WO2022190133A1 - A tank mix compatible composition - Google Patents
A tank mix compatible composition Download PDFInfo
- Publication number
- WO2022190133A1 WO2022190133A1 PCT/IN2022/050226 IN2022050226W WO2022190133A1 WO 2022190133 A1 WO2022190133 A1 WO 2022190133A1 IN 2022050226 W IN2022050226 W IN 2022050226W WO 2022190133 A1 WO2022190133 A1 WO 2022190133A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition
- tank mix
- polyoxyethylene
- compatible composition
- surfactants
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 274
- 239000000417 fungicide Substances 0.000 claims abstract description 59
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 54
- 239000012990 dithiocarbamate Substances 0.000 claims abstract description 47
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 claims abstract description 46
- 238000000034 method Methods 0.000 claims abstract description 26
- 150000003839 salts Chemical class 0.000 claims abstract description 25
- 208000031888 Mycoses Diseases 0.000 claims abstract description 15
- 230000008569 process Effects 0.000 claims abstract description 12
- -1 Polyoxyethylene monooleate Polymers 0.000 claims description 55
- 239000003945 anionic surfactant Substances 0.000 claims description 36
- 239000002736 nonionic surfactant Substances 0.000 claims description 33
- 239000004533 oil dispersion Substances 0.000 claims description 30
- 125000000217 alkyl group Chemical group 0.000 claims description 24
- 239000003921 oil Substances 0.000 claims description 23
- 229910019142 PO4 Inorganic materials 0.000 claims description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 18
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 18
- 239000005802 Mancozeb Substances 0.000 claims description 17
- 239000003905 agrochemical Substances 0.000 claims description 16
- 239000004094 surface-active agent Substances 0.000 claims description 16
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 14
- 239000004615 ingredient Substances 0.000 claims description 14
- 229920001577 copolymer Polymers 0.000 claims description 12
- 239000010452 phosphate Substances 0.000 claims description 12
- 239000004435 Oxo alcohol Substances 0.000 claims description 11
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 7
- 239000002671 adjuvant Substances 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 5
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 4
- 229920001213 Polysorbate 20 Polymers 0.000 claims description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 4
- 239000004009 herbicide Substances 0.000 claims description 4
- 239000002917 insecticide Substances 0.000 claims description 4
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 claims description 4
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 claims description 4
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 claims description 3
- 239000004147 Sorbitan trioleate Substances 0.000 claims description 3
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 claims description 3
- 239000011717 all-trans-retinol Substances 0.000 claims description 3
- 235000019169 all-trans-retinol Nutrition 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 3
- YKSNLCVSTHTHJA-UHFFFAOYSA-L maneb Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S YKSNLCVSTHTHJA-UHFFFAOYSA-L 0.000 claims description 3
- 229920000940 maneb Polymers 0.000 claims description 3
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 3
- 235000019337 sorbitan trioleate Nutrition 0.000 claims description 3
- 229960000391 sorbitan trioleate Drugs 0.000 claims description 3
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 2
- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 claims description 2
- OTWBGXPTCSGQEJ-UHFFFAOYSA-N 2-[(dimethylcarbamothioyldisulfanyl)carbothioylamino]ethylcarbamothioylsulfanyl n,n-dimethylcarbamodithioate Chemical compound CN(C)C(=S)SSC(=S)NCCNC(=S)SSC(=S)N(C)C OTWBGXPTCSGQEJ-UHFFFAOYSA-N 0.000 claims description 2
- CTXGTHVAWRBISV-UHFFFAOYSA-N 2-hydroxyethyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCO CTXGTHVAWRBISV-UHFFFAOYSA-N 0.000 claims description 2
- LBOUWIXJRPSXCJ-UHFFFAOYSA-N C(CCCCCCCCCC(C)C)C(CO)O Chemical compound C(CCCCCCCCCC(C)C)C(CO)O LBOUWIXJRPSXCJ-UHFFFAOYSA-N 0.000 claims description 2
- MPKTWNYCNKUVKZ-UHFFFAOYSA-N Carbamorph Chemical compound CN(C)C(=S)SCN1CCOCC1 MPKTWNYCNKUVKZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005644 Dazomet Substances 0.000 claims description 2
- 239000002169 Metam Substances 0.000 claims description 2
- 239000005809 Metiram Substances 0.000 claims description 2
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 2
- 239000005823 Propineb Substances 0.000 claims description 2
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 claims description 2
- RMMPZDDLWLALLJ-UHFFFAOYSA-N Thermophillin Chemical compound COC1=CC(=O)C(OC)=CC1=O RMMPZDDLWLALLJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005843 Thiram Substances 0.000 claims description 2
- 239000005870 Ziram Substances 0.000 claims description 2
- VQSUKBFBVMSNES-UHFFFAOYSA-K [Cl-].[Cl-].[Cu+].[Cu+].[Cu+].CN(C)C([S-])=S Chemical compound [Cl-].[Cl-].[Cu+].[Cu+].[Cu+].CN(C)C([S-])=S VQSUKBFBVMSNES-UHFFFAOYSA-K 0.000 claims description 2
- 229920001400 block copolymer Polymers 0.000 claims description 2
- JOXAXMBQVHFGQT-UHFFFAOYSA-J copper;manganese(2+);n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[Cu+2].[S-]C(=S)NCCNC([S-])=S.[S-]C(=S)NCCNC([S-])=S JOXAXMBQVHFGQT-UHFFFAOYSA-J 0.000 claims description 2
- QAYICIQNSGETAS-UHFFFAOYSA-N dazomet Chemical compound CN1CSC(=S)N(C)C1 QAYICIQNSGETAS-UHFFFAOYSA-N 0.000 claims description 2
- 229920000359 diblock copolymer Polymers 0.000 claims description 2
- ZHIKKPYAYGUYPV-UHFFFAOYSA-N dimethylaminocarbamothioylsulfanyl n-(dimethylamino)carbamodithioate Chemical compound CN(C)NC(=S)SSC(=S)NN(C)C ZHIKKPYAYGUYPV-UHFFFAOYSA-N 0.000 claims description 2
- 229960002563 disulfiram Drugs 0.000 claims description 2
- WHDGWKAJBYRJJL-UHFFFAOYSA-K ferbam Chemical compound [Fe+3].CN(C)C([S-])=S.CN(C)C([S-])=S.CN(C)C([S-])=S WHDGWKAJBYRJJL-UHFFFAOYSA-K 0.000 claims description 2
- 230000002363 herbicidal effect Effects 0.000 claims description 2
- HYVVJDQGXFXBRZ-UHFFFAOYSA-N metam Chemical compound CNC(S)=S HYVVJDQGXFXBRZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920000257 metiram Polymers 0.000 claims description 2
- UQJQVUOTMVCFHX-UHFFFAOYSA-L nabam Chemical compound [Na+].[Na+].[S-]C(=S)NCCNC([S-])=S UQJQVUOTMVCFHX-UHFFFAOYSA-L 0.000 claims description 2
- WTJKGGKOPKCXLL-RRHRGVEJSA-N phosphatidylcholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCCC=CCCCCCCCC WTJKGGKOPKCXLL-RRHRGVEJSA-N 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 2
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 claims description 2
- 235000010483 polyoxyethylene sorbitan monopalmitate Nutrition 0.000 claims description 2
- 239000000249 polyoxyethylene sorbitan monopalmitate Substances 0.000 claims description 2
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 claims description 2
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 claims description 2
- 235000010988 polyoxyethylene sorbitan tristearate Nutrition 0.000 claims description 2
- 239000001816 polyoxyethylene sorbitan tristearate Substances 0.000 claims description 2
- 229920000053 polysorbate 80 Polymers 0.000 claims description 2
- KKMLIVYBGSAJPM-UHFFFAOYSA-L propineb Chemical compound [Zn+2].[S-]C(=S)NC(C)CNC([S-])=S KKMLIVYBGSAJPM-UHFFFAOYSA-L 0.000 claims description 2
- AUZONCFQVSMFAP-UHFFFAOYSA-N tetraethylthiuram disulfide Natural products CCN(CC)C(=S)SSC(=S)N(CC)CC AUZONCFQVSMFAP-UHFFFAOYSA-N 0.000 claims description 2
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 claims description 2
- 229960002447 thiram Drugs 0.000 claims description 2
- 229940117013 triethanolamine oleate Drugs 0.000 claims description 2
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 claims description 2
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 claims 1
- 229940092714 benzenesulfonic acid Drugs 0.000 claims 1
- 150000002170 ethers Chemical class 0.000 claims 1
- 229910021653 sulphate ion Inorganic materials 0.000 claims 1
- 238000009472 formulation Methods 0.000 description 26
- 241000196324 Embryophyta Species 0.000 description 25
- 235000019198 oils Nutrition 0.000 description 21
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 18
- 235000021317 phosphate Nutrition 0.000 description 17
- 239000004480 active ingredient Substances 0.000 description 15
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 13
- 239000006185 dispersion Substances 0.000 description 12
- 238000011068 loading method Methods 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 230000001276 controlling effect Effects 0.000 description 10
- 239000000194 fatty acid Substances 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- 239000002562 thickening agent Substances 0.000 description 9
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
- 239000003085 diluting agent Substances 0.000 description 8
