WO2022179177A1 - Inline printing-based eco-friendly holographic laser positioning packaging material and manufacturing method therefor - Google Patents

Inline printing-based eco-friendly holographic laser positioning packaging material and manufacturing method therefor Download PDF

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Publication number
WO2022179177A1
WO2022179177A1 PCT/CN2021/129293 CN2021129293W WO2022179177A1 WO 2022179177 A1 WO2022179177 A1 WO 2022179177A1 CN 2021129293 W CN2021129293 W CN 2021129293W WO 2022179177 A1 WO2022179177 A1 WO 2022179177A1
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WIPO (PCT)
Prior art keywords
layer
packaging material
laser
microcapsules
printing
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PCT/CN2021/129293
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French (fr)
Chinese (zh)
Inventor
朱立纲
陈洋
刘伟
喻方清
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上海紫江喷铝环保材料有限公司
安徽紫江喷铝环保材料有限公司
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Publication of WO2022179177A1 publication Critical patent/WO2022179177A1/en

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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10Packing paper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00Inking and printing with a printer's forme
    • B41M1/26Printing on other surfaces than ordinary paper
    • B41M1/28Printing on other surfaces than ordinary paper on metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/0027After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using protective coatings or layers by lamination or by fusion of the coatings or layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/009After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using thermal means, e.g. infrared radiation, heat
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22Addition to the formed paper
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W90/00Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
    • Y02W90/10Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics

Definitions

  • the present application relates to the field of product packaging, in particular to an environmentally friendly holographic laser positioning packaging material printed in line and a manufacturing method thereof.
  • Packaging materials refer to the materials used in the manufacture of packaging containers, packaging and decoration, packaging printing, packaging and transportation, etc. to meet product packaging requirements, including metal, plastic, glass, ceramics, paper, bamboo, wild mushrooms, natural fibers, Main packaging materials such as chemical fibers and composite materials, as well as auxiliary materials such as coatings, adhesives, strapping tapes, decoration, and printing materials.
  • the Chinese patent with the publication number CN104129566A discloses a packaging material, which relates to the field of packaging materials. Airbags are provided, and the surface connecting the flame-retardant layer and the cardboard layer is provided with patterns. This packaging material has strong flame retardancy, good cushioning and excellent sterilization performance.
  • the present application provides an environmentally friendly holographic laser positioning packaging material printed in-line and a manufacturing method thereof.
  • the application provides an environmentally friendly holographic laser positioning packaging material for in-line printing, using the following technical solutions:
  • An in-line printed environmentally friendly holographic laser positioning packaging material comprising a backing paper, a degradable material layer is arranged on the surface of the backing paper, a degradation cavity is arranged between the backing paper and the degradation material layer, and the degradation cavity is A microcapsule is arranged in the cavity, and a degrading preparation for catalyzing the degradation of the degradable material layer is arranged in the microcapsule.
  • the degradable material layer can be easily degraded while improving the mechanical strength of the backing paper.
  • the microorganisms and bacteria in the soil will degrade the degradable material layer, causing it to decompose and be directly absorbed by the soil.
  • the microcapsules arranged in the degradation cavity and the degradable preparations in the microcapsules can increase the degradable preparations required by the degradable materials when the packaging materials are buried in the soil, thereby promoting the packaging materials.
  • the degradation of the material enables the degradation of the soil without the bacteria required for the degradation of the degrading material.
  • the base paper is white cardboard, coated paper or kraft paper.
  • the degradable material layer is a polylactic acid layer
  • the degradable preparation includes Rhizopus sp. lipase.
  • polylactic acid is a new type of biodegradable material, which can be completely degraded by microorganisms in nature after use, and finally generates carbon dioxide and water, which does not pollute the environment, which is very beneficial to protecting the environment and is recognized as an environmentally friendly material.
  • Rhizopus lipase is the enzyme with the best degradation effect, thereby improving the degradation efficiency of packaging materials;
  • polylactic acid has good mechanical and physical properties, and has good Therefore, its coating on the surface of the bottom paper can improve the strength of the packaging material and improve the antibacterial and antifungal properties of the packaging material.
  • the degradation preparation (121) further comprises amylase and cellulase.
  • Amylase can promote the degradation and decomposition of starch adhesive used in microcapsules, while cellulase can promote the degradation of the bottom paper and improve the degradation rate of other parts of the packaging material.
  • the wall material of the microcapsules (12) is sodium alginate.
  • the surface of the base paper is provided with embedded grooves along its length direction, and the microcapsules are embedded in the embedded grooves.
  • the enzyme preparation since the enzyme preparation has a certain biological activity, its structure will be destroyed and its activity will be lost after extrusion, so the enzyme preparation needs to be effectively protected, and the bottom paper will be under pressure during use. Therefore, embedding the microcapsules in the embedded grooves can effectively protect the microcapsules and prevent the microcapsules from being broken by pressure during use, thereby effectively protecting the microcapsules and the enzyme preparation inside the microcapsules.
  • an aluminum layer is provided on the surface of the degradable material layer, and a laser information layer is provided on the surface of the aluminum layer away from the degradable material layer.
  • the aluminum layer formed on the surface of the degradable material layer by vacuum evaporation can make the packaging material have metallic luster, and the aluminum layer can be plated on the degradable material layer by the transfer method of aluminum plating;
  • the laser information layer can generate radiant laser patterns and laser characters, and at the same time can improve the anti-counterfeiting effect of packaging materials.
  • a positioning pattern is provided on the surface of the laser information layer, and a printing layer is provided on the surface of the laser information layer away from the aluminum layer.
  • the setting of the positioning pattern facilitates the production of positioning marks on the surface of the laser information layer that are required in the process of in-line printing.
  • various colors of packaging are printed on the surface of the laser information layer by register printing. Patterns, thereby improving the style of packaging materials, easy to attract the attention of customers.
  • a surface treatment layer is provided on the surface of the printing layer away from the laser information layer.
  • the provision of the surface treatment layer improves the properties of the surface of the packaging material, so that the surface of the packaging material is wear-resistant, non-fading, water-repellent, and oil-repellent, and has a better tactile feel during use.
  • the surface treatment layer (6) is varnish or flocking.
  • the present application provides a method for making an environmentally friendly holographic laser positioning packaging material applied to in-line printing, using the following technical solutions:
  • a production method of an environmentally-friendly holographic laser positioning packaging material printed in line comprising:
  • a degradable material layer is formed on the surface of the bottom paper by lamination.
  • it also includes:
  • Laser molding is performed on the surface of the aluminum layer to form a laser pattern and position the cursor
  • the printed layer is formed by continuous register printing on the surface of the aluminum layer based on the positioning cursor;
  • Surface treatment is performed on the surface of the printing layer to form a surface treatment layer.
  • microcapsules with degradable preparations are added on the surface of the base paper, and a degradable material layer to improve the strength of the base paper is formed on the surfaces of the base paper and the microcapsules, and the packaging materials can be directly buried in the soil after they are discarded.
  • the degradable material layer can be rapidly degraded to generate substances that are harmless to the soil environment, thereby improving the degradation performance of the packaging material;
  • the surface of the degradable material is aluminized and formed by laser molding The surface has a brilliant metallic luster, and at the same time, the printing layer can be printed as required by positioning the cursor, which can add the pattern effect of the packaging material; finally, the finished product of the packaging material is formed through surface treatment, so that the surface of the packaging material has a better texture, making the packaging material
  • the material is wear-resistant, non-fading, water-repellent and oil-repellent, which improves the quality of packaging materials.
  • the embedding and fixing the degradable preparation on the surface of the bottom paper include:
  • the degradable preparation is fixed in water-soluble microcapsules by the method of microencapsulation
  • An embedded groove is set on the surface of the bottom paper, and the microcapsules are evenly sprinkled on the surface of the bottom paper; and,
  • the surface of the degradable material layer needs to be molded during the aluminizing process to form the laser information layer, if the microcapsules are attached to the surface of the base paper, there will inevitably be a gap between the degradable material layer and the base paper.
  • the microcapsules will be broken under pressure extrusion, resulting in the inactivation of the enzyme preparations in the microcapsules; and the embedded grooves on the surface of the bottom paper can embed the microcapsules therein, so as to accommodate the microcapsules , to prevent the microcapsules from breaking.
