WO2022193562A1 - 一种在线化学仪表智慧校验维护系统及方法 - Google Patents
一种在线化学仪表智慧校验维护系统及方法 Download PDFInfo
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- 239000000126 substance Substances 0.000 title claims abstract description 96
- 238000012423 maintenance Methods 0.000 title claims abstract description 35
- 238000000034 method Methods 0.000 title claims abstract description 12
- 238000012795 verification Methods 0.000 title abstract 3
- 239000012086 standard solution Substances 0.000 claims abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 238000005070 sampling Methods 0.000 claims description 9
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 239000000460 chlorine Substances 0.000 claims description 6
- 229910052801 chlorine Inorganic materials 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 5
- 239000010452 phosphate Substances 0.000 claims description 5
- 238000012360 testing method Methods 0.000 claims description 4
- 238000004891 communication Methods 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 238000003745 diagnosis Methods 0.000 claims description 2
- 230000008030 elimination Effects 0.000 claims description 2
- 238000003379 elimination reaction Methods 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 4
- 239000000377 silicon dioxide Substances 0.000 claims 2
- 239000000243 solution Substances 0.000 claims 1
- 238000005259 measurement Methods 0.000 description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 238000007689 inspection Methods 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 238000004164 analytical calibration Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/18—Water
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- the invention belongs to the field of daily maintenance of on-line chemical instruments in power plants, and relates to a smart calibration and maintenance system and method for on-line chemical instruments.
- Water vapor is an important working fluid for the operation of various thermal equipment in power plants. It must be continuously and accurately monitored by on-line chemical instruments and controlled within the range of standard requirements to prevent thermal equipment from corrosion, scaling and salt accumulation. Otherwise, safety accidents such as boiler tube burst, steam turbine salt accumulation and corrosion will occur. Therefore, the daily calibration and maintenance of online chemical instruments is an important task for operators. At present, the daily calibration of online chemical instruments mainly relies on manual labor, which is time-consuming and labor-intensive, the calibration procedure is cumbersome, the degree of automation is low, and the accuracy is difficult to guarantee. The main problems are as follows:
- the purpose of the present invention is to overcome the shortcomings of the above-mentioned prior art, and to provide an online chemical instrument intelligent calibration and maintenance system and method, which automatically completes the calibration and maintenance of the online chemical instrument.
- the online chemical meter intelligent calibration and maintenance system of the present invention includes a standard meter, a chemical meter to be calibrated and maintained, a data acquisition system, a control system, a standard solution source system and a number of water sample pipelines, wherein each water
- the sample pipeline is connected with the standard instrument and the chemical instrument to be calibrated and maintained.
- the standard solution source system is connected to the standard instrument and the chemical instrument to be calibrated and maintained.
- the output end of the standard instrument and the output end of the chemical instrument to be calibrated and maintained are connected with data.
- the input end of the acquisition system is connected, the output end of the data acquisition system is connected with the input end of the control system, and the output end of the control system is connected with the control end of the chemical instrument to be calibrated and maintained.
- each water sample pipeline is respectively connected with the inlet of the multi-channel switching sampling system, the outlet of the multi-channel switching sampling system is communicated with the inlet of the standard instrument, and the multi-channel switching inlet is connected.
- the control terminal of the sample system is connected with the output terminal of the control system.
- the outlet of the multi-channel switching sample introduction system is communicated with the inlet of the standard instrument through a communication pipe.
- the standard solution source system includes a standard solution source and a standard solution adding pump, wherein the standard solution source is communicated with the inlet of the standard instrument through the standard solution adding pump.
- the standard instruments are standard online conductivity meter, standard online hydrogen conductivity meter, standard online degassed hydrogen conductivity meter, standard online pH meter, standard online dissolved oxygen meter, standard online sodium meter, standard online silicon meter, standard online phosphoric acid meter Root meter, standard online chlorine meter or standard online sulfate meter.
- the chemical instruments to be calibrated and maintained are online conductivity meter, online hydrogen conductivity meter, online degassed hydrogen conductivity meter, online pH meter, online dissolved oxygen meter, online sodium meter, online silicon meter, online phosphate radical meter, online Chlorine meter or online sulfate meter.
- the maintenance chemical meter to be calibrated is of the same type as the standard meter.
- An online chemical instrument smart calibration and maintenance method includes the following steps:
- the water samples in the same water sample pipeline are respectively sent to the standard instrument and the chemical instrument to be calibrated and maintained for testing.
