WO2022182492A1 - Composite de toiture appliqué par voie liquide - Google Patents

Composite de toiture appliqué par voie liquide Download PDF

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Publication number
WO2022182492A1
WO2022182492A1 PCT/US2022/015094 US2022015094W WO2022182492A1 WO 2022182492 A1 WO2022182492 A1 WO 2022182492A1 US 2022015094 W US2022015094 W US 2022015094W WO 2022182492 A1 WO2022182492 A1 WO 2022182492A1
Authority
WO
WIPO (PCT)
Prior art keywords
textile
membrane
liquid applied
yarns
chemistry
Prior art date
Application number
PCT/US2022/015094
Other languages
English (en)
Inventor
Robert D. Miller
Yunzhang Wang
Randolph S. Kohlman
David W. Martin
Manuel Ramirez
Dennis Goff
Original Assignee
Milliken & Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US17/580,316 external-priority patent/US20220268027A1/en
Application filed by Milliken & Company filed Critical Milliken & Company
Priority to EP22705302.2A priority Critical patent/EP4298139A1/fr
Publication of WO2022182492A1 publication Critical patent/WO2022182492A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C08L75/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/06—Polyurethanes from polyesters
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D11/00—Roof covering, as far as not restricted to features covered by only one of groups E04D1/00 - E04D9/00; Roof covering in ways not provided for by groups E04D1/00 - E04D9/00, e.g. built-up roofs, elevated load-supporting roof coverings
    • E04D11/02—Build-up roofs, i.e. consisting of two or more layers bonded together in situ, at least one of the layers being of watertight composition
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D7/00—Roof covering exclusively consisting of sealing masses applied in situ; Gravelling of flat roofs

Definitions

  • the present invention relates generally to liquid applied roofing composites, more particularly to liquid applied roofing composites containing a textile with a compatibility coating.
  • a textile may be embedded into the membrane for beneficial physical properties. It is desirable to have an improved textile for the roofing system.
  • the invention relates to a liquid applied roofing membrane which contains a textile with a compatibility coating covering essentially all of the fibers of the textile forming a coated textile, a first membrane, and a second membrane.
  • the textile contains a plurality of yarns, the yarns comprising a plurality of fibers.
  • the compatibility coating has a weight of between about 0.5 and 10% of the weight of the textile and contains a first chemistry.
  • the first membrane contains a second chemistry and is located on the first side of the textile, forms the lower surface of the roofing membrane, and covers at least a majority of the second side of the textile.
  • the second membrane contains a third chemistry and is located on the second side of the textile.
  • the second membrane forms the upper surface of the roofing membrane.
  • the first, second, and third chemistries comprise the same class of polymeric material.
  • Figure 1 shows cross-sectional illustration of one embodiment of the liquid applied roofing membrane.
  • Figure 2 shows cross-sectional illustration of another embodiment of the liquid applied roofing membrane where the textile is fully embedded into the first membrane.
  • Figure 3A shows a photograph of the upper surface of the textile of example 4 and Figure 3B is a drawing of the image of Figure 3A.
  • Figure 4A shows a photograph of the upper surface of the textile of example 5 and Figure 4B is a drawing of the image of Figure 4A.
  • Figure 5A shows a photograph of the upper surface of the textile of example 6 and Figure 5B is a drawing of the image of Figure 5A.
  • the present invention generally relates to liquid applied roofing membranes and improved coated textiles that are embedded in and strengthen the membrane.
  • the liquid applied roofing membrane is designed to meet or exceed several FR testing protocols common in the roofing industry.
  • the liquid applied roofing composite 10 contains a textile 100 having a first side and a second side.
  • the textile 100 contains a plurality of yarns and the plurality of yarns contain a plurality of fibers.
  • There is a compatibility coating (also referred to as a capability coating in previous filings) covering at least a portion of the yarns in the textile which forms a coated textile.
  • the compatibility coating has a weight of between about 0.5 and 10% of the weight of the textile 100 and the compatibility coating comprises a first chemistry.
  • the liquid applied roofing membrane 10 also contains a first membrane 200 and a second membrane 300.
  • the first membrane 200 contains a second chemistry, is located on with the first side of the textile 100 and forms the lower surface 10a of the roofing membrane 10.
  • the second membrane 300 contains a third chemistry, is located on the second side of the textile, and forms the upper surface 10b of the roofing membrane 10.
  • the textile 100 is located between the first membrane 200 and the second membrane 300.
  • the textile 100 is at least partially embedded in the first membrane 200 and/or the second membrane 300.