  • the fixing the microcapsules in the embedded grooves includes:
  • the backing paper is rapidly heated to solidify the starch solution to hold the microcapsules in place.
  • the starch solution will be gelatinized at high temperature and transformed into a colloid.
  • the gelatinized starch solution has a relatively large viscosity, and the microcapsules can be glued and fixed in the embedded groove after cooling and solidification. , and the starch solution will not pollute the environment, and can be rapidly degraded after use, and will not pollute the environment.
  • forming an aluminum layer by plating aluminum on the surface of the degradable material layer includes:
  • the PET film or laser PET film is placed on the glued horse paper or cardboard for compounding, and then the PET film is peeled off.
  • the PET film can be used repeatedly, and the aluminum molecular layer is transferred to the degradable material layer through the adhesive effect. Thereby, an aluminum layer is formed.
  • performing laser molding on the surface of the aluminum layer to form a laser pattern and positioning the cursor includes:
  • the continuous register printing on the surface of the aluminum layer based on the positioning cursor to form the printing layer includes:
  • Continuous registration printing is performed according to the position of the positioning cursor extruded by the laser die, and the promotional pattern of the packaging material is printed on the surface of the aluminum layer.
  • the surface treatment includes varnish or flocking.
  • varnish or flocking on the surface of the printing layer can form a protective layer on the surface of the printing layer, so that the surface of the packaging material is wear-resistant, non-fading, water-repellent, and oil-repellent. Has a better tactile feel.
  • the present application includes at least one of the following beneficial technical effects:
  • Fig. 1 is the structural representation of the environmental protection holographic laser positioning packaging material of a kind of in-line printing according to the embodiment of the present application;
  • Fig. 2 is the enlarged schematic diagram of the structure at A place in Fig. 1;
  • FIG. 3 is a flow chart of a method for producing an environmentally-friendly holographic laser positioning packaging material printed in-line in an embodiment of the present application
  • FIG. 4 is a flow chart of sub-steps of step S100 in the embodiment of the present application.
  • FIG. 5 is a flowchart of sub-steps of step S130 in the embodiment of the present application.
  • the embodiment of the present application discloses an environmentally friendly holographic laser positioning packaging material printed in line.
  • the environmentally-friendly holographic laser positioning packaging material printed in line includes a backing paper 1, and the backing paper 1 can be one of white cardboard, coated paper or kraft paper.
  • a degradable material layer 2 is formed on the surface of the base paper 1 by coating, and the degradable material layer 2 is a polylactic acid layer.
  • the polylactic acid can naturally degrade in the environment while improving the tensile strength of the backing paper 1, thereby improving the degradability of the packaging material.
  • the surface of the backing paper 1 is provided with embedded grooves 11 along its length direction, and a degradation cavity is formed between the embedded groove 11 and the degradable material layer 2 .
  • the microcapsules 12 are glued and fixed in the degradation cavity, the microcapsules 12 are embedded in the embedded grooves 11, and the wall material of the microcapsules 12 is sodium alginate.
  • the microcapsules 12 are embedded with a degradation preparation 121 that catalyzes the degradation of the degradable material layer 2.
  • the degradation preparation 121 includes a lipase preparation of the genus Rhizopus, preferably also includes amylase, cellulase, and in various enzymes that degrade polylactic acid.
  • Rhizopus lipase has the strongest ability to degrade polylactic acid, and Rhizopus lipase can degrade polylactic acid and generate carbon dioxide and water, thereby improving the degradation rate of packaging materials.
  • Amylase can promote the degradation and decomposition of the starch adhesive used in the microcapsules 12 , and cellulase can promote the degradation of the bottom paper 1 , thereby increasing the degradation rate of other parts of the packaging material.
  • the surface of the degradable material layer 2 is plated with an aluminum layer 3 by vacuum evaporation technology.
  • the PET film or the laser PET film is placed on the glued horse paper or cardboard for compounding, and then the PET film is peeled off, and the aluminum molecules are removed.
  • the layer is transferred to the degraded material layer 2 by gluing, thereby forming the aluminium layer 3 .
  • a laser information layer 4 is formed on the surface of the aluminum layer 3 away from the degradable material layer 2 by a laser holographic molding machine.
  • the laser information layer 4 includes design contents such as the brand, product features, and functions of the packaged product.
  • design contents such as the brand, product features, and functions of the packaged product.
  • various holographic laser effects such as multi-angle hologram, true color hologram, miniature text hologram, precise banknote line hologram, coaxial off-axis lens hologram, matte white embossed hologram, etc., all the originally printed elements are passed through the hologram.
  • a positioning pattern is formed on the surface of the laser information layer 4 by molding, and the positioning pattern is used for positioning when printing the surface of the aluminum layer 3 .
  • the positioning pattern generally adopts a cross to ensure the accuracy of the positional coincidence of any two-color image during multi-color overprinting.
  • a printing layer 5 is formed on the surface of the laser information layer 4 away from the aluminum layer 3 by printing, and the printing layer 5 is formed by multi-color overprinting, including the packaging information, design drawings and publicity drawings of the products.
  • the surface of the printing layer 5 away from the laser information layer 4 is provided with a surface treatment layer 6 .
  • the surface treatment layer 6 may be varnish or flocking, and in this embodiment, varnish is preferred.
  • a layer of varnish is coated on the surface of the laser information layer 4, thereby improving the gloss, abrasion resistance and water resistance of the surface of the packaging material.
  • a plurality of holes can be made on the surface of the packaging material, and then the packaging material can be buried in the soil. Moisture in the soil dissolves the sodium alginate so that the degradable preparation 121 inside the microcapsules 12 recovers its activity.
  • the Rhizopus lipase inside the microcapsules 12 can degrade polylactic acid, while amylase can promote the degradation of the adhesive of the microcapsules 12, and cellulase can promote the degradation of the bottom paper 1, which significantly improves the degradation efficiency of the packaging paper. .
  • the embodiment of the present application also discloses a method for producing an in-line printed environmentally friendly holographic laser positioning packaging material.
  • the production method of the environmentally friendly holographic laser positioning packaging material printed in line includes:
  • S100 specifically includes:
  • the degradation preparation 121 is embedded in the microcapsules formed by sodium alginate by the water phase separation method, and after the enzyme is immobilized, a protective layer can be formed on the outer layer of the enzyme to effectively protect the enzyme, thereby maintaining the degradation preparation 121. enzyme activity.
  • Fixing the microcapsules 12 on the surface of the bottom paper 1 specifically includes:
  • An embedded groove 11 is opened along the length direction of the bottom paper 1 , the width of the embedded groove 11 can be the diameter of two microcapsules 12 , and the depth can be the diameter of one microcapsule 12 .
  • a plurality of embedded grooves 11 are provided along the width direction of the base paper 1 , and then the microcapsules 12 are evenly scattered on the surface of the base paper 1 .
  • the surface of the backing paper 1 is wiped with a scraper, and the microcapsules 12 fall into the embedded grooves 11 under wiping, so as to be evenly distributed in the embedded grooves 11 so that the degradation efficiency can be uniform.
  • fixing the microcapsules 12 in the embedded grooves 11 specifically includes:
  • the starch solution is a solution formed by dissolving water-soluble starch in water, and a small amount is sprayed between the microcapsules 12 and between the microcapsules 12 and the embedded grooves 11 .
  • the starch solution will be gelatinized during the heating process, and then transformed into a colloid with higher viscosity. After the colloid is cooled and solidified, the microcapsules 12 are fixed in the embedded groove 11 .
  • Polylactic acid is cast on the surface of the base paper 1 by a casting machine to form a layer of polylactic acid film. After the polylactic acid film is solidified, a layer of polylactic acid is formed, and polylactic acid can be degraded in the soil to generate carbon dioxide and water and directly It is absorbed by the soil, so it is environmentally friendly and will not pollute.
  • the PET film or laser PET film is placed on the glued horse paper or cardboard for compounding, and then the PET film is peeled off. During this process, the PET film can be used repeatedly for many times, and the aluminum molecular layer is transferred to the degradable material through the adhesive effect. layer 2, thereby forming an aluminum layer 3.
