包括二氧化硫、氮氧化物、二噁英中的一种或多种,在反应罩11内烟气中的二氧化碳和水蒸气与烧结料中的碳添加剂中的碳单质在烧结燃烧层附近发生反应,生成一氧化碳,氢气等还原性气体,在烧结燃烧层附近形成还原性气氛。通过增加第一烟气循环管路15和第二烟气循环管路50,可以使烟气进行多重循环,在多重循环过程中可以将烟气中的二氧化硫、氮氧化物、二噁英清除,而二氧化碳、水蒸气、水反复利用,生成一氧化碳、氢气,使烧结料附近始终形成还原性气氛,从而又可以进一步抑制氮氧化物生成,保证对氮氧化物的处理,实现对烧结烟气进行脱硝的目的,并且最终可以产生大量的二氧化碳,可以对烟气中的二氧化碳进行回收再利用,实现碳中和。That is to say, in this embodiment, the flue gas generated in the sintering device 10 can be led back to the reaction hood 11 through the first flue gas circulation pipeline 15, because the flue gas generated in the sintering device 10 has not passed through Subsequent purification, therefore, includes not only carbon dioxide, water vapor, water, but also one or more of sulfur dioxide, nitrogen oxides, and dioxins. The carbon element in the carbon additive reacts near the sintering combustion layer to generate reducing gases such as carbon monoxide and hydrogen, and forms a reducing atmosphere near the sintering combustion layer. By adding the first flue gas circulation pipeline 15 and the second flue gas circulation pipeline 50, the flue gas can be circulated multiple times, and sulfur dioxide, nitrogen oxides, and dioxins in the flue gas can be removed during the multiple circulation process, Carbon dioxide, water vapor, and water are reused repeatedly to generate carbon monoxide and hydrogen, so that a reducing atmosphere is always formed near the sintering material, which can further inhibit the formation of nitrogen oxides, ensure the treatment of nitrogen oxides, and realize denitrification of sintering flue gas The purpose, and ultimately can produce a large amount of carbon dioxide, the carbon dioxide in the flue gas can be recycled and reused to achieve carbon neutrality.
在如图7所示的实施例六中,同样公开了一种烧结工艺生产设备,与实施例三的区别在于,在本实施例中,冷却区31包括第一冷却区311和第二冷却区312,第二冷却区312的温度大于第一冷却区311的温度;烟气净化管路20还包括二次加热管路23,二次加热管路23包括二次加热入口231和二次加热出口232,二次加热入口231位于第一冷却区311的上方,二次加热出口232位于第二冷却区312的下方;烟气加热入口21位于第一冷却区311的下方,烟气加热出口22位于第二冷却区312的上方。In the sixth embodiment shown in Figure 7, a sintering process production equipment is also disclosed, the difference from the third embodiment is that in this embodiment, the cooling zone 31 includes a first cooling zone 311 and a second cooling zone 312, the temperature of the second cooling zone 312 is higher than the temperature of the first cooling zone 311; the flue gas purification pipeline 20 also includes a secondary heating pipeline 23, and the secondary heating pipeline 23 includes a secondary heating inlet 231 and a secondary heating outlet 232, the secondary heating inlet 231 is located above the first cooling zone 311, and the secondary heating outlet 232 is located below the second cooling zone 312; the flue gas heating inlet 21 is located below the first cooling zone 311, and the flue gas heating outlet 22 is located at above the second cooling zone 312 .
冷却区31设置为第一冷却区311和第二冷却区312,第一冷却区311内为冷却了较长时间的烧结料,而第二冷却区312内为冷却时间较短或刚刚加热完的烧结料,因此,第二冷却区312的温度大于第一冷却区311的温度,加热烟气时,将低温烟气首先通过温度较低的第一冷却区311进行初步加热,再通过设置二次加热管路23,将初步加热后的烟气输 送至温度较高的第二冷却区进行进一步加热,通过二次加热,可以大大提高换热效率,保证烟气的脱白效果,同时保证烟气的温度能够达到发生反应的温度,进而保证脱一氧化碳脱硝的效果。另外,还可以进一步降低熟料的冷却温度,提高余热回收的烟气温度一举多得。为了增强脱硝效果,可以在烟气进入第一冷却区311和/或第二冷却区312时,喷加还原性介质,如一氧化碳、氢气、尿素、氨等,还原介质在烧结料的加热下与烟气中的氮氧化物发生氧化还原反应,生成氮气、水和二氧化碳,从而增强脱硝效果。The cooling zone 31 is set as a first cooling zone 311 and a second cooling zone 312. The sintered material that has been cooled for a long time is in the first cooling zone 311, and the sintered material that has been cooled for a short time or has just been heated is in the second cooling zone 312. Therefore, the temperature of the second cooling zone 312 is higher than the temperature of the first cooling zone 311. When heating the flue gas, the low-temperature flue gas is firstly heated through the first cooling zone 311 with a lower temperature, and then passed through the second cooling zone. The heating pipeline 23 transports the initially heated flue gas to the second cooling zone with a higher temperature for further heating. Through secondary heating, the heat exchange efficiency can be greatly improved, and the whitening effect of the flue gas can be ensured. The temperature can reach the temperature at which the reaction occurs, thereby ensuring the effect of removing carbon monoxide and denitrification. In addition, the cooling temperature of the clinker can be further reduced, and the flue gas temperature for waste heat recovery can be increased. In order to enhance the denitrification effect, when the flue gas enters the first cooling zone 311 and/or the second cooling zone 312, a reducing medium, such as carbon monoxide, hydrogen, urea, ammonia, etc., can be sprayed, and the reducing medium is heated by the sintering material. The nitrogen oxides in the flue gas undergo redox reactions to generate nitrogen, water and carbon dioxide, thereby enhancing the denitrification effect.
在本实施例中,二次加热管路23设置有催化剂添加装置和/或还原剂添加装置。通过设置催化剂添加装置,能够添加催化剂增加反应效率,进而增加脱硫脱硝的效果。In this embodiment, the secondary heating pipeline 23 is provided with a catalyst adding device and/or a reducing agent adding device. By installing a catalyst adding device, the catalyst can be added to increase the reaction efficiency, thereby increasing the effect of desulfurization and denitrification.