- 229930195729 fatty acid Natural products 0.000 description 8
- 239000002270 dispersing agent Substances 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 150000003863 ammonium salts Chemical class 0.000 description 6
- 201000010099 disease Diseases 0.000 description 6
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 6
- 235000013399 edible fruits Nutrition 0.000 description 6
- 150000004665 fatty acids Chemical class 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000013049 sediment Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- 241000233866 Fungi Species 0.000 description 5
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 5
- 238000010790 dilution Methods 0.000 description 5
- 239000012895 dilution Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 4
- QRNATDQRFAUDKF-UHFFFAOYSA-N 2-carbamothioylsulfanylethyl carbamodithioate Chemical compound NC(=S)SCCSC(N)=S QRNATDQRFAUDKF-UHFFFAOYSA-N 0.000 description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 4
- 239000005642 Oleic acid Substances 0.000 description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 238000007792 addition Methods 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 4
- 239000002480 mineral oil Substances 0.000 description 4
- 235000010446 mineral oil Nutrition 0.000 description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 4
- 229920013635 phenyl ether polymer Polymers 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000006254 rheological additive Substances 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- 239000012868 active agrochemical ingredient Substances 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 230000000740 bleeding effect Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 230000009969 flowable effect Effects 0.000 description 3
- 239000012669 liquid formulation Substances 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 3
- 238000005191 phase separation Methods 0.000 description 3
- 229920001515 polyalkylene glycol Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000004062 sedimentation Methods 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 150000003460 sulfonic acids Chemical class 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- 241000208838 Asteraceae Species 0.000 description 2
- 235000011299 Brassica oleracea var botrytis Nutrition 0.000 description 2
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 2
- 240000003259 Brassica oleracea var. botrytis Species 0.000 description 2
- 244000178937 Brassica oleracea var. capitata Species 0.000 description 2
- 241000219193 Brassicaceae Species 0.000 description 2
- 241000871189 Chenopodiaceae Species 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 241000208292 Solanaceae Species 0.000 description 2
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 2
- 244000062793 Sorghum vulgare Species 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 125000000319 biphenyl-4-yl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C1=C([H])C([H])=C([*])C([H])=C1[H] 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 244000038559 crop plants Species 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 150000004659 dithiocarbamates Chemical class 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000005189 flocculation Methods 0.000 description 2
- 230000016615 flocculation Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 230000002538 fungal effect Effects 0.000 description 2
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 230000002147 killing effect Effects 0.000 description 2
- 235000010445 lecithin Nutrition 0.000 description 2
- 239000000787 lecithin Substances 0.000 description 2
- 229940067606 lecithin Drugs 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 125000005375 organosiloxane group Chemical group 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- BOTNYLSAWDQNEX-UHFFFAOYSA-N phenoxymethylbenzene Chemical compound C=1C=CC=CC=1COC1=CC=CC=C1 BOTNYLSAWDQNEX-UHFFFAOYSA-N 0.000 description 2
- 229920001521 polyalkylene glycol ether Polymers 0.000 description 2
- 229920000867 polyelectrolyte Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 235000011076 sorbitan monostearate Nutrition 0.000 description 2
- 239000001587 sorbitan monostearate Substances 0.000 description 2
- 229940035048 sorbitan monostearate Drugs 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 125000005504 styryl group Chemical group 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- ZMYFCFLJBGAQRS-IRXDYDNUSA-N (2R,3S)-epoxiconazole Chemical compound C1=CC(F)=CC=C1[C@@]1(CN2N=CN=C2)[C@H](C=2C(=CC=CC=2)Cl)O1 ZMYFCFLJBGAQRS-IRXDYDNUSA-N 0.000 description 1
- RYAUSSKQMZRMAI-ALOPSCKCSA-N (2S,6R)-4-[3-(4-tert-butylphenyl)-2-methylpropyl]-2,6-dimethylmorpholine Chemical compound C=1C=C(C(C)(C)C)C=CC=1CC(C)CN1C[C@H](C)O[C@H](C)C1 RYAUSSKQMZRMAI-ALOPSCKCSA-N 0.000 description 1
- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;(z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 description 1
- PPDBOQMNKNNODG-NTEUORMPSA-N (5E)-5-(4-chlorobenzylidene)-2,2-dimethyl-1-(1,2,4-triazol-1-ylmethyl)cyclopentanol Chemical compound C1=NC=NN1CC1(O)C(C)(C)CC\C1=C/C1=CC=C(Cl)C=C1 PPDBOQMNKNNODG-NTEUORMPSA-N 0.000 description 1
- QNBTYORWCCMPQP-JXAWBTAJSA-N (Z)-dimethomorph Chemical compound C1=C(OC)C(OC)=CC=C1C(\C=1C=CC(Cl)=CC=1)=C/C(=O)N1CCOCC1 QNBTYORWCCMPQP-JXAWBTAJSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 description 1
- LQDARGUHUSPFNL-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)-3-(1,1,2,2-tetrafluoroethoxy)propyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(COC(F)(F)C(F)F)CN1C=NC=N1 LQDARGUHUSPFNL-UHFFFAOYSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- XUJLWPFSUCHPQL-UHFFFAOYSA-N 11-methyldodecan-1-ol Chemical class CC(C)CCCCCCCCCCO XUJLWPFSUCHPQL-UHFFFAOYSA-N 0.000 description 1
- WHRZCXAVMTUTDD-UHFFFAOYSA-N 1h-furo[2,3-d]pyrimidin-2-one Chemical compound N1C(=O)N=C2OC=CC2=C1 WHRZCXAVMTUTDD-UHFFFAOYSA-N 0.000 description 1
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- FXNDIJDIPNCZQJ-UHFFFAOYSA-N 2,4,4-trimethylpent-1-ene Chemical group CC(=C)CC(C)(C)C FXNDIJDIPNCZQJ-UHFFFAOYSA-N 0.000 description 1
- STMIIPIFODONDC-UHFFFAOYSA-N 2-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)hexan-2-ol Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(O)(CCCC)CN1C=NC=N1 STMIIPIFODONDC-UHFFFAOYSA-N 0.000 description 1
- ILCOCZBHMDEIAI-UHFFFAOYSA-N 2-(2-octadecoxyethoxy)ethanol Chemical compound CCCCCCCCCCCCCCCCCCOCCOCCO ILCOCZBHMDEIAI-UHFFFAOYSA-N 0.000 description 1
- UFNOUKDBUJZYDE-UHFFFAOYSA-N 2-(4-chlorophenyl)-3-cyclopropyl-1-(1H-1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1CC(O)(C=1C=CC(Cl)=CC=1)C(C)C1CC1 UFNOUKDBUJZYDE-UHFFFAOYSA-N 0.000 description 1
- MNHVNIJQQRJYDH-UHFFFAOYSA-N 2-[2-(1-chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl]-1,2-dihydro-1,2,4-triazole-3-thione Chemical compound N1=CNC(=S)N1CC(C1(Cl)CC1)(O)CC1=CC=CC=C1Cl MNHVNIJQQRJYDH-UHFFFAOYSA-N 0.000 description 1
- SSORSZACHCNXSJ-UHFFFAOYSA-N 2-[2-(3,4-dichlorophenyl)-3-[2-(2-hydroxypropylamino)pyrimidin-4-yl]imidazol-4-yl]acetonitrile Chemical group ClC=1C=C(C=CC=1Cl)C=1N(C(=CN=1)CC#N)C1=NC(=NC=C1)NCC(C)O SSORSZACHCNXSJ-UHFFFAOYSA-N 0.000 description 1
- MGYUQZIGNZFZJS-KTKRTIGZSA-N 2-[2-[(z)-octadec-9-enoxy]ethoxy]ethanol Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCOCCO MGYUQZIGNZFZJS-KTKRTIGZSA-N 0.000 description 1
- NLMKTBGFQGKQEV-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-hexadecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO NLMKTBGFQGKQEV-UHFFFAOYSA-N 0.000 description 1
- DWKNOLCXIFYNFV-HSZRJFAPSA-N 2-[[(2r)-1-[1-[(4-chloro-3-methylphenyl)methyl]piperidin-4-yl]-5-oxopyrrolidine-2-carbonyl]amino]-n,n,6-trimethylpyridine-4-carboxamide Chemical compound CN(C)C(=O)C1=CC(C)=NC(NC(=O)[C@@H]2N(C(=O)CC2)C2CCN(CC=3C=C(C)C(Cl)=CC=3)CC2)=C1 DWKNOLCXIFYNFV-HSZRJFAPSA-N 0.000 description 1
- GXJQMKFJQFGQKV-KHPPLWFESA-N 2-[methyl-[(z)-octadec-9-enoyl]amino]ethanesulfonic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CCS(O)(=O)=O GXJQMKFJQFGQKV-KHPPLWFESA-N 0.000 description 1
- DHVLDKHFGIVEIP-UHFFFAOYSA-N 2-bromo-2-(bromomethyl)pentanedinitrile Chemical compound BrCC(Br)(C#N)CCC#N DHVLDKHFGIVEIP-UHFFFAOYSA-N 0.000 description 1
- BJRXGOFKVBOFCO-UHFFFAOYSA-N 2-hydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(C)O BJRXGOFKVBOFCO-UHFFFAOYSA-N 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- RMTFNDVZYPHUEF-XZBKPIIZSA-N 3-O-methyl-D-glucose Chemical compound O=C[C@H](O)[C@@H](OC)[C@H](O)[C@H](O)CO RMTFNDVZYPHUEF-XZBKPIIZSA-N 0.000 description 1
- BZOVBIIWPDQIHF-UHFFFAOYSA-N 3-hydroxy-2-methylbenzenesulfonic acid Chemical compound CC1=C(O)C=CC=C1S(O)(=O)=O BZOVBIIWPDQIHF-UHFFFAOYSA-N 0.000 description 1
- VKELSQNRSVJHGR-UHFFFAOYSA-N 4-oxo-4-sulfooxybutanoic acid Chemical compound OC(=O)CCC(=O)OS(O)(=O)=O VKELSQNRSVJHGR-UHFFFAOYSA-N 0.000 description 1