  • Continuous registration printing is performed according to the position of the positioning cursor extruded by the laser die, and the promotional pattern of the packaging material is printed on the surface of the aluminum layer 3 .
  • the surface treatment includes varnish or flocking.
  • the above varnish is taken as an example, and a layer of varnish is applied on the surface of the printing layer 5, which can be water-based varnish or oil-based varnish.
  • This application implements In the example, it is preferably water-based varnish, and finally, the packaging material coated with varnish is dried with hot air to form.

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Abstract

An inline printing-based eco-friendly holographic laser positioning packaging material and a manufacturing method therefor. The packaging material comprises base paper; a biodegradable material layer is provided on the surface of the base paper; a degradation cavity is formed between the base paper and the biodegradable material layer; a micro capsule is provided in the degradation cavity; and a degradation preparation for catalyzing the degradation of the biodegradable material layer is provided in the micro capsule. The manufacturing method comprises embedding the degradation preparation, and fixing the micro capsule on the surface of the base paper; forming the biodegradable material layer on the surface of the base paper by means of coating; plating aluminum on the surface of the biodegradable material layer to form an aluminum layer; performing laser molding on the surface of the aluminum layer to form a laser pattern and a positioning cursor; performing continuous registration printing on the surface of the aluminum layer on the basis of the positioning cursor to form a printing layer; and performing surface treatment on the surface of the printing layer to form a surface treatment layer. The obtained packaging material is easy to degrade.

Description

连线印刷的环保全息镭射定位包装材料及其制作方法Inline-printed environmentally friendly holographic laser positioning packaging material and manufacturing method thereof
本申请要求于2021年2月26日提交中国专利局、申请号为CN202110217341.1、发明名称为“连线印刷的环保全息镭射定位包装材料及其制作方法”的中国专利申请的优先权,其全部内容通过引用结合在本申请中。This application claims the priority of the Chinese patent application filed on February 26, 2021 with the application number CN202110217341.1 and the title of the invention is "Environmentally-friendly holographic laser positioning packaging material printed by connection and its production method", which The entire contents of this application are incorporated by reference.
技术领域technical field
本申请涉及产品包装的领域,尤其是涉及一种连线印刷的环保全息镭射定位包装材料及其制作方法。The present application relates to the field of product packaging, in particular to an environmentally friendly holographic laser positioning packaging material printed in line and a manufacturing method thereof.
背景技术Background technique
包装材料是指用于制造包装容器、包装装潢、包装印刷、包装运输等满足产品包装要求所使用的材料,它既包括金属、塑料、玻璃、陶瓷、纸、竹本、野生蘑类、天然纤维、化学纤维、复合材料等主要包装材料,又包括涂料、粘合剂、捆扎带、装潢、印刷材料等辅助材料。Packaging materials refer to the materials used in the manufacture of packaging containers, packaging and decoration, packaging printing, packaging and transportation, etc. to meet product packaging requirements, including metal, plastic, glass, ceramics, paper, bamboo, wild mushrooms, natural fibers, Main packaging materials such as chemical fibers and composite materials, as well as auxiliary materials such as coatings, adhesives, strapping tapes, decoration, and printing materials.
相关技术中,公开号为CN104129566A的中国专利,公开了一种包装用材料,涉及包装材料领域,包装用材料从外到内依次为阻燃层、纸板层、缓冲层和杀菌层,缓冲层内部设有空气气囊,阻燃层与纸板层连接的表面设有花纹,该种包装材料阻燃性强,缓冲性好,杀菌性能优异,是理想的包装用材料,值得推广。In the related art, the Chinese patent with the publication number CN104129566A discloses a packaging material, which relates to the field of packaging materials. Airbags are provided, and the surface connecting the flame-retardant layer and the cardboard layer is provided with patterns. This packaging material has strong flame retardancy, good cushioning and excellent sterilization performance.
针对上述中的相关技术,发明人认为存在有上述包装材料不易降解,容易导致环境污染的缺陷。In view of the above-mentioned related technologies, the inventors believe that the above-mentioned packaging materials are not easily degradable and easily lead to environmental pollution.
发明内容SUMMARY OF THE INVENTION
为了提高包装材料的降解性能,本申请提供一种连线印刷的环保全息镭射定位包装材料及其制作方法。In order to improve the degradation performance of the packaging material, the present application provides an environmentally friendly holographic laser positioning packaging material printed in-line and a manufacturing method thereof.
第一方面,本申请提供一种连线印刷的环保全息镭射定位包装材料,采用如下的技术方案:In the first aspect, the application provides an environmentally friendly holographic laser positioning packaging material for in-line printing, using the following technical solutions:
一种连线印刷的环保全息镭射定位包装材料,包括底纸,所述底纸的表面上设置有降解材料层,所述底纸与降解材料层之间设置有降解空腔, 所述降解空腔中设置有微型胶囊,所述微型胶囊中设置有催化降解材料层降解的降解制剂。An in-line printed environmentally friendly holographic laser positioning packaging material, comprising a backing paper, a degradable material layer is arranged on the surface of the backing paper, a degradation cavity is arranged between the backing paper and the degradation material layer, and the degradation cavity is A microcapsule is arranged in the cavity, and a degrading preparation for catalyzing the degradation of the degradable material layer is arranged in the microcapsule.
通过采用上述技术方案,降解材料层在提高底纸的机械强度的同时能够易于降解,在掩埋入土壤中时,土壤中的微生物和细菌会对降解材料层进行降解,使之分解而直接被土壤吸收,大大降低了包装材料产生的污染;而降解空腔中设置的微型胶囊以及微型胶囊中的降解制剂能够在包装材料掩埋入土壤中时提高降解材料所需要的降解制剂,从而促进了包装材料的降解,使得土壤中没有降解材料降解所需要的细菌时也能够进行降解。By adopting the above technical solution, the degradable material layer can be easily degraded while improving the mechanical strength of the backing paper. When buried in the soil, the microorganisms and bacteria in the soil will degrade the degradable material layer, causing it to decompose and be directly absorbed by the soil. The microcapsules arranged in the degradation cavity and the degradable preparations in the microcapsules can increase the degradable preparations required by the degradable materials when the packaging materials are buried in the soil, thereby promoting the packaging materials. The degradation of the material enables the degradation of the soil without the bacteria required for the degradation of the degrading material.
优选的,所述底纸为白卡纸、铜版纸或牛皮纸。Preferably, the base paper is white cardboard, coated paper or kraft paper.
优选的,所述降解材料层为聚乳酸层,所述降解制剂包括根霉属菌酯肪酶。Preferably, the degradable material layer is a polylactic acid layer, and the degradable preparation includes Rhizopus sp. lipase.
通过采用上述技术方案,聚乳酸是一种新型生物降解材料,使用后能被自然界中微生物完全降解,最终生成二氧化碳和水,不污染环境,这对保护环境非常有利,是公认的环境友好材料。而在降解聚乳酸的酶中,根霉属菌酯肪酶是降解效果最好的酶,从而提高了包装材料的降解效率;另一方面,聚乳酸具有良好的机械性能和物理性能,具有良好的抗拉强度和延展度,因而其淋膜在底纸的表面能够提高包装材料的强度且能够提高包装材料抑菌抗霉的性能。By adopting the above technical solution, polylactic acid is a new type of biodegradable material, which can be completely degraded by microorganisms in nature after use, and finally generates carbon dioxide and water, which does not pollute the environment, which is very beneficial to protecting the environment and is recognized as an environmentally friendly material. Among the enzymes that degrade polylactic acid, Rhizopus lipase is the enzyme with the best degradation effect, thereby improving the degradation efficiency of packaging materials; on the other hand, polylactic acid has good mechanical and physical properties, and has good Therefore, its coating on the surface of the bottom paper can improve the strength of the packaging material and improve the antibacterial and antifungal properties of the packaging material.
优选的,所述降解制剂(121)还包括淀粉酶和纤维素酶。淀粉酶能够促进微型胶囊使用的淀粉粘接剂降解分解,而纤维素酶能够促进底纸的降解,提高了包装材料其他部分的降解速率。Preferably, the degradation preparation (121) further comprises amylase and cellulase. Amylase can promote the degradation and decomposition of starch adhesive used in microcapsules, while cellulase can promote the degradation of the bottom paper and improve the degradation rate of other parts of the packaging material.