如图8所示,本发明还公开了实施例七,本实施例同样公开了一种烧结工艺生产设备,与实施例六的区别在于,在本实施例中,烧结工艺生产设备还包括第二烟气循环管路50,第二烟气循环管路50的第一端与尾部反应器40的烟气出口连通,第二烟气循环管路50的第二端与反应罩11的介质添加口111连通。烟气经过第一冷却区311、第二冷却区312以及二次加热管路23,已对烟气进行了一轮脱硫脱硝,烟气中的二噁英也非常少,再经过尾部反应器40净化,烟气中包括大量的二氧化碳、水蒸气,部分烟气通过第二烟气循环管路50回到反应罩11中,另一部分烟气通过烟囱排出,烟气中的二氧化碳和水蒸气与烧结料中的碳添加剂中的碳单质在烧结燃烧层附近发生反应,生成大量一氧化碳、氢气等还原性气体,在烧结燃烧层附近形成还原性气氛。保证对氮氧化物的处理,实现对烧结烟气进行脱硝的目的,其中碳和燃烧产物反应的具体化学方程式举例如下:As shown in Figure 8, the present invention also discloses Embodiment 7. This embodiment also discloses a sintering process production equipment. The difference from Embodiment 6 is that in this embodiment, the sintering process production equipment also includes a second The flue gas circulation pipeline 50, the first end of the second flue gas circulation pipeline 50 communicates with the flue gas outlet of the tail reactor 40, the second end of the second flue gas circulation pipeline 50 communicates with the medium addition port of the reaction hood 11 111 is connected. The flue gas passes through the first cooling zone 311, the second cooling zone 312 and the secondary heating pipeline 23. The flue gas has undergone a round of desulfurization and denitrification, and the dioxin in the flue gas is also very small, and then passes through the tail reactor 40 Purification, including a large amount of carbon dioxide and water vapor in the flue gas, part of the flue gas returns to the reaction hood 11 through the second flue gas circulation pipeline 50, and the other part of the flue gas is discharged through the chimney, the carbon dioxide and water vapor in the flue gas are combined with the sintering The carbon element in the carbon additive in the material reacts near the sintering combustion layer to generate a large amount of reducing gases such as carbon monoxide and hydrogen, and forms a reducing atmosphere near the sintering combustion layer. To ensure the treatment of nitrogen oxides and achieve the purpose of denitrification of sintering flue gas, the specific chemical equation of the reaction between carbon and combustion products is as follows:
C+H 2O(g)→CO+H 2C+H 2 O(g)→CO+H 2 ;
C+CO 2→CO。 C+CO 2 →CO.
需要说明的是,第二烟气循环管路50的第一端不仅可以与尾部反应器40的烟气出口连通,还可以与所述烟气加热出口22连通,也可以同时与二者连通。It should be noted that the first end of the second flue gas circulation pipeline 50 can not only communicate with the flue gas outlet of the tail reactor 40, but also communicate with the flue gas heating outlet 22, or communicate with both at the same time.
还需要说明的是,碳添加剂指能够直接或间接使烧结料形成含碳混合物的材料,如焦粉、生物质、煤炭、碳粉等。而循环烟气中的氧 气也可以作为助燃剂,通过增加助燃剂,可以提高反应效率,有助于进一步降低氮氧化物的产生。It should also be noted that carbon additives refer to materials that can directly or indirectly make sintered materials form carbon-containing mixtures, such as coke powder, biomass, coal, carbon powder, etc. The oxygen in the circulating flue gas can also be used as a combustion aid. By increasing the combustion aid, the reaction efficiency can be improved and the production of nitrogen oxides can be further reduced.
生成的一氧化碳和氢气可以对氮氧化物和硫化物进行还原,引入烧结料层的烟气中的氮氧化物在烧结燃烧层附近的还原性气体被还原为氮气,烧结料燃烧产生的氮氧化物也被还原为氮气。引入烧结料层烟气中的二氧化硫被烧结矿吸附和/或被还原为单质硫。引入烧结料层的烟气中的一氧化他被氧化为二氧化碳。引入烧结料层中的二噁英在穿越烧结料层时被高温分解。The generated carbon monoxide and hydrogen can reduce nitrogen oxides and sulfides. The nitrogen oxides in the flue gas introduced into the sintering material layer are reduced to nitrogen in the reducing gas near the sintering combustion layer. The nitrogen oxides produced by the sintering material combustion It is also reduced to nitrogen. The sulfur dioxide introduced into the flue gas of the sinter bed is adsorbed by the sinter and/or reduced to elemental sulfur. The monoxide in the flue gas introduced into the sinter bed is oxidized to carbon dioxide. The dioxins introduced into the sinter bed are pyrolyzed when passing through the sinter bed.
通过介质添加口向反应罩11内通入烟气,有效的克服了现有技术中需要对脱硝后产生的副产品进行处理的问题,同时避免氨气或臭氧泄露等进一步污染环境。The flue gas is introduced into the reaction hood 11 through the medium addition port, which effectively overcomes the problem in the prior art that the by-products produced after denitrification need to be treated, and avoids further environmental pollution such as leakage of ammonia or ozone.
如图9所示是本发明的实施例八,本实施例是在实施例七的基础上,烧结装置还包括第一烟气循环管路15,第一烟气循环管路15的第一端与抽风机构13的烧结烟道出口1331连通,第一烟气循环管路15的第二端与反应罩连通,烧结料产生的部分烟气通过第一烟气循环管路15至反应罩11内。As shown in Figure 9 is the eighth embodiment of the present invention, this embodiment is based on the seventh embodiment, the sintering device also includes a first flue gas circulation pipeline 15, the first end of the first flue gas circulation pipeline 15 It communicates with the sintering flue outlet 1331 of the exhaust mechanism 13, and the second end of the first flue gas circulation pipeline 15 communicates with the reaction hood. Part of the flue gas generated by the sintering material passes through the first flue gas circulation pipeline 15 into the reaction hood 11. .
也就是说,在本实施例中,可以将在烧结装置10中产生的烟气通过第一烟气循环管路15引回至反应罩11中,烧结装置10中产生的烟气由于还未经过后续净化,因此,不仅包括二氧化碳、水蒸气、水,还包括二氧化硫、氮氧化物、二噁英中的一种或多种,在反应罩11内烟气中的二氧化碳和水蒸气与烧结料中的碳添加剂中的碳单质在烧结燃烧层附近发生反应,生成一氧化碳,氢气等还原性气体,在烧结燃烧层附近形成还原性气氛。通过增加第一烟气循环管路15和第二烟气循环管路50,可以使烟气进行多重循环,在多重循环过程中可以将烟气中的二氧化硫、氮氧化物、二噁英清除,而二氧化碳、水蒸气、水反复利用,生成一氧化碳、氢气,使烧结料附近始终形成还原性气氛,从而又可以进一步抑制氮氧化物、硫化物的生成,保证对氮氧化物的处理,实现对烧结烟气进行脱硝的目的,并且最终可以产生大量的二氧化碳,可以对烟气中的二氧化碳进行回收再利用,实现碳中和。