WO2022184877A2

WO2022184877A2 - Oral care composition

Info

Publication number: WO2022184877A2
Application number: PCT/EP2022/055498
Authority: WO
Inventors: Huajin Jin; Weining LIU; Jinfang Wang
Original assignee: Unilever Ip Holdings B.V.; Unilever Global Ip Limited; Conopco, Inc., D/B/A Unilever
Priority date: 2021-03-05
Filing date: 2022-03-04
Publication date: 2022-09-09
Also published as: WO2022184877A3

Abstract

An oral care composition is disclosed comprising from 0.01 to 10% by weight of a deposition polymer, a sugar fatty acid ester surfactant and a benefit agent selected from optical agents, antimicrobial agents and mixtures thereof; wherein the benefit agent is a pigment having a hue angle, h, in the CIELAB system of from 220 to 320 degrees.

Description

ORAL CARE COMPOSITION

Field of the Invention

The present invention relates to oral care compositions comprising polymers, surfactants and benefit agents. In particular, the invention is also concerned with the use of such compositions for whitening teeth and/or improving the oral hygiene of an individual.

Background of the Invention

Most food and drinks we consume can impact our teeth and mouth negatively. For example, acidic drinks can damage tooth enamel to cause tooth erosion. Tobacco and dietary intake of tannin-rich foods can stain the teeth and reduce the tooth whiteness.

Consumers have a strong desire for healthier and whiter teeth. Benefit agents such as optical agents and antimicrobial agents are commonly used in oral care compositions to provide benefits such as whitening and better oral hygiene.

However, it is usually hard to get sufficient deposition of benefit agents from oral care compositions. Those benefit agents often do not adhere strongly to tooth surfaces so they are easy to be rinsed away during daily oral hygiene routine such as tooth brushing therefore provide little or no benefits.

There is still needs to enhance the deposition of benefit agents on teeth from oral care compositions to maximize the effectiveness of such benefit agents.

The present inventors have now found surprisingly that an oral care composition comprising a combination of a deposition polymer and a specific surfactant can enhance the deposition of benefit agents onto the teeth of an individual.

Summary of the Invention

In a first aspect, the present invention is directed to an oral care composition comprising:

(a) from 0.01% to 10% by weight of a deposition polymer;

(b) a sugar fatty acid ester surfactant; and

(c) a benefit agent selected from optical agents, antimicrobial agents and mixtures thereof; wherein the benefit agent is a pigment having a hue angle, h, in the CIELAB system of from 220 to 320 degrees.

In a second aspect, the present invention is directed to a packaged oral care product comprising the oral care composition of the first aspect of this invention.

In a third aspect, the present invention is directed to a method of whitening teeth of an individual comprising the steps of applying the oral care composition of any embodiment of the first aspect to at least one surface of the teeth of the individual.

All other aspects of the present invention will more readily become apparent upon considering the detailed description and examples which follow.

Detailed Description of the Invention

Except in the examples, or where otherwise explicitly indicated, all numbers in this description indicating amounts of material or conditions of reaction, physical properties of materials and/or use may optionally be understood as modified by the word “about”.

All amounts are by weight of the final oral care composition, unless otherwise specified. It should be noted that in specifying any ranges of values, any particular upper value can be associated with any particular lower value.

For the avoidance of doubt, the word “comprising” is intended to mean “including” but not necessarily “consisting of’ or “composed of”. In other words, the listed steps or options need not be exhaustive.

The disclosure of the invention as found herein is to be considered to cover all embodiments as found in the claims as being multiply dependent upon each other irrespective of the fact that claims may be found without multiple dependency or redundancy.