- ONPGOSVDVDPBCY-CQSZACIVSA-N 6-amino-5-[(1r)-1-(2,6-dichloro-3-fluorophenyl)ethoxy]-n-[4-(4-methylpiperazine-1-carbonyl)phenyl]pyridazine-3-carboxamide Chemical compound O([C@H](C)C=1C(=C(F)C=CC=1Cl)Cl)C(C(=NN=1)N)=CC=1C(=O)NC(C=C1)=CC=C1C(=O)N1CCN(C)CC1 ONPGOSVDVDPBCY-CQSZACIVSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 229910002016 Aerosil® 200 Inorganic materials 0.000 description 1
- 241000123646 Allioideae Species 0.000 description 1
- 235000005254 Allium ampeloprasum Nutrition 0.000 description 1
- 240000006108 Allium ampeloprasum Species 0.000 description 1
- 244000291564 Allium cepa Species 0.000 description 1
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 244000144725 Amygdalus communis Species 0.000 description 1
- 241000208223 Anacardiaceae Species 0.000 description 1
- 241000208173 Apiaceae Species 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000011330 Armoracia rusticana Nutrition 0.000 description 1
- 240000003291 Armoracia rusticana Species 0.000 description 1
- 235000007319 Avena orientalis Nutrition 0.000 description 1
- 244000075850 Avena orientalis Species 0.000 description 1
- 239000005730 Azoxystrobin Substances 0.000 description 1
- 235000021537 Beetroot Nutrition 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 description 1
- 241000219495 Betulaceae Species 0.000 description 1
- 239000005738 Bixafen Substances 0.000 description 1
- 239000005740 Boscalid Substances 0.000 description 1
- 241000167854 Bourreria succulenta Species 0.000 description 1
- 241000219198 Brassica Species 0.000 description 1
- 235000003351 Brassica cretica Nutrition 0.000 description 1
- 240000002791 Brassica napus Species 0.000 description 1
- 235000004221 Brassica oleracea var gemmifera Nutrition 0.000 description 1
- 235000017647 Brassica oleracea var italica Nutrition 0.000 description 1
- 244000308368 Brassica oleracea var. gemmifera Species 0.000 description 1
- 244000304217 Brassica oleracea var. gongylodes Species 0.000 description 1
- 235000003343 Brassica rupestris Nutrition 0.000 description 1
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 235000021538 Chard Nutrition 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 240000000560 Citrus x paradisi Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 235000009849 Cucumis sativus Nutrition 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 241000219104 Cucurbitaceae Species 0.000 description 1
- 239000005757 Cyproconazole Substances 0.000 description 1
- 239000005758 Cyprodinil Substances 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- 239000005760 Difenoconazole Substances 0.000 description 1
- 239000005761 Dimethomorph Substances 0.000 description 1
- LVGKNOAMLMIIKO-UHFFFAOYSA-N Elaidinsaeure-aethylester Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC LVGKNOAMLMIIKO-UHFFFAOYSA-N 0.000 description 1
- 239000005767 Epoxiconazole Substances 0.000 description 1
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 1
- 241000219428 Fagaceae Species 0.000 description 1
- 239000005778 Fenpropimorph Substances 0.000 description 1
- 239000005784 Fluoxastrobin Substances 0.000 description 1
- 240000009088 Fragaria x ananassa Species 0.000 description 1
- JZNWSCPGTDBMEW-UHFFFAOYSA-N Glycerophosphorylethanolamin Natural products NCCOP(O)(=O)OCC(O)CO JZNWSCPGTDBMEW-UHFFFAOYSA-N 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 241000208818 Helianthus Species 0.000 description 1
- 235000003222 Helianthus annuus Nutrition 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- 241000758791 Juglandaceae Species 0.000 description 1
- 239000005800 Kresoxim-methyl Substances 0.000 description 1
- 235000003228 Lactuca sativa Nutrition 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 235000006173 Larrea tridentata Nutrition 0.000 description 1
- 244000073231 Larrea tridentata Species 0.000 description 1
- 241000218195 Lauraceae Species 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 235000007849 Lepidium sativum Nutrition 0.000 description 1
- 244000211187 Lepidium sativum Species 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 241000234280 Liliaceae Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 244000070406 Malus silvestris Species 0.000 description 1
- 239000005805 Mepanipyrim Substances 0.000 description 1
- 239000005807 Metalaxyl Substances 0.000 description 1
- 239000005808 Metalaxyl-M Substances 0.000 description 1
- 241000218231 Moraceae Species 0.000 description 1
- 240000005561 Musa balbisiana Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 241000207836 Olea <angiosperm> Species 0.000 description 1
- 241000207834 Oleaceae Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 235000008753 Papaver somniferum Nutrition 0.000 description 1
- 241000218180 Papaveraceae Species 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010582 Pisum sativum Nutrition 0.000 description 1
- 240000004713 Pisum sativum Species 0.000 description 1
- 241000209504 Poaceae Species 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000005822 Propiconazole Substances 0.000 description 1
- 239000005825 Prothioconazole Substances 0.000 description 1
- 235000009827 Prunus armeniaca Nutrition 0.000 description 1
- 244000018633 Prunus armeniaca Species 0.000 description 1
- 240000005809 Prunus persica Species 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- 239000005869 Pyraclostrobin Substances 0.000 description 1
- 239000005828 Pyrimethanil Substances 0.000 description 1
- 241000220324 Pyrus Species 0.000 description 1
- 244000088415 Raphanus sativus Species 0.000 description 1
- 235000006140 Raphanus sativus var sativus Nutrition 0.000 description 1
- 235000004789 Rosa xanthina Nutrition 0.000 description 1
- 241000220222 Rosaceae Species 0.000 description 1
- 241001107098 Rubiaceae Species 0.000 description 1
- 241001093501 Rutaceae Species 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- 241000209056 Secale Species 0.000 description 1
- 235000007238 Secale cereale Nutrition 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000004141 Sodium laurylsulphate Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000011684 Sorghum saccharatum Nutrition 0.000 description 1
- 239000005837 Spiroxamine Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229930182692 Strobilurin Natural products 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 235000021536 Sugar beet Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000005839 Tebuconazole Substances 0.000 description 1
- 239000005840 Tetraconazole Substances 0.000 description 1
- 241001122767 Theaceae Species 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- 239000005846 Triadimenol Substances 0.000 description 1
- 239000005857 Trifloxystrobin Substances 0.000 description 1
- 239000005859 Triticonazole Substances 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- ZUQAPLKKNAQJAU-UHFFFAOYSA-N acetylenediol Chemical class OC#CO ZUQAPLKKNAQJAU-UHFFFAOYSA-N 0.000 description 1
- CGIHPACLZJDCBQ-UHFFFAOYSA-N acibenzolar Chemical compound SC(=O)C1=CC=CC2=C1SN=N2 CGIHPACLZJDCBQ-UHFFFAOYSA-N 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 235000020224 almond Nutrition 0.000 description 1
- 150000001408 amides Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000003931 anilides Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 235000021016 apples Nutrition 0.000 description 1
- 239000013011 aqueous formulation Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- AKNQMEBLVAMSNZ-UHFFFAOYSA-N azaconazole Chemical compound ClC1=CC(Cl)=CC=C1C1(CN2N=CN=C2)OCCO1 AKNQMEBLVAMSNZ-UHFFFAOYSA-N 0.000 description 1
- 229950000294 azaconazole Drugs 0.000 description 1
- WFDXOXNFNRHQEC-GHRIWEEISA-N azoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1OC1=CC(OC=2C(=CC=CC=2)C#N)=NC=N1 WFDXOXNFNRHQEC-GHRIWEEISA-N 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical class O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 235000021028 berry Nutrition 0.000 description 1
- 230000006696 biosynthetic metabolic pathway Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 description 1
- LDLMOOXUCMHBMZ-UHFFFAOYSA-N bixafen Chemical compound FC(F)C1=NN(C)C=C1C(=O)NC1=CC=C(F)C=C1C1=CC=C(Cl)C(Cl)=C1 LDLMOOXUCMHBMZ-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229940118790 boscalid Drugs 0.000 description 1
- WYEMLYFITZORAB-UHFFFAOYSA-N boscalid Chemical compound C1=CC(Cl)=CC=C1C1=CC=CC=C1NC(=O)C1=CC=CN=C1Cl WYEMLYFITZORAB-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 229940081620 ceteth-2 Drugs 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 235000019693 cherries Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229940071160 cocoate Drugs 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 229960002126 creosote Drugs 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- HAORKNGNJCEJBX-UHFFFAOYSA-N cyprodinil Chemical compound N=1C(C)=CC(C2CC2)=NC=1NC1=CC=CC=C1 HAORKNGNJCEJBX-UHFFFAOYSA-N 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 150000001470 diamides Chemical class 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- LVGKNOAMLMIIKO-QXMHVHEDSA-N ethyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC LVGKNOAMLMIIKO-QXMHVHEDSA-N 0.000 description 1