That is to say, in this embodiment, the flue gas generated in the sintering device 10 can be led back to the reaction hood 11 through the first flue gas circulation pipeline 15, because the flue gas generated in the sintering device 10 has not passed through Subsequent purification, therefore, includes not only carbon dioxide, water vapor, water, but also one or more of sulfur dioxide, nitrogen oxides, and dioxins. The carbon element in the carbon additive reacts near the sintering combustion layer to generate reducing gases such as carbon monoxide and hydrogen, and forms a reducing atmosphere near the sintering combustion layer. By adding the first flue gas circulation pipeline 15 and the second flue gas circulation pipeline 50, the flue gas can be circulated multiple times, and sulfur dioxide, nitrogen oxides, and dioxins in the flue gas can be removed during the multiple circulation process, Carbon dioxide, water vapor, and water are reused repeatedly to generate carbon monoxide and hydrogen, so that a reducing atmosphere is always formed near the sintering material, which can further inhibit the formation of nitrogen oxides and sulfides, ensure the treatment of nitrogen oxides, and realize the sintering process. The purpose of flue gas denitrification, and ultimately can produce a large amount of carbon dioxide, the carbon dioxide in the flue gas can be recycled and reused to achieve carbon neutrality.
图10所示的可以是烧结料冷却装置30的一种具体结构,包括承载台32、干雾发生器33和风机34,烧结料设置于承载台32上,冷却剂在 干雾发生器33内雾化后送至承载台32处,雾化后的冷却剂喷射或吸附到承载台32上与高温的烧结料进行热交换。Shown in Fig. 10 can be a kind of specific structure of sintered material cooling device 30, comprise bearing platform 32, dry mist generator 33 and blower fan 34, sintered material is arranged on the bearing platform 32, coolant is in the dry mist generator 33 After being atomized, it is sent to the carrier platform 32, and the atomized coolant is sprayed or adsorbed onto the carrier platform 32 to exchange heat with the high-temperature sintered material.
承载台32上设置有烟气加热入口21,干雾发生器33的入口与风机34进风口连通,风机34的出风口与烟气加热入口21连通,优选的,烟气加热入口21与承载台32的下部连通,利用风机34将雾化后的烟气吹向或负压吸附到承载台32上,方便烟气与高温烧结料进行热交换,并在吸热后形自然上升。The loading platform 32 is provided with a flue gas heating inlet 21, the inlet of the dry mist generator 33 communicates with the air inlet of the fan 34, and the air outlet of the fan 34 communicates with the flue gas heating inlet 21. Preferably, the flue gas heating inlet 21 is connected with the loading platform. The lower part of 32 is connected, and the fan 34 is used to blow the atomized flue gas to the bearing platform 32 or absorb it under negative pressure to facilitate the heat exchange between the flue gas and the high-temperature sintered material, and the shape will naturally rise after absorbing heat.
在如图11所示的实施例九中,还公开了一种烧结工艺生产设备,其反应原理与上述实施例三相同,区别在于该烧结工艺生产设备采用机上冷却烧结机,其烧结装置10和烧结料冷却装置30是连在一起的。在本实施例中,点火机构14、反应罩11、烟气加热入口21依次设置,烟气加热入口21位于冷却装置的冷却区31上方,而烟气加热出口22是设置在冷却区31的下方,冷却区31下方设置有抽风冷却机,也就是说,烟气是从上方进入烧结料后,在抽风冷却机的作用下,再从下方离开,这样设置更加节省空间。In the ninth embodiment shown in Figure 11, a sintering process production equipment is also disclosed, the reaction principle of which is the same as that of the third embodiment above, the difference is that the sintering process production equipment adopts an on-machine cooling sintering machine, and its sintering device 10 and The sinter cooling device 30 is connected together. In this embodiment, the ignition mechanism 14, the reaction hood 11, and the flue gas heating inlet 21 are arranged in sequence, the flue gas heating inlet 21 is located above the cooling area 31 of the cooling device, and the flue gas heating outlet 22 is arranged below the cooling area 31 , The cooling zone 31 is provided with a draft cooler below, that is to say, after the flue gas enters the sintered material from above, it leaves from the bottom under the action of the draft cooler, which saves more space.
如图12所示,本发明还公开了实施例十,本实施例同样公开了一种烧结工艺生产设备,与实施例九的区别在于,在本实施例中,烧结工艺生产设备还包括第二烟气循环管路50,第二烟气循环管路50的第一端与尾部反应器40的烟气出口连通,第二烟气循环管路50的第二端与反应罩11内部连通。烟气经过冷却区31和尾部反应器40净化,已将大部分烟气脱硫脱硝,二噁英含量也很少,此时,烟气中具有大量的二氧化碳以及一部分水蒸气、水,部分烟气通过第二烟气循环管路50回到反应罩11中,另一部分烟气通过烟囱排出,烟气中的二氧化碳和水蒸气与烧结料中的碳添加剂中的碳单质在烧结燃烧层附近发生反应,生成大量一氧化碳、氢气等还原性气体,在烧结燃烧层附近形成还原性气氛。保证对氮氧化物的处理,实现对烧结烟气进行脱硝的目的,其中碳和燃烧产物反应的具体化学方程式举例如下:As shown in Figure 12, the present invention also discloses Embodiment 10. This embodiment also discloses a sintering process production equipment. The difference from Embodiment 9 is that in this embodiment, the sintering process production equipment also includes a second The flue gas circulation pipeline 50 , the first end of the second flue gas circulation pipeline 50 communicates with the flue gas outlet of the tail reactor 40 , and the second end of the second flue gas circulation pipeline 50 communicates with the inside of the reaction hood 11 . The flue gas is purified by the cooling zone 31 and the tail reactor 40, and most of the flue gas has been desulfurized and denitrified, and the content of dioxins is also very small. Return to the reaction hood 11 through the second flue gas circulation pipeline 50, another part of the flue gas is discharged through the chimney, and the carbon dioxide and water vapor in the flue gas react with the carbon element in the carbon additive in the sintering material near the sintering combustion layer , generate a large amount of reducing gases such as carbon monoxide and hydrogen, and form a reducing atmosphere near the sintering combustion layer. To ensure the treatment of nitrogen oxides and achieve the purpose of denitrification of sintering flue gas, the specific chemical equation of the reaction between carbon and combustion products is as follows:
C+H 2O(g)→CO+H 2C+H 2 O(g)→CO+H 2 ;
C+CO 2→CO。 C+CO 2 →CO.
需要说明的是,第二烟气循环管路50的第一端不仅可以与尾部反应器40的烟气出口连通,还可以与所述烟气加热出口(22)连通,也 可以同时与二者连通。It should be noted that the first end of the second flue gas circulation pipeline 50 can not only communicate with the flue gas outlet of the tail reactor 40, but also communicate with the flue gas heating outlet (22), or communicate with both connected.