  • the textile 100 is fully embedded into the first membrane 200 or the second membrane 300.
  • the textile 100 may be any suitable textile depending on the end product and desired properties of the end product. The construction, yarns, materials, and other factors can contribute to the characteristics of the textile 100 and the liquid applied roofing membrane 10.
  • the textile 100 may be any suitable knit textile, for example a circular knit, reverse plaited circular knit, double knit, single jersey knit, two- end fleece knit, three-end fleece knit, terry knit or double loop knit, weft inserted warp knit, warp knit, and warp knit.
  • the knit textile is a circular knit textile.
  • the circular knit textile is a double knit textile. It has been found that double knit textiles have good stretch and recovery properties and also low curling.
  • a circular knit textile would typically have an areal weight of between about 3 and 6 oz/yd 2 .
  • Circular knits have a number of characteristics that make them suitable for membrane applications. Circular knit textiles tend to have high stability, the interconnected loops transfer load while minimizing yarns slipping. Circular knit textiles tend to not curl, and many constructions do not have a sidedness (no right or wrong side to the fabric).
  • Circular knit textiles have a tendency to create good cover per weight, demonstrate high elongation (50-80% in machine direction), (80-180% in the cross machine direction), and are flexible with changes in elevation/roof deformities. This flexibility allows for the knit textile to be “distorted” or “contorted” to fit around the roof details (fit around flashing) & penetrations without elastic recovery during the installation process. Circular knit textiles can be designed to have the right combination of openness to allow penetration of liquid applied base coating, but still provide the necessary cover to bridge gaps and roof elevation changes.
  • the knit textile is a warp knit textile which can be any suitable warp knit textile.
  • the warp knit textile is in a tricot stitch pattern.
  • the warp knit textile consists of a set of laid in warp yarns, a set of laid in weft yarns, and a set of stitching yarns.
  • the warp yarns and the weft yarns are not interwoven but are laid on top of one another and the stitching yarns use stitches to connect the warp and weft yarns together.
  • Consists of in this application means “only contains”.
  • this embodiment contains 3 set of yarns (laid in warp, laid in weft, and stitching) and precludes any embodiment with different sets of yarns.
  • the warp knit textile consists of a set of laid in weft yarns and a set of stitching yarns.
  • the knit textile would not contain a set of warp yarns.
  • the stitching yarns are in one embodiment a thicker yarn than what is typically used.
  • the stitching yarns have a denier of at least about 150 denier, more preferably greater than about 200 denier.
  • a warp knit textile would typically have an areal weight of between about 2 and 6 oz/yd 2 .
  • a warp knit allows the introduction of a set of straight warp yarns and/or a set of straight weft yarns which allow the mechanical properties to reflect the yarn properties which typically leads to stiffer fabrics.
  • One benefit of a warp knit textile is that the warp and weft direction mechanical properties can be more independently tailored.
  • the fabric is able to be designed to control tensile in both directions and demonstrate the elongation of the designed yarn.
  • Warp knit textiles may be designed to have the right combination of openness to allow penetration of liquid applied base coating, but still provide the necessary cover (due to the tricot stitch) to bridge gaps and roof elevation changes.
  • Knit textiles are generally preferred because of their stretch and recovery allowing easier application to roofs including parapets and other elements that may be in the roof area where the membrane is being installed.
  • at least about 60% by number of the fibers are within 45 degrees of the plane formed by the membrane, more preferably at least about 75% by number. This means that most of the fibers are laying in the plane of the membrane instead of a more perpendicular orientation to it.
  • fabrics such as nonwovens are used in a liquid applied roofing membrane, the fibers are at many random angles including angles approaching perpendicular to the plane of the roofing membrane. These more perpendicular fibers have a tendency to stick out of the roofing membrane which allows for a path for water to travel through the membrane and reach the roof below. In some cases, these more perpendicular fibers must be removed (by buffing, sanding, and the like) and then in some cases, an additional membrane might need to be applied.
  • the textile is a woven textile.
  • the weave may be, for example, plain, satin, twill, basket-weave, poplin, jacquard, and crepe weaves.
  • the woven textile is a plain weave textile. It has been shown that a plain weave has good abrasion and wear characteristics. A twill weave has been shown to have good properties for compound curves so may also be preferred for some roofing applications.
  • the textile is a nonwoven.
  • the term nonwoven refers to structures incorporating a mass of yarns that are entangled and/or heat fused so as to provide a coordinated structure with a degree of internal coherency.
