WO2022229512A1 - Method for recycling side products and/or waste for wastewater purification - Google Patents
Method for recycling side products and/or waste for wastewater purification Download PDFInfo
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- WO2022229512A1 WO2022229512A1 PCT/FI2022/050279 FI2022050279W WO2022229512A1 WO 2022229512 A1 WO2022229512 A1 WO 2022229512A1 FI 2022050279 W FI2022050279 W FI 2022050279W WO 2022229512 A1 WO2022229512 A1 WO 2022229512A1
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- Prior art keywords
- biochar
- purification
- waste
- side products
- water
- Prior art date
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- 238000000746 purification Methods 0.000 title claims abstract description 69
- 238000000034 method Methods 0.000 title claims abstract description 40
- 239000002699 waste material Substances 0.000 title claims abstract description 35
- 239000006227 byproduct Substances 0.000 title claims abstract description 34
- 239000002351 wastewater Substances 0.000 title claims abstract description 22
- 238000004064 recycling Methods 0.000 title claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 54
- 239000000047 product Substances 0.000 claims abstract description 27
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 24
- 238000003763 carbonization Methods 0.000 claims description 20
- 239000010802 sludge Substances 0.000 claims description 18
- 238000011282 treatment Methods 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 11
- 239000002994 raw material Substances 0.000 claims description 9
- 238000000197 pyrolysis Methods 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 239000002023 wood Substances 0.000 claims description 4
- 229920000426 Microplastic Polymers 0.000 claims description 2
- 239000003638 chemical reducing agent Substances 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- 239000002364 soil amendment Substances 0.000 claims description 2
- 239000002195 soluble material Substances 0.000 claims description 2
- 239000000428 dust Substances 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 230000004913 activation Effects 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 3
- 239000010841 municipal wastewater Substances 0.000 description 3
- 239000011122 softwood Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229940037003 alum Drugs 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000005352 clarification Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000005189 flocculation Methods 0.000 description 2
- 230000016615 flocculation Effects 0.000 description 2
- 239000010842 industrial wastewater Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000004065 wastewater treatment Methods 0.000 description 2
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 229910000856 hastalloy Inorganic materials 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/30—Active carbon
- C01B32/312—Preparation
- C01B32/318—Preparation characterised by the starting materials
- C01B32/324—Preparation characterised by the starting materials from waste materials, e.g. tyres or spent sulfite pulp liquor
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/30—Active carbon
- C01B32/312—Preparation
- C01B32/336—Preparation characterised by gaseous activating agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/40—Solid fuels essentially based on materials of non-mineral origin
- C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
- C10L5/447—Carbonized vegetable substances, e.g. charcoal, or produced by hydrothermal carbonization of biomass
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
- C10L9/08—Treating solid fuels to improve their combustion by heat treatments, e.g. calcining
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
- C10L9/08—Treating solid fuels to improve their combustion by heat treatments, e.g. calcining
- C10L9/086—Hydrothermal carbonization
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
- C02F1/004—Processes for the treatment of water whereby the filtration technique is of importance using large scale industrial sized filters
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/38—Treatment of water, waste water, or sewage by centrifugal separation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/10—Treatment of sludge; Devices therefor by pyrolysis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/26—Nature of the water, waste water, sewage or sludge to be treated from the processing of plants or parts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/14—Injection, e.g. in a reactor or a fuel stream during fuel production
- C10L2290/146—Injection, e.g. in a reactor or a fuel stream during fuel production of water
Definitions
- the present disclosure relates to a method for reusing side products and/or waste produced in a forest product mill in a water purification process.
- the present disclosure further relates to a system for purification of wastewater.
- Typical water purifica tion processes that may be applicable to both industrial and municipal wastewaters may include several distinct processes intended to purify the water in a stepwise manner.
- Water purification processes commonly include methods such as flocculation, filtration, precipita tion, clarification, biological treatment, and others.
- a method for reusing side products and/or waste originating in a forest product mill is disclosed.