- the data detected by the standard instrument and the data detected by the chemical instrument to be calibrated and maintained are sent to the control system through the data acquisition system.
- the difference between the data detected by the standard instrument and the data detected by the chemical instrument to be calibrated and maintained is greater than or equal to the preset value, the chemical instrument to be calibrated and maintained will be diagnosed and eliminated; when the data detected by the standard instrument and the chemical instrument to be calibrated and maintained
- control the standard solution source system to output the standard solution and send it to the standard instrument and the chemical instrument to be calibrated and maintained.
- the data detected by the standard instrument and the data detected by the chemical instrument to be calibrated and maintained The data is sent to the control system through the data acquisition system, and the control system automatically calibrates the chemical meters to be calibrated and maintained according to the data detected by the standard meters.
- the same water sample is firstly sent to the standard instrument and the chemical instrument to be calibrated and maintained, and the data detected by the standard instrument is compared with the to-be-calibrated maintenance chemical instrument.
- the difference between the data detected by the chemical instrument is greater than or equal to the preset value, the chemical instrument to be calibrated and maintained is diagnosed and eliminated.
- the same standard solution is sent to the standard instrument and the chemical instrument to be calibrated and maintained respectively.
- Automatic calibration of chemical instruments to be calibrated and maintained according to the data obtained from standard instrument detection in order to solve the existing problems in online chemical instrument calibration and maintenance, avoid the possibility of manual tampering of instrument measurement errors, and realize the operation and maintenance of online chemical instruments. It can improve the measurement accuracy of online chemical instruments, ensure accurate and effective water quality supervision, and improve the operation safety of generator sets. It can be widely used in chemical industry, pharmaceutical industry, food industry and municipal industry.
- FIG. 1 is a schematic structural diagram of the present invention.
- 1 is the multi-channel switching sampling system
- 2 is the standard instrument
- 3 is the online chemical instrument to be calibrated and maintained
- 4 is the data acquisition system
- 5 is the control system
- 6 is the standard solution adding pump
- 7 is the standard solution source.
- the online chemical meter intelligent calibration and maintenance system of the present invention includes a standard meter 2, a chemical meter to be calibrated and maintained 3, a data acquisition system 4, a control system 5, a standard solution source system and several water sample pipelines, wherein , each water sample pipeline is connected with the standard instrument 2 and the chemical instrument to be calibrated and maintained 3, the standard solution source system is connected to the standard instrument 2 and the chemical instrument to be calibrated and maintained, and the output end of the standard instrument 2 is connected to the chemical instrument to be calibrated.
- the output end of the maintenance chemical meter 3 is connected with the input end of the data acquisition system 4, the output end of the data acquisition system 4 is connected with the input end of the control system 5, and the output end of the control system 5 is connected with the input end of the maintenance chemical meter 3 to be calibrated. connected to the control terminal.
- the present invention also includes a multi-channel switching sampling system 1, wherein each water sample pipeline is respectively connected with the inlet of the multi-channel switching sampling system 1, and the outlet of the multi-channel switching sampling system 1 is communicated with the inlet of the standard instrument 2,
- the control end of the multi-channel switching sample introduction system 1 is connected with the output end of the control system 5.
- the outlet of the multi-channel switching sample introduction system 1 is connected with the inlet of the standard instrument 2 through a communication pipeline.
- the standard solution source system includes a standard solution source 7 and a standard solution adding pump 6 , wherein the standard solution source 7 is communicated with the inlet of the standard instrument 2 through the standard solution adding pump 6 .
- the standard meter 2 is a standard online conductivity meter, a standard online hydrogen conductivity meter, a standard online degassed hydrogen conductivity meter, a standard online pH meter, a standard online dissolved oxygen meter, a standard online sodium meter, a standard online silicon meter, and a standard online Phosphate radical meter, standard online chlorine meter or standard online sulfate radical meter;
- the chemical instrument 3 to be calibrated and maintained is an online conductivity meter, an online hydrogen conductivity meter, an online degassed hydrogen conductivity meter, an online pH meter, an online dissolved oxygen meter meter, online sodium meter, online silicon meter, online phosphate meter, online chlorine meter or online sulfate meter.
- the maintenance chemical meter 3 to be calibrated is of the same type as the standard meter 2 .
- the intelligent calibration and maintenance method of the online chemical instrument according to the present invention comprises the following steps:
- the water samples in the same water sample pipeline are respectively sent to the standard meter 2 and the chemical meter 3 to be calibrated and maintained for testing.