Where a feature is disclosed with respect to a particular aspect of the invention (for example a composition of the invention), such disclosure is also to be considered to apply to any other aspect of the invention (for example a method of the invention) mutatis mutandis. DEPOSITION POLYMER

The oral care composition of the invention comprises a deposition polymer. The term “deposition polymer”, as used herein, means a polymer which aids the deposition of benefit agents from the continuous phase of the composition onto the surface of teeth during use of the composition. Use of the composition in the context of this invention typically involves application of the composition to the oral cavity, followed by brushing and/or rinsing. The deposition polymer enhances the deposition of the benefit agents onto the surfaces of teeth and thereby enhances the performance of the composition. Suitable deposition polymers for use in the invention may be naturally or synthetically-derived.

Suitable deposition polymers for use in the invention include, for example, xanthan gum, hyaluronic acid, sodium alginate, pectin, modified starch, gelatin, carrageenan, gellan gum, fenugreek gum, konjac gum, tragacanth gum, karaga gum, g-polyglutamic acid, heparin sodium salt, a copolymer of methyl vinyl ether and maleic anhydride, polyacrylic acid, polystyrene sulfonate, deoxyribonucleic acids, poly(allylamine), locust bean gum, guar gum, polyglycolic acid, polylactic acid, poly(glycolic-co-lactic acid), chitosan, humic acid, phytate acid, derivatives or mixtures thereof. Preferably the deposition polymer comprises xanthan gum, hyaluronic acid, sodium alginate, pectin, modified starch, gelatin, carrageenan, gellan gum, fenugreek gum, konjac gum, tragacanth gum, karaga gum, y-polyglutamic acid, phytate acid, derivatives or mixtures thereof.

It is preferred that the deposition polymer is xanthan gum and/or its derivatives.

Xanthan gum is an extracellular polysaccharide secreted by the microorganism Xanthomonas campestris. It is a linear (1, 4)-linked b-D-glucose backbone (as in cellulose) with a trisaccharide side chain on every other glucose at C-3. This side chain comprises a glucuronic acid residue linked (1, 4) to a terminal mannose unit and (1, 2) to a second mannose that connects to the backbone. Approximately 50% of the terminal mannose residues are pyruvated and the non-terminal residue usually carries an acetyl group at C-6.

The structure of xanthan gum is given below:

Wherein n ranges from 10 to 10,000, preferably from 100 to 8,000, more preferably from 500 to 5,000, most preferably from 1 ,000 to 3,000.

The xanthan gum derivatives can be prepared by etherification, esterification, acetalation, amidation or oxidation of non-derivatized xanthan gum. Preferred xanthan gum derivatives are prepared by reacting non-derivatized gum with quaternary ammonium compounds in an amount equal to or greater than the stoichiometric amount required for complete derivatization. The quaternary ammonium compounds are preferably having a single alkyl or alkenyl substituent containing from 13 to 24 carbon atoms, and/or two alkyl or alkenyl substituents of 12 to 24 carbon atoms per substituent. Most preferably, the quaternary ammonium compound is alkyl dimethylbenzylammonium chloride with an alkyl group containing from 13 to 24 carbon atoms.

The composition comprises 0.01% to 10% by weight of the deposition polymer, preferably from 0.02 to 5% , more preferably from 0.05 to 3%, and most preferably from 0.05 to 2%, based on total weight of the oral care composition and including all ranges subsumed therein.

SUGAR FATTY ACID ESTER SURFACTANT

The composition comprises a sugar fatty acid ester surfactant. Sugar fatty acid esters, also called sugar esters, are non-ionic and biodegradable surfactants. The sugar fatty acid ester is an ester of sugar and a fatty acid. The sugar moiety of the sugar fatty acid ester is derived from monosaccharide, disaccharide and/or oligosaccharide including, for example, sucrose, fructose, glucose, methylglucose, rhamnose, fucose, deoxyribose, ribose, trehalose, xylose, mannose, arabinose, galactose, cellobiose, lactose, maltose, isomaltose, melibiose, gentobiose, maltotriose, raffinose, panose or mixtures thereof, preferably sucrose, fructose, glucose, trehalose or mixtures thereof, sucrose being particularly preferred.