优选的,所述微型胶囊(12)的壁材为海藻酸钠。Preferably, the wall material of the microcapsules (12) is sodium alginate.
优选的,所述底纸表面沿其长度方向开设有嵌置条槽,所述微型胶囊嵌置在嵌置条槽中。Preferably, the surface of the base paper is provided with embedded grooves along its length direction, and the microcapsules are embedded in the embedded grooves.
通过采用上述技术方案,由于酶制剂具有一定的生物活性,在挤压后会破坏其结构而导致其失去活性,因而需要对酶制剂进行有效保护,而由于底纸在使用的过程中会受到压力,因而将微型胶囊嵌置在嵌置条槽中能够有效保护微型胶囊,防止微型胶囊在使用的过程中受到压力而破碎,从而有效地保护了微型胶囊以及微型胶囊内部的酶制剂。By adopting the above technical solution, since the enzyme preparation has a certain biological activity, its structure will be destroyed and its activity will be lost after extrusion, so the enzyme preparation needs to be effectively protected, and the bottom paper will be under pressure during use. Therefore, embedding the microcapsules in the embedded grooves can effectively protect the microcapsules and prevent the microcapsules from being broken by pressure during use, thereby effectively protecting the microcapsules and the enzyme preparation inside the microcapsules.
优选的,所述降解材料层表面设置有铝层,所述铝层远离降解材料层 的表面设置有镭射信息层。Preferably, an aluminum layer is provided on the surface of the degradable material layer, and a laser information layer is provided on the surface of the aluminum layer away from the degradable material layer.
通过采用上述技术方案,通过真空蒸镀方式形成在降解材料层表面的铝层能够使得包装材料具有金属光泽,通过转移法镀铝能够将铝层镀附在降解材料层上;而通过模压形成的镭射信息层能够产生光芒四射的镭射图案及镭射文字,同时能够提高包装材料的防伪效果。By adopting the above technical solution, the aluminum layer formed on the surface of the degradable material layer by vacuum evaporation can make the packaging material have metallic luster, and the aluminum layer can be plated on the degradable material layer by the transfer method of aluminum plating; The laser information layer can generate radiant laser patterns and laser characters, and at the same time can improve the anti-counterfeiting effect of packaging materials.
优选的,所述镭射信息层表面设置有定位图案,所述镭射信息层远离铝层的表面设置有印刷层。Preferably, a positioning pattern is provided on the surface of the laser information layer, and a printing layer is provided on the surface of the laser information layer away from the aluminum layer.
通过采用上述技术方案,定位图案的设置便于在镭射信息层的表面生产用于连线印刷过程中需要的定位标记,基于定位标记通过套准印刷在镭射信息层的表面印刷出各种颜色的包装图案,从而提高了包装材料的样式,便于吸引客户的眼球。By adopting the above technical solution, the setting of the positioning pattern facilitates the production of positioning marks on the surface of the laser information layer that are required in the process of in-line printing. Based on the positioning marks, various colors of packaging are printed on the surface of the laser information layer by register printing. Patterns, thereby improving the style of packaging materials, easy to attract the attention of customers.
优选的,所述印刷层远离镭射信息层的表面设置有表面处理层。Preferably, a surface treatment layer is provided on the surface of the printing layer away from the laser information layer.
通过采用上述技术方案,表面处理层的设置提高了包装材料表面的性质,使得包装材料表面耐磨、不掉色、斥水、斥油,在使用的过程中具有更好的触感。By adopting the above technical solutions, the provision of the surface treatment layer improves the properties of the surface of the packaging material, so that the surface of the packaging material is wear-resistant, non-fading, water-repellent, and oil-repellent, and has a better tactile feel during use.
优选的,所述表面处理层(6)为光油或植绒。Preferably, the surface treatment layer (6) is varnish or flocking.
第二方面,本申请提供一种应用于连线印刷的环保全息镭射定位包装材料的制作方法,采用如下的技术方案:In the second aspect, the present application provides a method for making an environmentally friendly holographic laser positioning packaging material applied to in-line printing, using the following technical solutions:
一种连线印刷的环保全息镭射定位包装材料的制作方法,包括:A production method of an environmentally-friendly holographic laser positioning packaging material printed in line, comprising:
对降解制剂进行包埋并将微型胶囊固定在底纸的表面上;Embed the degradable preparation and fix the microcapsules on the surface of the bottom paper;
在底纸的表面通过淋膜形成降解材料层。A degradable material layer is formed on the surface of the bottom paper by lamination.
优选地,还包括:Preferably, it also includes:
在降解材料层表面镀铝形成铝层;Coating aluminum on the surface of the degradable material layer to form an aluminum layer;
在铝层表面进行镭射模压,形成镭射图案及定位光标;Laser molding is performed on the surface of the aluminum layer to form a laser pattern and position the cursor;
基于定位光标在铝层表面进行连续套准印刷形成印刷层;以及,The printed layer is formed by continuous register printing on the surface of the aluminum layer based on the positioning cursor; and,
在印刷层表面进行表面处理,形成表面处理层。Surface treatment is performed on the surface of the printing layer to form a surface treatment layer.
通过采用上述技术方案,在底纸的表面增加了带有降解制剂的微型胶囊并在底纸与微型胶囊的表面形成了提高底纸强度的降解材料层,在包装材料废弃后可直接掩埋入土壤,在降解制剂的辅助下降解材料层能够迅速降解生成对土壤环境无害的物质,从而提高了包装材料的降解性能;另一 方面,降解材料表面镀铝并通过镭射模压形成镭射图案使得包装材料表面具有绚丽的金属光泽,同时通过定位光标能够根据需要印刷出印刷层,能够增添包装材料的图案效果;最终通过表面处理形成包装材料的成品,使得包装材料的表面具有更好的质感,使得包装材料耐磨、不掉色、斥水、斥油,提高了包装材料的质量。By adopting the above technical solution, microcapsules with degradable preparations are added on the surface of the base paper, and a degradable material layer to improve the strength of the base paper is formed on the surfaces of the base paper and the microcapsules, and the packaging materials can be directly buried in the soil after they are discarded. , with the aid of the degrading agent, the degradable material layer can be rapidly degraded to generate substances that are harmless to the soil environment, thereby improving the degradation performance of the packaging material; on the other hand, the surface of the degradable material is aluminized and formed by laser molding The surface has a brilliant metallic luster, and at the same time, the printing layer can be printed as required by positioning the cursor, which can add the pattern effect of the packaging material; finally, the finished product of the packaging material is formed through surface treatment, so that the surface of the packaging material has a better texture, making the packaging material The material is wear-resistant, non-fading, water-repellent and oil-repellent, which improves the quality of packaging materials.
优选的,所述对降解制剂进行包埋并固定在底纸的表面上包括:Preferably, the embedding and fixing the degradable preparation on the surface of the bottom paper include:
将降解制剂通过微胶囊包封的方法固定在溶于水的微型胶囊中;The degradable preparation is fixed in water-soluble microcapsules by the method of microencapsulation;
在底纸表面开设嵌置条槽,将微型胶囊均匀洒在底纸的表面;以及,An embedded groove is set on the surface of the bottom paper, and the microcapsules are evenly sprinkled on the surface of the bottom paper; and,
刮拭底纸表面的微型胶囊,使得微型胶囊落入嵌置条槽中并将微型胶囊固定在嵌置条槽中。Scrape the microcapsules on the surface of the bottom paper, so that the microcapsules fall into the embedded grooves and fix the microcapsules in the embedded grooves.
通过采用上述技术方案,由于降解材料层的表面在镀铝的过程中需要进行模压形成镭射信息层,若微型胶囊附着在底纸的表面势必会使得降解材料层与底纸之间存在间隙,在模压时微型胶囊则会在压力挤压下破碎导致微型胶囊中的酶制剂失去活性;而在底纸表面开设的嵌置条槽能够将微型胶囊嵌置在其中,从而能够对微型胶囊进行容置,防止微型胶囊破碎。By adopting the above technical solution, since the surface of the degradable material layer needs to be molded during the aluminizing process to form the laser information layer, if the microcapsules are attached to the surface of the base paper, there will inevitably be a gap between the degradable material layer and the base paper. During molding, the microcapsules will be broken under pressure extrusion, resulting in the inactivation of the enzyme preparations in the microcapsules; and the embedded grooves on the surface of the bottom paper can embed the microcapsules therein, so as to accommodate the microcapsules , to prevent the microcapsules from breaking.