还需要说明的是,碳添加剂指能够直接或间接使烧结料形成含碳混合物的材料,如焦粉、生物质、煤炭、碳粉等。而循环烟气中的氧气也可以作为助燃剂,通过增加助燃剂,可以提高反应效率,有助于进一步降低氮氧化物的产生。It should also be noted that carbon additives refer to materials that can directly or indirectly make sintered materials form carbon-containing mixtures, such as coke powder, biomass, coal, carbon powder, etc. The oxygen in the circulating flue gas can also be used as a combustion aid. By increasing the combustion aid, the reaction efficiency can be improved and the production of nitrogen oxides can be further reduced.
生成的一氧化碳和氢气可以对氮氧化物和硫化物进行还原,引入烧结料层的烟气中的氮氧化物在烧结燃烧层附近的还原性气体被还原为氮气,烧结料燃烧产生的氮氧化物也被还原为氮气。引入烧结料层烟气中的二氧化硫被烧结矿吸附和/或被还原为单质硫。引入烧结料层的烟气中的一氧化他被氧化为二氧化碳。引入烧结料层中的二噁英在穿越烧结料层时被高温分解。The generated carbon monoxide and hydrogen can reduce nitrogen oxides and sulfides. The nitrogen oxides in the flue gas introduced into the sintering material layer are reduced to nitrogen in the reducing gas near the sintering combustion layer. The nitrogen oxides produced by the sintering material combustion It is also reduced to nitrogen. The sulfur dioxide introduced into the flue gas of the sinter bed is adsorbed by the sinter and/or reduced to elemental sulfur. The monoxide in the flue gas introduced into the sinter bed is oxidized to carbon dioxide. The dioxins introduced into the sinter bed are pyrolyzed when passing through the sinter bed.
通过介质添加口向反应罩11内通入烟气,有效的克服了现有技术中需要对脱硝后产生的副产品进行处理的问题,同时避免氨气或臭氧泄露等进一步污染环境。The flue gas is introduced into the reaction hood 11 through the medium addition port, which effectively overcomes the problem in the prior art that the by-products produced after denitrification need to be treated, and avoids further environmental pollution such as leakage of ammonia or ozone.
如图13所示是本发明的实施例十一,本实施例是在实施例十的基础上,烧结装置还包括第一烟气循环管路15,第一烟气循环管路15的第一端与抽风机构13的烧结烟道出口1331连通,第一烟气循环管路15的第二端与反应罩11内部连通,烧结料产生的部分烟气通过第一烟气循环管路15至反应罩11内。As shown in Figure 13, it is the eleventh embodiment of the present invention. This embodiment is based on the tenth embodiment. The sintering device also includes a first flue gas circulation pipeline 15. One end communicates with the sintering flue outlet 1331 of the exhaust mechanism 13, the second end of the first flue gas circulation pipeline 15 communicates with the inside of the reaction hood 11, and part of the flue gas generated by the sintering material passes through the first flue gas circulation pipeline 15 to the reaction chamber. Inside the cover 11.
也就是说,在本实施例中,可以将在烧结装置10中产生的烟气通过第一烟气循环管路15引回至反应罩11中,烧结装置10中产生的烟气由于还未经过后续净化,因此,不仅包括二氧化碳、水蒸气、水,还包括二氧化硫、氮氧化物、二噁英中的一种或多种,在反应罩11内烟气中的二氧化碳和水蒸气与烧结料中的碳添加剂中的碳单质在烧结燃烧层附近发生反应,生成一氧化碳、氢气等还原性气体,在烧结燃烧层附近形成还原性气氛。通过增加第一烟气循环管路15和第二烟气循环管路50,可以使烟气进行多重循环,在多重循环过程中可以将烟气中的二氧化硫、氮氧化物、二噁英清除,而二氧化碳、水蒸气、水反复利用,生成一氧化碳、氢气,使烧结料附近始终形成还原性气氛,从而又可以进一步抑制氮氧化物、硫化物的生成,保证对氮氧化物的处理,实现对烧结烟气进行脱硝的目的,并且最终可以产生大量的二 氧化碳,可以对烟气中的二氧化碳进行回收再利用,实现碳中和。That is to say, in this embodiment, the flue gas generated in the sintering device 10 can be led back to the reaction hood 11 through the first flue gas circulation pipeline 15, because the flue gas generated in the sintering device 10 has not passed through Subsequent purification, therefore, includes not only carbon dioxide, water vapor, water, but also one or more of sulfur dioxide, nitrogen oxides, and dioxins. The carbon element in the carbon additive reacts near the sintering combustion layer to generate reducing gases such as carbon monoxide and hydrogen, and forms a reducing atmosphere near the sintering combustion layer. By adding the first flue gas circulation pipeline 15 and the second flue gas circulation pipeline 50, the flue gas can be circulated multiple times, and sulfur dioxide, nitrogen oxides, and dioxins in the flue gas can be removed during the multiple circulation process, Carbon dioxide, water vapor, and water are reused repeatedly to generate carbon monoxide and hydrogen, so that a reducing atmosphere is always formed near the sintering material, which can further inhibit the formation of nitrogen oxides and sulfides, ensure the treatment of nitrogen oxides, and realize the sintering process. The purpose of flue gas denitrification, and ultimately can produce a large amount of carbon dioxide, the carbon dioxide in the flue gas can be recycled and reused to achieve carbon neutrality.
如图14所示是本发明的实施例十二,本实施例是的烧结工艺生产设备采用普通的烧结机,与机上冷却烧结机区别在于,其烧结装置10和烧结料冷却装置30是分开的,其反应原理以及其他结构相同均与机上冷却烧结机相同。As shown in Figure 14, it is the twelveth embodiment of the present invention. The sintering process production equipment in this embodiment adopts an ordinary sintering machine, which differs from the on-machine cooling sintering machine in that the sintering device 10 and the sintering material cooling device 30 are separated. , its reaction principle and other structures are the same as those of the cooling and sintering machine on the machine.
显然,本发明的上述实施方式仅仅是为清楚地说明本发明所作的举例,而并非是对本发明的实施方式的限定。对于所属领域的普通技术人员来说,在上述说明的基础上还可以做出其它不同形式的变化或变动。这里无法对所有的实施方式予以穷举。凡是属于本发明的技术方案所引伸出的显而易见的变化或变动仍处于本发明的保护范围之列。Apparently, the above-mentioned embodiments of the present invention are only examples for clearly illustrating the present invention, rather than limiting the embodiments of the present invention. For those of ordinary skill in the art, other changes or changes in different forms can be made on the basis of the above description. All the implementation manners cannot be exhaustively listed here. All obvious changes or variations derived from the technical solutions of the present invention are still within the protection scope of the present invention.