  • Nonwoven textiles may be formed from many processes such as for example, meltspun processes, hydroentangeling processes, mechanically entangled processes, stitch-bonded and the like.
  • the textile is a unidirectional textile and may have overlapping yarns or may have gaps between the yarns.
  • the nonwoven may contain warp and/or weft yarns stitched, embedded, adhered or otherwise attached to the nonwoven fibers.
  • the textile in the liquid applied roofing membrane has a first surface and a second surface and a thickness defined as the distance between the first surface and the second surface.
  • the textile contains a plurality of yarns crossing each other such that the plurality of yarns forms a plurality of aperture regions. These aperture regions are defined as areas of the textile where there are no yarns present between the first and second surfaces. This means that if you look at the textile from the first or second surface, the aperture regions would be holes where there are no yarns. These holes are bounded by the yarns and if a stray fiber or two lies within the aperture region, this does not affect the boundaries of the aperture region.
  • the aperture regions of the textile comprise between about 4 and 18 % of the surface area measured along the first surface of the textile.
  • at least 90% by number of the aperture regions with aperture size larger than 0.01 mm 2 have an aperture area of less than about 0.29 mm 2 . The description of how average aperture area and percentage of the surface area are described in the example section of the application.
  • the aperture regions of the textile form between about 5 and 18% of the surface area along the first surface of the textile. In another embodiment, the aperture regions of the textile form between about 5 and 16%, more preferably about 8 and 15 % of the surface area along the first surface of the textile. In another embodiment, the aperture regions of the textile form between about 2 and 40 % of the surface area along the first surface of the textile. In another embodiment, at least 90% by number of the aperture regions with aperture size larger than 0.01 mm 2 have an aperture area of less than about 0.28 mm 2 . In another embodiment, at least 90% by number of the aperture regions with aperture size larger than 0.01 mm 2 have an aperture area of less than about 0.24 mm 2 .
  • aperture regions having an area of less than about 0.01 mm 2 added together make up less than about 40% of the total aperture region area. More preferably, aperture regions having an area of less than about 0.01 mm 2 added together make up less than about 10% of the total aperture region area.
  • a compatibility coating covers at least a portion of the yarns in the textile 100.
  • the coating is applied using a dip-type method where the textile is immersed into the coating while the coating is liquid. This allows the coating to coat essentially all of the surface area of the yarns. “Essentially all” in this use means that at least 95% of the surface area of the yarns in the textile are coated.
  • the coating enters the yarns and coats at least a portion of the fibers within the yarns. In one embodiment essentially all of the surface area of the fibers is coated with the compatibility coating.
  • the textile 100 is coated with the compatibility coating, it is referred to herein as the coated textile.
  • This compatibility coating serves to better bond the textile 100 to the first and the second membranes 200, 300, gives an amount of rigidity to the textile 100 so that it can more easily be handled and installed, and allow for the easier and quicker wet out of the textile 100 by the membranes 200, 300 which are applied as a liquid.
  • the compatibility coating has a weight of between about 0.5 and 10% of the weight of the textile 100, more preferably between about 1.5 and 3.5% of the weight of the textile 100. In another embodiment, the compatibility coating has a weight of between about 0.1 and 20% of the weight of the textile 100. In another embodiment, the compatibility coating has a weight of at least about 0.5% of the weight of the textile 100. In another embodiment, the compatibility coating has a weight of less than about 8% of the weight of the textile 100. In another embodiment, the compatibility coating has a weight of between about 0.5 and 3.5% of the weight of the textile 100.
  • the compatibility coating contains a first chemistry. Because the goal is for the compatibility coating to help better adhere and wet out with the membranes, the first chemistry preferably contains the same class of polymeric material as the second chemistry and the third chemistry (which the first and second membranes 200, 300 contain, respectively). “Same class of polymeric material”, in this application, means that the two polymeric materials share a common backbone unit in the backbone of the polymeric material (they can have additional backbone units not common to both materials or branches also not common to both materials). Preferably, the first, second, and third chemistries contain almost exclusively polyurethane polymers or pre-polymer segments covalently linked by carbamate and/or urea functional groups.
  • Polyurethanes are a versatile class of materials. They have broad applications in numerous industries, such as foam and cushions, automotive interiors, films, floorcovering, etc. In this specific application the polyurethane polymers have high elongation and tensile strength, ideal properties for a roofing membrane. These class of materials are classically formed by the reaction of multifunctional isocyanates with polyhydritic alcohols. However, the reaction kinetic, polymeric architecture, and physical properties are all highly tunable through nuanced control of the system.