- 229940093471 ethyl oleate Drugs 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229940074046 glyceryl laurate Drugs 0.000 description 1
- 229940075529 glyceryl stearate Drugs 0.000 description 1
- 229940049294 glyceryl stearate se Drugs 0.000 description 1
- 229940100608 glycol distearate Drugs 0.000 description 1
- 229940100242 glycol stearate Drugs 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- ZOTBXTZVPHCKPN-HTXNQAPBSA-N kresoxim-methyl Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC=C1C ZOTBXTZVPHCKPN-HTXNQAPBSA-N 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- CIFWZNRJIBNXRE-UHFFFAOYSA-N mepanipyrim Chemical compound CC#CC1=CC(C)=NC(NC=2C=CC=CC=2)=N1 CIFWZNRJIBNXRE-UHFFFAOYSA-N 0.000 description 1
- ZQEIXNIJLIKNTD-GFCCVEGCSA-N metalaxyl-M Chemical compound COCC(=O)N([C@H](C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-GFCCVEGCSA-N 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- ZQEIXNIJLIKNTD-UHFFFAOYSA-N methyl N-(2,6-dimethylphenyl)-N-(methoxyacetyl)alaninate Chemical compound COCC(=O)N(C(C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-UHFFFAOYSA-N 0.000 description 1
- 229940073769 methyl oleate Drugs 0.000 description 1
- 235000019713 millet Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 235000010460 mustard Nutrition 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- XGXNTJHZPBRBHJ-UHFFFAOYSA-N n-phenylpyrimidin-2-amine Chemical compound N=1C=CC=NC=1NC1=CC=CC=C1 XGXNTJHZPBRBHJ-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 229940099570 oleth-2 Drugs 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 229940031709 peg-30-dipolyhydroxystearate Drugs 0.000 description 1
- RCMHUQGSSVZPDG-UHFFFAOYSA-N phenoxybenzene;phosphoric acid Chemical class OP(O)(O)=O.C=1C=CC=CC=1OC1=CC=CC=C1 RCMHUQGSSVZPDG-UHFFFAOYSA-N 0.000 description 1
- 150000008104 phosphatidylethanolamines Chemical class 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229920000172 poly(styrenesulfonic acid) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000059 polyethylene glycol stearate Polymers 0.000 description 1
- 229920001444 polymaleic acid Polymers 0.000 description 1
- 229960002796 polystyrene sulfonate Drugs 0.000 description 1
- 239000011970 polystyrene sulfonate Substances 0.000 description 1
- 229940005642 polystyrene sulfonic acid Drugs 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 description 1
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 description 1
- ZLIBICFPKPWGIZ-UHFFFAOYSA-N pyrimethanil Chemical compound CC1=CC(C)=NC(NC=2C=CC=CC=2)=N1 ZLIBICFPKPWGIZ-UHFFFAOYSA-N 0.000 description 1
- ARIWANIATODDMH-UHFFFAOYSA-N rac-1-monolauroylglycerol Chemical compound CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229940071089 sarcosinate Drugs 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
- IZWPGJFSBABFGL-GMFCBQQYSA-M sodium;2-[methyl-[(z)-octadec-9-enoyl]amino]ethanesulfonate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CCS([O-])(=O)=O IZWPGJFSBABFGL-GMFCBQQYSA-M 0.000 description 1
- 229960005078 sorbitan sesquioleate Drugs 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- PUYXTUJWRLOUCW-UHFFFAOYSA-N spiroxamine Chemical compound O1C(CN(CC)CCC)COC11CCC(C(C)(C)C)CC1 PUYXTUJWRLOUCW-UHFFFAOYSA-N 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229940098760 steareth-2 Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 235000021012 strawberries Nutrition 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 229960004793 sucrose Drugs 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 238000002054 transplantation Methods 0.000 description 1
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 description 1
- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 description 1
- 229960001124 trientine Drugs 0.000 description 1
- ONCZDRURRATYFI-TVJDWZFNSA-N trifloxystrobin Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)C1=CC=CC(C(F)(F)F)=C1 ONCZDRURRATYFI-TVJDWZFNSA-N 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P3/00—Fungicides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
- A01N47/14—Di-thio analogues thereof
Definitions
- the present disclosure relates to a tank mix compatible composition, and in particular, to a tank mix compatible composition comprising a dithiocarbamate fungicide.
- the present disclosure also relates to a process for preparing the tank mix compatible composition and a method of controlling a fungal disease using the tank mix compatible composition.
- Dithiocarbamate compounds such as ethylene bisdithiocarbamate (EBDC) fungicides, are generally known to have effective fungicidal activity.
- EBDC fungicides are important plant protection substances used for broad-spectrum fungal disease control because of their high tolerance by crop plants and general usefulness for controlling fungal plant diseases which are resistant to certain fungicides that are only active at a single target site in the fungus.
- Mancozeb is a broad spectrum fungicide and member of the EBDC class of fungicides, and can be formulated as both solid and liquid formulations.
- liquid mancozeb formulations address some of the shortcomings of the solid mancozeb formulations.
- the liquid products have the advantages of good miscibility, easy handling, good efficacy, and effective application onto crops.
- Mancozeb is frequently formulated as oil dispersion (OD).
- OD oil dispersion
- the agrochemical oil dispersions (OD) are stable suspensions of agrochemical active ingredients, such as pesticides and crop protection chemicals, in non-aqueous fluids, which may contain other dissolved active ingredients. Oil dispersions are particularly useful for formulating oil insoluble solid active ingredients.
- Oil dispersion formulations are a concentrate which is diluted with water before use to produce an aqueous composition which is used in crop protection. Oil dispersion formulations provide certain advantages to the farmer. Active ingredients which are usually unstable in water can be formulated as suspended form. Oil- based adjuvants may also be combined with these types of formulations in order to enhance efficacy.
- W02009/00428 describes the use of a thickener to prepare physically stable oil dispersion.
- the thickeners include organoclays such as smectite, hectorite or montmorillonite clays, which are organophilic and thus compatible with non-aqueous formulations.
- WO 2012/167321 is directed to an agricultural oil-based suspension formulation comprising an active ingredient suspended as a finely divided form in an oil and at least one unsaturated rubber-type copolymer comprising at least styrene as a residue.
- WO 2012/167322 is directed to an agricultural oil-based suspension formulation comprising an active ingredient suspended as finely divided form in an oil, and at least one surfactant selected from a polyalkylene glycol-fatty acid condensate or a polyalkylene glycolether fatty acid condensate.
- WO 2012/080208 is directed to a method of preparing an agrochemical oil dispersion comprising a thickener.
- the thickener is an amide obtained by reacting a polyhydroxystearic acid with diethylene triamine and/or triethylene tetramine.
- WO 2014/169363 is directed to agrochemical formulations that comprise at least one active ingredient suspended in an oil phase, a dispersant, a clay-based rheological additive, a cellulose-derived rheological additive, an emulsifier, and optionally at least one additional active ingredient solubilized in the oil phase.
- An object of the present disclosure is to provide tank mix compatible composition including a dithiocarbamate fungicide.
- Another object of the present disclosure is to provide tank mix compatible composition including a high concentration (loading) of a dithiocarbamate fungicide.
- Yet another object of the present disclosure is to provide a process of preparing tank mix compatible composition of high loading dithiocarbamate fungicide.
- Still another object of the present disclosure is to provide a method of controlling a fungal disease in a crop or a locus therein which comprise applying an agrochemically effective amount of the disclosed tank mix compatible composition to the crop or the locus thereof.
- Further object of the present invention is to use tank mix compatible composition of high loading dithiocarbamate fungicide in controlling pests.
- the present invention provides a tank mix compatible composition
- a tank mix compatible composition comprising: a dithiocarbamate fungicide, a salt thereof, a derivative thereof, or a combination thereof; at least two non-ionic surfactants each having an HLB value of greater than 6; and at least two anionic surfactants.
- a process of preparing tank mix compatible composition comprising: combining at least two non-ionic surfactants each having an HLB value of greater than 6 and optionally an auxiliary ingredient to obtain a mixture; adding at least two anionic surfactants to the mixture to obtain a pre-mix, and adding a dithiocarbamate fungicide to the pre-mix with continuous stirring to obtain the tank mix compatible composition.