- the method may comprise carbonization of side products and/or waste to form biochar and using the biochar in a water purification process to form a used biochar composition, wherein the used biochar composition can be burned, recycled, or regenerated.
- a system for purification of wastewater is also disclosed.
- the system may comprise a primary, a secondary, and a tertiary purification.
- Fig. 1 presents a flow chart of one embodiment of the water purification process utilizing activated carbon.
- Fig. 2 presents a schematic view of a jar test as described in Example 3.
- a method for reusing side products and/or waste produced in a forest product mill in purification of wastewater from said mill is disclosed.
- the method may comprise carbonization of side products and waste streams from the forest product mill to form biochar and using the biochar in a water purification process.
- a used biochar composition is formed from the biochar.
- the method comprises reusing side products and/or waste produced in a forest product mill including carbonization of side products and/or waste to form biochar and using the biochar in a water purification process to form a used biochar composition, wherein the used biochar composition can be burned, recycled, or regenerated.
- biochar refers to carbon or activated carbon produced from renewable sources of raw material. Terms such as “activated biochar”, “biocarbon”, or “activated biocarbon” may be used as synonyms to biochar.
- the term "forest product mill” refers to any factory or mill producing refined products from a raw material or raw materials originating from forests or other plant-based raw material.
- forest product mills are paper mills, sawmills, pulp mills, biorefineries, plywood mills, board mills, and paperboard mills.
- forest product mill also serves as a collective term including all separate activities and production facilities located in one facility.
- the biochar used in water purification may be formed by carbonization of side products and/or waste produced in a forest product mill.
- the side products and/or waste comprise side products and waste streams of the forest product mill.
- side products refers to any parts or components of the raw material that is not a part of and included in the main product of the forest product mill.
- waste streams refers to waste materials produced in the processes of a forest product mill.
- Non-limiting examples of side product and/or waste streams produced in forest product mills include sawdust, bark, knots, branches, lignin, sludge from water purification, black liquor residues, wood chips, or any combination thereof.
- the sludge used for the production of biochar may be sludge formed in the purification of wastewater from a forest product mill.
- the sludge used for the production of biochar may be sludge recovered from primary, secondary, tertiary water purification, or any combination thereof.
- the sludge used for the production of biochar may be sludge formed in the purification of wastewater from a forest product mill, purification of municipal wastewater, purification of other industrial wastewater, side products from other industrial process, or any combination thereof.
- the side products and/or waste used for the production of biochar may be a mixture of sludge and other side products and/or waste or side streams.
- a non-limiting example of such a mixture is a mixture of sludge with bark, knots, sawdust, or any combination thereof.
- the moisture content of the side products and/or waste may be reduced using any suitable method known to a person skilled in the art.
- the final moisture content will differ depending on the carbonization method.
- the water content of the side products and/or waste is reduced to 60 weight-% or less before production of the biochar.
- the biochar used in the method according to the present disclosure may be produced by carbonization of side products and/or waste produced in a forest product mill.
- the carbonization may be performed using any carbonization method known to a person skilled in the art. Examples of suitable carbonization methods include, but are not limited to, pyrolysis, slow pyrolysis, hydrothermal carbonization (HTC), torrefaction, or any combination thereof.
- suitable carbonization methods include, but are not limited to, pyrolysis, slow pyrolysis, hydrothermal carbonization (HTC), torrefaction, or any combination thereof.
- the biochar used for water purification may be activated biochar or activated carbon, which are used synonymously in the present disclosure.
- Activation of the biochar formed from the side products and/or waste may be done using any method for carbon activation known to a skilled person such as chemical or physical activation.
- the method comprises reusing side products and/or waste produced in a forest product mill comprising carbonization of side products and/or waste to form activated biochar and using the activated biochar in a water purification process to form a used biochar composition, wherein the used biochar composition can be burned, recycled, or regenerated.
- the water purification that utilizes the activated biochar may be any water purification process known to a person skilled in the art, including, but not limited to, purification of wastewater from a forest product mill, municipal wastewater, or any other wastewater in need of purification.