The fatty acid moiety of the sugar fatty acid ester is preferably a linear or branched, saturated or unsaturated fatty acid having from 6 to 28 carbon atoms, more preferably from 8 to 24 carbon atoms, more preferably still from 10 to 22 carbon atoms and most preferably from 12 to 20 carbon atoms. Specific examples include, for example, caproic acid, octanoic acid, lauric acid, coconut fatty acid, myristic acid, palmitic acid, stearic acid, behenic acid, arachidic acid, palmitoleic acid, oleic acid, linoleic acid, linolenic acid, arachidonic acid, erucic acid, 2-ethylhexanoic acid, isostearic acid, methyl-branched isostearic acid, 2-octyldodecanoic acid or mixtures thereof, preferably octanoic acid, lauric acid, coconut fatty acid, myristic acid, palmitic acid, stearic acid, arachidic acid, palmitoleic acid, oleic acid, linoleic acid, linolenic acid or mixtures thereof, more preferably lauric acid, coconut fatty acid, myristic acid, palmitic acid, stearic acid, palmitoleic acid, oleic acid or mixtures thereof, most preferably palmitic acid, stearic acid or mixtures thereof.

The sugar fatty acid ester may contain multiple ester groups according to the number of hydroxyl groups within the sugar that is used. It is preferred that the sugar fatty acid ester is sucrose fatty acid ester. Sucrose is a polyhydric alcohol with eight hydroxyl groups. The three primary hydroxyl groups on the sucrose molecule are the most reactive and are the easiest to substitute with fatty acids, forming mono-, di-, and tri-esters. Preferably, the sugar fatty acid ester is sucrose fatty acid monoesters. Typical examples of sucrose fatty acid monoesters include sucrose stearate, sucrose cocoate, sucrose laurate, sucrose palmitate, sucrose myristate, sucrose oleate or mixtures thereof. Sucrose stearate is most preferred.

The composition typically comprises from 0.01 to 10% by weight of the sugar fatty acid ester surfactant, more preferably from 0.1 to 8% and most preferably from 0.5 to 5%, based on total weight of the oral care composition and including all ranges subsumed therein.

BENEFIT AGENT

Benefit agent as used herein means an active typically delivered to human teeth and/or the oral cavity including the gums to enhance or improve a characteristic of those dental tissues. The only limitation with respect to the benefit agents that may be used in this invention is that the same is suitable for use in the mouth.

Typically benefit agent includes, for example, optical agents, biomineralization agents, adsorbing agents, antimicrobial agents, gum health agents, desensitizing agents, anti calculus agents, freshness agents or mixtures thereof. The benefit agent is selected from optical agents, antimicrobial agents and mixtures thereof.

Optical agents may be selected from one or more of whitening agents and pearlescent agents. When the optical agent is a whitening agent, it is preferable that the whitening agent is a dye or a pigment or a combination of the two. The pigment according to the invention is a shade/material which is insoluble in the relevant medium, at the relevant temperature. This is in contrast to dyes which are soluble. The term “soluble”, as used herein, means a source that dissolves in water to give a solution with a concentration of at least 0.1 moles per litre. The term “relevant medium”, as used herein, refers to human saliva, the liquid medium in which the composition is used, at the temperature of the oral cavity during brushing of the teeth, i.e. up to 37°C. The relevant medium may also be water and the relevant temperature to be 25°C. The pigment or dye for use in the present invention is violet or blue having a hue angle, h, in the CIELAB system of from 220 to 320 degrees, preferably from 250 to 290 degrees. When the whitening agent is a pigment, it is preferable that the pigment is violet or blue selected from one or more of those listed in the Colour Index International as pigment blue 1 through to pigment 83 and pigment violet 1 through to pigment violet 56. Other suitable pigments are pigment ultramarine blue and ultramarine violet. While the preferred pigment is blue or violet, the same effect may be achieved through mixing pigments outside of this hue angle range. For example, such a hue angle may also be obtained by mixing a red and green-blue pigment to yield a blue or violet shaded pigment.