- disclosed herein is a method of controlling a fungal disease in a crop or a locus thereof, comprising applying an agrochemically effective amount of the tank mix compatible composition disclosed herein to the crop or the locus thereof.
- tank mix compatible composition in another aspect, disclosed herein is the use of the present tank mix compatible composition to control a wide range of fungal diseases.
- the present invention provides a kit.
- the kit comprises a plurality of components, each of which components may include at least one, or more, of the ingredients of the tank mix compatible composition of the present invention.
- “About” or “approximately” as used herein is inclusive of the stated value and means within an acceptable range of deviation for the particular value as determined by one of ordinary skill in the art, considering the measurement in question and the error associated with measurement of the particular quantity (i.e., the limitations of the measurement system). For example, “about” can mean within one or more standard deviations, or within ⁇ 10% or ⁇ 5% of the stated value. Recitation of ranges of values are merely intended to serve as a shorthand method of referring individually to each separate value falling within the range, unless otherwise indicated herein, and each separate value is incorporated into the specification as if it were individually recited herein. The endpoints of all ranges are included within the range and independently combinable.
- tank mix means the addition of at least one agrochemical active ingredient to a spray medium, such as water or oil, at the point of use.
- tank mix compatible composition means a composition that can be mixed with other tank mix partners without altering the physicochemical characteristics of itself or the tank mix partner.
- agrochemical oil dispersions are stable suspensions of agrochemical active agents (e.g., pesticides, crop protection chemicals) in a non-aqueous fluid (oil), and which may contain other dissolved ingredients. Oil dispersions are particularly useful for formulating oil insoluble, solid active agents.
- a “tank mix compatible composition” refers to a concentrated oil dispersion formulation which is diluted with water to produce an aqueous based composition prior to its application to a crop.
- “effective amount” is an amount of active ingredient, such as the disclosed dithiocarbamate fungicide, which has an adverse effect on a fungus and/or which prevents a fungal disease in a plant.
- the adverse effect can include killing of the fungus (fungicidal), preventing growth of the fungus, blocking of biosynthetic pathway(s), or a combination thereof.
- an “agriculturally acceptable salt”, or a salt of a dithiocarbamate fungicide means a salt which is known and accepted for use in agricultural or horticultural applications.
- Alkyl as used herein means a straight or branched chain saturated aliphatic hydrocarbon having the specified number of carbon atoms, specifically 1 to 12 carbon atoms, more specifically 1 to 6 carbon atoms. Alkyl groups include, for example, groups having from 1 to 50 carbon atoms (Cl to C50 alkyl).
- locus refers to the vicinity, area, or place in which the plants are growing, where plant propagation materials of the plants are sown, and/or where the plant propagation materials of the plants will be placed into the soil. Unless otherwise specified, the locus includes the soil in which the plant is growing or is intended to be grown.
- plant propagation material is understood to denote generative parts of a plant, such as seeds, vegetative material such as cuttings or tubers, roots, fruits, tubers, bulbs, rhizomes, and other parts of plants, germinated plants, and/or young plants which are to be transplanted after germination or emergence from the soil. These young plants may be protected prior to transplantation by a total or partial immersion treatment/system.
- disease control of “controlling of a disease” as it relates to fungal diseases herein, refers to the treatment and prevention of a disease. Controlling effects include deviation from natural development of the disease, for example, killing of the fungal agent, retardation of disease development, and decrease in amount of the fungal disease.
- plant encompasses all of the physical parts of a plant, including for example, seeds, seedlings, saplings, roots, tubers, stems, stalks, foliage, and fruits.
- a “crop” refers to a plurality of plants.
- a formulation including a high concentration (i.e., loading) of a dithiocarbamate fungicide can be attained when the dithiocarbamate fungicide is combined with at least two non-ionic surfactants having a hydrophilic-lipophilic balance (HLB) value of greater than 6 and at least two anionic surfactants.
- HLB hydrophilic-lipophilic balance
- Such high loading dithiocarbamate fungicide compositions comprising the at least two non-ionic surfactants and the at least two anionic surfactants exhibit excellent compatibility with a greater number of tank mix partners.
- the high loading dithiocarbamate fungicide compositions also demonstrate increased storage stability and dilution stability, as well as tank mix compatibility.
- the tank mix compatible composition of the present disclosure comprises greater than 400 g/L, or more than 500 g/L, or more than 600 g/L of the dithiocarbamate fungicide, a salt thereof, a derivative thereof, or a combination thereof.
- a composition comprises: a dithiocarbamate fungicide, a salt thereof, a derivative thereof, or combination thereof; at least two non-ionic surfactants each having an HLB value of greater than 6; and at least two anionic surfactants.
- the dithiocarbamate fungicide comprises azithiram, carbamorph, cufraneb, cuprobam, disulfiram, ferbam, metam, nabam, tecoram, thiram, ziram, dazomet, mancopper, mancozeb, maneb, metiram, propineb, zineb, a salt thereof, a derivative thereof, or a combination thereof.
- the dithiocarbamate fungicide mancozeb According to an embodiment, the dithiocarbamate fungicide maneb.
- the dithiocarbamate fungicide zineb is the dithiocarbamate fungicide zineb.
- the tank mix compatible composition comprises from about 40% w/w to about 90% w/w, or from about 50% w/w to about 80% w/w, or from about 60% w/w to about 70% w/w of the dithiocarbamate fungicide based on the total weight of the tank mix compatible composition.
- a tank mix compatible composition comprises at least two non-ionic surfactants each having an HLB value of greater than 6.
- examples of the at least two non-ionic surfactants comprise an alkyl polyethylene glycol ether, oxo alcohol ethoxylate, a Cio-Guerbet alcohol ethoxylate comprising 3-9 ethylene oxide (EO) units (for example, a Cio-Guerbet alcohol ethoxylate comprising 4EO, and a Cio-Guerbet alcohol ethoxylate comprising 5EO), a Cio- Guerbet alcohol comprising 3-9 EO units (for example Cio-Guerbet alcohol comprising 3EO, and Cio-Guerbet alcohol comprising 4EO), Cio-Guerbet alcohol comprising 5EO, a Ci3-Ci5 oxo alcohol comprising 2-20 EO units (for example C13 oxo alcohol comprising 3- 10 EO units, C13 oxo alcohol comprising 3EO, C13 oxo alcohol comprising 4EO, and C13 oxo alcohol comprising 5EO), an alkyl alkoxylate
- EO
- the tank mix compatible composition comprises from about 1% w/w to about 30% w/w, or from about 2% w/w to about 25% w/w, or from about 3% to about 20% w/w of the at least two non-ionic surfactants based on the total weight of the tank mix compatible composition.
- the tank mix compatible composition comprises at least two anionic surfactants.
- the at least two anionic surfactants comprise a carboxylic acid-containing type surfactant, a sulfate-containing surfactant, a sulfonic acid- containing surfactant, a phosphate-containing surfactant, or a combination thereof.
- the tank mix compatible composition comprises at least two anionic surfactants selected from the following group of surfactants: a.
- Carboxylic acid containing surfactants including for example, carboxylic acids such as polyacrylic acid, polymethacrylic acid, polymaleic acid, a copolymer of maleic acid and an olefin (such as isobutylene and/or diisobutylene), copolymer of acrylic acid and itaconic acid, copolymer of methacrylic acid and itaconic acid, copolymer of maleic acid and styrene, copolymer of acrylic acid and methacrylic acid, copolymer of acrylic acid and methyl acrylate, copolymer of acrylic acid and vinyl acetate, copolymer of acrylic acid and maleic acid, an N-methyl-(Ci 2 -Cis fatty acid) sarcosinate, resin acid, a C 12 -C 18 fatty acid, salts thereof, or a combination thereof.
- Sulfate containing surfactants including, for example sulfates such as (C 12 -C 18 alkyl) sulfates, polyoxyethylene (Cn-Cis alkyl) ether sulfates, polyoxyethylene ( (mono- or di-) Cs-Ci 2 alkyl)phenyl ether sulfates, sulfates of polyoxyethylene ((mono- or di-) Cs-Ci 2 alkyl)phenyl ether polymers, polyoxyethylene (mono-, di- or tri-)phenyl phenyl ether sulfates, polyoxyethylene (mono-, di- or tri-)benzyl phenyl ether sulfates, polyoxyethylene (mono-, di- or tri-)styryl phenyl ether sulfates, sulfates of polyoxyethylene (mono-, di- or tri-) styryl phenyl ether polymers, sulfates
- Sulfonic acid containing surfactants including, for example sulfonic acids such as (C 12 -C 22 paraffin)sulfonic acids, (Cs-Ci 2 alkyl)benzenesulfonic acids, formalin condensates of (C 8 -C 12 alkyl)benzenesulfonic acids, formalin condensates of cresol sulfonic acid, (a- olefin(Ci 4 -Ci 6 ))sulfonic acids, di(Cs-Ci 2 alkyl) sulfo succinic acids, lignin sulfonic acid, polyoxyethylene ((mono- or di-) Cs-Ci 2 alkyl)phenyl ether sulfonic acids, polyoxyethylene (C 12 -C 18 alkyl)ether sulfosuccinic acid half esters, naphthalenesulfonic acid, ((mono- or di- ) Ci-C6alkyl
- Phosphate containing surfactants including, for example phosphates such as (C 8 Ci 2 alkyl)phosphates, polyoxyethylene (C 12 -C 18 alkyl) ether phosphates, polyoxyethylene ((mono- or di-) C 8 -C 12 alkyl) phenyl ether phosphates, phosphates of polyoxyethylene ((mono-, di- or tri-) Cs-Ci 2 alkyl)phenyl ether polymers, polyoxyethylene (mono-, di- or tri-)phenyl phenyl ether phosphates, polyoxyethylene (mono-, di- or tri- )benzyl phenyl ether phosphates, polyoxyethylene (mono-, di- or tri-)sty
- phosphates such as (C 8 Ci 2 alkyl)phosphates, polyoxyethylene (C 12 -C 18 alkyl) ether phosphates, polyoxyethylene ((mono- or di-) C
- the salts in (a) to (d) above include alkali metals (such as lithium, sodium and potassium), alkaline earth metals (such as calcium and magnesium), ammonium, and amines (such as alkylamines, cycloalkylamines and alkanolamines).