  • this class of material for the compatibility coating imbues the textile with a desirable modulus/stiffness. These characteristics help the textile lay down compliantly into the liquid application of the first membrane and minimizes wrinkling. These are features that simplify installation and reduces reworking, ultimately reducing time up on a roof.
  • matching the class of material for the compatibility coating to that of the second and third chemistry of the membranes, in this case polyurethane facilitates a rapid and more complete wetting of the textile in the liquid application of the first and second membranes. This enhanced interaction maximizes the bonding of the textile with each membrane at their respective interfaces to give a stronger composite.
  • the first, second, and third chemistries comprise polyacrylate. In another embodiment, the first, second, and third chemistries comprise polymethyl-methacrylate. In another embodiment, the first, second, and third chemistries comprise bitumen. In one preferred embodiment, the second and third chemistries comprise the same material, more preferably they consist of the same material (meaning that the second and third chemistries are exactly the same). [0029] In the embodiments where the first chemistry is a polymer, the polymer preferably has a high 100% modulus and a low elongation at break. Preferably the 100% modulus is higher than about 5 MPa, more preferably higher than about 10 MPa, even more preferably higher than about 20 MPa.
  • the elongation at break is preferably less than about 500%, more preferably less than about 250%, even more preferably less than about 200%, even more preferably less than about 150%.
  • the 100% modulus and elongation at break are typically tested according to ASTM D412.
  • the high 100% modulus and low elongation at break properties of the polymer allow the coated knit fabric to stiffen up, providing more dimensional stability and having a lower propensity to wrinkle, and thus easier to apply and work into second chemistry.
  • the yarns making up the textile 100 may be any suitable yarn.
  • “Yarn”, in this application, as used herein includes a monofilament elongated body, a multifilament elongated body, ribbon, strip, fiber, tape, and the like.
  • the term yarn includes a plurality of any one or combination of the above.
  • the yarns may be of any suitable form such as spun staple yarn, monofilament, or multifilament, single component, bi-component, or multi-component, continuous filament and have any suitable cross-section shape such as circular, multi-lobal, square or rectangular (tape), and oval. Most of the yarns described contain fibers (and some of the embodiments described above as yarns may also be described as fibers).
  • the yarns of the textile 100 contain polyester fibers.
  • the textile 100 contains at least about 40% by weight, more preferably at least about 50% by weight, more preferably at least about 70% by weight polyester fibers.
  • the textile 100 contains at least about 90% by weight, more preferably at least about 95% by weight.
  • the textile comprises essentially all polyester fibers, defined as being at least 98% by weight of the total textile.
  • the textile 100 can be formed from a single plurality or type of yarn (e.g., the fabric can be formed solely from polyester yarns), or the textile can be formed from several pluralities or different types of yarns (e.g., the fabric can be formed from a first plurality of polyester yarns a second plurality of aramid yarns).
  • the finished liquid applied roofing membrane may have some fire resistance (FR) characteristics.
  • FR fire resistance
  • One way to tailor the FR properties is through the addition of FR fibers and/or yarns. These FR yarns can contain just FR fibers, or blends of FR and other fibers.
  • the term “inherent flame resistant fibers” refers to synthetic fibers which, due to the chemical composition of the material from which they are made, exhibit flame resistance without the need for an additional flame retardant treatment.
  • the inherent flame resistant fibers can be any suitable inherent flame resistant fibers, such as polyoxadiazole fibers, polysulfonamide fibers, poly(benzimidazole) fibers, poly(phenylenesulfide) fibers, meta-aramid fibers, para-aramid fibers, polypyridobisimidazole fibers, fiberglass fibers, basalt fibers, fiberglass wrapped with polyester fibers, polybenzylthiazole fibers, polybenzyloxazole fibers, melamine- formaldehyde polymer fibers, phenol-formaldehyde polymer fibers, oxidized polyacrylonitrile fibers, polyamide-imide fibers and combinations, mixtures, or blends thereof.
  • suitable inherent flame resistant fibers such as polyoxadiazole fibers, polysulfonamide fibers, poly(benzimidazole) fibers, poly(phenylenesulfide) fibers, meta-aramid fibers, para-aramid fibers, polypyridobisimidazo
  • the inherent flame resistant fibers are preferably selected from the group consisting of polyoxadiazole fibers, polysulfonamide fibers, poly(benzimidazole) fibers, poly(phenylenesulfide) fibers, meta-aramid fibers, para- aramid fibers, and combinations, mixtures, or blends thereof. Fibers that are treated to have FR properties such as FR cellulose may also be used.