It is particularly preferred that the pigment is a blue pigment. Some examples of blue pigments suitable for use in this invention include inorganic blue pigments such as iron blue (C.l. 77510) and ultramarine blue (C.l. 77007). A preferred class of blue pigments suitable for use in the invention are organic blue pigments such as phthalocyanine blue pigments. It is especially preferred that the pigment is phthalocyanine blue pigment selected from alpha copper phthalocyanines Pigment Blue 15, Pigment Blue 15:1,

Pigment 15:2 and mixtures thereof. Most preferably the pigment is Pigment Blue 15:1. A commercially available example is Cosmenyl Blue A4R from Clariant. When the whitening agent is a dye, it is preferable that the dye is a blue dye, more preferably FD&C Blue 1 , Patent Blue V or Gardenia Blue.

In another preferred embodiment, the whitening agent is a particulate whitening agent having a refractive index of from 1.9 to 4.0. The refractive index is quoted at a temperature of 25°C and a wavelength of 589 nm. Suitable materials to provide such a high refractive index are metal compounds and preferred are compounds where the metal is selected from zinc (Zn), titanium (Ti), zirconium (Zr) or a mixture thereof. Preferably, the metal compound is (or at least comprises) a metal oxide such as titanium dioxide (T1O2), zinc oxide (ZnO), zirconium dioxide (ZrC>2) or a mixture thereof. Preferably, the particulate whitening agent is a composite particle. The term “Composite particle”, as used herein, means a particle comprising a first component core and a second component coating wherein the core and coating are composed of different materials.

The composite particle comprises a first component core and a second component coating. Particularly suitable core materials are metal compounds and preferred are compounds where the metal is selected from zinc (Zn), titanium (Ti), zirconium (Zr) or a mixture thereof. Preferably, the metal compound is (or at least comprises) a metal oxide such as titanium dioxide (T1O2), zinc oxide (ZnO), zirconium dioxide (Zr0₂) or a mixture thereof. The second component coating comprises material suitable to adhere to tooth enamel, dentin or both. Typically the coating material comprises the element calcium, and optionally, other metals like potassium, sodium, aluminium, magnesium as well as mixtures thereof whereby such optional metals are provided as, for example, sulphates, lactates, oxides, carbonates or silicates. Optionally, the coating material may be aluminium oxide or silica. In a preferred embodiment, the second component coating can comprise, for example, calcium phosphate, calcium gluconate, calcium oxide, calcium lactate, calcium carbonate, calcium hydroxide, calcium sulphate, calcium carboxymethyl cellulose, calcium alginate, calcium salts of citric acid, calcium silicate, mixture thereof or the like. Calcium silicate is particularly preferred. In an especially preferred embodiment, the particulate whitening agent is titanium dioxide coated with calcium silicate.

In another preferred embodiment, the optical agent is a pearlescent agent. The term “pearlescent”, as used herein, means an agent in the form of particles which reflects and partially transmits the incident light. Suitable pearlescent agent for use in the present invention includes mica, bismuth oxychloride or mixtures thereof. Preferably the pearlescent agent is formed by coating one or more metal oxide layers onto natural or synthetic mica flakes. Examples of suitable mica include, for example, muscovite, phlogopite, fluorophlogopite, biotite or mixtures thereof. Examples of suitable metal oxides include, for example, Ti0₂, Fe₂C>3, TiFe₂C>5, Fe₃C>4, Cr₂C>3, AI₂C>3, Si0₂, Zr0₂, ZnO, Sn0₂, CoO, C03O4, V0₂, V₂0₃, Sn(Sb)0₂, titanium suboxides or mixtures thereof. One example of a preferred pearlescent agent is mica coated with Ti0₂.