- alkali metals such as lithium, sodium and potassium
- alkaline earth metals such as calcium and magnesium
- ammonium such as sodium
- amines such as alkylamines, cycloalkylamines and alkanolamines.
- the at least two anionic surfactants comprise polyalkoxylated surfactants (such as tristryl phenol ethoxylate), for example polyethoxylated surfactants which are ionically modified, for example by conversion of the terminal free hydroxyl function of the alkylene oxide block into a sulfate or phosphate ester (such as sulfated polyaryl phenol ethoxylates ammonium salt); alkali metal and alkaline earth metal salts of alkylarylsulfonic acids having a straight-chain or branched alkyl chain; alkali metal and alkaline earth metal salts of paraffin-sulfonic acids such as chlorinated paraffin-sulfonic acids; polymeric ester of isotridecyl ethylene glycol and phosphoric acid (e.g., Hostaphat 1306, also known as phosphate ester); polyelectrolytes, such as lignosulfonates; condensates of naphthal
- the at least two anionic surfactants comprise, for example, a salt of an alkylarylsulfonic acid, a salt of a sulfosuccinic acid, a polyelectrolyte from the polycondensation of naphthalenesulfonate and formaldehyde, or a combination thereof.
- the tank mix compatible composition comprises from about 1% w/w to about 30% w/w, or from about 2% w/w to about 25% w/w, or from about 3% to about 20% of the at least two anionic surfactants based on the total weight of the tank mix compatible composition.
- the tank mix compatible composition may further include one or more agrochemically acceptable auxiliary ingredients such as adjuvants.
- the tank mix compatible composition further includes an adjuvant selected from wetting agents, oil, thickeners, fertilizers, dispersing agents, compatibility agents, stabilizers, defoamers, antimicrobial agents, antioxidants, correctives, and spray colorants (dyes).
- the tank mix compatible composition further comprises a wetting agent selected from soaps; salts of aliphatic monoesters of sulphuric acid including but not limited to, sodium lauryl sulphate; sulfoalkylamides and salts thereof including but not limited to N-methyl-N-oleoyltaurate Na salt; alkylarylsulfonates including but not limited to alkylbenzenesulfonates; alkylnaphthalenesulfonates and salts thereof; and salts of ligninsulfonic acid.
- soaps soaps
- salts of aliphatic monoesters of sulphuric acid including but not limited to, sodium lauryl sulphate
- sulfoalkylamides and salts thereof including but not limited to N-methyl-N-oleoyltaurate Na salt
- alkylarylsulfonates including but not limited to alkylbenzenesulfonates; alkylnaphthalenes
- the tank mix compatible composition further comprises a dispersing agent having a low HLB value (e.g., HLB of less than 6) selected from ethoxylated isotridecanol, a polymeric ester dispersant (e.g., ATLOX® 4916, ATLOX® 4912 or ATLOX® 4914; Croda), a modified styrene acrylic copolymer dispersant (e.g., ATLOX® Metasperse 550S, ATLOX® Metasperse 500L, or ATLOX® Metasperse), glycol distearate, sorbitan trioleate, propylene glycol iso stearate, glycol stearate, sorbitan sesquioleate, glyceryl stearate, lecithin, steareth-2, oleth-2, glyceryl laurate, ceteth-2, PEG-30 dipolyhydroxystearate, glyceryl stearate
- the tank mix compatible composition further comprises a rheological modifier (thickener) selected from organically modified hectorite clays such as BENTONE® 38 and SD3; organically modified bentonite clays, such as BENTONE® 34, SD1 and SD2; organically modified sepeolite such as PANGEL® B20, hydrophilic silica such as AEROSIL® 200, hydrophobic silica such as AEROSIL® R972, R974 and R812S; attapulgite such as ATTAGEL® 50; or organic rheological modifiers based on modified castor oil such as THIXCIN® R and THIXATROL® ST.
- a rheological modifier selected from organically modified hectorite clays such as BENTONE® 38 and SD3; organically modified bentonite clays, such as BENTONE® 34, SD1 and SD2; organically modified sepeolite such as PANGEL® B20, hydrophilic silica such as AEROSIL
- the tank mix compatible composition further comprises a stabilizer derived from an organic acid, for example a Cx-Cl 8 fatty acid such as oleic acid, stearic acid, myristic acid, palmitic acid, lauric acid, and polyhydroxystearic acid.
- a stabilizer derived from an organic acid for example a Cx-Cl 8 fatty acid such as oleic acid, stearic acid, myristic acid, palmitic acid, lauric acid, and polyhydroxystearic acid.
- the tank mix compatible composition comprises a diluent which does not dissolve the active ingredient enough to cause crystal growth or physical instability.
- the diluent is selected from paraffin oil, such as a kerosene, mineral oil for example, one of the EXXSOL® D range available from Exxon Chemical and more preferably, EXXSOL® D130; PROPAR®12 available from Caltex; and HYDROSEAL® G250H available from Total. Seed oil esters, such as methyl and ethyl oleate, methyl and ethyl soyate and their corresponding fatty acids are also suitable.
- Aromatic hydrocarbons such as alkyl benzenes and alkylnaphthalenes, polyalkylene glycol ethers, fatty acid diesters, fatty alkylamides and diamides, dialkylene carbonates, ketones and alcohols may also be suitable.
- the tank mix compatible composition comprises a defoamer selected from silicone -based compounds, alcohols, glycol ethers, mineral spirits, acetylene diols, polysiloxanes, organosiloxanes, siloxane glycols, reaction products of silicon dioxide and organosiloxane polymer, polydimethylsiloxanes, polyalkylene glycols, or a combination thereof.
- Defoamers that are suitable includes Silcolapse-0 and SAG-1572.
- the tank mix compatible composition is formulated as an oil dispersion (OD).
- the tank mix compatible composition comprises from about 40% w/w to about 99% w/w dithiocarbamate fungicide, from about 1% w/w to about 30% w/w of the at least two non-ionic surfactants having an HLB of greater than 6, and from about 1% w/w to about 25% w/w of the at least two anionic surfactants, based on the total weight of the tank mix compatible composition.
- the tank mix compatible composition comprises from about 45% w/w to about 99% w/w dithiocarbamate fungicide, from about 1% w/w to about 30% w/w of the at least two non-ionic surfactants having an HLB of greater than 6, and from about 1% w/w to about 30% w/w of the at least two anionic surfactants, based on the total weight of the tank mix compatible composition.
- the tank mix compatible composition comprises from about 45% w/w to about 99% w/w dithiocarbamate fungicide, from about 5% w/w to about 25% w/w of the at least two non-ionic surfactants having an HLB greater than 6, and from about 5% w/w to about 25% w/w of the at least two anionic surfactants, based on the total weight of the tank mix compatible composition, and wherein the tank mix compatible composition is in the form of liquid composition.
- the tank mix compatible composition comprises from about 45% w/w to about 99% w/w dithiocarbamate fungicide, from about 5% w/w to about 25% w/w of the at least two non-ionic surfactants having HLB greater than 6, and from about 5% w/w to about 25% w/w of the at least two anionic surfactants, based on the total weight of the tank mix compatible composition, and wherein said tank mix compatible composition is in the form of oil dispersion (OD).
- OD oil dispersion
- a tank mix compatible composition comprising: a dithiocarbamate fungicide, a salt thereof, a derivative thereof, or combination thereof; at least two non-ionic surfactants each having an HLB value of greater than 6; at least two anionic surfactants and at least on agrochemically acceptable agents.
- the present compositions further comprise an oil, an adjuvant, an additional fungicide, an insecticide, a herbicide, and other agrochemical ingredients or a combination thereof.
- a process of preparing a tank mix compatible composition comprises: combining at least two non-ionic surfactants each having HLB value of greater than 6 and optionally an auxiliary ingredient to obtain a mixture; adding at least two anionic surfactants to the mixture to obtain a pre-mix; and adding dithiocarbamate fungicide to the pre-mix with continuous stirring to obtain the tank mix compatible composition.