Claims (23)

  1. 一种烧结装置,包括用于运送烧结料的运输机构(12),其特征在于,还包括:A sintering device, comprising a transportation mechanism (12) for transporting sintering material, characterized in that it also includes:
    反应罩(11),所述反应罩(11)罩设在所述运输机构(12)的上方,所述反应罩(11)与所述运输机构(12)围成反应空间,所述反应罩(11)上开设有用于添加介质的介质添加口(111),所述介质添加口(111)与所述反应空间连通。Reaction cover (11), described reaction cover (11) cover is arranged on the top of described transport mechanism (12), and described reaction cover (11) and described transport mechanism (12) encircle reaction space, and described reaction cover (11) is provided with a medium addition port (111) for adding a medium, and the medium addition port (111) communicates with the reaction space.
  2. 根据权利要求1所述的烧结装置,其特征在于,The sintering device according to claim 1, characterized in that,
    所述介质添加口(111)位置位于所述反应罩(11)的靠近顶部位置处。The medium addition port (111) is located near the top of the reaction cover (11).
  3. 根据权利要求1所述的烧结装置,其特征在于,The sintering device according to claim 1, characterized in that,
    所述反应罩(11)上设置有用于控制介质加入量的阀门(112)。The reaction cover (11) is provided with a valve (112) for controlling the amount of medium added.
  4. 根据权利要求1所述的烧结装置,其特征在于,The sintering device according to claim 1, characterized in that,
    所述介质添加口(111)用于通入烟气。The medium addition port (111) is used for introducing flue gas.
  5. 根据权利要求4所述的烧结装置,其特征在于,所述烧结装置还包括:The sintering device according to claim 4, wherein the sintering device further comprises:
    抽风机构(13),所述抽风机构(13)设置在所述运输机构(12)下方;An exhaust mechanism (13), the exhaust mechanism (13) is arranged below the transport mechanism (12);
    点火机构(14),所述点火机构(14)用于点燃烧结料;Ignition mechanism (14), described ignition mechanism (14) is used for igniting and burning knot;
    第一烟气循环管路(15),所述第一烟气循环管路(15)的第一端与所述抽风机构(13)的烧结烟道出口(1331)连通,所述第一烟气循环管路(15)的第二端与所述介质添加口(111)连通,所述烧结料产生的部分烟气通过所述第一烟气循环管路(15)循环至反应罩(11)内。The first flue gas circulation pipeline (15), the first end of the first flue gas circulation pipeline (15) communicates with the sintering flue outlet (1331) of the draft mechanism (13), the first flue gas The second end of the gas circulation pipeline (15) communicates with the medium addition port (111), and part of the flue gas generated by the sintering material is circulated to the reaction hood (11) through the first flue gas circulation pipeline (15). )Inside.
  6. 根据权利要求4或5所述的烧结装置,其特征在于,The sintering device according to claim 4 or 5, characterized in that,
    所述烟气中包括二氧化碳、水蒸气、水、二氧化硫、氮氧化物、一氧化碳、二噁英中的一种或多种。The flue gas includes one or more of carbon dioxide, water vapor, water, sulfur dioxide, nitrogen oxides, carbon monoxide, and dioxins.
  7. 根据权利要求1所述的烧结装置,其特征在于,The sintering device according to claim 1, characterized in that,
    所述反应罩(11)上还设置有用于通入外部烟气的外部烟气添加口(113)。The reaction cover (11) is also provided with an external flue gas addition port (113) for introducing external flue gas.
  8. 根据权利要求1所述的烧结装置,其特征在于,所述烧结装置(10)还包括:The sintering device according to claim 1, characterized in that, the sintering device (10) further comprises:
    介质添加机构,所述介质添加机构的出料口与所述介质添加口(111)连通,所述介质添加机构用于向烧结料喷洒还原介质,所述介质添加机构输出的还原介质与烟气中的氮氧化物发生反应或与烧结料中的碳发生反应生成还原剂并放热。A medium adding mechanism, the discharge port of the medium adding mechanism communicates with the medium adding port (111), the medium adding mechanism is used to spray reducing medium to the sintering material, the reducing medium and flue gas output by the medium adding mechanism The nitrogen oxides in the sinter react or react with the carbon in the sinter to form a reducing agent and release heat.
  9. 根据权利要求8所述的烧结装置,其特征在于,The sintering device according to claim 8, characterized in that,
    所述运输机构(12)为烧结台车,烧结料设置于所述烧结台车中,且烧结料在所述烧结台车的移动过程中燃烧形成由上至下分布的已燃烧层、燃烧层和烧结料层,所述介质经过所述已燃烧层后与所述燃烧层和烧结料层反应并放热。The transportation mechanism (12) is a sintering trolley, and the sintering material is arranged in the sintering trolley, and the sintering material burns during the movement of the sintering trolley to form a burnt layer and a burning layer distributed from top to bottom. and the sintered material layer, the medium reacts with the burned layer and the sintered material layer after passing through the burned layer and releases heat.
  10. 根据权利要求9所述的烧结装置,其特征在于,The sintering device according to claim 9, characterized in that,
    所述介质添加机构将所述介质输送至所述烧结料的已燃烧层的上方,且所述介质由所述抽风机构(13)吸入烧结料内部与所述燃烧层和烧结料层中的碳接触应生成可燃性气体,可燃性气体发生氧化反应并放热。The medium adding mechanism transports the medium above the burnt layer of the sintered material, and the medium is sucked into the inside of the sintered material and the carbon in the burning layer and the sintered material layer by the ventilation mechanism (13). Contact should generate flammable gas, which will undergo oxidation reaction and release heat.