Antimicrobial agents may be selected from one or more of metal compounds where the metal is selected from zinc, copper, silver or a mixture thereof, triclosan, triclosan monophosphate, triclocarban, curcumin, quaternary ammonium compounds, bisbiguanides and long chain tertiary amines, preferably zinc compounds including zinc oxide, zinc chloride, zinc acetate, zinc ascorbate, zinc sulphate, zinc nitrate, zinc citrate, zinc lactate, zinc peroxide, zinc fluoride, zinc ammonium sulfate, zinc bromide, zinc iodide, zinc gluconate, zinc tartarate, zinc succinate, zinc formate, zinc phenol sulfonate, zinc salicylate, zinc glycerophosphate or a mixture thereof. Zinc citrate is particularly preferred.

It is preferred that the benefit agent is an optical agent selected from pigments, dyes, mica, mica coated with Ti0₂, titanium dioxide, titanium dioxide coated with calcium silicate and mixtures thereof. More preferably the benefit agent is a phthalocyanine blue pigment is selected from alpha copper phthalocyanines Pigment Blue 15, Pigment Blue 15:1, Pigment Blue 15:2 and mixtures thereof. Pigment Blue 15:1 is particularly preferred.

It is also preferred that the benefit agent is zinc compounds selected from zinc oxide, zinc chloride, zinc acetate, zinc ascorbate, zinc sulphate, zinc nitrate, zinc citrate, zinc lactate, zinc peroxide, zinc fluoride, zinc ammonium sulfate, zinc bromide, zinc iodide, zinc gluconate, zinc tartarate, zinc succinate, zinc formate, zinc phenol sulfonate, zinc salicylate, zinc glycerophosphate and mixtures thereof. Zinc citrate is particularly preferred.

The oral care composition of the present invention may comprise a single benefit agent or a mixture of two or more benefit agents. Typically, the benefit agent is present in an amount from 0.01 to 60%, and more preferably, from 0.05 to 40%, and most preferably from 0.1 to 30% by total weight of the oral care composition and including all ranges subsumed therein.

When the benefit agent is a pigment, the pigment is preferably present at a level of from 0.001 to 1% by weight of the oral care composition, more preferably from 0.01 to 0.5%, most preferably from 0.02 to 0.2%, based on total weight of the oral care composition and including all ranges subsumed therein.

The oral care composition may comprise other surfactants in addition to the sugar fatty acid ester. Suitable surfactants include anionic surfactants, such as the sodium, magnesium, ammonium or ethanolamine salts of C8 to C18 alkyl sulphates (for example sodium lauryl sulphate), C8 to C18 alkyl sulphosuccinates (for example dioctyl sodium sulphosuccinate), C8 to C18 alkyl sulphoacetates (such as sodium lauryl sulphoacetate), C8 to C18 alkyl sarcosinates (such as sodium lauryl sarcosinate), C8 to C18 alkyl phosphates (which can optionally comprise up to 10 ethylene oxide and/or propylene oxide units) and sulphated monoglycerides. Other suitable surfactants include nonionic surfactants, such as polyethoxylated fatty acid sorbitan esters, ethoxylated fatty acids, esters of polyethylene glycol, ethoxylates of fatty acid monoglycerides and diglycerides, and ethylene oxide/propylene oxide block polymers. Other suitable surfactants include amphoteric surfactants, such as betaines or sulphobetaines. Mixtures of any of the above described materials may also be used. More preferably the surfactant comprises or is anionic surfactant. The preferred anionic surfactants are sodium lauryl sulphate and/or sodium dodecylbenzene sulfonate. Most preferably the surfactant is sodium lauryl sulphate, sodium coco sulfate, cocamidopropyl betaine, sodium methyl cocoyl taurate or mixtures thereof.