  • the flame resistant fibers can be present in the textile in any suitable amount. Generally, the amount of inherent flame resistant fibers included in the textile will depend upon the desired properties of the final textile. In certain embodiments, the inherent flame resistant fibers can comprise about 50% or less, about 40% or less, about 30% or less, about 25% or less, about 15% or less, or about 10% or less, by weight, of the fibers present in the textile. In certain embodiments, the flame resistant fibers can comprise about 1% to about 50%, about 5% to about 40%, about 10% to about 30, by weight, of the fibers present in the textile. [0035] The liquid applied roofing composite 10 is preferably attached to a roof deck or built-up roof deck (or other structure).
  • the first membrane is applied to a prepared roof (which can have insulation, evening layers, plywood, or even another roofing membrane) in a liquid state. While the first membrane is still in liquid form, the coated textile is laid down onto the first membrane. The coated textile may wet out on its own or may need additional mechanical forces to push the coated textile into the first membrane. After the first membrane is solidified (at least partially cured), the second membrane is applied on top of the partially cured first membrane and the whole system is cured into the liquid applied roofing membrane. Additional layers may optionally be applied on top of the membrane 10 for additional sun reflection, abrasion resistance, or other properties.
  • a roof deck is generally described as a construction member or system comprising one or more essentially planar elements of, but not limited to steel, aluminum, concrete, wood, gypsum, composites, or other rigid or semi-rigid materials and which may form or rest upon one or more structural construction members, and which serves either as a complete roofing system or, more typically, as a base onto which additional roofing elements are added or built up.
  • a microscope capable of capturing images at least 50X magnification was used with a background that creates substantial contrast with fabric. If the fabric is white, a dark background will suffice. If the fabric is black, a white background will be acceptable. Otherwise a colored background may be required to provide contrast.
  • At least five images of the fabric are captured from five locations spanning width of fabric. Either manually or by using digital image analysis tools, the pixels of the image are marked that represent the background (the aperture areas) that can be clearly viewed through the fabric. For a fabric with multiple planes of yarns, the aperture area may be defined by yarns in different planes of the fabric. Whether a complete aperture is within the image or not, the area of the apertures is included in the measurement of % openness.
  • the % openness is included in the measurement of the % openness.
  • the number of pixels that represent the open area are measured.
  • the number of pixels that represent the open area divided by the total number of pixels in the image, multiplied by 100 is the percent openness. This represents the percentage of the surface area of the textile that is formed from the aperture areas.
  • At least five images of fabric from five locations spanning width of fabric are captured. Either manually or by using image analysis software, the area that represents the open space bounded by yarns or fibers of the fabric (aperture area) is marked and measured.
  • the apertures may be defined by yarns in different planes of the fabric.
  • An individual aperture that is not fully within the captured image is not included in the characterization of the aperture size distribution, since it would only represent part of the aperture area.
  • the image should be calibrated with a length scale so the area can be calculated. Multiple areas (aperture areas) may and likely will be available to be marked within an image. The area of each marked aperture is determined.
  • the distribution of aperture areas larger than a reference level of 0.01 mm 2 are characterized for each fabric. The measurements for the examples in this application were made using a Keyence VHX6000 microscope.
  • a polyester double-knit fabric was produced on a 30” diameter machine. 100 denier yarns were arranged as Dial and Cylinder on a 16 needle repeat rib-twill design. The fabric was knitted with 30 courses per inch alternating 3/1 Cylinder-Dial for a 1 1 ⁇ 2 Dial late and 24 Wales per inch.
  • the fabric was coated with an anionic polyurethane dispersion using a padding (dip/nip) process.
  • the polyurethane chemistry was a polycarbonate polyurethane. It contained approximately 35% non-volatile content and had a pH value of 8.5.
  • the dried film of the polyurethane had a 100% modulus value of 20-25 MPa and elongation at break value of 150-200%.
  • the fabric was first immersed in a chemical bath containing a 10% aqueous dilution by weight of the polyurethane dispersion. After fully saturated, the fabric was then passed through a set of squeeze rolls at 40 psi pressure and then dried in a forced air oven at 380 to 410°F under tension and support from tenter chains. The wet pickup of the polyurethane dispersion was approximately 70%. The following measurements were obtained for the fabric: a. Weight: 3.45 oz/yd 2 b. Thickness: 20.4 mils c. Air Perm @125 Pa: 450 cfm d. Grab Tensile i.