- the data detected by the standard meter 2 and the data detected by the chemical meter 3 to be calibrated and maintained are sent to the data acquisition system 4
- the control system 5 when the difference between the data detected by the standard instrument 2 and the data detected by the chemical instrument 3 to be calibrated and maintained is greater than or equal to the preset value, the chemical instrument 3 to be calibrated and maintained is diagnosed and eliminated;
- the standard solution source system is controlled to output the standard solution, and sent to the standard meter 2 and the maintenance chemical meter 3 to be calibrated. 2.
- the detected data and the data detected by the chemical meter 3 to be calibrated and maintained are sent to the control system 5 through the data acquisition system 4, and the control system 5 automatically calibrates the chemical meter 3 to be calibrated and maintained according to the data detected by the standard meter 2.
- the invention makes the online chemical instrument realize without manual intervention, can realize automatic online inspection, error calculation and analysis, error diagnosis and intelligent calibration and maintenance of elimination and automatic calibration, achieves intelligent operation of chemical instrument, and can be widely used in electric power, chemical industry, In the fields of water quality monitoring and supervision in various industries such as medicine, the measurement accuracy of online chemical instruments and the work efficiency of staff are greatly improved.
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Abstract
一种在线化学仪表智慧校验维护系统及方法，系统包括标准仪表（2）、待校验维护化学仪表（3）、数据采集系统（4）、控制系统（5）、标准溶液源（7）系统及若干水样管道，其中，各水样管道均与标准仪表（2）及待校验维护化学仪表（3）相连通，标准溶液源（7）系统与标准仪表（2）及待校验维护化学仪表（3）相连通，标准仪表（2）的输出端及待校验维护化学仪表（3）的输出端与数据采集系统（4）的输入端相连接，数据采集系统（4）的输出端与控制系统（5）的输入端相连接，控制系统（5）的输出端与待校验维护化学仪表（3）的控制端相连接，该系统及方法自动完成在线化学仪表的校验维护。
Description
本发明属于发电厂在线化学仪表日常维护领域，涉及一种在线化学仪表智慧校验维护系统及方法。
水汽是发电厂各类热力设备运行的重要工质，必须依靠在线化学仪表对其进行连续准确的监测，将其控制在标准要求的范围内，以达到防止热力设备腐蚀、结垢和积盐的目的，否则将发生锅炉爆管、汽轮机积盐及腐蚀等安全事故，因此对在线化学仪表进行日常校验维护是运行人员一项重要的工作。目前在线化学仪表日常校验主要依赖人工，费时费力、校验程序繁琐、自动化程度低，而且准确性难以保证，存在的主要问题如下：