When the oral care composition comprises surfactants in addition to the sugar fatty acid ester, the surfactant is typically present at a level from 0.01 to 7% by weight of the composition, more preferably from 0.1 to 7% and most preferably from 0.5 to 5%, based on total weight of the oral care composition and including all ranges subsumed therein.

Preferably, the oral care composition has a pH from 4.0 to 10.0, more preferably from 5.0 to 9.0, and most preferably from 5.5 to 8.0. The pH of oral care composition is measured when 5 parts by weight of the composition is uniformly dispersed and/or dissolved in 20 parts by weight pure water at 25°C. In particular, the pH may be measured by manually mixing 5 g oral care composition with 20 ml_ water for 30 s, then immediately testing the pH with indicator or a pH meter.

The oral care composition of the present invention may comprise a physiologically acceptable carrier. Water is the most common carrier for this invention. The carrier may further comprise at least thickener, humectant or a combination thereof. Thickener may be used in this invention in addition to the deposition polymer which is included in the oral care composition and is limited only to the extent that the same may be added to a composition suitable for use in the mouth. Illustrative examples of the types of thickeners that may be used in this invention include, sodium carboxymethyl cellulose (SCMC), hydroxyl ethyl cellulose, methyl cellulose, ethyl cellulose, silica based thickeners including silica aerogels, magnesium aluminum silicate (e.g., Veegum) and mixtures thereof.

Sodium carboxymethyl cellulose is typically preferred. The copolymer which is included in the composition can also behave as a thickener.

In an especially preferred embodiment, the sodium carboxymethyl cellulose (SCMC) used is SCMC 9H. It has been described as a sodium salt of a cellulose derivative with carboxymethyl groups bound to hydroxy groups of glucopyranose backbone monomers and identified via CAS number 9004-32-4. The same is available from suppliers like Alfa Chem.

Thickener typically makes up from 0.01 to about 10%, more preferably from 0.1 to 9%, and most preferably, from 0.1 to 5% by weight of the oral care composition, based on total weight of the composition and including all ranges subsumed therein.

Suitable humectants are preferably used in the oral care composition of the present invention and they include, for example, glycerin, sorbitol, propylene glycol, dipropylene glycol, diglycerol, triacetin, mineral oil, polyethylene glycol (preferably, PEG-400), alkane diols like butane diol and hexanediol, ethanol, pentylene glycol, or a mixture thereof. Glycerin, polyethylene glycol, sorbitol or mixtures thereof are the preferred humectants.

The carrier is typically present at a level of from 10 to 90% by weight of the oral care composition, more preferably 25 to 80%, and most preferably from 30 to 70% by weight of the composition, based on total weight of the composition and including all ranges subsumed therein.

The oral care composition of the present invention may contain a variety of other ingredients in addition to the benefit agent that is included in the composition, which are common in the art to enhance physical properties and performance. These ingredients include preservatives, pH-adjusting agents, sweetening agents, particulate abrasive materials, buffers and salts to buffer the pH and ionic strength of the compositions, and mixtures thereof. Such ingredients typically and collectively make-up less than 20% by weight of the composition, and preferably, from 0.0 to 15% by weight, and most preferably, from 0.01 to 12% by weight of the composition, including all ranges subsumed therein.

The oral care composition of this invention can be used in a method of benefiting teeth of an individual comprising the steps of applying the composition to at least one surface of the teeth of the individual. In particular, the oral care composition of this invention can be used in a method of whitening teeth and/or improving oral hygiene of an individual comprising the steps of applying the composition to at least one surface of the teeth of the individual. Preferably, the method is non-therapeutic. The oral care composition of this invention may additionally or alternatively be for used for whitening teeth and/or improving oral hygiene of an individual and/or used in the manufacture of a medicament for whitening teeth and/or improving oral hygiene of an individual. Preferably, the use is non-therapeutic.