  • Machine Direction Peak Load: 86.6 Lb; Elongation at peak load: 55.9%; Stiffness: -33.8 Lb/in ii.
  • Cross-Machine Direction Peak Load: 59.5 Lb; Elongation at peak load: 124.5%; Stiffness: -25.9 Lb/in
  • a polyester double-knit fabric was produced on a 30” diameter machine. 200 denier yarns were arranged as Dial and Cylinder on a repeat rib-twill design. The fabric was knitted with 30 courses per inch alternating Cylinder-Dial for a 1 1 ⁇ 2 Dial late and 24 Wales per inch.
  • the fabric was coated with an anionic polyurethane dispersion using a padding (dip/nip) process.
  • the polyurethane chemistry was a fire-retardant urethane co polymer with a stiff hand. It contained approximately 36% non-volatile content and had a pH value of 7.0.
  • the fabric was first immersed in a chemical bath containing a 10% aqueous dilution by weight of the polyurethane dispersion. After fully saturated, the fabric was then passed through a set of squeeze rolls at 40 psi pressure and then dried in a forced air oven at 380 to 410°F under tension and support from tenter chains. The wet pickup of the polyurethane dispersion was approximately 70%. The following measurements were obtained for the fabric: a. Weight: 5.7 oz/yd2 b. Thickness: 21.5 mils c. Air Perm 720 cfm d. Grab Tensile i.
  • Machine Direction Peak Load: 148.8 Lb; Elongation at peak load: 33.1%; Stiffness: ⁇ 56 Lb/in ii.
  • Cross-Machine Direction Peak Load: 73.2 Lb; Elongation at peak load: 165.7%; Stiffness: ⁇ 20 Lb/in
  • a weft-insertion, warp-knit fabric was produced on a Raschel warp-knitting machine.
  • Stitch yarns are a 2-ply 100 denier textured polyester, forming a tricot stitch at a density of 22 stitches per inch.
  • Weft construction density was 22 per inch; with a 2-ply 150 denier textured polyester designed to have specific strength and stretch properties.
  • the fabric was coated with an anionic polyurethane dispersion using a padding (dip/nip) process.
  • the polyurethane chemistry was a fire-retardant urethane co polymer with a stiff hand. It contained approximately 36% non-volatile content and had a pH value of 7.0.
  • To apply the coating the fabric was first immersed in a chemical bath containing a 10% aqueous dilution by weight of the polyurethane dispersion. After fully saturated, the fabric was then passed through a set of squeeze rolls at 40 psi pressure and then dried in a forced air oven at 380 to 410°F under tension and support from tenter chains.
  • the wet pickup of the polyurethane dispersion was approximately 70%.
  • the following measurements were obtained for the fabric: a. Weight: 3.45 oz/yd 2 b. Thickness: 16.3 mils c. Air Perm @ 125 Pa: 1000 cfm d. Grab Tensile i. Machine Direction: Peak Load: 96.5 Lb; Elongation at peak load: 21.5%; Stiffness: ⁇ 114.6 Lb/in ii. Cross Machine Direction: Peak Load: 87.4 Lb; Elongation at peak load: 36.6%; Stiffness: -50.4 Lb/in
  • a circular knit fabric was produced on a 30-inch knitting machine.
  • Machine gauge is 24 needles per inch.
  • the fabric can be identified as an 24 x 43 double Rib Knit.
  • the feeder yarn is a 1 ply 70 denier textured polyester with air entanglement nodes to bind the two cylinder and dial needles creating a double circular knit.
  • the feed rate of the stitching yarn is specifically controlled to achieve a low level of tension, so as to increase the crimp and elongation in the fabric,
  • the needles are set up in a 4 repeat and 2 dial late timing and 2,304 total needles.
  • the fabric was coated with an anionic polyurethane dispersion using a padding (dip/nip) process.
  • the polyurethane chemistry was a polycarbonate polyurethane. It contained approximately 35% non-volatile content and had a pH value of 8.5.
  • the dried film of the polyurethane had a 100% modulus value of 20-25 MPa and elongation at break value of 150-200%.
  • the fabric was first immersed in a chemical bath containing a 10% aqueous dilution by weight of the polyurethane dispersion. After fully saturated, the fabric was then passed through a set of squeeze rolls at 40 psi pressure and then dried in a forced air oven at 380°F under tension and support from tenter chains. The wet pickup of the polyurethane dispersion was approximately 70%. The following measurements were obtained for the fabric: a. Weight: about 3.9 oz/yd 2 b. Openness: 0.9% c. Greater than 90% by number of the aperture areas larger than 0.01 mm 2 are less than 0.05 mm 2
  • FIG. 3A An image of the representative section of the fabric is as Figure 3A and Figure 3B shows a drawing of Figure 3A. Due to low openness and/or small aperture area, failures due to air entrapment are predicted if this fabric was coated with liquid membrane materials.