- the water purification step includes removal of soluble material, colloidal material, microplastics, or any combination thereof.
- the use of biochar or activated carbon in a water purification treatment may enable elimination of one or more chemicals commonly used in the water purification process.
- the efficiency of the water purification according to the method of the present disclosure may be measured using any conventional measurement known to a skilled person.
- a non-limiting example of a measurement used to determine the efficiency of the water purification is chemical oxygen demand (COD).
- the used biochar is separated from the water and recovered. In one embodiment, the used biochar is separated from the water and recovered after the use in a water purification process. Separation of the used biochar from the water following the water purification may be performed using any suitable method or methods known to a person skilled in the art. Non-limiting examples of methods for separating biochar from water include filtration, centrifugation, and filter pressing.
- the used biochar is burned, regenerated, or recycled after the use in water purification.
- the used biochar is separated from the water, recovered, and recycled after the use in water purification. Once the used biochar has been recovered, it may be recycled by any method known to a person skilled in the art.
- the used biochar may be burned, regenerated, or recycled.
- the used biochar may be recycled as raw material for concrete, as filler material, as a metallurgical reducing agent, for soil amendment, or any combination thereof.
- the regenerated used biochar may be reused in water purification.
- a system for purification of wastewater comprises a primary, a secondary, and a tertiary purification. In one embodiment, the system comprises a quaternary purification.
- the quaternary purification comprises purification using biochar produced from side products and/or waste produced in a forest product mill.
- the primary purification is a physical purification
- the secondary purification is a biological purification
- the tertiary purification is a chemical treatment.
- the chemical treatment is a coagulation and/or flocculation.
- the quaternary purification is a purification using biochar or activated carbon.
- the method for reusing side products and/or waste produced in a forest product mill described in the current specification has the added utility of being suitable for the reusing or recycling of side products and/or waste produced in a forest product mill at the mill.
- This provides the advantage that the waste sludges and side products instead of their separate treatments are processed in a single processing unit within the mill, which may produce both energy and the added value biochar, leading to higher utilization degree of the acquired raw material.
- the single processing unit may be a carbonization unit, wherein the carbonization is performed by pyrolysis.
- the inorganic elements contained in the side streams and waste sludges will remain immobilised within the biochar, thus reducing their impact as undesired non-process elements in the mill.
- An additional advantage provided by the method of the present disclosure is a reduction in the amount of material needed to be purchased for the water purification process, leading to a reduction in costs.
- Example 1 Production of activated carbon using hydrothermal carbonization and steam activation
- Dried wood bark (with a dry matter content of approximately 90 %) and excess sludge from secondary treatment from the same softwood pulp mill as described in example 3 was thoroughly mixed in a ratio of 1:1 relative to dry matter content.
- the dry matter content of the mixture was adjusted by adding water. 2.1 kg of bark:sludge mixture with a dry matter content of 18.1 % was mixed with 3.9 kg water to yield 6.0 kg of a bark:sludge mixture with a dry matter content of 6.7 %.
- the pH of the diluted mixture was adjusted to approximately 4 by the addition of 6.0 g concentrated sulphuric acid using mechanical stirring.
- the formed mixture was treated in a Hastelloy C276 high-temperature autoclave at 260 °C for 2 h with constant stirring (300 rpm). After 3 h, the mixture was weighed (5.79 kg) and the pH was measured (4.7). The mixture was filtered using a Buchner funnel to collect the formed biochar. The collected biochar was dried at 105 °C to yield 200.2 g biochar with a dry matter content of 95.3 % (52.9 % yield).
- the reactor was heated to 800 °C at a rate of 5 °C/min under a nitrogen flow of 5 1/min. Once the target temperature was reached, water was pumped into the oven to generate steam. The water flow rate was 4,5 ml/min and nitrogen flow 51/min.