- a process of preparing the tank mix compatible composition comprises: combining at least two non-ionic surfactants each having HLB value greater than 6, a diluent, and optionally an auxiliary ingredient to obtain a mixture; adding at least two anionic surfactants to the mixture to obtain a pre-mix; and adding a dithiocarbamate fungicide to the pre-mix with continuous stirring to obtain tank mix compatible composition, wherein the dithiocarbamate fungicide comprises mancozeb.
- the process comprises applying shear to the mixture of the dithiocarbamate fungicide, at least two non-ionic surfactants, at least two anionic surfactants, and optional auxiliary agents in order to reduce particle size.
- Suitable devices for applying shear include high shear mixers, (such as an Ultra-Turrax apparatus, and dissolver mixers), static mixers (e.g. systems having mixing nozzles), bead mills, vibratory mills, agitator bead mills, colloid mills, cone mills, circulating mills (e.g., agitator ball mills with pin grinding system), disk mills, annular chamber mills, double cone mills, sprocket dispersers, homogenizers, or any combination thereof.
- high shear mixers such as an Ultra-Turrax apparatus, and dissolver mixers
- static mixers e.g. systems having mixing nozzles
- bead mills e.g. systems having mixing nozzles
- vibratory mills e.g. systems having
- the mixing of the at least two non-ionic surfactants, dithiocarbamate fungicide, and at least two anionic surfactants with a diluent is carried out under low shear to obtain an oil dispersion.
- the tank mix compatible composition is diluted with water (or an aqueous liquid) to form an end-use agrochemical formulation, for example, a spray formulation.
- the tank mix compatible composition has a pH ranging from 5-7.
- the pH of the tank mix compatible composition varies no more than 20%, or no more than 10%, or no more than 5%, when stored at 54°C for a period of 24 hours to 14 days.
- the tank mix compatible composition is used as the source of agrochemical active ingredient and is diluted to provide an end-use agrochemical formulations prior to application.
- the tank mix compatible composition may be diluted with water or an aqueous solution 1 to 10,000 fold, or 10 to 1,000 fold, to form the end-use agrochemical formulations (e.g., spray formulation).
- the tank mix compatible composition may be diluted to provide an end-use agrochemical formulation having an active ingredient (dithiocarbamate fungicide) concentration of about 0.001 wt.% to about 1 wt.%, or about 0.5 wt.% to about 1 wt.% based on the total weight of the end-use agrochemical formulation.
- the mixing steps in the process are carried out at a temperature in the range of about 20° C. to about 80° C., more preferably from about 20° C to about 40° C.
- the continuous mixing is carried out for a period of about 30 seconds to about 24 hours, preferably from about five minutes to about three hours.
- a method of controlling a fungal disease in a crop or a locus thereof comprises applying an agrochemically effective amount of the tank mix compatible composition to the crop or the locus thereof.
- a method of controlling a fungal disease in a crop or a locus thereof comprises applying an agrochemically effective amount of tank mix compatible composition comprising mancozeb, at least two non-ionic surfactants each having HLB value greater than 6, and at least two anionic surfactants.
- the method comprises applying an agrochemically effective amount of tank mix compatible composition to a plant, a locus thereof, or soil in which the plant is growing or intended to be grown.
- the tank mix compatible composition is compatible with ingredients such as oils, adjuvants, additional fungicides, herbicides, insecticides, and other agrochemical ingredients.
- the present tank mix compatible composition is compatible at tank mixing with fungicides.
- the fungicide can be added directly to the present tank mix compatible composition on its own or as a component in a different formulation.
- the tank mix compatible composition is combined with a conazole fungicide such as azaconazole, cyproconazole, difenoconazole, epoxiconazole, hexaconazole, propiconazole, prothioconazole, triadimenol, tebuconazole, tetraconazole, and/or triticonazole.
- a conazole fungicide such as azaconazole, cyproconazole, difenoconazole, epoxiconazole, hexaconazole, propiconazole, prothioconazole, triadimenol, tebuconazole, tetraconazole, and/or triticonazole.
- the tank mix compatible composition is combined with a strobilurin fungicide such as azoxystrobin, fluoxastrobin, pyraclostrobin, trifloxystrobin, and/or
- the tank mix compatible composition is combined with an anilide fungicide such as bixafen, boscalid, and/or metalaxyl, metalaxyl-M.
- anilide fungicide such as bixafen, boscalid, and/or metalaxyl, metalaxyl-M.
- the tank mix compatible composition is combined with a morpholine fungicide such as dimethomorph and/or fenpropimorph.
- the tank mix compatible composition is combined with an anilinopyrimidine fungicide such as cyprodinil, mepanipyrim, and/or pyrimethanil.
- the tank mix compatible composition is combined with a fungicide such as acibenzolar, benzalkonium chloride, bromothalonil, spiroxamine, and/or tricyclazole.
- the tank mix compatible composition is used to control fungal diseases cause by a wide range of different fungi.
- the tank mix compatible composition can be used for treatment of plant crops and/or for the treatment of inanimate materials e.g., in the household.
- the tank mix compatible composition is useful for controlling fungal disease in plant crops including: cotton, flax, grapevines, fruit, vegetables, such as Rosaceae sp. (for example pome fruit such as apples and pears, but also stone fruit such as apricots, cherries, almonds and peaches, and berry fruits such as strawberries), Ribesioidae sp., Juglandaceae sp., Betulaceae sp, Anacardiaceae sp., Fagaceae sp., Moraceae sp., Oleaceae sp., Actinidaceae sp., Lauraceae sp., Muscaceae sp.
- Rosaceae sp. for example pome fruit such as apples and pears, but also stone fruit such as apricots, cherries, almonds and peaches, and berry fruits such as strawberries
- Rosaceae sp. for example pome fruit such as apples and pears, but also
- Rubiaceae sp. for example coffee
- Theaceae sp. Sterculiceae sp.
- Rutaceae sp. for example lemons, organs and grapefruit
- Solanaceae sp. for example tomatoes
- Liliaceae sp. Asteraceae sp.
- Umbelliferae sp. for example Cruciferae sp.
- Chenopodiaceae sp. Cucurbitaceae sp. (for example cucumbers), Alliaceae sp. (for example leeks, onions), Papilionaceae sp.
- main crop plants such as Gramineae sp. (for example maize, turfgrass, cereals such as wheat, rye, rice, barley, oats, sorghum/millet and tritical e), Asteraceae sp. (for example sunflowers), Brassicaceae sp. (for example white cabbage, red cabbage, broccoli, cauliflower, Brussels sprouts, Pak Choi, kohlrabi, radishes, and rapeseed, mustard, horseradish and cress), Fabacae sp. (for example beans, peanuts), Papilionaceae sp. (for example soya beans), Solanaceae sp.
- Gramineae sp. for example maize, turfgrass, cereals such as wheat, rye, rice, barley, oats, sorghum/millet and tritical e
- Asteraceae sp. for example sunflowers
- Brassicaceae sp. for example white cabbage,
- the tank mix compatible composition and/or the end- use agrochemical formulation can be applied as a liquid formulation using customary methods, i.e., for example by spraying, pouring or injecting.
- the present disclosure provides a kit comprising a plurality of components, each of which comprises at least one of the ingredients of the tank mix compatible composition disclosed herein.
- the kit may include at least one, or all, of the components used to prepare the tank mix compatible composition.
- the kit may include the dithiocarbamate fungicide, a salt thereof, a derivative thereof, or a combination thereof, the at least two non-ionic surfactants each having HLB value of greater than 6, and the at least two anionic surfactants.
- One or more of the components may already be combined together or pre-formulated. When more than two components are provided in a kit, the components may already be combined together and as such are packaged in a single container such as a vial, bottle, can, pouch, bag or canister.
- Examples 4-11 were prepared to assess the effect of the presence of non-ionic surfactants and anionic surfactants on the high loading of mancozeb in the OD compositions.
- the compositions of Example 4, Example 5 and Example 6 included at least two non-ionic surfactants, each having an hydrophilic-lipophilic balance (HLB) of greater than 6 and at least two anionic surfactants.
- HLB hydrophilic-lipophilic balance
- Table 1 it was observed that all three of the compositions of Examples 4-6 exhibited very good stability with a very soft sediment that became completely flowable upon gentle shaking. Following dilution, each of the compositions of Examples 4-6 formed good dispersions without any cream or sediment.
- Example 7 & Example 8 with only one non-ionic surfactant
- Example 9 and Example 10 with only one anionic surfactant
- Example- 11 with no non-ionic surfactant did not exhibit the desired stability.
- the compositions of Examples 7-11 resulted in a hard sediment which was not dispersible upon shaking. Also, upon dilution, the compositions of Example 7-11 resulted in a poor dispersion.
- NIS3 Cio guerbet alcohol alkoxylate+5EO (Lutensol 50), NIS4: atlox 4916, AS1: phosphate ester, AS2: sulfated polyaryl phenol ethoxylates ammonium salt.
- Example 12 and Example 15 were prepared using only one anionic surfactant, and resulted in a hard sediment. These same compositions reported 5% bleeding. Although, after 14 days AHS, it became flowable after shaking but resulted into a poor dispersion when diluted with water.