  • a weft-insertion, warp-knit fabric was produced on a Raschel warp-knitting machine.
  • Stitch yarns are a 2-ply 100 denier textured polyester, forming a tricot stitch at a density of 22 stitches per inch.
  • Weft construction density was 22 per inch; with a 2-ply 150 denier textured polyester designed to have specific strength and stretch properties.
  • the fabric was coated with an anionic polyurethane dispersion using a padding (dip/nip) process.
  • the polyurethane chemistry was a fire-retardant urethane co polymer with a stiff hand. It contained approximately 36% non-volatile content and had a pH value of 7.0.
  • the fabric was first immersed in a chemical bath containing a 10% aqueous dilution by weight of the polyurethane dispersion. After fully saturated, the fabric was then passed through a set of squeeze rolls at 40 psi pressure and then dried in a pin tenter oven set at a width of 15% less than the incoming fabric width and overfed 10% in the machine direction to allow for a controlled shrinkage rate in the length and the width.
  • the tenter oven temperature was set at 400F.
  • the wet pickup of the polyurethane dispersion was approximately 70%.
  • the following measurements were obtained for the fabric: a. Weight: about 3.5 oz/yd 2 b. Openness: 31% c. Greater than 90% by number of aperture areas larger than 0.01 mm 2 are less than 0.465 mm 2
  • FIG. 4A An image of the representative section of the fabric is as Figure 4A and Figure 4B shows a drawing of Figure 4A. Due to high openness and/or large aperture area, failures due to pin-holing are predicted if this fabric was coated with liquid membrane materials.
  • a weft insertion, warp knit fabric was produced on a warp knitting machine with a weft insertion device.
  • Machine gauge is 18 needles per inch, and the fabric produced is 18 gauge. Stitches are formed at 22 per inch, and during each stitch formation, a weft yarn is inserted.
  • the fabric can be identified as an 18 x 22.
  • the stitching yarn is a 2 ply 150 denier textured polyester with air entanglement nodes to bind the 2 plies. This stitching yarn is used to form an open tricot stitch at a density of 22 stitches per inch.
  • the feed rate of the stitching yarn is specifically controlled to achieve a desired level of tension, so as to not “stretch” the crimp from the yarn.
  • the weft yarn is the same 2 ply 150 denier textured polyester with air entanglement to bind the 2 plies.
  • the weft yarn is laid into the fabric, one yarn per stitch, for a final density of 22 per inch.
  • the fabric was coated with an anionic polyurethane dispersion using a padding (dip/nip) process.
  • the polyurethane chemistry was a fire-retardant urethane co polymer with a stiff hand. It contained approximately 36% non-volatile content and had a pH value of 7.0.
  • the fabric was first immersed in a chemical bath containing a 7% aqueous dilution by weight of the polyurethane dispersion. After fully saturated, the fabric was then passed through a set of squeeze rolls at 40 psi pressure and then dried in a pin tenter oven set at a width of 15% less than the incoming fabric width and overfed 15% in the machine direction to allow for a controlled shrinkage rate in the length and the width.
  • the tenter oven temperature was set at 385F.
  • the wet pickup of the polyurethane dispersion was approximately 85%.
  • the following measurements were obtained for the fabric: a. Weight: about 5.7 oz/yd 2 b. Openness: 13% c. Greater than 90% by number of aperture areas greater than 0.01 mm 2 are less than 0.18 mm 2
  • FIG. 5A An image of the representative section of the fabric is as Figure 5A and Figure 5B shows a drawing of Figure 5A. Thanks to the right combinations of openness and aperture area, no air entrapment or pin-holing are predicted to be observed if this fabric was coated with liquid membrane materials.

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
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Abstract

L'invention concerne une membrane de toiture appliquée par voie liquide qui contient un textile pourvu d'un revêtement de compatibilité recouvrant essentiellement toutes les fibres du textile formant un textile enduit, une première membrane et une seconde membrane. Le textile contient une pluralité de fils qui comprennent une pluralité de fibres. Le revêtement de compatibilité présente un poids compris entre environ 0,5 et 10 % du poids du textile et contient une première composition chimique. La première membrane contient une deuxième composition chimique et est située sur le premier côté du textile, forme la surface inférieure de la membrane de toiture, et recouvre au moins une majorité du second côté du textile. La seconde membrane contient une troisième composition chimique et est située sur le deuxième côté du textile. Les première, deuxième et troisième compositions chimiques comprennent la même classe de matériau polymère.