- Example 2 Producing activated carbon using slow pyrolysis and steam activation
- Dried wood bark (with a dry matter content of approximately 90 %) and sludge from the same softwood pulp mill as described in example 3 was thoroughly mixed in a ratio of 1:1 relative to dry matter content and the mixture dried to a total dry matter content of approximately 90 %.
- 200 g of the dried bark:sludge mixture was weighed and placed inside a batch carbonization reactor which was thoroughly sealed and purged with nitrogen to remove any air inside the reactor.
- the reactor was slowly heated using a ramped heating program with temperature holding steps at 280 °C (heating rate 8 °C/min, hold time 3 h), 330 °C
- Example 3 Jar tests with different doses of activated biochar
- a wastewater sample was taken from a softwood pulp mill secondary clarifier overflow.
- the pulp mill has modern low-water consuming debarking and it produces 330 000 t/a bleached chemi-thermomechanical pulp.
- the wastewater treatment plant has a first primary clarification and an activated sludge plant, from where the treated water is discharged into a lake.
- activated biochars can achieve the same COD reduction of 35 - 45 % with a dose of 100 mg/1 as commercially available activated carbon.
- a dose of 200 mg/1 activated biochar increased COD reduction compared to 100 mg/1, but the reduction was only 5 - 10 % higher.
- COD reduction depends on wastewater composition, biochar raw material and carbonization and activation method. It was also possible to flocculate activated biochar with polymer and microsand and settle on the bottom as easily as the commercial activated carbon.
- the embodiments described hereinbefore may be used in any combination with each other. Several of the embodiments may be combined together to form a further embodiment.
- a method or system disclosed herein may comprise at least one of the embodiments described hereinbefore. It will be understood that the benefits and advantages described above may relate to one embodiment or may relate to several embodiments. The embodiments are not limited to those that solve any or all of the stated problems or those that have any or all of the stated benefits and advantages. It will further be understood that reference to 'an' item refers to one or more of those items.
- the term "comprising" is used in this specification to mean including the feature(s) or act(s) followed thereafter, without excluding the presence of one or more additional features or acts.
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Abstract
A method for reusing side products and/or waste produced in a forest product mill in a water purification process is disclosed. A system for purification of wastewater is further disclosed.
Description
METHOD FOR RECYCLING SIDE PRODUCTS AND/OR WASTE FOR WASTEWATER PURIFICATION
TECHNICAL FIELD
The present disclosure relates to a method for reusing side products and/or waste produced in a forest product mill in a water purification process. The present disclosure further relates to a system for purification of wastewater.
BACKGROUND
In addition to other streams of waste or side products, many industrial processes produce large amounts of wastewater that must be purified before it is allowed to exit the process. Typical water purifica tion processes that may be applicable to both industrial and municipal wastewaters may include several distinct processes intended to purify the water in a stepwise manner. Water purification processes commonly include methods such as flocculation, filtration, precipita tion, clarification, biological treatment, and others.
SUMMARY
A method for reusing side products and/or waste originating in a forest product mill is disclosed. The method may comprise carbonization of side products and/or waste to form biochar and using the biochar in a water purification process to form a used biochar composition, wherein the used biochar composition can be burned, recycled, or regenerated.
A system for purification of wastewater is also disclosed. The system may comprise a primary, a secondary, and a tertiary purification.
BRIEF DESCRIPTION OF THE DRAWINGS
The accompanying drawings, which are included to provide a further understanding of the embodiments and constitute a part of this specification, illustrates various embodiments. In the drawings:
Fig. 1 presents a flow chart of one embodiment of the water purification process utilizing activated carbon.
Fig. 2 presents a schematic view of a jar test as described in Example 3.
DETAILED DESCRIPTION
A method for reusing side products and/or waste produced in a forest product mill in purification of wastewater from said mill is disclosed. The method may comprise carbonization of side products and waste streams from the forest product mill to form biochar and using the biochar in a water purification process. In the water purification process, a used biochar composition is formed from the biochar. In one embodiment, the method comprises reusing side products and/or waste produced in a forest product mill including carbonization of side products and/or waste to form biochar and using the biochar in a water purification process to form a used biochar composition, wherein the used biochar composition can be burned, recycled, or regenerated.