1)把在线化学仪表测量传感器从测量回路中取出，采用标准溶液离线检验在线化学仪表测量准确性，不仅费时费力，还因为脱离了纯水因素及在线因素的影响，因此用标准溶液人工离线校验准确的在线化学仪表并不能保证在线测量时准确。另外校验时在线化学仪表需停用，在检验期间不能对水质进行监测，存在水质监督盲区，一旦水质超标将会严重影响设备运行安全。
2)在线化学仪表的测量误差需要人工计算得出，当计算出误差超标时还需要人工判断误差来源，进行消缺处理后才能配制标准溶液，采用人工方式对在线化学仪表进行校准，自动化程度较低，严重影响了仪表 维护人员的工作效率。
目前国内外尚无能够实现无需人工干预，能够实现自动检验、误差计算分析、误差来源查定及自动校准的在线化学仪表智慧校验维护系统及方法，该问题亟待解决。
发明内容
本发明的目的在于克服上述现有技术的缺点，提供了一种在线化学仪表智慧校验维护系统及方法，该系统及方法自动完成在线化学仪表的校验维护。
为达到上述目的，本发明所述的在线化学仪表智慧校验维护系统包括标准仪表、待校验维护化学仪表、数据采集系统、控制系统、标准溶液源系统及若干水样管道，其中，各水样管道均与标准仪表及待校验维护化学仪表相连通，标准溶液源系统与标准仪表及待校验维护化学仪表相连通，标准仪表的输出端及待校验维护化学仪表的输出端与数据采集系统的输入端相连接，数据采集系统的输出端与控制系统的输入端相连接，控制系统的输出端与待校验维护化学仪表的控制端相连接。
还包括多通道切换进样系统，其中，各水样管道分别与多通道切换进样系统的入口相连通，多通道切换进样系统的出口与标准仪表的入口相连通，所述多通道切换进样系统的控制端与控制系统的输出端相连接。
多通道切换进样系统的出口与标准仪表的入口通过连通管道相连通。
标准溶液源系统包括标准溶液源及标准溶液加入泵，其中，标准溶液源经标准溶液加入泵与标准仪表的入口相连通。
所述标准仪表为标准在线电导率表、标准在线氢电导率表、标准在线脱气氢电导表、标准在线pH表、标准在线溶解氧表、标准在线钠表、标准在线硅表、标准在线磷酸根表、标准在线氯表或标准在线硫酸根表。
所述待校验维护化学仪表为在线电导率表、在线氢电导率表、在线脱气氢电导表、在线pH表、在线溶解氧表、在线钠表、在线硅表、在线磷酸根表、在线氯表或在线硫酸根表。
待校验维护化学仪表与标准仪表的类型相同。
一种在线化学仪表智慧校验维护方法包括以下步骤：
同一水样管道中的水样分别送入标准仪表及待校验维护化学仪表中进行检测，标准仪表检测的数据及待校验维护化学仪表检测的数据经数据采集系统送入控制系统中，当标准仪表检测的数据与待校验维护化学仪表检测的数据之差大于等于预设值时，则对待校验维护化学仪表进行诊断及消缺；当标准仪表检测的数据与待校验维护化学仪表检测的数据之差小于预设值时，则控制标准溶液源系统输出标准溶液，并送入标准仪表及待校验维护化学仪表中，标准仪表检测的数据及待校验维护化学仪表检测的数据经数据采集系统送入控制系统中，控制系统根据标准仪表检测得到的数据对待校验维护化学仪表进行自动校准。
本发明具有以下有益效果：
本发明所述的在线化学仪表智慧校验维护系统及方法在具体操作时，先将同一水样分别送入标准仪表及待校验维护化学仪表中，当标准仪表检测的数据与待校验维护化学仪表检测的数据之差大于等于预设值时，则对待校验维护化学仪表进行诊断及消缺，在检验时，将相同的标 准溶液分别送入标准仪表及待校验维护化学仪表中，根据标准仪表检测得到的数据对待校验维护化学仪表进行自动校准，以解决在线化学仪表校验及维护存在的现有问题，避免人为篡改仪表测量误差的可能性，实现在线化学仪表的运维，提高在线化学仪表的测量准确，保证水质监督准确有效，提高发电机组运行安全性，可广泛应用于化工行业、制药行业、食品行业及市政行业中。
图1为本发明的结构示意图。
其中，1为多通道切换进样系统、2为标准仪表、3为待校验维护在线化学仪表、4为数据采集系统、5为控制系统、6为标准溶液加入泵、7为标准溶液源。
下面结合附图对本发明做进一步详细描述：
参考图1，本发明所述的在线化学仪表智慧校验维护系统包括标准仪表2、待校验维护化学仪表3、数据采集系统4、控制系统5、标准溶液源系统及若干水样管道，其中，各水样管道均与标准仪表2及待校验维护化学仪表3相连通，标准溶液源系统与标准仪表2及待校验维护化学仪表3相连通，标准仪表2的输出端及待校验维护化学仪表3的输出端与数据采集系统4的输入端相连接，数据采集系统4的输出端与控制系统5的输入端相连接，控制系统5的输出端与待校验维护化学仪表3的控制端相连接。
本发明还包括多通道切换进样系统1，其中，各水样管道分别与多 通道切换进样系统1的入口相连通，多通道切换进样系统1的出口与标准仪表2的入口相连通，所述多通道切换进样系统1的控制端与控制系统5的输出端相连接，具体的，多通道切换进样系统1的出口与标准仪表2的入口通过连通管道相连通。