PCT/US2022/015094 2021-02-25 2022-02-03 Composite de toiture appliqué par voie liquide WO2022182492A1 (fr)

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EP22705302.2A EP4298139A1 (fr) 2021-02-25 2022-02-03 Composite de toiture appliqué par voie liquide

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US202163153737P 2021-02-25 2021-02-25
US63/153,737 2021-02-25
US17/580,316 2022-01-20
US17/580,316 US20220268027A1 (en) 2021-02-25 2022-01-20 Liquid applied roofing composite

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Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4472086A (en) * 1981-02-26 1984-09-18 Burlington Industries Inc. Geotextile fabric construction
EP0145687A2 (fr) * 1983-12-09 1985-06-19 AB Mataki Etoffe non-tissée, feuille bitumineuse d'imperméabilisation à l'eau formée sur cette étoffe, et emploi de l'étoffe comme support d'une telle feuille
US20030017771A1 (en) * 1996-12-17 2003-01-23 Jurgen Kassner Textile lattice for reinforcing bitumen-bonded layers
US20100291827A1 (en) * 2008-07-30 2010-11-18 Johns Manville Base interlining and coated roofing membranes
WO2014122153A1 (fr) * 2013-02-08 2014-08-14 Sika Technology Ag Synthèse de polymères de polyuréthane par chimie click de couplage azide-alcyne catalysée par le cuivre pour revêtements, adhésifs, matériaux d'étanchéité et applications élastomères
EP2966103A1 (fr) * 2014-07-09 2016-01-13 Sika Technology AG Membrane d'imperméabilisation à application de liquide pour des toits
US20170081560A1 (en) * 2015-09-22 2017-03-23 Ronald SW Knighton Flexible sheet with hard particulate
KR101834521B1 (ko) * 2017-11-09 2018-03-05 주식회사 유니온건설공사 유리섬유 메쉬망을 이용한 바닥면 방수공법
EP3483353A1 (fr) * 2017-11-09 2019-05-15 Milliken & Company Membrane de toiture composite résistant au feu
WO2019185459A1 (fr) * 2018-03-29 2019-10-03 Sika Technology Ag Procédé pour la production d'une membrane d'imperméabilisation bitumineuse préformée
WO2022039894A1 (fr) * 2020-08-18 2022-02-24 Milliken & Company Composite de toiture appliqué par voie liquide

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4472086A (en) * 1981-02-26 1984-09-18 Burlington Industries Inc. Geotextile fabric construction
EP0145687A2 (fr) * 1983-12-09 1985-06-19 AB Mataki Etoffe non-tissée, feuille bitumineuse d'imperméabilisation à l'eau formée sur cette étoffe, et emploi de l'étoffe comme support d'une telle feuille
US20030017771A1 (en) * 1996-12-17 2003-01-23 Jurgen Kassner Textile lattice for reinforcing bitumen-bonded layers
US20100291827A1 (en) * 2008-07-30 2010-11-18 Johns Manville Base interlining and coated roofing membranes
WO2014122153A1 (fr) * 2013-02-08 2014-08-14 Sika Technology Ag Synthèse de polymères de polyuréthane par chimie click de couplage azide-alcyne catalysée par le cuivre pour revêtements, adhésifs, matériaux d'étanchéité et applications élastomères
EP2966103A1 (fr) * 2014-07-09 2016-01-13 Sika Technology AG Membrane d'imperméabilisation à application de liquide pour des toits
US20170081560A1 (en) * 2015-09-22 2017-03-23 Ronald SW Knighton Flexible sheet with hard particulate
KR101834521B1 (ko) * 2017-11-09 2018-03-05 주식회사 유니온건설공사 유리섬유 메쉬망을 이용한 바닥면 방수공법
EP3483353A1 (fr) * 2017-11-09 2019-05-15 Milliken & Company Membrane de toiture composite résistant au feu
WO2019185459A1 (fr) * 2018-03-29 2019-10-03 Sika Technology Ag Procédé pour la production d'une membrane d'imperméabilisation bitumineuse préformée
WO2022039894A1 (fr) * 2020-08-18 2022-02-24 Milliken & Company Composite de toiture appliqué par voie liquide

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