As used herein, the term "biochar" refers to carbon or activated carbon produced from renewable sources of raw material. Terms such as "activated biochar", "biocarbon", or "activated biocarbon" may be used as synonyms to biochar.
As used herein, the term "forest product mill" refers to any factory or mill producing refined products from a raw material or raw materials originating from forests or other plant-based raw material. Non-limiting
examples of forest product mills are paper mills, sawmills, pulp mills, biorefineries, plywood mills, board mills, and paperboard mills. As used herein, the term "forest product mill" also serves as a collective term including all separate activities and production facilities located in one facility.
The biochar used in water purification may be formed by carbonization of side products and/or waste produced in a forest product mill. In one embodiment, the side products and/or waste comprise side products and waste streams of the forest product mill. As used herein, the term "side products" refers to any parts or components of the raw material that is not a part of and included in the main product of the forest product mill. As used herein, the term "waste streams" refers to waste materials produced in the processes of a forest product mill. Non-limiting examples of side product and/or waste streams produced in forest product mills include sawdust, bark, knots, branches, lignin, sludge from water purification, black liquor residues, wood chips, or any combination thereof. In one embodiment, the sludge used for the production of biochar may be sludge formed in the purification of wastewater from a forest product mill.
In one embodiment, the sludge used for the production of biochar may be sludge recovered from primary, secondary, tertiary water purification, or any combination thereof. In certain embodiments, the sludge used for the production of biochar may be sludge formed in the purification of wastewater from a forest product mill, purification of municipal wastewater, purification of other industrial wastewater, side products from other industrial process, or any combination thereof.
In one embodiment, the side products and/or waste used for the production of biochar may be a mixture
of sludge and other side products and/or waste or side streams. A non-limiting example of such a mixture is a mixture of sludge with bark, knots, sawdust, or any combination thereof.
In certain embodiments, it will be necessary to decrease the moisture content of the side products and/or waste before production of the biochar. The moisture content of the side products and/or waste may be reduced using any suitable method known to a person skilled in the art. The final moisture content will differ depending on the carbonization method. In one embodiment, the water content of the side products and/or waste is reduced to 60 weight-% or less before production of the biochar.
The biochar used in the method according to the present disclosure may be produced by carbonization of side products and/or waste produced in a forest product mill. In certain embodiments, the carbonization may be performed using any carbonization method known to a person skilled in the art. Examples of suitable carbonization methods include, but are not limited to, pyrolysis, slow pyrolysis, hydrothermal carbonization (HTC), torrefaction, or any combination thereof.
The biochar used for water purification may be activated biochar or activated carbon, which are used synonymously in the present disclosure. Activation of the biochar formed from the side products and/or waste may be done using any method for carbon activation known to a skilled person such as chemical or physical activation.
In one embodiment, the method comprises reusing side products and/or waste produced in a forest product mill comprising carbonization of side products and/or waste to form activated biochar and using the activated biochar in a water purification process to form a used
biochar composition, wherein the used biochar composition can be burned, recycled, or regenerated.
The water purification that utilizes the activated biochar may be any water purification process known to a person skilled in the art, including, but not limited to, purification of wastewater from a forest product mill, municipal wastewater, or any other wastewater in need of purification. In one embodiment, the water purification step includes removal of soluble material, colloidal material, microplastics, or any combination thereof. The use of biochar or activated carbon in a water purification treatment may enable elimination of one or more chemicals commonly used in the water purification process.
In one embodiment, the efficiency of the water purification according to the method of the present disclosure may be measured using any conventional measurement known to a skilled person. A non-limiting example of a measurement used to determine the efficiency of the water purification is chemical oxygen demand (COD).
In one embodiment, the used biochar is separated from the water and recovered. In one embodiment, the used biochar is separated from the water and recovered after the use in a water purification process. Separation of the used biochar from the water following the water purification may be performed using any suitable method or methods known to a person skilled in the art. Non-limiting examples of methods for separating biochar from water include filtration, centrifugation, and filter pressing.