- Composition of Example- 17 and 18 were prepared using at least two anionic surfactants and two non-ionic surfactants.
- the non-ionic surfactants POE-(2)-cetyl alcohol (HLB:5.3), sorbitan monostearate (HLB:4.7) and polyalkylene glycol (HLB: 3) used were all less than 6 HLB. These compositions resulted into hard/stick sediment, bleeding between 5-15% and gave poor dispersion in water.
- NISI Tristryl phenol ethoxylate(BSU)
- NIS2 Lutensol 40
- NIS3 Lutensol 50
- NIS4 atlox 4916
- NIS5 POE-(2)-cetyl alcohol (HLB:5.3)
- NIS6 Sorbitan monostearate(HLB:4.7)
- NIS7 Polyalkylene glycol (HLB: 3)
- AS1 phosphate ester
- AS2 sulfated polyaryl phenol ethoxylate ammonium salt (3D484).
- compositions of Examples 1-16 were diluted with water and mixed with other tank mix partners. Observations were made to see if there is any separation and sedimentation in the tank. The results are shown in Table 3. The observations were made for different time intervals: 10 min, 20 min, and 30 min. While performing the tank mix study, the selected tank mix partners (as per Table 3 below) were added to about 20 ml water in a beaker, and subjected to gentle stirring to obtain mixture. Then the Example tank mix compatible compositions disclosed above were added to the above-described mixture followed by the addition of remaining water, with gentle stirring, to make a final volume of 50 ml. The percentage separation and percentage sedimentation of each tan mix was observed at various intervals of time, specifically, 10 min, 20 min and 30 min. As shown in Table 3, the compositions of Examples 1-6 exhibited good compatibility with other tank mix partners and resulted in a uniform tank mix dilution without any sedimentation or separation. (Table 3)
- Example 9-12 were tested for tank-mix compatibility with different tank-mix partners, and either separation or flocculation was observed. Hence Examples 9-12 were not considered to have good tank-mix compatibility (Table 4). Similarly, when the compositions of Examples 13-14 and Examples 15-16 were tested for tank-mix compatibility with different tank-mix partners, either separation or flocculation was observed and hence they were not considered to have good tank- mix compatibility. (Tables 5 & 6).
- a tank mix compatible composition of a high loading of dithiocarbamate fungicide which includes at least two non-ionic surfactants each having an HLB of greater than 6 and at least two anionic surfactants.
- the combination of the at least two non-ionic surfactants and the at least two anionic surfactants has been found to be essential for the preparation of tank mix compatible composition including a high loading of a dithiocarbamate fungicide.
- the tank mix compatible composition exhibits good storage stability, dilution stability, and tank mix compatibility for a wide number of formulations of various agrochemical compositions.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Zoology (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Toxicology (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BR112023017908A BR112023017908A2 (en) | 2021-03-12 | 2022-03-11 | COMPOSITION COMPATIBLE WITH TANK MIXING |
MX2023010709A MX2023010709A (en) | 2021-03-12 | 2022-03-11 | A tank mix compatible composition. |
CONC2023/0012080A CO2023012080A2 (en) | 2021-03-12 | 2023-09-12 | Composition compatible with tank mixing |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IN202121010523 | 2021-03-12 | ||
IN202121010523 | 2021-03-12 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2022190133A1 true WO2022190133A1 (en) | 2022-09-15 |
Family
ID=83227504
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IN2022/050226 WO2022190133A1 (en) | 2021-03-12 | 2022-03-11 | A tank mix compatible composition |
Country Status (5)
Country | Link |
---|---|
AR (1) | AR125067A1 (en) |
BR (1) | BR112023017908A2 (en) |
CO (1) | CO2023012080A2 (en) |
MX (1) | MX2023010709A (en) |
WO (1) | WO2022190133A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2023084524A1 (en) * | 2021-11-12 | 2023-05-19 | Adama Makhteshim Ltd. | Dithiocarbamate fungicide combinations and compositions thereof |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0697171A1 (en) * | 1994-07-12 | 1996-02-21 | Rohm And Haas Company | Novel agrochemical suspoemulsion |
US20190150430A1 (en) * | 2016-05-24 | 2019-05-23 | Adama Makhteshim Ltd. | Oil liquid fungicidal formulation |
CN106172385B (en) * | 2016-07-01 | 2019-10-22 | 深圳诺普信农化股份有限公司 | Pesticide dry suspending agent and its preparation and application |
CN110810401A (en) * | 2019-12-02 | 2020-02-21 | 贵州大学 | Dimethomorph and thiram bactericide, and preparation method and application thereof |
WO2020104475A1 (en) * | 2018-11-23 | 2020-05-28 | Lamberti Spa | Dithiocarbamate oil dispersions |
WO2020121345A1 (en) * | 2018-12-14 | 2020-06-18 | Isagro S.P.A. | Oil dispersion containing fluindapyr and use thereof as fungicide in crop plants |
US20200404904A1 (en) * | 2018-03-13 | 2020-12-31 | Lamberti Spa | Agrochemical oil dispersions |
-
2022
- 2022-03-10 AR ARP220100548A patent/AR125067A1/en unknown
- 2022-03-11 WO PCT/IN2022/050226 patent/WO2022190133A1/en active Application Filing
- 2022-03-11 BR BR112023017908A patent/BR112023017908A2/en unknown
- 2022-03-11 MX MX2023010709A patent/MX2023010709A/en unknown
-
2023
- 2023-09-12 CO CONC2023/0012080A patent/CO2023012080A2/en unknown
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0697171A1 (en) * | 1994-07-12 | 1996-02-21 | Rohm And Haas Company | Novel agrochemical suspoemulsion |
US20190150430A1 (en) * | 2016-05-24 | 2019-05-23 | Adama Makhteshim Ltd. | Oil liquid fungicidal formulation |
CN106172385B (en) * | 2016-07-01 | 2019-10-22 | 深圳诺普信农化股份有限公司 | Pesticide dry suspending agent and its preparation and application |
US20200404904A1 (en) * | 2018-03-13 | 2020-12-31 | Lamberti Spa | Agrochemical oil dispersions |
WO2020104475A1 (en) * | 2018-11-23 | 2020-05-28 | Lamberti Spa | Dithiocarbamate oil dispersions |
WO2020121345A1 (en) * | 2018-12-14 | 2020-06-18 | Isagro S.P.A. | Oil dispersion containing fluindapyr and use thereof as fungicide in crop plants |
CN110810401A (en) * | 2019-12-02 | 2020-02-21 | 贵州大学 | Dimethomorph and thiram bactericide, and preparation method and application thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2023084524A1 (en) * | 2021-11-12 | 2023-05-19 | Adama Makhteshim Ltd. | Dithiocarbamate fungicide combinations and compositions thereof |
Also Published As
Publication number | Publication date |
---|---|
CO2023012080A2 (en) | 2023-10-09 |
MX2023010709A (en) | 2023-09-19 |
BR112023017908A2 (en) | 2023-10-31 |
AR125067A1 (en) | 2023-06-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US9770021B2 (en) | Pesticidal compositions | |
CN101784184B (en) | The Enhancement Method of the effect of the composition pesticide that effect is enhanced and pesticide activity component | |
CN105451551B (en) | Auxiliary combination | |
RU2427133C2 (en) | Pesticide compositon and seed treatment method | |
US20100179228A1 (en) | Novel Oil-Based Adjuvant Composition | |
AU2010313076B2 (en) | Herbicidal combination | |
CA3193614A1 (en) | A liquid agrochemical composition | |
WO2020225276A1 (en) | Agrochemical formulation with enhanced performance and enhanced performance at low spray volumes and by uav application | |
WO2022190133A1 (en) | A tank mix compatible composition | |
EA039812B1 (en) | Aqueous dispersion of herbicidal agents, process for preparing same and use thereof | |
US20150237852A1 (en) | Alkoxylate compositions and their use as agricultural adjuvants | |
WO2024018456A1 (en) | Solid composition of cyantraniliprole and acetamiprid | |
US20230148591A1 (en) | Use of oil based suspo-emulsion concentrates for reducing drift during spray application | |
KR20220088841A (en) | Synergistic antiseptic composition | |
JP2015174834A (en) | aqueous suspension formulation | |
WO2023232559A1 (en) | Formulation | |
EA047278B1 (en) | LIQUID AGROCHEMICAL COMPOSITION | |
OA21455A (en) | Liquid composition comprising a neonictonoid | |
WO2024013738A1 (en) | Pymetrozine aqueous compositions | |
WO2023083897A1 (en) | Surfactant combination for aqueous agrochemical (crop protection) suspension formulations with high salt content and low-concentration of sulfonylurea herbicide |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 22766557 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 12023552231 Country of ref document: PH |
|
WWE | Wipo information: entry into national phase |
Ref document number: MX/A/2023/010709 Country of ref document: MX |
|
REG | Reference to national code |
Ref country code: BR Ref legal event code: B01A Ref document number: 112023017908 Country of ref document: BR |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 112023017908 Country of ref document: BR Kind code of ref document: A2 Effective date: 20230904 |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 22766557 Country of ref document: EP Kind code of ref document: A1 |