Typically, the composition will be packaged. In toothpaste or gel form, the composition may be packaged in a conventional plastic laminate, metal tube or a single compartment dispenser. The same may be applied to dental surfaces by any physical means, such as a toothbrush, fingertip or by an applicator directly to the sensitive area. In liquid mouthwash form the composition may be packaged in a bottle, sachet or other convenient container.

The oral care composition of the invention is preferably a toothpastes or gel. When the oral care composition is a toothpaste or gel, the same typically has a viscosity from about 30,000 to 180,000 centipoise, and preferably, from 60,000 to 170,000 centipoise, and most preferably, from 65,000 to 165,000 centipoise, taken at room temperature (25°C) with a Brookfield Viscometer, Spindle No.93/94 and at a speed of 5 rpm for 1 minute.

The composition can be effective even when used in an individual’s daily oral hygiene routine. For example, the composition may be brushed onto the teeth and/or be rinsed around the inside of the mouth of the individual. The composition may, for example, be contacted with the teeth for a time period of one second to 20 hours. More preferably from 1 s to 10 hours, more preferably still from 10 s to 1 hour and most preferably from 30 s to 5 minutes. The composition may be used daily, for example for use by an individual once, twice or three times per day.

The following examples are provided to facilitate an understanding of the present invention. The examples are not provided to limit the scope of the claims.

Examples

Example 1

This example demonstrated the deposition of pigments. All ingredients are expressed by weight percent of the total formulation and as level of active ingredient.

TABLE 1

a. Dispersion of C.l. 74160 (pigment blue 15:' ) in water/glycerol under the trade name

Cosmenyl Blue A4R from Clariant. b. Commercially available sucrose stearate under the trade name Crodesta™ F160 from

Croda.

Methods

To evaluate tooth whitening efficacy of the samples, the following in vitro test was performed. The WIO index is an index which has been optimized specifically for the evaluation of whiteness in teeth (as described in Journal of Dentistry, volume 36, Supplement 1, 2008, pages 2 to 7). Changes in whiteness was calculated based on L*, a*, b* values which were measured using DigiEye (VeriVide, England).

Sixteen human enamel blocks were used for each sample. The baseline L*, a*, b* of the bovine blocks was measured by DigiEye. The human enamel blocks were pre-soaked in Dl water and then soaked in samples as shown in Table 1 for one hour. Thereafter the human enamel blocks were rinsed three times each time with 20 mL water by hand. Excess water was removed by dabbing the sides of enamel blocks with tissue paper. After this step the L*, a*, b* values of each bovine block were re-measured based on which the changes in WIO values (AWIO) from baseline were calculated and statistically analyzed. Results

The results are reported in Table 2.

TABLE 2

Samples 3 had significantly higher AWIO values compared to other samples (p<0.01).The data indicated that the addition of sucrose stearate in a composition comprising xanthan gum improved its tooth whitening efficacy, indicating much better deposition of the pigment.

Claims

1. An oral care composition comprising:

(a) from 0.01 % to 10% by weight of a deposition polymer;

(b) a sugar fatty acid ester surfactant; and

2. The oral care composition according to claim 1 , wherein the deposition polymer comprises xanthan gum, hyaluronic acid, sodium alginate, pectin, modified starch, gelatin, carrageenan, gellan gum, fenugreek gum, konjac gum, tragacanth gum, karaga gum, g-polyglutamic acid, heparin sodium salt, a copolymer of methyl vinyl ether and maleic anhydride, polyacrylic acid, polystyrene sulfonate, deoxyribonucleic acids, poly(allylamine), locust bean gum, guar gum, polyglycolic acid, polylactic acid, poly(glycolic-co-lactic acid), chitosan, humic acid, phytate acid, or mixtures thereof, preferably xanthan gum, hyaluronic acid, sodium alginate, pectin, modified starch, gelatin, carrageenan, gellan gum, fenugreek gum, konjac gum, tragacanth gum, karaga gum, y-polyglutamic acid, phytate acid, or mixtures thereof.