In one embodiment, the used biochar is burned, regenerated, or recycled after the use in water purification. In one embodiment, the used biochar is separated from the water, recovered, and recycled after the use in water purification.
Once the used biochar has been recovered, it may be recycled by any method known to a person skilled in the art. In certain embodiments, the used biochar may be burned, regenerated, or recycled. In certain embodiments, the used biochar may be recycled as raw material for concrete, as filler material, as a metallurgical reducing agent, for soil amendment, or any combination thereof. In one embodiment, the regenerated used biochar may be reused in water purification.
A system for purification of wastewater is also disclosed. In one embodiment, the system for purification of wastewater comprises a primary, a secondary, and a tertiary purification. In one embodiment, the system comprises a quaternary purification.
In one embodiment, the quaternary purification comprises purification using biochar produced from side products and/or waste produced in a forest product mill.
In one embodiment, the primary purification is a physical purification, the secondary purification is a biological purification, and the tertiary purification is a chemical treatment. In one embodiment, the chemical treatment is a coagulation and/or flocculation.
In one embodiment, the quaternary purification is a purification using biochar or activated carbon.
The method for reusing side products and/or waste produced in a forest product mill described in the current specification has the added utility of being suitable for the reusing or recycling of side products and/or waste produced in a forest product mill at the mill. This provides the advantage that the waste sludges and side products instead of their separate treatments are processed in a single processing unit within the mill, which may produce both energy and the added value biochar, leading to higher utilization degree of the acquired raw material. In certain embodiments, the single processing unit may be a carbonization unit,
wherein the carbonization is performed by pyrolysis. In addition, due to the pyrolysis process, the inorganic elements contained in the side streams and waste sludges will remain immobilised within the biochar, thus reducing their impact as undesired non-process elements in the mill.
An additional advantage provided by the method of the present disclosure is a reduction in the amount of material needed to be purchased for the water purification process, leading to a reduction in costs.
EXAMPLES
Reference will now be made in detail to various embodiments.
The description below discloses some embodiments in such a detail that a person skilled in the art is able to utilize the embodiments based on the disclosure. Not all steps or features of the embodiments are discussed in detail, as many of the steps or features will be obvious for the person skilled in the art based on this specification.
Example 1 - Production of activated carbon using hydrothermal carbonization and steam activation
Dried wood bark (with a dry matter content of approximately 90 %) and excess sludge from secondary treatment from the same softwood pulp mill as described in example 3 was thoroughly mixed in a ratio of 1:1 relative to dry matter content. The dry matter content of the mixture was adjusted by adding water. 2.1 kg of bark:sludge mixture with a dry matter content of 18.1 % was mixed with 3.9 kg water to yield 6.0 kg of a bark:sludge mixture with a dry matter content of 6.7 %. The pH of the diluted mixture was adjusted to
approximately 4 by the addition of 6.0 g concentrated sulphuric acid using mechanical stirring.
The formed mixture was treated in a Hastelloy C276 high-temperature autoclave at 260 °C for 2 h with constant stirring (300 rpm). After 3 h, the mixture was weighed (5.79 kg) and the pH was measured (4.7). The mixture was filtered using a Buchner funnel to collect the formed biochar. The collected biochar was dried at 105 °C to yield 200.2 g biochar with a dry matter content of 95.3 % (52.9 % yield).
45 g of the dried biochar was weighed on a steel dish and placed in a batch carbonization reactor. The reactor was sealed and purged with nitrogen to remove all air inside the reactor.
The reactor was heated to 800 °C at a rate of 5 °C/min under a nitrogen flow of 5 1/min. Once the target temperature was reached, water was pumped into the oven to generate steam. The water flow rate was 4,5 ml/min and nitrogen flow 51/min.
The process was allowed to proceed for 3.5. h after which the flow of water was stopped, and the reactor allowed to cool before opening. Once the reactor had cooled, the obtained activated biochar was collected and weighed (10.1 g, yield 26.4 %).