标准溶液源系统包括标准溶液源7及标准溶液加入泵6，其中，标准溶液源7经标准溶液加入泵6与标准仪表2的入口相连通。
所述标准仪表2为标准在线电导率表、标准在线氢电导率表、标准在线脱气氢电导表、标准在线pH表、标准在线溶解氧表、标准在线钠表、标准在线硅表、标准在线磷酸根表、标准在线氯表或标准在线硫酸根表；所述待校验维护化学仪表3为在线电导率表、在线氢电导率表、在线脱气氢电导表、在线pH表、在线溶解氧表、在线钠表、在线硅表、在线磷酸根表、在线氯表或在线硫酸根表。
待校验维护化学仪表3与标准仪表2的类型相同。
本发明所述的在线化学仪表智慧校验维护方法包括以下步骤：
同一水样管道中的水样分别送入标准仪表2及待校验维护化学仪表3中进行检测，标准仪表2检测的数据及待校验维护化学仪表3检测的数据经数据采集系统4送入控制系统5中，当标准仪表2检测的数据与待校验维护化学仪表3检测的数据之差大于等于预设值时，则对待校验维护化学仪表3进行诊断及消缺；当标准仪表2检测的数据与待校验维护化学仪表3检测的数据之差小于预设值时，则控制标准溶液源系统输出标准溶液，并送入标准仪表2及待校验维护化学仪表3中，标准仪表2检测的数据及待校验维护化学仪表3检测的数据经数据采集系统4送 入控制系统5中，控制系统5根据标准仪表2检测得到的数据对待校验维护化学仪表3进行自动校准。
本发明使在线化学仪表实现无需人工干预，能够实现自动在线检验、误差计算分析、误差诊断及消缺、自动校准的智慧校验维护，达到化学仪表智慧化运行，可广泛应用于电力、化工、医药等各行业水质监测及监督领域，大大提高在线化学仪表测量准确性和工作人员工作效率。
Claims (8)
- 一种在线化学仪表智慧校验维护系统，其特征在于，包括标准仪表(2)、待校验维护化学仪表(3)、数据采集系统(4)、控制系统(5)、标准溶液源系统及若干水样管道，其中，各水样管道均与标准仪表(2)及待校验维护化学仪表(3)相连通，标准溶液源系统与标准仪表(2)及待校验维护化学仪表(3)相连通，标准仪表(2)的输出端及待校验维护化学仪表(3)的输出端与数据采集系统(4)的输入端相连接，数据采集系统(4)的输出端与控制系统(5)的输入端相连接，控制系统(5)的输出端与待校验维护化学仪表(3)的控制端相连接。
- 根据权利要求1所述的在线化学仪表智慧校验维护系统，其特征在于，还包括多通道切换进样系统(1)，其中，各水样管道分别与多通道切换进样系统(1)的入口相连通，多通道切换进样系统(1)的出口与标准仪表(2)的入口相连通，所述多通道切换进样系统(1)的控制端与控制系统(5)的输出端相连接。
- 根据权利要求2所述的在线化学仪表智慧校验维护系统，其特征在于，多通道切换进样系统(1)的出口与标准仪表(2)的入口通过连通管道相连通。
- 根据权利要求1所述的在线化学仪表智慧校验维护系统，其特征在于，标准溶液源系统包括标准溶液源(7)及标准溶液加入泵(6)，其中，标准溶液源(7)经标准溶液加入泵(6)与标准仪表(2)的入口相连通。
- 根据权利要求1所述的在线化学仪表智慧校验维护系统，其特征在于，所述标准仪表(2)为标准在线电导率表、标准在线氢电导率表、标准在线脱气氢电导表、标准在线pH表、标准在线溶解氧表、标准在线 钠表、标准在线硅表、标准在线磷酸根表、标准在线氯表或标准在线硫酸根表。
- 根据权利要求1所述的在线化学仪表智慧校验维护系统，其特征在于，所述待校验维护化学仪表(3)为在线电导率表、在线氢电导率表、在线脱气氢电导表、在线pH表、在线溶解氧表、在线钠表、在线硅表、在线磷酸根表、在线氯表或在线硫酸根表。
- 根据权利要求1所述的在线化学仪表智慧校验维护系统，其特征在于，待校验维护化学仪表(3)与标准仪表(2)的类型相同。
- 一种在线化学仪表智慧校验维护方法，其特征在于，基于权利要求1所述的在线化学仪表智慧校验维护系统，包括以下步骤：同一水样管道中的水样分别送入标准仪表(2)及待校验维护化学仪表(3)中进行检测，标准仪表(2)检测的数据及待校验维护化学仪表(3)检测的数据经数据采集系统(4)送入控制系统(5)中，当标准仪表(2)检测的数据与待校验维护化学仪表(3)检测的数据之差大于等于预设值时，则对待校验维护化学仪表(3)进行诊断及消缺；当标准仪表(2)检测的数据与待校验维护化学仪表(3)检测的数据之差小于预设值时，则控制标准溶液源系统输出标准溶液，并送入标准仪表(2)及待校验维护化学仪表(3)中，标准仪表(2)检测的数据及待校验维护化学仪表(3)检测的数据经数据采集系统(4)送入控制系统(5)中，控制系统(5)根据标准仪表(2)检测得到的数据对待校验维护化学仪表(3)进行自动校准。
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