优选的,所述将微型胶囊固定在嵌置条槽中包括:Preferably, the fixing the microcapsules in the embedded grooves includes:
向底纸表面喷涂淀粉溶液;以及,Spray the starch solution on the surface of the liner; and,
迅速对底纸进行加热,使得淀粉溶液凝固从而将微型胶囊固定。The backing paper is rapidly heated to solidify the starch solution to hold the microcapsules in place.
通过采用上述技术方案,淀粉溶液在高温状态下会发生糊化,转变为胶体,糊化后的淀粉溶液具有较大的粘性,待冷却凝固后能够将微型胶囊粘接固定在嵌置条槽中,而淀粉溶液并不会对环境造成污染,在使用后能够迅速降解,不会对环境产生污染。By adopting the above technical solution, the starch solution will be gelatinized at high temperature and transformed into a colloid. The gelatinized starch solution has a relatively large viscosity, and the microcapsules can be glued and fixed in the embedded groove after cooling and solidification. , and the starch solution will not pollute the environment, and can be rapidly degraded after use, and will not pollute the environment.
优选的,在降解材料层表面镀铝形成铝层包括:Preferably, forming an aluminum layer by plating aluminum on the surface of the degradable material layer includes:
通过转移法是将PET膜或镭射PET膜置于涂胶马纸或纸板复合,再将PET膜剥落,在此过程中PET膜可反复使用,铝分子层通过胶粘作用转移到降解材料层,从而形成铝层。Through the transfer method, the PET film or laser PET film is placed on the glued horse paper or cardboard for compounding, and then the PET film is peeled off. During this process, the PET film can be used repeatedly, and the aluminum molecular layer is transferred to the degradable material layer through the adhesive effect. Thereby, an aluminum layer is formed.
优选的,在铝层表面进行镭射模压,形成镭射图案及定位光标包括:Preferably, performing laser molding on the surface of the aluminum layer to form a laser pattern and positioning the cursor includes:
设计镭射图案,并将设定好的镭射图案制版,将镭射版包在镭射模压机上,控制温度和压力,将镭射图案模压至铝层的表面上形成镭射图案以及定位光标。Design the laser pattern, make a plate with the set laser pattern, wrap the laser plate on the laser molding machine, control the temperature and pressure, mold the laser pattern onto the surface of the aluminum layer to form the laser pattern and position the cursor.
优选的,基于定位光标在铝层表面进行连续套准印刷形成印刷层包括:Preferably, the continuous register printing on the surface of the aluminum layer based on the positioning cursor to form the printing layer includes:
根据镭射模压出的定位光标的位置进行连续套准印刷,在铝层的表面印刷出包装材料的宣传图案。Continuous registration printing is performed according to the position of the positioning cursor extruded by the laser die, and the promotional pattern of the packaging material is printed on the surface of the aluminum layer.
优选的,所述表面处理包括上光油或植绒。Preferably, the surface treatment includes varnish or flocking.
通过采用上述技术方案,在印刷层的表面上光油或植绒能够在印刷层表面形成一侧保护层,从而使得包装材料表面耐磨、不掉色、斥水、斥油,在使用的过程中具有更好的触感。By adopting the above technical solution, varnish or flocking on the surface of the printing layer can form a protective layer on the surface of the printing layer, so that the surface of the packaging material is wear-resistant, non-fading, water-repellent, and oil-repellent. Has a better tactile feel.
综上所述,本申请包括以下至少一种有益技术效果:To sum up, the present application includes at least one of the following beneficial technical effects:
1.通过采用降解材料层、降解空腔、微型胶囊和降解制剂相配合的技术,从而提高了包装材料的降解性能,更加绿色环保;1. By adopting the technology of degradable material layer, degradable cavity, microcapsule and degradable preparation, the degradation performance of packaging material is improved, and it is more green and environmentally friendly;
2.通过采用嵌置条槽、聚乳酸层和根霉属菌酯肪酶相配合的技术,从而便于对根霉属菌酯肪酶进行保护,从而保证酶制剂的活性;2. By adopting the technology of cooperating with embedded strip groove, polylactic acid layer and Rhizopus lipase, it is convenient to protect the Rhizopus lipase, thereby ensuring the activity of the enzyme preparation;
3.通过采用铝层、镭射信息层、定位图案、印刷层和表面处理层相配合的技术,从而便于提高包装材料的外观美观性,显著提高了包装材料的质量。3. By using the technology of aluminum layer, laser information layer, positioning pattern, printing layer and surface treatment layer, it is convenient to improve the appearance of packaging materials and significantly improve the quality of packaging materials.
说明书附图Instruction drawings
图1是本申请实施例的一种连线印刷的环保全息镭射定位包装材料的结构示意图;Fig. 1 is the structural representation of the environmental protection holographic laser positioning packaging material of a kind of in-line printing according to the embodiment of the present application;
图2是图1中A处结构的放大示意图;Fig. 2 is the enlarged schematic diagram of the structure at A place in Fig. 1;
图3是本申请实施例中一种连线印刷的环保全息镭射定位包装材料的制作方法的流程图;3 is a flow chart of a method for producing an environmentally-friendly holographic laser positioning packaging material printed in-line in an embodiment of the present application;
图4是本申请实施例中步骤S100的子步骤流程图;FIG. 4 is a flow chart of sub-steps of step S100 in the embodiment of the present application;
图5是本申请实施例中步骤S130的子步骤流程图;FIG. 5 is a flowchart of sub-steps of step S130 in the embodiment of the present application;
附图标记说明:1、底纸;11、嵌置条槽;12、微型胶囊;121、降解制剂;2、降解材料层;3、铝层;4、镭射信息层;5、印刷层;6、表面处理层。Explanation of reference numerals: 1. Bottom paper; 11. Embedded grooves; 12. Microcapsules; 121. Degradable preparation; 2. Degradable material layer; 3. Aluminum layer; 4. Laser information layer; 5. Printing layer; 6 , Surface treatment layer.
具体实施方式Detailed ways
以下结合附图1-5对本申请作进一步详细说明。The present application will be further described in detail below in conjunction with accompanying drawings 1-5.
本申请实施例公开一种连线印刷的环保全息镭射定位包装材料。参照 图1,连线印刷的环保全息镭射定位包装材料包括底纸1,底纸1可以是白卡纸、铜版纸或牛皮纸中的一种。The embodiment of the present application discloses an environmentally friendly holographic laser positioning packaging material printed in line. Referring to Fig. 1 , the environmentally-friendly holographic laser positioning packaging material printed in line includes a backing paper 1, and the backing paper 1 can be one of white cardboard, coated paper or kraft paper.
底纸1的表面上经淋膜形成有降解材料层2,降解材料层2为聚乳酸层,降解材料层2通过流延机将聚乳酸流延并凝固于底纸1的表面上形成。聚乳酸在提高底纸1的抗拉强度的同时能够在环境中自然降解,从而提高了包装材料的可降解性。A degradable material layer 2 is formed on the surface of the base paper 1 by coating, and the degradable material layer 2 is a polylactic acid layer. The polylactic acid can naturally degrade in the environment while improving the tensile strength of the backing paper 1, thereby improving the degradability of the packaging material.