Example 2 - Producing activated carbon using slow pyrolysis and steam activation
Dried wood bark (with a dry matter content of approximately 90 %) and sludge from the same softwood pulp mill as described in example 3 was thoroughly mixed in a ratio of 1:1 relative to dry matter content and the mixture dried to a total dry matter content of approximately 90 %. 200 g of the dried bark:sludge mixture was weighed and placed inside a batch carbonization reactor which was thoroughly sealed and
purged with nitrogen to remove any air inside the reactor.
The reactor was slowly heated using a ramped heating program with temperature holding steps at 280 °C (heating rate 8 °C/min, hold time 3 h), 330 °C
(heating rate 1 °C/ min, hold time 20 min) and 475 °C (heating rate 5 °C/ min, hold time 3 h). Nitrogen flow during entire program was 51/min. After carbonization at 475 °C, the reactor was allowed to cool before opening. Once the reactor had cooled, the obtained activated biochar was collected and weighed (66 g, yield 33 %).
Example 3 - Jar tests with different doses of activated biochar
A wastewater sample was taken from a softwood pulp mill secondary clarifier overflow. The pulp mill has modern low-water consuming debarking and it produces 330 000 t/a bleached chemi-thermomechanical pulp. There is no other industry that produces wastewater to the wastewater treatment plant. The wastewater treatment plant has a first primary clarification and an activated sludge plant, from where the treated water is discharged into a lake.
Conventional tertiary treatment to remove dis solved organic material was done with a laboratory scale batch-flotation unit. The unit consisted of a tank with a mixer and a dispersion water system. The tank was filled with 5 1 of wastewater sample and its pH was adjusted with H2SO4 to 5.5. 400 mg/1 of alum solution containing 100 g alum/1 was dosed to the sample and mixed well. Then, 3 mg/1 of flocculant solution of 1 g/1 cationic polyacrylamide was dosed. The water was mixed for 2 minutes at 120 rpm to achieve good floes. Finally, floes were separated with dispersion water and the treated water was collected for activated biochar
treatment. Dispersion water pressure was 6 bar and dose 1 litre. Dispersion water was prepared from the same wastewater sample using the above tertiary treatment method, so it did not change the composition of the wastewater.
6 plastic jars were each filled with 500 ml of tertiary treated wastewater and put in a laboratory scale flocculator (jar test bench, Fig. 2). Doses of 100 and 200 mg/1 of different activated biochars were dosed. The activated biochars were prepared according to exam ples 1 or 2. One commercially available activated carbon was also tested. The tested commercial product was a powdered high-grade coal-based activated carbon de signed for water treatment that had a BET number of 1150 m2/g. After activated biochar dosing, water was mixed for 15 minutes at 200 rpm. 3 mg/1 of the same flocculant as in the tertiary treatment and approximately 5 ml of microsand (quartz, 60 - 180 ym particle size) were added and mixed at 120 rpm for 3 minutes. Mixing was stopped and after the flocculated solids had settled on the bottom of the jars, water samples for analysis were collected. Microsand was dosed only to help solids set tle faster.
The jar tests proved that activated biochars can achieve the same COD reduction of 35 - 45 % with a dose of 100 mg/1 as commercially available activated carbon. A dose of 200 mg/1 activated biochar increased COD reduction compared to 100 mg/1, but the reduction was only 5 - 10 % higher. COD reduction depends on wastewater composition, biochar raw material and carbonization and activation method. It was also possible to flocculate activated biochar with polymer and microsand and settle on the bottom as easily as the commercial activated carbon.
It is obvious to a person skilled in the art that with the advancement of technology, the basic idea
may be implemented in various ways. The embodiments are thus not limited to the examples described above; instead they may vary within the scope of the claims.