3. The oral care composition according to claim 1 or claim 2, wherein the deposition polymer comprises xanthan gum.

4. The oral care composition according to any of the preceding claims, wherein the composition comprises the deposition polymer in an amount of from 0.02 to 5% by weight of the composition, preferably from 0.05 to 3%.

5. The oral care composition according to any of the preceding claims, wherein the sugar moiety of the fatty acid ester surfactant is derived from monosaccharide, disaccharide and/or oligosaccharide comprising sucrose, fructose, glucose, methylglucose, rhamnose, fucose, deoxyribose, ribose, trehalose, xylose, mannose, arabinose, galactose, cellobiose, lactose, maltose, isomaltose, melibiose, gentobiose, maltotriose, raffinose, panose or mixtures thereof, preferably sucrose, fructose, glucose, trehalose or mixtures thereof.

6. The oral care composition according to any of the preceding claims, wherein the fatty acid moiety of the sugar fatty acid ester surfactant is a linear or branched, saturated or unsaturated fatty acid having from 6 to 28 carbon atoms, preferably from 8 to 24 carbon atoms, more preferably from 10 to 22 carbon atoms.

7. The oral care composition according to claim 5, wherein the fatty acid moiety of the sugar fatty acid ester surfactant comprises caproic acid, octanoic acid, lauric acid, coconut fatty acid, myristic acid, palmitic acid, stearic acid, behenic acid, arachidic acid, palmitoleic acid, oleic acid, linoleic acid, linolenic acid, arachidonic acid, erucic acid, 2-ethylhexanoic acid, isostearic acid, methyl-branched isostearic acid, 2- octyldodecanoic acid or mixtures thereof, preferably octanoic acid, lauric acid, coconut fatty acid, myristic acid, palmitic acid, stearic acid, arachidic acid, palmitoleic acid, oleic acid, linoleic acid, linolenic acid or mixtures thereof, more preferably lauric acid, coconut fatty acid, myristic acid, palmitic acid, stearic acid, palmitoleic acid, oleic acid or mixtures thereof.

8. The oral care composition according to any of the preceding claims, wherein the sugar fatty acid ester is sucrose fatty acid ester, preferably sucrose fatty acid monoester.

9. The oral care composition according to claim 7, wherein the sucrose fatty acid ester comprises sucrose stearate, sucrose cocoate, sucrose laurate, sucrose palmitate, sucrose myristate, sucrose oleate or mixtures thereof, preferably sucrose stearate

10. The oral care composition according to any of the preceding claims, wherein the composition comprises from 0.01 to 10% by weight of the sugar fatty acid ester surfactant, preferably from 0.1 to 8%.

11. The oral care composition according to any of the preceding claims, wherein the benefit agent is a pigment having a hue angle, h, in the CIELAB system of from 250 to 290 degrees.

12. The oral care composition according to claim 11, wherein the pigment is a blue pigment, preferably a phthalocyanine blue pigment.

13. The oral care composition according to claim 12, wherein the phthalocyanine blue pigment is selected from alpha copper phthalocyanines Pigment Blue 15, Pigment Blue 15:1, Pigment Blue 15:2 and mixtures thereof, preferably Pigment Blue 15:1.

14. The oral care composition according to any of the preceding claims, wherein the benefit agent is an antimicrobial agent, preferably zinc compounds selected from zinc oxide, zinc chloride, zinc acetate, zinc ascorbate, zinc sulphate, zinc nitrate, zinc citrate, zinc lactate, zinc peroxide, zinc fluoride, zinc ammonium sulfate, zinc bromide, zinc iodide, zinc gluconate, zinc tartarate, zinc succinate, zinc formate, zinc phenol sulfonate, zinc salicylate, zinc glycerophosphate and mixtures thereof, more preferably zinc citrate.

15. A method of whitening of an individual comprising the steps of applying the composition according to any of the preceding claims to at least one surface of the teeth of an individual.