参照图2,底纸1表面沿其长度方向开设有嵌置条槽11,嵌置条槽11与降解材料层2之间形成有降解空腔。降解空腔中粘接固定有微型胶囊12,微型胶囊12嵌置在嵌置条槽11中,微型胶囊12的壁材为海藻酸钠。微型胶囊12中包埋有催化降解材料层2降解的降解制剂121,降解制剂121包括根霉属菌酯肪酶制剂,优选还包括淀粉酶、纤维素酶,在各种对聚乳酸降解的酶中,根霉属菌酯肪酶对聚乳酸的降解能力最强,根霉属菌酯肪酶能够对聚乳酸进行降解并产生二氧化碳和水,从而提高了包装材料的降解速率。淀粉酶能够促进微型胶囊12使用的淀粉粘接剂降解分解,而纤维素酶能够促进底纸1的降解,提高了包装材料其他部分的降解速率。Referring to FIG. 2 , the surface of the backing paper 1 is provided with embedded grooves 11 along its length direction, and a degradation cavity is formed between the embedded groove 11 and the degradable material layer 2 . The microcapsules 12 are glued and fixed in the degradation cavity, the microcapsules 12 are embedded in the embedded grooves 11, and the wall material of the microcapsules 12 is sodium alginate. The microcapsules 12 are embedded with a degradation preparation 121 that catalyzes the degradation of the degradable material layer 2. The degradation preparation 121 includes a lipase preparation of the genus Rhizopus, preferably also includes amylase, cellulase, and in various enzymes that degrade polylactic acid. Among them, Rhizopus lipase has the strongest ability to degrade polylactic acid, and Rhizopus lipase can degrade polylactic acid and generate carbon dioxide and water, thereby improving the degradation rate of packaging materials. Amylase can promote the degradation and decomposition of the starch adhesive used in the microcapsules 12 , and cellulase can promote the degradation of the bottom paper 1 , thereby increasing the degradation rate of other parts of the packaging material.
参照图1,降解材料层2表面经真空蒸镀技术镀附有铝层3,通过转移法是将PET膜或镭射PET膜置于涂胶马纸或纸板复合,再将PET膜剥落,铝分子层通过胶粘作用转移到降解材料层2,从而形成铝层3。Referring to FIG. 1, the surface of the degradable material layer 2 is plated with an aluminum layer 3 by vacuum evaporation technology. By the transfer method, the PET film or the laser PET film is placed on the glued horse paper or cardboard for compounding, and then the PET film is peeled off, and the aluminum molecules are removed. The layer is transferred to the degraded material layer 2 by gluing, thereby forming the aluminium layer 3 .
铝层3远离降解材料层2的表面通过镭射全息模压机模压形成有镭射信息层4,镭射信息层4包括包装产品的品牌、产品特征、功能等设计内容。通过多角度全息、真彩色全息图、微缩文字全息图、精密钞线全息图、同离轴透镜全息图、哑白浮雕全息图等各种全息镭射效果的组合,将所有原先印刷的元素通过全息镭射制版并通过模压形成在铝层3上。A laser information layer 4 is formed on the surface of the aluminum layer 3 away from the degradable material layer 2 by a laser holographic molding machine. The laser information layer 4 includes design contents such as the brand, product features, and functions of the packaged product. Through the combination of various holographic laser effects such as multi-angle hologram, true color hologram, miniature text hologram, precise banknote line hologram, coaxial off-axis lens hologram, matte white embossed hologram, etc., all the originally printed elements are passed through the hologram. Laser-engraved and formed on the aluminum layer 3 by embossing.
参照图1,镭射信息层4表面经模压形成有定位图案,定位图案用于在对铝层3表面进行印刷时进行定位。定位图案一般采用十字,以保证多色套印时任意两色图像位置重合的准确度。Referring to FIG. 1 , a positioning pattern is formed on the surface of the laser information layer 4 by molding, and the positioning pattern is used for positioning when printing the surface of the aluminum layer 3 . The positioning pattern generally adopts a cross to ensure the accuracy of the positional coincidence of any two-color image during multi-color overprinting.
镭射信息层4远离铝层3的表面经印刷形成有印刷层5,印刷层5经多色套印形成,包括商品的包装信息、设计图及宣传图样等。A printing layer 5 is formed on the surface of the laser information layer 4 away from the aluminum layer 3 by printing, and the printing layer 5 is formed by multi-color overprinting, including the packaging information, design drawings and publicity drawings of the products.
参照图1,印刷层5远离镭射信息层4的表面设置有表面处理层6, 表面处理层6可以为光油或植绒,本实施例优选为光油。在镭射信息层4表面涂覆一层上光油,从而提高包装材料表面的光泽度、耐磨性以及防水性。Referring to FIG. 1 , the surface of the printing layer 5 away from the laser information layer 4 is provided with a surface treatment layer 6 . The surface treatment layer 6 may be varnish or flocking, and in this embodiment, varnish is preferred. A layer of varnish is coated on the surface of the laser information layer 4, thereby improving the gloss, abrasion resistance and water resistance of the surface of the packaging material.
本申请实施例一种连线印刷的环保全息镭射定位包装材料的实施原理为:The implementation principle of an environmentally friendly holographic laser positioning packaging material printed in line in the embodiment of the present application is as follows:
当包装材料需要降解时,在包装材料的表面扎出多个孔,然后将包装材料掩埋至土壤中即可。土壤中的水分溶解海藻酸钠使得微型胶囊12内部的降解制剂121恢复活性。When the packaging material needs to be degraded, a plurality of holes can be made on the surface of the packaging material, and then the packaging material can be buried in the soil. Moisture in the soil dissolves the sodium alginate so that the degradable preparation 121 inside the microcapsules 12 recovers its activity.
微型胶囊12内部的根霉属菌酯肪酶能够降解聚乳酸,而淀粉酶能够促进微型胶囊12粘接剂的降解,纤维素酶能够促进底纸1的降解,显著提高了包装纸的降解效率。The Rhizopus lipase inside the microcapsules 12 can degrade polylactic acid, while amylase can promote the degradation of the adhesive of the microcapsules 12, and cellulase can promote the degradation of the bottom paper 1, which significantly improves the degradation efficiency of the packaging paper. .
本申请实施例还公开一种连线印刷的环保全息镭射定位包装材料的制作方法。参照图3,连线印刷的环保全息镭射定位包装材料的制作方法包括:The embodiment of the present application also discloses a method for producing an in-line printed environmentally friendly holographic laser positioning packaging material. Referring to Fig. 3, the production method of the environmentally friendly holographic laser positioning packaging material printed in line includes:
S100、对降解制剂121进行包埋并将微型胶囊12固定在底纸1的表面上;S100, embedding the degradable preparation 121 and fixing the microcapsules 12 on the surface of the bottom paper 1;
参照图3和图4,S100具体包括:3 and 4, S100 specifically includes:
S110、将降解制剂121通过微胶囊包封的方法固定在溶于水的微型胶囊12中;S110, fixing the degradation preparation 121 in the water-soluble microcapsules 12 by the method of microcapsule encapsulation;
将降解制剂121通过水相分离法包埋在海藻酸钠形成的微胶囊中,将酶固定化后能够在酶的外层形成一层保护层,对酶进行有效保护,从而维持降解制剂121中酶的活性。The degradation preparation 121 is embedded in the microcapsules formed by sodium alginate by the water phase separation method, and after the enzyme is immobilized, a protective layer can be formed on the outer layer of the enzyme to effectively protect the enzyme, thereby maintaining the degradation preparation 121. enzyme activity.
将微型胶囊12固定在底纸1的表面上具体包括:Fixing the microcapsules 12 on the surface of the bottom paper 1 specifically includes:
S120、在底纸1表面开设嵌置条槽11,将微型胶囊12均匀洒在底纸1的表面;S120, opening the embedded groove 11 on the surface of the base paper 1, and evenly sprinkle the microcapsules 12 on the surface of the base paper 1;
沿底纸1的长度方向开设处嵌置条槽11,嵌置条槽11的宽度可以为两个微型胶囊12的直径长度,深度可以为一个微型胶囊12的直径长度。嵌置条槽11沿底纸1宽度方向开设有多根,然后将微型胶囊12均匀地撒在底纸1的表面上。An embedded groove 11 is opened along the length direction of the bottom paper 1 , the width of the embedded groove 11 can be the diameter of two microcapsules 12 , and the depth can be the diameter of one microcapsule 12 . A plurality of embedded grooves 11 are provided along the width direction of the base paper 1 , and then the microcapsules 12 are evenly scattered on the surface of the base paper 1 .
S130、刮拭底纸1表面的微型胶囊12,使得微型胶囊12落入嵌置条 槽11中并将微型胶囊12固定在嵌置条槽11中。S130, wipe the microcapsules 12 on the surface of the bottom paper 1, so that the microcapsules 12 fall into the embedded grooves 11 and fix the microcapsules 12 in the embedded grooves 11.