The embodiments described hereinbefore may be used in any combination with each other. Several of the embodiments may be combined together to form a further embodiment. A method or system disclosed herein, may comprise at least one of the embodiments described hereinbefore. It will be understood that the benefits and advantages described above may relate to one embodiment or may relate to several embodiments. The embodiments are not limited to those that solve any or all of the stated problems or those that have any or all of the stated benefits and advantages. It will further be understood that reference to 'an' item refers to one or more of those items. The term "comprising" is used in this specification to mean including the feature(s) or act(s) followed thereafter, without excluding the presence of one or more additional features or acts.
Claims
1. Method for reusing side products and/or waste produced in a forest product mill comprising carbonization of side products and/or waste to form biochar and using the biochar in a water purification process to form a used biochar composition, wherein the used biochar composition can be burned, recycled, or regenerated, characterized in that the side products and/or waste may be sludge, bark, knots, saw dust, wood chips, or any combination thereof, and the sludge used for biochar production is sludge formed in the purification of wastewater from a forest product mill.
2. The method of claim 1, wherein the biochar is activated biochar or activated carbon.
3. The method of any of the preceding claims, wherein the biochar is produced by pyrolysis, slow pyrolysis, hydrothermal carbonization (HTC), torrefaction, or any combination thereof.
4. The method of any of the preceding claims, wherein the used biochar composition is burned, regenerated, or recycled after the use in water purification.
5. The method of claim 6, wherein recycling is burning, as raw material for concrete, as filler material, as a metallurgical reducing agent, for soil amendment, or any combination thereof.
6. The method of any of the preceding claims, wherein the water purification step includes removal of soluble material, colloidal material, microplastics, or any combination thereof.
7. The method of any the preceding claims, wherein the used biochar is separated from the water and recovered.
8. System for purification of wastewater comprising a primary, a secondary, a tertiary purification, and a quaternary purification, characterized in that the quaternary purification comprises purification using biochar produced from side products and/or waste produced in a forest product mill.
9. The system of claim 8, wherein the primary purification is a physical purification, the secondary purification is a biological purification, and the tertiary purification is a chemical treatment.
10. The system of any one of claims 8 - 9, wherein the quaternary purification is a purification using biochar or activated carbon.
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CN116177527A (en) * | 2023-02-28 | 2023-05-30 | 北华大学 | Method for preparing biochar and organic fertilizer by using corn straw and papermaking black liquor |
Citations (4)
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---|---|---|---|---|
US4134786A (en) * | 1976-12-15 | 1979-01-16 | Nasa | Process for purification of waste water produced by a Kraft process pulp and paper mill |
WO2007067127A1 (en) * | 2005-12-06 | 2007-06-14 | Holmen Aktiebolag | A method for the purification of contamined aqueous liquid in a pulp or paper mill |
US20150144564A1 (en) * | 2013-11-25 | 2015-05-28 | University Of Idaho | Biochar water treatment |
US20170333868A1 (en) * | 2014-01-16 | 2017-11-23 | Carbon Technology Holdings, LLC | Carbon micro-plant |
-
2021
- 2021-04-28 FI FI20215496A patent/FI20215496A1/en unknown
-
2022
- 2022-04-28 WO PCT/FI2022/050279 patent/WO2022229512A1/en active Application Filing
- 2022-04-28 EP EP22723153.7A patent/EP4330193A1/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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US4134786A (en) * | 1976-12-15 | 1979-01-16 | Nasa | Process for purification of waste water produced by a Kraft process pulp and paper mill |
WO2007067127A1 (en) * | 2005-12-06 | 2007-06-14 | Holmen Aktiebolag | A method for the purification of contamined aqueous liquid in a pulp or paper mill |
US20150144564A1 (en) * | 2013-11-25 | 2015-05-28 | University Of Idaho | Biochar water treatment |
US20170333868A1 (en) * | 2014-01-16 | 2017-11-23 | Carbon Technology Holdings, LLC | Carbon micro-plant |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN116177527A (en) * | 2023-02-28 | 2023-05-30 | 北华大学 | Method for preparing biochar and organic fertilizer by using corn straw and papermaking black liquor |
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