  11. 根据权利要求1所述的烧结装置,其特征在于,The sintering device according to claim 1, characterized in that,
    所述抽风机构(13)包括风机、多个烧结风箱和烧结烟道(133),所有所述烧结风箱设置于所述运输机构(12)的下方,且所有所述烧结风箱均与所述烧结烟道(133)连通,所述风机设置于所述烧结烟道(133)上。The exhaust mechanism (13) includes a blower fan, a plurality of sintering air boxes and a sintering flue (133), all of the sintering air boxes are arranged below the transport mechanism (12), and all of the sintering air boxes are connected to the sintering air boxes. The flue (133) is connected, and the fan is arranged on the sintering flue (133).
  12. 根据权利要求11所述的烧结装置,其特征在于,所述烧结风箱包括:The sintering device according to claim 11, wherein the sintering bellows comprises:
    风箱本体(131),所述风箱本体(131)内具有收集烟气的内腔(1311),所述风箱本体(131)上还设置有与所述内腔(1311)连通的进烟口;A bellows body (131), the bellows body (131) has an inner cavity (1311) for collecting smoke, and the bellows body (131) is also provided with a smoke inlet communicating with the inner cavity (1311);
    反应器(132),所述反应器(132)具有净化腔(1322),所述反应器(132)上还具有与所述净化腔(1322)连通的排烟口(1323),所述净化腔(1322)与所述内腔(1311)连通,所述净化腔(1322)用于净化所述内腔(1311)中的烟气。Reactor (132), the reactor (132) has a purification chamber (1322), also has a smoke outlet (1323) communicated with the purification chamber (1322) on the described reactor (132), the purification The chamber (1322) communicates with the inner chamber (1311), and the purification chamber (1322) is used to purify the smoke in the inner chamber (1311).
  13. 一种烧结工艺生产设备,其特征在于,包括权利要求1至12中任一项所述的烧结装置。A sintering process production equipment, characterized by comprising the sintering device according to any one of claims 1-12.
  14. 根据权利要求13所述的烧结工艺生产设备,其特征在于,所述 烧结装置(10)具有烧结烟道出口(1331),所述烧结工艺生产设备还包括:The sintering process production equipment according to claim 13, characterized in that, the sintering device (10) has a sintering flue outlet (1331), and the sintering process production equipment further comprises:
    烟气净化管路(20),所述烟气净化管路(20)包括对应设置的烟气加热入口(21)和烟气加热出口(22),所述烟气加热入口(21)与所述烧结烟道出口(1331)连通;A flue gas purification pipeline (20), the flue gas purification pipeline (20) includes a correspondingly arranged flue gas heating inlet (21) and a flue gas heating outlet (22), and the flue gas heating inlet (21) is connected to the flue gas heating inlet (21) The sintering flue outlet (1331) is connected;
    烧结料冷却装置(30),所述烧结料冷却装置(30)设置在烟气加热入口(21)和烟气加热出口(22)之间,所述烧结装置(10)产生的烟气通过所述烟气加热入口(21)进入所述烧结料冷却装置(30),烟气对燃烧后的烧结料进行冷却,同时,烧后的烧结料对通过的烟气进行加热,加热后的烟气进入所述烟气加热出口(22);A sintering material cooling device (30), the sintering material cooling device (30) is arranged between the flue gas heating inlet (21) and the flue gas heating outlet (22), the flue gas generated by the sintering device (10) passes through the The flue gas heating inlet (21) enters the sintering material cooling device (30), the flue gas cools the burned sintering material, and at the same time, the burned sintering material heats the passing flue gas, and the heated flue gas Enter the flue gas heating outlet (22);
    尾部反应器(40),所述尾部反应器(40)通过管路与所述烟气加热出口(22)连通,所述尾部反应器(40)用于对加热后的烟气进行净化处理。A tail reactor (40), the tail reactor (40) communicates with the flue gas heating outlet (22) through a pipeline, and the tail reactor (40) is used for purifying the heated flue gas.
  15. 根据权利要求14所述的烧结工艺生产设备,其特征在于,The sintering process production equipment according to claim 14, characterized in that,
    所述烧结料冷却装置(30)包括冷却区(31),所述烟气加热入口(21)位于所述冷却区(31)的下方,所述烟气加热出口(22)位于所述冷却区(31)的上方。The sintering material cooling device (30) includes a cooling area (31), the flue gas heating inlet (21) is located below the cooling area (31), and the flue gas heating outlet (22) is located in the cooling area (31) above.
  16. 根据权利要求15所述的烧结工艺生产设备,其特征在于,所述烧结工艺生产设备还包括:The sintering process production equipment according to claim 15, characterized in that, the sintering process production equipment further comprises:
    第二烟气循环管路(50),所述第二烟气循环管路(50)的第一端与所述尾部反应器(40)的烟气出口和/或所述烟气加热出口(22)连通,所述第二烟气循环管路(50)的第二端与所述反应罩(11)的介质添加口(111)连通。The second flue gas circulation pipeline (50), the first end of the second flue gas circulation pipeline (50) is connected to the flue gas outlet of the tail reactor (40) and/or the flue gas heating outlet ( 22) communication, the second end of the second flue gas circulation pipeline (50) communicates with the medium addition port (111) of the reaction hood (11).