用刮板在底纸1的表面刮拭,微型胶囊12在刮拭下落入嵌置条槽11中,从而尽可能均匀地分布在嵌置条槽11中以使得降解效率能够均匀。The surface of the backing paper 1 is wiped with a scraper, and the microcapsules 12 fall into the embedded grooves 11 under wiping, so as to be evenly distributed in the embedded grooves 11 so that the degradation efficiency can be uniform.
参照图4和图5,将微型胶囊12固定在嵌置条槽11中具体包括:4 and 5 , fixing the microcapsules 12 in the embedded grooves 11 specifically includes:
S131、向底纸1表面喷涂淀粉溶液;S131, spray starch solution to the surface of the bottom paper 1;
淀粉溶液为水溶性淀粉溶于水后形成的溶液,少量喷涂在微型胶囊12之间以及微型胶囊12与嵌置条槽11之间。The starch solution is a solution formed by dissolving water-soluble starch in water, and a small amount is sprayed between the microcapsules 12 and between the microcapsules 12 and the embedded grooves 11 .
S132、迅速对底纸1进行加热,使得淀粉溶液凝固从而将微型胶囊12固定。S132 , rapidly heating the bottom paper 1 to solidify the starch solution so as to fix the microcapsules 12 .
淀粉溶液在加热的过程中会糊化,然后转变成粘性较大的胶体,待胶体冷却凝固后微型胶囊12即被固定在嵌置条槽11中。The starch solution will be gelatinized during the heating process, and then transformed into a colloid with higher viscosity. After the colloid is cooled and solidified, the microcapsules 12 are fixed in the embedded groove 11 .
参照图3,S200、在底纸1的表面通过淋膜形成降解材料层2;Referring to FIG. 3, S200, forming a degradable material layer 2 on the surface of the base paper 1 by laminating;
通过流延机在底纸1的表面流延聚乳酸,形成一层聚乳酸薄膜,待聚乳酸薄膜凝固后形成一层聚乳酸层,而聚乳酸在土壤中能够被降解生成二氧化碳和水而直接被土壤吸收,因而对环境友好,不会产生污染。Polylactic acid is cast on the surface of the base paper 1 by a casting machine to form a layer of polylactic acid film. After the polylactic acid film is solidified, a layer of polylactic acid is formed, and polylactic acid can be degraded in the soil to generate carbon dioxide and water and directly It is absorbed by the soil, so it is environmentally friendly and will not pollute.
S300、在降解材料层2表面镀铝形成铝层3;S300, plating aluminum on the surface of the degradable material layer 2 to form an aluminum layer 3;
通过转移法是将PET膜或镭射PET膜置于涂胶马纸或纸板复合,再将PET膜剥落,在此过程中PET膜可反复使用多次,铝分子层通过胶粘作用转移到降解材料层2,从而形成铝层3。Through the transfer method, the PET film or laser PET film is placed on the glued horse paper or cardboard for compounding, and then the PET film is peeled off. During this process, the PET film can be used repeatedly for many times, and the aluminum molecular layer is transferred to the degradable material through the adhesive effect. layer 2, thereby forming an aluminum layer 3.
S400、在铝层3表面进行镭射模压,形成镭射图案及定位光标;S400, laser molding is performed on the surface of the aluminum layer 3 to form a laser pattern and a positioning cursor;
设计镭射图案,并将设定好的镭射图案制版,将镭射版包在镭射模压机上,控制温度和压力,将镭射图案模压至铝层3的表面上形成镭射图案以及定位光标。Design the laser pattern, make a plate with the set laser pattern, wrap the laser plate on the laser molding machine, control the temperature and pressure, and mold the laser pattern onto the surface of the aluminum layer 3 to form the laser pattern and position the cursor.
S500、基于定位光标在铝层3表面进行连续套准印刷形成印刷层5;S500, performing continuous registration printing on the surface of the aluminum layer 3 based on the positioning cursor to form the printing layer 5;
根据镭射模压出的定位光标的位置进行连续套准印刷,在铝层3的表面印刷出包装材料的宣传图案。Continuous registration printing is performed according to the position of the positioning cursor extruded by the laser die, and the promotional pattern of the packaging material is printed on the surface of the aluminum layer 3 .
S600、在印刷层5表面进行表面处理,形成表面处理层6。S600 , performing surface treatment on the surface of the printing layer 5 to form a surface treatment layer 6 .
表面处理包括上光油或植绒,本实施例以上光油为例,在印刷层5的表面涂覆一层光油,可以是水性上光油,也可以是油性上光油,本申请实施例中优选为水性上光油,最后将涂覆上光油的包装材料进行热风干燥 即可成型。The surface treatment includes varnish or flocking. In this embodiment, the above varnish is taken as an example, and a layer of varnish is applied on the surface of the printing layer 5, which can be water-based varnish or oil-based varnish. This application implements In the example, it is preferably water-based varnish, and finally, the packaging material coated with varnish is dried with hot air to form.
以上实施例的说明只是用于帮助理解本发明的方法及其核心思想。应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明原理的前提下,还可以对本发明进行若干改进和修饰,这些改进和修饰也落入本发明权利要求的保护范围内。对这些实施例的多种修改对本领域的专业技术人员来说是显而易见的,本文中所定义的一般原理可以在不脱离本发明的精神或范围的情况下在其它实施例中实现。因此,本发明将不会被限制于本文所示的这些实施例,而是要符合与本文所公开的原理和新颖特点相一致的最宽的范围。The descriptions of the above embodiments are only used to help understand the method and the core idea of the present invention. It should be pointed out that for those skilled in the art, without departing from the principle of the present invention, several improvements and modifications can also be made to the present invention, and these improvements and modifications also fall within the protection scope of the claims of the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be implemented in other embodiments without departing from the spirit or scope of the invention. Thus, the present invention is not intended to be limited to the embodiments shown herein, but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.

Claims (18)

  1. 一种连线印刷的环保全息镭射定位包装材料,其特征在于:包括底纸(1),所述底纸(1)的表面上设置有降解材料层(2),所述底纸(1)与降解材料层(2)之间设置有降解空腔,所述降解空腔中设置有微型胶囊(12),所述微型胶囊(12)中设置有催化降解材料层(2)降解的降解制剂(121)。An in-line printing environmentally friendly holographic laser positioning packaging material, characterized in that it comprises a backing paper (1), a degradable material layer (2) is provided on the surface of the backing paper (1), and the backing paper (1) A degradation cavity is arranged between the degradation material layer (2), a microcapsule (12) is arranged in the degradation cavity, and a degradation preparation that catalyzes the degradation of the degradation material layer (2) is arranged in the microcapsule (12). (121).
  2. 根据权利要求1所述的连线印刷的环保全息镭射定位包装材料,其特征在于:所述底纸(1)为白卡纸、铜版纸或牛皮纸。The in-line printed environmentally friendly holographic laser positioning packaging material according to claim 1, wherein the bottom paper (1) is white cardboard, coated paper or kraft paper.
  3. 根据权利要求1所述的连线印刷的环保全息镭射定位包装材料,其特征在于:所述降解材料层(2)为聚乳酸层,所述降解制剂(121)包括根霉属菌酯肪酶。The environmentally friendly holographic laser positioning packaging material printed in line according to claim 1, characterized in that: the degradable material layer (2) is a polylactic acid layer, and the degradable preparation (121) comprises Rhizopus sp. lipase .
  4. 根据权利要求3所述的连线印刷的环保全息镭射定位包装材料,其特征在于:所述降解制剂(121)还包括淀粉酶和纤维素酶。The in-line printed environmentally friendly holographic laser positioning packaging material according to claim 3, characterized in that: the degradation preparation (121) further comprises amylase and cellulase.
  5. 根据权利要求1所述的连线印刷的环保全息镭射定位包装材料,其特征在于:所述底纸(1)表面沿其长度方向开设有嵌置条槽(11),所述微型胶囊(12)嵌置在嵌置条槽(11)中。The environmentally friendly holographic laser positioning packaging material printed in line according to claim 1, characterized in that: the surface of the bottom paper (1) is provided with embedded grooves (11) along its length direction, and the microcapsules (12) ) is embedded in the embedded groove (11).
  6. 根据权利要求1或5所述的连线印刷的环保全息镭射定位包装材料,其特征在于:所述微型胶囊(12)的壁材为海藻酸钠。The in-line printed environmentally friendly holographic laser positioning packaging material according to claim 1 or 5, wherein the wall material of the microcapsules (12) is sodium alginate.
  7. 根据权利要求1所述的连线印刷的环保全息镭射定位包装材料,其特征在于:所述降解材料层(2)表面设置有铝层(3),所述铝层(3)远离降解材料层(2)的表面设置有镭射信息层(4)。The environmentally friendly holographic laser positioning packaging material printed by connection according to claim 1, characterized in that: the surface of the degradable material layer (2) is provided with an aluminum layer (3), and the aluminum layer (3) is far away from the degradable material layer. The surface of (2) is provided with a laser information layer (4).
  8. 根据权利要求7所述的连线印刷的环保全息镭射定位包装材料,其特征在于:所述镭射信息层(4)表面设置有定位图案,所述镭射信息层(4)远离铝层(3)的表面设置有印刷层(5)。The environmentally-friendly holographic laser positioning packaging material for inline printing according to claim 7, characterized in that: the laser information layer (4) is provided with a positioning pattern on the surface, and the laser information layer (4) is far away from the aluminum layer (3) The surface is provided with a printing layer (5).
  9. 根据权利要求8所述的连线印刷的环保全息镭射定位包装材料,其特征在于:所述印刷层(5)远离镭射信息层(4)的表面设置有表面处理层(6)。The environmentally-friendly holographic laser positioning packaging material for in-line printing according to claim 8, characterized in that: a surface treatment layer (6) is provided on the surface of the printing layer (5) away from the laser information layer (4).
  10. 根据权利要求9所述的连线印刷的环保全息镭射定位包装材料,其特征在于:所述表面处理层(6)为光油或植绒。The in-line printed environmentally friendly holographic laser positioning packaging material according to claim 9, wherein the surface treatment layer (6) is varnish or flocking.
  11. 一种权利要求1-10任一所述的连线印刷的环保全息镭射定位包装材料的制作方法,其特征在于,包括:A method for making the environmentally-friendly holographic laser positioning packaging material of any one of claims 1-10, characterized in that, comprising:
    对降解制剂(121)进行包埋并将所述包埋得到的微型胶囊(12)固定在底纸(1)的表面上;Embed the degradable preparation (121) and fix the microcapsules (12) obtained by the embedding on the surface of the bottom paper (1);
    在底纸(1)固定有微型胶囊(12)的表面通过淋膜形成降解材料层(2)。A degradable material layer (2) is formed on the surface of the bottom paper (1) on which the microcapsules (12) are fixed by lamination.
  12. 根据权利要求11所述的连线印刷的环保全息镭射定位包装材料的制作方法,其特征在于:还包括:The method for making an environmentally-friendly holographic laser positioning packaging material printed in line according to claim 11, further comprising:
    在降解材料层(2)表面镀铝形成铝层(3);Aluminium is formed on the surface of the degradable material layer (2) to form an aluminium layer (3);
    在铝层(3)表面进行镭射模压,形成镭射图案及定位光标;Laser molding is performed on the surface of the aluminum layer (3) to form a laser pattern and a positioning cursor;
    基于定位光标在铝层(3)表面进行连续套准印刷形成印刷层(5);以及,A printing layer (5) is formed by continuous register printing on the surface of the aluminum layer (3) based on the positioning cursor; and,
    在印刷层(5)表面进行表面处理,形成表面处理层(6)。Surface treatment is performed on the surface of the printing layer (5) to form a surface treatment layer (6).
  13. 根据权利要求11所述的连线印刷的环保全息镭射定位包装材料的制作方法,其特征在于:所述对降解制剂(121)进行包埋并固定在底纸(1)的表面上包括:The method for producing an environmentally-friendly holographic laser positioning packaging material printed in line according to claim 11, wherein the embedding and fixing the degradable preparation (121) on the surface of the bottom paper (1) comprises:
    将降解制剂(121)通过微胶囊包封的方法固定在溶于水的微型胶囊(12)中;The degradable preparation (121) is fixed in the microcapsules (12) dissolved in water by the method of microencapsulation;
    在底纸(1)表面开设嵌置条槽(11),将微型胶囊(12)均匀洒在底纸(1)的表面;以及,An embedded groove (11) is provided on the surface of the bottom paper (1), and the microcapsules (12) are evenly sprinkled on the surface of the bottom paper (1); and,
    刮拭底纸(1)表面的微型胶囊(12),使得微型胶囊(12)落入嵌置条槽(11)中并将微型胶囊(12)固定在嵌置条槽(11)中。Scrape the microcapsules (12) on the surface of the bottom paper (1), so that the microcapsules (12) fall into the embedded bar groove (11) and fix the microcapsules (12) in the embedded bar groove (11).
  14. 根据权利要求13所述的连线印刷的环保全息镭射定位包装材料的制作方法,其特征在于:所述将微型胶囊(12)固定在嵌置条槽(11)中包括:The method for producing an environmentally-friendly holographic laser positioning packaging material printed in line according to claim 13, wherein the fixing the microcapsules (12) in the embedded grooves (11) comprises:
    向底纸(1)表面喷涂淀粉溶液;以及,Spray the starch solution on the surface of the backing paper (1); and,
    迅速对底纸(1)进行加热,使得淀粉溶液凝固从而将微型胶囊(12)固定。The base paper (1) is rapidly heated to solidify the starch solution to fix the microcapsules (12).
  15. 根据权利要求12所述的连线印刷的环保全息镭射定位包装材料的制作方法,其特征在于:在降解材料层(2)表面镀铝形成铝层(3)包括:The method for producing an environmentally-friendly holographic laser positioning packaging material printed by connection according to claim 12, wherein: forming an aluminum layer (3) by plating aluminum on the surface of the degradable material layer (2) comprises:
    通过转移法是将PET膜或镭射PET膜置于涂胶马纸或纸板复合,再将PET膜剥落,在此过程中PET膜可反复使用,铝分子层通过胶粘作用转移到降解材料层(2),从而形成铝层(3)。Through the transfer method, the PET film or laser PET film is placed on the glued horse paper or cardboard for compounding, and then the PET film is peeled off. During this process, the PET film can be used repeatedly, and the aluminum molecular layer is transferred to the degradable material layer by adhesive action ( 2), thereby forming an aluminum layer (3).
  16. 根据权利要求12所述的连线印刷的环保全息镭射定位包装材料的制作方法,其特征在于:在铝层(3)表面进行镭射模压,形成镭射图案及 定位光标包括:The making method of the environment-friendly holographic laser positioning packaging material of connection printing according to claim 12, is characterized in that: carry out laser molding on the surface of aluminum layer (3), forming laser pattern and positioning cursor include:
    设计镭射图案,并将设定好的镭射图案制版,将镭射版包在镭射模压机上,控制温度和压力,将镭射图案模压至铝层(3)的表面上形成镭射图案以及定位光标。Design a laser pattern, make a plate with the set laser pattern, wrap the laser plate on a laser molding machine, control temperature and pressure, and mold the laser pattern onto the surface of the aluminum layer (3) to form the laser pattern and position the cursor.
  17. 根据权利要求12所述的连线印刷的环保全息镭射定位包装材料的制作方法,其特征在于:基于定位光标在铝层(3)表面进行连续套准印刷形成印刷层(5)包括:The method for making an environmentally-friendly holographic laser positioning packaging material of in-line printing according to claim 12, wherein the printing layer (5) formed by continuous registration printing on the surface of the aluminum layer (3) based on the positioning cursor comprises:
    根据镭射模压出的定位光标的位置进行连续套准印刷,在铝层(3)的表面印刷出包装材料的宣传图案。Continuous registration printing is performed according to the position of the positioning cursor extruded by the laser die, and the promotional pattern of the packaging material is printed on the surface of the aluminum layer (3).
  18. 根据权利要求12所述的连线印刷的环保全息镭射定位包装材料的制作方法,其特征在于:所述表面处理包括上光油或植绒。The method for manufacturing an in-line printed environmentally friendly holographic laser positioning packaging material according to claim 12, wherein the surface treatment includes varnish or flocking.
PCT/CN2021/129293 2021-02-26 2021-11-08 Inline printing-based eco-friendly holographic laser positioning packaging material and manufacturing method therefor WO2022179177A1 (en)

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