  17. 根据权利要求16所述的烧结工艺生产设备,其特征在于,所述烧结装置还包括:The sintering process production equipment according to claim 16, wherein the sintering device further comprises:
    第一烟气循环管路(15),所述第一烟气循环管路(15)的第一端与所述抽风机构(13)的烧结烟道出口(1331)连通,所述第一烟气循环管路(15)的第二端与反应罩(11)内部连通,所述烧结料产生的部分烟气通过所述第一烟气循环管路(15)至反应罩(11)内。The first flue gas circulation pipeline (15), the first end of the first flue gas circulation pipeline (15) communicates with the sintering flue outlet (1331) of the draft mechanism (13), the first flue gas The second end of the gas circulation pipeline (15) communicates with the interior of the reaction hood (11), and part of the flue gas generated by the sintering material passes through the first flue gas circulation pipeline (15) into the reaction hood (11).
  18. 根据权利要求17所述的烧结工艺生产设备,其特征在于,The sintering process production equipment according to claim 17, characterized in that,
    所述烟气中具有二氧化碳、水蒸气、水、二氧化硫、氮氧化物、 一氧化碳、二噁英中的一种或多种。The flue gas contains one or more of carbon dioxide, water vapor, water, sulfur dioxide, nitrogen oxides, carbon monoxide, and dioxins.
  19. 根据权利要求15所述的烧结工艺生产设备,其特征在于,The sintering process production equipment according to claim 15, characterized in that,
    所述冷却区(31)包括第一冷却区(311)和第二冷却区(312),所述第二冷却区(312)的温度大于所述第一冷却区(311)的温度;The cooling zone (31) includes a first cooling zone (311) and a second cooling zone (312), and the temperature of the second cooling zone (312) is greater than the temperature of the first cooling zone (311);
    所述烟气净化管路(20)还包括二次加热管路(23),所述二次加热管路(23)包括二次加热入口(231)和二次加热出口(232),所述二次加热入口(231)位于第一冷却区(311)的上方,所述二次加热出口(232)位于所述第二冷却区(312)的下方;The flue gas purification pipeline (20) also includes a secondary heating pipeline (23), and the secondary heating pipeline (23) includes a secondary heating inlet (231) and a secondary heating outlet (232), the The secondary heating inlet (231) is located above the first cooling zone (311), and the secondary heating outlet (232) is located below the second cooling zone (312);
    所述烟气加热入口(21)位于所述第一冷却区(311)的下方,所述烟气加热出口(22)位于所述第二冷却区(312)的上方。The flue gas heating inlet (21) is located below the first cooling zone (311), and the flue gas heating outlet (22) is located above the second cooling zone (312).
  20. 根据权利要求19所述的烧结工艺生产设备,其特征在于,The sintering process production equipment according to claim 19, characterized in that,
    所述二次加热管路(23)设置有催化剂添加装置和/或还原剂添加装置。The secondary heating pipeline (23) is provided with a catalyst adding device and/or a reducing agent adding device.
  21. 根据权利要求20所述的烧结工艺生产设备,其特征在于,所述烧结工艺生产设备还包括:The sintering process production equipment according to claim 20, characterized in that, the sintering process production equipment further comprises:
    第二烟气循环管路(50),所述第二烟气循环管路(50)的第一端与所述尾部反应器(40)的烟气出口和/或所述烟气加热出口(22)连通,所述第二烟气循环管路(50)的第二端与所述反应罩(11)内部连通。The second flue gas circulation pipeline (50), the first end of the second flue gas circulation pipeline (50) is connected to the flue gas outlet of the tail reactor (40) and/or the flue gas heating outlet ( 22) communication, the second end of the second flue gas circulation pipeline (50) communicates with the interior of the reaction hood (11).
  22. 根据权利要求21所述的烧结工艺生产设备,其特征在于,所述烧结装置还包括:The sintering process production equipment according to claim 21, wherein the sintering device further comprises:
    第一烟气循环管路(15),所述第一烟气循环管路(15)的第一端与所述抽风机构(13)的烧结烟道出口(1331)连通,所述第一烟气循环管路(15)的第二端与反应罩(11)内部连通,所述烧结料产生的部分烟气通过所述第一烟气循环管路(15)至反应罩(11)内。The first flue gas circulation pipeline (15), the first end of the first flue gas circulation pipeline (15) communicates with the sintering flue outlet (1331) of the draft mechanism (13), the first flue gas The second end of the gas circulation pipeline (15) communicates with the interior of the reaction hood (11), and part of the flue gas generated by the sintering material passes through the first flue gas circulation pipeline (15) into the reaction hood (11).
  23. 根据权利要求22所述的烧结工艺生产设备,其特征在于,The sintering process production equipment according to claim 22, characterized in that,
    所述烟气中具有二氧化碳、水蒸气、水、二氧化硫、氮氧化物、一氧化碳、二噁英中的一种或多种。The flue gas contains one or more of carbon dioxide, water vapor, water, sulfur dioxide, nitrogen oxides, carbon monoxide, and dioxins.
PCT/CN2021/097985 2021-06-02 2021-06-02 Sintering apparatus and sintering process production device WO2022252156A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/CN2021/097985 WO2022252156A1 (en) 2021-06-02 2021-06-02 Sintering apparatus and sintering process production device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2021/097985 WO2022252156A1 (en) 2021-06-02 2021-06-02 Sintering apparatus and sintering process production device

Publications (1)

Publication Number Publication Date
WO2022252156A1 true WO2022252156A1 (en) 2022-12-08

Family

ID=84322710

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2021/097985 WO2022252156A1 (en) 2021-06-02 2021-06-02 Sintering apparatus and sintering process production device

Country Status (1)

Country Link
WO (1) WO2022252156A1 (en)

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5448606A (en) * 1977-09-26 1979-04-17 Nippon Kokan Kk <Nkk> Treatment of sintering machine exhaust gas
JP2011105985A (en) * 2009-11-16 2011-06-02 Kobe Steel Ltd Method for treating exhaust gas in sintering machine
CN103157356A (en) * 2011-12-14 2013-06-19 鞍钢股份有限公司 Sintering denitrification system and nitrogen oxide removal method thereof
CN109569183A (en) * 2019-01-02 2019-04-05 中冶长天国际工程有限责任公司 A kind of bi serie sintering system smoke comprehensive circulation process method and processing unit
CN109772160A (en) * 2019-03-25 2019-05-21 秦皇岛新特科技有限公司 Can purifying smoke bellow assemblies, the processing equipment and processing method of clinker flue gas
CN110274463A (en) * 2019-07-22 2019-09-24 山东泰山钢铁集团有限公司 A kind of pure sintering system and method based on fuel formulations and roasting control
CN110639356A (en) * 2018-06-27 2020-01-03 高彦 Method and device for treating high-temperature clinker flue gas
CN110763033A (en) * 2019-10-21 2020-02-07 武汉科技大学 Flue gas circulation denitration sintering system and sintering method thereof
CN111054170A (en) * 2019-12-27 2020-04-24 北京中航泰达环保科技股份有限公司 Sintering flue gas circulation combined full pollutant treatment device and method
CN112815728A (en) * 2021-01-22 2021-05-18 秦皇岛新特科技有限公司 Flue gas purification device of on-board cooling sintering machine

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5448606A (en) * 1977-09-26 1979-04-17 Nippon Kokan Kk <Nkk> Treatment of sintering machine exhaust gas
JP2011105985A (en) * 2009-11-16 2011-06-02 Kobe Steel Ltd Method for treating exhaust gas in sintering machine
CN103157356A (en) * 2011-12-14 2013-06-19 鞍钢股份有限公司 Sintering denitrification system and nitrogen oxide removal method thereof
CN110639356A (en) * 2018-06-27 2020-01-03 高彦 Method and device for treating high-temperature clinker flue gas
CN109569183A (en) * 2019-01-02 2019-04-05 中冶长天国际工程有限责任公司 A kind of bi serie sintering system smoke comprehensive circulation process method and processing unit
CN109772160A (en) * 2019-03-25 2019-05-21 秦皇岛新特科技有限公司 Can purifying smoke bellow assemblies, the processing equipment and processing method of clinker flue gas
CN110274463A (en) * 2019-07-22 2019-09-24 山东泰山钢铁集团有限公司 A kind of pure sintering system and method based on fuel formulations and roasting control
CN110763033A (en) * 2019-10-21 2020-02-07 武汉科技大学 Flue gas circulation denitration sintering system and sintering method thereof
CN111054170A (en) * 2019-12-27 2020-04-24 北京中航泰达环保科技股份有限公司 Sintering flue gas circulation combined full pollutant treatment device and method
CN112815728A (en) * 2021-01-22 2021-05-18 秦皇岛新特科技有限公司 Flue gas purification device of on-board cooling sintering machine

Similar Documents

Publication Publication Date Title
CN106678805B (en) A kind of processing system and application method reducing incineration flue gas of household garbage dioxin
CN106705064A (en) Method for reducing dioxin in incineration gas of household garbage
KR102653672B1 (en) Method and device for denitrification of sinter flue gas
KR100309437B1 (en) Stackless waste material renewal process by oxygen enriched gas
CN112460604A (en) Hazardous waste incineration flue gas treatment system and hazardous waste incineration flue gas treatment method
CN111774410B (en) Medical waste low temperature carbonization treatment system
CN109908720A (en) A kind of method that sodium salt method removes heavy metal Hg in low-temperature flue gas
WO2022252156A1 (en) Sintering apparatus and sintering process production device
JP2004036983A (en) Method and device for treating ammonia containing gas
CN215676448U (en) Sintering device and sintering process production equipment
CN116422311A (en) Thermal regeneration device and regeneration method for activated carbon
CN215446475U (en) Dry type waste incineration treatment system
CN210198110U (en) Denitration treatment equipment for sintering flue gas
CN105546552A (en) Fluidized-bed high-temperature incineration and purification all-in-one device and method for resin type dangerous waste
CN113218186A (en) Sintering device and sintering process production equipment
AU2014289972B2 (en) Mineral carbonate looping reactor for ventilation air methane mitigation
CN219177718U (en) Low-temperature catalytic decomposition device for household garbage treatment
CN110822436A (en) Domestic garbage anoxic thermal decomposition treatment device and use method
CN214536189U (en) Household garbage incineration system capable of reducing dioxin emission
CN109668155A (en) The method of high temperature incineration method processing cycle gas decarbonization tail gas
CN115143473B (en) High-temperature dry distillation carbonization incineration device for household garbage
CN108421390A (en) A kind of method of flue gas of refuse burning combined denitration, Tuo bioxin
CN109603544A (en) A kind of equipment for denitrifying flue gas and method
CN219453978U (en) RCO catalytic combustion device
CN117685567A (en) Novel cremation machine tail gas dry treatment process method and device

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 21943523

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE